Patent Grant
11059204
This application is a National Phase of PCT Patent Application No. PCT/CN2018/079213 having International filing date of Mar. 16, 2018, which claims the benefit of priority of Chinese Patent Application No. 201810161037.0 filed on Feb. 27, 2018. The contents of the above applications are all incorporated by reference as if fully set forth herein in their entirety.
The present disclosure relates to the field of display technology, and more particularly to a method for manufacturing a flexible material having a surface protecting layer.
Flexible electronic elements and flexible display technology are subjects that manufacturers mainly focus their research on and are one of the directions that electronics is developing in the near decades. Flexible electronic products, which are light weight, flexible, foldable, and even windable, include flexible TFT-LCDs and flexible OLEDs, and have gradually become the high-tech products having the most promising future.
However, flexible substrates still have some problems, such as low surface hardness, poor abrasion resistance, poor chemical resistance, and unsatisfactory heat resisting properties.
The object of the present disclosure is to provide a method for manufacturing a flexible material having a surface protecting layer, which improves abrasion resistance of the flexible substrate.
In one aspect, the present disclosure provides a method for manufacturing a flexible material having a surface protecting layer, comprising:
dissolving and uniformly mixing a plurality of aluminum oxide nanoparticles and a polymerizable monomer into a polyimide solution to obtain a polyimide mixed solution, wherein the polymerizable monomer includes acrylamide-based acrylate and derivatives thereof;
coating the polyimide mixed solution onto a glass substrate, such that the aluminum oxide nanoparticles are uniformly distributed on a surface of the glass substrate;
irradiating the surface of the glass substrate with UV light to form a network polymer on the surface of the glass substrate, the network polymer enclosing the aluminum oxide nanoparticles; and
heating the glass substrate to form the flexible material having the surface protecting layer, wherein heating the glass substrate to form the flexible material having the surface protecting layer includes:
In accordance with the method of the present disclosure for manufacturing the flexible material having the surface protecting layer, the polymerizable monomer has a general formula of Sa-Sp-Sb,
Sa is
wherein R is H or CH3—(CH2)n—, n is an integer of 1-8, and H can be replaced by F;
Sp is —(CH2)n—, wherein n is a value of 1-5, and CH2 can be replaced by —O—, —S—, —CO—, —CO—O—, —O—CO—, —O—CO—O—, —OCH2—, —CH2O—, —CH═CH—, —CF═CF—, —C≡C—, —CH═CH—COO—, or —OCO—CH═CH—; and
Sb is
wherein R is H or CH3—(CH2)n—, n is an integer of 1-8, and H can be replaced by F.
In accordance with the method of the present disclosure for manufacturing the flexible material having the surface protecting layer, the polymerizable monomer is
In accordance with the method of the present disclosure for manufacturing the flexible material having the surface protecting layer, an irradiation energy of the UV light is 85-100 mW/cm2, and an irradiation duration of the UV light is 10-60 minutes.
In accordance with the method of the present disclosure for manufacturing the flexible material having the surface protecting layer, before dissolving and uniformly mixing the aluminum oxide nanoparticles and the polymerizable monomer into the polyimide solution to obtain the polyimide mixed solution, the method further comprises: dissolving one or more dianhydride monomers and one or more diamine monomers into an organic solvent selected from N-methyl-pyrrolidone, N-ethylpyrrolidine, γ-hexalactone, dimethyl sulfoxide, or dichloromethane to obtain a polyimide solution.
In accordance with the method of the present disclosure for manufacturing the flexible material having the surface protecting layer, after heating the glass substrate to form the flexible material having the surface protecting layer, the method further comprises: separating the glass substrate from the flexible material having the surface protecting layer.
In accordance with the method of the present disclosure for manufacturing the flexible material having the surface protecting layer, separating the glass substrate from the flexible material having the surface protecting layer is implemented by a laser or a mechanical separation method.
In another aspect, the present disclosure provides a method for manufacturing a flexible material having a surface protecting layer, comprising:
dissolving and uniformly mixing a plurality of aluminum oxide nanoparticles and a polymerizable monomer into a polyimide solution to obtain a polyimide mixed solution;
coating the polyimide mixed solution onto a glass substrate, such that the aluminum oxide nanoparticles are uniformly distributed on a surface of the glass substrate;
irradiating the surface of the glass substrate with UV light to form a network polymer on the surface of the glass substrate, the network polymer enclosing the aluminum oxide nanoparticles; and
heating the glass substrate to form the flexible material having the surface protecting layer.
