MEMBRANE AND A METHOD FOR MAKING A MEMBRANE

Abstract

A membrane 30 and a method 12 for making the membrane 30 comprising the steps of selectively placing a first material 14 upon a substrate 16, depositing a certain material 26 upon a first material 14, and heating the materials 14, 16, 26, thereby forming a membrane 30.

Description

FIELD OF THE INVENTION

[0001] The present invention generally relates to a membrane and to a method for making a membrane and more particularly, to a method which creates a wide variety of membranes in a cost effective manner, such as but not limited to a metal hydrogen permeable membrane.

BACKGROUND OF THE INVENTION

[0002] A membrane is used as a filter since it is adapted to allow only one or a few selected types of materials to pass through or traverse it. Particularly, a metallic membrane may be used in a wide variety of applications such as but not limited to a gasoline to hydrogen reformation process in which hydrogen is selectively removed from gasoline and used within a fuel cell.

[0003] While current metallic membranes do adequately provide desired filtering, they are relatively expensive requiring a relatively pure and relatively thick metallic layer in order to operatively obtain the desired filtering characteristics or attributes. Moreover, current metallic membrane creation processes are not readily adapted to efficiently and dynamically create different types of membranes having respectively diverse types of materials. Rather, these processes are usually adapted to utilize a certain type of metal and are not easily adaptable to allow the creation of diverse types of membranes having different types or selected types of metals or materials.

[0004] It is therefore desirable to provide a membrane and a process for creating a membrane which overcomes some or all of the previously delineated disadvantages of currently available membranes and processes.

SUMMARY OF THE INVENTION

[0005] It is a first non-limiting advantage of the present invention to provide a membrane which overcomes some or all of the previously delineated disadvantages of currently available membranes.

[0006] It is a second non-limiting advantage of the present invention to provide a process for creating a membrane which overcomes some or all of the previously delineated disadvantages of currently used membrane creating processes.

[0007] According to a first aspect of the present invention, a membrane is provided. The membrane includes a first material; and a second material which is selectively deposited upon the first material.

[0008] According to a second aspect of the present invention a method for producing a membrane is provided. The method includes the steps of providing a substrate; rolling a first material onto the substrate; selectively depositing a second material onto the first material; and heating the first and second materials.

[0009] These and other features, aspects, and advantages of the present invention will become apparent from a reading of the following detailed description of the preferred embodiment of the invention and by reference to the following drawings.

BRIEF DESCRIPTION OF THE DRAWINGS FIGS. 1(a-e) are diagrammatic illustrations of the steps comprising the methodology of the preferred embodiment of the invention.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT OF THE INVENTION

[0010] Referring now to FIGS. 1(a-e) there is shown a membrane creation methodology 10 of the preferred embodiment of the invention. As shown, methodology 10 begins with a first step 12 in which a first relatively inexpensive material 14, such as copper, is applied to a substrate material 16, such as inconel mesh.

[0011] Step 18 follows step 12 and, in this step 18, the first material 14 is compressed onto the substrate material 16 by a roller 20, thereby causing the first material 14 to be substantially integrated with and/or compressed into the substrate material 16. Step 22 follows step 18 and, in this step 22, a second material, 26 such as palladium, is selectively deposited upon the first material 14 by an evaporative or electrochemical deposition process. Other deposition processes may be used.

[0012] Step 28 follows step 22,in one embodiment and, in this step 28, the materials 14, 16, and 25 are heated at a predetermined temperature and for a predetermined time, effective to form membrane 30. For example, the materials 14, 16, and 26 are heated at a temperature of about 800 degrees Celsius for about one hour. Step 32 follows step 26 and in this step 32 the membrane 30 is removed from the furnace.

[0013] It should be realized that the foregoing rolling step 18 is accomplished before the deposition of palladium is accomplished, thereby substantially preventing structural degradation (e.g., the undesired separation of the mesh or material 16 from the membrane 30) caused by work hardening. Further, the processor methodology 10 allows for the selective and efficient deposition and use of a wide variety of materials, allows for the use of only a relatively thin layer of the relatively expensive material 26, thereby obviating the need for the formation of a relatively costly and relatively thick layer “pure” metal or “pure” palladium.

EXAMPLE

[0014] In order to fully appreciate the invention, the foregoing discussion describes an experiment which was conducted to verify the efficacy of the methodology of the invention and the produced membrane.

[0015] An inconel mesh was obtained and chosen since it resists interdiffusion from copper. Relatively inexpensive copper foil was then rolled onto the inconel mesh. By knowing the density of copper and palladium one can calculate the thickness required to produce a Pd40Cu alloy, using the following formula:

t c /t p =ρPdxF c /[ρCux (1−Fc)]

[0016] where:

[0017] tc=copper thickness

[0018] tp=palladium thickness

[0019] ρPd=density of palladium (12.02 grams/cc)

[0020] ρCu=density of copper (8.96 grams/cc)

[0021] Fc=weight fraction of copper (40%)

[0022] tc/tp=0.894

[0023] Thus, for every 894 Å of copper 1000 Å of palladium was deposited upon the copper foil. Particularly, a total thickness of 2.11 microns of palladium was evaporated on the surface of a 3 micron copper foil. The sample was then heated at 800° C for about one hour to produce a Pd40CU alloy.

[0024] Quantitative composition analysis was completed upon the created membrane using SEM energy dispersive spectroscopy. The analysis confirmed and indicated the presence of a Pd40Cu metal alloy having the elemental composition of about 40.69% copper and about 59.31% palladium. Scanning electron microscope (SEM) photographs were then taken of the produced membrane and these photographs indicated a substantially “tight” pinhole free gain structure of the resultant membrane formed from a combination of copper and palladium.

[0025] It is to be understood that the invention is not limited to the exact construction or method which has been illustrated and discussed above, but that various changes and modifications may be made without departing from the spirit and the scope of the inventions as are more fully delineated in the following claims.

Claims

1. A membrane comprising a first material; and a second material which is selectively deposited upon the first material.

2. The membrane of claim 1 wherein said first material comprises copper.

3. The membrane of claim 1 wherein said second material comprises palladium.

4. The membrane of claim 1 further comprising a substrate material which selectively receives said first material.

5. The membrane of claim 4 wherein said substrate material comprises inconel mesh.

6. A method for making a membrane comprising the steps of selectively depositing a first material onto a second material; and heating the two materials.

7. The method of claim 6 wherein said second material comprises copper.

8. The method of claim 6 wherein said first material comprises palladium.

9. The method of claim 6 wherein said step of heating said two materials comprises the step of heating said two materials at a temperature of about 800 degrees Celsius for about one hour.

10. The method of claim 6 wherein said first material is deposited on said second material by vapor deposition.

11. The method of claim 6 wherein said first material is deposited on said second material by electrochemical deposition.

12. The method of claim 11 wherein said first material forms a thin layer on said second material.

13. A method for making a membrane comprising the steps of providing a substrate; rolling a first material onto the substrate; selectively depositing a second material onto the first material; and heating the first and second materials.

14. The method of claim 13 wherein said first material comprises copper.

15. The method of claim 13 wherein said second material comprises palladium.

16. The method of claim 13 wherein said substrate comprises inconel mesh.

17. The method of claim 13 wherein said step of heating said first and second materials comprises the step of heating said materials at a temperature of about 800 degrees Celsius for about one hour.

18. The method of claim 17 wherein said second material is deposited on said first material by vapor deposition.

19. The method of claim 17 wherein said second material is deposited on said first material by electrochemical deposition.

20. The method of claim 17 wherein said a thin layer of said second material is deposited on said first material.