Patent Grant
8748072
The present invention relates to a method for producing a toner used as a developer for developing a latent electrostatic image in an electrophotography, electrostatic recording, electrostatic printing and the like, and an apparatus for producing a toner which suitably performs the method for producing a toner.
Conventionally, as a method for producing an electrophotographic toner used for copiers, printers, facsimiles or complex machines thereof on the basis of an electrophotographic recording method, only a pulverization method had been used. However, recently, a so-called polymerization method in which a toner is formed in an aqueous medium is widely used, wherein the toner produced by the polymerization method is a so-called “polymerized toner” or “chemical toner”, and the polymerization method is more commonly used than the pulverization method (Japanese Patent Application Laid-Open (JP-A) No. 07-152202). The polymerization method includes a production method without performing polymerization process for the sake of convenience. Examples of such polymerization methods in practical use include a suspension polymerization method, an emulsion polymerization method, a polymer suspension (polymer aggregation) method, and ester elongation method.
The polymerization method has an advantage of obtaining a toner having a small particle diameter with ease, a sharp particle size distribution and a substantially spherical shape, compared to the pulverization method. On the other hand, it also has a disadvantage of being inefficient because toner particles are desolvented in a solvent, typically water. Moreover, the polymerization process needs long time, and toner particles are solidified and separated from the solvent, and then repeatedly washed and dried. The process needs a long time, and a large amount of water and energy.
A spray dry method which has been known as a method in which a melt formed by dissolving a toner composition in an organic solvent, or a liquid formed by dissolving and dispersing a toner composition in an organic solvent is microparticulated using various atomizers so as to be ejected (JP-A No. 57-201248, Japanese Patent (JP-B) Nos. 3786034 and 3786035).
However, a method disclosed in JP-B Nos. 3786034 and 3786035 is not the spray dry method, but a method of ejecting droplets corresponding to a nozzle diameter from a plurality of nozzles. It has been inevitable that particle size distribution becomes broad due to aggregation of droplets, and the method does not satisfy monodispersibility of the resulted particles. A method for producing a toner disclosed in JP-A No. 57-201248 is a spray dry method that a toner material in a melting state is sprayed, and differs from the method disclosed in JP-B Nos. 3786034 and 3786035.
A method disclosed in JP-A No. 2006-293320 is that a toner composition containing a resin and a colorant and having fluidity is vibrated at a constant frequency so as to be ejected from a nozzle, thereby forming a minute droplet, and that the minute droplet is dried and solidified to from a toner particle.
The method disclosed in JP-A No. 2006-293320 has been proposed so as to solve the above-described problems disclosed in JP-B Nos. 3786034 and 3786035 by the inventors of the present invention, and enables to produce a toner with extremely high production efficiency and at energy saving because it is not necessary to use a large amount of cleaning liquid and to repeatedly separate a solvent and particles. Moreover, the time required for producing a toner can be far shorter than a polymerized toner. The method for producing a toner by jet-pulverizing disclosed in JP-A No. 2006-293320 is a method that a toner composition liquid, which is obtained by dissolving or dispersing a toner material containing at least a binder resin and a pigment in a solvent, is jetted from a head having a plurality of pores provided in a part of a container for containing the toner composition liquid, so as to form droplets, and that the jetted droplets are solidified and dried so as to obtain a toner. The jetted droplet at a certain initial velocity is decelerated at an accelerating rate by viscosity resistance of gas in a chamber, and if a direction of droplet flow is up-down, the droplet falls down at a constant velocity, i.e. free fall velocity at the point where the viscosity resistance and the gravity are counterbalanced.
This is specifically explained with reference to
The particle size distribution of the toner particles produced by the above-described method is actually examined, and double, triple, quadruple, or more droplets, which may be formed by aggregation of droplets at an equilibrium velocity, and a broad particle size distribution are observed, as it stands (
The present invention solves the above-described conventional problems, and aimed to provide a method for producing a toner and an apparatus for producing a toner, which can prevent toner particles from aggregation and stably produce a toner having a uniform particle size.
The means for solving the aforementioned problems are as follows:
where “g” represents an acceleration of gravity, Dp represents a particle diameter of a droplet, ρp represents a density of gas, ρf represents a density of the droplet, and Cr represents a coefficient of resistance which is a dimensionless number.
According to the present invention, a method and apparatus for producing a toner, which can prevent aggregation of toner particles and stably produce a toner having a uniform particle size, can be provided.
Firstly, in the case of using vertical downward air flow as transport air flow, an outline of a method and an apparatus for producing a toner of the first embodiment of the present invention will be explained. Inventors of the present invention have been studied on aggregation of droplets (hereinafter, also referred to as toner droplets) of a toner composition liquid during production of toner particles, and focused attention on that when the droplets of toner composition liquid are dried while falling down, the droplets fall at a free fall velocity before dried and solidified, and that droplets easily aggregate at the free fall velocity. Thus, the aggregation of droplets can be suppressed by preventing the droplets from falling down at the free fall velocity before they are dried and solidified.
