Patent Grant
10745637
The invention relates generally to a lubricant composition, and more particularly to a lubricant composition having a lubricant additive used for tribologically-activated in situ deposition of a carbon film.
The background description provided herein is for the purpose of generally presenting the context of the present invention. The subject matter discussed in the background of the invention section should not be assumed to be prior art merely as a result of its mention in the background of the invention section. Similarly, a problem mentioned in the background of the invention section or associated with the subject matter of the background of the invention section should not be assumed to have been previously recognized in the prior art. The subject matter in the background of the invention section merely represents different approaches, which in and of themselves may also be inventions. Work of the presently named inventors, to the extent it is described in the background of the invention section, as well as aspects of the description that may not otherwise qualify as prior art at the time of filing, are neither expressly nor impliedly admitted as prior art against the present invention.
The efficiency and reliability of automobiles and heavy machinery are ever-present concerns for the economic, industrial, and environmental status and growth of the world. In vehicle engine systems, at least one third of the energy from fuel goes into overcoming frictional losses [1]. A study by the U.S. Department of Energy concluded that $120 billion could be saved annually by reducing friction and wear in engine and drivetrain components, and tribological improvements could also save the utilities industry $2.5 billion annually. These savings can come from both reduced friction, as well as a reduction in repair costs from wear damage. The study suggests that these savings can most likely be achieved through enhanced tribological surface coatings and lubricant additives [2].
Engine, electric generators, and all types of machinery components are very commonly lubricated with an oil-based lubricant. These oils are viscosity-controlled fluids that contain a wide range of additives. Those lubricant additives are commonly used to soften the contact between two solids, optimize the viscosity of lubricants, and generate protective layers on top of contact surfaces. The lubricant additives used to reduce friction and wear include, for example, zinc dialkyldithiophosphates (ZDDP), molybdenum disulfide (MoS2), and carbon coating. However, it is still a challenge to form a lubricant composition that is environment friendly, highly efficient, long-lasting, wear preventing, and can be applied in situ.
Therefore, a heretofore unaddressed need exists in the art to address the aforementioned deficiencies and inadequacies.
In one aspect, the invention is related to a lubricant additive. The lubricant additive includes a surface active group attractable to a target surface, and a carbon containing component connected to the surface active group, for providing a carbon source to form a carbon film on the target surface.
In one embodiment, the carbon film is formed only when tribological energy activates the lubricant additive to unravel the carbon containing component. Flash heating from asperity contacts heats the lubricant additive to above a threshold temperature, which causes decomposition of the carbon containing component, releases lubricious carbon onto the target surface, thereby forming the carbon film on the target surface. Carbon is not formed in the bulk fluid before the lubricant additive is used as a lubricant.
In certain embodiments, the lubricant additive binds to the target surface via polar (electrostatic) or chemical interactions through the surface active group.
In certain embodiments, the surface active group has positive charges, and the target surface has negative charges, and vice versa, such that the surface active group is attractable to the target surface.
In certain embodiments, the surface active group includes a carboxyl group, a hydroxyl group, a siloxyl group, an amine group, or a mixture thereof.
In certain embodiments, the carbon containing component comprises a carbon ring, a straight carbon chain, a branched carbon chain, or a mixture thereof.
In one embodiment, the carbon ring includes three or more carbon atoms arranged in a strained, metastable ring, such as cyclopropane or cyclobutane.
In certain embodiments, the lubricant additive further includes a spacer group connecting the carbon ring to the surface active group. In one embodiment, the spacer group is a carbon chain having 1-20, or more, carbon atoms. In one embodiment, the length of the spacer is configured to form the carbon film under a temperature and a pressure at the target surface.
In certain embodiments, the lubricant additive includes cyclopropanecarboxylic acid, cyclobutanecarboxylic acid, cyclopropylacetic acid, cyclopropanol, cyclobutanol, or a mixture thereof.
In certain embodiments, the carbon film on the target surface is formed by releasing the carbon source from the carbon containing component under a pressure and a temperature at the target surface. In one embodiment, the pressure and the temperature at the target surface is resulted by running a target machine having the target surface. In certain embodiments, the temperature at the target surface is in a range of from about room temperature to about 500° C. The room temperature may be 20° C. or 25° C. In one embodiment, the temperature at the target surface is in a range of 60° C.-300° C. In one embodiment, the temperature at the target surface is in a range of 90° C.-115° C. In one embodiment, the temperature at the target surface is higher than 90° C. due to the heat generated by friction. In one embodiment, the nominal Hertzian pressure at the target surface is in a range of 0.4 to 2.0 GPa.
