Method for covering damaged protective layer areas, device for implementing said method and transport system

Information

  • Patent Grant
  • 6649209
  • Patent Number
    6,649,209
  • Date Filed
    Tuesday, July 3, 2001
    23 years ago
  • Date Issued
    Tuesday, November 18, 2003
    20 years ago
Abstract
The invention relates first of all to a method for covering areas of damaged protective coating on containers or the like, in which, according to the invention, protective coating material is stamped on to the zone in which the damaged areas occur. The invention also describes an apparatus for carrying out the method in which a carrier unit is provided for stamping protective coating material on to the damaged area. Apparatus is provided for positioning the carrier unit with respect to the container.
Description




BACKGROUND OF THE INVENTION




1. Technical Field




The present invention relates to methods and apparatus for manufacturing metal containers in general, and to methods and apparatus for providing a protective coating to an area of the metal containers in particular.




2. Background Information




In the manufacture of metal containers such as small tubs of 0.5 litre to several litres capacity, lugs are provided on either side of the container body as anchor points for the carrying handle. These lugs are attached to the bodies preferably by welding or by some other method of fixing after the bodies have been resistance spot welded; this, however, means that the protective coating or covering applied to the sheet metal prior to fabrication of the containers is damaged and/or that bare metal is left exposed after the attachment process. These areas of damaged coating or bare metal then have to be given a protective coating to prevent corrosion by, or contamination of, the product contained. The invention can of course be applied to any situation where unprotected areas of the kind described above are to be covered with a coating for similar reasons.




In principle, methods which suggest themselves for covering the areas of damaged protective coating or of bare metal are those used to produce large areas of protective coatings on bare metal. In one such method, can seams are coated by a wet lacquering process in which a lacquer is applied to the surface to be coated. Disadvantages of this known method are the long drying times and the solvent vapors given off in the drying phase, necessitating the increasing use, for environmental reasons, of special extraction systems.




In another known method for covering welded can seams which have been exposed by the welding process, electrically charged coating powder is sprayed between lateral shields on to the weld seam, which is carried continuously past the spraying unit and is therefore “endless”, while excess coating powder which accumulates in the shields is continuously extracted. The powder which has been sprayed on is then heated in heating lines, which can be up to 20 meters long, and is thereby cured. This known method, which is sometimes also used in the manufacture of welded tub bodies (to cover the exposed body seam) is, as has been said, continuous, that is to say endless, and is not suitable for treating small areas. Moreover, it is likely that the intact, already coated surface of the containers would be contaminated, which would necessitate subsequent cleaning, or heating of the entire internal surface of the container in order to bind the pulverulent coating material.




Lastly, there is the option of sticking a foil with protective coating material over the damaged areas. This known procedure utilizes an additional substance, namely an adhesive suited to the purpose, and this should be avoided if possible, to avoid further contamination and spoiling of the product contained. For containers intended to be filled with a food product, for example, this would mean that the foodstuff compatibility of the adhesive would have to be proved and/or approval obtained from such authorities as the FDA in the USA, which is a time-consuming and expensive process. In any event, the adhesive would still need to be pronounced completely safe for the individual product to be contained, not least in view of the shelf life of up to several years expected of metal packaging.




The amount of material absorbed in the process of restoring the covering layer is also relevant, as such containers may be manufactured in large numbers, with the result that the consumption of material (in addition to the capital costs) is a critical factor for the production line.




Accordingly the problem which lies at the basis of the present invention is to specify a method and an apparatus which are capable of performing the task with a minimum amount of additional coating material.




DISCLOSURE OF THE INVENTION




This problem is solved by the measures stated in the characterizing part of claim


1


. Advantageous configurations of the invention, an apparatus for carrying out the method and a transport system are indicated in further claims.




The invention has the following advantages. Because material is applied only in the region where bare or damaged areas occur, and there is no longer any need for surplus powder to be removed, it becomes possible to cover such areas at small cost in terms of coating material. Furthermore, there is no contamination of the container and no giving off of noxious solvent vapors, as it is possible to work with materials that are already recognized and accepted as appropriate, notwithstanding the fact that the methods used hitherto in the can industry (where lugs may be unknown) basically cannot be applied to the solution of the present problem.











These and other objects, features and advantages of the present invention will become apparent in light of the detailed description of the invention, and the accompanying drawings.




