Patent Application
20050139146
This application claims the benefit priority of European Patent Application Number 03293332.7 filed Dec. 24, 2003.
The invention is directed to optical fluoride crystals suitable for making optical elements used in the transmission of wavelengths below 200 nm, and in particular to a method of making such crystals by the use of sized particles of a selected optical fluoride premelt material.
The burden of the demands for improved performance of computers and other electronic devices falls on the lithographic processes used to fabricate integrated circuit chips. Lithography involves irradiating a mask and focusing the pattern of this mask through an optical microlithography system onto a wafer coated with a photoresist. The pattern on the mask is thereby transferred onto the wafer. Decreasing the line-widths of the features on a given wafer enables the writing on a wafer of more elements per unit area and consequently brings about advances in performance. The enhanced resolution required to achieve finer line-widths is enabled by decreasing the wavelength of the illumination source. As a result of the desire to achieve finer line widths, the energies used in lithographic patterning are moving deeper into the UV region. Consequently, optical components capable of reliable performance at these increasingly shorter optical microlithography wavelengths are required.
Few materials are known that have a high transmittance at wavelengths below 200 nm, for example, at 193 nm and 157 nm, and also do not deteriorate under exposure to intense laser radiation. Fluoride crystals such as those of magnesium fluoride, calcium fluoride and barium fluoride are potential materials with high transmittance at wavelengths <200 nm. Calcium fluoride crystals are particularly preferred for making optical elements for use at below 200 nm wavelengths. However, the commercial use and adoption of below 200 nm wavelengths has been hindered by the transmission nature of such deep ultraviolet wavelengths through optical materials and by the lack of economically manufacturable, high quality blanks of optically transmissive materials suitable for below 200 nm microlithography optical elements. Many factors go into making metal fluoride crystals and elements suitable for use in below 200 nm lithography. One of these is the purity of the metal fluoride starting material used to make a metal fluoride single crystal and subsequently an optical element.
The transmission of a metal fluoride crystal is greatly dependent on the purity of the starting material. Commercially available raw material powders are sufficiently pure in terms of cationic impurities, but these materials are not sufficiently pure in terms of the anionic impurities they contain. In order to remove these anionic impurities, mainly oxygen containing species, a purification step is carried out using a gaseous or a solid oxygen scavenger, or both, such as known in the art. Examples of such scavengers are solid lead fluoride (PbF2), zinc fluoride (ZnF2) or gaseous carbon tetrafluoride (CF4). There are numerous patents and technical articles whose authors discuss the detrimental effects of water and oxygen, and the necessity for adding an oxygen scavenger to remove these contaminants. For examples, see J. M. Ko et al., “Czochralski growth of UV grade CaF2 single crystals using ZnF2 additive as scavenger”, J. Crystal Growth 222 (2001) 243-248 [with references to the use of PbF2 and CF4 as scavengers]; R. C. Pastor, “Crystal growth of metal fluorides for CO2 laser operation. I. The necessity of the RAP approach”, J. Crystal Growth 200 (1999) 510-514, and “Crystal growth of metal fluorides for CO2 laser operation. II. Optimization of the reactive atmosphere process (RAP) choice.”, J. Crystal Growth 203 (1999) 421-424; and J. T. Mouchovski et al., “Growth of ultra-violet grade CaF2 crystals and their application for excimer laser optics.”, J. Crystal Growth 162 (1996) 79-82. See also U.S. Pat. Nos. 4,379,733 and 6,238,479, and European Patent Application Publication No. EP 0 995 820 A1.
In a process for removing oxygen-containing anionic impurities from a metal fluoride raw material, a metal fluoride powder is melted in the presence of an oxygen scavenger. The scavenger reacts with the oxygen containing species and converts it to a fluoride material. The resulting melt or liquid is then quickly cooled down in order to obtain a purified, high density metal fluoride material that will be used in crystal growth furnaces to fabricate the desired metal fluoride crystal. This specific purification-melting process of the raw material powder is generally called a “premelt” step or “cullet” production.
