1. Field of the Invention
The present invention is generally related to processes and systems for recovering a liquid natural gas (“LNG”) from a hydrocarbon-containing gas. More particularly, the present invention is generally related to processes and systems for recovering a LNG from a synthesis gas using a single closed-loop mixed refrigerant cycle.
2. Description of the Related Art
Synthesis gas, which is also known as “syngas,” is a common byproduct formed during steam reforming of natural gas or hydrocarbons, coal gasification, and waste-to-energy gasification. Syngas generally contains varying amounts of carbon monoxide and hydrogen and, in some circumstances, can also contain notable amounts of methane. Due to the commercial value of methane, it can be desirable in some cases to remove at least a portion of the methane from syngas. However, the presence of carbon monoxide and hydrogen in these gases can greatly reduce the efficiencies of conventional recovery processes since these processes are generally unable to fully condense and separate the carbon monoxide and hydrogen from the methane at the recovery temperatures commonly used during these various processes. Thus, the recovered methane can be contaminated with high levels of residual carbon monoxide and/or hydrogen. Consequently, the presence of carbon monoxide and hydrogen in syngas and other hydrocarbon-containing gases can negatively impact the recovery of methane from these gases.
Therefore, there is a need for processes and systems that can effectively recover methane from syngas and other hydrocarbon-containing gases despite the presence of carbon monoxide and hydrogen in these gases.
One or more embodiments described herein concern a process for recovering liquid methane gas from a hydrocarbon-containing gas. The method comprises: (a) cooling and at least partially condensing the hydrocarbon-containing gas to thereby provide a cooled feed stream; (b) separating at least a portion of the cooled feed stream in a primary distillation column to thereby form a first methane-rich bottom stream and a first methane-poor overhead stream; (c) fractionating at least a portion of the first methane-rich bottom stream in a secondary distillation column to thereby form a second methane-rich bottom stream and a second methane-poor overhead stream; and (d) recovering at least a portion of the second methane-rich stream to thereby produce an LNG-enriched stream.
One or more embodiments described herein concern a process for recovering liquid methane gas from a hydrocarbon-containing gas. The process comprises: (a) cooling and at least partially condensing the hydrocarbon-containing gas to thereby provide a cooled feed stream; (b) separating at least a portion of the cooled feed stream in a primary distillation column to thereby form a first methane-rich liquid stream and a first methane-poor vapor stream; (c) fractionating at least a portion of the first methane-rich liquid stream in a secondary distillation column to thereby form a second methane-rich liquid stream and a second methane-poor vapor stream; and (d) cooling at least a portion of the second methane-rich liquid stream to thereby produce an LNG-enriched liquid stream.
One or more embodiments described herein concern a facility for recovering liquid methane gas from a hydrocarbon-containing gas. The facility comprises: a primary heat exchanger having a first cooling pass disposed therein, wherein the first cooling pass is configured to cool the hydrocarbon-containing gas into a cooled hydrocarbon-containing gas; a vapor-liquid separator in fluid communication with the first cooling pass, wherein the vapor-liquid separator is configured to separate the cooled hydrocarbon-containing gas into a first methane-poor overhead stream and a first methane-rich bottom stream; a primary distillation column in fluid communication with the vapor-liquid separator, wherein the primary distillation column comprises a first liquid inlet to receive the first methane-rich bottom stream and a first vapor inlet to receive the first methane-poor overhead stream, wherein the primary distillation column is configured to separate the first methane-rich bottom stream and the first methane-poor overhead stream into a second methane-rich bottom stream and a second methane-poor overhead stream; a secondary distillation column in fluid communication with the primary distillation column, wherein the secondary distillation column comprises a second liquid inlet to receive the second methane-rich bottom stream and a second vapor inlet to receive the second methane-poor overhead stream, wherein the secondary distillation column is configured to separate the second methane-rich bottom stream and the second methane-poor overhead stream into a third methane-rich bottom stream and a third methane-poor overhead stream; a second cooling pass disposed within the primary heat exchanger in fluid communication with the secondary distillation column, wherein the second cooling pass is configured to cool the third-methane rich bottom stream into an LNG-enriched liquid stream; and a single closed-loop mixed refrigeration cycle at least partially disposed within the primary heat exchanger. The single closed-loop refrigeration cycle comprises a refrigerant compressor defining a suction inlet for receiving a mixed refrigerant stream and a discharge outlet for discharging a stream of compressed mixed refrigerant; a first refrigerant cooling pass in fluid communication with the discharge outlet of the refrigerant compressor, wherein the first refrigerant cooling pass is configured to cool the compressed mixed refrigerant stream; a refrigerant expansion device in fluid communication with the first refrigerant cooling pass, wherein the refrigerant expansion device is configured to expand the cooled mixed refrigerant stream and generate refrigeration; and a first refrigerant warming pass in fluid communication with the refrigerant expansion device and the suction inlet of the refrigerant compressor, wherein the first refrigerant warming pass is configured to warm the expanded mixed refrigerant stream via indirect heat exchange.