BRIEF DESCRIPTION OF THE DRAWINGS




The invention will now be described in detail with reference to drawings by way of example, in which





FIG. 1

is a perspective view of a lug for welding on to the body of a container.





FIG. 2

shows the lug after welding, in a section perpendicular to the body and also in an end view.





FIG. 3

shows an apparatus according to the invention for covering areas of damaged protective coating on a container.





FIG. 4

is a perspective view of a batching unit used in the apparatus according to FIG.


3


.





FIG. 5

represents schematically individual phases of a transport system according to the invention.





FIG. 6

is a view from above of one embodiment of the transport system according to

FIG. 5

, with two rotary manipulators.





FIG. 7

shows a further embodiment of the apparatus according to the invention for covering areas of damaged protective coating with foil.





FIG. 8

shows different variants of a foil heating unit required in the apparatus according to FIG.


7


.





FIG. 9

shows a heating device for heating containers during several working steps.





FIG. 10

shows various blanks cut from foil tapes.











DETAILED DESCRIPTION OF THE INVENTION





FIG. 1

shows a lug


20


which essentially consists of a cylindrical body which has a cover with a hole


21


at one end and a foot


22


extending away from the longitudinal axis of the body at the other end. Weld points, formed e.g. by the spot welding process, are indicated at


23


.





FIG. 2A

shows the body


24


of a container to which a lug


20


according to

FIG. 1

has been attached. The welding process has left areas of damaged protective coating, indicated at


25


, on the inside of the container. These damaged areas


25


correspond to the weld points on the foot


22


of the lug


20


, and preferably lie in a circle, spaced apart at regular intervals, as shown in FIG.


2


B. The problem of the invention is to repair the areas of damaged protective coating so that corrosion of the tub wall, and contamination of the product contained, cannot occur.




Two lugs


20


are provided on each container, and are located opposite each other on the outside of the container in the region of the container's upper rim. A carrying handle can be joined in a known manner to the lugs


20


, and thus to the container, by the hole


21


. The invention is of course not limited to the attachment of lugs of this type, and can be adopted in any situation where a connection has to be made with other parts, such as tear-off tabs or similar, leaving areas needing to be covered with a protective layer.





FIG. 3

shows one embodiment of apparatus according to the invention for coating areas of damaged protective coating located on the inside of a container


1


which has been provided with lugs


2


. In one way of carrying out the invention, the damaged areas are coated by stamping pulverulent coating material on to the zone susceptible to damage. Pulverulent coating material is applied by means of a carrier unit


12


, preferably a so-called “stamp pad”, which is pressed on to the affected area by means of a pusher unit


11


, causing coating material to be transferred on to the body of the container


1


. Transfer of coating material is assisted if the temperature of the container


1


, and/or of the region to which the coating powder is to be applied, is higher than that of the carrier unit


12


. A heating element


4


, which will be described presently, is provided for this purpose.




After every stamping of coating powder on to the zones subject to damage, the carrier unit


12


has to be recharged with powder. This is done by means of a rotatably mounted transfer unit


9


which is driven by an angular gear


10


and which preferably has a number of carrier units


12


with corresponding pusher units


11


arranged on it. Then, one carrier unit


12


can be picking up coating material while another carrier unit


12


is stamping coating material on to the container


1


. Yet another carrier unit


12


can be preheated during the same time interval by means of the above-mentioned heating element


4


in order that, in the ensuing step, it will be able to pick up coating material which has been prepared on a turntable


3


in a manner which will be described presently, the carrier unit


12


again being actuated by means of the corresponding pusher unit


11


to effect such pick-up of material.




As can be seen from

FIG. 3

, with optimum handling it is possible for the damaged areas


25


of both lugs


2


welded to the same container


1


to be provided with coating material. To accomplish this, an additional transfer unit


9


of similar construction to the one which has been described, and preferably driven by the same angular gear


10


, is provided. This means that perfectly synchronized coating of the damaged areas at the two lugs


2


is assured, or in other words that the two symmetrically arranged transfer units


9


work in unison on either side of the container


1


. Each transfer unit is rotatably mounted and holds four carrier units


12


i.e. stamps made of silicone. The carrier units


12


are displaced axially by the corresponding pusher unit


11


at every working step. In a first step, the carrier unit


12


is pressed on to the heating element


4


and preheated so that in the next step it will be able to pick up the prepared coating powder from the turntable


3


as a result of light adhesion due to heating. In the next step, the carrier unit


12


with the powder adhering to it is lightly vacuumed to remove any loose powder particles. This results in greater cleanliness in the container


1


. In the final step, the carrier unit


12


with the coating powder adhering to it is stamped on to the damaged areas.




