Method for the camera-assisted detection of the radiation intensity of a gaseous chemical reaction product and uses of the said method and corresponding device.
The invention relates to a method for the camera-assisted detection of the radiation intensity of a chemical reaction product, in particular a gaseous reaction product. Furthermore, the invention relates to suitable applications for the method.
From the German patent publication DE 197 10 206 A1, a method and a device are known for a combustion analysis as well as flame monitoring in a combustion chamber. In order to rapidly detect the temperature distribution, the concentration distribution of reaction products as a result of the combustion process, as well as the parameters of the flame, a picture is taken of the flame to determine from the locally defined intensities of the picture, a spatial distribution of the combustion process characterizing parameters, at least for a predetermined spectral range. An optical system of the device comprises a lens for detecting the flame, as well as three downstream beam splitters. The bundled beams that are detected by the lens are supplied to at least four spectral ranges by means of the beam splitters and then submitted to a CCD-image sensor.
From European Patent application EP 1 091 175 B1, a method as well as a corresponding device are known for determining the excess air in a combustion process, where the formation rates of the reaction products, CN and CO from the combustion reaction are determined. Subsequently, the ratio of the determined formation rates is expressed as a value represented by the excess of air. For detecting the beam intensities at least four special cameras are contemplated.
In the presently known methods and devices, the drawback is that the camera systems must be oriented in possibly pixel-exact manner relative to each other in order to avoid reproduction errors between the spectrally different evaluation ranges. Thereby, additional thermal expansion effects as well as mechanical vibration that impact the optical system must be taken into account. Accordingly, each optical system must be built for a robust and stable condition. As a result, the systems are very expensive.
A further disadvantage is the time consuming mechanical adjustment of such an optical system. In addition, such systems are comparatively maintenance intensive.
A further big disadvantage is the necessary temporal synchronization between the cameras in order to realize a temporal coordination of each of the brightness signals of the cameras for the different split wave lengths ranges. Thus, the control-technical expenditure is correspondingly high.
Starting from the prior art as discussed, it is an object of the invention, to provide a method for camera assisted detection that is less costly.
It is a further object of the invention to provide suitable applications for the method according to the present invention.
Finally, it is an object of the invention to provide a corresponding device, which is less complex and at the same time more reliable.
These objects are solved in accordance with the method as set forth in claim 1. Advantageous variants of the method are set forth in the dependent claims 2 to 5. In claims 6 and 7 suitable advantageous applications of the method according to the invention are also set forth. Claim 8 sets forth a device corresponding to the method according to the present invention. Claims 9 and 10 set forth advantageous embodiments of the device.
In accordance with the invention, a RGB-color camera is provided for the detection of the radiation intensity of a reaction product in a red, green and blue range of wavelength. From the respective blue signal of the RGB-color camera, a band radiation value of each of the reaction products is formed. From the respective red-and/or green signal of the RGB-color camera, a temperature radiation value is formed by means of pyrometry or comparative pyrometry. In other words, from each of the red signals or from each of the green signals, a temperature radiation value can be determined by means of pyrometry. Alternatively, from each of the red and green signals, the temperature radiation value can be formed by means of comparative pyrometry. The latter is more precise as compared to the measurement of solely the red signal or the green signal due to the ratio formation of the red signal and the green signal. Finally, from the difference of each of the band radiation value and the corresponding temperature radiation value, an emission ratio for the radiation intensity of each reaction product is computed. By means of the simultaneous pyrometric measurement, the thermal characteristic radiation of each of the reaction products can be detected and compensated for.
The colors are designated with respect to the optical detection capacity by humans. The chemical reaction products are for example, gaseous radicals, such as for example, CO—, C2—, CH—, CHOH—, CHO—, CN—, NH—, OH—, or O2 radicals which typically result from a high temperature process of above 1000° C. when burning hydrocarbons. The reaction products are alternatively, or additionally elemental gases such as for example O2, N2 or noble gases, which for example diffuse from the materials, or substances at a high temperature process or which are added in the high temperature process.
The essential principle of the present invention is in the use of a RGB-color camera instead of several black and white cameras. Such a camera is already provided with the required wave ranges necessary for the determination of the radiation intensity.
