Patent Application
20210325156
The present invention relates in general to the field of ammunition, specifically to compositions of matter and methods of making and using polymeric ammunition cartridge casings having visual indicia thereon.
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Without limiting the scope of the invention, its background is described in connection with lightweight polymer cartridge casing ammunition. Conventional ammunition cartridge casings for rifles and machine guns, as well as larger caliber weapons, are made from brass, which is heavy, expensive, and potentially hazardous. There exists a need for an affordable lighter weight replacement for brass ammunition cartridge cases that can increase mission performance and operational capabilities. Lightweight polymer cartridge casing ammunition must meet the reliability and performance standards of existing fielded ammunition and be interchangeable with brass cartridge casing ammunition in existing weaponry. Reliable cartridge casings manufacture requires uniformity (e.g., bullet seating, bullet-to-casing fit, casing strength, etc.) from one cartridge to the next in order to obtain consistent pressures within the casing during firing prior to bullet and casing separation to create uniformed ballistic performance. Plastic cartridge casings have been known for many years but have failed to provide satisfactory ammunition that could be produced in commercial quantities with sufficient safety, ballistic, handling characteristics, and survive physical and natural conditions to which it will be exposed during the ammunition's intended life cycle; however, these characteristics have not been achieved.
For example, U.S. patent application Ser. No. 11/160,682 discloses a base for a cartridge casing body for an ammunition article, the base having an ignition device; an attachment device at one end thereof, the attachment device being adapted to the base to a cartridge casing body; wherein the base is made from plastic, ceramic, or a composite material.
U.S. Pat. No. 7,610,858 discloses an ammunition cartridge assembled from a substantially cylindrical polymeric cartridge casing body defining a casing headspace with an open projectile-end and an end opposing the projectile-end, wherein the casing body has a substantially cylindrical injection molded polymeric bullet-end component with opposing first and second ends, the first end of which is the projectile-end of the casing body and the second end has a male or female coupling element; and a cylindrical polymeric middle body component with opposing first and second ends, wherein the first end has a coupling element that is a mate for the projectile-end coupling element and joins the first end of the middle body component to the second end of the bullet-end component, and the second end is the end of the casing body opposite the projectile end and has a male or female coupling element; and a cylindrical cartridge casing head-end component with an essentially closed base end with a primer hole opposite an open end with a coupling element that is a mate for the coupling element on the second end of the middle body and joins the second end of the middle body component to the open end of the head-end component; wherein the middle body component is formed from a material more ductile than the material head-end component is formed from but equal or less ductile than the material the bullet-end component is formed from. Methods for assembling ammunition cartridges and ammunition cartridges having the headspace length larger than the corresponding headspace length of the chamber of the intended weapon measured at the same basic diameter for the cartridge casing without being so large as to jam the weapon or otherwise interfere with its action are also disclosed.
One embodiment of the present invention provides a method of coding polymer ammunition cartridges comprising the steps of: providing a first colored polymer forming a polymeric bullet-end upper portion comprising a bullet-end coupling element extending to a bullet-end aperture to engage a bullet; providing a second colored polymer forming a polymeric middle body comprising a first coupling end connected to the bullet-end coupling element and a second coupling end connected to a primer insert to form a propellant chamber that connects the bullet-end aperture to the primer insert; and coding the first colored polymer, the second colored polymer or both to identify a projectile type, an ammunition type, a propellant charge, or a combination thereof.
The first colored polymer comprises one or more pigments selected from black pigments, white pigments, gray pigments, pink pigments, red pigments, orange pigments, yellow pigments, green pigments, cyan pigments, blue pigments, violet pigments, purple pigments, brown pigments, tan pigments, brass pigments, copper pigments, or gold pigments. The second colored polymer comprises one or more pigments selected from black pigments, white pigments, gray pigments, pink pigments, red pigments, orange pigments, yellow pigments, green pigments, cyan pigments, blue pigments, violet pigments, purple pigments, brown pigments, tan pigments, brass pigments, copper pigments, or gold pigments. The first colored polymer comprises one or more first pigments selected from black pigments, white pigments, gray pigments, pink pigments, red pigments, orange pigments, yellow pigments, green pigments, cyan pigments, blue pigments, violet pigments, purple pigments, brown pigments, tan pigments, brass pigments, copper pigments, or gold pigments and the second colored polymer comprises one or more second pigments selected from black pigments, white pigments, gray pigments, pink pigments, red pigments, orange pigments, yellow pigments, green pigments, cyan pigments, blue pigments, violet pigments, purple pigments, brown pigments, tan pigments, brass pigments, copper pigments, or gold pigments. The one or more pigments may be present in an amount of between 0.001 and 10 wt % and more specifically 0.001 wt %, 0.01 wt %, 0.1 wt %, 0.25 wt %, 0.5 wt %, 0.75 wt %, 1 wt %, 2 wt %, 2.1 wt %, 2.25 wt %, 2.5 wt %, 2.75 wt %, 3.1 wt %, 3.25 wt %, 3.5 wt %, 3.75 wt %, 4.0 wt %, 4.25 wt %, 4.5 wt %, 4.75 wt %, 5.0 wt %, 5.25 wt %, 5.5 wt %, 5.75 wt %, 6.0 wt %, 6.25 wt %, 6.5 wt %, 6.75 wt %, 7.0 wt %, 7.25 wt %, 7.5 wt %, 7.75 wt %, 8.0 wt %, 8.25 wt %, 8.5 wt %, 8.75 wt %, 9.0 wt %, 9.25 wt %, 9.5 wt %, 9.75 wt %, 10.0 wt % and incremental variations thereof. The one or more first pigments and the one or more second pigments may be different pigments. The first colored polymer, the second colored polymer or both comprise polybutylene terephthalate, polyurethane prepolymer, cellulose, fluoro-polymer, ethylene inter-polymer alloy elastomer, ethylene vinyl acetate, nylon, polyether imide, polyester elastomer, polyester sulfone, polyphenyl amide, polypropylene, polyvinylidene fluoride or thermoset polyurea elastomer, acrylics, homopolymers, acetates, copolymers, acrylonitrile-butadinen-styrene, thermoplastic fluoro polymers, inomers, polyamides, polyamide-imides, polyacrylates, polyatherketones, polyaryl-sulfones, polybenzimidazoles, polycarbonates, polybutylene, terephthalates, polyether imides, polyether sulfones, thermoplastic polyimides, thermoplastic polyurethanes, polyphenylene sulfides, polyethylene, polypropylene, polysulfones, polyvinylchlorides, styrene acrylonitriles, polystyrenes, polyphenylene, ether blends, styrene maleic anhydrides, polycarbonates, allyls, aminos, cyanates, epoxies, phenolics, unsaturated polyesters, bismaleimides, polyurethanes, silicones, vinylesters, urethane hybrids, polyphenylsulfones, copolymers of polyphenylsulfones with polyethersulfones or polysulfones, copolymers of poly-phenylsulfones with siloxanes, blends of polyphenylsulfones with polysiloxanes, poly(etherimide-siloxane) copolymers, blends of polyetherimides and polysiloxanes, and blends of polyetherimides and poly(etherimide-siloxane) copolymers. The polymeric bullet-end upper portion, the polymeric middle body or both comprise a nylon polymer or a polycarbonate polymer. The fiber-reinforced polymeric composite contains between about 3 and about 50 wt % glass fiber fillers, mineral fillers, or mixtures thereof. The ammunition cartridges is a 5.56 mm, 7.62 mm, 308, 338, 3030, 3006, 50 caliber, 45 caliber, 380 caliber, 38 caliber, 9 mm, 10 mm, 12.7 mm, 14.5 mm, 14.7 mm, 20 mm, 25 mm, 30 mm, 40 mm, 57 mm, 60 mm, 75 mm, 76 mm, 81 mm, 90 mm, 100 mm, 105 mm, 106 mm, 115 mm, 120 mm, 122 mm, 125 mm, 130 mm, 152 mm, 155 mm, 165 mm, 175 mm, 203 mm, 460 mm, 8 inch, or 4.2 inch ammunition cartridge. The primer insert comprises a top surface opposite a bottom surface and an insert coupling element that extends from the bottom surface, a primer recess in the top surface that extends toward the bottom surface, a primer flash hole positioned in the primer recess to extend through the bottom surface, and a flange that extends circumferentially about an outer edge of the top surface.
The present invention also provides a method of coding polymer metal ammunition cartridges comprising the steps of: providing a first colored polymer forming a polymeric bullet-end upper portion comprising a bullet-end coupling element extending to a bullet-end aperture to engage a bullet; providing a metal middle body comprising a first coupling end connected to the bullet-end coupling element and a primer insert at a second end to define a propellant chamber that connects the bullet-end aperture to the primer insert; and coding the first colored polymer to identify a projectile type, an ammunition type, a propellant charge, or a combination thereof.
The first colored polymer comprises one or more pigments selected from black pigments, white pigments, gray pigments, pink pigments, red pigments, orange pigments, yellow pigments, green pigments, cyan pigments, blue pigments, violet pigments, purple pigments, brown pigments, tan pigments, brass pigments, copper pigments, or gold pigments. The first colored polymer comprises polyurethane prepolymer, cellulose, fluoro-polymer, ethylene inter-polymer alloy elastomer, ethylene vinyl acetate, nylon, polyether imide, polyester elastomer, polyester sulfone, polyphenyl amide, polypropylene, polyvinylidene fluoride or thermoset polyurea elastomer, acrylics, homopolymers, acetates, copolymers, acrylonitrile-butadinen-styrene, thermoplastic fluoro polymers, inomers, polyamides, polyamide-imides, polyacrylates, polyatherketones, polyaryl-sulfones, polybenzimidazoles, polycarbonates, polybutylene, terephthalates, polyether imides, polyether sulfones, thermoplastic polyimides, thermoplastic polyurethanes, polyphenylene sulfides, polyethylene, polypropylene, polysulfones, polyvinylchlorides, styrene acrylonitriles, polystyrenes, polyphenylene, ether blends, styrene maleic anhydrides, polycarbonates, allyls, aminos, cyanates, epoxies, phenolics, unsaturated polyesters, bismaleimides, polyurethanes, silicones, vinylesters, urethane hybrids, polyphenylsulfones, copolymers of polyphenylsulfones with polyethersulfones or polysulfones, copolymers of poly-phenylsulfones with siloxanes, blends of polyphenylsulfones with polysiloxanes, poly(etherimide-siloxane) copolymers, blends of polyetherimides and polysiloxanes, and blends of polyetherimides and poly(etherimide-siloxane) copolymers. The metal middle body comprises stainless steel, brass, ceramic alloys, copper/cobalt/nickel/custom alloys, tungsten, tungsten carbide, carballoy, ferro-tungsten, titanium, copper, cobalt, nickel, uranium, depleted uranium, alumina oxide, zirconia and aluminum. The polymer metal ammunition cartridges is a 5.56 mm, 7.62 mm, 308, 338, 3030, 3006, 50 caliber, 45 caliber, 380 caliber, 38 caliber, 9 mm, 10 mm, 12.7 mm, 14.5 mm, 14.7 mm, 20 mm, 25 mm, 30 mm, 40 mm, 57 mm, 60 mm, 75 mm, 76 mm, 81 mm, 90 mm, 100 mm, 105 mm, 106 mm, 115 mm, 120 mm, 122 mm, 125 mm, 130 mm, 152 mm, 155 mm, 165 mm, 175 mm, 203 mm, 460 mm, 8 inch, or 4.2 inch ammunition cartridge.
The present invention provides a method of coding metal polymer ammunition cartridges comprising the steps of: providing a metal bullet-end upper portion comprising a bullet-end coupling element extending to a bullet-end aperture to engage a bullet; providing a colored polymer forming a polymeric middle body comprising a first coupling end connected to the bullet-end coupling element and a second coupling end connected to a primer insert to form a propellant chamber that connects the bullet-end aperture to the primer insert; and coding the colored polymer to identify a projectile type, an ammunition type, a propellant charge, or a combination thereof.