For below 200 nm lithographic optical material the quality of the premelt material may be quantified by determining the transmission characteristics of the premelt material in the wavelength range of 120-220 nm. In the absence of specific absorptions in VUV range at 130 nm, 150 nm and 193 nm, the premelt material is characterized as being an oxygen-free or substantially oxygen free material and hence suitable for making metal fluoride single crystals. Once the premelt's suitability for use in growing crystals has been determined, the premelt material is broken into pieces or ground into fine particles and loaded into crucibles that are placed in a crystal growth furnace. However, if the oxygen-free premelt material has been loaded into the crucible without the addition of an oxygen scavenger, or if the crystal growth is carried out in the absence of a gaseous oxygen scavenger, the crystal produced in the growth furnace will exhibit the characteristic oxygen absorption bands in the 120-220 nm range. The presence of these bands indicates that the oxygen-free premelt material has been re-contaminated by the formation of oxygen containing substances during handling or during the crystal growth process. The sources of contamination can be oxygen containing substances (for example, H2O, O2, CO2 and other oxygen containing species) adsorbed on the surface of the premelt particles while they are being prepared for the crystal growth process or they can come from oxygen containing substances released from the materials used to make either the furnace or the components used in the crystal growth process. For example, the oxygen containing substances can be released from the crucibles, heating elements, and insulating parts of the furnace among others. In any event, when the furnace is heated in the absence of an oxygen scavenger, metal fluoride premelt material fluoride reacts with these oxygen containing substances and this in turn gives rise to a low transmittance crystal. For example, if water vapor is released from the insulation, the vapor can react with the metal fluoride to form a hydroxy metal fluoride. For example, CaF2+H2O→Ca(OH)F+HF↑ or CaO+2HF↑.
While the use of an oxygen scavenger during the crystal growth process can alleviate the oxygen contamination problem, such use can give rise to additional problems. For example, one must estimate the amount of contaminants present in the material and use sufficient scavenger to remove all of it. This is frequently difficult to determine. As a result, excess oxygen scavenger is used in the crystal growing process. While the use of excess scavenger does not present problems when the scavenger is gaseous, when a solid scavenger such as PbF2 is used, the excess of scavenger could result in lead contamination of the grown crystal. If insufficient scavenger is used, then residual oxygen containing substances may be present in the grown crystal and these substances will absorb radiation in the 120-220 nm region, and consequently interfere with the transmission properties of the crystal and optical element made from it. Transmission of 96%/cm or greater at 157 nm and 99%/cm or greater at 193 nm of incident radiation is required for elements used in below 200 nm lithography.
Therefore, in view of the foregoing problems it is desirous to be able to identify metal fluoride materials that have characteristics that minimize the adsorption or presence of oxygen containing materials and to find a method of producing such materials.
The invention is directed to a method for making metal fluoride single crystals suitable for use in below 200 nm lithographic equipment and processes. In one aspect the invention is directed to a method comprising:
In one embodiment the oxygen scavenger is a solid oxygen scavenger added to the metal fluoride materials when it is placed in the crystal growth crucible.
In another embodiment a gaseous oxygen scavenger is used in addition to the solid oxygen scavenger and the gaseous oxygen scavenger is admitted into the furnace after the drying step and while the particles are being heated to a temperature in the range of 50-250° C. below the melting point of the metal fluoride, and the temperature is held at 50-250° C. below the metal fluoride's melting point for a period in the range of 4-48 hours. When using a gaseous oxygen scavenger the pressure within the furnace is increased from 10−6 mBar (vacuum state) to approximately 1000 mBar during the scavenging (or fluorinating) step. Once this step has been completed the pressure within the furnace is reduced to 10−6 mBar (vacuum conditions) and the process proceeds to the melting, crystal growing and cooling steps as described above. Alternatively, an inert gas for example, helium, argon or nitrogen) can be admitted and the melting, crystal growing and cooling steps carried out at atmospheric pressure.
