The present invention relates generally to improving the efficiency of coal-based power generation plants. More specifically, the present invention relates to the field of reducing the slagging and fouling at the exit of the coal boiler firebox.
Some coal boiler furnaces in use today were designed two to three decades ago. For economical reasons, these older furnaces were designed with an undersized firebox. Consequently, the furnace lacks enough surface area to effectively absorb the heat generated by the burning of the coal, and temperatures in the furnace are elevated. When the temperature of the flue gas at the exit of the firebox exceeds the specific coal ash melting temperature, the ash in the flue gas melts or partially melts so that ash deposits on the surfaces of the furnace, resulting in hard slag deposits.
These older coal boilers have been converted in the intervening years to burn types of coal that are different from what the boiler furnaces were originally designed for. Younger coal deposits are being used presently, and since younger coal tends to have more volatile content, the temperatures reached in the furnace are higher. Similar to and in conjunction with the problems related to an undersized furnace, the temperature of the heated flue gas at the exit of the firebox exceeds the ash fusion temperature, resulting in slagging and fouling of the surfaces of the waterwalls, firebox, superheater, and reheater of the steam boiler.
The problem of achieving a reduction in the temperature of the flue gas at the exit of the firebox to just below the specific ash melting temperature in order to control the slagging and fouling of the steam boiler has not been adequately resolved.
The present invention is a method for reducing the slagging and fouling of the surfaces of the waterwalls, firebox, superheater, and reheater of the furnace of a coal-fired steam boiler. The process reduces the firebox exit temperature to below the specific ash melting temperature by injecting the following, either alone or in combination, into ports located in the upper section of the firebox: recirculated flue gas from downstream of the electrostatic precipitator, atomized water, or a sorbent water slurry. All of these materials have a lower temperature than the main flue gas or require additional heat for evaporation. Mixing these materials with the main flue gas from the furnace will not affect the coal combustion process, yet will reduce the temperature of any fly ash particles in the main flue gas to below the specific ash fusion temperature, and thus, prevent slagging and fouling within the furnace.
In one aspect of the present invention, a method of reducing slagging and fouling in a furnace of a coal-fired steam boiler comprises diverting cooled flue gas from an output of a flue gas filter, wherein the flue gas filter is configured to clean the cooled flue gas by removing fly ash particulates, recirculating the cooled flue gas to one or more ports in an upper section of a firebox in the furnace, injecting the cooled flue gas into at least one of the one or more of the ports into the upper section of the firebox and mixing the cooled flue gas with hot flue gas from the furnace, the hot flue gas having a higher temperature than the cooled flue gas, wherein the mixing reduces the higher temperature of the hot flue gas from the furnace to below a threshold temperature. The method further comprises the flue gas filter receiving flue gas from an air preheater. The method further comprises the air preheater receiving flue gas from the furnace. The flue gas filter is an electrostatic precipitator or a bag house. The threshold temperature is a temperature at which fly ash melts and forms slag deposits.
In another aspect of the present invention, a method of reducing slagging and fouling in a furnace of a coal-fired steam boiler comprises atomizing a water-based coolant, injecting the water-based coolant through at least one of one or more ports into an upper section of a firebox in the furnace and mixing the water-based coolant with hot flue gas from the furnace, the hot flue gas having a higher temperature than the water-based coolant, wherein the mixing reduces the higher temperature to below a threshold temperature. The water-based coolant is water or a sorbent water slurry, and further wherein the slurry comprises water and a sorbent material. The sorbent material is calcium-based or magnesium-based. Mixing the water-based coolant with the hot flue gas from the furnace evaporates the water and carbonizes the sorbent material in the slurry. The threshold temperature is a temperature at which fly ash melts and forms slag deposits.
In yet another aspect of the present invention, a system for reducing slagging and fouling in a furnace of a coal-fired steam boiler comprises a flue gas duct coupled to a flue gas filter, and further coupled to one or more ports in an upper section of a firebox in the furnace, wherein the flue gas duct is configured to divert cooled flue gas, and further wherein the flue gas filter is configured to clean the cooled flue gas, at least one fan configured to propel the cooled flue gas through the flue gas duct and at least one recirculation jet to inject the cooled flue gas into one or more of the ports in the upper section of the firebox, wherein the cooled flue gas is mixed with hot flue gas from the furnace, and the cooled flue gas reduces the temperature of the hot flue gas from the furnace to below a threshold temperature. The flue gas filter receives flue gas from an air preheater. The air preheater receives flue gas from the furnace. The flue gas filter is an electrostatic precipitator or a bag house. The threshold temperature is a temperature at which fly ash melts and forms slag deposits.
