The present invention relates to a method for producing a multi-layer substrate, said substrate comprising a multifunctional coating, and to the use of the substrate produced by this method.
The Internet as a distribution channel for goods of all kinds has become increasingly important in recent years. Clothing, electronics, computers and shoes make up the largest share of goods sold on the Internet, but household goods, furniture and interior furnishings as well as everyday goods such as food, drugstore items and pet supplies are increasingly being purchased via the Internet. In order for the goods to reach the customer, not only complex logistics are required, but also safe transport so that sensitive or fragile goods arrive at the customer without damage.
Safe packaging of the goods can be achieved, for example, with the aid of suitable packaging material, the packaging material generally having a type of padding by which the goods to be transported are protected. A classic example of such a packaging material is an air cushion film, that is to say a plastic film which has pockets filled with air, by means of which mechanical vibrations can be cushioned. However, these bubble wrap films have the disadvantage that they are usually made from petroleum-based plastics and their production and disposal involve major ecological interventions. This problem is exacerbated in view of the increasing need and the increasing desire for sustainability. There is therefore a need for alternative packaging materials that have the same properties but show better environmental compatibility.
WO 2014/051876 describes an adhesive composition which is used for producing packaging materials, the adhesive composition having microspheres which have an insulating effect.
DE 20 2011109 020 describes a composite body consisting of a carrier substrate made of natural fibers and at least one bonded substrate layer made of a flexible film-shaped substrate, which are completely bonded to a dried adhesive layer, the adhesive layer being produced from an aqueous foamed adhesive.
WO 2010/129493 discloses an inflatable mailing bag that has an inflatable liner and a connector through which the liner can be inflated.
The materials described in the prior art are generally only accessible through complex production processes, as a result of which the amount that can be produced is limited. Furthermore, the conventional materials have the disadvantage that they have a large volume due to the cushion layer introduced, which can cause high costs, in particular when the material is transported and stored.
The object of the present invention is therefore to provide a method which allows the production of a packaging material which can absorb mechanical shocks and can be easily stored and transported.
It has surprisingly been found that this object is achieved by a method for producing a multi-layer substrate which has a multifunctional coating.
A first object of the present invention is therefore a method for producing a multi-layer substrate comprising the following steps:
It has surprisingly been found that a substrate with a small volume is accessible in this way. The method according to the invention is further characterized in that it allows the substrate to be produced in large quantities and can be carried out without the need for complex modifications to the device used.
In a preferred embodiment, the first material has more than one inner region.
The coating material is preferably applied over the entire surface. For the purposes of the present invention, this is to be understood to mean application in such a way that the entire inner region is covered with the coating material. In order to save costs and material, it can be advantageous to apply the coating material intermittently or only partially, so that the inner region is not completely covered. An alternative embodiment is therefore preferred, in which the coating material is partially applied to the inner region.
In a preferred embodiment, the contacting of the first and the second material takes place using an adhesive. The adhesive is preferably applied to the edge region of the first surface before the contacting of the first and the second material. The adhesive is particularly preferably applied uniformly or continuously to the edge region of the first surface, so that the edge region is completely covered with the adhesive. It has surprisingly been found that the composite adhesion of the materials in the substrate can be improved in this way without the performance of the coating material being impaired. The advantages of the method according to the invention come to full development when it is ensured that no adhesive gets onto the inner region.
In a preferred embodiment of the method according to the invention, the first and the second material are provided in the form of continuous webs. In an alternative preferred embodiment, the first material is divided into individual units before or after application of the coating material, which have an edge region and an inner region enclosed by the edge region. In an alternative preferred embodiment, the division of the first material and the application of the coating material to the inner region take place simultaneously. In terms of process technology, the cutting is combined with the application of the coating material and is preferably carried out in a combined step.
In a preferred embodiment, the first material is selected from the group consisting of material based on cellulose, plastic and metal. The first material can have synthetic fibers, for example, in order to increase the stability of the material.
