Patent Grant
8568851
The present invention relates to an optical information recording medium having a plurality of information recording layers. Particularly, the invention relates to a method of manufacturing an optical information recording medium having a laminate of unit layers each including a resin layer having an uneven surface and a recording layer laminated on the uneven surface of the resin layer, and an optical information recording medium.
There is an optical information recording medium having a laminate of unit layers each including a resin layer having an uneven surface and a recording layer laminated on the uneven surface of the resin layer (Patent Literature 1 and Patent Literature 2).
Patent Literature 1 discloses a method of manufacturing an optical information recording medium (optical disc) including the following six steps.
(First step) A liquid ultraviolet-curing resin is dropped onto a grooved resin stamper.
(Second step) A flat resin stamper is laminated on the ultraviolet-curing resin on the grooved resin stamper, and ultraviolet rays are irradiated via the flat resin stamper to cure the ultraviolet-curing resin, thereby forming a first groove transfer layer.
(Third step) The grooved resin stamper is peeled to expose the first groove transfer layer.
(Fourth step) A recording layer is formed on the exposed first groove transfer layer. Further, steps of dropping a liquid ultraviolet-curing resin onto the recording layer, laminating a grooved resin stamper on the ultraviolet-curing resin, irradiating ultraviolet rays via the flat resin stamper to cure the ultraviolet-curing resin, then peeling the grooved resin stamper, and forming a recording layer thereon are repeated to form a laminate having groove transfer layers and recording layers alternately laminated on each other.
(Fifth step) A substrate is adhered onto the topmost recording layer of the laminate, and the flat resin stamper is peeled from the laminate.
(Sixth step) The recording layer of the laminate manufactured separately through the fourth step and the recording layer of the laminate manufactured through the fifth step are adhered so that the recording layers face each other, and then the flat resin stamper is peeled from the laminate manufactured separately through the fourth step.
According to the manufacture method disclosed in Patent Literature 1, ultraviolet rays are irradiated via the flat resin stamper so that the amount of ultraviolet rays which reach the ultraviolet-curing resin between the grooved resin stamper and a recording layer becomes smaller than the amount of ultraviolet rays which reach the recording layer and the ultraviolet-curing resin on an underlying recording layer. Therefore, the degree of polymerization of the ultraviolet-curing resin between the grooved resin stamper and the recording layer, i.e., the adhesion strength becomes smaller than that of the ultraviolet-curing resin on another layer. This method is assumed not to cause peeling between a recording layer and an underlying recording layer or between a recording layer and the flat resin stamper.
However, it is difficult to control the amount of ultraviolet rays which reach the ultraviolet-curing resin between the grooved resin stamper and the recording layer. Therefore, it is difficult to control the degree of polymerization of the ultraviolet-curing resin between the grooved resin stamper and the recording layer, so that the adhesion strength of the ultraviolet-curing resin between the grooved resin stamper and the recording layer may not become smaller than that of the ultraviolet-curing resin on another layer. In this case, peeling may occur in an unexpected location, e.g., between a recording layer and an underlying recording layer or between a recording layer and the flat resin stamper.
The invention has been made in view of the foregoing situations, and it is an object of the invention to provide a method of efficiently manufacturing an optical information recording medium by reliably peeling a stamper from an ultraviolet-curing resin layer, and an optical information recording medium manufactured by the method.
According to a first aspect of the invention, there is provided a method of manufacturing an optical information recording medium having a laminate of unit layers each including a resin layer having an uneven surface and a recording layer laminated on the uneven surface of the resin layer, the method including:
a first resin applying step of applying a first photo-curing resin to one surface of a first substrate;
a first resin curing step of laminating a first stamper having an uneven surface on the first photo-curing resin applied to the one surface of the first substrate, and irradiating ultraviolet rays onto the first photo-curing resin via the first stamper to cure the first photo-curing resin;
a second resin applying step of applying a second photo-curing resin to the other surface of the first substrate;
a second resin curing step of laminating a second stamper having an uneven surface on the second photo-curing resin applied to the other surface of the first substrate, and irradiating ultraviolet rays onto the second photo-curing resin via the first second to cure the second photo-curing resin;
a first stamper peeling step of peeling the second stamper from the second photo-curing resin; and
a first recording layer laminating step of laminating a first recording layer on a surface of the second photo-curing resin which is exposed by peeling of the second stamper.