In yet another aspect of the present invention, a system for reducing slagging and fouling in a furnace of a coal-fired steam boiler comprises at least one atomizer for atomizing a water-based coolant and at least one injection jet for injecting the atomized water-based coolant through one or more ports into an upper section of a firebox in the furnace to mix with hot flue gas from the furnace, the hot flue gas having a higher temperature than the water-based coolant, wherein the mixing reduces the higher temperature to below a threshold temperature. The water-based coolant is water or a sorbent water slurry, and further wherein the slurry comprises water and a sorbent material. The sorbent material is calcium-based or magnesium-based. Mixing the water-based coolant with the hot flue gas from the furnace evaporates the water and carbonizes the sorbent material in the slurry. The threshold temperature is a temperature at which fly ash melts and forms slag deposits.
In yet another aspect of the present invention, a system for reducing slagging and fouling in a furnace of a coal-fired steam boiler comprises means for diverting cooled flue gas from an output of a flue gas filter, wherein the flue gas filter is configured to clean the cooled flue gas by removing fly ash particulates, means for recirculating the cooled flue gas to one or more ports in an upper section of a firebox in the furnace, means for injecting the cooled flue gas into one or more of the ports in the upper section of the firebox and means for mixing the cooled flue gas with hot flue gas from the furnace, the hot flue gas having a higher temperature than the cooled flue gas, wherein the mixing reduces the higher temperature to below a threshold temperature. The flue gas filter receives flue gas from an air preheater. The air preheater receives flue gas from the furnace. The flue gas filter is an electrostatic precipitator or a bag house. The threshold temperature is a temperature at which fly ash melts and forms slag deposits.
In yet another aspect of the present invention, a system for reducing slagging and fouling in a furnace of a coal-fired steam boiler comprises means for atomizing a water-based coolant, means for injecting the water-based coolant through one or more ports into an upper section of a firebox in the furnace and means for mixing the water-based coolant with hot flue gas from the furnace, the hot flue gas having a higher temperature than the water-based coolant, wherein the mixing reduces the higher temperature to below a threshold temperature. The water-based coolant is water or a sorbent water slurry, and further wherein the slurry comprises water and a sorbent material. The sorbent material is calcium-based or magnesium-based. Mixing the water-based coolant with the hot flue gas from the furnace evaporates the water and carbonizes the sorbent material in the slurry. The threshold temperature is a temperature at which fly ash melts and forms slag deposits.
In yet another aspect of the present invention, a method of reducing slagging and fouling in a furnace of a coal-fired steam boiler comprises diverting cooled flue gas from an output of a flue gas filter, wherein the flue gas filter is configured to clean the cooled flue gas by removing fly ash particulates, recirculating the cooled flue gas to one or more ports in an upper section of a firebox in the furnace, injecting the cooled flue gas into at least one of the one or more of the ports into the upper section of the firebox, atomizing a water-based coolant, injecting the water-based coolant through at least one of the one or more ports into the upper section of the firebox in the furnace and mixing the cooled flue gas and the water-based coolant with hot flue gas from the furnace, the hot flue gas having a higher temperature than the cooled flue gas and the water-based coolant, wherein the mixing reduces the higher temperature to below a threshold temperature. The method further comprises the flue gas filter receiving flue gas from an air preheater. The method further comprises the air preheater receiving flue gas from the furnace. The threshold temperature is a temperature at which fly ash melts and forms slag deposits. The water-based coolant is water or a sorbent water slurry, and further wherein the slurry comprises water and a sorbent material.
In yet another aspect of the present invention, a system for reducing slagging and fouling in a furnace of a coal-fired steam boiler comprises a flue gas duct coupled to a flue gas filter, and further coupled to one or more ports in an upper section of a firebox in the furnace, wherein the flue gas duct is configured to divert cooled flue gas, and further wherein the flue gas filter is configured to clean the cooled flue gas, at least one fan configured to propel the cooled flue gas through the flue gas duct, at least one recirculation jet to inject the cooled flue gas into at least one of the one or more of the ports in the upper section of the firebox, at least one atomizer for atomizing a water-based coolant and at least one injection jet for injecting the water-based coolant into at least one of the one or more ports in the upper section of the firebox in the furnace, wherein the cooled flue gas and the water-based coolant mix with hot flue gas from the furnace having a higher temperature than the cooled flue gas and the water-based coolant mix, and the cooled flue gas and the water-based coolant reduce the temperature of the hot flue gas to below a threshold temperature. The flue gas filter receives flue gas from an air preheater. The air preheater receives flue gas from the furnace. The threshold temperature is a temperature at which fly ash melts and forms slag deposits. The water-based coolant is water or a sorbent water slurry, and further wherein the slurry comprises water and a sorbent material.