The first material is particularly preferably a material based on cellulose. In particular, the first material is selected from the group consisting of paper, cardboard and coated paper.
In a preferred embodiment, the second material is selected from the group consisting of material based on cellulose, plastic and metal. The second material can have synthetic fibers, for example, in order to increase the stability of the material.
The second material is particularly preferably a material based on cellulose. In particular, the second material is selected from the group consisting of paper, cardboard and coated paper.
In a preferred embodiment, the first and second materials are paper. The second material is particularly preferably present in the form of a continuous web.
The method according to the invention is distinguished by its rapid process control, which allows large quantities of the multi-layer substrate to be produced in a short time. This is achieved, among other things, by carefully coordinating the properties of the materials used. Therefore, an embodiment of the present invention is preferred in which the drying of the coating material is carried out at a temperature of 80° C. or less, preferably at a temperature of 40° C. to 75° C. It has surprisingly been found that rapid drying is achieved at these temperatures without the performance of the coating material being impaired, as a result of which the process throughput is improved.
The best results in terms of process throughput were achieved when a polymer-based coating material was used. An embodiment is therefore preferred in which the coating material is a polymer-based coating material which has 10 to 40 wt. %, preferably 15 to 35 wt. % of expandable microparticles, in each case based on the total weight of the coating material. It has surprisingly been found that such a coating material can be applied at a high speed, but at the same time has sufficient stability so that it does not run after application.
The coating material used in the method according to the invention has expandable microparticles. The microparticles preferably have a particle size, expressed as a D50 value, of 5 to 18 μm, preferably 10 to 17 μm, in the unexpanded state.
The expandable microparticles are preferably thermally expandable microparticles, which preferably have the shape of spheres.
In a preferred embodiment of the method according to the invention, the multi-layer substrate is converted into packaging in a further step. This implementation can take place, for example, by cutting and folding the multi-layer substrate. The packaging is preferably an envelope, a mailing bag, a bag, a carrier bag, a pouch or a carton, the format and size being variable. In a particularly preferred embodiment, the packaging is a mailing bag.
In a preferred embodiment, the method according to the invention comprises a further step in which the multi-layer substrate is subjected to a treatment for expanding the expandable microparticles.
In a preferred embodiment, the heat treatment step follows step d) of the method according to the invention.
The method according to the invention allows the production of a substrate, the volume of which can be increased by a heat treatment, wherein this heat treatment can be carried out independently of the production method. In a preferred embodiment, the heat treatment is carried out separately from the other method steps in terms of time and/or location. In this way it is possible to transport and store the substrate in the state of a small volume. The substrate reaches its final volume as a result of the heat treatment, which causes the microparticles of the coating material to expand. The method according to the invention makes it possible to carry out the heat treatment only shortly before the substrate is used, which was not possible with conventional methods described in the prior art. For example, the substrate can be further processed into a mailing bag, which takes up little space due to the small volume and the small thickness. Before the mailing bag is used, it can be subjected to a heat treatment, whereby the microparticles are expanded and the mailing bag develops its desired cushioning effect. In this way, valuable storage and transport capacity can be saved by the method according to the invention.
The heat treatment is preferably carried out at temperatures from 85° C. to 150° C., preferably 90 to 140° C. This ensures that the microparticles fully expand without being damaged and without losing their shock-absorbing effect.
In order to achieve optimal absorption of mechanical influences, it has proven to be advantageous if the microparticles in the expanded state have a particle size in the range from 20 μm to 200 μm. An embodiment is therefore preferred in which the microparticles in the expanded state have a particle size, expressed as a D50 value, of 20 μm to 200 μm, preferably 20 to 150 μm.
The heat treatment is preferably carried out using conventional heat sources. The heat treatment is particularly preferably carried out using infrared radiation and/or warm air.