In certain embodiments, the carbon film includes a plurality of graphitic sheets, amorphous and diamond-like carbon, or a mixture thereof. In one embodiment, percentages of the graphitic sheet and the amorphous and diamond-like carbon in the carbon film depends on a temperature and a pressure at the target surface. In one embodiment, the carbon film comprises substantially the graphitic sheet.
In another aspect, the present invention relates to a lubricant composition. In one embodiment, the lubricant composition includes a plurality of lubricant additive molecules. Each of the lubricant additive molecules has a surface active group attractable to a target surface, and a carbon containing component connected to the surface active group, for providing a carbon source to form a carbon film on the target surface. The target surface can be a surface of an engine or other machinery.
In one embodiment, the lubricant composition further include a base lubricant. That is, the lubricant additive molecules are added to a base lubricant, such as an oil-based lubricant, to form the lubricant composition.
In certain embodiments, the lubricant composition has about 1-10 weight percentage (wt %) of the lubricant additive molecules. In one embodiment, the lubricant composition comprises about 2.5 wt % of the lubricant additive molecules.
In certain embodiments, the lubricant additive binds to the target surface via polar (electrostatic) or chemical interactions through the surface active group.
In certain embodiments, the surface active group has positive charges, and the target surface has negative charges, and vice versa, such that the surface active group is attractable to the target surface. In other embodiments, the surface active group can have other properties that can be used to be attached to the target surface.
In one embodiment, the surface active group includes a carboxyl group, a hydroxyl group, a siloxyl group, an amine group or a mixture thereof.
In certain embodiments, the carbon containing component comprises a carbon ring, a straight carbon chain, a branched carbon chain, or a mixture thereof.
In one embodiment, the carbon ring includes three or more carbon atoms arranged in a strained, metastable ring, such as cyclopropane or cyclobutane.
In certain embodiments, the lubricant additive further includes a spacer group connecting the carbon ring to the surface active group. In one embodiment, the spacer group is a carbon chain having 1-20, or more, carbon atoms. In one embodiment, the length of the spacer is configured to form the carbon film under a temperature and a pressure at the target surface.
In certain embodiments, the lubricant additive includes cyclopropanecarboxylic acid, cyclobutanecarboxylic acid, cyclopropylacetic acid, cyclopropanol, cyclobutanol, or a mixture thereof.
In certain embodiments, the carbon film on the target surface is formed by releasing the carbon source from the carbon containing component under a pressure and a temperature at the target surface. In one embodiment, the pressure and the temperature at the target surface is resulted by running a target machine having the target surface. In certain embodiments, the temperature at the target surface is in a range of from about room temperature to about 500° C. The room temperature may be 20° C. or 25° C. In one embodiment, the temperature at the target surface is in a range of 60° C.-300° C. In one embodiment, the temperature at the target surface is in a range of 90° C.-115° C. In one embodiment, the temperature at the target surface is higher than 90° C. due to the heat generated by friction. In one embodiment, the nominal Hertzian pressure at the target surface is in a range of 0.4 to 2.0 GPa.
In certain embodiments, the carbon film includes a plurality of graphitic sheets, amorphous and diamond-like carbon, or a mixture thereof. In one embodiment, percentages of the graphitic sheet and the amorphous and diamond-like carbon in the carbon film depends on a temperature and a pressure at the target surface. In one embodiment, the carbon film comprises substantially the graphitic sheet.
In yet another aspect, the present invention relates to a method for in situ forming of a carbon film on a target surface of a target machine. The method includes: adding a lubricant composition into the target machine, wherein the lubricant composition is in contact with the target surface of the target machine, and comprises a plurality of lubricant additive molecules, and each lubricant additive molecule comprising a surface active group and a carbon containing component connected to the surface active group, and operating the target machine to cause a temperature and a pressure at the target surface so that the carbon containing component is unraveled thereon to form a carbon film on the target surface during the operation. In curtain embodiments, the carbon containing component comprises a carbon ring, a straight carbon chain, a branched carbon chain, or a mixture thereof.
