This application claims priority to French Patent Application No. 2109178, filed Sep. 2, 2021, the entire content of which is incorporated herein by reference in its entirety.
The present invention relates to the semiconductor substrates used to manufacture integrated circuits, and more particularly radiofrequency (RF) circuits.
Different types of substrate can be used to manufacture integrated circuits. The substrate is generally chosen according to the type of circuit to be manufactured: radiofrequency (RF) circuit, MOS transistor-based logic circuits with, image sensors . . .
Among the substrates of interest, mention can be made of the SOI (for “Silicon On Insulator”) multilayer structure. The SOI multilayer structure successively comprises a support layer made of silicon, an electrically insulating layer, generally a so-called buried oxide layer (or BOX layer), and a thin film made of monocrystalline silicon, also called the active layer. The active layer is named as such because it is intended to receive active components, typically MOS transistors (acronym for “Metal Oxide Semiconductor”). The conduction channel of the MOS transistors is formed in the active layer. The structure SOI offers in particular the possibility of manufacturing fully depleted (or FDSOI, for “Fully Depleted SOI”) or partially depleted (or PDSOI, for “Partially Depleted SOI”) transistors.
This multilayer structure 10, called “TR-SOI”, successively comprises a support layer 11 made of high resistivity silicon, a trap-rich layer 12, a buried oxide layer 13 and an active layer 14 made of monocrystalline silicon. The trap-rich layer 12 prevents the parasitic conduction phenomenon at the interface between the support layer 11 and the buried oxide layer 13, this phenomenon usually being caused by free electrons that accumulate at the interface under the effect of the fixed positive charges contained in the buried oxide layer 13. Thanks to the trap-rich layer 12, the electrons are trapped and can no longer circulate. The effective resistivity of the support layer 11 is thus increased with respect to a multilayer structure devoid of a trap-rich layer (structure called “HR-SOI”). The trap-rich layer 12 can be constituted of polycrystalline silicon. The traps are located at the grain boundary of the polycrystalline silicon.
The TR-SOI structure 10 greatly improves the RF performance of the integrated circuits manufactured from this structure, in particular in terms of linearity and cross talk. The passive elements (inductances, capacitances . . . ) formed above the active layer 14 benefit from a better quality factor.
This multilayer structure 20 successively comprises a support substrate 21 made of high resistivity silicon, a dielectric layer 22 made of silicon dioxide disposed on the support substrate 21, an active layer 23 made of monocrystalline silicon disposed on the dielectric layer 22 and trenches 24 extending in the support substrate 21 from the interface between the support substrate 21 and the dielectric layer 22. The walls of the trenches 24 are lined with a material 25 that has mobile electrical charge trapping properties. The remaining portion of the trenches 24 is filled with a gas or a gaseous mixture, for example air. The trenches are thus conserved at the state of cavities.
Thanks to these cavities, the effective resistivity of the support substrate 21 is further increased.
The manufacturing of the multilayer structure 20 comprises a step of transferring the dielectric layer 22 and the active layer 23 on the support substrate 21. This transfer can be accomplished thanks to a bonding technique (direct or via molecular adhesion) such as the Smart Cut™ method. It remains however complex to implement, because the bonding interface is not entirely constituted of silicon. More particularly, the bonding is made difficult by the presence of the trenches 24.
There is therefore a need to provide a method for manufacturing a multilayer structure provided with cavities that is simpler to implement.
According to a first aspect of the invention, this need tends to be satisfied by providing a method for manufacturing comprising the following steps:
providing a stack comprising a substrate and a dielectric layer disposed on the substrate, the substrate being formed from a semiconductor material having a resistivity greater than or equal to 500 Ω.cm,
etching trenches extending through the dielectric layer and opening onto the substrate;
etching the substrate isotropically and selectively with respect to the dielectric layer to form first cavities in the substrate; and
depositing a mobile electrical charge-trapping layer on the walls of the first cavities and on the side walls of the trenches, in such a way as to fill in the trenches in the dielectric layer, thus closing the first cavities in the substrate.
In an embodiment of the method of manufacturing, the stack provided further comprises an active layer disposed on the dielectric layer and a protective layer disposed on the active layer, the etching of the trenches further extending in the active layer and in the protective layer.
According to a development of this embodiment, second cavities are formed in the active layer at the same time as the first cavities in the substrate, by etching of the active layer isotropically and selectively with respect to the dielectric layer and to the protective layer, and wherein the second cavities are filled by the mobile electrical charge-trapping layer.