The multi-layer substrate produced by the method according to the invention is distinguished by its flexible volume. Another object of the present invention is therefore a multi-layer substrate which can be obtained by the method according to the invention. The substrate according to the invention is preferably in the form of a continuous web. In an alternative preferred embodiment, the substrate according to the invention is in the form of a packaging, preferably in the form of an envelope, a mailing bag, a bag, a carrier bag, a pouch or a carton, the format and the size being variable.
The substrate according to the invention can be easily processed into packaging. Another object is therefore a method for producing a package using a multi-layer substrate which has been produced by the method according to the invention, the multi-layer substrate being formed into a package by means of cutting and folding.
Another object of the present application is a package obtainable according to the inventive method. The packaging is preferably an envelope, a mailing bag, a bag, a carrier bag, a pouch or a carton, the format and the size being variable.
The present invention is to be explained in more detail with reference to the following example, which is in no way to be understood as a restriction of the inventive concept.
A suitable coating material can contain 30 to 70 wt-% of VAE copolymer dispersion (Vinamul® 3928), 5 to 15 wt. % of paraffin dispersion (Michemlube® 743 PE), 15 to 30 wt. % of microparticles (Expancel® 031 WUF 40), 5 to 10 wt. % of glycerol and optionally up to a wt. % of hydroxyethylcellulose (MEHC, Natrosol® 250LR), wherein the weight percentages refer to the total weight of the coating material and add up to 100 wt. %.
Number | Date | Country | Kind |
---|---|---|---|
18157071 | Feb 2018 | EP | regional |
Number | Name | Date | Kind |
---|---|---|---|
2147689 | Chaffee | Feb 1939 | A |
2998501 | Edberg et al. | Aug 1961 | A |
3152749 | Young | Oct 1964 | A |
3252064 | Duncan | May 1966 | A |
3253064 | Buonaiuto | May 1966 | A |
3300360 | Williams et al. | Jan 1967 | A |
3342613 | Schelhom | Sep 1967 | A |
3401475 | Morehouse et al. | Sep 1968 | A |
3563851 | Armour et al. | Feb 1971 | A |
3583851 | Harrington et al. | Jun 1971 | A |
3615972 | Morehouse, Jr. et al. | Oct 1971 | A |
3732975 | Poncy | May 1973 | A |
3904429 | Eastman et al. | Sep 1975 | A |
4005033 | Georgeau et al. | Jan 1977 | A |
4006273 | Wolinski et al. | Feb 1977 | A |
4038762 | Swan, Jr. | Aug 1977 | A |
4087002 | Bambara et al. | May 1978 | A |
4094685 | Lester et al. | Jun 1978 | A |
4193499 | Lockholder | Mar 1980 | A |
4350788 | Shimokawa et al. | Sep 1982 | A |
4483889 | Andersson | Nov 1984 | A |
4531038 | Lillibridge | Jul 1985 | A |
4661401 | Akao | Apr 1987 | A |
4690843 | Inagaki | Sep 1987 | A |
4708896 | Akao | Nov 1987 | A |
4720410 | Lundquist et al. | Jan 1988 | A |
4900594 | Quick | Feb 1990 | A |