Depending on the lubricant additive used, specifically the length of the spacer and groups attached to some of the carbon atoms in the carbon ring, the temperature and pressure at the target surface, and the duration of the operation time of the target machine, the formed carbon film can be a plurality of graphitic sheets, amorphous and diamond-like carbon, or a mixture thereof. In one embodiment, the carbon film is substantially one or more graphitic sheets.
In certain embodiments, the carbon film is formed in less than seconds to one hour.
In certain embodiments, the lubricant additive is mixed with the base lubricant to form the lubricant composition before use. In other embodiments, the lubricant additive is added directly to the target machine where base lubricant has already been added.
These and other aspects of the invention will become apparent from the following description of the preferred embodiment taken in conjunction with the following drawings, although variations and modifications therein may be affected without departing from the spirit and scope of the novel concepts of the invention.
The accompanying drawings illustrate one or more embodiments of the invention and, together with the written description, serve to explain the principles of the invention. Wherever possible, the same reference numbers are used throughout the drawings to refer to the same or like elements of an embodiment.
The invention will now be described more fully hereinafter with reference to the accompanying drawings, in which exemplary embodiments of the invention are shown. This invention may, however, be embodied in many different forms and should not be construed as limited to the embodiments set forth herein. Rather, these embodiments are provided so that this disclosure will be thorough and complete, and will fully convey the scope of the invention to those skilled in the art. Like reference numerals refer to like elements throughout.
The terms used in this specification generally have their ordinary meanings in the art, within the context of the invention, and in the specific context where each term is used. Certain terms that are used to describe the invention are discussed below, or elsewhere in the specification, to provide additional guidance to the practitioner regarding the description of the invention. For convenience, certain terms may be highlighted, for example using italics and/or quotation marks. The use of highlighting has no influence on the scope and meaning of a term; the scope and meaning of a term is the same, in the same context, whether or not it is highlighted. It will be appreciated that same thing can be said in more than one way. Consequently, alternative language and synonyms may be used for any one or more of the terms discussed herein, nor is any special significance to be placed upon whether or not a term is elaborated or discussed herein. Synonyms for certain terms are provided. A recital of one or more synonyms does not exclude the use of other synonyms. The use of examples anywhere in this specification including examples of any terms discussed herein is illustrative only, and in no way limits the scope and meaning of the invention or of any exemplified term. Likewise, the invention is not limited to various embodiments given in this specification.
It will be understood that, as used in the description herein and throughout the claims that follow, the meaning of “a”, “an”, and “the” includes plural reference unless the context clearly dictates otherwise. Also, it will be understood that when an element is referred to as being “on” another element, it can be directly on the other element or intervening elements may be present therebetween. In contrast, when an element is referred to as being “directly on” another element, there are no intervening elements present. As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items.
It will be understood that, although the terms first, second, third etc. may be used herein to describe various elements, components, regions, layers and/or sections, these elements, components, regions, layers and/or sections should not be limited by these terms. These terms are only used to distinguish one element, component, region, layer or section from another element, component, region, layer or section. Thus, a first element, component, region, layer or section discussed below could be termed a second element, component, region, layer or section without departing from the teachings of the invention.
Furthermore, relative terms, such as “lower” or “bottom” and “upper” or “top,” may be used herein to describe one element's relationship to another element as illustrated in the Figures. It will be understood that relative terms are intended to encompass different orientations of the device in addition to the orientation depicted in the Figures. For example, if the device in one of the figures is turned over, elements described as being on the “lower” side of other elements would then be oriented on “upper” sides of the other elements. The exemplary term “lower”, can therefore, encompasses both an orientation of “lower” and “upper,” depending of the particular orientation of the figure. Similarly, if the device in one of the figures is turned over, elements described as “below” or “beneath” other elements would then be oriented “above” the other elements. The exemplary terms “below” or “beneath” can, therefore, encompass both an orientation of above and below.
It will be further understood that the terms “comprises” and/or “comprising,” or “includes” and/or “including” or “has” and/or “having” when used in this specification, specify the presence of stated features, regions, integers, steps, operations, elements, and/or components, but do not preclude the presence or addition of one or more other features, regions, integers, steps, operations, elements, components, and/or groups thereof.
Unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs. It will be further understood that terms, such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the relevant art and the present disclosure, and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein.
As used herein, “around”, “about” or “approximately” shall generally mean within 20 percent, preferably within 10 percent, and more preferably within 5 percent of a given value or range. Numerical quantities given herein are approximate, meaning that the term “around”, “about” or “approximately” can be inferred if not expressly stated.
As used herein, the terms “comprising,” “including,” “carrying,” “having,” “containing,” “involving,” and the like are to be understood to be open-ended, i.e., to mean including but not limited to.
The description will be made as to the embodiments of the invention in conjunction with the accompanying drawings. In accordance with the purposes of this disclosure, as embodied and broadly described herein, this disclosure, in one aspect, relates to a lubricant composition having a lubricant additive used for tribologically-activated in situ deposition of a carbon film.
Specifically, the lubricant composition utilizes carbon lubrication as an additive to reduce friction and wear in the boundary lubrication regime of sliding contact. Carbon layers can mitigate friction and wear by using this sliding motion to absorb the stress of asperity contact [3,4].
Graphite is stable at high temperatures, and is commonly used for high load, low speed boundary lubrication conditions. Several commercial engine lubrication products use graphite suspended in oil as an anti-wear, anti-friction additive. These products are especially popular as a “breaking-in” engine oil, where a large amount of asperity contact is expected. Current carbon lubrication products have several limitations. First, graphite suspended in oil or applied directly to a contact must frequently be replenished. “Squeeze-out” occurs where the asperity contact dislocates the carbon away from the contact point. Issues with agglomeration of the carbon also limit the lifetime of these products. Currently, carbon coatings are applied prior to the service of a part, and once they wear away, there is no way to reapply them without disassembly of a machine.
In one aspect, the invention relates to a carbon lubrication using diamond-like carbon (DLC). DLC is a layer of sp2 and sp3 bonded carbon atoms over contact surfaces and show remarkable performance in friction reduction and wear protection [5, 6]. DLC exhibits the traits of graphitic carbon, diamond, and polymeric carbon, which combine for a flexible, hard, inert, and friction reducing coating [7]. In vehicles, DLC has the potential for replacing molybdenum disulfide anti-friction films, which are currently used for the same purpose. These sulfur-containing films may damage catalytic converters and are therefore environmentally detrimental [8, 9]. However, application of DLC normally requires a vacuum-based process and is expensive. Once worn, it cannot be replenished by such a process unless the machinery is disassembled, which is not practical. DLC's wear resistance is attributed to the hardness of the sp3 carbon bonds. It was recently discovered that DLC films show low friction results through the creation of a carbon “transfer film.” This transfer film is made up of graphite-like carbon sourced from the DLC surface, which behaves similarly to graphitic lubricant additives for friction reduction [10].
In one aspect, the invention relates to generating carbon-enhanced surfaces through surface catalysis, using frictional heat and contact pressure already present during operation of engines and machinery [11].
In one aspect, the invention is related to a lubricant additive. The lubricant additive includes a surface active group attractable to a target surface, and a carbon containing component connected to the surface active group, for providing a carbon source to form a carbon film on the target surface. In certain embodiments, the surface active group includes a carboxyl group, a hydroxyl group, a siloxyl group, an amine group, or a mixture thereof. In certain embodiments, the carbon containing component comprises a carbon ring, a straight carbon chain, a branched carbon chain, or a mixture thereof. In certain embodiments, the carbon film is formed only when tribological energy activates the lubricant additive to unravel the carbon containing component. Flash heating from asperity contacts heats the lubricant additive to above a threshold temperature, which causes decomposition of the carbon containing component, releases lubricious carbon onto the target surface, thereby forming the carbon film on the target surface. Carbon is not formed in the bulk fluid before the lubricant additive is used as a lubricant.
The surface active group 110 attracts to a metallic oxide surface. In one embodiment, the attraction of OH− to metal oxide surfaces is used. Alternatively, other strategies for attraction to metal surfaces could be used. The carbon ring 150 is a metastable, carbon ring, such as a cyclopropane group, or a cyclobutane group. The carbon ring 150 may include three or more carbon atoms. In certain embodiments, the lubricant additive 100 further includes a spacer 130. The spacer 130 can be a carbon chain. The carbon chain can include 1-20 carbon atoms.
