This is a national stage application filed under 35 U.S.C. § 371 of pending international application PCT/EP2018/059493 filed Apr. 13, 2018, which claims priority to Belgian Patent application BE 20175270, filed Apr. 19, 2017, the entirety of which applications are hereby incorporated by reference herein.
The present invention relates to a method and system for analysing an at least partially transparent object, such as a gemstone, and in particular for analysing internal and/or external features of a gemstone, such as inclusions. Embodiments of the invention are described herein with particular reference to evaluation of diamonds, but the skilled person will understand that the invention is also applicable to other types of precious and semi-precious gemstones. Moreover, the invention is applicable for both rough gemstones, polished gemstones as well as semi-polished gemstones. In addition, the invention is also applicable for any at least partially transparent object that requires study of its internal and/or external features, such as objects made of glass and synthetic minerals with different shapes.
The value of a cut diamond is determined to a significant extent by the four C's: cut, clarity, carat and colour. In addition to measuring weight, colour, size and cut, to evaluate the diamond, the inclusions must be located and their influence on the cost of the final brilliant must be minimized. The stone may have internal or external flaws or inclusions. Note that the terms “flaw”, “inclusion” and “defect” are used as synonyms referring to a visually discernible irregularity inside the gemstone. There are various causes of inclusions, e.g. crystals of a foreign material, another crystal of the gemstone itself, or imperfections such as cracks which may appear whitish or cloudy. The clarity of a gemstone such as a diamond will depend on the number, size, colour, location, orientation and visibility of the inclusions. By locating and identifying inclusions within a rough (unpolished) gemstone, it is possible, in principle, to plan the cutting of the gemstone in such a manner as to minimize the impact of those inclusions upon the clarity of the final cut and polished stone.
The task of evaluating a diamond appears at almost all stages of the process from mining to selling. The choice of the evaluation method in a particular case depends on many factors. From the point of view of technique, many methods have been developed historically. One known method is based on the use of an immersion liquid. In this method, typically, a diamond is glued to a holder and submerged in an immersion solution with the same refractive index as diamond. As a result, the diamond “disappears”, but any inclusions remain visible. The stone in the immersion liquid is rotated and 2D images are obtained from a plurality of different viewing directions to determine properties of the inclusion(s). A problem which occurs when using this method is that the holder holding the diamond remains visible during the analysis, and the obscuration or reflection of light caused by the holder hampers the quality of evaluation. In addition, the diamond cannot be evaluated from all directions due the obscuration caused by the holder.
WO2012/004351 in the name of the applicant addresses this problem and discloses a method for analysing a gemstone, typically for locating inclusions in a gemstone, comprising the steps of: selecting a solid material which is transparent in at least a segment of the visible spectrum; melting or plasticizing said solid material and immersing the gemstone in said melted or plasticized material such that the gemstone is at least partly covered therein; allowing said melted or plasticized material to become solid such that a solid transparent block is obtained containing the gemstone; and analysing the gemstone through a surface of the transparent block using light rays in the visible spectrum. By immersing the gemstone in a solid block it is not necessary to polish out windows in the gemstone itself, avoiding the risk that volume of the potential polished stone is decreased. This also means that after examination if the gemstone is under pre-purchase consideration and is rejected based on the inclusion evaluation, the gemstone can be removed from the transparent material and returned to its owner. Although this method addresses the above mentioned problem, it may not always be desirable to include the object to be analysed in a solid block.
It is an object of embodiments of the present invention to provide an improved method for analysing an at least partially transparent object, such as a gemstone, which allows for obtaining an improved view of the internal and/or external features of the at least partially transparent object without having to built in the object in a solid material.
According to an aspect of the invention there is provided a method for analysing an at least partially transparent object, such as a gemstone, comprising: fixing the object in a holder; immersing the object in the holder in an immersion material; analysing internal and/or external features of the object. The analysing comprises visualizing an internal and/or external portion of the object using light rays of a wavelength while the object is immersed in the immersion material, and determining characteristics of the object based on the visualized internal and/or external portion of the object. Under the conditions at which the analysing is performed, the difference between the refractive index (RI) of the immersion material and the RI of at least an immersed portion of the holder which is in contact with the object is less than 0.3.