Embodiments of the present invention are described herein with reference to the following drawing FIGURES, wherein:
The following detailed description of embodiments of the invention references the accompanying drawing. The embodiments are intended to describe aspects of the invention in sufficient detail to enable those skilled in the art to practice the invention. Other embodiments can be utilized and changes can be made without departing from the scope of the claims. The following detailed description is, therefore, not to be taken in a limiting sense. The scope of the present invention is defined only by the appended claims, along with the full scope of equivalents to which such claims are entitled.
The present invention is generally directed to processes and systems for the separation of a hydrocarbon-containing gas into an LNG stream and a byproduct stream comprising hydrogen and carbon monoxide. As described below, the processes and systems can utilize a refrigerant system to recover at least a portion of the methane from the hydrocarbon-containing gases. Although
Turning now to
As shown in
Depending on its source, the hydrocarbon-containing gas can comprise varying amounts of methane, hydrogen, and carbon monoxide. For example, the hydrocarbon-containing gas can comprise at least about 1, 5, 10, 15, or 25 and/or not more than about 80, 70, 60, 50, or 40 mole percent of methane. More particularly, the hydrocarbon-containing gas can comprise in the range of about 1 to 80, 5 to 70, 10 to 60, 15 to 50, 15 to 50, or 25 to 40 mole percent of methane. It should be noted that all mole percentages are based on the total moles of the hydrocarbon-containing gas.
Additionally or alternatively, the hydrocarbon-containing gas can comprise at least about 15, 25, or 40 and/or not more than about 95, 90, or 80 mole percent of carbon monoxide. More particularly, the hydrocarbon-containing gas can comprise in the range of about 15 to 95, 25 to 90, or 40 to 80 mole percent of carbon monoxide. Furthermore, in certain embodiments, hydrocarbon-containing gas can comprise at least about 25, 40, or 50 and/or not more than about 99, 90, or 75 mole percent of hydrogen. More particularly, the hydrocarbon-containing gas can comprise in the range of about 25 to 99, 40 to 90, or 50 to 70 mole percent of hydrogen.
As one skilled in the art would appreciate, the hydrogen and carbon monoxide contents of the hydrocarbon-containing gas can vary depending on its source. Thus, in various embodiments, the hydrocarbon-containing gas can comprise a molar ratio of hydrogen to carbon monoxide of at least 1:1, 1.5:1, or 2:1 and/or not more than 10:1, 5:1, or 2.5:1. More particularly, the hydrocarbon-containing gas can comprise a molar ratio of hydrogen to carbon monoxide in the range of 1:1 to 10:1, 1.5:1 to 5:1, or 2:1 to 2.5:1.
Furthermore, the hydrocarbon-containing gas can comprise some amount of C2-C5 components, which includes paraffinic and olefinic isomers thereof. For example, the hydrocarbon-containing gas can comprise less than 15, 10, 5, or 2 mole percent of C2-C5 components.
As shown in
The treated gas stream exiting pretreatment zone 16 via conduit 112 can then be routed to a dehydration unit 18, wherein substantially all of the residual water can be removed from the feed gas stream. Dehydration unit 18 can utilize any known water removal system, such as, for example, beds of molecular sieve. Once dried, the gas stream in conduit 114 can have a temperature of at least 5, 10, or 15° C. and/or not more than 100, 75, or 40° C. More particularly, the gas stream in conduit 114 can have a temperature in the range of 5 to 100° C., 10 to 75° C., or 15 to 40° C. Additionally or alternatively, the gas stream in conduit 114 can have a pressure of at least 1.5, 2.5, 3.5, or 4.5 and/or 9, 8, 7, or 6 MPa. More particularly, the gas stream in conduit 114 can have a pressure in the range of 1.5 to 9, 2.5 to 8, 3.5 to 7, or 4.5 to 6 MPa.