The method according to the first aspect of the invention can also have one or more of the characteristics hereinbelow, taken individually or according to all technically permissible combinations:
the step of providing the stack comprises a thermal oxidation operation of a surface of the substrate, a nitriding operation of the surface of the substrate or a deposition operation of the dielectric layer on the substrate;
the method further comprises a step of removing a portion of the mobile electrical charge-trapping layer deposited on the dielectric layer;
the trenches further extend in a portion of the substrate;
each trench has a width comprised between 20 nm and 100 nm;
each trench has a length comprised between 50 μm and 2000 μm;
each trench has a depth comprised between 50 nm and 300 nm;
the trenches are of identical dimensions;
the trenches are disjointed and extend in the dielectric layer along planes parallel together and perpendicular to a main face of the substrate;
the trenches are spaced two by two by a distance such that the first cavities merge into one larger cavity during the step of etching of the substrate;
the trenches are spaced two by two by a distance comprised between 300 nm and 5000 nm;
the trenches communicate between them and form a meshing in the dielectric layer;
the trenches have a first pitch comprised between 100 nm and 5000 nm in a first direction and a second pitch comprised between 100 nm and 5000 nm in a second direction secant to the first direction;
each first cavity has a width comprised between 200 nm and 5000 nm;
each first cavity has a length comprised between 50 μm and 2000 μm ; and
each first cavity has a depth comprised between 100 nm and 2500 nm;
the first cavities are of identical dimensions.
A second aspect of the invention relates to a method for manufacturing an integrated circuit, comprising the following steps:
manufacturing a multilayer structure by accomplishing a method according to the first aspect of the invention;
forming passive components on the multilayer structure, vertically with respect to the first cavities.
The method according to the second aspect of the invention can also comprise one or more of the steps hereinbelow, taken individually or according to all technically permissible combinations:
a step of forming electrical insulation trenches before the step of etching the trenches;
a step of forming active components in a first zone of the multilayer structure, the first zone being devoid of first cavities, the passive components being formed in a second zone of the multilayer structure, separate from the first zone and provided with first cavities;
a step of total removal of the dielectric layer before the step of forming active components;
a step of forming at least one level of electrical interconnection that connects the active components, the passive components being formed on the at least one level of electrical interconnection.
A third aspect of the invention relates to a multilayer structure comprising:
a substrate;
a dielectric layer disposed on the substrate;
trenches extending through the dielectric layer to the substrate;
first cavities extending in the substrate, from the interface between the substrate and the dielectric layer;
a mobile electrical charge-trapping layer entirely filling the trenches in the dielectric layer and lining the walls of the first cavities arranged in the substrate.
In an embodiment, the multilayer structure further comprises:
an active layer disposed on the dielectric layer;
second cavities arranged in the active layer and at least partially filled by the mobile electrical charge-trapping layer.
Other characteristics and benefits of the invention shall appear clearly in the description that is given thereof hereinbelow, for the purposes of information and in no way limiting, in reference to the following figures:
For increased clarity, identical or similar elements are marked with identical reference signs in all the figures.
The step S1 of
The substrate 31, also called support layer, is formed from a high resistivity semiconductor material, for example high resistivity silicon. A semiconductor material is here qualified as high resistivity when its electrical resistivity is greater than or equal to 500 Ω.cm. Such a resistivity makes it possible to reduce the leakage currents between the different components (active or passive) formed on the substrate and the eddy currents in the substrate, thus limiting losses by the Joule effect that stem therefrom.
The dielectric layer 32 is formed from a material that can be etched selectively with respect to the material of the substrate 31. The dielectric layer 32 can in particular be constituted of a silicon oxide (for example silicon dioxide, or SiO2) or of a silicon nitride (e.g. Si3N4).
The step S1 of supplying the stack 30 beneficially comprises a thermal oxidation operation (or a nitriding operation) of the surface of the substrate 31 so as to form the dielectric layer 32. A good quality interface can thus be obtained. Alternatively, the step S1 of supplying the stack 30 can comprise a deposition operation of the dielectric layer 32 on the substrate 31, for example by plasma-enhanced chemical vapor deposition (PECVD) or low pressure chemical vapor deposition (LPCVD).
In this first embodiment, the substrate 31 is a so-called “bulk” substrate, i.e. comprised solely of semiconductor material (as opposed to innovative substrates such as the SOI substrate). The thickness of the dielectric layer 32 is in an embodiment comprised between 50 nm and 100 nm.
The dielectric layer 32 can possibly be constituted of a stack of several sublayers, for example a sublayer of silicon oxide surmounted with a sublayer of silicon nitride (STI integration).
