This patent application claims the priority of the German patent application 10 2015 108 420.1, the disclosure content of which is hereby incorporated by reference.
A method for producing a carrier element, a carrier element, a method for producing an electronic component with a carrier element and an electronic component with a carrier element are provided.
For electronic applications, substrates are often needed which have high thermal conductivity together with insulating properties, in particular high electrical insulating strength, and high mechanical strength at the same time as low costs. Substrates of this type are used e.g. for mounting semiconductor chips during so-called COB assembly (COB: chip-on-board) or together with surface-mounted SMD components (SMD: surface-mounted device). It is known, for example, to use ceramic substrates composed of e.g. aluminum oxide, aluminum nitride or silicon nitride for this purpose. Furthermore, printed circuit boards such as e.g. metal core boards (MCBs) are known which consist of a copper or aluminum substrate with an organic dielectric material with inorganic fillers applied on one or both sides. Furthermore, copper-ceramic-copper laminates are also known by the catchword “direct bonded copper” (DCB).
Objects of specific embodiments are to provide a method for producing a carrier element, in particular for an electronic component, a carrier element of this type, a method for producing an electronic component with a carrier element and an electronic component with a carrier element.
These objects are achieved by methods and items according to the independent claims. Advantageous embodiments and developments of the method and items are characterized in the dependent claims and can also be taken from the following description and the drawings.
According to at least one embodiment, in a method for producing a carrier element a first metal layer is provided. The first metal layer comprises in particular a first and a second main surface which face away from one another. In particular, those areas having the greatest extension of the surfaces of the first metal layer are referred to as a main surface. In particular, the first metal layer can be provided as a metal film or metal sheet having two main surfaces opposite one another, which are connected to one another by side surfaces, wherein the side surfaces can have a smaller surface area than the main surfaces. The first metal layer can be provided in unpatterned form and thus as a coherent sheet- or film-shaped structure. Alternatively, it may also be possible to provide the first metal layer in patterned form, that is e.g. with recesses, openings, holes, indentations and/or bulges. For example, a patterned first metal layer can be provided in the form of a patterned lead frame. The first metal layer can in particular be self-supporting. This means that the first metal layer, owing to a suitable composition, thickness and structure, has sufficient stability for the method steps described below and in the finished carrier element can be the element that provides the carrier element with its basic stability and strength.
According to a further embodiment, a second metal layer is applied on at least one of the main surfaces. This means that either a second metal layer is applied on the first main surface or a second metal layer is applied on the second main surface or a second metal layer is applied on each of the first and second main surfaces. In particular, the second metal layer is applied on the respective main surface of the first metal layer over a large area and coherently, such that the second metal layer preferably covers the entire area of the main surface on which it is applied. If a second metal layer is applied on each of the two main surfaces, these two second metal layers therefore preferably each cover the respective main surfaces over a large area and coherently. Moreover, it may also be possible that side surfaces of the first metal layer which connect the main surfaces to one another are also covered with the second metal layer. If the first metal layer has a patterning, e.g. in the form of openings, holes or recesses, it may in particular also be possible that the second metal layer is applied on side walls of these structures.
According to a further embodiment, the first metal layer comprises a first metal material and the second metal layer comprises a second metal material. The first metal material of the first metal layer can in particular be different from the second metal material of the second metal layer. The first metal material is formed in particular by a material having high thermal conductivity and/or high mechanical strength, such that the first metal layer is in particular self-supporting as described above. The first metal material can in particular be formed by one or more of the following materials: copper, nickel, titanium, steel, stainless steel and alloys therewith. The second metal material can in particular be formed by a material which can be applied on the first metal material by electroplating. In particular, the second metal material can comprise or be composed of aluminum, in particular aluminum with a purity of greater than or equal to 99.99%.
According to a further embodiment, the second metal layer is applied on the first metal layer by means of an electroplating method. In order to apply the second metal material, in particular aluminum, in the highest possible purity as a second metal layer, it is particularly advantageous if the electroplating method takes place with the exclusion of oxygen and water.
