Patent Grant
9570675
This application claims the benefit of priority under 35 U.S.C. §119 from Korean Patent Application No. 10-2013-0025745, filed on Mar. 11, 2013, in the Korean Intellectual Property Office, the disclosure of which is incorporated herein in its entirety by reference.
1. Field
Example embodiments relate to magnetoresistive structures, magnetic random-access memory devices including the same, and/or methods of manufacturing the magnetoresistive structure.
2. Description of the Related Art
As thin-film deposition technology and surface processing technology in a high-vacuum state have rapidly developed, it has become possible to precisely grow a magnetic thin film within a thickness of several nanometers (nm) to be used in the manufacture a magnetic random-access memory device. The thickness of the magnetic thin film is grown so as to match an exchange interaction distance between spins of a magnetic random-access memory device. Accordingly, various phenomena have been discovered which were not observed from a magnetic material in a bulk form, and thus these various phenomena are being applied to home appliances and industrial components, for example, a magnetic recording head or a magnetic random-access memory (MRAM) for recording information in an ultra high-density information storage apparatus.
A magnetic random-access memory device is a memory device which stores data by using a resistance change in a magnetic tunneling junction (MTJ), which is a magnetoresistive structure. The magnetoresistive structure is formed to have a pinned layer and a free layer. A resistance of the magnetoresistive structure varies with a magnetization direction of the free layer. For example, if a magnetization direction of the free layer is the same as that of the pinning layer, the magnetoresistive structure may have a low resistance value. If a magnetization direction of the free layer is opposite to that of the pinning layer, the magnetoresistive structure may have a high resistance value. As such, if the magnetoresistive structure of the magnetic random-access memory device has a low resistance value, the low resistance value may correspond to, for example, data ‘0’. If the magnetoresistive structure of the magnetic random-access memory device has a high resistance value, the low resistance value may correspond to data ‘1’.
It is necessary to implement a high magnetoresistance (MR) ratio, so as to achieve a magnetic random-access memory device which has excellent characteristics. To achieve this, a lot of research is being conducted.
Provided are magnetoresistive structures which have excellent magnetoresistive characteristics and may allow high degree of integration.
Provided are magnetic random-access memory devices that include a magnetoresistive structure which has excellent magnetoresistive characteristics and may allow high degree of integration.
Provided are methods of manufacturing a magnetoresistive structure.
According to example embodiments, a magnetoresistive structure includes a first magnetic layer having a magnetization direction that is fixed, a second magnetic layer corresponding to the first magnetic layer, wherein a magnetization direction of the second magnetic layer being changeable, and a magnetoresistance (MR) enhancing layer and an intermediate layer both between the first magnetic layer and the second magnetic layer.
An area of the second magnetic layer may be larger than an area of the first magnetic layer.
An area of the MR enhancing layer and an area of the intermediate layer may be each larger than the area of the first magnetic layer.
The MR enhancing layer may cover an upper surface and side surfaces of the first magnetic layer.
The second magnetic layer may cover an upper surface of the intermediate layer.
The MR enhancing layer may have a thickness of about 0.1 nm to 10 nm.
The first magnetic layer and the second magnetic layer may each include a material having a magnetic anisotropy that is horizontal.
The first magnetic layer and the second magnetic layer may each include a material having a magnetic anisotropy that is perpendicular.
According to example embodiments, a magnetic random-access memory device includes a switching structure; and a magnetoresistive structure connected to the switching structure, wherein the magnetoresistive structure includes a first magnetic layer having a magnetization direction that is fixed; a second magnetic layer corresponding to the first magnetic layer, wherein a magnetization direction of the second magnetic layer is changeable, and an magnetoresistance (MR) enhancing layer and an intermediate layer both between the first magnetic layer and the second magnetic layer.
According to example embodiments, a method of forming a magnetoresistive structure includes forming a first magnetic layer; forming a magnetoresistance (MR) enhancing layer and an intermediate layer on the first magnetic layer; and forming a second magnetic layer on the intermediate layer, wherein an area of the second magnetic layer is larger than an area of the first magnetic layer.
The MR enhancing layer may cover an upper surface and side surfaces of the first magnetic layer.
