Patent Application
20140127424
This disclosure relates to a process for modifying the surface of a substrate to include additional functional groups.
Surface treatments for carbon fibers, polymeric composites, glass fibers, metallic substrates, ceramic substrates and glass substrates includes flame treatment, corona treatment, and air plasma treatment. Such surface treatments are known to be used to add a limited number of functional groups to a surface. Functional groups may be added to promote adhesion and increase surface wetting.
One example of a functional group is a hydroxyl functional group (OH−). Other types of functional groups may also be grafted onto a substrate. Using flame treatment, corona treatment, or air plasma treatment only adds a limited number of functional groups to a surface due to the limited availability of sources of hydroxyl ions and other ions in the atmosphere.
There is a need for a cost-effective and robust process for enhancing interfacial adhesion between polymeric resins and carbon, metal, ceramic and glass substrates. One example of such a substrate is a carbon fiber reinforced polymeric composite that may offer one potential solution to the problem of reducing the weight of vehicle components to achieve better fuel economy as required by government regulations.
In a carbon fiber reinforced polymeric composite, the majority of the loads are taken by the carbon fibers. The polymer transfers loads between the fibers. The load transfer efficiency of the polymer determines the mechanical performance of the composite part. The fiber/matrix interface in a conventional carbon fiber reinforced polymeric composite is limited to physical friction due to the lack of substantial chemical bonding to the surface.
Improving adhesion of the polymer to the carbon fiber surface may increase load transfer efficiency. Improved load transfer efficiency may result in a reduction in the required thickness of a carbon fiber composite part and a reduction in cost because less carbon fiber is required to handle a given load.
The above problems and other problems are addressed by this disclosure as summarized below.
The disclosed method and apparatus for adding functional groups to a surface of the substrate is unique and innovative because it increases the quantity of ions available in the plasma. For example, introducing steam into the plasma increases the availability of hydroxide (OH−) ions in the plasma. As a result, the number of hydroxyl groups on the surface may be increased.
According to one aspect of this disclosure, a method is provided for treating a substrate. This method includes the steps of providing a substrate to a tool and supplying a gaseous composition to the tool. A plasma jet generates plasma that decomposes the gaseous composition to form ions. Ions are incorporated into the plasma when the gaseous composition is ionized and the ions are more freely available to be bonded to the substrate.
According to other aspects of the method, the step of directing the plasma jet may further comprise fracturing the surface of the substrate. The substrate in one embodiment may be a carbon fiber and the gaseous composition may be steam that is decomposed to form hydroxyl ions and hydrogen ions. Carbon-to-carbon chains may be fractured to bond to new functional groups. The plasma jet may bond the hydroxyl ions to the carbon fiber substrate.
According to one aspect of this disclosure, a method is provided for making a carbon fiber reinforced polymeric composite. The method includes the steps of providing a carbon fiber substrate to a tool and supplying steam to the pre-treatment tool. A plasma jet is directed through the steam toward the carbon fiber substrate to decompose the steam to form hydroxyl ions and hydrogen ions. Some of the hydroxyl ions are then bonded to the carbon fiber.
According to other aspects of the method, the step of directing the plasma jet may further comprise fracturing a surface of the carbon fiber substrate. The method may further include covalently bonding the hydroxyl ions and hydrogen ions to the fractures in the carbon fiber substrate. The step of supplying steam may further comprise supplying water to a heating unit to form the steam, pressurizing the steam, and spraying the steam through a nozzle.
According to another aspect of this disclosure, a system is disclosed for making a carbon fiber reinforced polymeric composite from a carbon fiber substrate and a polymer resin. The system comprises a steam generator that provides steam to a pre-treatment chamber that contains the carbon fiber substrate, and a plasma jet that directs plasma towards the carbon fiber substrate through the steam. The plasma jet may be used to decompose the steam to form hydroxyl ions and hydrogen ions and bond the hydroxyl ions to the carbon fiber.
Other aspects of the disclosed system are directed to the concept of using the plasma jet to fracture a surface of the carbon fiber substrate to facilitate bonding the hydroxyl ions to the carbon fiber. The steam generator may further include a water feed system that supplies water and a heating unit that heats the water to form steam. A pump may be operatively connected to the heating unit to apply pressure to the steam in the heating unit. A spray nozzle may be used to spray the steam between the plasma jet and the carbon fiber substrate. The steam generator may further include a mass flow controller that controls the quantity of water provided by the water feed system to the heating unit.
The above aspects of the disclosure and other aspects will be described in detail below with reference to the attached drawings.
A detailed description of the illustrated embodiments of the present invention is provided below. The disclosed embodiments are examples of the invention that may be embodied in various and alternative forms. The figures are not necessarily to scale. Some features may be exaggerated or minimized to show details of particular components. The specific structural and functional details disclosed in this application are not to be interpreted as limiting, but merely as a representative basis for teaching one skilled in the art how to practice the invention.
Referring to
A gaseous composition, such as steam 20 is provided between the plasma jet 18 and the substrate. As described herein the gaseous composition provided or supplied to the plasma 16 is distinguished from using a plasma jet 18 through the atmosphere because normally occurring gases in the atmosphere fail to provide sufficient functional groups for treating the surface of a substrate. Other precursors for (OH−) functional groups include methanol, alcohol, and the like. Other gaseous compositions that may be introduced into the plasma 16 include precursors for aminogen (NH2−) functional groups that include ammonia(NH3), hydroxylamine(NH3OH), or the like. In one example, the substrate may be carbon fiber 12 and the gaseous composition may be steam 20 that facilitates forming plasma 16 that includes OH− ions 22, H+ ions, and other ions 24 that are created by the plasma 16. The steam 20 is decomposed into the hydroxyl ions 22 and the hydrogen ions 24 by the plasma jet.
The steam 20 is created by a heating unit 30 that supplies the steam 20 through a nozzle 32. The nozzle 32 directs the steam 20 into the plasma 16 created by the plasma jet 18. The plasma 16 breaks down the water molecules and the steam 20 into the OH− 22 ions and the H+ions 24. Water 36 is heated in the heating unit 30 to create the steam 20. A mass flow controller 38 is used to control the rate at which water 36 is provided to the heating unit 30. A pump 40 pumps air into the heating unit 30 to provide additional pressure at a controlled level to the heating unit 30.
Referring to
While exemplary embodiments are described above, it is not intended that these embodiments describe all possible forms of the invention. Rather, the words used in the specification are words of description rather than limitation, and it is understood that various changes may be made without departing from the spirit and scope of the invention. Additionally, the features of various implementing embodiments may be combined to form further embodiments of the invention.