In the step S2 of
Beneficially, the trenches 40 further extend in a portion of the substrate 31, such as shown in
In the step S3 of
The first cavities 50 in the substrate 31 communicate with the trenches 40 in the dielectric layer 32. Indeed, the substrate 31 is etched starting from the trenches 40. When the latter emerge on the upper face of the substrate 31, the first cavities 50 globally have the shape of a half cylinder. When the trenches 40 further extend partially in the substrate 31, the first cavities 50 have a more extended shape and extend more deeply in the substrate 31.
In an embodiment, each one of the first cavities 50 has a width L2 comprised between 200 nm and 5000 nm and a depth P2 comprised between 100 nm and 2500 nm. The length of the first cavities 50 is substantially equal to the length of the trenches 40, for example comprised between 50 μm and 2000 μm.
The trenches 40 can have identical dimensions, although that is not necessary to obtain first cavities 50. In the same way, the first cavities 50 can have identical dimensions (such as is the case when the trenches 40 have identical dimensions).
This, in the step S4 of
The trapping layer 60 beneficially has an electrical resistivity greater than 50 Ω.cm for frequencies comprised between 100 MHz and 100 GHz. Thus, the trapping layer 60 prevents or significantly limits the propagation of electrical signals the frequency of which is comprised between 100 MHz and 100 GHz.
The trapping layer 60 is deposited in such a way as to fill in the trenches 40 in the dielectric layer 32, thus closing the first cavities 50 in the substrate 31. In an embodiment, a conformal deposition technique such as low pressure chemical vapor deposition (LPCVD) is used during the step S4. The trapping layer 60 is then of a constant thickness, for example comprised between 10 nm and 50 nm, and follows the contours of the substrate 31 and of the dielectric layer 32. In particular, the trapping layer 60 covers all the side walls of the trenches 40 and all the walls of the first cavities 50. It also extends to the surface of the dielectric layer 32.
On the other hand, the trapping layer 60 does not entirely fill the first cavities 50. The remaining portion of the first cavities 50 is filled with a gas or gaseous mixture, for example air or other gases introduced into the deposition reactor. The pressure present in the first cavities 50 can be very low (it is in particular according to the partial pressures of the gases introduced into the deposition reactor), so as to reach a practically vacuum configuration. It is in an embodiment comprised between 1 Pa and 100 Pa.
The trapping layer 60 is in an embodiment formed from a material that has properties of trapping mobile electrical charges (electrons), such as polycrystalline silicon.
Alternatively, the trapping layer 60 is made from a dielectric material, for example an oxide such as SiO2 or a nitride such as SiN.
Finally, the step S5 of
Thus, in reference to
the substrate 31;
the dielectric layer 32 disposed on the substrate 31;
the trenches 40 extending through the dielectric layer 32 to the substrate 31;
the first cavities 50 extending in the substrate 31, from the interface between the substrate 31 and the dielectric layer 32;
the trapping layer 60 entirely filling the trenches 40 in the dielectric layer 32 and lining the walls of the first cavities 50 arranged in the substrate 31 (without however filling them entirely).
As is known in the field of SOI multilayer structures for radiofrequency applications, a dielectric layer (for example made of SiO2) on a semiconductor substrate comprises positive charges. These charges are compensated by negative charges coming from the substrate, at the interface with the dielectric layer. These charges generate a parasitic surface conduction (PSC) layer in the substrate under the dielectric layer, which decreases the effective resistivity of the substrate. The electrical performance sensitive to the resistivity of the substrate (such as the linearity of the signal, the level of insertion losses, the quality factors of the passive components . . . ) are therefore substantially degraded by the presence of this conduction layer.
The first cavities 50 and the trapping layer 60 (when the latter is not made from a dielectric material) limit the surface on which the mobile electrical charges accumulate. Furthermore, they prevent the movement of these electrical charges in the substrate 31 at the interface with the dielectric layer 32. The electrical charges are obliged to circumvent the first cavities 50, thus passing through zones of the substrate 31 of higher resistivity (the deeper the first cavities 50 are, the more pronounced this circumventing effect is). This results in that the effective resistivity of the substrate 31 is greatly improved.
The plugs formed by the trapping layer 60 through the dielectric layer 32 and the presence of the trapping layer 60 on the ceiling of the first cavities 50 are recognisable elements of the method of manufacturing a multilayer structure according to the invention.
