Patent Grant
12159951
The present invention relates to a device and method for harvesting radiant energy emanated by a distant radiant energy source, particularly, to collecting the sunlight and absorbing it by a light sensitive material, medium or device. More particularly, the present invention relates to photovoltaic devices, solar cells and light detectors having light trapping microstructures or layers to improve absorption of light within the light sensitive layer, and to a method for generating electricity from sunlight thereof.
Conventionally, photovoltaic solar cells or light detectors employ an active photoresponsive layer that absorbs at least a portion of the electromagnetic spectrum of the light and generates charge carriers due to the photovoltaic effect. Since most photovoltaic materials absorb much more weakly in certain wavelengths than in the others, the active layer has to have at least a minimum thickness to be able to absorb most of the light to which the photovoltaic material is responsive.
One exemplary material suitable for converting light into electricity is silicon (Si). However, Si is an indirect bandgap semiconductor and is poorly absorbing the long wavelength light. For the active layer made with crystalline silicon the minimum thickness is typically between 200 and 400 μm (micro-meters). While Si is very abundant, stable and well-suited for solar cell and light detector manufacturing, the cost of this thick layer of silicon is quite high which results in the high cost of the devices.
Some other than crystalline silicon types of photovoltaic devices, such as amorphous silicon thin-film cells, for example, allow for a much smaller thickness of the active layer. However, with certain wavelengths being still absorbed very weakly, they usually require some form of light trapping that would cause the incident light to pass through the active layer multiple times thus improving the absorption. The light trapping is usually implemented in the prior art by texturing one or more surfaces comprising the solar cell in order to scatter the incident light at different angles thus resulting in a longer average light path through the active layer. In case of a monocrystalline silicon cell, light scattering and trapping is conventionally provided by microstructures such as periodic or random pyramids on the front surface and a reflective or light scattering surface at the rear of the cell. In case of an amorphous thin-film Si cell consisting of several layers, a transparent top conductor layer is often textured to scatter light and hence increase the light path through the active layer.
During light trapping, some scattered light can be trapped in the active layer of the solar photovoltaic device by means of TIR which can even allow for the multiple passage of a portion of solar rays through the active layer thus resulting in a better absorption and sunlight conversion. However, the existing approaches for light trapping in the photovoltaic devices cannot prevent for a substantial portion of incident light to escape from the device without being absorbed. For example, in case of the front surface employing random pyramidal microstructures, a large portion of the escaping light is usually lost through this front surface due to the random nature of the secondary interactions of the light rays with the pyramids. Furthermore, up to 10 percent or more light can be lost in conventional photovoltaic systems due to the reflection from front contacts or absorption by layers or surfaces which produce no photovoltaic effect.
An additional problem encountered in photovoltaic devices is that most photovoltaic materials have a relatively large refractive index which results in poor light coupling efficiency due to the high reflection losses from the light receiving surface. The bulk crystalline Si, for example, has the refractive index of 3.57 at 1,000 nm (nanometers) and 5.59 at 400 nm which results in the Fresnel reflection of 32% to 49% of the incident light at 1,000 nm and 400 nm, respectively. Typically, these problems can be addressed by adding an antireflective layer to the light receiving surface and/or surface microstructuring. However, the antireflective coating works efficiently only in a limited bandwidth and adds system cost and processing time, while the microstructures are still somewhat inefficient for light coupling or otherwise are quite expensive to be used for mass production, considering that the entire area of the photovoltaic device must be processed to cover it with these microstructures.
These drawbacks of the prior art approaches and the loss of useful light are hampering the utility of the photovoltaic devices. None of the previous efforts provides an efficient solution for coupling and trapping essentially all of the incident light and allowing it to pass through the sufficient effective depth of photosensitive material or allow the light to interact with the active layer as many times as necessary to cause the efficient light absorption in a controlled manner. It is therefore an object of this invention to provide an improved light harvesting system employing a novel photovoltaic structure with efficient light coupling and trapping thus minimizing energy loss.
The present invention solves the above problems by providing a layered structure having correlated surface relief features or microstructures that allow for enhancing the light coupling efficiency, increasing the light path through the photosensitive material and for trapping the incident light within the device by means of at least TIR. The light trapping causes multiple passage of the trapped light through the photoresponsive (active) layer thus improving the light absorption and energy conversion efficiency. Other objects and advantages of this invention will be apparent to those skilled in the art from the following disclosure.