According to a further embodiment, the second metal layer is applied directly on the first metal layer. This means in other words that, after the second metal layer has been applied on one or both main surfaces of the first metal layer, a laminate is provided for further processing, which is provided from the first metal layer and a second metal layer directly thereon, or from the first metal layer between two second metal layers in direct contact therewith. In particular, it may be possible to apply aluminum as a second metal material on one of the above-mentioned first metal materials without an intermediate layer and thus directly on one or both main surfaces of the first metal layer. This can facilitate the application of layers.
According to a further embodiment, part of the second metal layer is converted to a dielectric ceramic layer. In particular, the conversion can be started from an external side of the second metal layer, which is formed by a surface of the second metal layer facing away from the first metal layer. In other words, the process for converting part of the second metal layer is started from an external side or from both external sides of the laminate composed of the first metal layer and one or two second metal layers on one or both main surfaces of the first metal layer. In particular, the second metal material can form part of the ceramic layer after conversion. The ceramic layer can form a surface over the second metal layer facing away from the first metal layer. This means in other words that, after the conversion of part of the second metal layer, the unconverted part of the second metal layer is arranged between the first metal layer and the dielectric ceramic layer. If a second metal layer is applied only on one main surface of the first metal layer, a three-layer laminar composite is produced by the conversion of part of the second metal layer, which is formed by the first metal layer, on this the non-converted part of the second metal layer, and over these the dielectric ceramic layer. If a second metal layer is applied on both main surfaces of the first metal layer, a five-layer laminar composite is produced by the conversion of part of each of the second metal layers, which is formed by a dielectric ceramic layer on which an unconverted part of a second metal layer is arranged, over which is the first metal layer, and on this again an unconverted part of a second metal layer and over this a further dielectric ceramic layer.
According to a further embodiment, the ceramic layer is produced over a large area and coherently, such that the dielectric ceramic layer covers the unconverted part of the second metal layer over a large area and coherently. Thus, in particular, the second metal layer and the ceramic layer can both be applied or produced over a large area and coherently on at least one of the main surfaces of the first metal layer. This can also mean that the remaining second metal layer is entirely surrounded by the first metal layer and the dielectric ceramic layer.
According to a further embodiment, the dielectric ceramic layer comprises a material which is formed by an oxide of the second metal material. If the second metal material comprises or consists of aluminum, the dielectric ceramic layer can in particular comprise or be formed by aluminum oxide.
According to a further embodiment, the dielectric ceramic layer is produced by means of electrolytic oxidation. In particular, it may be possible that the ceramic layer is not applied by anodizing, plasma-electrolytic oxidation or spray coating, since these methods usually create a more or less porous or cracked layer, and in the case of aluminum accordingly a more or less porous or cracked aluminum oxide layer. By electrolytic oxidation, on the other hand, an impervious, preferably as far as possible crack-free ceramic layer, and in the case of aluminum as a second metal material therefore ceramic aluminum oxide layer, can be produced which is particularly suitable for electrical applications. This can mean in particular that the ceramic layer has high thermal conductivity, e.g. greater than or equal to 5 W/mK, and high dielectric strength, in particular greater than or equal to 30 V/μm. In terms of the electrolytic oxidation method, aluminum can be particularly advantageous here as a second metal material whereas other materials, such as e.g. copper or steel, cannot be converted to an oxide that can be used for electronic applications.