As shown in
The hydrocarbon-containing feed gas stream passing through the cooling pass 22 of primary heat exchanger 20 can be cooled and at least partially condensed via indirect heat exchange with refrigerant and/or residue gas streams in respective passes 24 and 26, which are described below in further detail. During cooling, a substantial portion of the methane components in the feed gas stream can be condensed out of the vapor phase to thereby provide a cooled, two-phase gas stream in conduit 116. In one or more embodiments, at least 50, 60, 70, 80, or 90 mole percent of the total amount of methane introduced into primary exchanger 20 via conduit 114 can be condensed within cooling pass 22.
The cooled gas stream in conduit 116 can have a temperature of at least −30, −40, −50, or −60° C. and/or not more than about −130, −120, −110, or −100° C. More particularly, the cooled gas stream in conduit 116 can have a temperature in the range of about −30 to −130° C., −40 to −120° C., −50 to −110° C., or −60 to −100° C. In certain embodiments, the cooled gas stream in conduit 116 can have a temperature of about −66° C. Additionally or alternatively, the cooled gas stream in conduit 116 can have a pressure of at least 1.5, 2.5, 3.5, or 4.5 and/or 9, 8, 7, or 6 MPa. More particularly, the gas stream in conduit 114 can have a pressure in the range of 1.5 to 9, 2.5 to 8, 3.5 to 7, or 4.5 to 6 MPa.
As shown in
While in the reboiler 28, the cooled gas stream from conduit 116 can be further cooled by the liquid stream from conduit 118. For example, while in the reboiler 28, the temperature of the cooled gas stream from conduit 116 can be lowered by at least 20, 30, 40, or 50° C. and/or not more than about 100, 80, 70, or 60° C. More particularly, while in the reboiler 28, the temperature of the cooled gas stream from conduit 116 can be lowered in the range of 20 to 100° C., 30 to 80° C., 40 to 70° C., or 50 to 60° C.
Upon exiting the reboiler 28, the cooled gas stream in conduit 120 can have a pressure of at least 1.5, 2.5, 3.5, or 4.5 and/or 9, 8, 7, or 6 MPa. More particularly, the gas stream in conduit 120 can have a pressure in the range of 1.5 to 9, 2.5 to 8, 3.5 to 7, or 4.5 to 6 MPa. It should be noted that the only pressure drop can be generally attributed to inefficiencies associated with the piping and heat exchanger.
Turning again to
The cooled gas stream in conduit 122 can have a temperature of at least temperature of at least −120, −130, −140, or −−145° C. and/or not more than about −200, −190, −180, or −165° C. More particularly, the cooled gas stream in conduit 122 can have a temperature in the range of about −120 to −200° C., −130 to −190° C., −140 to −180° C., or −145 to −165° C. In certain embodiments, the cooled gas stream in conduit 122 can have a temperature of about −156° C. Additionally or alternatively, the cooled gas stream in conduit 122 can have a pressure of at least 1.5, 2.5, 3.5, or 4.5 and/or 9, 8, 7, or 6 MPa. More particularly, the gas stream in conduit 122 can have a pressure in the range of 1.5 to 9, 2.5 to 8, 3.5 to 7, or 4.5 to 6 MPa.
As shown in
The separation vessel 34 can be any suitable vapor-liquid separation vessel and can have any number of actual or theoretical separation stages. In one or more embodiments, separation vessel 34 can comprise a single separation stage, while in other embodiments, the separation vessel 34 can include 2 to 10, 4 to 20, or 6 to 30 actual or theoretical separation stages. When separation vessel 34 is a multistage separation vessel, any suitable type of column internals, such as mist eliminators, mesh pads, vapor-liquid contacting trays, random packing, and/or structured packing, can be used to facilitate heat and/or mass transfer between the vapor and liquid streams. In some embodiments, when separation vessel 34 is a single-stage separation vessel, few or no column internals can be employed.