To avoid having to move the angular gear


10


and the two transfer units


9


up and down, the containers


1


to be coated can be raised by means of an elevating platform


6


to enable the carrier units


12


to stamp coating powder on to the damaged areas.




As has already been mentioned, the pulverulent coating material to be stamped on to the damaged areas is removed from the rotatably mounted turntable


3


by the carrier unit


12


concerned. This turntable


3


forms part of a batching unit


31


which also has other components and which will now be further described with reference to FIG.


4


.





FIG. 4

shows the batching unit


31


in a perspective view. In addition to the preferably horizontal turntable


3


, which has recesses


14


that are about to be explained and which is preferably rotatable about a vertical axis


17


and capable of being driven in such rotation by a drive unit


13


(FIG.


3


), a bin


8


for pulverulent coating material and a cleaning unit


16


are provided.




The recesses


14


are filled with coating powder, which runs out from the bottom of the bin


8


, up to the level of the top of the turntable


3


. For this purpose a wiper


18


, for example in the form of a strip, is provided behind the bin


8


, viewed in the direction of rotation of the turntable


3


. In

FIG. 4

, the reference numeral


15


denotes the transfer position in which a carrier unit


12


(

FIG. 3

) picks up as nearly as possible all the coating material contained in the recess


14


.




Transfer is assisted by heating the carrier unit


12


concerned, or the surface thereof, by means of the heating element


4


before pick-up takes place.




After the coating powder is picked up, the turntable


3


goes on turning. When it reaches the cleaning unit


16


, at the entry to which a brush


16


a is provided, any coating material remaining in the recess


14


is removed.




The configuration of the recesses


14


, and hence of the coating patches actually applied, is such that consumption of coating material can be kept to a minimum and yet is sufficient to ensure that the damaged areas—together with a certain margin—are reliably covered. Moreover, the thickness of the coating applied is set by the depth of the recesses


14


.




In keeping with the arrangement of weld points assumed here and in view of the criteria mentioned above, the chosen form for the recesses


14


is that of a ring.




The method of handling the containers


1


is shown schematically in

FIG. 5

, in which individual process steps, each corresponding to one segment of cycle time, are numbered


52


to


58


. The same steps and numbers also appear in FIG.


6


.




Referring to

FIG. 5

, a container


1


, which has already been provided with a bottom, lugs


2


, and a handle, is transferred to the coating unit


7


, that is to say it is initially placed in position


52


. Here the lugs


2


are aligned to ensure that the coating m material will be stamped in the right place. By a pendulum step process which will be described presently, the containers


1


are individually transported to the next position


53


,


56


in order that the target zones can be heated with a heating unit


30


, designed as an induction heater, hot air blower, or infra-red radiator. For a more homogeneous contact with the powder adhering to the transfer unit


12


, the container


1


is preferably heated from the inside. In one embodiment of the invention, the containers


1


are lifted vertically by means of an elevating platform


6


, to avoid having to move the heating units


30


. Hot air or infrared radiation can be brought to bear from both sides, and can be used simultaneously if desired. The container


1


—if need be after pausing in a waiting position W—is then transferred to position


54


, where coating material in powder form is applied, preferably in the manner described with reference to

FIGS. 3 and 4

. Here again the container


1


is raised, to avoid having to move the batching unit


31


and transfer units


9


together with their angular gear


10


(FIG.


3


). Finally, in position


55


,


57


, heating again takes place: by means of heating units


30


, the temperature of at least the zones subject to damage is raised, preferably to the melting point of tin. Depending on the melting point of the protective coating material employed, the requisite temperatures will lie e.g. between 150 and 240° Celsius.





FIG. 6

shows a transport system according to the invention in which the positions


52


to


58


which have been described with reference to

FIG. 5

are realized in an arrangement that is compact and allows for rigidly imposed transport cycle times. The application of coating takes place in a production line for the containers concerned which may extend from the cutting-up of sheet-metal blanks to form the containers to the filling and closure of the containers, so that the transport cycle is preordained. With the aid of a rotary manipulator


60


the containers


1


can be preheated in tandem, one being heated while the other is being transported and vice versa.