In yet another embodiment the oxygen scavenging is conducted using only a gaseous oxygen scavenger as described in the paragraph above, including increasing the pressure within the furnace to approximately 1000 mBar. The steps after oxygen scavenging (the melting, crystal growing and cooling steps) remain the same, including reducing the pressure within the furnace to 10−6 mBar. When only a gaseous oxygen scavenger is used, the time scavenging (fluorinating) step time may be increased to a range of 4-96 hours to maximize the removal of oxygen containing species.
The method of the invention can further comprise making a premelt material that is ground and sieved, or otherwise separated into particles substantially all of which have a size of 1 mm or greater (for example, using cyclone separation), and using such particles in the growth crucible to make a metal fluoride single crystal suitable for use in below 200 nm lithographic equipment and processes. The method comprises:
In one embodiment the oxygen scavenger in the crystal growth steps is a solid oxygen scavenger added to the sieved, or other separated, metal fluoride materials having a size of 1 mm or greater when it is placed in the crystal growth crucible.
In another embodiment a gaseous oxygen scavenger is used in the crystal growth steps in addition to the solid oxygen scavenger and the gaseous oxygen scavenger is admitted into the furnace after the drying step and while the particles are being heated to a temperature in the range of 50-250° C. below the melting point of the metal fluoride, and the temperature is held at 50-250° C. below the metal fluoride's melting point for a period in the range of 4-48 hours. When using a gaseous oxygen scavenger the pressure within the furnace is increasing from 10−6 mBar (vacuum state) to approximately 1000 mBar during the scavenging (or fluorinating) step. Once this step has been completed the pressure within the furnace is reduced to 10−6 mBar (vacuum conditions) and the process proceeds to the melting, crystal growing and cooling steps as described above. Alternatively, an inert gas (for example, helium, argon or nitrogen) can be admitted and the melting, crystal growing and cooling steps carried out at atmospheric pressure.
In yet another embodiment the solid scavenger is omitted and the entire oxygen scavenging during the crystal growth steps is conducted using a gaseous oxygen scavenger as described in the paragraph above, including increasing the pressure within the furnace to approximately 1000 mBar. The steps after oxygen scavenging (the melting, crystal growing and cooling steps) remain the same, including reducing the pressure within the furnace to 10−6 mBar. When only a gaseous oxygen scavenger is used, the time scavenging (fluorinating) step time may be increased to a range of 4-96 hours to maximize the removal of oxygen containing species.
In practicing the invention the metal fluoride particles are used, and substantially all of the particles have a size of 1 mm or greater are used. The metal fluoride material is treated with an oxygen scavenger to remove oxygenated impurities, liquefied and cooled to form a metal fluoride single crystal having improved properties for below 200 nm lithographic processes. The particles of 1 mm or greater size can be prepared by any method known in the art; for example, as described herein or as described in U.S. Pat. No. 6,451,106 B1.
In another aspect of the invention the particles are separated to have a size in the range of 1-10 mm and the 1-10 mm particles used to grow metal fluoride single crystals suitable for use as optical elements in below 200 nm lithographic equipment and processes. In a preferred embodiment the particles are separated into a size in the range of 1-7 mm and the 1-7 mm particles are used to grow an optical fluoride crystal.
The method is used to make single crystals of calcium fluoride, barium fluoride, magnesium fluoride and strontium fluoride, and can also be used to make single crystals containing mixtures of the foregoing metals. In addition, the method is also used to make crystals in which any of the crystals of the previous sentence also contains lanthanide series metal fluorides, lithium fluoride, potassium fluoride and sodium fluoride, either alone or in combination.
The invention is also directed to a metal fluoride single crystal suitable for making <200 nm lithography elements, said crystal being made by any of the methods described herein and in the claims.
