Method for producing a multi-layer substrate

Information

  • Patent Grant
  • 11833788
  • Patent Number
    11,833,788
  • Date Filed
    Monday, August 10, 2020
    4 years ago
  • Date Issued
    Tuesday, December 5, 2023
    12 months ago
Abstract
The present invention relates to a method for producing a multi-layer substrate, said substrate comprising a multifunctional coating, and to the use of the substrate produced by this method.
Description
FILED OF THE INVENTION

The present invention relates to a method for producing a multi-layer substrate, said substrate comprising a multifunctional coating, and to the use of the substrate produced by this method.


The Internet as a distribution channel for goods of all kinds has become increasingly important in recent years. Clothing, electronics, computers and shoes make up the largest share of goods sold on the Internet, but household goods, furniture and interior furnishings as well as everyday goods such as food, drugstore items and pet supplies are increasingly being purchased via the Internet. In order for the goods to reach the customer, not only complex logistics are required, but also safe transport so that sensitive or fragile goods arrive at the customer without damage.


BACKGROUND OF THE INVENTION

Safe packaging of the goods can be achieved, for example, with the aid of suitable packaging material, the packaging material generally having a type of padding by which the goods to be transported are protected. A classic example of such a packaging material is an air cushion film, that is to say a plastic film which has pockets filled with air, by means of which mechanical vibrations can be cushioned. However, these bubble wrap films have the disadvantage that they are usually made from petroleum-based plastics and their production and disposal involve major ecological interventions. This problem is exacerbated in view of the increasing need and the increasing desire for sustainability. There is therefore a need for alternative packaging materials that have the same properties but show better environmental compatibility.


WO 2014/051876 describes an adhesive composition which is used for producing packaging materials, the adhesive composition having microspheres which have an insulating effect.


DE 20 2011109 020 describes a composite body consisting of a carrier substrate made of natural fibers and at least one bonded substrate layer made of a flexible film-shaped substrate, which are completely bonded to a dried adhesive layer, the adhesive layer being produced from an aqueous foamed adhesive.


WO 2010/129493 discloses an inflatable mailing bag that has an inflatable liner and a connector through which the liner can be inflated.


The materials described in the prior art are generally only accessible through complex production processes, as a result of which the amount that can be produced is limited. Furthermore, the conventional materials have the disadvantage that they have a large volume due to the cushion layer introduced, which can cause high costs, in particular when the material is transported and stored.


BRIEF SUMMARY OF THE INVENTION

The object of the present invention is therefore to provide a method which allows the production of a packaging material which can absorb mechanical shocks and can be easily stored and transported.


It has surprisingly been found that this object is achieved by a method for producing a multi-layer substrate which has a multifunctional coating.


A first object of the present invention is therefore a method for producing a multi-layer substrate comprising the following steps:

    • a) Providing a first material having a first surface with at least one edge region and at least one inner region enclosed by the edge region;
    • b) Applying a coating material to the inner region of the first surface, the coating material comprising expandable microparticles;
    • c) Drying the coating material;
    • d) Contacting the first surface of the first material with a surface of a second material to form the multi-layer substrate such that the coating material is between the first material and the second material.


It has surprisingly been found that a substrate with a small volume is accessible in this way. The method according to the invention is further characterized in that it allows the substrate to be produced in large quantities and can be carried out without the need for complex modifications to the device used.


In a preferred embodiment, the first material has more than one inner region.


The coating material is preferably applied over the entire surface. For the purposes of the present invention, this is to be understood to mean application in such a way that the entire inner region is covered with the coating material. In order to save costs and material, it can be advantageous to apply the coating material intermittently or only partially, so that the inner region is not completely covered. An alternative embodiment is therefore preferred, in which the coating material is partially applied to the inner region.


In a preferred embodiment, the contacting of the first and the second material takes place using an adhesive. The adhesive is preferably applied to the edge region of the first surface before the contacting of the first and the second material. The adhesive is particularly preferably applied uniformly or continuously to the edge region of the first surface, so that the edge region is completely covered with the adhesive. It has surprisingly been found that the composite adhesion of the materials in the substrate can be improved in this way without the performance of the coating material being impaired. The advantages of the method according to the invention come to full development when it is ensured that no adhesive gets onto the inner region.