To heat a container, the container is transferred, by means of suction cups


62


or the like forming part of the rotary manipulator


60


, from position


52


to position


53


, where it is parked. In the next step of the cycle, the next container arriving in position


52


is picked up and transferred to position


56


. During this transfer phase, the container parked in position


53


stays where it is. Not until a container has been parked in position


56


is the container in position


53


picked up again, and transferred by rotation of the manipulator


60


to position


54


, where for example the stamping-on of coating powder as described with reference to

FIGS. 3 and 4

takes place. The second rotary manipulator


61


is used in a similar way.




In this way, the heating phase is extended without affecting the fundamental cycle time. If baking is necessary following application of the coating powder, a second rotary manipulator


61


, connected in series, will be required, again giving the heating unit


30


(

FIG. 5

) an extended dwell time.




The method according to the invention and the transport system according to the invention are particularly suited for mechanized and continuous operation in a production line, as has already been stated. Over 80 cycles per minute can be achieved. Consumption costs can be kept to a minimum by the precise nature of the batching. With the method according to the invention, contamination of the container with loose powder does not occur, as any loose powder will stay stuck to the carrier units.




In another embodiment of the invention, instead of using stamping pads as carrier units these are formed as a solid bar of protective coating material. Shortly before being stamped on to the damaged areas, the bar end is melted and/or the target zones are preheated to a temperature above the melting point of the coating material. This involves only minor modifications of the apparatus according to the invention. For instance the batching unit in the form described is no longer required. But the essence of the inventive idea still remains.




In one embodiment of the apparatus according to the invention, a foil tape which is cut up into blanks is used instead of powder. These blanks are then picked up by the transfer unit and applied to the inner wall of the container in the same way as a prepared ring of powder. The apparatus can remain essentially unchanged, the only difference being that the bin


8


will then be dispensing foil blanks instead of powder on to the turntable


3


. An expert will be capable of making the necessary modifications without needing further instruction.




A preferred embodiment of an apparatus for applying blanks will be described with reference to

FIGS. 7

to


10


.





FIG. 7

shows the preferred embodiment of the invention in a partly cutaway view perpendicularly to the transport direction of the containers


1


. The containers


1


are transported in a series of steps; before the application of foil (and if a heating device—which will be explained later (FIG.


9


)—is used, before reaching the heating device), the containers


1


are aligned so that the point of application is in register with the position of the lugs


2


. Preferably, the containers


1


are aligned so that the lugs


2


are located laterally when viewed in the transport direction.




Foil


100


is supplied from a reel


107


located in a hot box


112


under the transport system for the containers


1


. In the case of the apparatus illustrated in

FIG. 7

, the foil tape


100


is double-wound on the reel


107


. This makes it possible by means of suitable deflection pulleys


102


to


104


to convey the foil


100


to the transfer unit in a simple manner, as follows: the foil tape is fed by means of a tape feed unit and tape holder


109


which are operated alternately, and the foil


100


is cut into the desired shapes by means of a punch


108


and transferred to the transfer unit


9


fitted with carrier units


12


. Here the carrier units


12


preferably consist of so-called “stamp pads” which pick up the foil blanks by suction. These stamp pads have holes at suitable points which communicate with a chamber connected in turn to a low-power vacuum pump.




In

FIG. 7

the transfer unit


9


has been drawn in two positions. In the upper position, the carrier unit


12


is charged with a blank of foil material. A container


1


with areas of damaged protective coating in the region of the lugs


2


has been prepared and placed in position underneath the transfer unit


9


. The transfer unit


9


is then moved to the second, i.e. lower, position by means of a pneumatic or hydraulic cylinder


111


. A further, horizontally mounted cylinder presses the carrier units


12


charged with blanks radially outwards at the same level as the lugs


2


, so that the blanks are applied to the areas of damaged protective coating. Prior to the application of the blanks, the container


1


is heated, in a manner which will be described presently, to a temperature affording ideal conditions for joining the foil material to the interior of the container.




Polyamide-12 (also known under the trade name. NYLON), polyamide-6 and polyester have all proved suitable as foil material, especially polyamide-12. In the case of the last mentioned product, the containers


1


and/or their interiors in the region of the lugs


2


are preferably heated to a temperature of approx. 160° Celsius. This ensures perfect bonding of the foil material to the inner wall of the container.




