Patent Application
20100127217
This invention relates to the on-line analysis of vapour phase process streams in the steam reforming of hydrocarbons utilising near infra-red spectroscopy (NIR).
Synthesis gases for the production of chemicals such as methanol customarily have been derived from the steam reforming of a hydrocarbon, typically naphtha or natural gas in the presence of a catalyst. The synthesis gas produced by the steam reforming reaction comprises a mixture of carbon monoxide, hydrogen and carbon dioxide. Generally, the molar ratio of carbon monoxide:hydrogen produced is not optimum for use in downstream chemical processes such as the production of methanol. Accordingly, it is normal practice to remove the carbon dioxide co-produced in the reforming reaction and recycle a desired quantity back to the reformer. The addition of carbon dioxide to the reformer feed alters the carbon monoxide:hydrogen molar ratio. Careful control of the amount of recycled carbon dioxide allows a desired carbon monoxide:hydrogen ratio to be achieved. In conventional practice, separation of carbon dioxide is achieved by absorption stripping with a solvent, typically aqueous alkanolamines, followed by compression to reach the necessary pressure for recycle back to the reformer. It would be advantageous if the amount of carbon dioxide produced in the steam reforming reaction could be tailored or minimised.
The feed components to a steam reforming reaction are water (steam), hydrocarbon and optionally carbon dioxide. The feed components are typically pre-heated to a temperature of at least 500° C. and fed to the reformer at a pressure of at least 15 barg. Under these conditions, the feed components are present as gases.
A conventional vapour phase analytical technique is gas chromatography. However, when gas chromatography is employed, it has been found that condensation of some of the components, such as steam, can occur which makes it difficult to obtain compositional data of acceptable precision. It would therefore be highly desirable to maintain the process stream in the vapour phase during analysis. However, it would be undesirable to perform analysis on process streams of very high temperature, such as the temperatures employed in a steam reformer, since analytical equipment which can withstand such temperatures may not be readily available, or may be expensive.
Accordingly, the present invention provides a method for the on-line analysis of a process stream, which process stream is a feedstream to or an exit stream from a steam reformer, which process stream has a temperature of at least 200° C., the components of which process stream are in the vapour phase, which method comprises:
Typically, in the steam reforming of a hydrocarbon, the components: steam, hydrocarbon and optionally carbon dioxide are fed to a reformer at high temperature and pressure. The hydrocarbon may be, for example naphtha or natural gas. Natural gas predominantly comprises methane but may also contain smaller quantities of lower aliphatic hydrocarbons such as ethane and propane. Thus, the process stream may comprise the components steam, methane and carbon dioxide. The carbon dioxide may be from a carbon dioxide-containing recycle stream or from any other source. Advantageously, the slipstream may be taken from the feedstream to the reformer at a point subsequent to the tie-in of a carbon dioxide recycle feed.
The steam reforming reaction produces an exit stream comprising carbon monoxide, hydrogen, unconverted hydrocarbon and carbon dioxide. Thus, the process stream may comprise the components carbon monoxide, hydrogen, methane and carbon dioxide. Typically, in commercial practice, carbon dioxide is separated from the exit stream and at least a portion of the carbon dioxide is recycled back to the reformer. Advantageously, the slipstream may be taken from the exit stream from the reformer at a point prior to separation of carbon dioxide from the exit stream.
The steam reformer can be any suitable reformer unit, such as those available commercially, and may be a single-pass reformer or a two-stage reformer. Typically, the reformer is a fired furnace containing parallel tube banks filled with a conventional steam reforming catalyst such as alumina supported nickel oxide.
In the method of the present invention, the components of the process stream are in the vapour phase but the components may also be at pressure. The temperature and pressure of the process stream will depend upon the nature of the steam reforming process. The method of the present invention is suitable for analysing feed streams to and/or exit streams from a steam reformer which have temperatures of at least 200° C., such as 200 to 500° C., for example 200 to 350° C. The process stream may be at atmospheric pressure or higher, for example, at a pressure of at least 10 barg, such as in the range 10 barg to 100 barg.
The slipstream consists of a portion of the process stream. The volume of the slipstream is not critical; however, the speed at which cooling of the slipstream can be carried out will increase with decreasing slipstream volume. Faster cooling of the slipstream may allow the method of the present invention to be carried out more frequently.
Cooling of the slipstream may be effected by air-cooling. Alternatively, cooling of the slipstream may be effected by the use of a water jacket.