In a preferred embodiment of the method according to the invention, the first and the second material are provided in the form of continuous webs. In an alternative preferred embodiment, the first material is divided into individual units before or after application of the coating material, which have an edge region and an inner region enclosed by the edge region. In an alternative preferred embodiment, the division of the first material and the application of the coating material to the inner region take place simultaneously. In terms of process technology, the cutting is combined with the application of the coating material and is preferably carried out in a combined step.


In a preferred embodiment, the first material is selected from the group consisting of material based on cellulose, plastic and metal. The first material can have synthetic fibers, for example, in order to increase the stability of the material.


The first material is particularly preferably a material based on cellulose. In particular, the first material is selected from the group consisting of paper, cardboard and coated paper.


In a preferred embodiment, the second material is selected from the group consisting of material based on cellulose, plastic and metal. The second material can have synthetic fibers, for example, in order to increase the stability of the material.


The second material is particularly preferably a material based on cellulose. In particular, the second material is selected from the group consisting of paper, cardboard and coated paper.


In a preferred embodiment, the first and second materials are paper. The second material is particularly preferably present in the form of a continuous web.





BRIEF DESCRIPTION OF THE DRAWINGS


FIG. 1 shows schematically the first material in the form of a continuous web, wherein (1) denotes the edge region and (2) the inner region.



FIG. 2 shows schematically the first material in the form of a single unit, wherein (1) denotes the edge region and (2) the inner region.





DETAILED DESCRIPTION OF THE INVENTION

The method according to the invention is distinguished by its rapid process control, which allows large quantities of the multi-layer substrate to be produced in a short time. This is achieved, among other things, by carefully coordinating the properties of the materials used. Therefore, an embodiment of the present invention is preferred in which the drying of the coating material is carried out at a temperature of 80° C. or less, preferably at a temperature of 40° C. to 75° C. It has surprisingly been found that rapid drying is achieved at these temperatures without the performance of the coating material being impaired, as a result of which the process throughput is improved.


The best results in terms of process throughput were achieved when a polymer-based coating material was used. An embodiment is therefore preferred in which the coating material is a polymer-based coating material which has 10 to 40 wt. %, preferably 15 to 35 wt. % of expandable microparticles, in each case based on the total weight of the coating material. It has surprisingly been found that such a coating material can be applied at a high speed, but at the same time has sufficient stability so that it does not run after application.


The coating material used in the method according to the invention has expandable microparticles. The microparticles preferably have a particle size, expressed as a D50 value, of 5 to 18 μm, preferably 10 to 17 μm, in the unexpanded state.


The expandable microparticles are preferably thermally expandable microparticles, which preferably have the shape of spheres.


In a preferred embodiment of the method according to the invention, the multi-layer substrate is converted into packaging in a further step. This implementation can take place, for example, by cutting and folding the multi-layer substrate. The packaging is preferably an envelope, a mailing bag, a bag, a carrier bag, a pouch or a carton, the format and size being variable. In a particularly preferred embodiment, the packaging is a mailing bag.


In a preferred embodiment, the method according to the invention comprises a further step in which the multi-layer substrate is subjected to a treatment for expanding the expandable microparticles.


In a preferred embodiment, the heat treatment step follows step d) of the method according to the invention.


The method according to the invention allows the production of a substrate, the volume of which can be increased by a heat treatment, wherein this heat treatment can be carried out independently of the production method. In a preferred embodiment, the heat treatment is carried out separately from the other method steps in terms of time and/or location. In this way it is possible to transport and store the substrate in the state of a small volume. The substrate reaches its final volume as a result of the heat treatment, which causes the microparticles of the coating material to expand. The method according to the invention makes it possible to carry out the heat treatment only shortly before the substrate is used, which was not possible with conventional methods described in the prior art. For example, the substrate can be further processed into a mailing bag, which takes up little space due to the small volume and the small thickness. Before the mailing bag is used, it can be subjected to a heat treatment, whereby the microparticles are expanded and the mailing bag develops its desired cushioning effect. In this way, valuable storage and transport capacity can be saved by the method according to the invention.