The present invention solves a number of light harvesting problems within a compact system utilizing efficient light coupling and trapping mechanisms. Light is injected into a photoresponsive layer through light input ports using a focusing array and trapped within the layer so that the useful light absorption is substantially enhanced.
A light harvesting system employing microstructures for efficient light trapping and comprising a focusing array and a photoresponsive layer is described. The focusing array comprises a plurality of light collecting elements distributed over a planar surface of the array. Each light collecting element is configured to collect light from a larger area and focus the incident light onto a substantially smaller focal area. The photoresponsive layer comprises light input ports formed in its light receiving surface. Each light input port is disposed in energy receiving relationship with respect to at least one light collecting element of the focusing array. More particularly, each light input port is disposed in a vicinity of the respective light collecting element and aligned (centered) with respect to its optical axis. Each light input port is configured to receive a focused light beam and communicate it into the photoresponsive layer a sufficiently oblique angle so as to result in an improved light coupling and generally increased light path and absorption in said layer compared to the case when light enters the photoresponsive layer elsewhere through its light receiving surface.
The invention is amenable to being embodied in a number of ways, including but not limited to the following descriptions.
At least one embodiment of the invention is configured as a light harvesting system comprising: (a) a photoresponsive layer configured to internally absorb at least a portion of the light propagating through its body; (b) a plurality of light input ports associated with a light receiving surface of said photoresponsive layer; and (c) a plurality of light collecting elements within a planar focusing array configured for focusing received light onto said light input ports. Each of the plurality of light input ports is configured to communicate the incident light into the photoresponsive layer at a sufficiently oblique angle so as to increase the optical path of the light rays through the designated layer. The device operates in response to the light received on the aperture of the focusing array being injected into the photoresponsive layer and angularly redirected at generally oblique angles with respect to the prevailing plane of the light harvesting system.
In at least one implementation, the light harvesting system further comprises at least one electrical contact associated with the photoresponsive layer. In at least one further implementation, the electrical contact associated with the photoresponsive layer is made from an optically transparent material. In at least one implementation, the electrical contact associated with the photoresponsive layer comprises a reflective metallic material and is made in the form of a grid. In at least one implementation, the electrical contact comprises a reflective metallic material and is made in the form of a thin sheet or a film. In at least one implementation, the electrical contact comprises a plurality of electrical contact fingers disposed in spaces between adjacent pairs of light input ports and away from the light paths of the focused beams formed by the light collecting elements. In at least one implementation, the photoresponsive layer comprises at least one photovoltaic cell.
In alternative implementations, the planar focusing array and its light collecting elements can be configured in different ways. In at least one implementation, the focusing array comprises a lenticular lens array. In at least one implementation, the focusing array comprises a point-focus lens array. In at least one implementation, the focusing array comprises point focus lenses which have a shape selected from the group consisting of round, rectangular, square, and hexagonal. In at least one implementation, each of the light collecting elements is selected from the group of optical elements consisting of imaging lenses, non-imaging lenses, spherical lenses, aspherical lenses, lens arrays, Fresnel lenses, TIR lenses, gradient index lenses, diffraction lenses, mirrors, Fresnel mirrors, spherical mirrors, parabolic mirrors, mirror arrays, and trough mirrors.
In different implementations, the plurality of light input ports can be differently configured. In at least one implementation, each of the plurality of light input ports is disposed in a predetermined alignment with the plurality of light collecting elements. In at least one implementation, the oblique propagation angle within the photoresponsive layer is so selected as to result in the propagation of at least a substantial portion of light rays at sufficiently high angles, above the predetermined critical angle for total internal reflection (TIR), with respect to a surface normal to at least one surface of said photoresponsive layer. In at least one implementation, each of the plurality of light input ports comprises a refractive or reflective face inclined at an angle with respect to the prevailing plane of the photoresponsive layer. In at least one implementation, the plurality of light input ports comprises a parallel array of elongated grooves. In at least one implementation, each of the plurality of light input ports comprises at least one cavity. In at least one implementation, the cavity has a sufficiently high aspect ratio. In at least one implementation, each of the light input ports comprises at least one surface relief feature selected from the group of elements consisting of cavities, holes, extensions, bulges, prisms, prismatic grooves, cones, conical cavities, funnel-shaped cavities, surface texture, reflective surfaces, refractive surfaces, diffraction gratings, holograms, light scattering elements, and so forth.