The forming of the first magnetic layer may include forming a capping layer and a sacrificial layer on a layer of a material of the first magnetic layer, forming a mask layer on the sacrificial layer; and forming the first magnetic layer using the mask layer in an etching process.
The forming of the first magnetic layer may include forming the first magnetic layer, applying an insulating material on the first magnetic layer to form a passivation layer, and removing the sacrificial layer to expose the capping layer using a chemical-mechanical polishing (CMP) process.
According to example embodiments, a magnetic random-access memory device includes a first magnetic layer having a fixed magnetization direction, a second magnetic layer operatively connected to the first magnetic layer, and a resistive structure separating the first magnetic layer from the second magnetic layer. The second magnetic layer extends over the first magnetic layer, and the second magnetic layer has a variable magnetization direction. The resistive structure includes at least one magnetoresistive layer and at least one intermediate layer.
A surface area of the second magnetic layer may be larger than a surface area of the first magnetic layer.
The first and second magnetic layers may have the same magnetic anisotropy.
The at least one magnetoresistive layer may cover at least one of an upper surface of the first magnetic layer and sidewalls of the first magnetic layer, and the at least one intermediate layer has a profile conformal with a profile of the at least one magnetoresistive layer.
The magnetic random-access memory device may further include at least one passivation layer covering the sidewalls of the first magnetic layer. The at least one passivation layer and the at least one magnetoresistive layer may collectively form a protective cap over the first magnetic layer.
The at least one intermediate layer may be stacked over the at least one magnetoresistive layer, and the at least one magnetoresistive layer may contact the first magnetic layer.
A width of the second magnetic layer may be larger than a width of the first magnetic layer.
Example embodiments will be more clearly understood from the following detailed description taken in conjunction with the accompanying drawings.
Various example embodiments will now be described more fully with reference to the accompanying drawings in which some example embodiments are shown. However, specific structural and functional details disclosed herein are merely representative for purposes of describing example embodiments. Thus, the invention may be embodied in many alternate forms and should not be construed as limited to only example embodiments set forth herein. Therefore, it should be understood that there is no intent to limit example embodiments to the particular forms disclosed, but on the contrary, example embodiments are to cover all modifications, equivalents, and alternatives falling within the scope.
In the drawings, the thicknesses of layers and regions may be exaggerated for clarity, and like numbers refer to like elements throughout the description of the figures.
Although the terms first, second, etc. may be used herein to describe various elements, these elements should not be limited by these terms. These terms are only used to distinguish one element from another. For example, a first element could be termed a second element, and, similarly, a second element could be termed a first element, without departing from the scope of example embodiments. As used herein, the term “and/or” includes any and all combinations of one or more of the associated listed items.
It will be understood that, if an element is referred to as being “connected” or “coupled” to another element, it can be directly connected, or coupled, to the other element or intervening elements may be present. In contrast, if an element is referred to as being “directly connected” or “directly coupled” to another element, there are no intervening elements present. Other words used to describe the relationship between elements should be interpreted in a like fashion (e.g., “between” versus “directly between,” “adjacent” versus “directly adjacent,” etc.).
The terminology used herein is for the purpose of describing particular embodiments only and is not intended to be limiting of example embodiments. As used herein, the singular forms “a,” “an” and “the” are intended to include the plural forms as well, unless the context clearly indicates otherwise. It will be further understood that the terms “comprises,” “comprising,” “includes” and/or “including,” if used herein, specify the presence of stated features, integers, steps, operations, elements and/or components, but do not preclude the presence or addition of one or more other features, integers, steps, operations, elements, components and/or groups thereof.
Spatially relative terms (e.g., “beneath,” “below,” “lower,” “above,” “upper” and the like) may be used herein for ease of description to describe one element or a relationship between a feature and another element or feature as illustrated in the figures. It will be understood that the spatially relative terms are intended to encompass different orientations of the device in use or operation in addition to the orientation depicted in the figures. For example, if the device in the figures is turned over, elements described as “below” or “beneath” other elements or features would then be oriented “above” the other elements or features. Thus, for example, the term “below” can encompass both an orientation that is above, as well as, below. The device may be otherwise oriented (rotated 90 degrees or viewed or referenced at other orientations) and the spatially relative descriptors used herein should be interpreted accordingly.