The heat treatment is preferably carried out at temperatures from 85° C. to 150° C., preferably 90 to 140° C. This ensures that the microparticles fully expand without being damaged and without losing their shock-absorbing effect.


In order to achieve optimal absorption of mechanical influences, it has proven to be advantageous if the microparticles in the expanded state have a particle size in the range from 20 μm to 200 μm. An embodiment is therefore preferred in which the microparticles in the expanded state have a particle size, expressed as a D50 value, of 20 μm to 200 μm, preferably 20 to 150 μm.


The heat treatment is preferably carried out using conventional heat sources. The heat treatment is particularly preferably carried out using infrared radiation and/or warm air.


The multi-layer substrate produced by the method according to the invention is distinguished by its flexible volume. Another object of the present invention is therefore a multi-layer substrate which can be obtained by the method according to the invention. The substrate according to the invention is preferably in the form of a continuous web. In an alternative preferred embodiment, the substrate according to the invention is in the form of a packaging, preferably in the form of an envelope, a mailing bag, a bag, a carrier bag, a pouch or a carton, the format and the size being variable.


The substrate according to the invention can be easily processed into packaging. Another object is therefore a method for producing a package using a multi-layer substrate which has been produced by the method according to the invention, the multi-layer substrate being formed into a package by means of cutting and folding.


Another object of the present application is a package obtainable according to the inventive method. The packaging is preferably an envelope, a mailing bag, a bag, a carrier bag, a pouch or a carton, the format and the size being variable.


The present invention is to be explained in more detail with reference to the following example, which is in no way to be understood as a restriction of the inventive concept.


A suitable coating material can contain 30 to 70 wt-% of VAE copolymer dispersion (Vinamul® 3928), 5 to 15 wt. % of paraffin dispersion (Michemlube® 743 PE), 15 to 30 wt. % of microparticles (Expancel® 031 WUF 40), 5 to 10 wt. % of glycerol and optionally up to a wt. % of hydroxyethylcellulose (MEHC, Natrosol® 250LR), wherein the weight percentages refer to the total weight of the coating material and add up to 100 wt. %.



FIG. 1 shows schematically the first material in the form of a continuous web, wherein (1) denotes the edge region and (2) the inner region.



FIG. 2 shows schematically the first material in the form of a single unit, wherein (1) denotes the edge region and (2) the inner region.