In yet another aspect of the present invention, a system for reducing slagging and fouling in a furnace of a coal-fired steam boiler comprises means for diverting cooled flue gas from an output of a flue gas filter, wherein the flue gas filter is configured to clean the cooled flue gas by removing fly ash particulates, means for recirculating the cooled flue gas to one or more ports in an upper section of a firebox in the furnace, means for injecting the cooled flue gas into at least one of the one or more of the ports into the upper section of the firebox, means for atomizing a water-based coolant, means for injecting the water-based coolant through at least one or more of the one or more ports into the upper section of the firebox in the furnace and means for mixing the cooled flue gas and the water-based coolant with hot flue gas from the furnace, the hot flue gas having a higher temperature than the cooled flue gas and the water-based coolant, wherein the mixing reduces the higher temperature to below a threshold temperature. The flue gas filter receives flue gas from an air preheater. The air preheater receives flue gas from the furnace. The threshold temperature is a temperature at which fly ash melts and forms slag deposits. The water-based coolant is water or a sorbent water slurry, and further wherein the slurry comprises water and a sorbent material.
The preferred embodiment of the present invention takes a portion of the flue gas downstream from the ESP 270 and with the use of the fan 280, recirculates the clean and significantly cooler flue gas through the flue gas duct 290 to the ports 295 located in the upper section of the firebox 210, and injects the cool flue gas using recirculation jets. The recirculation jets may be positioned inside, or farther away from the firebox 210, according to the dimensions of the particular furnace 250 in which the present invention is implemented. The cooler recirculated flue gas mixes with the higher temperature main flue gas coming directly from the coal combustion in the firebox 210, thus reducing the temperature of the main flue gas to below the specific fly ash melting temperature. This process prevents slagging and fouling of the surfaces of the furnace. In particular, this prevents slagging and fouling in the firebox 210, the waterwalls 215, the superheater 230, and the reheater 240, by particles of molten fly ash.
In yet another alternative embodiment of the present invention, a readily available low-cost sorbent additive, preferably CaCO3 or MgCO3 or other similar sorbent, is mixed with water to form a slurry and injected into the upper section of the firebox 210 at the same location as the flue gas recirculation ports 295 shown in FIG. 2. The water slurry jet is carried out by the flue gas recirculation jets and mixes with the main flue gas flow from the furnace. The higher temperature of the main flue gas flow causes the water droplets to evaporate and the sorbent to dissociate, resulting in a significant amount of heat extraction from the main flue gas flow and a corresponding decrease in the temperature of the flue gas. By optimizing the amount of sorbent slurry recirculated in the flue gas in the furnace, slagging and fouling on the surfaces at the boiler furnace is minimized.
The process of flue gas recirculation is useful alone or in conjunction with water injection or slurry injection, or both, to prevent slagging and fouling of the surfaces of the furnace by melted or partially melted fly ash. Preferably, re-circulated flue gas is utilized independently. However, alternative embodiments may include any combination of flue gas recirculation, water injection, and slurry injection. No re-design of the original furnace is necessary in order to implement these processes for preventing slagging and fouling of the surfaces of the furnace due to melted fly ash.
The present invention has been described in terms of specific embodiments incorporating details to facilitate the understanding of the principles of construction and operation of the invention. Such reference herein to specific embodiments and details thereof is not intended to limit the scope of the claims appended hereto. It will be apparent to those skilled in the art that modifications can be made in the embodiment chosen for illustration without departing from the spirit and scope of the invention. Specifically, it will be apparent to one of ordinary skill in the art that the device of the present invention could be implemented in several different ways and have several different appearances.
This Patent Application claims priority under 35 U.S.C. §119 (e) of the co-pending U.S. Provisional Patent Application, Ser. No. 60/409,611, filed Sep. 9, 2002, and entitled, “METHOD FOR REDUCTION OF SLAGGING AND FOULING OF THE WATERWALLS AND OF THE FIREBOX AND SUPERHEATER AND REHEATER OF STEAM BOILERS WITH COAL COMBUSTION.” The Provisional Patent Application, Ser. No. 60/409,611, filed Sep. 9, 2002, and entitled, “METHOD FOR REDUCTION OF SLAGGING AND FOULING OF THE WATERWALLS AND OF THE FIREBOX AND SUPERHEATER AND REHEATER OF STEAM BOILERS WITH COAL COMBUSTION” is also hereby incorporated by reference in its entirety. This Patent Application claims priority under 35 U.S.C. §119 (e) of the co-pending U.S. Provisional Patent Application, Ser. No. 60/410,489, filed Sep. 12, 2002, and entitled, “METHOD OF USING WATER INJECTION IN THE STEAM BOILERS FURNACE WITH COAL COMBUSTION TO PREVENT SLAGGING AND FOULING IN THE FURNACE AND THE CONVECTIVE PASS.” The Provisional Patent Application, Ser. No. 60/410,489, filed Sep. 12, 2002, and entitled, “METHOD OF USING WATER INJECTION IN THE STEAM BOILERS FURNACE WITH COAL COMBUSTION TO PREVENT SLAGGING AND FOULING IN THE FURNACE AND THE CONVECTIVE PASS” is also hereby incorporated by reference in its entirety.
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