The colored polymer comprises one or more pigments selected from black pigments, white pigments, gray pigments, pink pigments, red pigments, orange pigments, yellow pigments, green pigments, cyan pigments, blue pigments, violet pigments, purple pigments, brown pigments, tan pigments, brass pigments, copper pigments, or gold pigments. The colored polymer comprises polybutylene terephthalate, polyurethane prepolymer, cellulose, fluoro-polymer, ethylene inter-polymer alloy elastomer, ethylene vinyl acetate, nylon, polyether imide, polyester elastomer, polyester sulfone, polyphenyl amide, polypropylene, polyvinylidene fluoride or thermoset polyurea elastomer, acrylics, homopolymers, acetates, copolymers, acrylonitrile-butadinen-styrene, thermoplastic fluoro polymers, inomers, polyamides, polyamide-imides, polyacrylates, polyatherketones, polyaryl-sulfones, polybenzimidazoles, polycarbonates, polybutylene, terephthalates, polyether imides, polyether sulfones, thermoplastic polyimides, thermoplastic polyurethanes, polyphenylene sulfides, polyethylene, polypropylene, polysulfones, polyvinylchlorides, styrene acrylonitriles, polystyrenes, polyphenylene, ether blends, styrene maleic anhydrides, polycarbonates, allyls, aminos, cyanates, epoxies, phenolics, unsaturated polyesters, bismaleimides, polyurethanes, silicones, vinylesters, urethane hybrids, polyphenylsulfones, copolymers of polyphenylsulfones with polyethersulfones or polysulfones, copolymers of poly-phenylsulfones with siloxanes, blends of polyphenylsulfones with polysiloxanes, poly(etherimide-siloxane) copolymers, blends of polyetherimides and polysiloxanes, and blends of polyetherimides and poly(etherimide-siloxane) copolymers. The metal middle body comprises stainless steel, brass, ceramic alloys, copper/cobalt/nickel/custom alloys, tungsten, tungsten carbide, carballoy, ferro-tungsten, titanium, copper, cobalt, nickel, uranium, depleted uranium, alumina oxide, zirconia and aluminum. The metal polymer ammunition cartridge is a 5.56 mm, 7.62 mm, 308, 338, 3030, 3006, 50 caliber, 45 caliber, 380 caliber, 38 caliber, 9 mm, 10 mm, 12.7 mm, 14.5 mm, 14.7 mm, 20 mm, 25 mm, 30 mm, 40 mm, 57 mm, 60 mm, 75 mm, 76 mm, 81 mm, 90 mm, 100 mm, 105 mm, 106 mm, 115 mm, 120 mm, 122 mm, 125 mm, 130 mm, 152 mm, 155 mm, 165 mm, 175 mm, 203 mm, 460 mm, 8 inch, or 4.2 inch ammunition cartridge.
For a more complete understanding of the features and advantages of the present invention, reference is now made to the detailed description of the invention along with the accompanying figures and in which:
While the making and using of various embodiments of the present invention are discussed in detail below, it should be appreciated that the present invention provides many applicable inventive concepts that can be embodied in a wide variety of specific contexts. The specific embodiments discussed herein are merely illustrative of specific ways to make and use the invention and do not delimit the scope of the invention.
To facilitate the understanding of this invention, a number of terms are defined below. Terms defined herein have meanings as commonly understood by a person of ordinary skill in the areas relevant to the present invention. Terms such as “a”, “an” and “the” are not intended to refer to only a singular entity, but include the general class of which a specific example may be used for illustration. The terminology herein is used to describe specific embodiments of the invention, but their usage does not delimit the invention, except as outlined in the claims.
As used herein the term colorant is denotes pigment and dye are used interchangeably to denote a substance that provides a color to a material. Pigments and dyes are include compositions that is a powders, solutions or suspensions and may be added to a polymer, doped into the polymer, doped or mixed into a polymer that is then combined with a second (or more) polymer produce a specific color and polymer composition. The present invention provides the ability to mix various colors to produce the exact color desired and in fact allows the production of any color when the specific colors are combined in the correct proportions. In addition various dyes and pigments and glazes may be combined in numerous combinations to produce the specific desired color or colors. The dye chemical structures include nitroso, nitro, monoazo, diazo, stilbene, diarylmethane, triarylmethane, xanthene, acridine, quinoline, methine, thiazole, indamine, indophenol, azine, oxazine, thiazine, aminoketone, anthraquinone, indigoid, phthalocyanine, natural dyes, inorganic pigments and/or combinations thereof. Similarly the colors may be applied to produce a pattern (either specific e.g., stripes, lines, geometric, natural objects leaves, camo, etc. and/or a combination thereof.
Reliable cartridge manufacture requires uniformity from one cartridge to the next in order to obtain consistent ballistic performance. Among other considerations, proper bullet seating and bullet-to-casing fit is required. In this manner, a desired pressure develops within the casing during firing prior to bullet and casing separation. Historically, bullets employ a cannelure, which is a slight annular depression formed in a surface of the bullet at a location determined to be the optimal seating depth for the bullet. In this manner, a visual inspection of a cartridge could determine whether or not the bullet is seated at the proper depth. Once the bullet is inserted into the casing to the proper depth, one of two standard procedures is incorporated to lock the bullet in its proper location. One method is the crimping of the entire end of the casing into the cannelure. A second method does not crimp the casing end; rather the bullet is pressure fitted into the casing.
The polymeric ammunition cartridges of the present invention are of a caliber typically carried by soldiers in combat for use in their combat weapons. The present invention is not limited to the described caliber and is believed to be applicable to other calibers as well. This includes various small and medium caliber munitions, including .22, .22-250, .223, .243, .25-06, .270, .300, .30-30, .30-40, 30.06, .300, .303, .308, .338, .357, .38, .380, .40, .44, .45, .45-70, .50 BMG, caliber ammunition cartridges, as well as medium/small caliber ammunition such as including 5.45 mm, 5.56 mm, 6.5 mm, 6.8 mm, 7 mm, 7.62 mm, 8 mm, 9 mm, 10 mm, 12.7 mm, 14.5 mm, 14.7 mm, 20 mm, 25 mm, 30 mm, 40 mm, 57 mm, 60 mm, 75 mm, 76 mm, 81 mm, 90 mm, 100 mm, 105 mm, 106 mm, 115 mm, 120 mm, 122 mm, 125 mm, 130 mm, 152 mm, 155 mm, 165 mm, 175 mm, 203 mm, 460 mm, 8 inch, 4.2 inch and the like and military style ammunition. Thus, the present invention is also applicable to the sporting goods industry for use by hunters and target shooters and military applications.