On the basis of the consideration, the inventors of the present invention have further studied, and found that when a toner composition liquid is formed into droplets and ejected from nozzles, the aggregation of droplets can be suppressed by transporting the droplets by vertical downward air flow, as transport air flow, which has a flow rate larger than the free fall velocity of the droplets, thereby achieving the method and apparatus for producing a toner of the present invention.
According to the first embodiment of the present invention, the toner aggregation can be prevented by transporting the droplets which are entrained in transport air flow having a flow rate larger than the free fall velocity of the droplets in a method in which a solution and/or dispersion obtained by dissolving or dispersing a toner material containing at least a binder resin and a pigment in a solvent is jetted in the form of droplets from a head having a plurality of pores provided in a part of a container for containing the solution and/or dispersion, and then the jetted droplets are dried and solidified to obtain a toner. It is more preferred that a chamber for housing the jetted droplets is provided, and that a shroud for covering an area other than a plurality of pores is provided outside a container for containing a solution and/or dispersion, wherein the transport air flow is obtained by flowing gas in the shroud.
Next, in the case of using rotational air flow as transport air flow, an outline of a method and apparatus for producing a toner of the second embodiment of the present invention will be explained.
As in a method and apparatus for producing a toner of the second embodiment of the present invention, when a toner is produced in such a manner that the toner droplets jetted from a head portion are entrained in rotational air flow, the particle size distribution of the toner becomes sharp, compared to a toner obtained by a conventional toner production method in which the toner droplets are fallen down in a vertical direction, which will be described later as a result of Comparative Example.
The reasons for this may be as follows.
When a toner is produced by a conventional jet pulverization, the toner droplets are jetted vertically downward. Therefore, both a toner droplet falling down at high velocity with slow deceleration and a toner droplet falling down at low velocity with fast deceleration take the same track. Thus, when a toner droplet jetted later falls down faster than that jetted earlier, the toner droplet jetted later catches up with that jetted earlier both of which take the same track, and then the toner droplets aggregate.
On the other hand, in the case where the jetted toner droplets are entrained in rotational air flow containing a component orthogonal to a direction of gravity in any position of the air flow direction, when the particle diameters and shapes of the toner droplets vary, the velocity changes and influence from the gravity are varied depending on how viscous resistance of the gas affects the droplets of different sizes and shapes, and thus the toner droplet falling down with slow deceleration and the toner droplet falling down with fast deceleration take different tracks. Therefore, the toner droplet jetted later falling down at high velocity with slow deceleration is not easily brought into contact with the toner droplet jetted earlier.
Moreover, as each of the jetted toner droplets falls down while entrained in rotational air flow, and moves with the surrounding gas, the viscous resistance of the gas against the toner droplets is decreased, reducing deceleration. Thus, the droplet jetted later is hard to catch up with the droplet jetted earlier, and the droplet jetted later is not easily brought into contact with the droplet jetted earlier.
When a toner droplet falls down vertically just like a toner produced by a conventional jet pulverization method, all toner droplets move vertically downward, so that a moving direction of the droplet jetted later becomes a direction of the droplet jetted earlier which is caught up with the droplet jetted later. Thus, when the droplet jetted later catches up with and is brought into contact with the droplet jetted earlier, a force is applied to the droplet jetted later in a direction where the toner droplets aggregate. Thus, the toner droplets easily aggregate.
On the other hand, in the case where toner droplets are entrained in rotational air flow containing a component orthogonal to a direction of gravity in any position of the air flow direction, the velocity change of the jetted toner droplets needs to be the same in order that the jetted toner droplets fall down in the same track. Because the rotational air flow is air flow containing a component orthogonal to a direction of gravity in any position of the air flow direction, i.e. a component of the horizontal direction, in the case where the velocity change of the toner droplets are different, a balance between a velocity of movement in a gravity direction by gravity and a velocity of movement in a horizontal direction by a component of the horizontal direction of air flow is different depending on the rate of the velocity change of the toner droplet, and the jetted toner droplets take different tracks. In the case where the velocity change of the jetted toner droplets are the same, although the toner droplets take the same track, the toner droplet jetted earlier never be caught up with the toner droplet jetted later. Therefore, the toner droplets are brought into contact with each other because they fall down in the different tracks due to variations in velocity change. In the state where one toner droplet is in contact with another toner droplet, the moving direction of the one toner droplet is not the same as a direction where another toner droplet is positioned in most cases. Thus, even if the toner droplets are brought into contact with each other, they do not easily aggregate, compared to the conventional configuration in which the toner droplets fall down vertically.
When the rotational air flow is used as transport air flow, the jetted toner droplets are not easily brought into contact with each other, and they do not easily aggregate, even when they are in contact with each other. Therefore, the toner droplets are prevented from aggregation during production of a toner, and the toner has a sharp particle size distribution.
In this way, the method and apparatus for producing a toner using the rotational air flow as transport air flow enables to prevent the toner droplets from aggregation during production of a toner, and to produce the toner having a sharp particle size distribution.