4925711 | Akao et al. | May 1990 | A |
5030302 | Jud et al. | Jul 1991 | A |
5082744 | Akao et al. | Jan 1992 | A |
5100721 | Akao | Mar 1992 | A |
5114509 | Johnston et al. | May 1992 | A |
5236977 | Eden et al. | Aug 1993 | A |
5264467 | DiStefano | Nov 1993 | A |
5277737 | Li et al. | Jan 1994 | A |
5325781 | Dupont et al. | Jul 1994 | A |
5342467 | Corey | Aug 1994 | A |
5356683 | Egolf et al. | Oct 1994 | A |
5387626 | Boehme-Kovac et al. | Feb 1995 | A |
5393336 | Foran et al. | Feb 1995 | A |
5451437 | Insley et al. | Sep 1995 | A |
5542599 | Sobol | Aug 1996 | A |
5636493 | Weder | Jun 1997 | A |
5685480 | Choi | Nov 1997 | A |
5759624 | Neale et al. | Jun 1998 | A |
5881883 | Siegelman | Mar 1999 | A |
5928741 | Andersen et al. | Jul 1999 | A |
6139961 | Blankenship et al. | Oct 2000 | A |
6231970 | Andersen et al. | May 2001 | B1 |
6255369 | Philbin et al. | Jul 2001 | B1 |
6312713 | Korol et al. | Nov 2001 | B1 |
6352769 | Mori | Mar 2002 | B1 |
6379497 | Sandstrom et al. | Apr 2002 | B1 |
6648955 | Swiezkowski et al. | Nov 2003 | B1 |
6740373 | Swoboda et al. | May 2004 | B1 |
6740706 | Skryniarz et al. | Jun 2004 | B2 |
6749705 | Skrzyniarz et al. | Jun 2004 | B2 |
6838187 | Figiel et al. | Jan 2005 | B2 |
7335279 | Mohan et al. | Feb 2008 | B2 |
7799968 | Chen et al. | Sep 2010 | B2 |
8529723 | Fu et al. | Sep 2013 | B2 |
8568283 | Broering et al. | Oct 2013 | B2 |
8574698 | Fung et al. | Nov 2013 | B2 |
8747603 | Huang et al. | Jun 2014 | B2 |
9056712 | Cook et al. | Jun 2015 | B2 |
9260633 | Hoa et al. | Feb 2016 | B2 |
9273230 | Huang et al. | Mar 2016 | B2 |
9522772 | Fu et al. | Dec 2016 | B2 |
9580228 | Fu et al. | Feb 2017 | B2 |
9580629 | Huang et al. | Feb 2017 | B2 |
9591937 | Fu et al. | Mar 2017 | B2 |
9648969 | Fu et al. | May 2017 | B2 |
9657200 | Huang et al. | May 2017 | B2 |
9771499 | Huang et al. | Sep 2017 | B2 |
9849655 | Huang et al. | Dec 2017 | B2 |
9865551 | Takano et al. | Jan 2018 | B2 |
10099459 | Huang et al. | Oct 2018 | B2 |
10100204 | Huang et al. | Oct 2018 | B2 |
10100231 | Huang et al. | Oct 2018 | B2 |
10144573 | Fu et al. | Dec 2018 | B2 |
10183458 | Fu et al. | Jan 2019 | B2 |
10208429 | Huang et al. | Feb 2019 | B2 |
10815397 | Huang et al. | Oct 2020 | B2 |
11193048 | Huang et al. | Dec 2021 | B2 |
11427963 | Huang et al. | Aug 2022 | B2 |
20010049007 | Jones | Dec 2001 | A1 |
20020068139 | Polak et al. | Jun 2002 | A1 |
20020071947 | Soane et al. | Jun 2002 | A1 |
20020094403 | Ishikawa et al. | Jul 2002 | A1 |
20020115785 | Weitzel et al. | Aug 2002 | A1 |
20020182347 | DeBraal et al. | Dec 2002 | A1 |
20030003197 | Berlin et al. | Jan 2003 | A1 |
20030034117 | Thomas et al. | Feb 2003 | A1 |
20040033343 | Comeau et al. | Feb 2004 | A1 |
20040191438 | Cosentino et al. | Sep 2004 | A1 |
20040265539 | Hashimoto | Dec 2004 | A1 |
20050067095 | Hasenoehrl | Mar 2005 | A1 |
20050163974 | Geeroms | Jul 2005 | A1 |
20070009723 | Ogawa et al. | Jan 2007 | A1 |