Although
The present invention includes cartridge casings that are made from polymeric materials or at least partially from a polymer material. In addition, the cartridge casings may be made of similar or dissimilar materials. For example, the cartridge casing may be entirely made of polymer materials or from a combination of polymer materials and metals or metal alloys. The cartridge casing may be made in multiple components that are assembled, e.g., the bullet-end component may be connected to the middle body component that includes a primer insert as in
For example, the bullet-end component may be made of a first polymer while the middle body component may be made from the same first polymer; the bullet-end component may be made of a first polymer while the middle body component may be made from a second polymer; the bullet-end component may be made of a first metal while the middle body component may be made from the same first metal; the bullet-end component may be made of a first metal while the middle body component may be made from a second metal; the bullet-end component may be made of a first alloy while the middle body component may be made from the same first alloy; the bullet-end component may be made of a first alloy while the middle body component may be made from a second alloy; the bullet-end component may be made of a first polymer while the middle body component may be made from a metal; the bullet-end component may be made of a first polymer while the middle body component may be made from an alloy; the bullet-end component may be made of a metal while the middle body component may be made from a polymer; or the bullet-end component may be made of an alloy while the middle body component may be made from a polymer. In these variations, the bullet-end component must be joined to the middle body component. This joining may be accomplished using a variety of methods in the art used to join similar and dissimilar materials. For example, the bullet-end component must be joined to the middle body component by brazing (e.g., furnace brazing, induction brazing, resistance brazing and hydrogen brazing); welding (e.g., electron beam welding, ultrasonic welding, laser welding, fusion welding, resistance welding (e.g., spot, seam, and flash welding), pressure welding and fusion welding); soldering; and adhesive bonding. In addition the bullet-end component may be joined to the projectile by physically crimping the bullet-end component to the projectile or by brazing (e.g., furnace brazing, induction brazing, resistance brazing and hydrogen brazing); welding (e.g., electron beam welding, ultrasonic welding, laser welding, fusion welding, resistance welding (e.g., spot, seam, and flash welding), pressure welding and fusion welding); soldering; and bonding.
For example, the bullet-end component may be made of a first colored polymer while the middle body component may be made from a second colored polymer; the bullet-end component may be made of a colored polymer while the middle body component may be made from a metal; the bullet-end component may be made of a metal while the middle body component may be made from a colored polymer; the bullet-end component may be made of a colored polymer while the middle body component may be made from an alloy; the bullet-end component may be made of an alloy while the middle body component may be made from a colored polymer; or the bullet-end component may be made of a colored polymer while the middle body component may be made from the colored polymer.
The colored polymer may be a single colored polymer or multiple colored polymers. In addition, the colored polymer may include bands of color to further provide indicia to code the round.
For illustrative purposes only and not to limit the scope of the invention in any way: the bullet-end component may be made of a first colored polymer to denote the type of projectile, with red for incendiary projectiles, blue for tracer projectiles, green for armor piercing projectiles, yellow for explosive projectiles, and so forth. Similarly, the middle body component may be made of a first colored polymer to denote the type of projectile, with red for incendiary projectiles, blue for tracer projectiles, green for armor piercing projectiles, yellow for explosive projectiles, and so forth. In another embodiment, the ammunition may be further characterized using multiple combinations the bullet-end component having a first colored polymer to denote the type of projectile and the middle body component having a second colored polymer to denote the type of load.
In addition, the present invention provides indicia to identify the type of propellant load in a cartridge. For example, an ammunition may have a middle body component having a tan colored polymer to denote the normal load, a gray colored polymer to denote a subsonic load, a pink colored polymer to denote a substantially subsonic load of −70% of a normal load.
As result, the number of possible combinations are numerous. For example, the ammunition may have a red bullet-end component for incendiary projectiles and a metal middle body to denote a normal load; the ammunition may have a red bullet-end component for incendiary projectiles and a tan colored middle body to denote the normal load; the ammunition may have a red bullet-end component for incendiary projectiles and a gray colored middle body to denote a subsonic load; the ammunition may have a blue bullet-end component for tracer projectiles and a tan colored middle body to denote normal load; the ammunition may have a blue bullet-end component for tracer projectiles and a gray colored middle body to denote a subsonic load; the ammunition may have a yellow bullet-end component for explosive projectiles and a colored middle body to denote a subsonic load; and the ammunition may have a yellow bullet-end component for explosive projectiles and a tan colored middle body to denote normal load.
In these variations, the bullet-end component must be joined to the middle body component. This joining may be accomplished using a variety of methods in the art used to join similar and dissimilar materials. For example, the bullet-end component must be joined to the middle body component by brazing (e.g., furnace brazing, induction brazing, resistance brazing and hydrogen brazing); welding (e.g., electron beam welding, ultrasonic welding, laser welding, fusion welding, resistance welding (e.g., spot, seam, and flash welding), pressure welding and fusion welding); soldering; and adhesive bonding. In addition, the bullet-end component may be joined to the projectile by physically crimping the bullet-end component to the projectile or by brazing (e.g., furnace brazing, induction brazing, resistance brazing and hydrogen brazing); welding (e.g., electron beam welding, ultrasonic welding, laser welding, fusion welding, resistance welding (e.g., spot, seam, and flash welding), pressure welding and fusion welding); soldering; and bonding.
The polymeric and composite casing components may be injection molded. Polymeric materials for the bullet-end and middle body components must have propellant compatibility and resistance to gun cleaning solvents and grease, as well as resistance to chemical, biological and radiological agents. The polymeric materials must have a temperature resistance higher than the cook-off temperature of the propellant, typically about 320° F. The polymeric materials must have elongation-to-break values that to resist deformation under interior ballistic pressure as high as 60,000 psi in all environments (temperatures from about −65 to about 320° F. and humidity from 0 to 100% RH).
According to one embodiment, the middle body component is either molded onto or snap-fit to the casing head-end component after which the bullet-end component is snap-fit or interference fit to the middle body component. The components may be formed from high-strength polymer, composite or ceramic.