By a driving device (not shown), a voltage is applied to the annular vibration unit 17 so as to vibrate. The thin film 16 vibrates by the vibration of the vibration unit 17. As shown in
If the transport air flow is not used, as described above and shown in
In this way, the production of a toner in which toner particles having a uniform particle size are stably produced while suppressing the aggregation of the toner particles.
The vibration unit 17 is not particularly limited as long as it can surely apply vibration at a constant frequency. For example, a bimorph piezoelectric element capable of exciting flexural vibration is preferable. Examples of the piezoelectric elements include piezoelectric ceramics such as lead zirconium titanate (PZT). PZT is used in a laminated state because it produces a small amount of deflection. Additionally, examples of the piezoelectric elements include piezoelectric polymers such as polyvinylidene fluoride (PVDF); crystals; and single crystals such as LiNbO3, LiTaO3 and KNbO3.
The vibrational frequency of the vibration unit 17 is preferably 20 kHz or more to less than 2.0 MHz, and more preferably 50 kHz to 500 kHz. When the vibrational frequency is less than 20 kHz, it is hard to accelerate dispersion of fine particles of colorant, wax and the like in the toner composition liquid 10 by applying vibration thereto. When the vibrational frequency is more than 2.0 MHz or more, it is difficult to stably form droplets.
The thin film 16 is a metal thin film having a thickness of 5 μm to 500 μm, and a plurality of nozzles 15 preferably have the same pore diameters in a range of 3 μm to 35 μm. The number of nozzles 15 is preferably 50 to 3,000.
The transport air flow 8 is preferably air flow formed with gas supplied through the shroud arranged in the outer periphery of the container 13, as described later. Alternatively, the transport air flow 8 may be air flow formed by a suction unit arranged at the bottom side of the container. In this case, the air flow is preferably laminar flow so that the air flow impairs the flow of the droplets 23 as little as possible.
Next, an apparatus for producing a toner of the first embodiment of the present invention will be explained with reference to
As shown in
This droplet jetting unit 2 is equipped with the droplet forming unit 11 for forming the toner composition liquid 10, which is obtained by dispersing and/or dissolving a toner composition containing at least a resin and a colorant in an organic solvent, into droplets and then ejecting the droplets, and the container 13 in which the reservoir (flow passage) 12 for supplying the droplet forming unit 11 with the toner composition liquid 10 is formed.
The droplet forming unit 11 is composed of a thin film 16 arranged on the container 13 in which a plurality of nozzles (ejection ports) 15 are formed facing the reservoir 12, and an annular vibration unit (mechanical vibration unit) 17 arranged circumference of the thin film 16 so as to vibrate the thin film 16. The circumferential portion of the thin film 16 is connected to the container 13 by soldering or with a resin binder material insoluble in the toner composition liquid 10 so as to be fixed. The annular vibration unit 17 is also connected to the thin film 16 by soldering or with a resin binder material insoluble in the toner composition liquid 10 so as to be fixed. A drive voltage is applied from a drive circuit (not shown) to the vibration unit 17 via a lead wire or the like.
It is preferable that the thin film 16 be formed of a metal plate having a thickness of 5 μm to 500 μm, in which the nozzle pores 15 have a diameter of 3 μm to 35 μm, as shown in
The liquid supply hole 20 for supplying the reservoir 12 with the toner composition liquid 10, and the liquid discharge hole 21 are respectively connected to at least a point of the container 13. A mechanism of formation of droplets by the droplet forming unit 11 is that each of the droplets 23 is ejected from the nozzles 15 in such a manner as explained with reference to
Then, in the outer periphery of the container 13, the shroud 30 having an opening 30a which faces the nozzles 15 is arranged, which forms a flow passage for gas which transports the droplets 23 flowing along an ejection direction of the toner composition liquid 10 from the nozzles 15. The shroud 30 is formed of pot-shaped double walls 30b, 30c, which are connected together with a lid 31. In the side surface of the shroud 30, a blowoff pipe 91 for blowing gas off is airtightly inserted. Of the double walls, the inner wall 30c extends to near the lower end of the container 13, and the outer wall 30b has inwardly rounded shape and extends to the position under the nozzles 15 so as to have the circular opening 30a which faces the nozzles 15. The diameter of the opening 30a is represented by “D”. The inner surface of a bottom 30d of the outer wall 30b and the lower end of the nozzles 15 maintain a clearance “G”. The size of G is smaller than that of D. Thus, G is a main factor for deciding the flow velocity of the transport air flow 8.