An optical information recording medium according to a second aspect of the invention is manufactured by the method of manufacturing an optical information recording medium according to the first aspect of the invention.
According to the invention, an optical information recording medium can be efficiently manufactured by reliably peeling a stamper from an ultraviolet-curing resin layer. In addition, the invention can provide an optical information recording medium efficiently manufactured.
[Optical Information Recording Medium]
As shown in
As shown in
The first substrate 2 is a disk with a diameter of about 120 mm and a thickness of 20 to 30 μm or so. The first substrate 2 includes a base formed by a PC film or the like. The first substrate 2 has optical transparency.
The first recording layer 3 and the second recording layer 4 are, for example, a magneto-optical film, a phase shifting film, a pigmented coat or a hologram film with a thickness of 10 to 100 nm or so. The first recording layer 3 and the second recording layer 4 have recesses and projections. The recesses and projections of the first recording layer 3 and the second recording layer 4 are arranged so as to overlap the same locations when the optical information recording medium 1 is seen in a plan view. That is, arranged on the second recording layer 4 directly above a projection of the first recording layer 3 is a projection having the same shape and the same size as the former projection.
The first ultraviolet-curing resin layer 5 has a thickness of 1 μm or so. The first ultraviolet-curing resin layer 5 is formed by applying a liquid resin to the first substrate 2. The first ultraviolet-curing resin layer 5 is formed from a position away from the rotational center of the first substrate 2 by a length of R1 in a radial direction. The resin for forming the first ultraviolet-curing resin layer 5 is a mixture of a fluorine-contained monomer, tetra ethylene glycol diacrylate, 2-methyl-2-adamantyl acrylate, a surface active agent, and a photopolymerization initiator blended in a predetermined weight ratio. It is to be noted that the mixture has such a property that the lower the ratio of the fluorine-contained monomer content (weight ratio), the higher the degree of polymerization or the greater the adhesion strength to an object to be adhered.
The second ultraviolet-curing resin layer 6 has a thickness of 1 μm or so. The second ultraviolet-curing resin layer 6 is formed by applying a liquid resin to the first substrate 2. The second ultraviolet-curing resin layer 6 is formed from a position away from the rotational center of the first substrate 2 by a length of R2 in a radial direction. The length of R2 in a radial direction is larger than the length of R1 in a radial direction. As a result, the area of the second ultraviolet-curing resin layer 6 is smaller than the area of the first ultraviolet-curing resin layer 5. The resin for forming the second ultraviolet-curing resin layer 6 is a mixture made of the same components as those of the first ultraviolet-curing resin layer 5, with the ratio of the fluorine-contained monomer content (weight ratio) set larger. Accordingly, the second ultraviolet-curing resin layer 6 has a lower adhesion strength to an object to be adhered than the first ultraviolet-curing resin layer 5.
The third ultraviolet-curing resin layer 7 has an average thickness of 0.5 μm or so. A resin which is a mixture made of the same components as those of the first ultraviolet-curing resin layer 5, with the ratio of the fluorine-contained monomer content (weight ratio) set smaller, or a resin which essentially consists of acrylic ester and does not contain a fluorine-contained monomer is selected as the resin for forming the third ultraviolet-curing resin layer 7.
The second substrate 8 is a disk with a diameter of about 120 mm and a thickness of 20 to 30 μm or so. The second substrate 8 includes a base formed by a PC film or the like, and has optical transparency.
The third substrate 9 is a disk with a diameter of about 120 mm and a thickness of 20 to 30 μm or so. The third substrate 9 is a dummy substrate which prevents warping of the optical information recording medium 1 and improves the mechanical strength thereof. The third substrate 9 includes a base formed by a PC film or the like, and has optical transparency.