In certain embodiments, the carbon-based lubricant additive 100 may be cyclopropanecarboxylic acid (CPCa,
Further, hydrocarbon “spacers” can be added between the surface active group and the carbon ring of the additive molecule, such as cyclopropylacetic acid, as shown in
In addition, the carbon ring can be modified to improve the additive's compatibility with the base lubricant or a formulated oil and to alter the stability of the carbon ring. In one embodiment, one can attach a side chain to one or more of the carbon atoms in the carbon ring. The side chain can alter the strain energy in the carbon ring and hence its stability.
In certain embodiments, the lubricant additive 100 can be mixed with a base lubricant, such as an oil-based lubricant, to form a lubricant composition. The lubricant composition can be used for lubrication of a machinery. In other embodiments, when the base lubricant has already been added to the machinery, the lubricant additive 100 can be added later to the base lubricant to improve lubrication efficiency and to repair wear.
In certain embodiments, the lubricant composition has about 1-10 weight percentage (wt %) of the lubricant additive molecules. In one embodiment, the lubricant composition comprises about 2.5 wt % of the lubricant additive molecules.
In certain embodiments, the lubricant additive binds to the target surface via polar (electrostatic) or chemical interactions through the surface active group.
In another aspect, the invention relates to a method of using the novel additive described above to formulate carbon coatings in situ, or during machine operation. It does so by inducing a localized chemical transformation at the site of surface contact.
Referring to
In certain embodiments, the carbon film includes a plurality of graphitic sheets, amorphous and diamond-like carbon, or a mixture thereof. In one embodiment, percentages of the graphitic sheet and the amorphous and diamond-like carbon in the carbon film depends on a temperature and a pressure at the target surface. In one embodiment, the carbon film comprises substantially the graphitic sheet.
In certain embodiments, the temperature at the target surface is in a range of from about room temperature to about 500° C. The room temperature may be 20° C. or 25° C. In one embodiment, the temperature at the target surface is in a range of 60° C.-300° C. In one embodiment, the temperature at the target surface is in a range of 90° C.-115° C. In one embodiment, the ambient temperature of the experiment is about 90° C. and the temperature at the target surface is higher than 90° C. due to the heat generated by friction. In one embodiment, the nominal Hertzian pressure at the target surface is in a range of 0.1 to 10 GPa. In one embodiment, the nominal Hertzian pressure at the target surface is in a range of 0.4 to 2.0 GPa. In one embodiment, by adjusting the distance between the surface active group 110 and the carbon ring 150, or the length of the spacer 130, a corresponding decomposition temperature and pressure for the carbon-based lubricant additive 100 can be obtained.
In certain embodiments, after adding the lubricant composition having the lubricant additive as described above and running the machinery such as an engine, the carbon film may be formed in a few seconds In certain embodiments, depending on the specific composition, the machinery, and environment, the carbon film may be formed in a range of less than a second minutes to 1 day. To improve tribological feature and wear, the lubricant composition or the lubricant additive may be added to the machinery one or more times, or added when it is needed, or once in a determined time.
In this exemplary embodiment shown in
This in situ carbon coating technology allows machines to run with normal operation while carbon is released locally onto contacts surfaces. The carbon will reduce friction and wear. A small amount of this additive may provide just enough lubrication at the site of contact, eliminating the need of graphite suspensions in oil and agglomeration issues.
Without intent to limit the scope of the disclosure, exemplary examples and their related results according to the embodiments of the disclosure are given below. Note that titles or subtitles may be used in the examples for convenience of a reader, which in no way should limit the scope of the disclosure. Moreover, certain theories are proposed and disclosed herein; however, in no way they, whether they are right or wrong, should limit the scope of the disclosure so long as the disclosure is practiced according to the disclosure without regard for any particular theory or scheme of action.