In further implementations, the light harvesting system can be configured in various ways to enhance the light trapping in the photoresponsive layer. In at least one implementation, the light harvesting system further comprises an optical interface disposed between the photoresponsive layer and the focusing array and characterized by a drop in refractive index in the direction of light propagation from the photoresponsive layer toward the focusing array. In at least one implementation, the light harvesting system further comprises means for promoting a total internal reflection in the photoresponsive layer.
In at least one implementation, the focusing array and the photoresponsive layer are adapted for being retained in a translated, a reversed and/or a rotated orientation relative to each other toward adjusting the acceptance angle or for tracking the source of light. In at least one further implementation, the light harvesting system can comprise at least one tracking means for tracking a light source.
At least one embodiment of the invention is configured as a light harvesting system having a layered structure and comprising: (a) a photovoltaic layer disposed between a first and a second reflective surfaces; and (b) a light focusing layer having surface relief features each configured to focus the incident light. At least one of the first and second reflective surfaces comprises light input ports disposed in energy receiving relationship to the surface relief features and configured to inject incident light into the space between the first and second reflective surfaces so as to cause multiple passage of light through the photovoltaic layer.
In at least one implementation, at least one of the first and second reflective surfaces is configured for reflecting light by means of at least TIR. In at least one implementation, the light harvesting system is further comprising at least one cladding layer associated with at least one of the first and second reflective surfaces. In at least one implementation, at least one of the first and second reflective surfaces is associated with a mirror layer comprising a metallic material. In at least one implementation, at least one of the first and second reflective surfaces is associated with a mirror layer comprising a Bragg reflector. In at least one implementation, the light focusing layer comprises a lens array. In at least one implementation, the photovoltaic layer comprises at least one photovoltaic cell. In at least one implementation, the photovoltaic layer is associated with at least one light detector. In at least one implementation, each of the light input ports is formed by a microstructured area in at least one of the first and second reflective surfaces.
The present invention provides a number of beneficial elements which can be implemented either separately or in any desired combination without departing from the present teachings.
An element of the invention is a light harvesting system collecting light over a given area and communicating the incident light into a photoresponsive layer, such as a photovoltaic layer, with an enhanced light coupling efficiency and with increasing the light path through the photoresponsive layer.
Another element of the invention is a plurality of light collecting elements within a focusing array which collectively collect the incident light over a broad area and focus it into a plurality of small-aperture focal areas.
Another element of the invention is the inclusion of distributed light input ports, such as areas having surface relief features, microstructures or texture, associated with a light receiving surface or the interior of photoresponsive layer and disposing them in a light receiving relationship to the light collecting elements of the focusing array.
Another element of the invention is the inclusion of one or more cladding layers or mirrored surfaces to enhance respectively the total internal reflection or the specular reflection of light within the photoresponsive layer.
Another element of the invention is the use of electrical contacts which can additionally be provided with enhanced reflective properties to promote retaining the light within the photoresponsive layer.
Another element of the invention is the use of contact fingers associated with the light receiving surface of the photovoltaic layer and disposed in the spaces between the pairs of adjacent light input ports and away from the light paths of the focused beams formed by the light collecting elements.
Another element of the invention is the use of linear arrays of light collecting elements and/or light input ports which span the surface of the device, or a portion thereof. Alternatively, another element of the invention is the use of point-focus arrays of light collecting elements and/or light input ports as well as portions and combinations of linear and point-focus arrays thereof.
Another element of the invention is the use of a predetermined alignment for disposing the light collecting elements with respect to the light input ports and/or the electrical contacts.
Another element of the invention is the use of light input ports in the form of cavities, holes or other microstructures having a sufficiently high aspect ratio.
Another element of the invention is the use of light input ports each comprising a refractive or reflective face inclined at an angle to the light receiving surface of the photoresponsive layer for injecting at least a substantial part of the incident light into the layer at an oblique angle.
Another element of the invention is the use of tracking means for tracking a light source.
A still further element of the invention is a light harvesting system which can be utilized in a wide range of light collecting or light sensing applications.
Further elements of the invention will be brought out in the following portions of the specification, wherein the detailed description is for the purpose of fully disclosing preferred embodiments of the invention without placing limitations thereon.
The invention will be more fully understood by reference to the following drawings which are for illustrative purposes only:
Referring more specifically to the drawings, for illustrative purposes the present invention is embodied in the apparatus generally shown in the preceding figures. It will be appreciated that the apparatus may vary as to configuration and as to details of the parts without departing from the basic concepts as disclosed herein. Furthermore, elements represented in one embodiment as taught herein are applicable without limitation to other embodiments taught herein, and in combination with those embodiments and what is known in the art.