In various embodiments, the separation vessel 34 can operate at a pressure of at least 1.5, 2.5, 3.5, or 4.5 and/or 9, 8, 7, or 6 MPa. More particularly, the separation vessel 34 can operate at a pressure in the range of 1.5 to 9, 2.5 to 8, 3.5 to 7, or 4.5 to 6 MPa. The initial methane-rich bottom stream in conduit 124 and/or the initial methane-poor overhead stream in conduit 126 can have a temperature of at least temperature of at least −120, −130, −140, or −145° C. and/or not more than about −200, −190, −180, or −165° C. More particularly, the initial methane-rich bottom stream in conduit 124 and/or the initial methane-poor overhead stream in conduit 126 can have a temperature in the range of about −120 to −200° C., −130 to −190° C., −140 to −180° C., or −145 to −165° C.
The initial methane-rich bottom stream in conduit 124 can be in the form of a liquid and can comprise a large portion of methane. For example, the initial methane-rich bottom stream in conduit 124 can comprise at least about 10, 25, 40, or 50 and/or not more than about 95, 85, 75, or 70 mole percent of methane. More particularly, the initial methane-rich bottom stream in conduit 124 can comprise in the range of about 10 to 95, 25 to 85, 40 to 75, or 50 to 70 mole percent of methane. Furthermore, the initial methane-rich bottom stream in conduit 124 can comprise at least 50, 60, 70, 80, or 90 percent of the methane originally present in the stream from conduit 122.
The initial methane-rich bottom stream in conduit 124 can also comprise residual amounts of hydrogen and carbon monoxide. For example, the initial methane-rich bottom stream in conduit 124 can comprise less than about 40, 30, 20, or 10 mole percent of hydrogen. Additionally or alternatively, the initial methane-rich bottom stream in conduit 124 can comprise less than about 60, 50, 45, or 40 mole percent of carbon monoxide.
The initial methane-poor overhead stream in conduit 126 can be in the form of a vapor and comprise a large portion of hydrogen and/or carbon monoxide. For example, the initial methane-poor overhead stream in conduit 126 can comprise at least about 10, 20, 35, or 50 and/or not more than about 95, 90, 85, or 70 mole percent of hydrogen. More particularly, the initial methane-poor overhead stream in conduit 126 can comprise in the range of 10 to 95, 20 to 90, 35 to 85, or 50 to 70 mole percent of hydrogen. Additionally or alternatively, the initial methane-poor overhead stream in conduit 126 can comprise at least about 5, 10, 15, or 20 and/or not more than about 80, 60, 50, or 40 mole percent of carbon monoxide. More particularly, the initial methane-poor overhead stream in conduit 126 can comprise in the range of about 5 to 80, 10 to 60, 15 to 50, or 20 to 40 mole percent of carbon monoxide. Furthermore, the initial methane-poor overhead stream in conduit 126 can contain minor amounts of methane. For example, the initial methane-poor overhead stream in conduit 126 can comprise less than about 20, 15, 10, or 5 mole percent of methane.
As depicted in
As a result of the expansion, the temperature of the flashed or expanded fluid stream in conduit 128 can be at least 2, 5, or 10° C. and/or not more than 50, 40, or 30° C. lower than the temperature of the stream in conduit 124. Furthermore, the pressure of the flashed or expanded fluid stream in conduit 128 can be at least 0.1, 0.2, or 0.3 and/or not more than 1.5, 1, or 0.5 MPa lower than the pressure of the stream in conduit 124.
As shown in
The distillation column 40 can be any vapor-liquid separation vessel capable of further separating methane from hydrogen and carbon monoxide. In one or more embodiments, the distillation column 40 can be a multi-stage distillation column comprising at least 2, 5, 10, or 12 and/or not more than 50, 40, 30, or 20 actual or theoretical separation stages. When the distillation column 40 comprises a multi-stage column, one or more types of column internals may be utilized in order to facilitate heat and/or mass transfer between the vapor and liquid phases. Examples of suitable column internals can include, but are not limited to, vapor-liquid contacting trays, structured packing, random packing, and any combination thereof.
In various embodiments, the distillation column 40 can be operable to separate at least 65, 75, 85, 90, or 99 percent of the methane present in the fluid streams introduced thereto. The distillation column 40 can operate at a pressure of at least about 1, 1.5, 2, or 2.5 and/or not more than about 5, 4, 3.5, or 3 MPa. More particularly, the distillation column 40 can operate at a pressure in the range of 1 to 5, 1.5 to 4, 2 to 3.5, or 2.5 to 3 MPa. In certain embodiments, the distillation column 40 can operate at a pressure of about 2.6 MPa.