Next, a method of manufacturing the optical information recording medium 1 will be described.
(First Resin Applying Step)
First, as shown in
It is to be noted that deaeration of the resin in vacuum in advance before injecting the resin into the spin coater can prevent minute bubbles from being produced in the first ultraviolet-curing resin layer 5. The same is true of other resin applying steps to be discussed later.
(First Resin Curing Step)
Next, as shown in
The first stamper 10 has an uneven surface. The first stamper 10 is a die for transferring the uneven surface to the first ultraviolet-curing resin layer 5. The first stamper 10 is injection-molded of polycarbonate or the like, and has optical transparency.
The depth of the uneven surface of the first stamper 10 varies according to the wavelength of a laser beam used in writing/reading on/from the optical information recording medium 1 and the recording system of the optical information recording medium 1. When the wavelength of the laser beam is 405 nm and the land/groove type is employed, for example, the depth of the uneven surface is selected so that the depth of the spiral groove becomes 32 nm. In case of the pit type, the depth of the uneven surface is selected so that the depth of the pits becomes 64 nm
After laminating the first stamper 10 on the first ultraviolet-curing resin layer 5, ultraviolet rays are irradiated onto the first ultraviolet-curing resin layer 5 from above the first stamper 10 using an ultraviolet-rays irradiating apparatus (not shown) to cure the first ultraviolet-curing resin layer 5.
(Second Resin Applying Step)
Next, as shown in
The length of R2 in a radial direction is larger than the length of R1 in a radial direction (see
(Second Resin Curing Step)
Next, as shown in
The second stamper 11, like the first stamper 10, has an uneven surface. The second stamper 11 is a die for transferring the uneven surface to the second ultraviolet-curing resin layer 6. The second stamper 11 is injection-molded of polycarbonate or the like, and has optical transparency.
After laminating the second stamper 11 on the second ultraviolet-curing resin layer 6, ultraviolet rays are irradiated onto the second ultraviolet-curing resin layer 6 from above the second stamper 11 using the ultraviolet-rays irradiating apparatus (not shown) to cure the second ultraviolet-curing resin layer 6.
(First Stamper Peeling Step)
Next, as shown in
As mentioned above, the area of the second ultraviolet-curing resin layer 6 is smaller than the area of the first ultraviolet-curing resin layer 5. Since the ratio of the fluorine-contained monomer content in the resin for forming the second ultraviolet-curing resin layer 6 is changed from the ratio of the fluorine-contained monomer content in the resin for forming the first ultraviolet-curing resin layer 5, the first stamper 10 is adhered to the first substrate 2 more firmly than the second stamper 11. Therefore, pulling the first stamper 10 and the second stamper 11 in the opposite directions peels only the second stamper 11 from the second ultraviolet-curing resin layer 6.
(First Recording Layer Laminating Step)
Lastly, as shown in
For the sake of descriptive convenience hereinafter, a half-finished product of the optical information recording medium 1 as shown in
Next, procedures of further processing the first block 12 to complete an optical information recording medium having a double-layered recording layer (hereinafter called “double-layered medium A”), specifically, the optical information recording medium 1 as shown in
(Third Resin Applying Step)
First, as shown in
The third ultraviolet-curing resin layer 7 is formed thinner than the first ultraviolet-curing resin layer 5. In general, the thinner the thickness of an adhesive to be applied, the less likely defects, such as voids, are formed in the applied adhesive layer and the greater the adhesion strength to an object to be adhered. Therefore, the adhesion strength of the third ultraviolet-curing resin layer 7 becomes greater than that of the first ultraviolet-curing resin layer 5.
(First Substrate Fixing Step)
Next, as shown in
With the second substrate 8 laminated, ultraviolet rays are irradiated onto the third ultraviolet-curing resin layer 7 from above the second substrate 8 using the ultraviolet-rays irradiating apparatus (not shown). The irradiation of the ultraviolet rays cures the third ultraviolet-curing resin layer 7 to thereby fix the second substrate 8.