As shown in
Next, the flow 23a of the droplets 23 is guided in the chamber 18 having a large capacity, on which the shroud 30 and the container 13 are arranged. In
Next, the operation of the apparatus for producing a toner of the present embodiment will be explained. In the present embodiment, the toner composition liquid 10 is circulated. When the toner composition liquid 10 is contained in the container 13 with an appropriate pressure, the annular vibration unit 17 serving as a vibration unit is driven by a driving device (not shown) so as to vibrate at 100 kHz, and the vibration is transmitted to the thin film 16, and then the toner composition liquid 10 is ejected in the form of droplets 23 from each of a plurality of nozzles 15, as shown in
On the other hand, gas is blown off in the shroud 30 from the blowoff pipe 91, through which the gas is formed into the transport air flow 95, and discharged from the opening 30a to the chamber 18. The transport air flow 95 is, as shown in
Here, the laminar flow 96 as shown in
In this embodiment, the flow velocity v1 of the transport air flow 95 is larger than the initial velocity v0 of the droplet 23, and the droplet 23 is accelerated and then transported while entrained in the transport air flow 95. In the chamber, the flow velocity v2 of air flow 96 larger than the flow velocity v1 is formed. The larger the flow velocity v2 of the air flow 96 is, the more preferably the aggregation of droplets is prevented. The air flow 96 in the chamber 18 is uniformly formed in a circumferential direction by blowing gas off from the blowoff pipe 91, just like in the shroud 30. In the chamber 18 laminar flow is preferable. In order to smoothly flow the flow 23a (having a flow velocity v1) of the droplets including the droplets 23 ejected in the chamber 18 without generating turbulent flow, the flow velocity v1 of the transport air flow 95 and the flow velocity v2 of the air flow 96 in the chamber 18 preferably satisfy the relation: v2≧v1.
The transport air flow 95 in the shroud 30 and the flow velocity of the air flow 96 in the chamber 18 are controlled by the pressure gauges PG2 and PG1. The pressure P1 in the shroud 30 and the pressure P2 in the chamber 18 preferably satisfy the relation: P1≧P2. If this relation is not maintained, the droplets 23 may possibly flow back. In
As described above, a rate limiting factor for determining the flow velocity of the transport air flow 95 in the shroud 30 is the clearance G between the wall 30b and the head 2a, because of the condition D>G.
In this way, both the transport air flow 95 in the shroud 30 and the air flow 96 in the chamber 18 are respectively formed by blowing gas from the blowoff pipe 91 located above the chamber 18, and from the blowoff pipe 93 located in the chamber 18. However, air flow can be formed by suctioning the internal air from the pipe 92 arranged at the bottom of the chamber 18.
The cross-section of the diameter of the opening 30a of the wall 30b of the shroud 30 increases along the direction for discharging gas. That is, a taper 30e is arranged so that its diameter increases with distance from the opening 30a. The taper 30e formed in the opening 30a can prevent the droplets 23 from being in contact with and adhering to the surface of the opening 30a, when the droplets 23 pass through the opening 30a.
The size of the main part of the apparatus for producing a toner of the present embodiment is as follows:
The container 13 has a diameter of 23 mm and a height of 10 mm. The liquid supply hole 20 and the liquid discharge hole 21 have a height of 54 mm. The pipes 7 and 9 have a diameter of 4 mm. The thin film 16 is a nickel plate and has a diameter of 12 mm and a thickness of 20 μm. The nozzle 15 has a diameter of 10 μm and 800 nozzles are formed in a central area having a diameter of 5 mm of the thin film 16. The shroud 30 has an inner wall 30c having a diameter of 22 mm, an outer wall 30b having a diameter of 36 mm and a height of 55 mm. The clearance G is 3 mm, and the opening 30a has a diameter of 9 mm. The blowoff pipe 91 of the shroud 30 has a diameter of 6 mm. The chamber 18 has an inner diameter of 74 mm and a height of 160 mm. The blowoff pipe 93 of the chamber 18 has a diameter of 12 mm. In the apparatus, the amount of gas blowing in the chamber 18 is 1.5 g/min. The shroud 30 has a pressure P1 of 40 kPa and the chamber 18 has a pressure P2 of 15 kPa. The flow velocities v0 and v1 are respectively 8 m/s and 26 m/s. The temperature inside the chamber 18 is 27° C. to 28° C. The free fall velocity is 2 mm/s to 10 mm/s. The fall velocity of the droplets is substantially the same as the flow velocity v1. It is understood that the flow velocities v0 and v1 are drastically larger than the free fall velocity. These velocities can be measured in such a manner that a scale for measuring a length is set in the background part of the flow 23a of the droplets 23 ejected from the droplet forming unit 11, and then the droplets 23 are photographed with a high speed camera and recorded.
In the present embodiment, as the gas to be blown, nitrogen gas is used in the shroud 30 and the chamber 18. Air may also be used. In
Hereinafter, the second embodiment of an apparatus for producing a toner of the present invention will be explained.
The apparatus 100 for producing a toner includes a liquid container 114 for containing a toner liquid 103 obtained by dissolving or dispersing a toner material containing at least a binder resin and a pigment in a solvent, and a chamber 109 serving as a dry container which is arranged under the liquid container 114.
In a part of the lower part of the liquid container 114, a head portion 101 having a plurality of pores is provided, and the toner liquid 103 in the liquid container 114 is ejected from the pores of the head portion 101 in the form of droplets (toner droplets Td), and then the ejected droplets are dried and solidified in the chamber 109, thereby obtaining a toner. As shown in
As shown in
The shroud 123 is formed of pot-shaped double walls including an outer wall 231a and an inner wall 231b, and the liquid container 114 is arranged inside the inner wall 231b. The outer wall 231a and the inner wall 231b are formed in a cylindrical shape except the lower part thereof, and the outer wall 231a and inner wall 231b are connected with a lid 232. Both the outer wall 231a and the inner wall 231b have openings which face the head portion 101.