To produce the dielectric ceramic layer, the first metal layer with the one second metal layer applied thereon or the two second metal layers applied thereon can be placed into an aqueous electrolyte solution. The ceramic layer in this case is formed as an oxygen-containing reaction product of the second metal material with the electrolyte solution. For example, an alkaline aqueous solution having e.g. a pH value of 9 or more can be used as the electrolyte solution. Moreover, it may be advantageous if the electrolyte solution has an electrical conductivity of more than 1 mS/cm. The aqueous electrolyte solution can comprise e.g. an alkali metal hydroxide, such as e.g. potassium hydroxide or sodium hydroxide. By using the electrolytic oxidation method, in particular a ceramic layer can be formed which has a nanocrystalline structure, i.e. a ceramic structure with crystalline particles having an average diameter of less than 200 nm and preferably of less than 100 nm. As a result of such a small particle size, the material of the dielectric ceramic layer can have great homogeneity and stability. A method for producing a ceramic layer by means of electrolytic oxidation is described e.g. in the document US 2014/0293554 A1, the relevant disclosure content of which is hereby incorporated in full by reference. The electrolytic oxidation method can in particular be advantageous in association with the previously described electroplating method for applying the second metal layer, since the electroplating method allows the second metal material to be applied with high purity, which in turn can lead, in the method for converting part of the second metal layer, to a high-quality ceramic material, in particular a high-quality nanoceramic.
Compared with e.g. a monolayer self-supporting aluminum substrate, which is provided with a dielectric ceramic layer by the method described here, the carrier element described here, which in addition to the second metal layer also comprises the first metal layer as a supporting element, has the advantage that a material can be used as a first metal material of the first metal layer which has a higher thermal conductivity than the second metal material of the second metal layer. Furthermore, a material can be used as a first metal material which is more stable than the second metal material, i.e. which has a higher modulus of elasticity, for example. As a result, it is possible to achieve easier processing of the carrier element when populating it with further components and/or during further electroplating methods, e.g. for producing traces. Moreover, a first metal material can be used for the first metal layer which can be more easily patterned, e.g. by etching, compared to the second metal material. As a result of this, finer structures can be achieved during patterning, and therefore ultimately resulting components can be given smaller dimensions. This can also result in a cost saving due to a gain in area. Furthermore, it may be possible to choose as the material of the first metal layer a material having a lower coefficient of thermal expansion compared with the second metal material, which, depending on the surrounding material such as e.g. chips and/or printed circuit boards, can result in lower mechanical stresses.
According to a further embodiment, a carrier element comprises a first metal layer with a first metal material. The first metal layer comprises in particular a first and a second main surface, which face away from one another. Furthermore, the carrier element comprises on at least one of the main surfaces a second metal layer with a second metal material. Furthermore, the carrier element comprises on the second metal layer a dielectric ceramic layer, wherein the second metal material of the second metal layer forms part of the ceramic layer and the ceramic layer forms a surface over the second metal layer facing away from the first metal layer.
According to a further embodiment, an electronic component comprises such a carrier element and at least one electronic semiconductor chip thereon.
According to a further embodiment, in a method for producing an electronic component, a carrier element is produced and on the carrier element at least one electronic semiconductor chip is arranged.
The embodiments and features mentioned above and below apply in the same way to the method for producing the carrier element, to the carrier element and to the method of producing the electronic component with the carrier element and to the electronic component with the carrier element.
According to a further embodiment, a patterned third metal layer is applied on the ceramic layer. The patterned third metal layer can at least partly form e.g. patterned contact surfaces and/or traces. In particular, the patterned third metal layer can be provided for mounting and/or electrically connecting further components which are arranged on the carrier element, e.g. one or more electronic semiconductor chips or other electronic or electrical components.
According to a further embodiment, the patterned third metal layer is applied by means of an electroplating method. To this end, a seed layer can be applied directly on the ceramic layer over a large area, on which the third metal layer is then applied by means of the electroplating method. A patterning of the third metal layer can be achieved e.g. by means of a photolithographic method. To this end, e.g. before carrying out the electroplating method for applying the third metal layer, a photoresist can be applied on the seed layer in a patterned manner. During the electroplating method, regions of the third metal layer are then applied only in regions in which no photoresist is present. The photoresist can then be removed. Alternatively, it may also be possible that the third metal layer is first applied on the seed layer over a large area. Next, a photoresist can be applied on the unpatterned third metal layer in a patterned manner. By means of an etching method, the third metal layer can be removed again in the regions in which no photoresist is present. Next, the photoresist can be removed.