By cooling the slipstream to a temperature above its dew point, i.e. the temperature at which components of the slipstream would begin to condense, the components of the slipstream are maintained in the vapour phase. Thus, the present invention allows the determination of compositional data of high precision, since condensation of components during analysis is avoided.
In practice, a slipstream is suitably cooled to a temperature of at least 20° C. above the dew point of the slipstream to avoid the formation of cold spots in the stream. Suitably, the slipstream is maintained at a temperature in the range 200 to 300° C.
Near infra-red (NIR) spectroscopic techniques can be used to characterise molecules which absorb in the near infra-red portion of the spectrum. NIR spectroscopy permits both qualitative and quantitative analyses. NIR analysers are available commercially. The principal components of a MR analyser include a detector, a light source, a means of transferring the light signal to the detector and a spectrometer. The detector is coupled to the means for transferring the light signal to the light source and the spectrometer.
Light of wavelength 10000 to 4000 cm−1 is transmitted to the detector by any suitable means known in the art. Typically, such transfer means include fibre optic cables, for example, low OH silica fibre optic cables. Suitably, for use at high temperatures, the fibre optic cables are coated with a coating that is not susceptible to degradation at temperatures above 200° C. For example, the fibre optic cables may be coated with a polyimide material, or with a metal, such as gold.
The source of light is not deemed critical and may be, for example, a quartz halogen light source or near infra-red light emitting diodes.
Analysis of the slipstream is conducted in a detector which operates in the near infra-red region (10000 cm−1 to 4000 cm−1).
For use in the method of the present invention, wherein the components are in the vapour phase, it is preferred that a detector of the flow cell type is employed. Flow cells are available commercially, for example, from Specac Limited.
The choice of the NIR flow cell should be such that analysis of the components can be achieved under the temperature and pressure conditions of the cooled slipstream. For example, the flow cell may be capable of being electronically heated to a temperature above the dew point of the slipstream. NIR flow cells suitable for use in the method of the present invention include the Typhoon-T cell (Specac Limited).
Suitably, the body of the flow cell is made of a high quality stainless steel, such as stainless steel grade 316L, duplex stainless steel or Hastelloy C.
Suitably, the cell windows are comprised of a material which is transparent in the near infra-red, is chemically resistant and mechanically robust under the conditions of the cooled slipstream. A suitable cell window material is, for example, sapphire.
The cell windows are adhered to the body of the flow cell by a sealing material which is capable of withstanding the temperature and pressure of the cooled slipstream. For example, appropriate epoxy based sealants may be employed.
The cell pathlength used is dependent upon the specific pressure and temperature of the components to be analysed. Increasing the intensity of a spectrum results in a non-linear correlation between absorption strength and concentration. A non-linear correlation is undesirable as it may give rise to false analysis results. Suitably, therefore, the Spectrum of an analysed component has an absorption of less than 1.5 absorption units.
The intensity of a spectrum increases with pressure. Thus, as the pressure of the components to be analysed increases, the cell pathlength should be correspondingly decreased. For example, where the pressure of the components to be analysed is in the range 12 to 25 barg, the cell pathlength may be in the range 5 to 10 cm. Typically, feedstreams to and exit streams from a natural gas steam reformer are at approximately 17 barg pressure, thus, a cell pathlength in the range 7.0 to 8.0 cm, such as 7.5 cm will allow quantification of steam, methane, carbon dioxide and other components absorbing in the near infra-red.
Many types of NIR spectrometer are commercially available and may be employed in the method of the present invention. For example, the NIR spectrometer may be a Fourier Transform infra-red spectrometer (FTIR spectrometer) or a diode array spectrometer. As is well known in the art, operation of a FTIR spectrometer at high resolution provides distortion free spectra whilst operation at low resolution allows a more frequent analysis of the components of a process stream. Suitably, the frequency of measurement should be effective to enable process control to be achieved. Using an FTIR spectrometer, it has been found that a resolution in the range 0.1 to 2 cm−1 enables distortion free spectra to be achieved at a frequency of approximately thirty seconds. However, the use of resolutions above 4 cm−1 such as in the range 4 to 16 cm−1 will enable faster response times to be achieved.
The spectral region where water, methane and carbon dioxide can be quantified is 7500 to 4800 cm−1.