The temperature of the distillation column 40 can vary depending on the contents of the hydrocarbon-containing gas introduced into the system. In various embodiments, the top half of the distillation column 40 can operate at a temperature of at least −125, −150, −160, or −170° C. and/or not more than about −215, −200, −190, or −180° C. More particularly, the top half of the distillation column 40 can operate at a temperature in the range of −125 to −215° C., −150 to −200° C., −160 to −190° C., or −170 to −180° C. In certain embodiments, the top half of the distillation column 40 can operate at a temperature of about −173° C. Furthermore, the bottom half of the distillation column 40 can operate at a temperature of at least about −110, −125, −140, or −150° C. and/or not more than about −200, −190, −180, or −160° C. More particularly, the bottom half of the distillation column 40 can operate at a temperature in the range of −110 to −200° C., −125 to −190° C., −140 to −180° C., or −150 to −160° C. In certain embodiments, the bottom half of the distillation column 40 can operate at a temperature of about −158° C. Additional information regarding the operation of the distillation column 40 is discussed in further detail below.
Referring back to the initial methane-poor overhead stream in conduit 126, at least a portion of this stream can be transferred to an expansion device 42. As shown in
As a result of the expansion, the temperature of the flashed or expanded fluid stream in conduit 130 can be at least 2, 5, or 10° C. and/or not more than 50, 40, or 30° C. lower than the temperature of the stream in conduit 126. Furthermore, the pressure of the flashed or expanded fluid stream in conduit 130 can be at least 0.1, 0.2, or 0.3 and/or not more than 1.5, 1, or 0.5 MPa lower than the pressure of the stream in conduit 126.
As shown in
As depicted in
The first methane-rich bottom stream in conduit 132 can be in the form of a liquid and comprise a significant amount of methane. For example, the first methane-rich bottom stream in conduit 132 can comprise at least about 10, 25, 40, or 50 and/or not more than about 95, 85, 75, or 70 mole percent of methane. More particularly, the first methane-rich bottom stream in conduit 132 can comprise in the range of 10 to 95, 25 to 85, 40 to 75, or 50 to 70 mole percent of methane.
Furthermore, the first methane-rich bottom stream in conduit 132 can also comprise some residual hydrogen and carbon monoxide. For example, the first methane-rich bottom stream in conduit 132 can comprise less than 15, 10, 5, or 2 mole percent of hydrogen. Additionally or alternatively, first methane-rich bottom stream in conduit 132 can comprise less than about 60, 50, 45, or 40 mole percent of carbon monoxide.
The first methane-poor overhead stream in conduit 134 can be in the form of a vapor and comprise significant amounts of hydrogen and carbon monoxide. For example, the first methane-poor overhead stream in conduit 134 can comprise at least about 25, 40, 60, or 75 and/or not more than about 99, 95, 90, or 85 mole percent of hydrogen. More particularly, the first methane-poor overhead stream in conduit 134 can comprise in the range of 25 to 99, 40 to 95, 60 to 90, or 75 to 85 mole percent of hydrogen. Additionally or alternatively, the first methane-poor overhead stream in conduit 134 can comprise at least about 1, 5, 10, or 20 and/or not more than about 75, 60, 50, or 40 mole percent of carbon monoxide. More particularly, the first methane-poor overhead stream in conduit 134 can comprise in the range of 1 to 75, 5 to 60, 10 to 50, or 20 to 40 mole percent of carbon monoxide.
Furthermore, the first methane-poor overhead stream in conduit 134 can also comprise some residual methane. For example, the first methane-poor overhead stream in conduit 134 can comprise less than about 10, 5, 1, or 0.5 mole percent of methane.
As shown in
Turning once again to the first methane-rich bottom stream in conduit 132, at least a portion of this stream can be introduced into the methane fractionator 30 via inlet 50. In various embodiments, the purpose of the methane fractionator is to further purify the stream in conduit 132.