The invention will now be described in detail with reference to a few preferred embodiments and the accompanying figures. In the following description numerous details are set forth in order to provide a thorough understanding of the invention. However, it will be apparent to one skilled in the art who reads this specification that the invention may be practiced without some of these specific details. In addition, well-known features and/or process steps have not been described in detail in order to not unnecessarily obscure the invention.
As used herein, the term “metal fluoride” means a fluoride of general formula MF2, where M is calcium, barium, magnesium or strontium, and includes mixtures of the foregoing metals. Also as used herein, the terms “metal fluoride crystal” and “metal fluoride single crystals” are synonymous and should be understood to also include optical blanks and optical elements made from such crystals, for example, lenses, laser chamber windows, prisms and other optical elements.
Below 200 nm lithographic systems such as those operating at 193 nm and 157 nm require the use of lenses and other optical elements made from metal fluorides of general formula MF2, where M is calcium, barium, strontium or magnesium, or mixtures thereof. Calcium fluoride (CaF2) is a particularly preferred material for optical elements in below 200 nm lithographic systems. While calcium fluoride is used in the detailed description that follows to exemplify the invention, the invention is not restricted to calcium fluoride, but also includes barium fluoride, magnesium fluoride and strontium fluoride, and mixtures of such metal fluorides.
Generally, metal fluoride particles, substantially all of which have a size of the 1 mm or greater, are used to prepare a single crystal in accordance with the invention. These particles can be made by any method known in the art; for example, as in U.S. Pat. No. 6,451,106 that describes the preparation of metal fluoride beads. The 1 mm or greater particles can also be prepared from an ingot of metal fluoride material as described below.
In order for a metal fluoride crystal, or element made therefrom, to be used in below 200 nm lithographic systems, and specifically 193 and 157 nm, the crystal transmission must be higher than 96%/cm or greater at 157 nm and 99%/cm or greater at 193 nm. As stated above, the transmission of the crystal is greatly dependent of the purity of the starting material. While raw material powders that are sufficiently pure in terms of cationic impurities are commercially available, they are not sufficiently pure in terms of their anionic impurities. In order to remove these anionic impurities, mainly oxygen related species; a purification step is carried out that uses a solid or gaseous oxygen scavenger to remove the oxygenated species. Examples of such scavengers include lead fluoride (PbF2), stannous fluoride (SnF2), zinc fluoride (ZnF2), xenon difluoride (XeF2), fluorinated and/or chlorofluoro hydrocarbons such as carbon tetrafluoride (CF4), tetrafluorethylene (C2F4) and hexafluoroethane (C2F6), and other oxygen scavengers known in the art. The raw powder is heated in the presence of the oxygen scavenger for a time and at temperatures known in the art to remove the oxygenated impurity. (See U.S. Patent Application Publications 2002/0160177 and 2003/0089304 whose teaching are incorporated herein by reference.) Subsequently, the purified raw material is melted in situ and the resulting metal or liquid quickly cooled down to obtain a purified high density premelt that can be used as the starting material in crystal growth furnaces to fabricate the desired metal fluoride single crystal. This specific purification-melting process of the raw material powder is generally called a “premelt” step or “cullet” production.
In accordance with the invention, the premelt material or mass is then ground or otherwise converted into particles and, instead of being directly loaded into a crystal growth furnace, the ground material is sieved, or otherwise separated, to remove particles having a particle size less than, for example, 1 mm. The grinding can be done by any method known in the art. For example, the premelt mass can be hammered into pieces and/or particles, or the premelt mass can first be hammered into pieces and the size of the pieces further reduced by passage through one or more sets of rollers. Typically, metal hammers and rollers are used in this process. However, in order to avoid metal contamination of the premelt materials, the hammers and rollers can be coated with a suitable material. For example, the hammer or rollers can be coated with a polymeric material, preferably a partially or fully fluorinated polymeric material. If any of the fluorinated material becomes admixed with the processed premelt, it can serve as an oxygen scavenger during the subsequent crystal growth process.