Tribological Test Setup
Tribological tests (or tribometer tests) were performed on the CETR-UMT ball-on-disk (or pin-on-disk) tribometer, as shown in
During the tribological tests, a stationary ball was brought into contact with a rotating disk, creating pure sliding contact. The temperature of the ball-on-disk tribometer was controlled, and the contact area was fully flooded with lubricating oil. Capacitive sensors on the ball holder maintained a prescribed constant vertical force, while the lateral (friction) force was measured. Each tribological test was run with two parallel trials. The ratio of the measured friction force to the applied vertical force gives the coefficient of friction over the duration of the test.
The disk and ball were both cleaned with acetone before testing. The various pin-on-disk operating conditions for boundary lubrication simulation are shown in Table 1. The conditions generally followed the ASTM Designation G99-05 [12]. The load and speed of these tests were varied slightly, and tests were done at room temperature and at 90° C., in order to simulate an engine environment.
The 90° C.-ambient temperature tests were performed on a different CETR-UMT ball-on-disk tribometer with the same configuration, except for a smaller ball size. The benchmark oil used for the high temperature tests was Synfluid Poly-alpha-olefin 4 (PAO4), which is a synthetic base fluid with no additives, and has a viscosity of 4 centistokes (cSt) at room temperature [13]. Low concentrations of a lubricant additive was added to this base lubricant (or base fluid, or base oil) to test the effectiveness of the lubricant additive. Tests were also performed on fully formulated 5w30 engine oil with and without the lubricant additive, to examine any interactive benefits or issues. These tests were run under both boundary lubrication conditions, and hydrodynamic lubrication (high speed, low load) conditions.
The post-test tribometer disks were cleaned with acetone and then analyzed for wear damage using White Light Interferometry (WLI). Referring to
Referring to
Proof-of-Concept Test
In this example, CPCa, a lubricative additive according to certain embodiments of the present invention, was tested for its carbon release by heating. Referring to
In this example, the lubricant composition (mixture of lubricant additive and base lubricant/oil according to certain embodiments of the invention) was tested in the tribometer for friction and wear results under various conditions. The lubricant composition included 5 wt % of CPCa in PAO4 as described above. The addition of CPCa to PAO4 base oil did not change the viscosity or appearance of the oil. The tribological test was performed using the parameters listed in the following Table 2.
The tribological test was performed for a few hours. After the tribological test, the post-test fluid contained carbon flakes, especially near the contact zone. An image of the post-test oil sitting on a disk is shown in
Further, the surfaces of the disks were tested for carbon using Raman analysis, and the results are shown in
Optimal Lubricant Additive Concentration
In this example, the optimal lubricant additive concentration for friction and wear reduction was tested. Boundary lubrication tests for pure PAO4 and PAO4 containing 1, 2.5, and 5 wt % of CPCa were performed. The tribological test was performed using the parameters listed in the following Table 3.
According to the friction results as shown in
Friction Versus Time
In this example, a friction versus time test is performed on a tribometer.
Referring to
Varied Load and Speed
Tribological test were performed with the estimated optimal concentration of 2.5 wt % lubricant additive.
Referring to
Wear Volume
2-Stage Test
With significant friction and wear reduction demonstrated, this example aimed to examine if the carbon deposited by the CPCa remains effective even after the additive is no longer present in the lubricant.
A 2-stage tribometer test was performed: in stage 1, boundary lubrication tests were performed on disk A with PAO4, and on disk B with PAO4+2.5 wt % CPCa. Then, without removing the disks from the tribometer, the fluids were cleaned from the system. After that, in stage 2, the tests were repeated using pure PAO4 on both disks. As with all tribometer tests in this example, the experiment was repeated at least twice. The tribological test was performed using the parameters listed in the following Table 4.
Adding Lubricant Additive to a Formulated Oil
In this example, a fully formulated 5w30 engine oil mixed with CPCa was tested. The formulated oil is made of a base fluid similar to PAO4, but it also contains its own assortment of anti-friction, anti-wear, viscosity modifying, and detergent additives. It is important to examine how the CPCa interacts with these additives, and to see the additive can be effective with formulated oil. In one specific example, one or more of the components in the formulated oil made the CPCa insoluble. As shown in
Two tribometer tests were performed using pure 5w30 and a mixture of 5w30 with 2.5 wt % CPCa. A boundary condition test was performed with similar conditions to previous tests, at 15 kg load and 0.91 m/s relative motion. Another test simulated hydrodynamic lubrication (HL), with a load of 1 kg and relative motion of 5 m/s. The HL test was performed because the insolubility of the additive was expected to change the viscosity of the fluid and increase friction.