By selecting an immersion material that has a RI similar to the RI of the immersed portion of the holder, the holder remains substantially “invisible” during the analysis of the object and in the images obtained. Therefore any obscuration or reflection of light by the holder is significantly reduced, improving the quality of analysis. Indeed, the visualizing of an internal and/or external portion of the object while the object is immersed in the immersion material, will result in images with less “noise” caused by the holder. Hence, the determining of characteristics of the object using computer means based on the visualized internal and/or external portion of the object, will result in improved results.
The conditions comprise any conditions that may influence the value of the refractive index during the analysing, such as the temperature range used during the analysing and the wavelength range used during the analysing. The refractive index of a material is dependent on the temperature and the wavelength of the light rays. Preferably, the immersion material is selected such that for the temperature and wavelength range used during the analysing, the difference between the RI of the object and the RI of the immersion material is lower than 0.3.
Preferably, under the conditions at which the analysing is performed, the difference between the RI of the object and the RI of the immersion material is lower than the difference between the RI of the gemstone and the RI of air. More preferably, the difference between the RI of the object and the RI of the immersion material is less than 0.5, even more preferably less than 0.3. This will further improve the quality of the obtained images.
Preferably, under the conditions at which the analysing is performed, the difference between the RI of the immersion material and the RI of the immersed portion of the holder is less than 0.2, more preferably less than 0.1, and most preferably less than 0.05. However if the RI of the studied object is low enough to match more or less with the RI of the immersion liquid, then the immersed portion of the holder may be made from the same material as studied object.
According to an exemplary embodiment, the visualizing comprises a step of illuminating the object while the object in the holder is immersed in the immersion material, and detecting the illumination having passed through the illuminated object in order to obtain a 2D image. The illuminating may be done using light rays with different wavelengths, e.g. using light rays in the visible spectrum.
Preferably the analysing is controlled by computer means. For example, the moving of the holder, the illuminating by an illumination system and/or the detecting of light having passed though the illuminated object may be controlled by one or more computers. More in particular, the computer means can control the holder, the illumination system, and the detector in order to obtain images of the object in different positions of the holder with respect to the illuminating system and detector.
From those images relevant information regarding the internal and/or external features of the object may be derived. If the object is a gemstone, e.g. a location and/or shape of an inclusion can be derived. More in particular such images will allow building a 3D model of an inclusion of the gemstone. For the building of a 3D model of an inclusion based on images of the gemstone, further reference is made to U.S. Pat. No. 9,292,966 in the name of the same inventor, which is included herein by reference.
According to yet another exemplary embodiment, the at least partially transparent object is a gemstone, such as diamond, ruby, sapphire and emerald. However embodiments of the invention can also be used to analyse any at least partially transparent object that requires study of its internal and/or external features, for example, objects made of glass and synthetic minerals with various shapes, e.g. flat plates, cylinders, lenses, and complex forms.
According to yet another exemplary embodiment, the immersed portion of the holder is made of a material or a combination of materials belonging to the classes of glass, or quartz, or plastic.
Preferably, the immersion material is an immersion liquid, more preferably a transparent or translucent liquid. Preferably, the transmittance of the immersion liquid, under the conditions used during the analysing, is larger than 10%, more preferably larger than 50%, and most preferably larger than 75%. The transmittance depends on the immersion liquid used, the thickness of the liquid layer, the wavelength and the temperature, and the immersion liquid and/or the analysing conditions are preferably chosen such that the transmittance of the immersion liquid, is larger than 10%, more preferably larger than 50%, and most preferably larger than 75%.
Preferably the immersion liquid is an oil. In an exemplary embodiment, under the conditions used during the analysing, the oil has a refractive index between 1.43 and 1.45, e.g. RI approximately 1.44. Oil with RI of approximately 1.44 has the advantage that the RI is close to the RI of fused silica which is a suitable material for manufacturing the holder. In another exemplary embodiment, under the conditions used during the analysing, the oil has a refractive index between 1.51 and 1.53, e.g. RI approximately 1.52. In that case quartz can be used for manufacturing the holder.