(Second Stamper Peeling Step)
Next, as shown in
As mentioned above, the third ultraviolet-curing resin layer 7 is formed thinner than the first ultraviolet-curing resin layer 5. The ratios of the fluorine-contained monomer contents in the resins for forming the third ultraviolet-curing resin layer 7 and the first ultraviolet-curing resin layer 5 are made different from each other. This causes the second substrate 8 to be adhered more firmly than the first stamper 10. Therefore, pulling the second substrate 8 and the first stamper 10 in the opposite directions peels only the first stamper 10 from the first ultraviolet-curing resin layer 5.
(Second Recording Layer Laminating Step)
Next, as shown in
(Fourth Resin Applying Step)
Next, as shown in
(Second Substrate Fixing Step)
Next, as shown in
With the third substrate 9 laminated, ultraviolet rays are irradiated onto the third ultraviolet-curing resin layer 7 from above the third substrate 9 using the ultraviolet-rays irradiating apparatus (not shown). The irradiation of the ultraviolet rays cures the third ultraviolet-curing resin layer 7 to thereby fix the third substrate 9.
The optical information recording medium 1 (double-layered medium A) is completed through the foregoing process.
Next, a method of manufacturing an optical information recording medium having a four-layered recording layer (hereinafter called “four-layered medium B”) by further laminating recording layers on the optical information recording medium (double-layered medium A) 1.
To manufacture the four-layered medium B, first, a second block 13 as shown in
(Fifth Resin Applying Step)
First, as shown in
(Third Substrate Fixing Step)
Next, as shown in
With the second substrate 8 laminated, ultraviolet rays are irradiated onto the third ultraviolet-curing resin layer 7 from above the second substrate 8 using the ultraviolet-rays irradiating apparatus (not shown). The irradiation of the ultraviolet rays cures the third ultraviolet-curing resin layer 7 to thereby fix the second substrate 8.
(Third Stamper Peeling Step)
Next, as shown in
(Third Recording Layer Laminating Step)
Next, as shown in
For the sake of descriptive convenience hereinafter, a half-finished product of the four-layered medium B as shown in
(Sixth Resin Applying Step)
Next, as shown in
(First Double-Layered Medium Fixing Step)
Next, as shown in
Then, ultraviolet rays are irradiated onto the third ultraviolet-curing resin layer 7 from above the second substrate 8 of the double-layered medium A using the ultraviolet-rays irradiating apparatus (not shown). The irradiation of the ultraviolet rays cures the third ultraviolet-curing resin layer 7 to thereby fix the double-layered medium A.
The optical information recording medium 1 (four-layered medium B) is completed through the foregoing process.
The four-layered medium B may be manufactured by laminating the second block 13 (see
(Seventh Resin Applying Step)
First, as shown in
(Fourth Substrate Fixing Step)
Next, as shown in
With the third substrate 9 laminated, ultraviolet rays are irradiated onto the third ultraviolet-curing resin layer 7 from above the third substrate 9 using the ultraviolet-rays irradiating apparatus (not shown). The irradiation of the ultraviolet rays cures the third ultraviolet-curing resin layer 7 to thereby fix the third substrate 9.
(Eighth Resin Applying Step)
Next, as shown in
(First Block Fixing Step)
Next, as shown in
With the second block 13 laminated, ultraviolet rays are irradiated onto the third ultraviolet-curing resin layer 7 from above the second stamper 11 using the ultraviolet-rays irradiating apparatus (not shown). The irradiation of the ultraviolet rays cures the third ultraviolet-curing resin layer 7 to thereby fix the second block 13 to the first block 12.
(Fourth Stamper Peeling Step)
Next, as shown in
As mentioned above, the area of the fourth ultraviolet-curing resin layer 15 is smaller than the area of the first ultraviolet-curing resin layer 5. Since the ratio of the fluorine-contained monomer content in the resin for forming the fourth ultraviolet-curing resin layer 15 is changed from the ratio of the fluorine-contained monomer content in the resin for forming the first ultraviolet-curing resin layer 5, the first stamper 10 is adhered to the first substrate 2 more firmly than the second stamper 11. Therefore, pulling the first stamper 10 and the second stamper 11 in the opposite directions peels only the second stamper 11 from the fourth ultraviolet-curing resin layer 15.
