This invention relates generally to semiconductor devices, and in particular to embodiments to electrodes and methods of forming electrodes.
Although applicable in principle to arbitrary integrated circuits, the present invention and also the problem area on which it is based will be explained with regard to integrated memory circuits, in particular DRAM cells, in silicon technology.
A stacked capacitor array has a multiplicity of stacked capacitors which are preferably arranged regularly. As is known, a stacked capacitor is preferably connected to a transistor downward in order to form a DRAM cell. In the known fabrication of stacked capacitors, in particular of cylindrical stacked capacitors, in a stacked capacitor array, there is the problem that as the aspect ratio of the individual stacked capacitors increases, their mechanical stability decreases. If the aspect ratio of pillarlike or crownlike capacitors increases above a specific value, then the structures become mechanically unstable. In a disadvantageous manner, capacitors may incline toward one another on account of this instability. If two neighboring capacitors incline toward one another to such an extent that they touch one another, a short circuit arises between these two capacitors. Memory errors occur within a stacked capacitor array on account of a short circuit between two capacitors. With a lack of mechanical stability, stacked capacitors may also completely topple over and thus bring about defects within the stacked capacitor array.
This problem has been solved hitherto by keeping the aspect ratio of the individual capacitor below a limit value determined empirically. The capacitance that can be achieved per capacitor is thereby limited, however. In order to further improve the large scale integration of memory circuits, however, it is necessary to increase the capacitance of the respective capacitor per chip area by increasing the aspect ratio.
To form a semiconductor device, a plurality of upwardly extending conductors can be formed. The conductors extend outward from a surface of a semiconductor body, adjacent ones of the conductors being separated from each other by a separating material. At least one support structure is formed between adjacent ones of the upwardly extending conductors. The support structure is formed of a material different than the separating material. The separating material can be removed and further processing can be performed on the semiconductor device.
This patent is a continuation-in-part of two co-pending patent applications, which are both incorporated herein by reference. The entirety of details described in the co-pending applications apply here, whether explicitly stated or not.
For a more complete understanding of the present invention, and the advantages thereof, reference is now made to the following descriptions taken in conjunction with the accompanying drawings, in which:
a-2i diagrammatically depict successive method stages involved in a fabrication method as a first embodiment of the present invention, illustrating the stacked capacitors which adjoin one another in first directions;
a-3i diagrammatically depict successive method stages of the fabrication method according to the first embodiment of the present invention, illustrating the stacked capacitors which adjoin one another in second directions;
a, 4b in each case diagrammatically depict an intermediate stage of a fabrication method as a second embodiment of the present invention;
a-6c show schematic illustrations of successive method stages of a fabrication method as a first embodiment of the present invention, the stacked capacitors that are adjacent in first directions being illustrated;
a-7e show schematic illustrations of successive method stages of the fabrication method according to the first embodiment of the present invention, the stacked capacitors that are adjacent in second directions being illustrated; and
a-8g show schematic illustrations of successive method stages of a fabrication method as second embodiment of the present invention.
The making and using of the presently preferred embodiments are discussed in detail below. It should be appreciated, however, that the present invention provides many applicable inventive concepts that can be embodied in a wide variety of specific contexts. The specific embodiments discussed are merely illustrative of specific ways to make and use the invention, and do not limit the scope of the invention.
In one aspect, the present invention relates to a stacked capacitor array and a fabrication method for a stacked capacitor array having a multiplicity of stacked capacitors, an insulator keeping at least two adjacent stacked capacitors mutually spaced apart, so that no electrical contact can arise between them and the stacked capacitors are mechanically stabilized.
Embodiments of the present invention can be used with stacked capacitor arrays where the stacked capacitors have a high aspect ratio. An insulator connects at least two adjacent stacked capacitors to one another and thus mechanically stabilizes them mutually. Two stacked capacitors connected by means of the insulator are mechanically stabilized and cannot incline toward one another or tip over. In an array, the insulator connects many or all adjacent stacked capacitors to one another and thus mechanically stabilizes them.
In one particular embodiment, the multiplicity of stacked capacitors is arranged regularly, such that a stacked capacitor having a smaller spacing from the respective adjacent stacked capacitors in specific first directions than in specific second directions, the insulator keeping spaced apart at least two stacked capacitors that are adjacent in the first direction.
