This invention relates to methods and apparatus for plating substrates.
There are various manufacturing processes during which one plates substrates. For example, during some processes for making magnetic disks, one places an aluminum alloy substrate in a plating bath to electroless plate a nickel-phosphorus alloy layer onto the substrate. Thereafter, the plated substrate is polished and textured, and one or more underlayers, one or more magnetic layers, and one or more protective overcoats are deposited (e.g. by sputtering) onto the plated substrate. (During some manufacturing processes, other layers are deposited onto the substrate as well.) Merely by way of example, one method for polishing a substrate is discussed in U.S. Pat. No. 6,149,696, issued to Jia on Nov. 21, 2000. A method for texturing a substrate is discussed in U.S. patent application Ser. No. 10/299,029, filed by Homola on Nov. 18, 2002. A method for depositing various layers onto a plated substrate is discussed in U.S. patent application Ser. No. 10/075,123, filed by Bertero et al. on Feb. 12, 2002. Jia, Homola and Bertero are incorporated by reference.
Apparatus for plating magnetic disk substrates is discussed in U.S. Pat. No. 4,581,260, issued to Mawla on Apr. 8, 1986; U.S. Pat. No. 4,516,523 issued to Knox on May 14, 1985; and U.S. Pat. No. 5,951,763, issued to Knox on Sep. 14, 1999. In these devices the substrates are held by a dowel extending through the central opening in the substrates. The substrates are then moved through a plating bath. During plating, the substrates can wobble. Imperfections may result if they touch one another. One could try to prevent the substrates from touching one another by increasing the distance between adjacent substrates, but that would reduce the number of substrates that could be plated at one time.
Apparatus in accordance with one embodiment of our invention comprises a novel structure for holding substrates during plating. The substrates are typically planar and disk-shaped. The novel holding structure comprises a set of mandrels. (As used herein, mandrels are elongated members.) The mandrels are typically cylindrical, and typically comprise notches for receiving the outer edges of the substrates. However, in other embodiments, the mandrels are not cylindrical, and do not have circular cross sections. Also, in other embodiments, the mandrels do not have notches.
In one embodiment, the holding structure holds one or more sets of substrates, each substrate within a set being generally parallel to the other substrates within that set. In one embodiment, each substrate is held at its outer edge by the mandrels. Because of this, the substrates do not wobble during plating, and therefore do not touch each other during plating.
At least one of the mandrels is removable to facilitate loading and unloading of the substrates from the holding structure. The substrates can be magnetic disk substrates having a central opening therein. Because of the manner in which the substrates are held at their outer edges, it is easier to load and unload the substrates compared to earlier substrate plating apparatus in which the substrates were held by a dowel extending through their central opening.
In one embodiment, each set is held by one side of the central mandrel and an associated set of one or more outer mandrels. (The mandrels hold the set of substrates at the outer edges of the substrates.) Thus, a plurality of sets of substrates abuts the central mandrel. In one exemplary embodiment, three sets of substrates abut the central mandrel. The first, second and third set of substrates abut a top, lower left and lower right side of the central mandrel, respectively. This arrangement of substrates permits a larger number of substrates to be held in a given volume than if the plurality of sets of substrates did not abut a common central mandrel.
In one embodiment, a gear mechanism imparts planetary motion to the substrates during plating. This gear mechanism is mechanically coupled to the holding structure.
The mandrels are typically held on their left and right ends by a left plate and a right plate, respectively. (In one embodiment, the mandrels are parallel.) At least some of the mandrels are removable to permit one to load and unload substrates into and from the holding structure. The plates comprise a slot that permits use of a tool to load and unload the holding structure. The tool comprises a mandrel for extending through an opening in the substrates. Thus, during loading and unloading, the tool mandrel is placed in the inner opening of the substrates, and lifts the substrates out of the holding structure.
A method in accordance with the invention includes the act of placing one or more substrates in a holding structure as described above. The holding structure is coupled to apparatus for moving the substrates (typically in a planetary manner). The apparatus, holding structure, and substrates are placed in a bath where a layer of material is plated onto the substrates. In one embodiment, the substrates are metallic (e.g. aluminum or an aluminum alloy), and a metallic layer (e.g. a nickel phosphorus alloy) is plated onto the substrates. After plating, the apparatus is removed from the bath, and the substrates are removed from the holding structure.
