Patent Application
20130068735
The present invention relates to a method of forming a metal coating having a microstructure and a structural member having the metal coating formed by the method. In particular, the invention relates to an advantageous method of forming a metal coating in which fine carbides are uniformly dispersed. The term “microstructure” in the present invention means a structure in which base material has a crystal grain size of 5 μm or less and carbides have a grain size of 1 μm or less and the carbides are uniformly dispersed in the base material.
It has been known that metal material has mechanical characteristics (e.g., hardness, strength) that are significantly influenced by the structure of the metal material. Thus, the finer the structure of the metal material is, the more improved the mechanical characteristics generally become. Thus, metal material (e.g., tool steel, stellite), which is used for various tools, blades, or metal molds and which is required to have high mechanical characteristics, is composed to contain carbides having high hardness such as chromium carbide and vanadium carbide dispersed in the base material. In order to refine the structure of the metal material, the base material is desired to have not only fine crystal grains but also have fine carbides.
The inventors have suggested a method in which a steel material such as tool steel is subjected to a laser processing and a friction stirring process to refine the structure of the steel material (Non-patent document 1). According to this method, the crystal grains of the base material and the carbide can be refined in an arbitrary surface region of a steel material (plate member). The refined carbides are not unevenly dispersed, and a favorable structure in which the carbides are uniformly dispersed in the base material can be obtained.
On the other hand, tool steel and stellite are high-cost material containing a large amount of scarce elements. Furthermore, from the viewpoint of providing a member having a lower price and a sustainable industry development, such metal materials have been desired to be used in a smaller amount. Thus, various techniques of covering the surface of a base material with such metal materials have been considered (for example, refer to Patent document 1 and Non-patent document 2).
The method already suggested by the inventors (Non-patent document 1) is a method of refining the structure of the surface of a metal plate member, and this method is not so effective to reduce the amount of tool steel or the like to be used. Furthermore, carbides are allowed to have microstructures of different levels. Thus, if a material to be processed contains vanadium carbide, a problem has been caused in which vanadium carbides of a few μm are left even after a processing for refining the structure.
Furthermore, when a substrate is covered with a material such as tool steel and stellite containing a high amount of carbides by a conventional method such as TIG welding, the resulting coating layer becomes a rapidly-solidified structure that is an uneven structure in which the carbides are unevenly dispersed in the crystal grain boundary of the base material. Such a structure has been known to cause a brittle coating layer, which is a significant problem.
The present invention has been devised in view of the problem as described above, and it is an objective of the invention to provide a metal coating having a microstructure as well as a structural member having the metal coating formed by the method. In particular, the invention provides an effective method of forming a metal coating in which fine carbides are uniformly dispersed.
A method of forming a metal coating of the present invention includes: the first step of cladding a surface of a substrate with metal powders by a laser cladding; and the second step of forming the metal coating having a microstructure by applying a friction stir processing to the cladded region. When the metal powders contain chromium carbide in particular, a metal coating having a microstructure can be formed easily. Even when the metal powders contain vanadium carbide, a metal coating having a microstructure can be formed.
In the method of forming a metal coating of the present invention, laser cladding is preferably conducted along an equivalent axis on which the supply of the metal powders and the laser emission are performed. For example, by moving a cladding torch capable of supplying the metal powders to the surface of the substrate and the laser emission along an equivalent axis by a position control robot, the metal powders can be cladded on an arbitrary region of the surface of the substrate.
A structural member of the present invention can be manufactured by a method of forming a metal coating of the present invention. The structural member of the present invention is obtained by forming a metal coating having a microstructure on the surfaces of various substrates. The use of the metal coating can provide superior mechanical characteristics such as high hardness. The metal coating preferably contains chromium carbide and more preferably contains vanadium carbide.
A method of forming a metal coating of the present invention can form a metal coating having a microstructure on a surface of a substrate. Regardless of the type of carbides, carbides contained in a metal material can be refined to a size of 1 μm or less and the carbides can be uniformly dispersed in the base material.