Examples of suitable high strength polymers include composite polymer material including a tungsten metal powder, nylon 6/6, nylon 6, and glass fibers; and a specific gravity in a range of 3-10. The tungsten metal powder may be 50%-96% of a weight of the bullet body. The polymer material also includes about 0.5-15%, preferably about 1-12%, and most preferably about 2-9% by weight, of nylon 6/6, about 0.5-15%, preferably about 1-12%, and most preferably about 2-9% by weight, of nylon 6, and about 0.5-15%, preferably about 1-12%, and most preferably about 2-9% by weight, of glass fibers. It is most suitable that each of these ingredients be included in amounts less than 10% by weight. The cartridge casing body may be made of a modified ZYTEL® resin, available from E.I. DuPont De Nemours Co., a modified 612 nylon resin, modified to increase elastic response. Examples of suitable polymers include polyurethane prepolymer, cellulose, fluoro-polymer, ethylene inter-polymer alloy elastomer, ethylene vinyl acetate, nylon, polyether imide, polyester elastomer, polyester sulfone, polyphenyl amide, polypropylene, polyvinylidene fluoride or thermoset polyurea elastomer, acrylics, homopolymers, acetates, copolymers, acrylonitrile-butadinen-styrene, thermoplastic fluoro polymers, inomers, polyamides, polyamide-imides, polyacrylates, polyatherketones, polyaryl-sulfones, polybenzimidazoles, polycarbonates, polybutylene, terephthalates, polyether imides, polyether sulfones, thermoplastic polyimides, thermoplastic polyurethanes, polyphenylene sulfides, polyethylene, polypropylene, polysulfones, polyvinylchlorides, styrene acrylonitriles, polystyrenes, polyphenylene, ether blends, styrene maleic anhydrides, polycarbonates, allyls, aminos, cyanates, epoxies, phenolics, unsaturated polyesters, bismaleimides, polyurethanes, silicones, vinylesters, or urethane hybrids. Examples of suitable polymers also include aliphatic or aromatic polyamide, polyeitherimide, polysulfone, polyphenylsulfone, poly-phenylene oxide, liquid crystalline polymer and polyketone. Examples of suitable composites include polymers such as polyphenylsulfone reinforced with between about 30 and about 70 wt %, and preferably up to about 65 wt % of one or more reinforcing materials selected from glass fiber, ceramic fiber, carbon fiber, mineral fillers, organo nanoclay, or carbon nanotube. Preferred reinforcing materials, such as chopped surface-treated E-glass fibers provide flow characteristics at the above-described loadings comparable to unfilled polymers to provide a desirable combination of strength and flow characteristics that permit the molding of head-end components. Composite components can be formed by machining or injection molding. Finally, the cartridge case must retain sufficient joint strength at cook-off temperatures. More specifically, polymers suitable for molding of the projectile-end component have one or more of the following properties: Yield or tensile strength at −65° F.>10,000 psi Elongation-to-break at −65° F.>15% yield or tensile strength at 73° F.>8,000 psi Elongation-to-break at 73° F.>50% yield or tensile strength at 320° F.>4,000 psi Elongation-to-break at 320° F.>80%. Polymers suitable for molding of the middle-body component have one or more of the following properties: Yield or tensile strength at −65° F.>10,000 psi yield or tensile strength at 73° F.>8,000 psi yield or tensile strength at 320° F.>4,000 psi.
Commercially available polymers suitable for use in the present invention thus include polyphenylsulfones; copolymers of polyphenylsulfones with polyether-sulfones or polysulfones; copolymers and blends of polyphenylsulfones with polysiloxanes; poly(etherimide-siloxane); copolymers and blends of polyetherimides and polysiloxanes, and blends of polyetherimides and poly(etherimide-siloxane) copolymers; and the like. Particularly preferred are polyphenylsulfones and their copolymers with poly-sulfones or polysiloxane that have high tensile strength and elongation-to-break to sustain the deformation under high interior ballistic pressure. Such polymers are commercially available, for example, RADEL® R5800 polyphenylesulfone from Solvay Advanced Polymers. The polymer can be formulated with up to about 10-15 wt % of one or more additives selected from internal mold release agents, heat stabilizers, anti-static agents, colorants, impact modifiers and UV stabilizers.
The polymers of the present invention can also be used for conventional one, two and three piece plastic-plastic or metal-plastic hybrid cartridge case designs and conventional designs. One example of such a design is an ammunition cartridge with a one-piece substantially cylindrical polymeric cartridge casing body with an open projectile-end and an end opposing the projectile-end with a male or female coupling element; and a cylindrical metal cartridge casing head-end component with an essentially closed base end with a primer hole opposite an open end having a coupling element that is a mate for the coupling element on the opposing end of the polymeric cartridge casing body joining the open end of the head-end component to the opposing end of the polymeric cartridge casing body. The high polymer ductility permits the casing to resist breakage.
One embodiment includes a 2 cavity prototype mold having an upper portion and a base portion for a 5.56 case having a metal insert over-molded with a Nylon 6 (polymer) based material. In this embodiment, the polymer in the base includes a lip or flange to extract the case from the weapon. One 2-cavity prototype mold to produce the upper portion of the 5.56 case can be made using a stripper plate tool using an Osco hot spur and two subgates per cavity. Another embodiment includes a subsonic version, the difference from the standard and the subsonic version is the walls are thicker, thus requiring less powder. This will decrease the velocity of the bullet, thus creating a subsonic round.
The extracting inserts are used to give the polymer case a tough enough ridge and groove for the weapons extractor to grab and pull the case out from the chamber of the gun. The extracting insert is made of 17-4 ss that is hardened to 42-45rc. The insert may be made of aluminum, brass, cooper, steel, or even an engineered resin with enough tensile strength.
The insert is over molded in an injection molded process using a nano clay particle filled Nylon material. The inserts can be machined or stamped. In addition, an engineered resin able to withstand the demand on the insert allows injection molded and/or even transfer molded. The insert may also be over molded in an injection molded process using a fiber-reinforced polymeric composite material. The fiber-reinforced polymeric composite may contain between about 2 wt %, 2.1 wt %, 2.25 wt %, 2.5 wt %, 2.75 wt %, 3.0 wt %, 3.25 wt %, 3.5 wt %, 3.75 wt %, 4.0 wt %, 4.25 wt %, 4.5 wt %, 4.75 wt %, 5.0 wt %, 5.25 wt %, 5.5 wt %, 5.75 wt %, 6.0 wt %, 6.25 wt %, 6.5 wt %, 6.75 wt %, 7.0 wt %, 7.25 wt %, 7.5 wt %, 7.75 wt %, 8.0 wt %, 8.25 wt %, 8.5 wt %, 8.75 wt %, 9.0 wt %, 9.25 wt %, 9.5 wt %, 9.75 wt %, 10 wt %, 11 wt %, 12 wt %, 13 wt %, 14 wt %, 15 wt %, 16 wt %, 17 wt %, 18 wt %, 19 wt %, 20 wt %, 21 wt %, 22 wt %, 23 wt %, 24 wt %, 25 wt %, 26 wt %, 27 wt %, 28 wt %, 29 wt %, 30 wt %, 31 wt %, 32 wt %, 33 wt %, 34 wt %, 35 wt %, 36 wt %, 37 wt %, 38 wt %, 39 wt %, 40 wt %, 41 wt %, 42 wt %, 43 wt %, 44 wt %, 45 wt %, 46 wt %, 47 wt %, 48 wt %, 49 wt %, 50 wt %, 51 wt %, 52 wt %, 53 wt %, 54 wt %, 55 wt %, 56 wt %, 57 wt %, 58 wt %, 59 wt %, 60 wt %, 61 wt %, 62 wt %, 63 wt %, 64 wt %, 65 wt %, 66 wt %, 67 wt %, 68 wt %, 69 wt %, 70 wt % fiber fillers and incremental variations thereof. The fiber fillers may be glass fiber fillers, mineral fillers, polymer fillers or mixtures thereof.