As shown in
Into the shroud space 231c, gas is blown off from the pipes 191 in a tangential direction with respect to the cylindrical shaped part of the pot-shaped inner wall 231b. The gas blown from the pipes 191 passes through the shroud space 231c between the cylindrical shaped part of the inner wall 231b and the cylindrical shaped part of the outer wall 231a, so as to form spiral rotational air flow 106 as shown in
The inner wall 231b of the double wall of the shroud 123 extends to near the lower end of the container forming member 121. The outer wall 231a has the inwardly rounded shape and extends to the bottom of the head portion 101 so as to form a circular-shaped outer wall opening 234 located under the head portion 101. The inner surface of a bottom of the outer wall 231a of the shroud 123 and the lower end of the head portion 101 maintain a clearance 233. The width “G” of the clearance 233 is smaller than the diameter “D” of the outer wall opening 234. Thus, the width G is a main factor for deciding the flow velocity (confluent position of flow velocity v1) of the rotational air flow 106 in a position where the rotational air flow 106 entrains the jetted toner droplets Td.
As shown in
Specifically, the air flow which has passed through the shroud space 231c of the shroud 123 is hard to pass though the clearance 233, because the width G of the clearance 233 between the top surface of the opening member 238 and the lower surface of the head portion 101 is narrow, and then the air flow passes through the six grooves 238a. The six grooves are arranged at substantially equal spaces and extend from the periphery of the opening member 238 to the outer wall opening 234 located in the center, so as to guide the air flow to the outer wall opening 234 in such a manner that the air flow spirally rotates with the rotation diameter gradually narrowing as the air flow coming closer to the bottom as shown in
As shown in
The container formation member 121 has two holes in which two guide pipes 122a and 122b are fitted and fixed. The toner liquid supplying part 102 is composed of the liquid container 114 which is composed of the container formation member 121 and the guide pipes 122a and 122b. A disc 111 is arranged on the bottom of the container formation member 121 so as to form the bottom of the liquid container 114.
The toner liquid supplying part 102 which supplies the chamber 109 with the toner liquid 103 is as explained above with reference to
The toner liquid 103 is jetted while circularly flowed in the apparatus 100 for producing the toner of the present invention. When the toner liquid 103 in the liquid container 114 is used up under resting condition, the valve 131 is opened to fill the toner liquid 103 therein.
The toner droplets Td jetted from the head portion 101 pass through the outer wall opening 234 of the shroud 123 and are guided to the chamber 109 having a large capacity. In
Next, the operation of the apparatus for producing a toner of the present embodiment will be explained.
When vibration is applied to the annular vibration plate 112 by a driving device (not shown), the vibration is transmitted to the disc 111 in the head portion 101 (
In the present embodiment when the vibration of 100 kHz is applied to the annular vibration plate 112, the vibration is transmitted to the disc 111 so as to vibrate the disc 111 up and down (
Here, when the rotational air flow 106 is not formed, the jetted toner droplets Td are decelerated by the resistance of air viscosity, and counterbalanced at terminal velocity, occurring aggregation (
The terminal velocity is calculated by Equation (1).
Terminal velocity=[{4g·Dp·(ρp−ρf)}/(3ρf·Cr)]1/2 Equation (1)
In Equation (1), “g” represents an acceleration of gravity, Dp represents a particle diameter of a droplet, ρp represents a density of gas, ρf represents a density of the droplet, and Cr represents a coefficient of resistance (dimensionless number).
According to the present embodiment, the toner droplets Td jetted from the head portion 101 have substantially the same size, and have a spherical shape because of the surface tension of the droplets. Therefore, the droplets do not have different terminal velocities, but the same terminal velocity.
Specifically, according to the present embodiment, the toner droplet Td jetted from the head portion 101 has a diameter of 12 μm and a terminal velocity of 4.1×10−3 m/sec, being an extremely small value. The direction of the rotational air flow 106 is formed by air flow containing a component orthogonal to a direction of gravity, and the flow velocity v1′ at the confluence point of the rotational air flow 106 is set faster than the terminal velocity, thereby more certainly preventing the toner droplets Td from aggregation.
The track of the toner droplets Td entrained in the rotational air flow 106 is corrected in the transport air flow, and the toner droplets Td flow down at the velocity equal to that of the rotational air flow 106. Thus, turbulent flow is formed, and the jetted droplets do not aggregate and are dried and collected. In view of preventing the droplets from aggregation, the flow velocity v1′ of the rotational air flow 106 is preferably larger than the initial velocity v0′.
When the air flow for entraining the jetted toner droplets Td is not the rotational air flow 106 but laminar flow, a considerably large amount of gas is necessary to be charged in the shroud in order to satisfy the relation: v1′>v0′. The rotational air flow 106 enables to reduce the amount of gas down to one-tenth of the amount of the gas required for the laminar flow.