The structural member of the present invention is configured such that a surface of a substrate has a metal coating having a microstructure formed thereon. Thus, when compared with a structural member composed of general metal material, the structural member of the present invention has superior mechanical characteristics (e.g., high hardness). Furthermore, because carbides are finely refined, the influence on the surface shape of the structural member by the dropout of the carbide is fairly minimal. The structural member of the present invention can be widely used for applications requiring high hardness, high toughness, high abrasion resistance characteristics and the like, and can be used for various blades and rolling dies, for example.
The method of forming a metal coating of the present invention includes: the first step of cladding a surface of a substrate with metal powders by a laser cladding; and the second step of forming the metal coating having a microstructure by applying a friction stir processing to the cladded region.
After the metal powders supplied to the surface of the substrate are melted by the laser emission, the metal powders melted along the move of the laser are rapidly-solidified on the surface of the substrate, thereby forming a cladded portion. The position control robot can be used to move the cladding torch to form the cladded portion on an arbitrary region on the surface of the substrate. Alternatively, the position of the cladding torch may be fixed and the substrate may be moved by an XY stage or the like to form the cladded portion in a similar manner as above. The formation of a cladded portion does not always require an exclusive torch designed for a cladding process, and any apparatus can be used as long as the apparatus can supply metal powders to a surface of a substrate and can emit laser. Cladding can also be achieved by using wires as a material and melting the wires.
The method of supplying metal powders to a surface of a substrate and the laser emission method are not particularly limited. However, from the viewpoint of efficiently forming a cladded portion of an arbitrary shape having fine carbides, the supply of the metal powders and the laser emission are preferably carried out along the equivalent axis.
The metal powders discharged from the metal powder supply path 12 are supplied to the surface of the substrate 20. Then, laser 14 is emitted to the surface of the substrate 20 that has received the metal powders, thereby forming a cladded portion 22. The shielding gas such as argon gas supplied from the shielding gas circulation path 16 suppresses oxidation of the cladded portion 22 and the periphery thereof. The cooling water circulating in the cooling water circulation path 18 suppresses the excessive heating of the laser cladding torch 10 due to the laser emission. The laser 14 may be any type of laser including, for example, semiconductor laser, YAG laser, fiber laser, or CO2 laser.
The metal powders preferably contain chromium carbide and more preferably contain vanadium carbide. If a laser cladding is performed using chromium carbide-containing metal powders as material, the resulting cladded portion 22 has a structure in which chromium carbides having a reduced size up to about 1 μm are unevenly dispersed in the crystal grain boundary of the base material. The second step subjects the cladded portion 22 to a friction stirring process to break and uniformly disperse the chromium carbides, thereby forming a metal coating having a microstructure. Here, the chromium carbides dispersed in the base material also provides an effect of promoting the size reduction of the crystal grain of the base material through the friction stirring process. Specifically, the existence of the chromium carbides increases the distortion introduced in the base material by the friction stirring process and also suppresses, by the flux pinning, coarsening of the crystal grains of the base material that have been finely refined through recrystallization.
Vanadium carbides also provide the similar function as that provided by the above-described chromium carbide. However, vanadium carbide has higher hardness than chromium carbide, and thus significantly improves the mechanical characteristics of the finally-resulting metal coating having microstructure. Although refining vanadium carbide is very difficult, the use of a laser cladding can provide vanadium carbide refined to a size of about 1 μm or less.
The friction stirring process is method obtained by applying the friction stirring bonding method, which is a bonding technology suggested by TWI (The Welding Institute) of U.K. in 1991, to a method for the surface modification of metal material. The friction stirring bonding is carried out by pressing a cylindrical tool rotating at a high speed into a region to be bonded (the bottom face of the tool has a projection called a probe and the probe is pressed into the region). Then, the material to be bonded that has become softer by friction heat is scanned in a direction along which the bonding is desired while the material is being stirred to thereby achieve the bonding. The region stirred by the rotating tool is generally called a stirring section. Some bonding conditions provide improved mechanical characteristics achieved by homogeneous material and a reduced grain size. Thus, the friction stirring process is a technique that uses the improved mechanical characteristics provided by homogeneous material and a reduced grain size by the friction stirring as surface modification. The friction stirring process has been actively studied in recent years. In the present invention, a probe is not always required at the bottom face of the tool for the friction stirring process, and a so-called flat tool not having a probe can also be used.
