Mesitylene As An Octane Enhancer For Automotive Gasoline, Additive For Jet Fuel, And Method Of Enhancing Motor Fuel Octane And Lowering Jet Fuel Carbon Emissions

Abstract

A motor fuel providing higher gas mileage comprising gasoline produced from petroleum and from about 1 to 30 wt % of mesitylene. This fuel can advantageously contain conventional additives used in gasoline. The use of mesitylene in gasoline blend yields a fuel blend with a higher research octane number and motor octane number. In addition, an improved jet fuel is provided, having from 1-10 wt % biomass-derived mesitylene added thereto, having improved carbon emission characteristics while maintaining required specifications. Further, an improved bio-fuel is provided, which may function as a replacement for conventional Jet A/JP-8 fuel and has lowered carbon emission specifications, the bio-fuel comprised of 75-90 wt % synthetic parafinnic kerosene (SPK) and 10-25 wt % mesitylene.

Description

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates in general to fuels and fuel additives and, more particularly, to automotive gasoline and jet fuel, and additives for enhancing the octane number of automotive gasoline and lowering carbon emissions of jet fuel. In one aspect, the present invention is concerned with a fuel additive for automotive fuel for enhancing the research octane number, and in another aspect to a fuel additive for enhancing the motor octane number. Another aspect of the present invention is concerned with providing a replacement additive for alcohol in motor fuels. In addition, an improved jet fuel is provided, having biomass-based and/or petroleum-based mesitylene therein, which acts to lower carbon emissions. Further, a method is provided for enhancing the octane of motor fuels by adding such mesitylene to petroleum-based gasoline, as well as additional fuel additives.

2. Description of Related Art

U.S. Pat. No. 4,398,921 discloses using a fuel additive of ethanol in automotive gasoline to boost the octane number. Ethanol was also thought to stretch the remaining worldwide supply of crude oil. There are at least two major problems with using ethanol as a fuel additive. The first problem is that ethanol-infused automotive gasoline results in much reduced mileage per gallon when compared with 100% pure gasoline. A second problem is that ethanol, at least domestically, is produced almost entirely from corn which negatively impacts on our food supply.

A careful analysis of most petroleum distillates used in the production of gasoline reveals that many trace hydrocarbons can be found. Included in those trace hydrocarbons is occasionally mesitylene, but only in very minor trace amounts of less than 0.1 wt %.

It is therefore an object of the present invention to provide a fuel additive which will boost the octane rating of automotive grade gasoline.

Another object of the present invention is to provide a fuel additive which can be combined with gasoline to boost the octane number and improve the mileage values for modern automobiles.

Yet another object of the present invention is to provide a fuel additive which can replace ethanol currently used in gasoline, and which will provide a fuel blend with improved mileage which will not negatively impact on our food supplies.

Still another object of the present invention is to provide a fuel additive which can be used to replace ethanol in gasoline, and which will provide a greater mileage range than alcohol containing gasoline.

BRIEF SUMMARY OF THE INVENTION

The present inventors have conducted research in earnest to find a fuel additive which will provide all of the benefits of ethanol without being derived from foodstuffs such as corn. The present inventors unexpectedly discovered that a fuel additive comprising mesitylene (1,3,5-trimethylbenzene) can be employed in automotive gasoline in an amount of from about 1 to 30 wt % to boost both the research octane number and the motor octane number of these fuels. It was also unexpectedly discovered that mesitylene, both bio-derived and petroleum-derived, could be used as a satisfactory replacement for ethanol in gasoline, and that the resultant gasoline/mesitylene blend would satisfy the quality fuel standard of ASTM D4814.

In a preferred embodiment, mesitylene fuel additive in an amount of about 5 to 15 wt % can be used in automotive grade gasolines (fuels) as a replacement for ethanol. These resulting blends of gasoline have surprisingly been found to produce higher research octane numbers and motor octane numbers than pure gasoline obtained from petroleum.