In regions in which no third metal layer is arranged on the seed layer, the seed layer can then be removed again, so that in the regions in which no patterned third metal layer is present, the ceramic layer can form an external surface of the carrier element and the patterned regions of the patterned third metal layer are electrically insulated from one another. The third metal layer can comprise a third metal material, which in particular can have high conductivity and can be readily patterned, e.g. copper.
According to a further embodiment, the first metal layer is provided with at least one opening. The opening can extend in particular from one of the main surfaces into the first metal layer. In this case, it may also be possible in particular that the opening extends from the first main surface to the second main surface through the first metal layer. The opening has a wall surface. During the method steps described above, the second metal layer and the ceramic layer can be applied on the wall surface of the opening.
According to a further embodiment, according to the method steps described above a third metal layer is applied on the ceramic layer on the wall surface of the opening to form an electrical feed-through, which passes through the first metal layer and the second metal layer and the ceramic layer on the at least one main surface of the first metal layer.
The carrier element described here can be used in particular for an electronic component, in which at least one electronic semiconductor chip is mounted on the carrier element. The electronic semiconductor chip can in particular be mounted on the patterned third metal layer and/or can be electrically contacted by means thereof. In particular, the carrier element described here can therefore be provided for surface mounting or as a substrate for SMD components or as a substrate for non-SMD components, e.g. in the production of a so-called light kernel, an IGBT module, a substrate for a component for through-hole mounting or similar components.
Particularly advantageous aspects of the embodiments described above are provided below:
Aspect 1: A method for producing a carrier element, e.g. for use in an electronic component, has the following steps:
Aspect 2: The method according to Aspect 1, in which the first metal material comprises one or more materials selected from copper, nickel, titanium, steel, stainless steel and alloys therewith.
Aspect 3: The method according to Aspect 1 or 2, in which the second metal material comprises aluminum, in particular aluminum with a purity of greater than or equal to 99.99%.
Aspect 4: The method according to Aspect 1, 2 or 3, in which the second metal layer is applied on the first metal layer by means of an electroplating method.
Aspect 5: The method according to Aspect 4, in which the electroplating method takes place with the exclusion of oxygen and water.
Aspect 6: The method according to Aspect 1, 2, 3, 4 or 5, in which the ceramic layer is produced by means of electrolytic oxidation.
Aspect 7: The method according to Aspect 1, 2, 3, 4, 5 or 6, in which the second metal layer is applied directly on the first metal layer.
Aspect 8: The method according to Aspect 1, 2, 3, 4, 5, 6 or 7, in which the second metal layer and the ceramic layer are applied over a large area and coherently on at least one of the main surfaces of the first metal layer.
Aspect 9: The method according to Aspect 1, 2, 3, 4, 5, 6, 7 or 8, in which a patterned third metal layer is applied on the ceramic layer, wherein a seed layer is applied directly on the ceramic layer, on which seed layer the third metal layer is applied by means of an electroplating method.
Aspect 10: The method according to Aspect 9, in which the patterned third metal layer at least partly forms patterned contact surfaces and/or traces.
Aspect 11: The method according to Aspect 1, 2, 3, 4, 5, 6, 7, 8, 9 or 10, in which the first metal layer is provided with at least one opening and the second metal layer and the ceramic layer are applied on a wall surface of the opening.
Aspect 12: The method according to Aspect 11, in which a third metal layer is applied on the ceramic layer on the wall surface of the opening to form an electrical feed-through, which passes through the first metal layer and through the second metal layer and the ceramic layer on the at least one main surface of the first metal layer.
Aspect 13: The method according to Aspect 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11 or 12, in which method steps B and C are performed on each of the two main surfaces.
Aspect 14: A carrier element, e.g. for use in an electronic component, comprising
a first metal layer with a first metal material and with a first and second main surface, which face away from one another,
on at least one of the main surfaces a second metal layer with a second metal material and
on the second metal layer a dielectric ceramic layer, wherein the second metal material forms part of the ceramic layer and the ceramic layer forms a surface over the second metal layer facing away from the first metal layer.