In various embodiments, a method for fabricating a stacked capacitor array, which comprises a regular arrangement of a plurality of stacked capacitors, with a stacked capacitor being at a shorter distance from the respectively adjacent stacked capacitor in certain first directions than in certain second directions, with the fabrication method comprising the following method steps: provision of an auxiliary layer stack having first auxiliary layers with a predetermined etching rate and at least one second auxiliary layer with a higher etching rate on a substrate; etching of in each case one hollow cylinder for each stacked capacitor through the auxiliary layer stack in accordance with the regular arrangement, with the auxiliary layer stack being left in place in intermediate regions between the hollow cylinders; isotropic etching of the second auxiliary layers to form widened portions of the hollow cylinders, without any second auxiliary layer being left in place between in each case two hollow cylinders which adjoin one another in the first direction and with a second residual auxiliary layer being left in place between in each case two hollow cylinders which adjoin one another in the second direction; conformal deposition of an insulator layer in order to completely fill the widened portions; deposition of a first electrode layer in the hollow cylinders in order to form the stacked capacitors; filling of the hollow cylinders with a first filling; removal of the first auxiliary layers, the second residual auxiliary layers and the first filling and completion of the stacked capacitor array.
A second embodiment method for fabricating a stacked capacitor array, which comprises a regular arrangement of a plurality of stacked capacitors, with a stacked capacitor being at a shorter distance from the respective adjacent stacked capacitor in certain first directions than in certain second directions, with the fabrication method comprising the following method steps of: provision of an auxiliary layer stack having first auxiliary layers with a predetermined etching rate and at least one second auxiliary layer with a higher etching rate on a substrate; etching of in each case one hollow cylinder for each stacked capacitor through the auxiliary layer stack in accordance with the regular arrangement, with the auxiliary layer stack being left in place in intermediate regions between the hollow cylinders; isotropic etching of the second auxiliary layers to form widened portions of the hollow cylinders, without any second auxiliary layer being left in place between in each case two hollow cylinders which adjoin one another in the first direction and with a second residual auxiliary layer being left in place in each case in a central region between two hollow cylinders which adjoin one another in the second direction; deposition of a first electrode layer in the hollow cylinders, completely filling the widened portions of the hollow cylinders; filling of the hollow cylinders with a first filling, removal of the first auxiliary layers, the second residual auxiliary layers and the first filling; completion of the stacked capacitors and etchback of the stacked capacitors to a level below the widened portions, so that individual stacked capacitors are no longer electrically connected.
In a third embodiment method for fabricating a stacked capacitor array having a regular arrangement of a multiplicity of stacked capacitors, a stacked capacitor having a smaller spacing from the respective adjacent stacked capacitors in specific first directions than in specific second directions: providing a first auxiliary layer on a substrate; providing a respective cylinder for each stacked capacitor in the first auxiliary layer in accordance with the regular arrangement, the first auxiliary layer remaining only in intermediate regions between the cylinders; etching back the first auxiliary layer in an upper region of the intermediate regions; depositing an insulator in the upper region of the intermediate regions; etching back the insulator, so that in each case two stacked capacitors that are adjacent in the first direction remain connected by means of the insulator and so that in each case a hole is formed through the insulator between two stacked capacitors that are adjacent in the second direction; removing the first auxiliary layer by means of the holes formed in the intermediate regions; and completing the stacked capacitor array.
The figures show that the capacitors 2 each have a circular cross section when viewed from above. This does not need to be the case. For example, in certain embodiments the capacitor electrode could be formed from a hollow cylinder with an elliptical or rectangular cross section.
In the second directions 4, two adjacent stacked capacitors 2 are in each case separated by a first auxiliary layer 6. The method stage illustrated in
Apart from
a to 2i diagrammatically depict successive method stages of a fabrication method as a first embodiment of the present invention, illustrating the stacked capacitors 2 which adjoin one another in first directions 3.
In one embodiment, the first auxiliary layers 6 have a predetermined etching rate and the second auxiliary layers 7 have a higher etching rate in comparison thereto. For example, the auxiliary layer stack 2 has precisely one second auxiliary layer 7, which has a higher etching rate than the first auxiliary layers 6. In one specific example, the first auxiliary layers 6 are formed by silicon oxide with a predetermined etching rate, and the second auxiliary layer(s) 7 are formed by silicon oxide with a higher etching rate. Silicon oxide is advantageously easy to etch, making the structure simple to fabricate. The second auxiliary layer(s) 7 can alternatively be formed by borophosphosilicate glass (BPSG).
In one particular embodiment, the second auxiliary layer 7 is provided close to the surface, below a thin first auxiliary layer. One advantage of this preferred refinement is that this therefore allows the supporting structure or the insulator layer to be provided very close to the surface.