The spectrum obtained is recorded in the NIR spectrometer. The spectrum is correlated to reference data of the process stream components using chemometric techniques to simply compute a direct value for the concentration of each of the components analysed and/or the partial pressure of each component analysed. Techniques that may be used include partial least squares (PLS), multiple linear regression (MLR) and principal component regression (PCR). Software for PLS type analysis is commercially available, for example, GRAMS software by Galactic Limited and MATLAB by Mathsoft Inc. MATLAB may also be used for MLR and PCR type analyses.
Typically, in the steam reforming of natural gas, the feedstream to a steam reformer will comprise methane, carbon dioxide and steam. Calibration mixtures can be generated off-line by a flow blending technique. In the flow blending technique, the gaseous components are blended with a liquid component under the desired pressure and heated to the desired temperature, to form a blended vapour mixture. The vapour mixture is then passed through a NIRR flow cell to generate spectra. Control of the liquid and gas flows may be by means of mass flow controllers. The liquid may be fed from a stainless steel bottle which has been pressurised with helium to avoid pulsation of the flow. The vapour return from the NIR flow cell is cooled and the liquid condensate collected in a knock out bottle. The gas can then be used to control the system pressure before being sent to vent. The NIR spectra generated from the vapour mixtures are then used to establish the calibration models.
In addition to the off-line calibration data, the accuracy of the calibration model may be verified and/or the model improved by taking samples from process streams and analysing the samples by standard analytical techniques such as gas chromatography. Sampling of vapour phase process streams may be carried out by employing a stainless steel bottle of suitable capacity such as 300 ml. Prior to use, the bottle is pressure purged with an inert gas which is not present in the process stream to be analysed. The choice of inert gas is also dependent upon the chromatography. Suitably, the inert gas may be krypton. In addition, a small volume of solvent (about 5 ml) is injected into the bottle via septum. This is necessary in order to quantitatively wash out the sample components that condense onto the inner walls of the bottle. Again the solvent used must not be in the process and must be miscible with all condensed components. In the case of a reformer feedstream, methanol is suitable as the solvent. An internal standard may be present in the methanol to aid quantitation. When installed on the plant the bottle is opened up to the process very briefly (approx 0.5 second). This gives supersonic sample flows into the bottle to mitigate loss of the inert gas or solvent. The bottle can then be removed from the plant and the gas and/or liquid contents analysed off-line by gas chromatography. Any liquid contained in the bottle should be removed and analysed by gas chromatography. Similarly, the gas is analysed by gas chromatography. From the dilution of the krypton that has occurred the volume of sample that was actually collected can be calculated. The number of moles of each component in each phase is then calculated and this readily allows the vapour concentrations in vol % to be determined. This data can then be used to verify and/or improve the accuracy of the calibration model.
The method of the present invention may be employed to determine the concentration of one or more of the NIR-absorbing components of a process stream fed to or exiting from a steam reformer.
Alternatively, the method of the present invention may be employed to determine the partial pressure of one or more of the NIR-absorbing components of a process stream fed to or exiting from a steam reformer.
Where the process stream comprises water, methane and carbon dioxide, the obtained spectrum is correlated to reference data using chemometric techniques to determine the concentration of one or more of water, methane and carbon dioxide. Once such compositional data is known, if necessary, the flow rates of the feed components may be adjusted, thereby improving the efficiency of the process.
Alternatively, the obtained spectrum for water, methane and carbon dioxide may be correlated to reference data using chemometric techniques to determine the partial pressure of one or more of water, methane and carbon dioxide. Some gases such as hydrogen and nitrogen have no dipole and therefore do not absorb infra-red radiation. Consequently, these gases are not analysable by NIR. However, nitrogen may be present in the feed stream to a reformer and hydrogen is present in the exit stream from a reformer. Conventionally, chemical plants, including reformers have pressure detectors associated therewith. These pressure detectors, such as transducers, determine the total gas pressure of a process stream. Thus, by using the method of the present invention, the sum of the partial pressures of the NIR-absorbing components of a process stream may be determined. A comparison of the pressure value determined by the NIR method of the present invention with the absolute gas pressure data from, for example, a pressure transducer, will enable the pressure of the remaining gaseous components, for example, nitrogen and hydrogen, to be determined. This is of particular value in situations where the amount of nitrogen present in the natural gas changes, which may occur, for example, if the supply source of natural gas is changed.
One advantage of the method of the present invention is the ability to rapidly determine compositional information of a vapour phase process stream, at process pressure and at a temperature above the dew point of the process stream. In practicing the invention, measurement of the concentrations of steam and/or hydrocarbon, such as methane, and/or carbon dioxide in the cooled slipstream according to the present invention can be made continually, for example, as often as every thirty seconds.