Example embodiments are described herein with reference to cross-sectional illustrations that are schematic illustrations of idealized embodiments (and intermediate structures). As such, variations from the shapes of the illustrations as a result, for example, of manufacturing techniques and/or tolerances, may be expected. Thus, example embodiments should not be construed as limited to the particular shapes of regions illustrated herein but may include deviations in shapes that result, for example, from manufacturing. For example, an implanted region illustrated as a rectangle may have rounded or curved features and/or a gradient (e.g., of implant concentration) at its edges rather than an abrupt change from an implanted region to a non-implanted region. Likewise, a buried region formed by implantation may result in some implantation in the region between the buried region and the surface through which the implantation may take place. Thus, the regions illustrated in the figures are schematic in nature and their shapes do not necessarily illustrate the actual shape of a region of a device and do not limit the scope.
It should also be noted that in some alternative implementations, the functions/acts noted may occur out of the order noted in the figures. For example, two figures shown in succession may in fact be executed substantially concurrently or may sometimes be executed in the reverse order, depending upon the functionality/acts involved.
Unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meaning as commonly understood by one of ordinary skill in the art to which example embodiments belong. It will be further understood that terms, such as those defined in commonly used dictionaries, should be interpreted as having a meaning that is consistent with their meaning in the context of the relevant art and will not be interpreted in an idealized or overly formal sense unless expressly so defined herein.
As appreciated by the present inventive entity, devices and methods of forming devices according to various embodiments described herein may be embodied in microelectronic devices such as integrated circuits, wherein a plurality of devices according to various embodiments described herein are integrated in the same microelectronic device. Accordingly, the cross-sectional view(s) illustrated herein may be replicated in two different directions, which need not be orthogonal, in the microelectronic device. Thus, a plan view of the microelectronic device that embodies devices according to various embodiments described herein may include a plurality of the devices in an array and/or in a two-dimensional pattern that is based on the functionality of the microelectronic device.
The devices according to various embodiments described herein may be interspersed among other devices depending on the functionality of the microelectronic device. Moreover, microelectronic devices according to various embodiments described herein may be replicated in a third direction that may be orthogonal to the two different directions, to provide three-dimensional integrated circuits.
Accordingly, the cross-sectional view(s) illustrated herein provide support for a plurality of devices according to various embodiments described herein that extend along two different directions in a plan view and/or in three different directions in a perspective view. For example, when a single active region is illustrated in a cross-sectional view of a device/structure, the device/structure may include a plurality of active regions and transistor structures (or memory cell structures, gate structures, etc., as appropriate to the case) thereon, as would be illustrated by a plan view of the device/structure.
With regard to a magnetoresistive structure and a magnetic random-access memory device including the same according to example embodiments, reference will now be made in detail to embodiments, examples of which are illustrated in the accompanying drawings.
Referring to
According to example embodiments, the second magnetic layer 17 may be formed to have a larger area than the first magnetic layer 13. Additionally, the MR enhancing layer 15 and the intermediate layer 16 may each be formed to have a larger area than the first magnetic layer 13. The MR enhancing layer 15 and the intermediate layer 16 may be formed to have a three-dimensional (3D) structure that surrounds an upper surface and a side of the first magnetic layer 13.
The first magnetic layer 13 may be a pinned layer of which magnetization direction is fixed. The first magnetic layer 13 may be formed of a ferromagnetic material which is formed of a metal or an alloy that includes at least one material from among nickel (Ni), cobalt (Co) or iron (Fe). Also, the first magnetic layer 13 may further include boron (B), chrome (Cr), platinum (Pt), or palladium (Pd). For example, the first magnetic layer 13 may be formed of nickel iron (NiFe), cobalt iron (CoFe), nickel iron boron (NiFeB), cobalt iron boron (CoFeB), nickel iron silicon boron (NiFeSiB), or cobalt iron silicon boron (CoFeSiB). Additionally, in order to fix a magnetization direction of the first magnetic layer 13, a pinning layer 12 may be selectively further included below the first magnetic layer 13. The pinning layer 12 may be formed by using an antiferromagnetic layer or a synthetic antiferromagnetic (SAF) structure. If an antiferromagnetic layer is used as the pinning layer 12, the antiferromagnetic layer may be formed by using an alloy that includes manganese (Mn). For example, the antiferromagnetic layer may be formed by using an iridium manganese (IrMn), iron manganese (FeMn), or nickel manganese (NiMn) alloy. Instead of using the pinning layer 12, shape anisotropy of the first magnetic layer 13 may also be used to fix a magnetization direction of the first magnetic layer 13. The first magnetic layer 13 may be formed on a first electrode 11 so that a power source may be applied to the magnetic layer 13. The first electrode 11 may be formed on a lower structure 10 such as a substrate. The first electrode 11 may be formed to include a conductive material such as metal, conductive metal oxide, or conductive metal nitride.