Thus, this already reduces the number of cameras necessary by two. In other words, for the detection of the emission rate of a chemical reaction product, only a single camera is necessary. For the device according to the publications as afore-discussed, only two RGB-color cameras would be needed instead of the four black and while cameras. As a result, this device represents a far simpler assembly. Since the cost for the RGB-color camera is only slightly higher than that of a black and white camera with comparable resolution and sensitivity, the cost for the assembly are drastically reduced.
In addition, advantageously, the number of required beam splitters is also reduced. Thus, for the detection of the radiation intensity of a single chemical reaction product, a beam splitter is not even required. Generally, the number of required beam splitters correspond to the number of radiation intensities to be detected and reduced by one. Contrariwise, with the devices in the prior art, the number is increased by one.
A far greater advantage however, is such that the numerous RGB color pixels are already from the start, locally and temporally coordinated in a color sensor chip of a RGB-color camera and thereby already ideally adjusted. As a result, the mechanical adjusting job directed to the orientation of the cameras as well as the technical control effort directed to the temporal synchronization of the brightness signal for each wave length range is advantageously eliminated.
Typically, the RGB color pixel consists of one subpixel each for the color red, green and blue, wherein each subpixel if reserved for each of the colors red, green and blue. Alternatively, there can also be four subpixels per RGB color pixel, in particular, a red, two green and a blue subpixel. The three subpixels are thus also at the same resolution location within a color pixel. At the same time, the selection of each RGB subpixel of a color sensor follows, such as for example with a CCD color sensor (CCD, for charge coupled device) or a MOS color sensor (MOS, for metal oxide semiconductor) and are thus synchronized either by lines or also by image.
According to a variant of the method, an optical rejection filter with a predetermined acceptance wave length for a characteristic spectral line for the respective reaction product is placed anterior at each of the RGB-color cameras. With this, an especially high selectivity can be realized with respect to the emission of a chemical reaction product. Typically, such a rejection filter exhibits an acceptance wave length range of approximately 5 to 10 nm. Thus, for example, the specific frequency band of a line spectrum for CO (carbon monoxide) is in the range of 445 to 455 nm and for the reaction product CN (for cyanide) in the range of 430 to 440 nm (see also
Such a rejection filter permits transmission of more than 90% of the incoming emission. The filter further preferably permits transmission of only a few percent, in particular only maximal 1% of the incoming emission in the exclusion range. Moreover, an IR filter, that is an infrared filter can be placed anterior at the rejection filter in order to filter out the majority of the incoming heat radiation. Both filters can also be integrated into a single rejection filter.
According to a further variant of the method, a light source is directed to the reaction product regarding the detection of its radiation intensity, in order to optically excite each of the reaction products into emission of a characteristic emission spectrum. The light source preferably emits a bundled light beam, in particular a laser beam. Especially, the light source emits light of a wave length of less than 500 nm, such as for example 250 nm. The emitted light is thus within a range which extends from blue, violet to ultraviolet.
According to another variant of the process, the reaction product to be detected with respect to its light intensity is formed in a high temperature process and/or is already present there. Thus, the respective reaction product radiates a characteristic emission spectrum which is predominantly in the wave length range of blue to violet. Indeed in this wave length range, the chemical reaction products, in particular, the radicals, and the optically excited gases radiate their emission spectrum as chemo-luminescence in the form of distributed spectral lines. The term “chemo-luminescence” indicates an emission of light not of a thermal source. In particular, for detecting the radiation intensity, only the frequency bands of spectral lines of a specific radiation product to be detected are being observed and filtered out, and wherein possibly further reaction products do not exhibit any characteristic spectral lines.
According to yet another variant of the process, (precisely) two RGB cameras a provided for the detection of radiation intensity which result from the combustion process and which produce the chemical reaction products CN and CO in a red, green and blue wave length range. According to the present invention from each of the blue signals of the two RGB-color cameras a band radiation value of the reaction product CN and a band radiation value of the reaction product CO is formed. From each of the red and green signals of the two color cameras, a respective temperature radiation value is formed by means of comparative pyrometry. Furthermore, from each difference of the band radiation values and the corresponding temperature radiation values a CN— formation rate and a CO formation rate are generated. Finally, from the ratio K(CN)/K(CO) of the detected formation rates, a regulating variable representing the excess air during the combustion process is generated.
Thus, a controlled, optimal combustion of combustible material based on hydrocarbons, such as coal, oil or natural gas is realized, where the air supply and/or the supply of auxiliary materials, such as additives are controlled in dependence of the determined regulating variable.