Suitable polymer materials can include polybutylene terephthalate (PBT), polycarbonate (PC), polyvinyl butyral (PVB), polyvinyl alcohol (PVA), polyvinyl acetate (PVAc), polyurethane (PU), polyureas, polycyclic olefin copolymer (COC), polymethyl methacrylate (PMMA), polyethyl methacyrlate (PEMA), acrylate copolymers, polyvinylidine fluoride (PVDF), polyimides, copolymers of the afore-mentioned, and mixture thereof. Suitable solvents can include dimethylacetamide (DMAc), water, toluene, benzene, xylene, mesitylene, ethylbenzene, dimethylsulfoxide (DMSO), diethylsulfoxide, N,N-dimethylformamide (DMF), N,N-diethylformamide, N,N-diethylacetamide, N-methyl-2-pyrrolidone (NMP), N-cyclohexyl-2-pyrrolidone, 1,3-dimethyl-2-imidazolidinone, diethyleneglycol dimethoxyether, o-dichlorobenzene, dichloromethane, chloroform, phenols, cresols, xylenol, catechol, butyrolactones, hexamethylphosphoramide, acetone, methyl ethyl ketone, methyl ethyl ketone, methyl isobutyl ketone, cyclopentanone, acetyl acetone, tetrahydrofuran, 1,4-dioxane, and mixtures thereof.
The present invention includes polymer compositions that include one or more pigments or organic molecules that produce a color. The pigment may be selected from among carbon black, any organic pigment related to a class of azo or azo condensed pigments, metal complexes, benzimidazolones, azomethines, methines, cyanines, azacarbocyanines, enamines, hemicyanines, streptocyanines, styryls, zeromethines, mono-, di-, tri-, and tetraazamethines, caratenoids, arylmethanes, diarylmethanes, triarylmethanes, xanthenes, thioxanthenes, flavanoids, stilbenes, coumarins, acridenes, fluorenes, fluorones, benzodifuranones, formazans, pyrazoles, thiazoles, azines, diazines, oxazines, dioxazines, triphenodioxazines, phenazines, thiazins, oxazones, indamines, nitroso, nitro, quinones, hydroquinones, naphthaquinones, anthraquinones, rhodamines, phthalocyanines, neutrocyanines, diazahemicyanines, porphirines, perinones, perylenes, pyronins, diketopyrrolopyrroles, indigo, indigoids, thioindigo, indophenols, naphthalimides, isoindolines, isoindolinones, iminoisoindolines, iminoisoindolinones, quinacridones, flavanthrones, indanthrones, anthrapyrimidines, quinophthalones, isoviolanthrones, pyranthrones, titanium dioxide, zinc oxide, chromium oxide (green, brown, etc.), silica, iron oxide (yellow, red, black, brown, or a combination or mixture thereof), antimony yellow, lead chromate, lead chromate sulfate, lead molybdate, ultramarine blue, cobalt blue, manganese blue, chrome oxide green, hydrated chrome oxide green, cobalt green, metal sulfides, cadmium sulfoselenides, zinc ferrite, bismuth vanadate, and derivatives, C.I. Pigment Black 1, 2, 3, 6, 7, 9, 11, 12, 14, 15, 22, 26, 27, 28, 29, 30, 31, 32, 33, 34 and 35; C.I. Pigment Green 7, 18, 20, 21, 22, 36, 37, 47, 54, and 58; C.I. Pigment Blue 15:1, 15:2, 15:3, 15:4, 15:6, 16, 21, 22, 25, 27, 30, 60, 64, 65, 73, 75, 76, and 79; 60, 64, 65, 75, 76, and 79; C.I. Pigment Red 12, 13, 14, 15, 21, 23, 32, 40, 85, 88, 89, 112, 114, 122, 123, 144, 147, 149, 166, 168, 170, 171, 175, 176, 177, 178, 179, 180, 181, 183, 184, 185, 187, 188, 189, 190, 192, 194, 195, 196, 202, 208, 209, 214, 216, 220, 221, 224, 226, 242, 245, 248, 251, 254, 255, 256, 260, 264, 265, 266, 269, 271 and 275; C.I. Pigment Orange 2, 3, 4, 5, 16, 22, 24, 36, 38, 40, 43, 51, 60, 61, 62, 64, 66, 69, 71, 72, 73, and 77; C.I. Pigment Yellow 38, 40, 53, 119, 157, 158, 160, 161, 162, and 184; C.I. Pigment White 4, 5, 6, 6:1, 7, 8, 9, 10, 12, 13, 14, 15, 18, 18:1, 19, 21, 22, 23, 24, 25, 26, 27, 28, 32, 33, and 36; C.I. Vat Black 1, 2, 7, 8, 25, 27, 28, 29, 30, 35, 65; C.I. Vat Green 1, 2, 3, 4, 6, 8, 9, 11, 12, 17, 23; C.I. Vat Blue 1, 2, 3, 4, 5, 6, 7, 8, 9, 11, 12, 13, 14, 16, 18, 19, 20, 21, 22, 25, 30, 31, 32, 33, 37, 40, 42, 43, 47, 53, 64, and 67; C.I. Vat Violet 1, 2, 3, 4, 5, 8, 9, 10, 13, 14, 15, 16, 17, 18, and 19; C.I. Vat Brown 1, 3, 5, 8, 9, 14, 16, 21, 22, 25, 26, 31, 33, 37, 42, and 45; C.I. Vat Red 10, 13, 14, 15, 18, 19, 20, 21, 23, 24, 28, 29, 32, 35, 37, 38, 39, 40, 42, 44, and 48; C. I. Vat Orange 1, 2, 3, 4, 7, 9, 11, 13, 15, 16, 17, 18, 19, and 20; C. I. Vat Yellow 1, 2, 3, 4, 9, 10, 11, 12, 13, 17, 18, 20, 23, 26, 27, 28, 29, 31, 33, and 44; and any combination thereof, and wherein the pigment comprises a vat or disperse dye or insoluble salt or complex of acid, direct, reactive, mordant, solvent, natural, basic (cationic), sulfur, fluorescent, or optical brightener, a mixture of organic pigment, inorganic pigment or extenders or solid solutions thereof, shell type pigments with inorganic nuclei covered with organic shell, or dispersed polymer particles or any combination thereof. Other examples include, quinacridones, such as PR122, PR202, PR207, PR209, PV19, and their solid solutions; phthalocyanines, such as PB15:1, PB15:2, PB15:3, PB15:4, PB15:6, PB16, PG7, PG36, and PG37; azo such as PY74, PY83; disazo, such as PY93, PY95, PY155, PY158, PY166, PR144, PR220, and PR221; metal complexes such as