In accordance with the method of the present disclosure for manufacturing the flexible material having the surface protecting layer, the polymerizable monomer includes acrylamide-based acrylate and derivatives thereof.
In accordance with the method of the present disclosure for manufacturing the flexible material having the surface protecting layer, the polymerizable monomer has a general formula of Sa-Sp-Sb,
Sa is
wherein R is H or CH3—(CH2)n—, n is an integer of 1-8, and H can be replaced by F;
Sp is —(CH2)n—, wherein n is a value of 1-5, and CH2 can be replaced by —O—, —S—, —CO—, —CO—O—, —O—CO—, —O—CO—O—, —OCH2—, —CH2O—, —CH═CH—, —CF═CF—, —C≡C—, —CH═CH—COO—, or —OCO—CH═CH—; and
Sb is
wherein R is H or CH3—(CH2)n—, n is an integer of 1-8, and H can be replaced by F.
In accordance with the method of the present disclosure for manufacturing the flexible material having the surface protecting layer, the polymerizable monomer is
In accordance with the method of the present disclosure for manufacturing the flexible material having the surface protecting layer, an irradiation energy of the UV light is 85-100 mW/cm2, and an irradiation duration of the UV light is 10-60 minutes.
In accordance with the method of the present disclosure for manufacturing the flexible material having the surface protecting layer, heating the glass substrate to obtain the polyimide mixed solution includes:
In accordance with the method of the present disclosure for manufacturing the flexible material having the surface protecting layer, before dissolving and uniformly mixing the aluminum oxide nanoparticles and the polymerizable monomer into the polyimide solution to obtain the polyimide mixed solution, the method further comprises:
dissolving one or more dianhydride monomers and one or more diamine monomers into an organic solvent selected from N-methyl-pyrrolidone, N-ethylpyrrolidine, γ-hexalactone, dimethyl sulfoxide, or dichloromethane to obtain a polyimide solution.
In accordance with the method of the present disclosure for manufacturing the flexible material having the surface protecting layer, after heating the glass substrate to form the flexible material having the surface protecting layer, the method further comprises:
separating the glass substrate from the flexible material having the surface protecting layer.
In accordance with the method of the present disclosure for manufacturing the flexible material having the surface protecting layer, separating the glass substrate from the flexible material having the surface protecting layer is implemented by a laser or a mechanical separation method.
According to the present disclosure, a plurality of aluminum oxide nanoparticles and a polymerizable monomer are dissolved in a polyimide solution to obtain a polyimide mixed solution. Next, the polyimide mixed solution is coated onto a glass substrate. Then, the surface of the glass substrate is irradiated with UV light to form a network polymer on the surface of the glass substrate, the network polymer enclosing the aluminum oxide nanoparticles. Finally, the glass substrate is heated to form the flexible material having the surface protecting layer. The abrasion resistance of the flexible material manufactured according to the present disclosure is excellent.
To explain in detail the technical schemes of the embodiments or existing techniques, drawings that are used to illustrate the embodiments or existing techniques are provided. The illustrated embodiments are just a part of those of the present disclosure. It is easy for any person having ordinary skill in the art to obtain other drawings without labor for inventiveness.
The following embodiments refer to the accompanying drawings for exemplifying specific implementable embodiments of the present disclosure. Moreover, directional terms described by the present disclosure, such as upper, lower, front, back, left, right, inner, outer, side, etc., are only directions by referring to the accompanying drawings, and thus the used directional terms are used to describe and understand the present disclosure, but the present disclosure is not limited thereto. In the drawings, the same reference symbol represents the same or similar components.
Please refer to
a step S101 of dissolving and uniformly mixing a plurality of aluminum oxide nanoparticles and a polymerizable monomer into a polyimide solution to obtain a polyimide mixed solution;
a step S102 of coating the polyimide mixed solution onto a glass substrate, such that the aluminum oxide nanoparticles are uniformly distributed on a surface of the glass substrate;
a step S103 of irradiating the surface of the glass substrate with UV light to form a network polymer on the surface of the glass substrate, the network polymer enclosing the aluminum oxide nanoparticles; and
a step S104 of heating the glass substrate to form the flexible material having the surface protecting layer.
The following detailed description is made with reference to the accompanying drawings to explain each step of the method for manufacturing a flexible material having a surface protecting layer.