The methane fractionator 30 can be any vapor-liquid separation vessel capable of further separating methane from hydrogen and carbon monoxide. In one or more embodiments, the methane fractionator 30 can be a multi-stage distillation column comprising at least 2, 5, 10, or 12 and/or not more than 50, 40, 30, or 20 actual or theoretical separation stages. When the methane fractionator 30 comprises a multi-stage column, one or more types of column internals may be utilized in order to facilitate heat and/or mass transfer between the vapor and liquid phases. Examples of suitable column internals can include, but are not limited to, vapor-liquid contacting trays, structured packing, random packing, and any combination thereof.
In various embodiments, the methane fractionator 30 can be operable to separate at least 65, 75, 85, 90, or 99 percent of the methane present in the fluid streams introduced thereto. The methane fractionator 30 can operate at a pressure of at least about 0.25, 0.5, 1, or 1.5 and/or not more than about 4, 3, 2, or 1.8 MPa. More particularly, the methane fractionator 30 can operate at a pressure in the range of 0.25 to 4, 0.5 to 3, 1 to 2, or 1.5 to 1.8 MPa. In certain embodiments, the methane fractionator 30 can operate at a pressure of about 1.7 MPa.
The temperature of the methane fractionator 30 can vary depending on the contents of the hydrocarbon-containing gas introduced into the system. In various embodiments, the top half of the methane fractionator 30 can operate at a temperature of at least −110, −125, −140, or −150° C. and/or not more than about −215, −200, −175, or −160° C. More particularly, the top half of the methane fractionator 30 can operate at a temperature in the range of −110 to −215° C., −125 to −200° C., −140 to −175° C., or −150 to −160° C. In certain embodiments, the top half of the methane fractionator 30 can operate at a temperature of about −154° C. Furthermore, the bottom half of the methane fractionator 30 can operate at a temperature of at least about −80, −90, −100, or −110° C. and/or not more than about −200, −160, −130, or −120° C. More particularly, the bottom half of the methane fractionator 30 can operate at a temperature in the range of −80 to −200° C., −90 to −160° C., −100 to −130° C., or −110 to −120° C. In certain embodiments, the bottom half of the methane fractionator 30 can operate at a temperature of about −112° C.
As depicted in
The second methane-rich bottom stream in conduit 140 can be in the form of a liquid and comprise significant amounts of methane. For example, the second methane-rich bottom stream in conduit 140 can comprise at least about 60, 75, 90, or 99 mole percent of methane. Furthermore, the second methane-rich bottom stream in conduit 140 can also contain residual amounts of hydrogen and/or carbon monoxide. For instance, the second methane-rich bottom stream in conduit 140 can comprise less than 1, 0.5, 0.1, or 0.01 mole percent of hydrogen. Additionally or alternatively, the second methane-rich bottom stream in conduit 140 can comprise less than 1, 0.5, 0.1, or 0.01 mole percent of carbon monoxide.
The second methane-poor overhead stream in conduit 142 can be in the form of a vapor and comprises predominantly hydrogen and/or carbon monoxide. For example, the second methane-poor overhead stream in conduit 142 can comprise at least about 1, 2, 4, or 10 and/or not more than about 40, 30, 20, or 15 mole percent of hydrogen. More particularly, the second methane-poor overhead stream in conduit 142 can comprise in the range of 1 to 40, 2 to 30, 4 to 20, or 10 to 15 mole percent of hydrogen. Additionally or alternatively, the second methane-poor overhead stream in conduit 142 can comprise at least about 50, 65, 80, or 90 mole percent of carbon monoxide. Moreover, the second methane-poor overhead stream in conduit 142 can comprise some residual methane. For instance, the second methane-poor overhead stream in conduit 142 can comprise less than 1, 0.5, 0.1, or 0.01 mole percent of methane.
As shown in
Turning back to the second methane-poor overhead stream in conduit 142, this stream can be routed to a cooling pass 54 disposed within the primary heat exchanger 20, wherein the stream can be cooled and at least partially condensed via indirect heat exchange with the refrigerant and/or residue gas streams in respective passes 24 and 26, which are described below in further detail. The cooled gas stream exiting cooling pass 54 via conduit 146 can have a temperature of at least −120, −130, −140, or −145° C. and/or not more than about −200, −190, −180, or −165° C. More particularly, the cooled stream in conduit 146 can have a temperature in the range of about −120 to −200° C., −130 to −190° C., −140 to −180° C., or −145 to −165° C. In certain embodiments, the cooled stream in conduit 146 can have a temperature of about −156° C.