A wide range of applications exist for the present invention in relation to the collection of electromagnetic radiant energy, such as light, in a broad spectrum or any suitable spectral bands or domains. Therefore, for the sake of simplicity of expression, without limiting generality of this invention, the term “light” will be used herein although the general terms “electromagnetic energy”, “electromagnetic radiation”, “radiant energy” or exemplary terms like “visible light”, “infrared light”, or “ultraviolet light” would also be appropriate.
In order to be able to compare and contrast the present invention with typical photovoltaic structures,
Referring further to
In
However, ray 108 bouncing from back contact 16 exits layer 4 the next time it interacts with the front surface. It will be appreciated by those skilled in the art, that if the chance of light reflection from the front surface of layer 4 is further reduced and if the effective light path in layer 4 is further extended, the useful light absorption will increase thus resulting in the enhanced photocurrent generation. In conventional devices, further reducing the front surface reflectivity requires applying antireflective coatings or implementing more expensive and less practical microstructuring methods for the entire surface. The extension of the effective light path usually requires the increase in material thickness thus resulting in greater material consumption which can be detrimental to the system cost effectiveness.
Focusing array 6, hereinafter referred to also as a lens array, comprises an array of imaging micro lenses 10. The lens array can be made from of a sheet or planar plate or slab of a transparent material by appropriate contouring its frontal surface and obtaining surface relief features approximating individual refractive lenses. Each lens has a spherical or aspherical light input surface and is configured to receive an impinging beam of light, as may emanate from a distant light source (not shown), and to focus this incident light in at least one dimension onto a focal area having a transversal size substantially smaller than the transversal size of the lens in the same dimension.
For the purpose of this invention and from the practical standpoint, the terms “focal area” or “focus” of an individual lens 10 of lens array 6 should be understood broadly and generally refers to an area within the envelope of the focused beam which said lens may form when exposed to an incident beam of light, where said area has a cross section substantially smaller than the cross section of respective lens 10. Accordingly, the focal area can include areas at a relatively small distance from the “ideal” focus of lens 10 and where the focused beam can be convergent (before focus) or divergent (after focus).
It will be appreciated by those skilled in the art that focusing array 6, when positioned with one side representing the entrance aperture perpendicular to the incident beam, will provide a plurality of foci on the opposite side which will be spaced apart from each other in accordance with the spacing of individual lenses in the lens array. A planar lens array formed by lenses 10 having the same focal length will form a plurality of foci in a common focal plane disposed at a distance from lenses 10.
In accordance with at least one embodiment of the present invention, the focal length of each lens 10 in the lens array is selected to approximate the thickness of the layer forming the array. More particularly, when each micro lens in the lens array has a convex spherical shape with the radius of curvature R and the index of refraction of the transparent material forming the lens array is n, the approximate lens array thickness T can be found from the following expression:
Thus, focusing array 6 will form a plurality of foci in a plane located in a proximity of its back surface at a focal distance from lenses 10.
Focusing array 6 can have a linear, or linear-focus, geometry when it is based on lenticular lenses 10 providing light focusing in one dimension. Alternatively, it can have a point-focus geometry when it is based on lenses 10 focusing the incident light in two dimensions. While a cross-section of system 2 is illustrated in
Lenses 10 can be fabricated using any conventional method such as replication, molding, embossing, micro-machining, grinding, chemical etching, beam etching and the like. The individual lenses 10 can be integrated with focusing array 6 and preferably comprise the same material as the body of the array. Alternatively, lenses 10 can be formed on a transparent substrate sheet or film and fabricated of the same or a different material than the substrate. Individual lenses 10 can also be configured as separate pieces and attached to the substrate sheet or plate. Suitable materials for making focusing array 6 and/or lenses 10 include but are not limited to optical glass, polymethyl methacrylate (PMMA), silicone, polycarbonate, polystyrene, polyolefin, any optically clear resin which is obtainable by polymerization and curing of various compositions or other materials suitable for creating a sufficiently transparent structure. The placement of lenses 10 in focusing array 6 can be according to any suitable spatial metric and by any desired means. For example, lenses 10 can be spaced apart, contacting each other or overlapping and can be positioned in any desired pattern in the array.