In the step S101, the polymerizable monomer includes acrylamide-based acrylate and derivatives thereof. Specifically, the polymerizable monomer has a general formula of Sa-Sp-Sb, wherein
Sa is
wherein R is H or CH3—(CH2)n—, n is an integer of 1-8, and H can be replaced by F;
Sp is —(CH2)n—, wherein n is a value of 1-5, and CH2 can be replaced by —O—, —S—, —CO—, —CO—O—, —O—CO—, —O—CO—O—, —OCH2—, —CH2O—, —CH═CH—, —CF═CF—, —C≡C—, —CH═CH—COO—, or —OCO—CH═CH—; and
Sb is
wherein R is H or CH3—(CH2)n—, n is an integer of 1-8, and H can be replaced by F.
For example, the polymerizable monomer can be a
Please refer to
The diamine monomers can be
For instance, firstly, N-methyl-pyrrolidone, propylene glycol monomethyl ether acetate, and 2-butanone are uniformly mixed to prepare 1000 g of polyamic acid solvent, where N-methyl-pyrrolidone, propylene glycol monomethyl ether acetate, and 2-butanone have a mass ratio of 45%: 40%: 15%. Next, 75 g of dianhydride monomer and 75 g of diamine monomer are uniformly mixed to obtain a polyimide solution. Then, 5 g of aluminum oxide nanoparticles and 10 g of polymerizable monomer are dissolved in the polyimide solution to obtain a polyimide mixed solution. It is understood that quantities of the components could be adjusted, and are not limited to that shown in this preferred embodiment.
To explain the step S102, please refer to
To explain the step S103, please refer to
Preferably, an irradiation energy of the UV light is 85-100 mW/cm2, and an irradiation duration of the UV light is 10-60 minutes.
To explain the step S104, please refer to
a step S1041 of heating the glass substrate at 100-120° C. for 5-10 minutes;
a step S1042 of heating the glass substrate at 200-250° C. for 20-60 minutes; and
a step S1043 of heating the glass substrate at 300-350° C. for 5-15 minutes.
The step S1041, in which the glass substrate is heated at 100-120° C. for 5-10 minutes, is performed in order to remove solvents in the polyimide mixed solution. The step S1042, in which the glass substrate is heated at 200-250° C. for 20-60 minutes, is performed in order to have dianhydride react with polyamic acid and amide of polymerizable monomer to cause dehydration condensation. The step S1043, in which the glass substrate is heated at 300-350° C. for 5-15 minutes, is performed in order to have reactions taking place complete. Thus, a polymer material is formed on the glass substrate. The polymer material includes the polymer/aluminum oxide layer 104 and the polyimide layer 106.
Please refer to
According to the present disclosure, a plurality of aluminum oxide nanoparticles and a polymerizable monomer are dissolved and uniformly mixed into a polyimide solution to obtain a polyimide mixed solution. Next, the polyimide mixed solution is coated onto a glass substrate, such that the aluminum oxide nanoparticles are uniformly distributed on a surface of the glass substrate. Then, the surface of the glass substrate is irradiated with UV light to form a network polymer on the surface of the glass substrate, the network polymer enclosing the aluminum oxide nanoparticles. Finally, the glass substrate is heated to form the flexible material having the surface protecting layer. The abrasion resistance of the flexible material manufactured according to the present disclosure is excellent.
While the present disclosure has been described with the aforementioned preferred embodiments, it is preferable that the above embodiments should not be construed as limiting of the present disclosure. Anyone having ordinary skill in the art can make a variety of modifications and variations without departing from the spirit and scope of the present disclosure as defined by the following claims.
| Number | Date | Country | Kind |
|---|---|---|---|
| 201810161037.0 | Feb 2018 | CN | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/CN2018/079213 | 3/16/2018 | WO | 00 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2019/165652 | 9/6/2019 | WO | A |
| Number | Name | Date | Kind |
|---|---|---|---|
| 20120292086 | Auman et al. | Nov 2012 | A1 |
| Number | Date | Country |
|---|---|---|
| 102712754 | Oct 2012 | CN |
| 106009015 | Oct 2016 | CN |
| 107698785 | Feb 2018 | CN |
| Entry |
|---|
| English abstract of CN107698785A (Year: 2018). |
| English abstract of CN106009015A (Year: 2016). |
| International Search Report and the Written Opinion dated Nov. 22, 2018 From the International Searching Authority Re. Application No. PCT/CN2018/079213 and Its Translation of Search Report Into English. (11 Pages). |
| Number | Date | Country | |
|---|---|---|---|
| 20190263028 A1 | Aug 2019 | US |