In another preferred embodiment, mesitylene is blended with automotive grade gasoline that does not contain ethanol. It was found that mesitylene has a higher motor octane number than ethanol and a higher energy density. This translates directly into increased mileage over ethanol-gasoline blends. This added energy of mesitylene also eliminates the need for using corn, and other foodstuffs such as sugar cane, in producing high-energy fuels.

In a first preferred embodiment, there is provided an improved motor fuel providing higher mileage per gallon (than conventional or ethanol-containing gasoline) comprising gasoline produced from petroleum and at least 1 wt % of mesitylene.

In a second preferred embodiment, there is provided in the motor fuel of the first preferred embodiment a gasoline which is a hybrid compound incorporating additives selected from the group consisting of combustion catalysts, burn rate modifiers, stabilizers, demulsifiers, dispersants, corrosion inhibitors, catalysts, detergents, ethers, antioxidants, anti-knock agents, lead scavengers, fuel dyes, and mixtures thereof.

In a third preferred embodiment, there is provided in the motor fuel of the first preferred embodiment a gasoline containing additives to increase fuel economy selected from the group consisting of Ferox, Oxyhydrogen, ferrous picrate, and mixtures thereof.

In a fourth preferred embodiment, there is provided an improved motor fuel yielding higher mileage per gallon, said motor fuel comprising:

• • (a) gasoline produced from petroleum; and
  • (b) from between about 1 to 30 wt % of mesitylene, based on the total weight of the motor fuel.

In a fifth preferred embodiment, there is provided in the motor fuel of the fourth preferred embodiment a gasoline which is a hybrid compound incorporating additives selected from the group consisting of combustion catalysts, burn rate modifiers, stabilizers, demulsifiers, dispersants, corrosion inhibitors, catalysts, detergents, ethers, antioxidants, anti-knock agents, lead scavengers, fuel dyes, and mixtures thereof.

In a sixth preferred embodiment, there is provided in the motor fuel of the fourth preferred embodiment a gasoline which contains additives to increase fuel economy selected from the group consisting of Ferox, Oxyhydrogen, ferrous picrate, and mixtures thereof.

In a seventh preferred embodiment, there is provided an improved motor fuel yielding higher mileage per gallon and comprising gasoline produced from petroleum and from about 5 to 15 wt % of mesitylene.

In an eighth preferred embodiment, there is provided in the motor fuel of the seventh preferred embodiment a gasoline which is a hybrid compound incorporating additives selected from the group consisting of combustion catalysts, burn rate modifiers, stabilizers, demulsifiers, dispersants, corrosion inhibitors, catalysts, detergents, ethers, antioxidants, anti-knock agents, lead scavengers, fuel dyes, and mixtures thereof.

In a ninth preferred embodiment, there is provided in the motor fuel of the seventh preferred embodiment a gasoline, which is a hybrid compound, incorporating additives to increase fuel economy selected from the group consisting of Ferox, Oxyhydrogen, ferrous picrate, and mixtures thereof.

In a tenth preferred embodiment, there is provided in the motor fuel of the first preferred embodiment a gasoline component having a research octane number of at least 91.6 and a motor octane number of at least 83.4.

In an eleventh preferred embodiment, there is provided in the motor fuel of the fourth preferred embodiment a gasoline component having a research octane number of at least 91.6 and a motor octane number of at least 83.4.

In a twelfth preferred embodiment, there is provided in the motor fuel of the seventh preferred embodiment a gasoline component having a research octane number of at least 91.6 and a motor octane number of at least 83.4.

In a thirteenth preferred embodiment, there is provided in the motor fuel of the first preferred embodiment a gasoline which is obtained from petroleum having a research octane number of about 91.6.

In a fourteenth preferred embodiment, there is provided in the motor fuel of the seventh preferred embodiment a gasoline obtained from petroleum which has a research octane number of about 91.6, and in admixture with mesitylene has a research octane number of at least 94.6.

In a fifteenth preferred embodiment, there is provided in the motor fuel of the seventh preferred embodiment a gasoline obtained from petroleum having a research octane number of about 88.4, and in admixture with mesitylene a research octane number of at least 90.9.