(Fourth Recording Layer Laminating Step)
Next, as shown in
(Ninth Resin Applying Step)
Next, as shown in
(Fifth Substrate Fixing Step)
Next, as shown in
With the third substrate 9 laminated, ultraviolet rays are irradiated onto the third ultraviolet-curing resin layer 7 from above the third substrate 9 using the ultraviolet-rays irradiating apparatus (not shown). The irradiation of the ultraviolet rays cures the third ultraviolet-curing resin layer 7 to thereby fix the third substrate 9.
(Fifth Stamper Peeling Step)
Next, as shown in
(Fifth Recording Layer Laminating Step)
Next, as shown in
(Tenth Resin Applying Step)
Next, as shown in
(Sixth Substrate Fixing Step)
Lastly, as shown in
With the second substrate 8 laminated, ultraviolet rays are irradiated onto the third ultraviolet-curing resin layer 7 from above the second substrate 8 using the ultraviolet-rays irradiating apparatus (not shown). The irradiation of the ultraviolet rays cures the third ultraviolet-curing resin layer 7 to thereby fix the second substrate 8.
The optical information recording medium 1 (four-layered medium B) is completed through the foregoing process.
The four-layered medium B may be manufactured by laminating two first blocks 12 (see
(Second Block Fixing Step)
First, the third ultraviolet-curing resin layer 7 and the second substrate 8 are laminated on the first recording layer 3 of a first block 12a shown in
(Eleventh Resin Applying Step)
Next, as shown in
(Seventh Substrate Fixing Step)
Next, as shown in
With the third substrate 9 laminated, ultraviolet rays are irradiated onto the third ultraviolet-curing resin layer 7 from above the third substrate 9 using the ultraviolet-rays irradiating apparatus (not shown). The irradiation of the ultraviolet rays cures the third ultraviolet-curing resin layer 7 to thereby fix the third substrate 9.
(Twelfth Resin Applying Step)
Next, as shown in
(Third Block Fixing Step)
Next, as shown in
With the fourth block 18 laminated on the first block 12b, ultraviolet rays are irradiated onto the third ultraviolet-curing resin layer 7 from above the second substrate 8 of the fourth block 18 using the ultraviolet-rays irradiating apparatus (not shown). The irradiation of the ultraviolet rays cures the third ultraviolet-curing resin layer 7 to thereby fix the fourth block 18 to the first block 12b.
(Sixth Stamper Peeling Step)
Next, as shown in
(Sixth Recording Layer Laminating Step)
Next, as shown in
(Thirteenth Resin Applying Step)
Next, as shown in
(Eighth Substrate Fixing Step)
Lastly, as shown in
With the second substrate 8 laminated, ultraviolet rays are irradiated onto the third ultraviolet-curing resin layer 7 from above the second substrate 8 using the ultraviolet-rays irradiating apparatus (not shown). The irradiation of the ultraviolet rays cures the third ultraviolet-curing resin layer 7 to thereby fix the second substrate 8.
The optical information recording medium 1 (four-layered medium B) is completed through the foregoing process.
An optical information recording medium 1 which has 2N(N being a natural number) recording layers provided by laminating recording layers on the first block 12 (see
(Seventh Stamper Peeling Step)
First, as shown in
(Seventh Recording Layer Laminating Step)
Next, as shown in
(First-Substrate Duplicating Step)
The above step is repeated N times to duplicate N first substrates 2 having the sixth recording layer 20 deposited thereon as shown in
(Fourteenth Resin Applying Step)
Next, as shown in
(Ninth Substrate Fixing Step)
Next, as shown in
With the second substrate 8 laminated, ultraviolet rays are irradiated onto the third ultraviolet-curing resin layer 7 from above the second substrate 8 using the ultraviolet-rays irradiating apparatus (not shown). The irradiation of the ultraviolet rays cures the third ultraviolet-curing resin layer 7 to thereby fix the second substrate 8.