PY117, PY150, PY153; benzimidazolones such as PY120, PY151, PY154, PY156, PY175, PY180, PY181, PY194, PR171, PR175, PR176, PR185, PR208, PO36, PO60, PO62, PO64, PO72, PV32; diketopyrrolopyrroles such as, PR254, PR255, PR264, PR272, PO71, PO73; dioxazines such as PV23 and PV37; isoindolenones such as PY109, PY110, PY139, PY173, PY185, PO61, PO180; isoindolines such as PY139 and PY185; anthraquinones such as PY99, PY108, PY123, PY147, PY193, PR43, PR83, PR89, PR177 and PR196; indanthrones such as PB60 and PB64; flavanthrones, such as PY24; perylene such as PR123, PR178; PR179; PR190, PR224, PB31, and PB32; pyranthrone PR226; violanthrone PB65; and carbon black such as PB7. Non-limiting examples of suitable pigments include azo or azo condensed pigments, metal complexes, benzimidazolones, azomethines, methines such as cyanines, azacarbocyanines, enamines, hemicyanines, streptocyanines, styryls, zeromethines, mono-, di-, tri-, and tetraazamethine; caratenoids, arylmethanes such as diarylmethanes and triarylmethanes; xanthenes, thioxanthenes, flavanoids, stilbenes, coumarins, acridenes, fluorenes, fluorones, benzodifuranones, formazans, pyrazoles, thiazoles, azines, diazines, oxazines, dioxazines, triphenodioxazines, phenazines, thiazines, oxazones, indamines, nitroso, nitro, quinones such as hydroquinones, naphthaquinones, and anthraquinones; rhodamines, phthalocyanines, neutrocyanines, diazahemicyanines, porphirines, perinones, perylenes, pyronins, diketopyrrolopyrroles, indigo, indigoids, thioindigo, indophenols, naphthalimides, isoindolines, isoindolinones, iminoisoindolines, iminoisoindolinones, quinacridones, flavanthrones, indanthrones, anthrapyrimidines, quinophthalones, isoviolanthrones, pyranthrones, and any combinations and/or any solid solution thereof; vat or disperse dyes or insoluble salt/complex of acid, direct, reactive, mordant, solvent, natural, basic (cationic), sulfur, fluorescent, or optical brightener; mixtures of organic, inorganic pigments or extenders, solid solutions thereof, shell type pigments with inorganic nuclei covered with organic shell. The pigment also can be a dispersed polymer particle, such as polystyrene, polyamides, polysulfones, polyesters, polyurethanes, polyalkylenes, polysulfides, co-polymers and mixtures or co-polymers thereof, but not limited by them only. The dispersed polymer particles can be non-colored or colored with any of the aforementioned pigments and/or dyes.
Non-limiting examples of inorganic pigments include carbon black, titanium dioxide, zinc oxide, silica, iron oxide, antimony yellow, lead chromate, lead chromate sulfate, lead molybdate, ultramarine blue, cobalt blue, manganese blue, chrome oxide green, hydrated chrome oxide green, cobalt green, metal sulfides, cadmium sulfoselenides, zinc ferrite, bismuth vanadate, and derivatives and any combinations thereof.
In the dispersions provided herein, the surface modified pigment of the invention can be present in an amount at or about 0.001 wt % to at or about 60 wt %, or at or about 2 wt % to at or about 50 wt %, or at or about 3 wt % to at or about 40 wt %, or at or about 5 wt % to at or about 30 wt % based on the weight of the dispersion. Pigment concentrations below 1% are possible but are not economical to mill. Pigment concentrations above 60% are possible but typically will not provide acceptable rheological behavior. In some instance, the surface modified pigment is present in an amount of 0.001 wt %, 0.01 wt %, 0.1 wt %, 1 wt %, 2 wt %, 3 wt %, 4 wt %, 5 wt %, 6 wt %, 7 wt %, 8 wt %, 9 wt %, 10 wt %, 11 wt %, 12 wt %, 13 wt %, 14 wt %, 15 wt %, 16 wt %, 17 wt %, 18 wt %, 19 wt %, 20 wt %, 21 wt %, 22 wt %, 23 wt %, 24 wt %, 25 wt %, 26 wt %, 27 wt %, 28 wt %, 29 wt %, 30 wt %, 31 wt %, 32 wt %, 33 wt %, 34 wt %, 35 wt %, 36 wt %, 37 wt %, 38 wt %, 39 wt %, 40 wt %, 41 wt %, 42 wt %, 43 wt %, 44 wt %, 45 wt %, 46 wt %, 47 wt %, 48 wt %, 49 wt %, 50 wt %, 51 wt %, 52 wt %, 53 wt %, 54 wt %, 55 wt %, 56 wt %, 57 wt %, 58 wt % or 60 wt %, based on the weight of the dispersion and more specifically 0.001 wt %, 0.01 wt %, 0.1 wt %, 0.25 wt %, 0.5 wt %, 0.75 wt %, 1 wt %, 2 wt %, 2.1 wt %, 2.25 wt %, 2.5 wt %, 2.75 wt %, 3.1 wt %, 3.25 wt %, 3.5 wt %, 3.75 wt %, 4.0 wt %, 4.25 wt %, 4.5 wt %, 4.75 wt %, 5.0 wt %, 5.25 wt %, 5.5 wt %, 5.75 wt %, 6.0 wt %, 6.25 wt %, 6.5 wt %, 6.75 wt %, 7.0 wt %, 7.25 wt %, 7.5 wt %, 7.75 wt %, 8.0 wt %, 8.25 wt %, 8.5 wt %, 8.75 wt %, 9.0 wt %, 9.25 wt %, 9.5 wt %, 9.75 wt %, 10.0 wt % and incremental variations thereof. One of ordinary skill in the art will know that many propellant types and weights can be used to prepare workable ammunition and that such loads may be determined by a careful trial including initial low quantity loading of a given propellant and the well known stepwise increasing of a given propellant loading until a maximum acceptable load is achieved. Extreme care and caution is advised in evaluating new loads. The propellants available have various burn rates and must be carefully chosen so that a safe load is devised.