Focusing array 6 can have one or more layers of anti-reflective coating (not shown) deposited on its frontal surface and/or the opposite surface in order to reduce the Fresnel reflections at optical interfaces and improve the light transmission of the array. Also, an anti-reflective layer can be embedded at any suitable part of system 2, e.g., between any of its layers to further promote the transmissivity and overall system efficiency. For these purposes, conventional anti-reflective coatings such as TiO2 deposited by Atmospheric Pressure Chemical Vapor Deposition (APCVD) and Si3N4 deposited by Plasma Enhanced Chemical Vapor Deposition (PECVD) can be used, for example.
Additionally, any suitable encapsulation or adhesion promoting layers can be incorporated into system 2. Particularly, EVA resin, fluoropolymer or optically clear silicone can be provided for encapsulating photovoltaic layer 4.
Photovoltaic layer 4 preferably has generally smooth front and back surfaces so that the light scattering of light interacting with these surfaces is minimized. Photovoltaic layer 4 may include any suitable photovoltaic element or structure that absorbs light and converts it into charge carriers and/or electric current and can comprise one or more photoabsorptive layers. More particularly, photovoltaic layer 4 may incorporate any structures or design commonly found in solar cells of photovoltaic light detectors.
By way of example and not limitation, photovoltaic layer 4 can be made from crystalline silicon so that one side is p-type, dominated by positive holes, and the other side is n-type, dominated by negative electrons. The free electrons and holes generated by light in the silicon diffuse to the p/n junction junction formed by p-type crystalline Si layer and n-type crystalline Si layer and then separate to produce an electric current.
In a further example, photovoltaic layer 4 may incorporate a thin film photovoltaic structure such as that found in amorphous silicon (a-Si) solar cells where a typical cell can employ a p-i-n design, in which a middle intrinsic layer (i-type or undoped) is sandwiched between a p-layer and an n-layer. When photovoltaic layer is of a-Si cell type, the top layer can be p-type a-Si, the middle layer can be intrinsic silicon layer, and the bottom layer is n-type a-Si. In this case, light entering photovoltaic layer 4 is at least partially absorbed and generates free electrons and holes in the intrinsic region, which are then separated by the electric field. Similarly, a CdTe photovoltaic structure with an n-i-p design can be employed in which the top layer can be cadmium sulfide (CdS), the middle layer can be intrinsic CdTe, and the bottom layer can be zinc telluride (ZnTe). In a further example, photovoltaic layer 4 can be also designed as a copper indium gallium deselenide (CIGS) structure.
In a yet further example, photovoltaic layer 4 can incorporate a multi-junction PV structure which can have the so-called cascade or tandem architecture and can be based on two or more individual cells with different bandgaps stacked on top of one another. Photons in a spectral band that is not absorbed well by the first cell are transmitted to the second cell, which then absorbs at least a portion of the remaining solar radiation while it can remain transparent to the lower-energy photons. This selective absorption process continues through the entire stack of individual cells forming photovoltaic layer 4 and being designed for the respective bandgaps so that more solar energy spectrum is absorbed compared to a single-cell design of the photovoltaic layer. A multi-junction cell can be made as a mechanical stack of independently made solar cells or as a monolithic structure in which one complete solar cell is made first, and then the layers for the second cell are grown or deposited directly on the first.
In a yet further example, photovoltaic layer 4 can incorporate Si or other semiconductor photovoltaic materials in the form of particles, spheres, rods, clusters, quantum dots, nanodots, nanowires, etc. embedded into various transparent or semi-transparent materials, such as films of silicon oxide and silicon nitride abound. Such embedded photovoltaic features can be evenly or unevenly distributed with a prescribed concentration in the bulk of photovoltaic layer 4 and can allow for efficient conversion of light into electricity provided the optical path of rays propagating in said photovoltaic layer is sufficiently long for the full light absorption.
Photovoltaic layer 4 can be associated with ohmic metallic or non-metallic contacts or electrodes which in turn can be connected to an external load. These contacts are exemplified by front contact fingers 24 and back contact 16 in
Back contact 16 can also be customarily covered with a suitable protective backsheet material (not shown) for protecting it and photovoltaic layer 4 from the environment. The backsheet can also include any suitable layers or coatings such as radiation protective coatings or films, scratch and stain resistant coatings, and the like. An illustrative example of the protective backsheet is Polyvinyl fluoride (PVF), a fluoropolymer which is commercially available as a film from DuPont and is sold under the Tedlar® brand.