The process of the present invention is advantageous for detecting at least one formation rate of a respective chemical reaction product at a combustion process in a power station, a garbage incineration installation, in an industrial oven or in a domestic burner installation, specifically, for the generation of thermal energy. The reaction products in question are for example CO—, C2—, CH—, CHOH—, CHO—, CN— or NH radicals which are formed by hydrocarbon flame in a combustion chamber.
The process according to the present invention is respectively also applicable for use in a combustion engine or a gear drive, in particular, a traffic vehicle such as a motor car, a rail vehicle, boat or air plane. Thus, the combustion process in the inside of the cylinder of a benzene or diesel motor can for example be observed by means of a device corresponding to the respective process. To this end, an opening passage can be provided in the cylinder through which the optical detection of the combustion flames is carried out while the combustion engine is running. An optimal combustion can then be adjusted in dependence on the determined formation rates, in particular, the formation rates for CN and CO. Preferably, the steps of the method according to the invention are carried out on the basis of a processor-based work unit of the motor control, by means of which the air and fuel supply are adjustable. One or more devices corresponding to the method can be attached to the respective cylinder or screwed on similar to a spark plug. In a device which is preferably configured as an encapsulated device, a RGB color sensor with a placed anterior rejection filter for a respective reaction product is integrated in a pressure-tight manner with respect to the cylinder chamber. The processing unit is preferably integrated as a part of the device into the motor control. Instead of a combustion motor, the combustion process in a turbine such as for example a kerosene- or gas turbine can be monitored and observed. In that case, the afore-described the device is disposed in the area of the turbine combustion chamber.
Furthermore, the process according to the invention can be advantageously applied for the detection of at least a volume rate of a respective reaction product in a combustion process in a blast furnace for the metal production industry, in a diffusion furnace for the semiconductor industry or in a furnace where metal is hardened or sintered. In that case, compounds that are generated in the combustion chamber, can be optically detected, in particular, diffusing compounds, such as for example those that result from the hardening process by means of nitrogenizing. In dependence of the detected volume rate, an overriding process computer can be engaged for the method and the technical control. Preferably, the reaction products that are to be detected in such a combustion process may also be optically excited by means of a light source.
Likewise, the compounds that are added during the combustion process such as for example, dopant compounds in the semiconductor industry such as indium, gallium, arsenide, phosphorus and similar, are detected with respect of their volume rate, whereby by means of the simultaneous pyrometric measurement, the thermal characteristic radiation is detected and compensated for. Thus, a controlled optimal adjustment of a concentration of a specific dopant present in the combustion chamber is advantageously realized.
An object of the present invention is furthermore solved by means of a device corresponding to the method of the invention. Such a device includes a RGB-color camera for the detection of the radiation intensity of a reaction product in the red, green and blue wave length range. It furthermore includes a signal- and/or data technological processing unit connected to the respective RGB-color camera. The preferably processor-supported processing unit includes means for the detection of a radiation value of bands of the respective reaction products from a respective blue signal of the RGB camera. Furthermore, it includes means to form a temperature radiation value from each the red and green signal of the RGB-color camera by a ratio pyrometry. Finally it includes means to form a respective emission rate for the radiation intensity for each reaction product from the difference of each band radiation value and each of the corresponding temperature radiation values.
The device comprises in particular, a number of beam splitters, which are anterior to at least two RGB-color cameras, wherein the number of beam splitters is then reduced by the value 1 as compared to the number of RGB-color cameras.
The invention and advantageous embodiments are described in more detail in the following paragraphs where in the following figures it is shown:
In accordance with the invention, the processing unit 6 includes a first partial unit 61 as a means to determine a radiation value TS though a comparative pyrometry from the red- and green signal IR, IG of the RGB-color camera 8. Furthermore, the processing unit 6 includes means not shown here in detail which form the blue signal IB of RGB-color camera 8 from a corresponding band radiation value BS of the reaction product. In the example of
Alternatively thereto and not shown in
The device as shown in
In present
Furthermore, the processing unit 6 of device according to
Number | Date | Country | Kind |
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10 2007 012 553.6 | Mar 2007 | DE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP2008/001923 | 3/11/2008 | WO | 00 | 8/20/2009 |