Once the particles have been reduced in size they are sieved, or otherwise separated, to separate particles of different sizes. For example, in accordance with the invention it is desirable to use particles substantially all of which have a size greater than 1 mm. Accordingly, the ground premelt material is sieved using a sieve that will retain particles greater than 1 mm and allow particles less than 1 mm to pass through. Alternatively, a combination of sieves can be used to separate and collect particles in having a range of sizes; for example, particles in the range of 1-10 mm. In this instance a first sieve is used that will retain particles greater than 10 mm and allow particles less than 10 mm to pass through, and a second sieve is used that will retain particles greater than 1 mm and allow particles less than 1 mm to pass through. If one wants further separation according to particle size, one can include other sieves to further separate the particles in to different ranges; for example, greater than 10 mm, 5-10 mm, 1-5 mm and less than 1 mm. The ground particles can also be separated by other method known in the art, for example cyclone separations. If a cyclone separator is used to separate the particles, it is preferred that the separation be carried out using a dried gas. In addition, it is preferred that the surfaces of the cyclone be pre-dried prior to the separation. This can be done by passing a hot dried gas through the cyclone prior to its being used for the particle separation. A hot gas including an oxygen scavenging gas can also be used to dry the cyclone.
In practicing the invention it is advantageous to use a sieved material, or material prepared by other methods such as U.S. Pat. No. 6,451,106 patent, containing a range of particle sizes in order to pack the growth crucible as densely as possible. For example, instead of using a sieved material having particle sized in the range of 1-10 mm, one can use a sieved material having particle sizes in the range of 1-7 mm, preferably in the range 1-5 mm, because one can pack the growth crucible with a greater weight of material and hence utilize the volume of the crucible more efficiently by reducing the interstitial void volume between the particles. For a crucible of given diameter and volume one is thus able to grow a thicker crystal. However, restricting particles to the size range 1-7 mm and/or 1-5 mm is not an absolute requirement, and larger particles can be used. In the extreme limit one would not grind the premelt material and use it directly. However, one must take into account the difference in the coefficient of thermal expansion between the crucible (graphite or other material) and the CaF2 premelt material to avoid fracturing the crucible during processing.
The sieved particles are loaded into a crucible and the crucible is placed in a crystal growth furnace where the particles are melted and used to grow a metal fluoride single crystal by methods known in the art; for example, the Stockbarger, Bridgman-Stockbarger and Czochralski methods, and the methods described in U.S. Pat. Nos. 6,630,117, 6,395,657, and 6,333,922 B1. An oxygen scavenger, solid or gaseous, or a combination of both, is used in conjunction with the sieved premelt particles. A solid oxygen scavenger is typically mixed with the particles before they are placed in the crucible. If the sieved premelt particles are used without adding an oxygen scavenger (either as a solid material mixed with the particles, or a gaseous material added during the process, or both) the resulting single crystals will have a transmission curve having the characteristic oxygen absorption bands. This is a result of the premelt being re-contaminated by oxygen containing substances during the growth process. As has already been mentioned, the sources of contamination can be oxygenated substances adsorbed on the surface of metal fluoride premelt particles during grinding and other handling, or coming from materials within the furnace, for example, the crucibles, heating elements and insulating materials. When the furnace and crucible containing the premelt materials is heated in the absence of an oxygen scavenger, calcium fluoride or other metal fluoride reacts with the oxygen containing substances and gives rise to a low transmittance crystal product.
The total quantity of oxygen containing substances trapped in the furnace is dependent of the properties of the materials used in making the furnace and equipment used therein; for example, the carbon materials used for the crucible and the furnace insulation. In addition, the total quantity is dependent on the amount of oxygen containing substances adsorbed on the ground premelt, and this amount is dependent on the premelt particles' total surface area. The reactivity of the premelt with gases produced by the furnace is also greatly dependent on its total surface area (“TSA”). The concentration of oxygen scavenger that is added to the premelt when it is charged to the crucible or otherwise added to the furnace during the growth process will vary with the TSA of the initial ground premelt. This complicates the overall process. Generally, the concentration of the oxygen scavenger is higher than necessary and longer holding times for the fluorination step of the growth process are used to overcome any re-contamination of the premelt material that may have occurred. However, this increases the manufacturing time and can result in contamination of the grown crystal by the oxygen scavenger itself, neither of which are desirable and both of which are costly.