Analogously to
b shows a method stage that follows
c and 3c show that the second auxiliary layers 7 are etched back to form widened portions 11 of the hollow cylinders 9, without any auxiliary layer 7 being left in place between in each case two hollow cylinders 9 which adjoin one another in the first direction 3 (
Then, referring now to
Referring now to
e and 3e illustrate that excess material in the insulator layer 12 which has been deposited within the hollow cylinders 9 is removed by means of an etchback process.
Referring now to
g and 3g show that a first filling 14 is deposited over the first electrode layer 13 in the hollow cylinders 9. The first filling 14 serves as an auxiliary layer.
It is preferable for the electrode layer 13 to be formed by polysilicon or by a metal.
Since the first electrode layer 13 has also been deposited over the intermediate regions 10, it is removed there by means of chemical mechanical polishing or an etchback process, as shown in
It is then possible for all the auxiliary layers, namely the first auxiliary layers 6, the second residual auxiliary layers 7a and the first filling 14, to be removed by means of an etching process.
The connection of two stacked capacitors 2 by means of the insulator layer 12 forms the supporting structure which spaces the individual stacked capacitors apart from one another and improves the stability of the stacked capacitors, which may have even a very high aspect ratio.
a and 4b in each case diagrammatically depict an intermediate stage of a fabrication method as a second embodiment of the present invention.
a and 4b illustrate an intermediate stage for fabrication of a stacked capacitor array 1 according to an alternate embodiment of the invention after the following method steps. An auxiliary layer stack 5 comprising first auxiliary layers 6 with a predetermined etching rate and at least one second auxiliary layer 7 with a higher etching rate was provided on a substrate 8. (See e.g.
Then, referring now to
Additional embodiments of the invention will now be described with respect to
The plan view according to
a-6c show schematic illustrations of successive method stages of a fabrication method as a first embodiment of the present invention, the stacked capacitors 2 that are adjacent in first directions 3 being illustrated.
Analogously to this,
All of
In this case,
In specific first directions 3, a stacked capacitor 2 has a smaller spacing from the respective adjacent stacked capacitors 2 than from the stacked capacitors 2 that are adjacent in specific second directions 4.
a illustrates the stacked capacitors 2 in the first direction 3 spaced apart to a smaller extent. The cross-sectional view of
In accordance with one embodiment, the first auxiliary layer 5 is formed by silicon or by silicon oxide. One advantage of this embodiment is that both silicon and silicon oxide are readily etchable and it is thus possible to carry out the fabrication of the cylinders for the stacked capacitors in a simple manner.
The first auxiliary layer 5 can be alternatively formed by a superimposition of an undoped silicate glass layer and a borosilicate glass layer. It is known that, in a disadvantageous manner, generally a cone rather than a cylinder arises in the course of dry etching through a specific layer. By virtue of the fact, however, that during the subsequent wet-chemical etching or expansion, the borosilicate glass layer has a higher etching rate with respect to the undoped silicon glass layer, the conical form is avoided and a substantially cylindrical form is formed after etching.
In one embodiment, before the first auxiliary layer is etched back, a first electrode layer is deposited into the hollow cylinders for the purpose of forming crown-type first electrodes for the stacked capacitors and the hollow cylinders are subsequently filled with a first filling. The electrode layer deposited in the hollow cylinder forms a first electrode for the respective stacked capacitor, said electrode having the form of a crown. One advantage of this preferred development is that, as a result of the deposition of the electrode layer and as a result of filling with the first filling, the hollow cylinders are stabilized in such a way as to ensure their mechanical stability during the etching back of the first auxiliary layer and also during subsequent method steps.
The etching of the hollow cylinders is carried out by means of a dry etching process and/or a wet-chemical etching process. Etching of the hollow cylinders is advantageously carried out by means of a combined sequence of both processes.
b and 7b show that the insulator 16 is partly etched back by means of an isotropic etching process. In accordance with
The etching back of the insulator 10 can be carried out by means of an anisotropic and/or isotropic etching process. One advantage of this preferred development is that the thickness of the insulator can be set as desired through the variable use of isotropic and anisotropic etching processes.
The first auxiliary layer 5 is subsequently removed by means of the holes 17 formed below the upper region 18 of the intermediate regions 19 (not shown). The stacked capacitor array 1 is finally completed by deposition of a dielectric and counterelectrode.
d and 7e in each case show an alternative process sequence to the process sequence illustrated in
a-8g show schematic illustrations of successive method stages of a fabrication method as another embodiment of the present invention. These figures illustrate the respective stacked capacitors 2 and the adjacent stacked capacitors 2 exclusively in the first directions 3.
a shows that a first auxiliary layer 5 is provided on a substrate 8.