(Fifteenth Resin Applying Step)
Next, as shown in
(Tenth Substrate Fixing Step)
Next, as shown in
With the third substrate 9 laminated, ultraviolet rays are irradiated onto the third ultraviolet-curing resin layer 7 from above the third substrate 9 using the ultraviolet-rays irradiating apparatus (not shown). The irradiation of the ultraviolet rays cures the third ultraviolet-curing resin layer 7 to thereby fix the third substrate 9.
(First Recording-Layer Layout Step)
Lastly, the above steps are repeated to alternately laminate the first substrate 2 and the third substrate 9 on which the sixth recording layers 20 are laminated, by N−1 times, and fix the substrates. As a result, a structure having a 2N-layered recording layer is formed.
The optical information recording medium 1 (N-layered medium C) is completed through the foregoing process.
The following will illustrate examples, and will exemplify the invention in more detail. The following examples are not to be considered as restricting the technical scope of the invention.
The advantages of the invention were checked using a sample 21 as shown in
The sample 21 is a disk with a diameter of 120 mm. The sample 21 is acquired by laminating the first ultraviolet-curing resin layer 5 and the second ultraviolet-curing resin layer 6 on and under the first substrate 2, and further laminating the first stamper 10 on the bottom surface of the first ultraviolet-curing resin layer 5 and the second stamper 11 on the top surface of the second ultraviolet-curing resin layer 6.
A PC film with a thickness of 25 μm was used for the first substrate 2. A polycarbonate resin was used for the first stamper 10 and the second stamper 11. The first stamper 10 and the second stamper 11 have recesses and projections with a depth of 64 nm
The first ultraviolet-curing resin layer 5 was formed by applying a resin to be discussed later in an annular region extending from a position away from the rotational center of the sample 21 by the length of R1 in a radial direction to the periphery thereof by spin coating. The second ultraviolet-curing resin layer 6 was formed by applying a resin to be discussed later in an annular region extending from a position away from the rotational center of the sample 21 by the length of R2 in a radial direction to the periphery thereof by spin coating. Both of the first and second ultraviolet-curing resin layers 5, 6 have a thickness of 1 μm.
The resins for forming the first and second ultraviolet-curing resin layers 5, 6 have compositions as given in Table 1. As apparent from Table 1, the ratio of the fluorine-contained monomer content in the resin for forming the first ultraviolet-curing resin layer 5 is set smaller than the ratio of the fluorine-contained monomer content in the resin for forming the second ultraviolet-curing resin layer.
Samples 21 with the difference (R2−R1) between the length of R2 in a radial direction and the length of R1 in a radial direction being varied were prepared, and subjected to an experiment in which the first and second stampers 10, 11 were peeled from each sample 21. A 180-degree peeling tester conforming to BS K-6854-2 was used in the test. Table 2 shows the results.
It is apparent from Table 2 that in the case of peeling from the first stamper 10, the second stamper 11 is peeled at the same time, regardless of the value of R2−R1. In the case of peeling from the second stamper 11, on the other hand, the first stamper 10 is peeled at the same time when the value of R2−R1 is in the range of 0 to 0.4 mm, while only the second stamper 11 can be peeled when the value of R2−R1 becomes 0.5 mm or greater.
Resins shown in Table 3 were formed as the resins for forming the first and second ultraviolet-curing resin layers 5, 6 of the same sample 21 as the Example 1, and the comparative example was compared with the Example 1.
As in the Example 1, samples 21 with the difference (R2−R1) between the length of R2 in a radial direction and the length of R1 in a radial direction being varied were prepared, and subjected to an experiment in which the first and second stampers 10, 11 were peeled from each sample 21. A 180-degree peeling tester conforming to JIS K-6854-2 was used in the test. Table 4 shows the results.