In a sixteenth preferred embodiment of the present invention, a method of increasing the research octane numbers and motor octane numbers of pure gasoline obtained from petroleum comprising mixing with said gasoline mesitylene in an amount sufficient to create a blended motor fuel comprising from about 1 to about 30 wt % of mesitylene.

In a seventeenth preferred embodiment, the method of the sixteenth preferred embodiment above is provided, further comprising adding one or more additives selected from the group consisting of combustion catalysts, burn rate modifiers, stabilizers, demulsifiers, dispersants, corrosion inhibitors, catalysts, detergents, ethers, antioxidants, anti-knock agents, lead scavengers, fuel dyes, and mixtures thereof to the blended motor fuel.

In an eighteenth preferred embodiment, the method of the sixteenth preferred embodiment above is provided, further comprising adding one or more additives to increase fuel economy selected from the group consisting of ferrocene compounds and derivatives thereof (such as Ferox®), oxyhydrogen, ferrous picrate, and mixtures thereof.

In a nineteenth preferred embodiment, an improved jet fuel (turbine fuel) having lowered carbon emission specifications is provided, comprising 90-99 wt % petroleum-derived jet fuel, and 1-10 wt % of biomass-derived or petroleum-derived mesitylene. In a most preferred embodiment, the improved jet fuel is comprised of 97 wt % jet fuel and 3 wt % mesitylene.

In a twentieth preferred embodiment, an improved an improved bio-diesel and/or bio-turbine fuel having lowered carbon emission specifications is provided, comprising 75-90 wt % synthetic parafinnic kerosene (SPK), and 10-25 wt % of biomass-derived mesitylene. In a more preferred embodiment, the improved bio-diesel fuel is comprised of 85 wt % SPK and 15 wt % biomass-derived mesitylene. In a most preferred embodiment, the improved bio-turbine fuel is comprised of 80 wt % SPK and 20 wt % biomass-derived mesitylene.

DETAILED DESCRIPTION OF THE INVENTION

In the present invention, mesitylene in an amount of at least 1 wt % can advantageously be added to any grade of gasoline. In a preferred embodiment, the mesitylene is added to a commercial grade of gasoline having a research octane number of at least about 88 and a motor octane number of at least about 81. In a more preferred embodiment, a high grade gasoline is used having a research octane number of at least about 91 and a motor octane number of at least about 83.

In a further present invention, biomass-derived mesitylene in an amount of from 10-26 wt % can advantageously be combined with SPK (synthetic paraffinic kerosene) to provide an improved diesel or turbine fuel.

The mesitylene used in the present invention can be obtained commercially by various known chemical processes, or it can be obtained by fermentation and further chemical processing of natural products such as corn, sorghum, sugar cane, sugar beets and even cellulosic materials such as certain grasses, brush, and wood. It was unexpectedly found that mesitylene, when blended with commercial grades of gasoline, meets the major parameters of the ASTM D4814 specification for automotive gasoline. These tests demonstrate that the improved motor fuel of the present invention qualifies for use in automobiles used in the United States.

According to the present invention, the gasoline component can be a hybrid compound blending in combustion catalysts such as organo-metallic compounds, burn rate modifiers to increase the fuel time burned, stabilizers/demulsifiers/dispersants to prolong the life of the fuel and prevent contamination, corrosion inhibitors, catalyst additives to prolong engine life and increase fuel economy, and detergents to clean the engines.

In a preferred embodiment, the fuel of the present invention can contain oxygenates including alcohols and ethers. In addition, the improved fuel of the present invention can include antioxidants, stabilizers, and antiknock agents, lead scavengers for leaded gasoline as well as the common fuel dyes. Other fuel additives which can be used include ferrocene compounds and derivatives thereof (such as Ferox®), catalyst additives that increase fuel economy, oxyhydrogen used to inject hydrogen and oxygen into the engine, and ferrous picrate to improve combustion and increase fuel economy.

The improved fuel of the present invention is not harmful to the environment and does not release any harmful gas and particulate matter emissions from a motor vehicle and its engines.