The cooled stream in conduit 146 can then be routed to a reflux condenser drum 56, wherein at least a portion of the cooled stream in conduit 146 can be divided into a methane-rich liquid reflux stream and an overhead methane-poor stream. The methane-rich liquid reflux stream exits the reflux condenser drum 56 via conduit 148 and the overhead methane-poor stream exits the reflux condenser drum 56 via conduit 150. The methane-rich liquid reflux in conduit 148 can have the same or similar composition to the second methane-rich bottom stream described above and the overhead methane-poor stream in conduit 150 can have the same or similar composition to the second methane-poor overhead stream described above.
The methane-rich liquid reflux in conduit 148 can be pumped via reflux pump 58 to conduit 152 where it can be transferred to expansion device 62 and/or expansion device 64, where the pressure of the liquid can be reduced to thereby flash or vaporize at least a portion thereof. Expansion devices 62, 64 can be any suitable expansion device, such as, for example, a Joule-Thompson valve or orifice or a hydraulic turbine. It should be noted that expansion devices 62, 64 can function and operate in the same or similar manner as expansion device 36 described above. In certain embodiments, at least a portion of the methane-rich liquid reflux in conduit 152 can be introduced into expansion device 62 and transferred via conduit 154 to be used as a reflux stream in the distillation column 40. Additionally or alternatively, at least a portion of the methane-rich liquid reflux in conduit 152 can be introduced into expansion device 64 and transferred via conduit 156 to be used as a reflux stream in the methane fractionator 30.
Turning again to
Turning now to refrigeration cycle 12 of LNG recovery facility 10 depicted in
The resulting two-phase stream in conduit 164 can be introduced into interstage accumulator 74, wherein the vapor and liquid portions can be separated. A vapor stream withdrawn from accumulator 74 via conduit 166 can be routed to the inlet of the second (high pressure) stage of refrigerant compressor 70, wherein the stream can be further compressed. The resulting compressed refrigerant vapor stream can be recombined with a portion of the liquid phase refrigerant withdrawn from interstage accumulator 74 via conduit 168 and pumped to pressure via refrigerant pump 82, as shown in
The combined refrigerant stream in conduit 170 can then be routed to refrigerant condenser 76, wherein the pressurized refrigerant stream can be cooled and at least partially condensed via indirect heat exchange with a cooling medium (e.g., cooling water) before being introduced into refrigerant accumulator 78 via conduit 172. As shown in
As the compressed refrigerant stream flows through refrigerant cooling pass 24, the stream is condensed and sub-cooled, such that the temperature of the liquid refrigerant stream withdrawn from primary heat exchanger 20 via conduit 178 is well below the bubble point of the refrigerant mixture. The sub-cooled refrigerant stream in conduit 178 can then be expanded via passage through an expansion device 86 (illustrated herein as Joule-Thompson valve 86), wherein the pressure of the stream can be reduced, thereby cooling and at least partially vaporizing the refrigerant stream. The cooled, two-phase refrigerant stream in conduit 180 can then be routed through a refrigerant warming pass 26, wherein a substantial portion of the refrigeration generated via the expansion of the refrigerant can be recovered as cooling for one or more process streams, including the feed stream flowing through cooling pass 24, as discussed in detail previously. The warmed refrigerant stream withdrawn from primary heat exchanger 20 via conduit 182 can then be routed to refrigerant suction drum 80 before being compressed and recycled through closed-loop refrigeration cycle 12 as previously discussed.
According to various embodiments, during each step of the above-discussed refrigeration cycle, the temperature of the refrigerant can be maintained such that at least a portion, or a substantial portion, of the methane originally present in the feed gas stream can be condensed in primary exchanger 20. For example, in various embodiments, at least 50, 65, 75, 80, 85, 90, or 95 percent of the total methane originally present in the feed gas stream introduced into primary exchanger 20 can be condensed. In some embodiments, operating refrigeration cycle 12 at warmer temperatures may decrease the formation of one or more undesirable byproducts within the feed gas stream, such as, for example nitrogen oxide gums (e.g., NOx gums) which can form at temperatures below about −100° C. According to embodiments of the present invention, formation of such byproducts can be minimized or nearly eliminated.