Where the method of the present invention is operated continually, it is preferred that the temperature to which the slipstream is cooled remains constant. This is advantageous, since the intensity of the spectra obtained will be unaffected by changing temperature, thereby simplifying the correlation of the spectra to established calibration models.
Further, continual operation of the method of the present invention allows the method to be suitable for effecting process control. For example, by continually monitoring the concentration of unconverted methane in the exit stream from a reformer, the flow rate (concentration) of methane to the reformer may be adjusted to maximise the amount of carbon monoxide produced, thereby improving the efficiency of the reforming process.
Accordingly, the present invention further provides a method for effecting process control in a steam reforming process, said process having a process stream which is a feedstream to or an exit stream from a steam reformer, wherein the process stream has a temperature of at least 200° C., the components of which process stream are in the vapour phase, wherein said method comprises:
Process control of a chemical process, based on the information obtained from the near infra-red analysis of a slipstream from the feed stream to and/or exit streams from a steam reformer can be either manual or automatic. Preferably, the data obtained from the near infra-red analysis is fed to a computerised control unit, which automatically adjusts the feed components to the steam reformer to achieve the desired flow rates for the components.
Alternatively, the data may be fed to a display unit and is interpreted by an operator who adjusts the flow rates of the feed components manually.
The method of the present invention will now be illustrated by the following non-limiting example and with reference to
The apparatus comprises thermal mass flow controllers (1), a controlled evaporator mixer (CEM) (2), a NIR flow cell (3), fibre optic cables (4) and a NIR spectrometer (5).
In use, a component in the liquid phase is fed via line (6) to a heated controlled evaporator mixer (2) where it is evaporated to form a vapour. Gaseous components are fed via lines 7 and 8 to the heated controlled evaporator mixer (2) where they are mixed with the vapourised liquid. The flows of the liquid and the gaseous components to the heated controlled evaporator mixer (2) may be regulated by thermal mass flow controllers (1). The vapour mixture produced in the heated controlled evaporator mixer (2) is passed to the NIR flow cell (3). Effluent from the NIR flow cell (3) is passed through a heat-exchanger (9) and vented via a condenser (10), which knocks out liquids and a pressure regulator (11), which controls the pressure in the system. The NIR flow cell (3) is coupled by fibre optic cables (4) to a NIR spectrometer (5). The vapour mixture in the NIR flow cell (3) is analysed by the NIR spectrometer (5) using multiple scans at variable resolution between 10000 and 4000 cm-1 and employing the flow cell under nitrogen or a fibre loop as reference.
The apparatus arrangement shown in
Calibration mixtures of water vapour, methane and carbon dioxide were prepared as follows. Water (0 to 10 g/hr) was vaporised, mixed with methane (0 to 3 nl/hr) and carbon dioxide (0 to 3 nl/hr) in the controlled evaporator mixer and fed to the flow cell at 200 to 280° C. and 15 to 20 bara total pressure. This produced vapour mixtures containing 8 to 12 bara water vapour, 2 to 6 bara methane, and 1 to 4 bara carbon dioxide. NIR spectra of the mixtures were recorded between 10000 and 4000 wavenumbers at 2 wavenumber resolution using the flow cell under nitrogen at the measuring temperature as reference.
A sample spectrum showing regions of carbon dioxide (2.60 bara), methane (3.64 bara) and water vapour (10.81 bara) absorption at total pressure 17.05 bara and 240° C. is shown in
A slipstream from a steam reformer feedstream comprising steam, carbon dioxide and methane at a temperature of approx. 278° C. and at a pressure of approx. 17 barg is air-cooled to a temperature of 250 to 260° C. and is subsequently analysed by recording NIR spectra between 10000 and 4000 wavenumbers at 2 wavenumber resolution at intervals of 30 seconds using an NIR spectrometer, NIR flow cell and fibre optic cables of the type described above. The partial least squares calibration models are applied to the generated NIR spectra so that the concentration of each of the components, methane, steam and carbon dioxide in the reformer feed stream is determined. In response to the determined concentration of the components methane, steam and carbon dioxide, the concentration of methane in the feedstream to the steam reformer may be adjusted.
| Number | Date | Country | Kind |
|---|---|---|---|
| 07252448.1 | Jun 2007 | EP | regional |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/GB2008/001778 | 5/23/2008 | WO | 00 | 12/14/2009 |