As shown in
Friction and Wear Performance
These experiments were performed to further assess the friction and wear performance of the additive technology in typical vehicle engine environments (about 1 GPa, 25-175° C.), and to further examine the carbon materials present after tribological testing, both in the lubricating fluid, and on the tribological surface using Raman spectroscopy.
The tribological experiments were performed using a CETR UMT-3 tribometer in the pin-on-disk configuration, with the conditions listed in Table 5.
Friction and wear performances were measured similarly to the other experiments disclosed above. The wear data is presented using Archard's wear coefficient, which normalizes the wear by material properties, load, and distance traveled.
As shown in
As shown in
Raman data was collected using a Confocal Raman Spectrometer. Carbon materials appear through Raman spectrum in two peaks, as shown in
In sum, the present invention discloses, among other things, a lubricant composition including the lubricant additive molecules and a method for in situ forming of a carbon film using the lubricant composition. Each lubricant additive molecule includes a surface active group attractable to a target surface, and a carbon containing component connected to the surface active group, for providing a carbon source to form a carbon film on the target surface. The method includes adding the lubricant composition into a target machine such that the lubricant composition is in contact with a target surface of the target machine, and operating the target machine to cause a temperature and a pressure at the target surface so that the carbon containing component is unraveled thereon to form a carbon film on the target surface during the operation.
Certain embodiments of the invention, among other things, have the following advantages.
(1) In situ carbon coating additive releases lubricious carbon when activated by heat and/or pressure.
(2) Carbon is supplied locally to the point of contact, without the need of pre-processing or suspension of graphite in oil.
(3) Effective in reducing boundary lubrication friction and wear, compared to pure base oil: about 20% friction reduction, and one order of magnitude reduction in wear.
(4) Lasting effectiveness of carbon coatings is present even after additive is removed from oil.
(5) Can be applied during operation of machinery.
(6) Wear improvement with formulated oil.
The foregoing description of the exemplary embodiments of the invention has been presented only for the purposes of illustration and description and is not intended to be exhaustive or to limit the invention to the precise forms disclosed. Many modifications and variations are possible in light of the above teaching.
The embodiments were chosen and described in order to explain the principles of the invention and their practical application so as to activate others skilled in the art to utilize the invention and various embodiments and with various modifications as are suited to the particular use contemplated. Alternative embodiments will become apparent to those skilled in the art to which the present invention pertains without departing from its spirit and scope. Accordingly, the scope of the present invention is defined by the appended claims rather than the foregoing description and the exemplary embodiments described therein.
This application is a continuation application of U.S. patent application Ser. No. 15/521,337, filed Apr. 24, 2017, now allowed, which is a national stage entry of PCT Application Serial No. PCT/US2015/056965, filed Oct. 22, 2015, which itself claims priority to and the benefit of U.S. Provisional Patent Application Ser. No. 62/067,719, filed Oct. 23, 2014, which are incorporated herein in their entireties by reference. Some references, which may include patents, patent applications and various publications, are cited and discussed in the description of this invention. The citation and/or discussion of such references is provided merely to clarify the description of the present invention and is not an admission that any such reference is “prior art” to the invention described herein. All references cited and discussed in this specification are incorporated herein by reference in their entireties and to the same extent as if each reference was individually incorporated by reference. In terms of notation, hereinafter, “[n]” represents the nth reference cited in the reference list. For example, [1] represents the 1st reference cited in the reference list, namely, K. Holmberg, P. Andersson, and A. Erdemir, Global energy consumption due to friction in passenger cars, Tribology International 47 (2012) 221-234.
| Number | Name | Date | Kind |
|---|---|---|---|
| 2576032 | Morway et al. | Nov 1951 | A |
| 5558805 | Colclough | Sep 1996 | A |
| 7635669 | Culley | Dec 2009 | B2 |
| 10414997 | Chung | Sep 2019 | B2 |
| Number | Date | Country | |
|---|---|---|---|
| 20190367832 A1 | Dec 2019 | US |
| Number | Date | Country | |
|---|---|---|---|
| 62067719 | Oct 2014 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 15521337 | US | |
| Child | 16521631 | US |