Example 1

A number of gasoline/mesitylene blends were prepared and tested as described hereinafter. The results of these tests are shown in Table 1, which describes tests of four fuels, and the research octane number (RON) and motor octane number (MON) for each fuel.

TABLE 1
Wt % of N-87 (87 octane) gasoline	100	95	90	85
Wt % of mesitylene	0	5	10	15
Research octane number	91.6	93.3	94.6	96.1
(BRE/30.2in/129F)
Motor octane number	83.4	84.3	84.5	84.8
(BRE/30.2in/300F)

Example 2

A number of gasoline/mesitylene blends were prepared and tested as described hereinafter. The results of these tests are shown in Table 2 which describes tests of four fuels, and the research octane number (RON) and motor octane number (MON) for each fuel.

TABLE 2
Wt % of regular gasoline (ethanol free)	100	95	90	85
Wt % of mesitylene	0	5	10	15
Research octane number (RON)	88.4	89.5	90.9	93.2
(BRE/30.2in/129F)
Motor octane number (MON)	81.4	81.6	82.2	83.1
(BRE/30.2in/300F)

It can be seen from the test results shown in Tables 1 and 2 above that the addition of various components of mesitylene to several grades of gasoline produced markedly improved research and motor octane numbers (RON and MON). Unlike general aviation, RON is just as important as MON in automotive fuel. Importantly, it has been found that the average of the MON and RON, listed at the pump as (R+M)/2, increased to 87+, which is equivalent to regular unleaded gasoline. This is significant because it is the overall same increase achieved using ethanol without the significant mileage deduction. Stated another way, the biomass-derived mesitylene-containing gasoline of the present invention is a substitute for ethanol-containing conventional gasoline, in that petroleum content of the fuel is decreased as required by law in many U.S. states, which provides increased mileage in comparison to the ethanol-containing conventional gasolines now sold.

As discussed above, in addition to motor fuel, the present inventors have found that an improved jet fuel, having lowered carbon emission specifications while maintaining other important characteristics within required specifications, can be obtained by adding thereto biomass-derived mesitylene in a certain weight range. In particular, such an improved jet fuel is comprised of 90-99 wt % petroleum-derived jet fuel, and 1-10 wt % of mesitylene.

In a most preferred embodiment, the improved jet fuel is comprised of 97 wt % jet fuel and 3 wt % mesitylene. This particular improved jet fuel composition was experimentally verified by testing performed by an independent testing laboratory. In particular, a jet fuel composition comprised of 97 wt % conventional jet fuel, and 3 wt % mesitylene was prepared, and the characteristics thereof determined to be as shown in Table 3 below:

TABLE 3
ASTM Method	Parameter	Value
D 3242	Acid number	0.002	mg KOH/g
D 1319	Aromatics	16.3	volume %
D 3227	Mercaptan sulfur	0.0005	mass %
D 5453	Sulfur	556	mg/kg
D 56	Flash point	57°	C.
D 4052	Density, 15° C.	817.9	kg/m3
D 2386	Freezing point	−46.5°	C.
D 445	Viscosity, −20° C.	5.534	mm2/s
D 4809	Net heat of combustion	42.990	MJ/kg
D 1018	Hydrogen	13.59	mass %
D 1322	Smoke point	20.5	mm
D 1840	Naphthalenes	1.56	volume %
D 130	Corrosion copper strip	1a
	(2 h/100° C.)
D 3241	Thermal Oxidation Stability
	(2.5 h/260° C.)
	Heater tube deposit rating, visual	1
	Filter pressure drop	4.6	mm Hg
D 381	Existent gum	2 mg/100 mL
D 3948	Water separation, MSEP-A	83
	rating
D 86	Distillation
	10% Recovered	185.5°	C.
	50% Recovered	216.0°	C.
	90% Recovered	252.0°	C.
	Final boiling point	274.0°	C.
	Residue	1.0	volume %
	Loss	0.5	volume %
(Barometric pressure, 761.0 mm Hg; Procedure arithmetical)