According to an exemplary embodiment, the analysing comprises translating and/or rotating the holder, so that the visualizing of the object can be done from a plurality of directions.
According to an exemplary embodiment, the analysing comprises selecting at least one monochromatic light source with a certain wavelength from a plurality of monochromatic light sources with different wavelengths. This will allow optimizing the analysing. For example, when different object features have to be analysed, the analysis of which requires different optimal wavelengths, then this embodiment will allow selecting the post appropriate wavelength for the respective feature to be analysed, resulting in an improved analysis result. Also, the wavelength may be selected such that the difference in RI between the object to be measured and the RI of the immersion material is minimal.
According to an exemplary embodiment, the analysing comprises selecting at least one monochromatic light source set at a certain location from a plurality of monochromatic light sources set at different locations. This will allow optimizing the analysing. For example, using light sources set at different locations, the object can be illuminated from different directions, and different object features can be better revealed.
According to an exemplary embodiment, the analysing comprises controlling the temperature of the immersion material during the analysing in order to control the difference between the RI of the immersion material and the RI of the immersed portion of the holder, and more in particular in order to minimize said difference for the wavelength used. In that manner a close match between the RI of the immersed portion of the holder and the RI of the immersion material can be achieved for a defined monochromatic light source as will be further explained below with reference to
According another aspect of the invention there is also provided a system for analysing an at least partially transparent object, such as a gemstone, comprising: a holder for fixing the object; a cuvette with an immersion material; and an analysing system configured for analysing internal and/or external features of the object, wherein the analysing comprises visualizing an internal and/or external portion of the object using light rays while the object is immersed in the immersion material, and determining characteristics of the object based on the visualized internal and/or external portion of the object. The immersion material, the holder and the analysing system are configured such that, during the analysing, the difference between the refractive index (RI) of the immersion material and the RI of at least an immersed portion of the holder which is in contact with the object is less than 0.3.
In an exemplary embodiment the analysing system comprises: an illumination system configured to illuminate the object in the holder when immersed in the immersion material; and a detector configured to detect illumination having passed through the illuminated object, such as a camera. The illumination system may comprise a plurality of monochromatic light sources with different wavelengths. Further, the illumination system may comprise a plurality of monochromatic light sources set at different locations. Preferably, the analysing system comprises a drive means configured for translating and/or rotating the holder, such that the visualizing of the object can be done from a plurality of directions. Preferably, the analysing system comprises a computer means configured for controlling at least one of the drive means, the illumination system, and the detector. The computer means may be a single computer and/or a plurality of computers.
The skilled person understands that the features and considerations disclosed in the above method embodiments apply mutatis mutandis to the system.
Preferably, the immersion material, the holder and the analysing system are configured such that, during the analysing, the difference between the RI of the immersion material and the RI of the immersed portion of the holder is less than 0.2, more preferably less than 0.1, and most preferably less than 0.05.
Preferably the holder is configured for mechanically clamping the object to be analysed. Alternatively or in addition the object may be glued to the holder. Preferably, the glue is semi-transparent and has approximately the same RI as the immersion liquid. Preferably, the difference between the RI of the glue and the RI of the immersion liquid, under the analysing conditions, is smaller than 0.3, more preferably smaller than 0.2. In that manner the object will have substantially no hidden zones.
According to an exemplary embodiment, at least the immersed portion of the holder is made of a material or a combination of materials belonging to the classes of glass, or quartz, or plastic.
Preferably the immersion liquid is an oil, e.g. an oil as specified above in connection with the embodiments of the method.
According to an exemplary embodiment the analysing system comprises a temperature control means configured to control the temperature of the immersion material during the analysing in order to control the difference between the RI of the immersion material and the RI of the immersed portion of the holder, and in particular in order to minimize said difference by controlling the temperature of the immersion liquid for the wavelength used.