In accordance with
e shows that both the first auxiliary layer 5 in the intermediate regions 19 and the first filling 14 in the hollow cylinders 9 are etched back in an upper region 18. Referring to
In accordance with an alternative embodiment, the insulator is deposited only on the outside around the cylinder. In an advantageous manner, by virtue of the fact that no insulator is deposited inside the cylinder for the stacked capacitor, the area of the capacitor and thus the capacitance of the capacitor are increased. In accordance with another embodiment, the insulator is deposited on the outside around the cylinder and on the inside. One advantage of this preferred development is that the processing of the stacked capacitor array is thus simplified. Simplifying the processing saves costs. In accordance with certain other embodiments, the insulator surrounds the corresponding stacked capacitor only in insulating fashion and does not connect two adjacent stacked capacitor to one another.
The insulator 16 is subsequently etched back by means of an anisotropic and/or isotropic etching process, so that, on the one hand, in each case the first filling 14 is uncovered upward and, on the other hand, in each case a hole 17 (not shown) is formed through the insulating layer 16 between two stacked capacitors 2 that are adjacent in the second direction 4 (see
Referring to
Although the present invention has been described above on the basis of preferred exemplary embodiments, it is not restricted thereto, but rather can be modified in diverse ways.
By way of example, it is not always necessary for the insulator to connect to one another two stacked capacitors that are adjacent in a direction spaced apart to a smaller extent. It is also possible for each stacked capacitor only to be surrounded with a ring comprising the insulator so that, in the case of stacked capacitors getting closer to one another, exclusively the rings comprising the insulator touch one another and no electrical contact can therefore arise between two stacked capacitors. Furthermore, the selection of the materials for the layers used is only by way of example; many other materials are conceivable and can be used.
One advantage of embodiments of the present invention is that the insulator insulates two adjacent stacked capacitors from one another such that no electrical contact can arise between them even if they incline toward one another. Short circuits between the adjacent stacked capacitors are thus avoided. Therefore, in accordance with preferred embodiments, the insulator keeps many or all adjacent stacked capacitors spaced apart.
Moreover, the connection of the individual stacked capacitors improve the mechanical stability of the individual stacked capacitors even with a high aspect ratio. A further advantage resides in the fact that the height at which the supporting structures or the insulator layer are generated can be set freely as desired by suitable selection of the layer thicknesses and of the number of first and second auxiliary layers of the auxiliary layer stack. Therefore, the position or height of the insulator layer can be varied as desired. A further advantage is that it is not imperative that an insulator layer be used to space apart the stacked capacitors if the electrode layer itself serves as a supporting structure and the stacked capacitors are etched back to below the level of the supporting structure after they have been completed.
In another embodiment, the hollow cylinder described above can be formed as a solid cylinder which consists of an electrode material. The solid cylinder is then used as an electrode of the capacitor. One advantage of this preferred refinement is that the fabrication method according to the invention is also suitable for solid cylinders, allowing very large scale integration of the memory circuits. Accordingly, the solid cylinder may be elliptical or rectangular in cross section. One advantage of these preferred developments is that the fabrication method according to the invention can be used variably both for hollow and for solid cylinders or for a combination of the two.
Although the present invention has been described above on the basis of preferred exemplary embodiments, it is not restricted to these embodiments, but rather can be modified in various ways. For example, the choice of materials for the layers used is only an example, and many other materials are conceivable and may be employed.
While this invention has been described with reference to illustrative embodiments, this description is not intended to be construed in a limiting sense. Various modifications and combinations of the illustrative embodiments, as well as other embodiments of the invention, will be apparent to persons skilled in the art upon reference to the description. It is therefore intended that the appended claims encompass any such modifications or embodiments.
Number | Date | Country | Kind |
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102004021399.2 | Apr 2004 | DE | national |
102004021401.8 | Apr 2004 | DE | national |
This is a continuation-in-part of patent application Ser. No. 11/079,131, which was filed on Mar. 14, 2005 (published as U.S. Patent Application Publication 2005/0245027) and which claims priority to German Application DE 102004021399.2, filed Apr. 30, 2004. This is also a continuation-in-part of patent application Ser. No. 11/112,940, which was filed on Apr. 22, 2005 (published as U.S. Patent Application Publication 2005/0245022) and which claims priority to German application DE 102004021401.8, filed Apr. 30, 2004. Both earlier filed U.S. patent applications and their German counterparts are incorporated herein by reference.
Number | Date | Country | |
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Parent | 11079131 | Mar 2005 | US |
Child | 11526788 | Sep 2006 | US |
Parent | 11112940 | Apr 2005 | US |
Child | 11526788 | Sep 2006 | US |