In one embodiment, the refrigerant utilized in the closed-loop refrigeration cycle 12 can be a mixed refrigerant. As used herein, the term “mixed refrigerant” refers to a refrigerant composition comprising two or more constituents. In one embodiment, the mixed refrigerant utilized by refrigeration cycle 12 can comprise two or more constituents selected from the group consisting of methane, ethylene, ethane, propylene, propane, isobutane, n-butane, isopentane, n-pentane, and combinations thereof. In some embodiments, the refrigerant composition can comprise methane, ethane, propane, normal butane, and isopentane and can substantially exclude certain components, including, for example, nitrogen or halogenated hydrocarbons. According to one or more embodiments, the refrigerant composition can have an initial boiling point of at least −80, −85, or −90° C. and/or not more than −50, −55, or −60° C. Various specific refrigerant compositions are contemplated according to embodiments of the present invention. Table 1, below, summarizes broad, intermediate, and narrow ranges for several exemplary refrigerant mixtures.
In some embodiments of the present invention, it may be desirable to adjust the composition of the mixed refrigerant to thereby alter its cooling curve and, therefore, its refrigeration potential. Such a modification may be utilized to accommodate, for example, changes in composition and/or flow rate of the feed gas stream introduced into LNG recovery facility 10. In one embodiment, the composition of the mixed refrigerant can be adjusted such that the heating curve of the vaporizing refrigerant more closely matches the cooling curve of the feed gas stream. One method for such curve matching is described in detail in U.S. Pat. No. 4,033,735, the disclosure of which is incorporated herein by reference in its entirety.
Thus, the above described processes and systems can be utilized to recover a LNG stream from a hydrocarbon-containing feed gas stream. Furthermore, due to configurations described above, the processes and systems described herein due not need to utilize a nitrogen refrigerant stream that is separate from the mixed refrigerant system described above.
The preferred forms of the invention described above are to be used as illustration only, and should not be used in a limiting sense to interpret the scope of the present invention. Modifications to the exemplary embodiments, set forth above, could be readily made by those skilled in the art without departing from the spirit of the present invention.
The inventors hereby state their intent to rely on the Doctrine of Equivalents to determine and assess the reasonably fair scope of the present invention as it pertains to any apparatus not materially departing from but outside the literal scope of the invention as set forth in the following claims.
It should be understood that the following is not intended to be an exclusive list of defined terms. Other definitions may be provided in the foregoing description, such as, for example, when accompanying the use of a defined term in context.
As used herein, the terms “a,” “an,” and “the” mean one or more.
As used herein, the term “and/or,” when used in a list of two or more items, means that any one of the listed items can be employed by itself or any combination of two or more of the listed items can be employed. For example, if a composition is described as containing components A, B, and/or C, the composition can contain A alone; B alone; C alone; A and B in combination; A and C in combination, B and C in combination; or A, B, and C in combination.
As used herein, the terms “comprising,” “comprises,” and “comprise” are open-ended transition terms used to transition from a subject recited before the term to one or more elements recited after the term, where the element or elements listed after the transition term are not necessarily the only elements that make up the subject.
As used herein, the terms “having,” “has,” and “have” have the same open-ended meaning as “comprising,” “comprises,” and “comprise” provided above.
As used herein, the terms “including,” “include,” and “included” have the same open-ended meaning as “comprising,” “comprises,” and “comprise” provided above.
As used herein, references to “one embodiment,” “an embodiment,” or “embodiments” mean that the feature or features being referred to are included in at least one embodiment of the technology. Separate references to “one embodiment,” “an embodiment,” or “embodiments” in this description do not necessarily refer to the same embodiment and are also not mutually exclusive unless so stated and/or except as will be readily apparent to those skilled in the art from the description. Thus, the present invention can include a variety of combinations and/or integrations of the embodiments described herein.
As used herein, the term “about” means that the associated value can vary by 10 percent from its recited value.
The present description uses numerical ranges to quantify certain parameters relating to the invention. It should be understood that when numerical ranges are provided, such ranges are to be construed as providing literal support for claim limitations that only recite the lower value of the range as well as claim limitations that only recite the upper value of the range. For example, a disclosed numerical range of 10 to 100 provides literal support for a claim reciting “greater than 10” (with no upper bounds) and a claim reciting “less than 100” (with no lower bounds).
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