In a further preferred embodiment, as mentioned above, an improved bio-fuel, which can function as both bio-diesel and bio-turbine fuel, has been developed by the present inventors, which has been found to favorably have lowered carbon emission specifications. This improved bio-fuel is currently intended for use in turbine engines, as well as possibly diesel engines, as ethanol (which is currently contained in most gasoline) is not allowed in turbine fuel. Such improved bio-turbine/diesel fuel is comprised of 75-90 wt % synthetic parafinnic kerosene (SPK), and 10-25 wt % of biomass-derived mesitylene. In a more preferred embodiment, the improved bio-diesel fuel is comprised of 85 wt % SPK and 15 wt % biomass-derived mesitylene. In a most preferred embodiment, the improved bio-turbine fuel is comprised of 80 wt % SPK and 20 wt % biomass-derived mesitylene.

In order to determine the characteristics of such bio-fuel, as compared to conventional fuels, four test compositions (fuel blends) were prepared, as outlined in Table 4 shown below. Of the four test compositions prepared, test composition #4, having 20 wt % mesitylene, exhibited characteristics closest to conventional Jet AIJP-8 fuel. In particular, every tested parameter for test composition #4 meets the standards for Jet A/JP-8 fuel. By interpolation, a composition having 84 wt % bio-SPK and as low as 16 wt % MES will meet the specifications for Jet A/JP-8 fuel as well. In contrast, as illustrated in Table 4 below, test composition #1, comprised solely of bio-SPK, does not meet the density specification for Jet A and JP-8, which is 0.775-0.840 kg/L.

It was unexpectedly discovered that adding mesitylene at 16 wt % or greater insures that important parts of ASTM D 1655 and MEL-DTL-83133E, which are the specifications for Jet A and JP-8 respectively, are met. Further, such bio-fuel should not contain greater than 25 wt % mesitylene, as the standards for Jet A and JP-8 list the maximum aromatic content at 25 wt %. The test composition containing 20 wt % of mesitylene is most preferred, as this content of mesitylene eliminates the issues that bio-SPK has with seals (i.e., seals won't swell to the necessary degree without some level of aromatics (mesitylene in this case) in the fuel) while meeting all parameters for Jet A and JP-8. It has been found that adding mesitylene to the mixture in a 20 wt % content provides both the necessary seal swelling characteristics, while also being less damaging on those same seals versus other lighter aromatics such as toluene and xylene. Accordingly, the inclusion of mesitylene in the claimed ranges decreases issues with over-swelling and deterioration of seals in the engine.

TABLE 4
Test Composition #:	1	2	3	4
% Tri-Methylbenzene (Mesitylene):	0	5	10	20
% HRJ Tallow (bio-derived SPK):	100	95	90	80
ASTM D 4052 - 09 Density @ 15° C. (kg/L)	0.758	0.763	0.769	0.779
ASTM D 445 - 09 Viscosity @ −20° C. (mm2/s)	5.3	4.6	4.2	3.5
ASTM D 445 - 09 Viscosity @ −40° C. (mm2/s)	10.6	9.8	8.9	7.2
ASTM D 445 - 09 Viscosity @ 40° C. (mm2/s)	1.4	1.3	1.3	1.1
ASTM D93 - 09 Flash Point, ° C.	55			52
ASTM D5972 - 09 Freezing Point, ° C.	−62			<−77
indicates data missing or illegible when filed

Although specific embodiments of the invention have been disclosed, those having ordinary skill in the art will understand that changes can be made to the specific embodiments without departing from the spirit and scope of the invention. The scope of the invention is not to be restricted, therefore, to the specific embodiments. Furthermore, it is intended that the appended claims cover any and all such applications, modifications, and embodiments within the scope of the present invention.

Claims

1. An improved motor fuel providing higher gas mileage comprising: gasoline produced from petroleum, and at least 1 wt % of mesitylene.

2. The motor fuel of claim 1, wherein the gasoline is a hybrid compound incorporating additives selected from the group consisting of combustion catalysts, burn rate modifiers, stabilizers, demulsifiers, dispersants, corrosion inhibitors, catalysts, detergents, ethers, antioxidants, anti-knock agents, lead scavengers, fuel dyes, and mixtures thereof.