It is understood from Table 4 that in the case of peeling from the first stamper 10, the second stamper 11 is peeled at the same time, regardless of the value of R2−R1, as per the Example 1. In the case of peeling from the second stamper 11, on the other hand, tendency similar to that of the Example 1 was observed. That is, only the second stamper 11 was peeled easily when the value of R2−R1 was 0.5 mm or greater, but part of the first stamper 10 was peeled when the value of R2−R1 was 1 mm and 15 mm. The results show that it is difficult to safely peel only the second stamper 11 by merely varying the value of R2−R1.
The advantages of the invention were checked using a sample 22 as shown in
The sample 22 is a disk with a diameter of 120 mm, and is acquired by laminating the third ultraviolet-curing resin layer 7 on and under the third substrate 9, and further laminating the first block 12 on the bottom surface of the third ultraviolet-curing resin layer 7 laminated under the third substrate 9, and the second block 13 on the top surface of the third ultraviolet-curing resin layer 7 laminated above the third substrate 9.
A PC film with a thickness of 25 μm was used for the third substrate 9. A resin essentially consisting of acrylic ester free of a fluorine-contained monomer was used for the resin for forming the third ultraviolet-curing resin layer 7.
The same bases of the Example 1 were used from the first substrate 2 and the first stamper 10 both constituting the first and second blocks 12, 13.
The resins for forming the first and second ultraviolet-curing resin layers 5, 6 of the first and second blocks 12, 13 have compositions given in Table 5.
As apparent from Table 5, the ratio of the fluorine-contained monomer content in the resin for forming the first ultraviolet-curing resin layer 5 of the first block 12 is set smaller than the ratio of the fluorine-contained monomer content in the resin for forming the first ultraviolet-curing resin layer 5 of the second block 13.
The first ultraviolet-curing resin layer 5 of the first block 12 is formed from a position away from the rotational center of the first substrate 2 by a length of R31 in a radial direction, and the first ultraviolet-curing resin layer 5 of the second block 13 is formed from a position away from the rotational center of the first substrate 2 by an length of R11 in a radial direction. Since the length of R31 in a radial direction is smaller than the length of R11 in a radial direction, the area of the first ultraviolet-curing resin layer 5 of the first block 12 is larger than the area of the first ultraviolet-curing resin layer 5 of the second block 13. Therefore, adhesion strength F31 of the first ultraviolet-curing resin layer 5 of the first block 12 to the first stamper 10 is greater than adhesion strength F11 of the first ultraviolet-curing resin layer 5 of the second block 13 to the first stamper 10.
An experiment of peeling the first stamper 10 from the second block 13 was conducted using a 180-degree peeling tester conforming to JIS K-6854-2. It was confirmed that only the first stamper 10 of the second block 13 could be peeled without peeling the first stamper 10 from the first block 12.
This application is based on Japanese Patent Application No. 2009-088430 filed on Mar. 31, 2009. The specification, claims, and drawings of Japanese Patent Application No. 2009-088430 are incorporated herein by reference in their entirety.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2009-088430 | Mar 2009 | JP | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/JP2010/053669 | 3/5/2010 | WO | 00 | 9/30/2011 |
| Publishing Document | Publishing Date | Country | Kind |
|---|---|---|---|
| WO2010/113592 | 10/7/2010 | WO | A |
| Number | Name | Date | Kind |
|---|---|---|---|
| 6821460 | Kerfeld et al. | Nov 2004 | B2 |
| Number | Date | Country |
|---|---|---|
| 64-070939 | Mar 1989 | JP |
| 07-121912 | May 1995 | JP |
| 09-091265 | Apr 1997 | JP |
| 10-283682 | Oct 1998 | JP |
| 2007-018569 | Jan 2007 | JP |
| 2008-159175 | Jul 2008 | JP |
| Entry |
|---|
| International Search Report—PCT/JP2010/053669—Apr. 6, 2010. |
| Number | Date | Country | |
|---|---|---|---|
| 20120021160 A1 | Jan 2012 | US |