The pigment may be incorporated into a polymer that is added to the polymer composition used to form a copolymer used to form a polymeric bullet-end upper portion comprising a first polymer composition and/or a polymeric middle body comprising a second polymer composition. The first polymer composition may be a copolymer of the polymer and a polymer having a pigment incorporated therein. Similarly, the second polymer composition may be a copolymer of the polymer and a polymer having a pigment incorporated therein. Also, both the first polymer composition may be a copolymer of the polymer and a polymer having a pigment incorporated therein and the second polymer composition may be a copolymer of the polymer and a polymer having a pigment incorporated therein.
In addition the present invention also includes a coating applied to the ammunition cartridge and more specifically to the bullet-end upper portion, the middle body or both. The coating may be a pigment incorporated into a polymer that is used for indicia rather than for structural support. As a result, the thickness may be thin from microns to millimeters and all thicknesses there between. Similarly the concentration of the pigment or dye may be up to 75 weight percent as it is solely used for color indicia. The polymer used may be any polymer that will adhere to the ammunition cartridge and more specifically to the bullet-end upper portion, the middle body or both and may be a single polymer or a mixture of copolymers.
The description of the preferred embodiments should be taken as illustrating, rather than as limiting, the present invention as defined by the claims. As will be readily appreciated, numerous combinations of the features set forth above can be utilized without departing from the present invention as set forth in the claims. Such variations are not regarded as a departure from the spirit and scope of the invention, and all such modifications are intended to be included within the scope of the following claims.
It is contemplated that any embodiment discussed in this specification can be implemented with respect to any method, kit, reagent, or composition of the invention, and vice versa. Furthermore, compositions of the invention can be used to achieve methods of the invention.
It will be understood that particular embodiments described herein are shown by way of illustration and not as limitations of the invention. The principal features of this invention can be employed in various embodiments without departing from the scope of the invention. Those skilled in the art will recognize, or be able to ascertain using no more than routine experimentation, numerous equivalents to the specific procedures described herein. Such equivalents are considered to be within the scope of this invention and are covered by the claims.
All publications and patent applications mentioned in the specification are indicative of the level of skill of those skilled in the art to which this invention pertains. All publications and patent applications are herein incorporated by reference to the same extent as if each individual publication or patent application was specifically and individually indicated to be incorporated by reference.
The use of the word “a” or “an” when used in conjunction with the term “comprising” in the claims and/or the specification may mean “one,” but it is also consistent with the meaning of “one or more,” “at least one,” and “one or more than one.” The use of the term “or” in the claims is used to mean “and/or” unless explicitly indicated to refer to alternatives only or the alternatives are mutually exclusive, although the disclosure supports a definition that refers to only alternatives and “and/or.” Throughout this application, the term “about” is used to indicate that a value includes the inherent variation of error for the device, the method being employed to determine the value, or the variation that exists among the study subjects.
As used in this specification and claim(s), the words “comprising” (and any form of comprising, such as “comprise” and “comprises”), “having” (and any form of having, such as “have” and “has”), “including” (and any form of including, such as “includes” and “include”) or “containing” (and any form of containing, such as “contains” and “contain”) are inclusive or open-ended and do not exclude additional, unrecited elements or method steps.
The term “or combinations thereof” as used herein refers to all permutations and combinations of the listed items preceding the term. For example, “A, B, C, or combinations thereof” is intended to include at least one of: A, B, C, AB, AC, BC, or ABC, and if order is important in a particular context, also BA, CA, CB, CBA, BCA, ACB, BAC, or CAB. Continuing with this example, expressly included are combinations that contain repeats of one or more item or term, such as BB, AAA, MB, BBC, AAABCCCC, CBBAAA, CABABB, and so forth. The skilled artisan will understand that typically there is no limit on the number of items or terms in any combination, unless otherwise apparent from the context.
All of the compositions and/or methods disclosed and claimed herein can be made and executed without undue experimentation in light of the present disclosure. While the compositions and methods of this invention have been described in terms of preferred embodiments, it will be apparent to those of skill in the art that variations may be applied to the compositions and/or methods and in the steps or in the sequence of steps of the method described herein without departing from the concept, spirit and scope of the invention. All such similar substitutes and modifications apparent to those skilled in the art are deemed to be within the spirit, scope and concept of the invention as defined by the appended claims.
This application is a Divisional application of U.S. patent application Ser. No. 15/721,861 filed Sep. 30, 2017, which is a Continuation-in-Part application of U.S. patent application Ser. No. 14/724,240 filed May 28, 2015 now U.S. Pat. No. 9,927,219, which is a Divisional Application of U.S. patent application Ser. No. 14/011,202 filed Aug. 27, 2013 now U.S. Pat. No. 9,546,849, which is a Divisional Application of U.S. patent application Ser. No. 13/292,843 filed Nov. 9, 2011 now U.S. Pat. No. 8,561,543, which claims priority to U.S. Provisional Application Ser. No. 61/456,664, filed Nov. 10, 2010, the contents of each of which are all incorporated by reference herein in their entirety.
| Number | Date | Country | |
|---|---|---|---|
| 61456664 | Nov 2010 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 15721861 | Sep 2017 | US |
| Child | 17319613 | US | |
| Parent | 14011202 | Aug 2013 | US |
| Child | 14724240 | US | |
| Parent | 13292843 | Nov 2011 | US |
| Child | 14011202 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 14724240 | May 2015 | US |
| Child | 15721861 | US |