3. The motor fuel of claim 1, wherein the gasoline contains additives to increase fuel economy selected from the group consisting of Ferox, Oxyhydrogen, ferrous picrate, and mixtures thereof.

4. An improved motor fuel providing higher gas mileage comprising: gasoline produced from petroleum, and from between about 1 to 30 wt % of mesitylene.

5. The motor fuel of claim 4, wherein the gasoline is a hybrid compound incorporating additives selected from the group consisting of combustion catalysts, burn rate modifiers, stabilizers, demulsifiers, dispersants, corrosion inhibitors, catalysts, detergents, ethers, antioxidants, anti-knock agents, lead scavengers, fuel dyes, and mixtures thereof.

6. The motor fuel of claim 4, wherein the gasoline contains additives to increase fuel economy selected from the group consisting of Ferox, Oxyhydrogen, ferrous picrate, and mixtures thereof.

7. An improved motor fuel providing higher gas mileage comprising: gasoline produced from petroleum, and from about 5 to 15 wt % of mesitylene.

8. The motor fuel of claim 7, wherein the gasoline is a hybrid compound incorporating additives selected from the group consisting of combustion catalysts, burn rate modifiers, stabilizers, demulsifiers, dispersants, corrosion inhibitors, catalysts, detergents, ethers, antioxidants, anti-knock agents, lead scavengers, fuel dyes, and mixtures thereof.

9. The motor fuel of claim 7, wherein the gasoline contains additives to increase fuel economy selected from the group consisting of Ferox, Oxyhydrogen, ferrous picrate, and mixtures thereof.

10. The motor fuel of claim 1, wherein the gasoline component has a research octane number of at least 91.6 and a motor octane number of at least 83.4.

11. The motor fuel of claim 4, wherein the gasoline component has a research octane number of at least 91.6 and a motor octane number of at least 83.4.

12. The motor fuel of claim 7, wherein the gasoline component has a research octane number of at least 91.6 and a motor octane number of at least 83.4.

13. The motor fuel of claim 1, wherein the gasoline is obtained from petroleum and has a research octane number of about 91.6. and in admixture with mesitylene a research octane number greater than 91.6.

14. The motor fuel of claim 7, wherein the gasoline obtained from petroleum has a research octane number of about 91.6, and in admixture with mesitylene a research octane number of at least 94.6.

15. The motor fuel of claim 7, wherein the gasoline obtained from petroleum has a research octane number of about 88.4, and in admixture with mesitylene a research octane number of at least 90.9.

16. A method of increasing the research octane numbers and motor octane numbers of pure gasoline obtained from petroleum comprising: mixing with said gasoline mesitylene in an amount sufficient to create a blended motor fuel comprising from about 1 to about 30 wt % of mesitylene.

17. The method of claim 16, further comprising adding to the blended motor fuel one or more additives selected from the group consisting of combustion catalysts, burn rate modifiers, stabilizers, demulsifiers, dispersants, corrosion inhibitors, catalysts, detergents, ethers, antioxidants, anti-knock agents, lead scavengers, fuel dyes, and mixtures thereof.

18. The method of claim 16, further comprising adding to the blended motor fuel one or more additives to increase fuel economy selected from the group consisting of Ferox, Oxyhydrogen, ferrous picrate, and mixtures thereof.

19. An improved jet fuel having lowered carbon emission specifications, said jet fuel comprising: 90-99 wt % petroleum-derived jet fuel, and1-10 wt % of biomass-derived mesitylene.

20. The improved jet fuel of claim 19, comprising: 97 wt % jet fuel, and3 wt % biomass-derived mesitylene.

21. An improved bio-fuel having lowered carbon emission specifications, comprising: 75-90 wt % synthetic parafinnic kerosene (SPK), and10-25 wt % of biomass-derived mesitylene.

22. The improved bio-fuel of claim 21, comprising of 80 wt % SPK and 20 wt % biomass-derived mesitylene.