At the same time, the hot box


112


containing the reel


107


of foil tape is heated to a temperature of approx. 80° Celsius. This prepares the foil material for the application process. Any water droplets which may have been deposited on the tape are evaporated by this warming process before the foil is applied. This will effectively prevent flaking.




In a further embodiment of the apparatus according to the invention, shown in

FIG. 8A

, a skid


113


is substituted for the hot box


112


. The foil tape is guided along this skid


113


, which is heated to approximately 100° Celsius. This again prevents water droplets from being deposited on the foil tape, and evaporates any water droplets which may be present.





FIG. 8B

shows an alternative embodiment to the skid


113


shown in FIG.


8


A. The foil tape is guided through a hot-air tunnel


114


which performs the functions stated above.





FIG. 9

shows an arrangement for three-stage heating of the areas of damaged coating on the interior of the containers


1


, which are advanced in steps in the direction of the arrow


120


by means of a transport system (not shown in FIG.


9


). During the stages when the containers are at rest, hot air supply lines


124


,


125


,


126


are positioned in the open topped containers over the damaged areas. In synchronization with the advance of the containers


1


in the direction


120


, a drive unit


121


is triggered so that the supply lines


124


,


125


,


126


do not come into contact with the containers


1


. The drive unit


121


is coupled with the heat supply lines


124


,


125


,


126


by drive belts


122


and swiveling axes


127


,


128


,


129


. The heat supply lines


124


,


125


,


126


are supplied with hot air via a heating air duct


123


, in which they are pivotally mounted.




With the proposed heating device, there is no need to vary the transport cycle for the containers


1


even if the heating operation has to be performed in a number of cycles. Also, the amount of movement of the heating assemblies is minimal.





FIG. 10

shows some foil tapes


100


and blanks


150


,


151


,


152


taken therefrom. For example,

FIG. 10A

shows rectangular blanks


150


which can be made without leaving any waste.




In

FIG. 10B

, round blanks


151


are produced by means of a punch


108


(FIG.


7


A). A strip of waste


155


is left over.




Lastly,

FIG. 1

OC shows the preferred type of blank. By means of the punch


108


(FIG.


7


A), blanks


152


are produced that are circular except for two straight segments. The intermediate pieces


156


that are left over as waste are extracted by means of an extraction device


110


.




The invention can be used to advantage in other applications besides the covering of areas of damaged protective coating on containers. The invention is highly suitable for covering areas on components of any description.




Although this invention has been shown and described with respect to the detailed embodiments thereof, it will be understood by those skilled in the art that various changes in form and detail thereof may be made without departing from the spirit and the scope of the invention.