Aspect 15: The carrier element according to Aspect 14, wherein the first metal material comprises one or more materials selected from copper, nickel, titanium, steel, stainless steel and alloys therewith and the second metal material comprises aluminum, in particular aluminum with a purity of greater than or equal to 99.99%.
Aspect 16: The carrier element according to Aspect 14 or 15, wherein the second metal layer is arranged directly on the first metal layer and the ceramic layer is arranged directly on the second metal layer.
Aspect 17: The carrier element according to Aspect 14, 15 or 16, wherein on the ceramic layer a patterned third metal layer is arranged, which at least partly forms patterned contact surfaces and/or traces.
Aspect 18: The carrier element according to Aspect 14, 15, 16 or 17, wherein
the first metal layer has at least one opening,
the second metal layer and the ceramic layer are arranged on a wall surface of the opening and
a third metal layer is arranged on the ceramic layer on the wall surface of the opening to form an electrical feed-through, which passes through the first metal layer and through the second metal layer and the ceramic layer on the at least one main surface of the first metal layer.
Aspect 19: The carrier element according to Aspect 14, 15, 16, 17 or 18, wherein the carrier element comprises on each of the main surfaces of the first metal layer a second metal layer and over this a ceramic layer.
Further advantages, advantageous embodiments and developments can be taken from the exemplary embodiments described below in association with the figures.
The figures show the following:
In the exemplary embodiments and figures, identical or similar elements or elements having the same effect can be provided with the same reference numbers. The elements illustrated and the size ratios to one another thereof should not be considered as being to scale; rather, to illustrate them better and/or to make them easier to understand, the size of individual elements such as e.g. layers, parts, components and areas may be exaggerated.
In
In a further method step, as shown in
The second metal layer is applied on each of the main surfaces 10, 11 by means of an electroplating method. In order to achieve the highest possible purity of the second metal material, in particular of greater than or equal to 99.99%, the electroplating method is performed with the exclusion of oxygen and water. As a result, the multilayer laminate shown in
The electroplating method can be performed directly on the first metal layer 1, so that no further layers are present between the second metal layers 2 and the first metal layer 1 on the main surfaces 10, 11 of the first metal layer 1 and the second metal layers 2 are arranged directly on the first metal layer 1. The second metal layers 2 are applied on the first metal layer 1 in particular over a large area and coherently and thus covering the entire main surfaces 10, 11 as far as possible. Compared with a monolayer substrate, which is formed only by a self-supporting aluminum film, the formation of a laminate composed of the first metal layer and one or two second metal layers 2 on one or both main surfaces 10, 11 of the first metal layer 1 with or composed of copper can in particular have the following advantages:
The above-mentioned features and advantages can also apply mutatis mutandis to other first metal materials.
In a further method step, as shown in
In particular, the conversion of the part of the second metal layers 2 is carried out in each case over a large area, so that the dielectric ceramic layers 3 cover the remaining second metal layers 2 over a large area and coherently. The ceramic layers 3 thus each form a surface 30 over the second metal layers 2 facing away from the first metal layer 1. In carrying out the method for converting part of each of the second metal layers 2 to dielectric ceramic layers 3, it is advantageous if at least a thin second metal layer 2 remains after the conversion, since as a result of this, good adhesion of the dielectric ceramic layers 3 on the first metal layer 1 can be achieved by means of the remaining second metal layers 2. Furthermore, it is possible to avoid a risk of an undefined conversion of the first metal material of the first metal layer 1 should the entire second metal material of the second metal layers 2 be used up.
The carrier element 100 produced in this way therefore has a five-layer construction in the exemplary embodiment shown, in which between two ceramic layers 3, two second metal layers 2 are arranged and between these in turn a first metal layer 1, wherein the said layers are each applied one directly on top of another.