On the other hand, gas is blown into the shroud 123 from the blowoff pipe 191, and the blown air flow passes through the shroud so as to form the rotational air flow 106 and is discharged from the outer wall opening 234 to the chamber 109. The rotational air flow 106 is as shown in
According to the apparatus 100 for forming a toner of the present invention, by forming the rotational air flow 106 in a position where the toner droplets Td are jetted from the head portion 101, the jetted toner droplets Td are not decelerated as in the conventional example explained with reference to
In the apparatus 100 for forming a toner of the present embodiment, the flow velocity v1′ at the confluence point of the rotational air flow 106 is larger than the initial velocity v0, and the movement of the toner droplets Td are accelerated when being entrained in the rotational air flow 106 and then the toner droplets Td are transported while entrained in the rotational air flow 196 in the chamber. The larger flow velocity of the rotational air flow 106 is preferably used to prevent the droplets from aggregation. The air flow in the chamber 109 is uniformly formed in a circumferential direction by blowing gas off from the blowoff pipe 197 in the chamber, just like in the shroud 123. In the chamber 109, turbulent flow is preferred in order to enhance drying capability. In order to smoothly flow down the rotational air flow 106 even when the rotational air flow 106 having a flow velocity v1 including the toner droplets Td ejected in the chamber 109 becomes turbulent flow, the flow velocity v1 of the rotational air flow 106 and the flow velocity v2′ in the chamber 109 preferably satisfy the relation: v2′≧v1′.
The flow velocity in the shroud 123 and that in the chamber 109 are controlled by the pressure gauges. When the pressure in the shroud 123 and that in the chamber 109 are respectively defined as P1 and P2, P1 and P2 preferably satisfy the relation: P1≧P2. If this relation is not maintained, the toner droplets Td may possibly flow back from the chamber 109 to the shroud 123.
As described above, the factor for deciding the flow velocity v1′ at the confluence point, which is the flow velocity of the rotational air flow 106 at the confluence point where the rotational air flow 106 entrains the toner droplets Td in the shroud 123 is the relation between the diameter D of the outer wall opening 234 and the width G of the clearance 233 which satisfies D>G. Moreover, other factors for deciding the flow velocity v1′ at the confluence point are the opening member 238 having the groove 238a, and the width G of the clearance 233 between the outer wall 231a and the head portion 101 which has been explained with reference to
In the apparatus 100 for producing a toner of the present embodiment, the rotational air flow 106 in the shroud 123 and the rotational air flow 196 in the chamber 109 are formed by blowing gas from the blowoff pipes 191 and 197 respectively arranged in the upper part thereof. Alternatively, the air flow may be formed by a suction pipe arranged at the bottom part of the chamber 109.
The cross-sectional outer wall opening 234 which is an opening for the outer wall 231a of the shroud 123 preferably has a taper of which diameter increases outwardly as shown in
The size of the main part of the apparatus 100 for producing a toner of the present embodiment is as follows:
The container formation member 121 has an outer diameter of 23 mm, and a height of 10 mm. The toner liquid supplying part 102 has a height of 54 mm. The guide pipes 122a and 122b have an inner diameter of 4 mm. The disc 111 is a nickel plate having a diameter of 12 mm and a thickness of 20 mm. A plurality of nozzle pores 113 have a diameter of 10 mm, and 800 nozzle pores are formed in a central area having a diameter of 5 mm of the disc 111. The shroud 123 has an inner wall 231b having an outer diameter of 22 mm, an outer wall 231a having an outer diameter of 36 mm, and a height of 55 mm. The clearance 233 has a width “G” of 3 mm, and the opening having a diameter of 9 mm. The blowoff pipe 191 of the shroud 123 has an inner diameter of 6 mm. The chamber 109 has an inner diameter of 74 mm, and has a height “H” shown in
The explanation of other configurations is omitted, because the configurations of the first embodiment can be applied to the second embodiment.
Hereinafter, the preparation of a toner composition used in the present invention will be explained on the basis of the examples, which however shall not be construed as limiting the scope of the present invention. All percentages and parts are based on mass unless indicated otherwise.
—Preparation of Colorant Dispersion Liquid—
Firstly, as a colorant, a dispersion liquid of carbon black was prepared.
Specifically, 17 parts of carbon black (REGAL 400, manufactured by Cabot Corp.) and 3 parts of a pigment dispersant were added to 80 parts of ethyl acetate, and primarily dispersed using a mixer having a stirring blade to obtain a primary dispersion liquid. As the pigment dispersant, AJISPER PB821 (manufactured by Ajinomoto Fine-Techno Co., Inc.) was used. The obtained primary dispersion liquid was finely dispersed under strong shearing force using a DYNO MILL to prepare a secondary dispersion liquid in which aggregates having a size of 5 μm or more were completely removed.
—Preparation of Wax Dispersion Liquid—
Next, a wax dispersion liquid was prepared.