The “fine” particles in a ground premelt (for example, particles less than 1 mm in size) have a high TSA. These fine particles contribute significantly to oxygen contamination of the CaF2 product because their large total surface area is capable of adsorbing a significant amount of a contaminant such as water vapor that can subsequently react with the metal fluoride surface to produce species such as Ca(OH)F or CaO on the surface and lead to incorporate oxygen ions into the fluoride crystalline structure. In order to maximize the transmission at 193 nm and 157 nm, the present invention teaches that the metal fluoride premelt particles used to grow a metal fluoride single crystal for optical lithography use should have a particle size that is 1 mm or larger. That is, “fines” of less than 1 mm in size should be removed from the ground premelt material before it is used to grow a single metal fluoride crystal. The advantage of using larger premelt particles for crystal growth is that the total particle surface area is decreased, resulting in less water (and other oxygen containing species like O2, CO2, . . . ) being adsorbed during handling. When this is done metal fluoride crystals having a higher transmission are produced.
Assuming that the ground premelt CaF2 particles will have a cubic or spherical shape, with no porosity and no roughness, the TSA for a given weight of particles can be calculated using Equation 1:
TSA=6/da Equation 1
The theoretical total surface area for different calcium fluoride premelt particle sizes is reported in Table 1. In reality, one must consider that the particles formed during grinding the premelt are not perfect cubes or spheres and that their surfaces develop roughness. Consequently, the experimental TSA, which could be measured using physisorption (with N2 or Kr adsorbate, the latter being preferred), is a little higher than the theoretical estimate given by Equation 1. Nevertheless, Equation 1 gives a correct order of magnitude of the total surface area.
As shown in Table 1, particles of 1 mm size have a TSA of approximately 0.0019 m2/g or less.
In order to exemplify the invention, a premelt material was ground and sieved in order to separate particles according to pre-selected size ranges. Table 2 shows the particle size ranges that were collected by sieving and the distribution in weight % of particles within each size range.
Particles with a selected size have then been used to grow crystals. Experimental conditions are the same for each preparation (run). Specifically, the total quantity of CF4, the oxygen scavenger, is the same for each run as are the time and temperature conditions under which the crystals were grown. The difference in results from run-to-run lies in the size distribution of the premelt particles that were used to make the crystals. The size distributions of the particles used in each run are as follows:
Using
The crucibles containing the premelt particles are placed in a crystal growth furnace and heated in accordance with a crystal growth procedure as described below. During the heating of the furnace, the oxygenated species physisorbed (water, oxygen, carbon dioxide) and chemisorbed (chemical groups containing O atoms) on the surface of the CaF2 particles will desorb and react with CaF2. It is known that oxygen incorporation in fluorides occurs preferentially by a mechanism of hydrolysis rather than oxidation. Very low partial pressure of water gas is sufficient to catalyse the diffusion of oxygen into fluorides. The quantity of oxygenated molecules desorbed in the furnace atmosphere increases when the TSA of the CaF2 powder introduced in the crucible increases (proportionality relationship). It is possible to experimentally quantify these desorption differences using either (1) Temperature Programmed Desorption coupled to a Mass Spectrometer or (2) Infra-Red analysis.
The crystals grown in Runs 1-3 were made in a two heating zone furnace using the Bridgman-Stockbarger technique. The grown crystal dimensions have a 95 mm diameter and a height of 55 mm.