The invention will be further elucidated on the basis of a number of non-limitative exemplary embodiments of the method of the invention, with reference to the accompanying drawings.
The system of the exemplary embodiment comprises a holder 10 for fixing the object O, a cuvette 20 with an immersion material I, an analysing system comprising an illumination system 30 configured to illuminate the object O in the holder 10 when immersed in the immersion material I, and a detector 40 configured to detect corresponding illumination having passed through the illuminated object O. The detector 40 is for example a camera. The difference between the refractive index (RI) of the immersion material and the RI of the immersed portion of the holder, under conditions used during the analysing of the object, is less than 0.3, preferably less than 0.2, more preferably less than 0.1, and most preferably less than 0.05. Preferably, at least the immersed portion P of the holder 10 is made of a material or a combination of materials belonging to the classes of glass, or quartz, or plastic. Preferably, the immersion liquid I is oil, preferably a lapping oil with an RI between 1.40 and 1.50, under conditions used during the analysing of the object. The cuvette 20 may be made of any material, preferably a transparent or translucent material such as glass or quartz.
The illumination system 30 may comprise a plurality of monochromatic light sources 31, 32, 33. The different light sources 31, 32, 33 may have the same or a different wavelength, and may be positioned at different locations. Preferably, there is provided a first plurality of monochromatic light sources 31 at a first location, said first plurality of light sources having different wavelengths, and a second plurality of monochromatic light sources 32 at a second location, said second plurality of light sources having different wavelengths. Alternatively, there may be provided a first light source 31 capable of emitting light with different wavelengths at a first location, and a second light source 32 capable of emitting light with different wavelengths at a second location. In that manner, a light source of the first plurality may be selected depending on e.g. a feature of the object that is to be analysed. Further, by providing light sources at different positions, the object can be illuminated according to different orientations.
Further, the analysing system comprises a drive means 60 configured for translating and/or rotating the holder. Also the analysing system comprises a computer means 50 configured for controlling the drive means 60, the illumination system 30, and the detector 40.
The holder 10 is shown schematically in
Preferably, the holder 10 is mounted such that it can be translated and/or rotated via drive means 60, in order to reposition the studied object relative to the illumination system 30 and the detector 40, such that the visualizing of the object can be done from a plurality of directions. At least an immersed portion P; P1, P2 of the holder 10 is made of a material or a combination of materials belonging to the classes of glass, or quartz, or plastic. The immersion material I is preferably a substantially transparent liquid. However, according to another embodiment of the invention, the immersion material I can also be a substantially transparent semi-liquid, such as a gel. The immersion material I is selected such that the difference between the refractive index (RI) of the immersion material I and the RI of at least an immersed portion of the holder 10 which is in contact with the object O, under conditions used during the analysing of the object, is less than 0.3, preferably less than 0.2, more preferably less than 0.1, and most preferably less than 0.05. The immersion liquid I may be an oil, preferably a lapping oil. At least the immersed portion of the holder 10 is preferably made of a material belonging to the class of quartz.
An exemplary embodiment of the method will be described with reference to
As explained above, the measurements may be performed with light having different wavelengths and the measurements may be performed at different temperatures. Hence, for specific measurements the difference in RI may be smaller or bigger depending on the wavelength of the light used and depending on the temperature.
In an exemplary embodiment, if it is necessary to perfectly match the RI between the immersion liquid and the holder, and if a light source with the required wavelength is not available, then it is possible to use the light source with nearest wavelength and to adjust the temperature of the immersion liquid and/or the holder to fine tune the RI match between the immersion liquid and the holder.
It will be understood that the foregoing described embodiments of the invention are intended to be exemplary only, and should not be considered limiting of the scope of the invention, as defined in the following claims.
Number | Date | Country | Kind |
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2017/5270 | Apr 2017 | BE | national |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2018/059493 | 4/13/2018 | WO | 00 |
Publishing Document | Publishing Date | Country | Kind |
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WO2018/192842 | 10/25/2018 | WO | A |
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Number | Date | Country | |
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20200371042 A1 | Nov 2020 | US |