Specifically, 18 parts of a carnauba wax and 2 parts of a wax dispersant were added to 80 parts of ethyl acetate and primarily dispersed using a mixer having a stirring blade to prepare a primary dispersion liquid. The primary dispersion liquid was heated to 80° C. with stirring to dissolve the carnauba wax therein, and then the temperature of the primary dispersion liquid was decreased to room temperature to precipitate wax particles so as to have a maximum diameter of 3 μm or less. As the wax dispersant, the one prepared by grafting a styrene-butyl acrylate copolymer on a polyethylene wax was used. The obtained dispersion liquid was further finely dispersed under strong shearing force using a DYNO MILL so as to prepare a wax dispersion liquid having a maximum diameter of 2 μm or less.
—Preparation of Toner Composition—
Next, a toner composition dispersion liquid, in which a binder resin, the colorant dispersion liquid and the wax dispersion liquid were added, composed of the following composition was prepared.
Specifically, 100 parts of polyester resin as a binder resin, 30 parts of the colorant dispersion liquid, 30 parts of the wax dispersion liquid, and 840 parts of ethyl acetate were stirred for 10 minutes using a mixer having a stirring blade so as to be uniformly dispersed. The pigment or wax particles were not aggregated by solvent dilution.
Such toner composition liquid was used in the apparatus 1 for producing a toner (an apparatus for producing a toner using vertical downward air flow) as shown in
Next, a carrier was produced by the following method.
Core: spherical ferrite particles having an average particle diameter of 50 μm
Coating material: a silicone resin
The silicone resin was dispersed in toluene so as to prepare a dispersion liquid. The dispersion liquid was spray coated on the core under heating condition, fired, and cooled so as to produce a carrier particle coated with a resin film having an average thickness of 0.2 μm.
The final toner (5 parts) were added to and mixed in 100 parts of the carrier so as to obtain a developer.
An image was formed using the developer by a commercially available copier, IMAGIO NEO 450 (manufactured by Ricoh Company, Ltd.), thereby obtaining an image having a sufficient image density and sharpness.
A toner of Comparative Example 1 was obtained in the same manner as in Example 1 by jetting droplets under the conditions of the same toner composition, the droplet jetting unit 2, the chamber 18 and the like, except that the shroud 30 was not provided. The particle size distribution of the toner was measured in the same manner as in Example 1. The toner of Comparative Example 1 had a mass average particle diameter (D4) of 5.9 μm and a number average particle diameter (Dn) of 5.4 μm, and an average ratio of D4/Dn of 1.09. The toner of Comparative Example 1 was compared with the toner of Example 1 as follows:
The aggregation of toners was evaluated using a plurality of samples of toners respectively obtained by the method for producing a toner of Example 1 and the method for producing a toner of Comparative Example 1. The evaluation was based on the occupancy of so-called toner having a large particle diameter, namely, a particle diameter of 12.7 μm or more. The occupancy was obtained by measuring a particle size distribution using COULTER COUNTER MULTISIZER III, manufactured by Beckman Coulter Inc. The so-called toner having a large particle diameter, i.e. a particle diameter of 12.7 μm or more, has been known that it is inconvenient for use. As a result of measurement, the occupancy of the particle diameter of 12.7 μm or more in the toner of Comparative Example 1 was 30% to 40%, while that in the toner of Example 1 was 3% to 5%, being outstandingly low. As is clear from the result, the aggregation of droplets was outstandingly decreased by using the toner obtained by the method for producing a toner of Example 1 of the present invention.
A toner of Example 2 was produced in the same manner as in Example 1, except that the apparatus 1 for producing a toner shown in
As a result of measuring the particle size distribution of the toner of Example 2 in the same manner as in Example 1, the occupancy of the particle diameter of 12.7 μm or more in the toner of Example 2 was 0.5% to 4%, being outstandingly low.
Thus, it is understood that the aggregation was outstandingly decreased by generating the rotational air flow as in the apparatus 100 for producing a toner of the present embodiment.
In the apparatus 100 for producing a toner, gas is flowed in a shroud space 231c between an outer wall 231a and an inner wall 231b in a shroud 123, so as to generate rotational air flow 106. The configuration of generating the rotational air flow is not particularly limited as long as the rotational air flow for entraining the toner droplets Td jetted from a head portion 101 can be generated. The configuration is not limited to those using the shroud 123.