According to at least one embodiment of the present invention, the photoabsorptive layer, or layers, if more than one, that form photovoltaic layer 4 can be made relatively thin in order to reduce the intake of expensive semiconductor materials. The photoabsorptive layer can be made so thin that it absorbs only a small portion of the incident light in a single path. For example, 10% or less incident sunlight can be absorbed when the light passes through photovoltaic layer 4 in either direction at normal incidence. The rest of the light, however, can be absorbed in system 2 through multiple passages of light through photovoltaic layer 4 as well as through increasing the light path through the photoabsorptive layer(s) by means of communicating the light oblique angles and/or by means of light trapping.
Referring further to
Light input ports 14 have the same number as the number of lenses 10 in focusing array 6 disposed on top of photovoltaic layer 4. Light input ports 14 are also distributed over surface 32 in accordance with the distribution of lenses 10 in the lens array so that there is a pairwise optical relationship between each lens 10 and the corresponding light input port 14. It is also preferred that lenses 10 and light input ports 14 are distributed so that contact fingers 24 are disposed between the optical axes of lenses 10 and away from the optical paths in order to allow the focused light to enter photovoltaic layer 4 through light input ports and minimize light interception by contact fingers. In other words, when contact fingers 24 are disposed between the optical centers of lenses 10, each lens 10 effectively steers the focused light away from the contact fingers and eliminates light shadowing by the front electrical contacts thus further enhancing the light coupling and system efficiency.
When focusing array 6 is formed by a lenticular lens array, each light input port 14 can extend parallel to the respective lens 10 and along its entire length. In a cross-section, such as that illustrated in
It is important that at least the transversal size of each light input port 14 is substantially smaller than the distance between the adjacent light input ports so that the cumulative area occupied by light input ports 14 on surface 32 is substantially less than the area of said surface. Yet, the receiving aperture of each light input port 14 should be sufficient in order to intercept at least a substantial portion of the light focused by the respective lens 10. It is generally preferred that light input ports occupy no more than approximately 10% of surface 32.
According to at least one embodiment of the invention, the transversal size of each light input port 14 is selected to approximate that of the focal area of the respective lens 10. In this case and when, for example, focusing array 6 is formed by densely packed cylindrical lenses each having the focal area which is about 20 times smaller than the aperture of the lens, light input ports 14 will cumulatively occupy approximately 5% of the area of surface 32. In a further example, if each lens 10 has a point focus with 400 times geometrical concentration (the geometrical concentration being defined as the ratio between the aperture of the lens and the focal area in a plane perpendicular to the lens's optical axis), the cumulative area of light input ports 14 will make approximately 0.25% of the area of surface 32.
Referring yet further to
In at least some embodiments of the present invention, light input ports 14 are formed by high aspect ratio cavities or recesses in surface 32. In the context of describing a surface relief feature or microstructure element such as a surface cavity or recess, the term “high aspect ratio” is meant to mean a geometric configuration of the microstructure element, in a cross-section, where the height or depth of the microstructure element is approximately equal or greater than its base at the surface. This term also includes the case when the height of the microstructure element is much greater than the base thus corresponding to a relatively deep cavity or recess with almost vertical walls. Each cavity or recess can have at least one face which can be perpendicular to or inclined at an angle to surface 32.
According to an embodiment of the present invention illustrated in
In at least one embodiment of
In operation, referring yet further to
Obviously, some rays propagating in photovoltaic layer can strike one of the light input ports 14 and can be scattered, reflected or absorbed as a result. Such secondary interactions with light input ports 14 can also result in the respective ray exiting photovoltaic layer 4 without being fully absorbed. However, since the size of microstructures forming light input ports 14 and distributed through surface 32 is relatively small, the chance of ray 110 encountering another light input port and decoupling from photovoltaic layer 4 is also reduced compared to the case when the entire surface 32 is covered with microstructures (as in a conventional monocrystalline Si cell, for example). It will be appreciated by those skilled in the art that the greater the concentration achieved by lenses 10 and the smaller the respective focal spots and thus the smaller light input ports 14 are, the lesser light losses will be and the greater light absorption efficiency can be achieved.
Similarly, ray 112 is injected into photovoltaic layer 4 at an oblique angle by another matching pair of lens 10 and light input port 14. Accordingly, ray 112 can also propagate through a greater effective thickness of the photoresponsive material due to off-normal propagation and due to bouncing from parallel opposing surfaces 32 and 34 until it is absorbed.