Claims
  • 1. A method of producing a multi-layer substrate comprising the following steps: a) providing a first material having a first surface with at least one edge region and at least one inner region enclosed by the edge region;b) applying a coating material to partial portions of the inner region of the first surface, the coating material comprising expandable microparticles;c) drying the coating material; andd) contacting the first surface of the first material with a surface of a second material to form the multi-layer substrate such that the coating material is between the first material and the second material,wherein the inner region does not contain an adhesivewherein the coating material consists of: (i) 30 to 70 wt-% of VAE copolymer dispersion;(ii) 5 to 15 wt. % of paraffin dispersion;(iii) 15 to 30 wt. % of microparticles;(iv) 5 to 10 wt. % of glycerol; and(v) optionally, hydroxyethylcellulose,wherein the total weight of the coating material and add up to 100 wt. %.
  • 2. The method according to claim 1, characterized in that the contacting in step d) is carried out using an adhesive, wherein the adhesive is applied continuously to the edge region of the first material.
  • 3. The method according to claim 1, characterized in that the coating material is dried at a temperature of 80° C. or less.
  • 4. The method according to claim 1, characterized in that the coating material is a polymer-based coating material which has 10 to 40 wt. %, of expandable microparticles based on the total weight of the coating material.
  • 5. The method according to claim 4, characterized in that the expandable microparticles are thermally expandable microparticles.
  • 6. The method according to claim 1, characterized in that the multi-layer substrate is converted into a packaging in a further step.
  • 7. The method according to claim 6, characterized in that the packaging is an envelope, a mailing bag, a bag, a carrier bag, a pouch or a carton.
  • 8. The method according to claim 1, characterized in that the method comprises a further step e) in which the multi-layer substrate is subjected to a treatment for expanding the expandable microparticles.
  • 9. The method according to claim 8, characterized in that the treatment is a heat treatment carried out at a temperature of 85° C. to 150° C.
  • 10. The method according to claim 8, characterized in that the treatment is carried out separately from the other method steps from time and/or location.
  • 11. The method according to claim 8, characterized in that the treatment is a heat treatment which is carried out using infrared radiation and/or warm air.
  • 12. A method of producing a package using a multi-layer substrate produced by a method according to claim 1, wherein the multi-layer substrate is formed into the package by cutting and folding.
Priority Claims (1)
Number Date Country Kind
18157071 Feb 2018 EP regional
US Referenced Citations (150)
Number Name Date Kind
2147689 Chaffee Feb 1939 A
2998501 Edberg et al. Aug 1961 A
3152749 Young Oct 1964 A
3252064 Duncan May 1966 A
3253064 Buonaiuto May 1966 A
3300360 Williams et al. Jan 1967 A
3342613 Schelhom Sep 1967 A
3401475 Morehouse et al. Sep 1968 A
3563851 Armour et al. Feb 1971 A
3583851 Harrington et al. Jun 1971 A
3615972 Morehouse, Jr. et al. Oct 1971 A
3732975 Poncy May 1973 A
3904429 Eastman et al. Sep 1975 A
4005033 Georgeau et al. Jan 1977 A
4006273 Wolinski et al. Feb 1977 A
4038762 Swan, Jr. Aug 1977 A
4087002 Bambara et al. May 1978 A
4094685 Lester et al. Jun 1978 A
4193499 Lockholder Mar 1980 A
4350788 Shimokawa et al. Sep 1982 A
4483889 Andersson Nov 1984 A
4531038 Lillibridge Jul 1985 A
4661401 Akao Apr 1987 A