As stated above, in the apparatus 100 for producing a toner of the second embodiment, a toner liquid 103, which is a solution and/or dispersion obtained by dissolving or dispersing a toner material containing at least a binder resin and a pigment in a solvent, is contained in a liquid container 114 equipped with a head portion 101 having a plurality of nozzle pores 113, and the toner liquid 103 in the liquid container 114 is jetted from the head portion 101 so as to form toner droplets Td, and the jetted toner droplets Td entrained in the rotational air flow 106 and are dried and solidified so as to obtain a toner. In the case where the jetted toner droplets Td are entrained in the rotational air flow 106, when the particle diameters and shapes of the toner droplets Td vary, the velocity changes and influence from the gravity are varied depending on how viscous resistance of the gas affects the toner droplets Td of different sizes and shapes, and thus the toner droplets Td falling down with slow deceleration and the toner droplets Td falling down with fast deceleration take different tracks. Therefore, the toner droplet Td jetted later falling down at high velocity with slow deceleration is not easily brought into contact with the toner droplet Td jetted earlier. Each of the jetted toner droplets Td falls down while entrained in the rotational air flow 106, so that each of the toner droplets Td moves with the surrounding gas, and the viscous resistance of the gas against the toner droplets Td is decreased, reducing deceleration. Thus, the toner droplet Td jetted later is hard to catch up with the toner droplet Td jetted earlier, and the toner droplet Td jetted later is not easily brought into contact with the toner droplet Td jetted earlier. As for the toner droplets Td entrained in the rotational air flow 106, in the state where one toner droplet Td is in contact with another toner droplet Td, the moving direction of the one toner droplet Td is not the same as a direction where another toner droplet Td is positioned in most cases. Thus, even if the toner droplets Td are brought into contact with each other, they do not easily aggregate, compared to those in the conventional art. In the apparatus 100 for producing a toner of the present embodiment, the jetted toner droplets Td are not easily brought into contact with each other, and even if they are in contact with each other, they do not easily aggregate. Therefore, it is possible to prevent the toner droplets Td from aggregation during production of a toner, and the toner having a sharp particle size distribution can be produced.
In the apparatus 100 for producing a toner, the flow velocity v1′ of the rotational air flow 106 at the confluence point is set faster than the terminal velocity of the toner droplets Td. Thus, the toner droplets Td can be certainly prevented from contacting therebetween, and can also be prevented from aggregation.
In the apparatus 100 for producing a toner, the shroud 123 which covers an area other than the head portion having a plurality of nozzle pores 113 is provided outside the liquid container 114, and the rotational air flow 106 is obtained by flowing gas in the shroud space 231c between the outer wall 231a and the inner wall 231b of the shroud 123. The rotational air flow 106 can be generated by providing such shroud 123.
In the apparatus 100 for producing a toner, the rotational air flow 106 is obtained by blowing gas from a blowoff pipe 191 arranged in the upper part inside the shroud 123. Thus, by blowing gas off in the upper part of the shroud 123, the gas passes through the cylindrical shroud space 231c so as to form the rotational air flow 106. Even if the gas is introduced in the shroud space 231c by other methods, it is difficult to efficiently form the rotational air flow 106 in the same manner as in the apparatus 100 for producing a toner of the present embodiment.
In the apparatus 100 for producing a toner, the rotational air flow 106 is obtained by blowing gas off from the pipe 191 in a tangential direction with respect to the inner wall 231b of the shroud 123. The rotational air flow 106 is generated by blowing off gas from the pipe 191 in the tangential direction. When the air flow is generated in directions other than the tangential direction, the air flow strikes on the inner wall 231b or the outer wall 231a of the shroud 123 so as to form turbulent flow. Thus, it is difficult to efficiently form the rotational air flow 106 in the same manner as in the apparatus 100 for producing a toner of the present invention.
In the apparatus 100 for producing a toner, the shroud 123 having the outer wall opening 234 in a position corresponding to a plurality of nozzle pores 113, and in which a taper is arranged so that its diameter increases with distance from the outer wall opening 234.
Thus, the space density of the toner droplets Td ejected from an outlet of the shroud 123 can be decreased. That is, in the case of the large particle density, the droplets aggregate to some extend during drying even in the rotational air flow 106, and the effect of preventing droplets from aggregation is decreased. By contrast, the taper can enhance the effect of aggregation prevention obtained by generating the rotational air flow 106, as much as possible.
Moreover, unlike the apparatus 100 for producing a toner of the present embodiment, an apparatus may have a chamber 109 which is a dry container for containing and drying the jetted toner droplets Td, and may be configured to obtain the rotational air flow 106 by suctioning gas from a suction pipe arranged at the bottom of the chamber 109. Furthermore, the configuration of blowing gas off from the blowoff pipe 191 and the pipe 197 in the chamber, and the configuration of suctioning gas from a suction pipe arranged under the chamber 109 may be combined. Thus, the toner droplets Td ejected from the outer wall opening 234 serving as the outlet of the shroud 123 can be effectively dried. That is, air flow can be generated so as to fall straightly down the toner droplets Td with rotating, while they are entrained in the rotational air flow 106, just like a spray dry method. Thus, the toner droplets Td are rapidly dried to be a toner.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2008-162781 | Jun 2008 | JP | national |
| 2008-164049 | Jun 2008 | JP | national |
| Number | Name | Date | Kind |
|---|---|---|---|
| 20080063971 | Watanabe et al. | Mar 2008 | A1 |
| 20080286679 | Norikane et al. | Nov 2008 | A1 |
| 20080292985 | Suzuki et al. | Nov 2008 | A1 |
| 20090117486 | Watanabe et al. | May 2009 | A1 |
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| Entry |
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| Office Action issued Aug. 3, 2012, in Japanese Patent Application No. 2008-164049. |
| Office Action issued Aug. 21, 2012, in Japanese Patent Application No. 2008-162781. |
| Number | Date | Country | |
|---|---|---|---|
| 20090317738 A1 | Dec 2009 | US |