While the pairs of lenses 10 and light input ports 14 work best for injecting a direct normal-incidence beam received by the entrance aperture of focusing array 6 into photovoltaic layer 4 at advantageously oblique angles, system 2 can harvest off-axis rays as well as illustrated further in
Due to the combined effect of two-stage bending, the incident ray by lens 10 and light input port 14, ray 120 is communicated a greater propagation angle with respect to the surface normal of photovoltaic layer 4 as compared to the case when the same ray would enter photovoltaic layer 4 of conventional devices such as those illustrated in
Furthermore, even if ray 120 is not absorbed in a single pass, it can bounce from surface 34 by means of a specular reflection or TIR, in which case it can pass through photovoltaic layer 4 at least one more time which increases the chance of absorption with photocurrent generation. This is illustrated by a ray 122 which enters photovoltaic layer 4 at a similar angle as ray 120 but is not absorbed in the single layer passage. Ray 122 reaches surface 34, reflects from the surface back into photovoltaic layer 4 and is absorbed with the generation of another electron-hole pair 52.
According to at least one embodiment of this invention, sufficient specular reflectivity of surface 34 can be provided by metallic back contact 16 so as to result in minimum reflection losses. By way of example and not limitation, if photovoltaic layer 4 comprises a crystalline Si cell, back contact 16 can be conventionally made from aluminum by means of sputtering, sintering, plating or by applying an aluminum film or foil onto surface 34. Aluminum back contact 16 can be subsequently fired at high temperature which will normally provide p+ doping for a Si-type cell and improve the photovoltaic performance of the device. Alternatively, contact 16 can be made by depositing a silver layer which will provide both good reflectance of surface 34 and back contact conductivity.
Obviously, when the light beam focused by lens 10 enters the cavity of light input port 14, at least some rays can undergo Fresnel reflection from the surface of the cavity, especially considering the high refractive index of photovoltaic layer 4. Therefore, the shape of the cavity can be selected to provide for improved coupling of the reflected light. By way of example and not limitation, when light input port 14 is formed by a V-shaped cavity, the cavity can be provided with the aspect ratio high enough to prevent escaping the reflected light from photovoltaic layer without having at least a second interaction with the cavity wall(s). Furthermore, the aspect ratio can be so selected as to allow for multiple Fresnel reflections from the cavity walls thus substantially enhancing the light coupling efficiency into photovoltaic layer 4. Every time the light ray interacts with the surface of the cavity it can enter photovoltaic layer 4 with some refraction while obtaining a greater angle with respect to photovoltaic layer 4 surface normal. The refracted ray can thus further propagate in photovoltaic layer 4 at a sufficiently high angle with respect to a surface normal. Since the cumulative base area and the cross-section area of light input ports is sufficiently small compared to the frontal area a cross-section of photovoltaic layer 4, the probability of the propagating ray exiting through another light input port 14 is relatively low. Therefore, even if the propagation path of the ray is not parallel to the longitudinal dimensions of photovoltaic layer 4 and said ray can strike either surface 32 or 34 multiple times, it will strike mostly the surface portions free of any microstructures and can thus be reflected back into photovoltaic layer 4 maintaining the same incidence angle. The ray will thereby become trapped and its propagation in photovoltaic layer 4 can continue, which may include additional bounces from surfaces 32 and 34 until the ray energy is absorbed and converted to electric current.
When ray 126 undergoes refraction at point 72, it can further propagate in the medium of photovoltaic layer 4 (the respective ray segment is denoted as 156). When photovoltaic layer 4 comprises material with sufficiently high refractive index, the larger bend angles can result in increasing the optical path within the photovoltaic layer before it reaches surface 34. Segment 156 or ray 126 can undergo multiple reflections from surfaces 34 and 32 passing photovoltaic layer 4 multiple times till it is absorbed or, when the bend angle is large enough, ray segment 156 may even never reach either surface 32 or 34 before being essentially absorbed and converted to electricity.
Referring further to
Although a near-normal incidence of ray 126 is illustrated in
Similarly, in
As a matter of optics, when the angle of incidence of ray 130 onto surface 32 is greater than arcsin n2/n1, ray 130 will undergo a virtually lossless total internal reflection (TIR) back into photovoltaic layer 4. The TIR condition can be relatively easy achieved in system 2 for most rays propagating in photovoltaic layer 4, considering the high refractive index of most photovoltaic materials such as Si (n1≥3.5) and the low refractive index of the ambient air (n2≈1), in which case the critical TIR angle will be approximately 16.6° or less, depending on the wavelength. The critical angle at which TIR occurs will define the escape cone in relation to the angular distribution of rays impinging onto surface 32 internally from the inside of photovoltaic layer 4 so that when an incident ray is outside of this cone, it will become trapped in photovoltaic layer 4.