A graphite crucible containing a sieved premelt material was placed in a furnace and the furnace was heated while maintaining a vacuum (10−6 mBar) to a temperature of approximately 1200° C., which is below the melting point of calcium fluoride (mp=1418° C., Handbook of Physics & Chemistry 76th Ed., CRC Publishing, 1995-97). During the heating period the temperature was raised held at plateaus of 300° C. and 500° C. over a five hour period while vacuum was maintained. This was done in order to remove water adsorbed on graphite crucible, any carbon or graphite furnace elements, other elements present in the furnace and the calcium fluoride particles (the drying step). After the drying step the temperature was increased to 1200° C. at a rate of 100° C./hour, still under vacuum. Once 1200° C. was reached, a gas mixture of argon, or other inert gas, and CF4 was introduced into the furnace (the fluorination step). The CF4 gas reacts with any oxides of calcium that may be present due to hydrolysis of CaF2; for example, CaO, Ca(OH)2 or Ca(OH)F. During the foregoing steps the pressure in the furnace is slowing increasing to approximately 1000 mBar. With the introduction of the scavenger containing gas, the fluorination or conversion of the oxides of calcium was carried out under dynamic conditions in which the CF4 containing gas, 1 vol. % in an inert gas, was flowed through the furnace at atmospheric pressure. (For the preparation of crystals described herein, the CF4 and argon were sourced from separate gas cylinders and were flowed into the furnace at a rate of 300 sccm Ar and 3 sccm CF4). The fluorination step was carried out for 5 hours at a temperature of 1200° C. Once the fluorination is completed, the furnace atmosphere is switch back to 10−6 mBar and the temperature of the CaF2 material is raised to its melting point and a crystal is grown according to the according to methods known in the art. The growth of crystals of selected orientation, for example, a <111>, <110> or <100> crystal can be done by using a crucible having a reservoir in its bottom into which a <111> seed crystal is placed.
The VUV measured transmission of the crystals produced in Runs 1-3 is shown in
The transmission data in
To improve the transmission, residual small particles have to be eliminated and the CF4 total quantity increased (total quantity=% CF4 x time). This means an increase in CF4 concentration or/and holding time at 1200° C. The advantage to use low TSA premelt is the minimization of the oxygen content introduced in the crucible. The probability of obtaining a high UV transmittance crystal is thereby improved. This is demonstrated for the utilization of CF4, and it should be the same for the utilization of solid fluorinating agents such PbF2, ZnF2 and others known in the art. The crystals of Runs 2 and 3 would not be acceptable for deep UV applications, nor could the crystals of these runs be ground and polished into acceptable crystals or made into acceptable optical elements. They will not resist the 193 nm or 157 nm laser flux, and they present induced absorptions in the UV-Visible range of electromagnetic radiation.
For a constant concentration of oxygen scavenger in the process, the contamination by oxygen is increasing with the TSA of the loaded ground premelt. This contamination in oxygen is related to oxygenated species adsorbed on the surface of the premelt and then desorbing in the furnace during heating. When the TSA of the ground premelt increases, the quantity of adsorbed oxygen containing substances can be higher and the reactivity of the premelt material with the adsorbed substances increases. That is, the efficiency of the contaminant formation process is higher with a high TSA premelt powder, giving rise to a strongly contaminated material. As shown in
The foregoing examples of specific compositions, processes, articles and/or apparatus employed in the practice of the present invention are, of course, intended to be illustrative rather than limiting, and it will be apparent that numerous variations and modifications of these specific embodiments may be practiced within the scope of the appended claims.
Any discussion of the background to the invention herein is included to explain the context of the invention. Where any document or information is referred to as “known”, it is admitted only that it was known to at least one member of the public somewhere prior to the date of this application. Unless the content of the reference otherwise clearly indicates, no admission is made that such knowledge was available to the public or to experts in the art to which the invention relates in any particular country (whether a member-state of the PCT or not), nor that it was known or disclosed before the invention was made or prior to any claimed date. Further, no admission is made that any document or information forms part of the common general knowledge of the art either on a world-wide basis or in any country and it is not believed that any of it does so.
| Number | Date | Country | Kind |
|---|---|---|---|
| 03293332.7 | Dec 2003 | EP | regional |