Unlike the first magnetic layer 13, the second magnetic layer 17 may be formed so that a magnetization direction of the second magnetic layer 17 may be changed. The first magnetic layer 17 may be formed of a ferromagnetic material which is formed of a metal or an alloy that includes at least one material from among Ni, Co or Fe. Also, the second magnetic layer 17 may further include B, Cr, Pt, or Pd. For example, the second magnetic layer 17 may be formed of NiFe, CoFe, NiFeB, CoFeB, NiFeSiB, or CoFeSiB.
The MR enhancing layer 15 is applied to enhance an MR ratio of a magnetoresistive structure. The MR enhancing layer 15 is formed of at least one material from among Co, Fe, or Ni. Additionally, the MR enhancing layer 15 may be formed of an amorphous magnetic material that further includes B, Si, zirconium (Zr), or titanium (Ti). The MR enhancing layer 15 may be formed to have a thickness of about 0.1 nm to 10 nm.
The intermediate layer 16 may be formed to include an insulating material such as magnesium (Mg) oxide or aluminum (Al) oxide. However, the intermediate layer 16 is not limited to an insulating material. The intermediate layer 16 may be formed of a conductive material that includes at least one material from among ruthenium (Ru), copper (Cu), Al, gold (Au) and silver (Ag). The intermediate layer 16 may be formed to have a thickness of several nanometers, for example, 1 to 10 nm.
The passivation layer 14 may be formed of an insulating material, generally, a material of an interlayer insulating layer which is used for an electronic device. The passivation layer 14 may be formed of silicon oxide or silicon nitride.
Referring to
The first magnetic layer 23 may be a pinned layer of which magnetization direction is fixed. In order to fix a magnetization direction of the first magnetic layer 23, a pinning layer 22 may be selectively further included below the first magnetic layer 23. The pinning layer 22 may be formed by using an antiferromagnetic layer or an SAF structure. Instead of using the pinning layer 22, shape anisotropy of the first magnetic layer 23 may also be used to fix a magnetization direction of the first magnetic layer 23. The first magnetic layer 23 may be formed on a first electrode 21 so that a power source may be applied to the first magnetic layer 23. The first electrode 21 may be formed on a lower structure 20 such as a substrate. The second magnetic layer 27 may be formed to have a larger area than the first magnetic layer 23. Additionally, the MR enhancing layer 25 and the intermediate layer 26 may each be formed to have a larger area than the first magnetic layer 23.
The descriptions about materials of each member shown in
According to the example embodiments shown in
Hereinafter, by referring to
Referring to
Referring to
Referring to
Referring to
Additionally, referring to
Referring to
If the magnetoresistive structure, according to example embodiments shown in
Referring to
Referring to
Additionally, an example of forming an electrode connection structure, which may apply a power source to the first magnetic layer 13 and the second magnetic layer 17, is described by referring to
Referring to
Then, referring to
An object specimen, shown in
According to example embodiments, the magnetoresistive structure may be applied to various types of electronic devices or magnetic devices. For example, the magnetoresistive structure may be applied to a magnetic random-access memory device.
The magnetoresistive structure in the current example embodiment may be connected to a switching structure.
Referring to
As described above, according to the one or more of the above example embodiments, provided is the magnetoresistive structure, in which the second magnetic layer is formed to have a wider area compared to the first magnetic layer, and in which the MR enhancing layer is included; thus, the magnetoresistive structure has a high MR ratio. Additionally, provided is a magnetic device which has a high degree of integration, which is achieved by forming the magnetoresistive structure to have a 3D structure.
It should be understood that the example embodiments described therein should be considered in a descriptive sense only and not for purposes of limitation. For example, numerous modifications of the magnetoresistive structure shown in
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