20070155859 | Song et al. | Jul 2007 | A1 |
20070224395 | Rowitsch et al. | Sep 2007 | A1 |
20070228134 | Cook et al. | Oct 2007 | A1 |
20070287776 | Nordin et al. | Dec 2007 | A1 |
20080017338 | Nordin et al. | Jan 2008 | A1 |
20080055380 | Regan et al. | Mar 2008 | A1 |
20080118693 | Bilski et al. | May 2008 | A1 |
20090280322 | Daniels et al. | Nov 2009 | A1 |
20090306255 | Patel et al. | Dec 2009 | A1 |
20090321508 | Fu et al. | Dec 2009 | A1 |
20100012712 | Swoboda et al. | Jan 2010 | A1 |
20100068544 | Huang et al. | Mar 2010 | A1 |
20100119741 | Cimecioglu et al. | May 2010 | A1 |
20100136269 | Andersen et al. | Jun 2010 | A1 |
20100139878 | Nicolucci | Jun 2010 | A1 |
20100181015 | Kohler | Jul 2010 | A1 |
20110019121 | Mo et al. | Jan 2011 | A1 |
20110033398 | Gauvin et al. | Feb 2011 | A1 |
20110064926 | Babinsky et al. | Mar 2011 | A1 |
20110248076 | Bentmar et al. | Oct 2011 | A1 |
20120015162 | Lion et al. | Jan 2012 | A1 |
20120043373 | Babinsky et al. | Feb 2012 | A1 |
20120048450 | Fu et al. | Mar 2012 | A1 |
20120100289 | Egan et al. | Apr 2012 | A1 |
20130160945 | Huang et al. | Jun 2013 | A1 |
20130303351 | Fu et al. | Nov 2013 | A1 |
20140087109 | Huang et al. | Mar 2014 | A1 |
20140087177 | Huang | Mar 2014 | A1 |
20140131367 | Bordary et al. | May 2014 | A1 |
20140141185 | Huang et al. | May 2014 | A1 |
20140154492 | Traser et al. | Jun 2014 | A1 |
20140243442 | Coles et al. | Aug 2014 | A1 |
20150322301 | Ellis et al. | Nov 2015 | A1 |
20160050722 | Fu et al. | Feb 2016 | A1 |
20160263876 | Huang et al. | Sep 2016 | A1 |
20170130058 | Huang et al. | May 2017 | A1 |
20170130399 | Huang et al. | May 2017 | A1 |
20170361573 | Malmgren | Dec 2017 | A1 |
20180148246 | Fu et al. | May 2018 | A1 |
20190031415 | Kumar | Jan 2019 | A1 |
20190062028 | Getty et al. | Feb 2019 | A1 |
20190284438 | McLeod et al. | Mar 2019 | A1 |
20190106263 | Fu et al. | Apr 2019 | A1 |
20190136456 | Huang et al. | May 2019 | A1 |
20190152183 | Fu et al. | May 2019 | A1 |
20190218419 | McLeod et al. | Jul 2019 | A1 |
20190218429 | Huang et al. | Jul 2019 | A1 |
20190218720 | Huang et al. | Jul 2019 | A1 |
20200247105 | Getty et al. | Aug 2020 | A1 |
20210214581 | McLeod et al. | Jul 2021 | A1 |
20220073787 | McLeod et al. | Mar 2022 | A1 |
Number | Date | Country |
---|---|---|
VE990023 | Nov 2000 | AT |
2145938 | Oct 1995 | CA |
2078476 | May 1997 | CA |
1354085 | Jun 2002 | CN |
1449913 | Oct 2003 | CN |
1643100 | Jul 2005 | CN |
101263184 | Sep 2008 | CN |
101476265 | Jul 2009 | CN |
103079791 | May 2013 | CN |
103189460 | Jul 2013 | CN |
103717690 | Apr 2014 | CN |
104685125 | Jun 2015 | CN |
105765023 | Jul 2016 | CN |
3685819 | Jan 1993 | DE |
60107070 | Nov 2005 | DE |
202011109020 | Mar 2012 | DE |
0526396 | Feb 1993 | EP |
0890625 | Jan 1999 | EP |
1142801 | Oct 2001 | EP |
1216146 | Oct 2005 | EP |
1634897 | Mar 2006 | EP |
1669490 | Jun 2006 | EP |
1674543 | Jun 2006 | EP |