Claims
  • 1. A method for manufacturing a metal container, comprising the steps of:welding one or more lugs to the metal container at predetermined positions, wherein after the welding process an area of damaged protective coating is disposed proximate each of the predetermined positions; stamping a protective coating material onto the area of damaged protective coating; and heating the area to which the protective coating material has been applied to stabilize the protective coating material.
  • 2. The method of claim 1 wherein said protective coating material is in pulverant form.
  • 3. The method of claim 2, wherein the stamping of the protective coating material is performed using a carrier unit, wherein the carrier unit transports the protective coating material from a source to the container.
  • 4. The method of claim 3, further comprising the step of heating the container to a first temperature prior to stamping the protective coating material, wherein the carrier unit is at a second temperature, and the first temperature is higher than the second temperature.
  • 5. The method of claim 4, wherein the carrier unit is heated to the second temperature, which is higher than ambient temperature, prior to transporting the protective coating material.
  • 6. The method of claim 5, further comprising the step of vacuuming the carrier unit after the carrier unit transports the protective coating material away from the source, but before the carrier unit transports the protective coating material to the container.
  • 7. The method of claim 1, wherein the protective coating material is a solid bar that has a stamping end that is heated to approximately the melting point of the protective coating material prior to stamping, wherein material from the heated solid bar is transferred to the container during the stamping.
  • 8. The method of claim 1, wherein the protective coating material is a foil tape.
  • 9. The method of claim 8, wherein the stamping of the protective coating material is performed using a carrier unit, and wherein the carrier unit transports blanks of the foil tape from a source to the container.
  • 10. The method of claim 9, wherein the foil tape is preheated to a temperature higher than ambient prior to stamping.
  • 11. An apparatus for coating an area of damaged protective coating on a container, comprisinga source of protective coating material; at least one carrier unit; at least one pusher, wherein the at least one pusher selectively actuates the carrier unit into contact with the source of protective coating material, and selectively actuates the carrier unit into contact with the area of damaged protective coating on the container, thereby stamping protective coating material attached to the at least one carrier unit onto the area of damaged protective coating on the container; and a first heater for heating the area of the can to which the protective coating material has been deposited to stabilize the protective coating material.
  • 12. The apparatus of claim 11, further comprising a second heater for heating the at least one carrier unit.
  • 13. The apparatus of claim 12, wherein the first heater is capable of heating the container to a first temperature prior to stamping the protective coating material, and wherein the second heater is capable of heating the carrier unit to a second temperature, and the first temperature is higher than the second temperature.
  • 14. The apparatus of claim 12, further comprising a vacuum for vacuuming the carrier unit after the carrier unit is selectively actuated into contact with the source of protective coating material, and before the carrier unit is selectively actuated into contact with the area of damaged protective coating on the can.
  • 15. The apparatus of claim 11, wherein the source of protective coating material is a foil tape, and the pusher selectively actuates the carrier unit into contact with the foil tape.
  • 16. The apparatus of claim 15, further comprising a third heater for heating the foil tape to a temperature higher than ambient prior to stamping.
  • 17. The apparatus of claim 11, further comprising:a rotatable transfer unit for mounting a plurality of carrier units and a like number of pushers; and a drive for selectively rotating the transfer unit; wherein the drive selectively rotates each carrier unit between a first position proximate the source of protective coating material and a second position proximate the container; and wherein each pusher selectively actuates the carrier unit into contact with the source of protective coating material, and selectively actuates the carrier unit into contact with the area of damaged protective coating on the container.
  • 18. The apparatus of claim 17, further comprising a second heater for heating one the plurality of carrier units, wherein the drive selectively rotates each carrier unit to a third position proximate the second heater.
  • 19. The apparatus of claim 17, further comprising at least one selectively moveable platform for supporting the container, wherein the container is disposed on then platform in a first position and the platform can be selectively moved to a second position so that the area of damaged protective coating on the container is proximate the rotatable transfer unit.
  • 20. The apparatus of claim 17, wherein the source of protective coating material comprises:a rotatable turntable; a bin; and a cleaning unit; wherein the bin and the cleaning unit are disposed on a side of the turntable; and wherein the bin and cleaning unit are positioned such that protective coating material selectively released from bin is deposited on the rotatable turnable, and the rotatable turntable rotates to expose the deposited protective coating material to one of the carrier units, and subsequently rotates to allow the cleaning unit to remove whatever protective coating material is left after the respective carrier unit is selectively actuated into the protective coating material deposited on the turntable.
  • 21. The apparatus of claim 20, wherein the turntable comprises a plurality of recesses positioned to receive protective coating material from the bin.
  • 22. The apparatus of claim 21, wherein the bin includes a wiper disposed in contact with the turntable.
  • 23. The apparatus of claim 21, wherein the cleaning unit includes a brush in contact with the turntable.
  • 24. An apparatus for coating an area of damaged protective coating on a container, comprisinga solid rod of protective coating material; a first heater for heating a stamping end of the solid rod to approximately the melting point of the protective coating material; a pusher for actuating the solid rod into contact with the area of damaged protective coating on the container, thereby enabling the deposition of protective coating material onto the container; and a first heater for heating the area of the can to which the protective coating material has been depositied to stabilize the protective coating material.
Priority Claims (1)
Number Date Country Kind
118/99 Jan 1999 CH
PCT Information
Filing Document Filing Date Country Kind
PCT/CH00/00025 WO 00
Publishing Document Publishing Date Country Kind
WO00/43569 7/27/2000 WO A
US Referenced Citations (3)
Number Name Date Kind
1772318 Lontke Aug 1930 A
3551184 Dremann et al. Dec 1970 A
4519493 Dyer May 1985 A
Foreign Referenced Citations (12)
Number Date Country
889.313 Oct 1981 BE
28 31 207 Jan 1980 DE
41 39 365 Nov 1991 DE
44 11 680 Aug 1995 DE
0 590 664 Apr 1994 EP
0 676 259 May 2000 EP
1.468.471 Dec 1966 FR
751863 Jul 1956 GB
62-267481 Nov 1987 JP
1015925 May 1983 SU
WO8704957 Aug 1987 WO
WO9314236 Jul 1993 WO