The following sections will describe embodiments and comparison examples of the present invention with reference to the drawings. However, the present invention is not limited to these embodiments.
Wires of stellite 6 (diameter: 2.0 mm) were used as a source material to subject the surface of the SKD 11 substrate to a TIG welding by a DC welding machine having a rated current of 300 A. During the TIG welding, argon gas was allowed to flow as a shielding gas and a cladded portion was formed under the conditions of the voltage of 10V, the current of 100 A, and the traveling speed of 50 mm/min.
The surface of the SKD 11 substrate was subjected to a laser cladding using stellite powders (stellite No. 6 made by Mitsubishi Materials Corporation) having a grain size of about 20 μm (the first step in the method of forming a metal coating of the present invention). The laser cladding was performed by the laser cladding apparatus shown in
The cladded portion (stellite layer) formed on the surface of the SKD 11 substrate was subjected to the friction stirring process (the second step in the method of forming a metal coating of the present invention). The friction stirring process was performed by a cylindrical tool of cemented carbide under the conditions of the tool rotation rate of 400 rpm, the tool traveling speed of 1000 mm/min, and the tool press-in load of 3.8 t. During cladding, argon gas was allowed to flow as a shielding gas.
By using SPC5 powders having a grain size of about 20 μm (made by Sanyo Special Steel Co., Ltd.: SPC5 is powders obtained by adding 5 mass % vanadium to SUS440C and includes chromium carbide and vanadium carbide) as a material, the surface of the SKD 11 substrate was subjected to a laser cladding (the first step in the method of forming a metal coating of the present invention). The laser cladding was performed by the laser cladding apparatus shown in
The cladded portion (SPC5 layer) formed on the surface of the SKD 11 substrate was subjected to the friction stirring process (the second step in the method of forming a metal coating of the present invention). The friction stirring process was performed by a cylindrical tool of cemented carbide under the conditions of the tool rotation rate of 400 rpm, the tool traveling speed of 1000 mm/min, and the tool press-in load of 3.8 t. During cladding, argon gas was allowed to flow as a shielding gas.
The inventors have already suggested a method of refining the structure of a metal material by combining a laser processing with a friction stirring process. In order to clarify the difference between this method and the present invention, structural refinement was tried by subjecting an SPC5 plate member to a laser processing and a friction stirring process.
The SPC5 plate member was subjected to semiconductor laser (output: 1 kW) to form a laser processing region. The laser was just focused on the surface of the SPC5 plate member (the laser diameter at the surface of the SPC5 plate member was about 1 mm) with the laser scanning speed of 1000 mm/min. In order to allow laser processing regions formed by a single laser scanning to be at least partially superposed, the laser emission position was moved by 0.7 mm in the direction vertical to the laser scanning direction after the completion of every one laser scanning, thereby performing the total of 15 laser scannings.
The friction stirring process was performed by a cemented carbide tool having a cylindrical shape of a diameter of 10 mm. The tool rotating at the speed of 400 rpm was pressed into the laser processing region at a load of 3800 kg. The tool was moved at a traveling speed of 400 mm/min, and argon gas was allowed to flow to prevent the oxidation of the tool and the sample. The tool was inserted at a center of the laser processing region, and much attention was paid so as not to allow the tool to agitate a SPC5 plate member, which is not yet processed.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2010-070680 | Mar 2010 | JP | national |
This application is a national phase application under 35 U.S.C. §371 of International Application Serial No. PCT/JP2011/057394, filed on Mar. 25, 2011, and claims the priority under 35 U.S.C. §119 to Japan Patent Application No. 2010-070680, filed on Mar. 25, 2010, which are hereby expressly incorporated by reference in their entirety for all purposes.
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/JP2011/057394 | 3/25/2011 | WO | 00 | 11/30/2012 |