Alternatively to the method shown, it may also be possible that a second metal layer 2 is applied only on one of the main surfaces 10, 11 and this is partly converted to a dielectric ceramic layer 3, so that the carrier element thus produced then has a three-layer construction and is formed by the first metal layer 1, directly on this the second metal layer 2 and directly on this the dielectric ceramic layer 3.
In association with
As shown in
Next, as shown in
Alternatively to applying a patterned photoresist 5 before carrying out the electroplating method for applying the patterned third metal layer 6, it may also be possible to apply the third metal layer 6 on the seed layer 4 in an unpatterned manner and over a large area and, following this, to apply a photoresist in a patterned manner. The photoresist in this case represents a structure which is a positive of the patterned third metal layer 6 to be produced. In regions in which the third metal layer 6 is not covered by the photoresist, the third metal layer 6 and the seed layer 4 can be removed so that, after a subsequent removal of the photoresist, the carrier element 100 shown in
In
In
The third metal layer 6 is likewise additionally applied on the wall surface of the opening 7, so that an electrical feed-through 70 can be formed, which passes through the first metal layer 1 and through the second metal layer 2 and the ceramic layer 3 on the main surfaces 10, 11 of the first metal layer 1 and thus electrically connects the top and the bottom of the carrier element 100 to one another.
In the following exemplary embodiments, electronic components 200 are described, which comprise carrier elements 100, which are produced according to the methods described in association with the preceding exemplary embodiments. To produce an electronic component like the components 200 shown below, in addition to the method steps and features described above, an electronic semiconductor chip is arranged on the carrier element 100. The electronic components 200 described below are, purely by way of example, in the form of optoelectronic components and in particular light-emitting electronic components. Alternatively, however, using the carrier elements 100 described here, other electronic components, in particular also with non-optoelectronic functionalities, can also be produced.
In
The electronic component 200 comprises a plurality of electronic semiconductor chips 21, each of which is in the form of a light-emitting semiconductor chip, in particular a light-emitting diode. On each of these, a wavelength conversion layer 22 is applied, which can convert at least part of the light generated by the light-emitting semiconductor chips 21 during operation to light with a different wavelength. Alternatively, it may also be possible that no wavelength conversion layer 22 is applied on one, more or all of the semiconductor chips 21. The semiconductor chips 21 are each arranged on and electrically connected to patterned contact surfaces 60, which are formed by parts of the patterned metal layer 6 described above. By means of bonding wires 23, the semiconductor chips 21 are connected together in series.
By means of through-connections 70 as described above, contact surfaces 60 on the top of the electronic component 200 are connected to contact surfaces 61 on the bottom of the electronic component 200 formed by a further patterned metal layer 3, so that by means of the contact surfaces 61 an electrical contacting of the electronic component 200 can take place. The contact surfaces 61 on the bottom of the electronic component 200 thus form an anode and a cathode for connecting the electronic component 200. Furthermore, on the bottom of the electronic component 200 a further contact surface 62 is formed, which is electrically insulated from the rest of the contact surfaces 61 and which is provided for a thermal connection of the electronic component 200 to an external heat sink.
On the top of the electronic component 200, furthermore, a potting 24 is applied, in which the semiconductor chips 21, at least partly the wavelength conversion layers 22 and the bonding wires are arranged. The potting 24 can be produced e.g. by means of a foil-assisted molding (FAM) method. Furthermore, it may also be possible that e.g. a dam is formed around the semiconductor chips 1, which is filled with the potting 24. The potting 24 can comprise or be composed of a plastics material, which can be transparent, reflective or light-absorbing and which can comprise fillers that are appropriate in this context.
In association with
In association with
In association with
The description with the aid of the exemplary embodiments does not limit the invention thereto. Rather, the invention comprises any new feature and any combination of features, which in particular includes any combination of features in the patent claims, even if this feature or this combination is not itself explicitly stated in the patent claims or exemplary embodiments.
Number | Date | Country | Kind |
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102015108420.1 | May 2015 | DE | national |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2016/059517 | 4/28/2016 | WO | 00 |