4690843 Inagaki Sep 1987 A
4708896 Akao Nov 1987 A
4720410 Lundquist et al. Jan 1988 A
4900594 Quick Feb 1990 A
4925711 Akao et al. May 1990 A
5030302 Jud et al. Jul 1991 A
5082744 Akao et al. Jan 1992 A
5100721 Akao Mar 1992 A
5114509 Johnston et al. May 1992 A
5236977 Eden et al. Aug 1993 A
5264467 DiStefano Nov 1993 A
5277737 Li et al. Jan 1994 A
5325781 Dupont et al. Jul 1994 A
5342467 Corey Aug 1994 A
5356683 Egolf et al. Oct 1994 A
5387626 Boehme-Kovac et al. Feb 1995 A
5393336 Foran et al. Feb 1995 A
5451437 Insley et al. Sep 1995 A
5542599 Sobol Aug 1996 A
5636493 Weder Jun 1997 A
5685480 Choi Nov 1997 A
5759624 Neale et al. Jun 1998 A
5881883 Siegelman Mar 1999 A
5928741 Andersen et al. Jul 1999 A
6139961 Blankenship et al. Oct 2000 A
6231970 Andersen et al. May 2001 B1
6255369 Philbin et al. Jul 2001 B1
6312713 Korol et al. Nov 2001 B1
6352769 Mori Mar 2002 B1
6379497 Sandstrom et al. Apr 2002 B1
6648955 Swiezkowski et al. Nov 2003 B1
6740373 Swoboda et al. May 2004 B1
6740706 Skryniarz et al. Jun 2004 B2
6749705 Skrzyniarz et al. Jun 2004 B2
6838187 Figiel et al. Jan 2005 B2
7335279 Mohan et al. Feb 2008 B2
7799968 Chen et al. Sep 2010 B2
8529723 Fu et al. Sep 2013 B2
8568283 Broering et al. Oct 2013 B2
8574698 Fung et al. Nov 2013 B2
8747603 Huang et al. Jun 2014 B2
9056712 Cook et al. Jun 2015 B2
9260633 Hoa et al. Feb 2016 B2
9273230 Huang et al. Mar 2016 B2
9522772 Fu et al. Dec 2016 B2
9580228 Fu et al. Feb 2017 B2
9580629 Huang et al. Feb 2017 B2
9591937 Fu et al. Mar 2017 B2
9648969 Fu et al. May 2017 B2
9657200 Huang et al. May 2017 B2
9771499 Huang et al. Sep 2017 B2
9849655 Huang et al. Dec 2017 B2
9865551 Takano et al. Jan 2018 B2
10099459 Huang et al. Oct 2018 B2
10100204 Huang et al. Oct 2018 B2
10100231 Huang et al. Oct 2018 B2
10144573 Fu et al. Dec 2018 B2
10183458 Fu et al. Jan 2019 B2
10208429 Huang et al. Feb 2019 B2
10815397 Huang et al. Oct 2020 B2
11193048 Huang et al. Dec 2021 B2
11427963 Huang et al. Aug 2022 B2
20010049007 Jones Dec 2001 A1
20020068139 Polak et al. Jun 2002 A1
20020071947 Soane et al. Jun 2002 A1
20020094403 Ishikawa et al. Jul 2002 A1
20020115785 Weitzel et al. Aug 2002 A1
20020182347 DeBraal et al. Dec 2002 A1
20030003197 Berlin et al. Jan 2003 A1
20030034117 Thomas et al. Feb 2003 A1
20040033343 Comeau et al. Feb 2004 A1
20040191438 Cosentino et al. Sep 2004 A1
20040265539 Hashimoto Dec 2004 A1
20050067095 Hasenoehrl Mar 2005 A1
20050163974 Geeroms Jul 2005 A1
20070009723 Ogawa et al. Jan 2007 A1
20070155859 Song et al. Jul 2007 A1
20070224395 Rowitsch et al. Sep 2007 A1
20070228134 Cook et al. Oct 2007 A1
20070287776 Nordin et al. Dec 2007 A1
20080017338 Nordin et al. Jan 2008 A1
20080055380 Regan et al. Mar 2008 A1
20080118693 Bilski et al. May 2008 A1
20090280322 Daniels et al. Nov 2009 A1
20090306255 Patel et al. Dec 2009 A1
20090321508 Fu et al. Dec 2009 A1
20100012712 Swoboda et al. Jan 2010 A1
20100068544 Huang et al. Mar 2010 A1
20100119741 Cimecioglu et al. May 2010 A1
20100136269 Andersen et al. Jun 2010 A1
20100139878 Nicolucci Jun 2010 A1
20100181015 Kohler Jul 2010 A1
20110019121 Mo et al. Jan 2011 A1
20110033398 Gauvin et al. Feb 2011 A1
20110064926 Babinsky et al. Mar 2011 A1
20110248076 Bentmar et al. Oct 2011 A1
20120015162 Lion et al. Jan 2012 A1
20120043373 Babinsky et al. Feb 2012 A1
20120048450 Fu et al. Mar 2012 A1
20120100289 Egan et al. Apr 2012 A1
20130160945 Huang et al. Jun 2013 A1
20130303351 Fu et al. Nov 2013 A1
20140087109 Huang et al. Mar 2014 A1
20140087177 Huang Mar 2014 A1
20140131367 Bordary et al. May 2014 A1
20140141185 Huang et al. May 2014 A1
20140154492 Traser et al. Jun 2014 A1
20140243442 Coles et al. Aug 2014 A1
20150322301 Ellis et al. Nov 2015 A1