An apparatus in accordance with another embodiment of the invention comprises a holder for holding one or more substrates during plating. The holder typically has a plastic exterior, and includes a plastic member for coupling with a first race of a bearing. A second race of the bearing is also plastic, and is coupled to a rotating structure that imparts motion to the holder (and therefore to the one or more substrates held by that holder). A metallic interface (typically comprising balls or rollers) is provided between the first and second races. (The metallic interface is typically passivated to prevent the interface from becoming plated during use). Of importance, the bearing permits one to avoid or minimize the motion of plastic against plastic. This reduces the amount of friction, mechanical wear, and most importantly, generation of contaminant particles in the plating bath.
In one embodiment, a bearing with metallic races (e.g. stainless steel) as well as a metallic interface is employed. In such an embodiment, the races are typically passivated. Although this embodiment may be acceptable, metal-on-metal wearing of the races and the interface may grind away the passivation, thereby exposing metallic surfaces to the plating bath and permitting the bearing to be plated. Further, contamination particles (e.g. plated material on the bearing) may be generated. Accordingly, the embodiment using plastic races may be more desirable.
In one embodiment, a gear mechanism imparts planetary motion to the one or more substrates within the holder.
A method in accordance with another embodiment of the invention comprises the act of providing one or more substrates in a holder. The holder is mechanically coupled via a bearing to apparatus for imparting motion to the holder. The holder, one or more substrates and apparatus are placed in a plating bath, and the apparatus imparts motion to the holder. In one embodiment, the holder comprises first and second plastic races, and a metallic mechanical interface (typically a set of metal balls) therebetween. As mentioned above, this reduces the amount of friction, mechanical wear and generation of contaminant particles in the plating bath.
Referring to
In one embodiment, substrates S are disk-shaped, and can include a centrally defined opening O therein. However, in other embodiments, substrates S have other shapes.
The plating process can be electroless plating or electroplating. Optionally, in the case of electroless plating one can apply a strike voltage to substrates S to facilitate initiation of plating. Alternatively, in some embodiments, a strike voltage is not applied to substrates S. During plating, substrates S are held by four holders 12, and a drive mechanism imparts planetary motion to these holders (and therefore to the substrates S held by the holders). (Only a part of one holder 12 is shown in
Prior to plating, apparatus 10 is removed from bath 8, and substrates S are loaded into the apparatus. Apparatus 10 is then placed in bath 8 for plating. After plating, apparatus 10 is again removed from bath 8, and substrates S are removed from apparatus 10.
Holders 12
Referring to
As described below, outer mandrels MO are removable to facilitate loading or unloading holders 12 with substrates S. Also, mandrels MC, MI and MO typically comprise notches N for holding substrates S. Mandrels MC, MI and MO cooperate to hold three sets of substrates S. Substrates S are typically generally parallel, each set abutting an associated side of central mandrel MC.
In the illustrated embodiment, mandrel MC, two mandrels MI and two mandrels MO cooperate to hold one set of parallel substrates S. (Mandrels MO are removable; mandrels MC and MI are not removable.) Holder 12 comprises six removable outer mandrels MO and six non-removable mandrels MI to hold the above-mentioned three sets of substrates S. Although
Mandrels MC include portions PL, PR (
Drive Mechanism for Imparting Motion to Holders 12
Referring to
Portion PR of central mandrel MC is rigidly connected to an inner race 16R of a bearing BR (
As shown in
Ring 24R contains an opening 25R (
Portion PL of central mandrel MC is rigidly connected to a gear GL and an inner race 16L of bearing BL (
Referring to
The major difference between the drive mechanism on the right and left sides of apparatus 10 is that in the illustrated embodiment, there are no gears analogous to gear GL and GL4 on the right side of apparatus 10 for causing holder 12 to rotate about the central axis of gear GL. However, in alternate embodiments, gears analogous to gear GL and GL4 are provided on the right side of apparatus 10, either in addition to or in lieu of gear GL.
Loading and Unloading Substrates From Apparatus 10
As mentioned above, before plating, one loads substrates S into apparatus 10. After plating one removes substrates S from apparatus 10. Typically, one loads and unloads one holder 12 at a time. This is accomplished by a) moving holder 12 into a position where it can be loaded and unloaded; and then b) removing mandrels MO to load or unload holder 12.