Thus, the stack 30 provided in the step S1 of
The active layer 33 is in an embodiment a thin film of semiconductor material, intrinsic or doped, for example made of monocrystalline silicon, of germanium, of a silicon-germanium alloy or of a III-V semiconductor material. The active layer 33 is more particularly intended for the manufacturing of active components, typically transistors. Its thickness is in an embodiment comprised between 6 nm and 200 nm.
The protective layer 34 has for purpose to protect the active layer 33 during later steps of the method for manufacturing the multilayer structure. It can also be used as a hard mask layer and/or etch stop layer during a method for manufacturing an integrated circuit from the multilayer structure. The protective layer 34 can comprise several superimposed sublayers, for example a first sublayer 34a made of SiO2 and a second sublayer 34b made of SiN disposed on the first sublayer 34a.
The dielectric layer 32 constitutes the electrically insulating layer of the SOI substrate (also called buried oxide layer or BOX, in the case of an oxide such as SiO2). In this second embodiment, the thickness of the dielectric layer 32 is beneficially comprised between 20 nm and 400 nm.
After the step S2 of etching trenches 40 shown in
Finally, the upper portion of the trapping layer 60 (deposited on the protective layer 34) is removed in the step S5 shown in
The multilayer structure 200 obtained at the end of the method for manufacturing according to the second embodiment (
Such a multilayer structure 200 is obtained by etching in the step S2 of the trenches 40 that communicate together and form a meshing in the dielectric layer 32. In an embodiment, the trenches 40 have a first pitch (also called spatial period) PX comprised between 100 nm and 5 μmin the first direction X and a second pitch PY comprised between 100 nm and 5 μmin the second direction Y. By way of example, the trenches 40 form a rectangular meshing (second direction Y perpendicular to the first direction X). The first pitch PX can be equal to the second pitch PY (square meshing).
In an alternative embodiment not shown in the figures, the trenches 40 are disjointed and all extend along planes parallel to one another and perpendicular to the main face of the substrate 31. They can further have a pitch Px in the first direction X, in an embodiment comprised between 50 nm and 5 μm. The first cavities 50 then all extend parallelly to one another in the second direction Y.
In this alternative embodiment, the trenches 40 extend parallelly to one another (for example in the second direction Y). Furthermore, the distance d between two consecutive trenches 40 (measured in the first direction X; cf.
Thus, thanks to a more substantial spacing of the trenches 40 (and therefore a more substantial spatial period), a wider cavity can be obtained in the substrate 31. The distance d between two consecutive trenches 40 is beneficially comprised between 300 nm and 5000 nm. This distance d can vary from one pair of trenches 40 to the other. In other words, it is not necessary that the trenches 40 be regularly spaced (or that they have identical dimensions) in order to obtain the first large cavity 50′.
In an embodiment, the first large cavity 50′ has a width L3 comprised between 5 μm and 20 μm. Its length and its depth can be respectively identical to the length and the depth P2 of the first cavities 50 when they are disjointed (respectively between 50 μm and 2000 μm and between 100 nm and 2500 nm).
By providing several groups of trenches 40 (regularly spaced or not), it is possible to obtain in the substrate 31 several first large separate cavities 50′ (i.e. non-communicating).
The method for manufacturing a multilayer structure described hereinabove in relation with
Moreover, it can easily be integrated into a method for manufacturing an integrated circuit, for example of the radiofrequency type. The steps S2 to S5 can in particular be accomplished immediately after having formed electrical insulating trenches 80 called STI (for “Shallow Trench Isolation”) in the SOI substrate (cf.
The active components 91 are for example transistors. They are for example formed in the active layer 33 of the SOI substrate or on the surface of the bulk substrate 31, in other words in the so-called FEOL (“front-end of line”) portion of the integrated circuit 400. In the case of a bulk substrate, the dielectric layer 32 is entirely removed before forming the active components 91 on the surface of the substrate.
The passive components 90 are for example coils, capacitors, resistors, etc. They are located vertically with respect to the first cavities 50 in the substrate 31 in order to optimise their electrical performance. They are for example formed above the levels of electrical interconnection 92 (or metal levels). Like the levels of electrical interconnection 92, the passive components 90 belong to the so-called BEOL (“back-end of line”) portion of the integrated circuit 400.
The active components 91 can be formed in a first zone Z1 of the multilayer structure, while the passive components 90 are formed in a second zone Z2. The second zone Z2 is separate from the first zone Z1 and provided with first cavities 50. The first and second zones Z1-Z2 are in an embodiment separated by an electrical insulation trench 80.
Number | Date | Country | Kind |
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2109178 | Sep 2021 | FR | national |