1780250 | May 2007 | EP |
3672805 | Jul 2020 | EP |
S6144965 | Mar 1986 | JP |
H05208597 | Aug 1993 | JP |
H05239423 | Sep 1993 | JP |
H06313163 | Nov 1994 | JP |
H08175576 | Jul 1996 | JP |
H09164621 | Jun 1997 | JP |
H09217050 | Aug 1997 | JP |
H10329297 | Dec 1998 | JP |
2000006285 | Jan 2000 | JP |
2000159268 | Jun 2000 | JP |
2001191436 | Jul 2001 | JP |
2001207146 | Jul 2001 | JP |
2002241450 | Aug 2002 | JP |
2003154589 | May 2003 | JP |
2004511616 | Apr 2004 | JP |
2005097816 | Apr 2005 | JP |
2010202996 | Sep 2010 | JP |
2013067070 | Apr 2013 | JP |
20140090995 | Jul 2014 | KR |
2216495 | Nov 2003 | RU |
2252825 | May 2005 | RU |
2011129597 | Jan 2013 | RU |
2519451 | Jun 2014 | RU |
2015135327 | Mar 2017 | RU |
9014223 | Nov 1990 | WO |
9854004 | Dec 1998 | WO |
0069747 | Nov 2000 | WO |
0110635 | Feb 2001 | WO |
0154828 | Aug 2001 | WO |
0154988 | Aug 2001 | WO |
200162986 | Aug 2001 | WO |
0200800 | Jan 2002 | WO |
0231077 | Apr 2002 | WO |
2005110737 | Nov 2005 | WO |
2007091961 | Aug 2007 | WO |
2007126783 | Nov 2007 | WO |
2007135451 | Nov 2007 | WO |
2007142593 | Dec 2007 | WO |
2008084372 | Jul 2008 | WO |
2010069451 | Jun 2010 | WO |
2010129493 | Nov 2010 | WO |
2012030596 | Mar 2012 | WO |
2012033998 | Mar 2012 | WO |
2014015060 | Jan 2014 | WO |
2014051876 | Apr 2014 | WO |
2015036901 | Mar 2015 | WO |
2015081097 | Jun 2015 | WO |
2016014486 | Jan 2016 | WO |
2019018523 | Jan 2019 | WO |
2019040624 | Feb 2019 | WO |
Entry |
---|
Popil, Roman E. et aL “Adhesive level effect on corrugated board strength—experiment and FE modeling.” In: International progress in paper physics seminar. Oxford, Ohio: Miami University, 2006. |
Bermesheva, Ev “Zavisimost mezhdu vyazkoupru9imi l adgezivnymi svoistvami polimemykh adgezivov. Dopolneni kriteriya liplosti Dalkkuista”, 25 Sipozium Po Reologii, G.Ostashkov, Sep. 5-10, 2010, pp. 61, 62. |
Radio frequency (RF)vs, microwave (MW) (n.d.), Retrieved from https://www,stalam.com/eng/technology?and-benefits/rf-vs-microwaves. |
Jiao, Shunshan et al., “Principles of Radio-Frequency and Microwave Heating”, Radio-Frequency Heating in Food Processing, CRC Press, 2015, p. 4. Month of Publication Unknown. (Year: 2015). |
NXP, FTF 2016 Technology Forum, “Advantages of Solid State RF Power Over Vacuum Tubes in Industrial Applications”, May 18, 2016. (Year: 2016). |
Skylighter, “Kraft Paper Weights and Thickness Comparison Chart”, Feb. 14, 2018. (Year: 2018). |
European Search Results Under Rule 164(2)(b) EPC EO 18769557 Completed: May 27, 2021; dated Jun. 2, 2021 7 Pages. |
International Search Report and Written Opinion, International Application No. PCT/US2018/047526, dated Jan. 18, 2019. |
Number | Date | Country | |
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20200369010 A1 | Nov 2020 | US |
Number | Date | Country | |
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Parent | PCT/EP2019/053056 | Feb 2019 | US |
Child | 16988812 | US |