To move one of holders 12 into a position where it may be loaded or unloaded, one first rotates wheels WL, WR until openings 22L, 22R are aligned with openings 25L, 25R (e.g. the position as shown in
One then rotates holder 12 so that one can access a desired portion of holder 12. A second pin 56 (
Thereafter, one removes the mandrels MO associated with the portion of holder 12 being accessed. As shown in
In one embodiment, mandrels MO extend through left and right locking plates 30L, 30R (
Thereafter, one reattaches mandrels MO to holder 12. Pin 56 is removed, and holder 12 is rotated so that a second portion of the holder can be accessed. Mandrels MO associated with that second portion are removed, substrates are loaded therein, and mandrels MO are reattached. The third portion of holder 12 is similarly loaded. Holder 12 is then placed back into openings 25L, 25R, and wheels WL, WR are rotated so that one can access a second one of holders 12. The second, third and fourth holders are then loaded, and locking pieces 26L, 26R are re-inserted into rings 24L, 24R. Apparatus 10 is then placed into bath 8, and motor 10 is turned on to impart motion to substrates S. After plating, apparatus 10 is removed from bath 8, mandrels MO are removed, and substrates S are removed from holders 12. (As shown in
In one embodiment, slots 60 are provided in the end plate ER of holders 12 to facilitate loading substrates S into and removing substrates S from holder 12. In particular, during loading a U-shaped tool 62 (
Embodiment in Which End Pieces EL and ER are Metallic
As mentioned above, in some embodiments end pieces EL and ER are metallic (e.g. electropolished stainless steel). Advantageously, such end plates have improved dimensional stability compared, for example, to plastics such as PVDF, which can shrink as a result of exposure to the plating environment. Optionally, the end pieces can be passivated.
In another embodiment, metallic end pieces have the additional advantage that during plating, the electrochemical environment of the surfaces of the outer substrates S directly adjacent end pieces EL and ER is similar to the electrochemical environment of the other substrates. If end pieces EL and ER were plastic, the electrochemical environment of the substrates directly adjacent to end pieces EL and ER would differ from the electrochemical environment of the other substrates, and thus the plated surfaces of the substrates directly adjacent end pieces EL and ER might not be sufficiently identical to those of the other surfaces. (This can occur because a different concentration of atoms to be plated would diffuse to the interior substrates compared to the substrates directly adjacent plates EL and ER.) Accordingly, there is a novel advantage to using metallic end pieces EL and ER.
At least some of the above-mentioned advantage concerning the electrochemical environment for the outer substrates is present even if end plates EL, ER are passivated. However, in lieu of using metallic end plates EL, ER, one could use “dummy substrates” adjacent end pieces EL and ER to achieve this result.
In embodiments in which portions of the apparatus subject to the plating bath are metal, optionally, one may subject the apparatus to a stripping and re-passivating operation between plating steps or as desired.
Alternative Embodiment of Apparatus for Holding Substrates
Holder 102 also includes left and right end pieces EL′, ER′ for holding mandrels M. Each holder coupled to a gear mechanism (similar to the gear mechanism described above) for imparting planetary motion to the substrates.
While the invention has been described with respect to specific embodiments, those skilled in the art will appreciate that changes can be made in form and detail. For example, a method and apparatus in accordance with our invention can be used to plate various types of materials, e.g. nickel phosphorus alloys, other metals, or non-metallic materials. The method and apparatus can be used to plate workpieces other than magnetic disk substrates. As used herein, “workpieces” encompasses articles to be plated. When practicing the invention, one can either a) place the plating solution in the bath prior to placing substrates in the bath; b) place the substrates in the bath prior to placing the plating solution in the bath; or c) place the plating solution and substrates in the bath simultaneously.
In some embodiments, the mandrels may comprise concave regions for holding a portion of the arc of the outer edge of the substrates being plated. Also, in some embodiments, there may be sufficient clearance for the substrates to have some degree of movement while being held by the mandrels, whereas in other embodiments, the substrates may be firmly held by the mandrels.
Pins 50 and 56 and locking pieces 26 can be tied to strings (not shown) so that they can easily be retrieved if they accidentally fall into bath 8. In lieu of engaging with gear GL, pin 56 can be pushed through wall 10R and engage with end piece ER.
It is also noted that one aspect of the invention as described above may be practiced without practicing other aspects of the invention. Accordingly, all such changes come within our invention.
This Application is a continuation-in-part of co-pending U.S. Patent Application Ser. No. 10/853,953, filed May 26, 2004, incorporated herein by reference.
Number | Date | Country | |
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Parent | 10853953 | May 2004 | US |
Child | 11088052 | Mar 2005 | US |