20160050722 Fu et al. Feb 2016 A1
20160263876 Huang et al. Sep 2016 A1
20170130058 Huang et al. May 2017 A1
20170130399 Huang et al. May 2017 A1
20170361573 Malmgren Dec 2017 A1
20180148246 Fu et al. May 2018 A1
20190031415 Kumar Jan 2019 A1
20190062028 Getty et al. Feb 2019 A1
20190284438 McLeod et al. Mar 2019 A1
20190106263 Fu et al. Apr 2019 A1
20190136456 Huang et al. May 2019 A1
20190152183 Fu et al. May 2019 A1
20190218419 McLeod et al. Jul 2019 A1
20190218429 Huang et al. Jul 2019 A1
20190218720 Huang et al. Jul 2019 A1
20200247105 Getty et al. Aug 2020 A1
20210214581 McLeod et al. Jul 2021 A1
20220073787 McLeod et al. Mar 2022 A1
Foreign Referenced Citations (75)
Number Date Country
VE990023 Nov 2000 AT
2145938 Oct 1995 CA
2078476 May 1997 CA
1354085 Jun 2002 CN
1449913 Oct 2003 CN
1643100 Jul 2005 CN
101263184 Sep 2008 CN
101476265 Jul 2009 CN
103079791 May 2013 CN
103189460 Jul 2013 CN
103717690 Apr 2014 CN
104685125 Jun 2015 CN
105765023 Jul 2016 CN
3685819 Jan 1993 DE
60107070 Nov 2005 DE
202011109020 Mar 2012 DE
0526396 Feb 1993 EP
0890625 Jan 1999 EP
1142801 Oct 2001 EP
1216146 Oct 2005 EP
1634897 Mar 2006 EP
1669490 Jun 2006 EP
1674543 Jun 2006 EP
1780250 May 2007 EP
3672805 Jul 2020 EP
S6144965 Mar 1986 JP
H05208597 Aug 1993 JP
H05239423 Sep 1993 JP
H06313163 Nov 1994 JP
H08175576 Jul 1996 JP
H09164621 Jun 1997 JP
H09217050 Aug 1997 JP
H10329297 Dec 1998 JP
2000006285 Jan 2000 JP
2000159268 Jun 2000 JP
2001191436 Jul 2001 JP
2001207146 Jul 2001 JP
2002241450 Aug 2002 JP
2003154589 May 2003 JP
2004511616 Apr 2004 JP
2005097816 Apr 2005 JP
2010202996 Sep 2010 JP
2013067070 Apr 2013 JP
20140090995 Jul 2014 KR
2216495 Nov 2003 RU
2252825 May 2005 RU
2011129597 Jan 2013 RU
2519451 Jun 2014 RU
2015135327 Mar 2017 RU
9014223 Nov 1990 WO
9854004 Dec 1998 WO
0069747 Nov 2000 WO
0110635 Feb 2001 WO
0154828 Aug 2001 WO
0154988 Aug 2001 WO
200162986 Aug 2001 WO
0200800 Jan 2002 WO
0231077 Apr 2002 WO
2005110737 Nov 2005 WO
2007091961 Aug 2007 WO
2007126783 Nov 2007 WO
2007135451 Nov 2007 WO
2007142593 Dec 2007 WO
2008084372 Jul 2008 WO
2010069451 Jun 2010 WO
2010129493 Nov 2010 WO
2012030596 Mar 2012 WO
2012033998 Mar 2012 WO
2014015060 Jan 2014 WO
2014051876 Apr 2014 WO
2015036901 Mar 2015 WO
2015081097 Jun 2015 WO
2016014486 Jan 2016 WO
2019018523 Jan 2019 WO
2019040624 Feb 2019 WO
Non-Patent Literature Citations (8)
Entry
Popil, Roman E. et aL “Adhesive level effect on corrugated board strength—experiment and FE modeling.” In: International progress in paper physics seminar. Oxford, Ohio: Miami University, 2006.
Bermesheva, Ev “Zavisimost mezhdu vyazkoupru9imi l adgezivnymi svoistvami polimemykh adgezivov. Dopolneni kriteriya liplosti Dalkkuista”, 25 Sipozium Po Reologii, G.Ostashkov, Sep. 5-10, 2010, pp. 61, 62.
Radio frequency (RF)vs, microwave (MW) (n.d.), Retrieved from https://www,stalam.com/eng/technology?and-benefits/rf-vs-microwaves.
Jiao, Shunshan et al., “Principles of Radio-Frequency and Microwave Heating”, Radio-Frequency Heating in Food Processing, CRC Press, 2015, p. 4. Month of Publication Unknown. (Year: 2015).
NXP, FTF 2016 Technology Forum, “Advantages of Solid State RF Power Over Vacuum Tubes in Industrial Applications”, May 18, 2016. (Year: 2016).
Skylighter, “Kraft Paper Weights and Thickness Comparison Chart”, Feb. 14, 2018. (Year: 2018).
European Search Results Under Rule 164(2)(b) EPC EO 18769557 Completed: May 27, 2021; dated Jun. 2, 2021 7 Pages.
International Search Report and Written Opinion, International Application No. PCT/US2018/047526, dated Jan. 18, 2019.
Related Publications (1)
Number Date Country
20200369010 A1 Nov 2020 US
Continuations (1)
Number Date Country
Parent PCT/EP2019/053056 Feb 2019 US
Child 16988812 US