Even when a layer of conventional encapsulating material is used as an intermediate layer between focusing array 6 and photovoltaic layer 4, such as EVA (n2≈1.48) or optically clear silicone (n2≈1.4), the critical TIR angles at the interface with bulk silicon will be approximately 25° and 23.6°, respectively. Accordingly, the optical configuration of lenses 10 and light input ports 14 can be optimized to provide sufficient bend angles for the entire incident beam so that the TIR condition is met for all rays propagating in photovoltaic layer 4. For this purpose, each surface relief feature 14 should be configured to receive the focused light beam from the respective feature 10 and inject said focused beam into photovoltaic layer with a new angular pattern so that most of the rays in the injected beam will make generally greater angles with respect to a normal to the prevailing plane of system 2 than the half-angle of the escape cone.
The escape cone can be further minimized by selecting low-n materials such as fluoropolymers or certain silicones having the refractive indices in the 1.29-1.36 range or by providing a cladding layer made from any of these materials. In a further alternative, surface 32 can be provided with specular reflective propertied by means of metallization of depositing other highly reflective layers such as, for example, distributed Bragg reflector (DBR).
Similarly, ray 132 of
Ray 134 strikes a lower portion of another V-shaped cavity forming light input port 14 of
Referring further to
In
Referring to
Although the preceding embodiments described light input ports which were formed by individual cavities in surface 32, the present invention can be implemented with each light input port 14 formed by a textured area having multiple surface relief features or microstructural elements that can enhance light coupling into photovoltaic layer 4 and minimize reflection from surface 32. Any suitable surface texture that allows the incident light to pass through surface 32 with a reduced reflection and greater off-normal propagation angles in photovoltaic layer 4 compared to light entrance through the smooth portions of surface 32 can be used for making light input ports 14. By way of example and not limitation, each light input port 14 can include random or ordered arrays of high-aspect-ratio pyramids or inverted pyramids, nano-rods, nano-wires, close positioned micro-cavities, micro-holes, micro-extensions or bulges, etc.
In
It will be appreciated that diffusers or a random light scattering microstructure or surface texture can also be used for forming light input ports 14 in which case the light will be more randomly distributed across a range of angles in photovoltaic layer 4. A further example of useful feature 14 can be a matte-finish textured area in surface 32 having the aperture approximating the dimensions of the focal area of the respective lens 10. When light-scattering surface texture is used for forming light input ports 14, a portion of light injected into photovoltaic layer 4 at near-normal angles may escape from the system. However, due to the usually high refractive index of the material of photovoltaic layer 4 and the resulting small TIR escape cone, a substantial portion of the incident light can still be trapped in a manner described above thus resulting in a generally longer optical path of the rays within the photoresponsive layer and improved photocurrent generation. The light injection of incident light into photovoltaic layer 4 at advantageously high angles with respect to the surface can also be provided using diffraction gratings or holograms which can additionally be tuned for a specific spectral band. For example, when the photoresponsive layer of photovoltaic layer 4 comprises crystalline silicon which has reduced absorption in the infrared, light input ports 14 can be tuned to provided greater bend angles for the wavelengths in the range of 800-1100 nanometers.
Although the preceding embodiments described font electrical contact of photovoltaic layer 4 which was configured as metallic contact fingers 24 attached to surface 32, the present invention can be implemented using other types of front and back electrical contacts. By way of example and not limitation, a transparent electro-conducting layer can be attached to surface 32 instead or in addition to contact fingers 24. Such transparent front contact can be made from any conventional transparent conducting material. Particularly, transparent conducting films (TCFs) conventionally used for photovoltaic applications can be employed. TCF can be fabricated from inorganic and/or organic materials. An example of inorganic films is a layer of transparent conducting oxide (TCO). Suitable materials for the TCO include, but are not limited to, aluminum-doped zinc oxide (AZO), boron-doped zinc oxide, fluorine doped tin oxide (FTO), indium tin oxide (ITO), indium molybdenum oxide (IMO), indium zinc oxide (IZO) and tantalum oxide. The TCO layer can be deposited onto surface 32 by any suitable process, such as chemical vapor deposition (CVD) or physical vapor deposition (PVD). The thickness of the transparent electro-conducting layer can be fairly small compared to the thickness of photovoltaic layer 4 and can be typically up to about a few thousand nanometers. Furthermore, back contact 16 can also be implemented as a transparent electro-conducting layer and made as described above.
The foregoing embodiments are described upon the case when back contact 16 is applied to surface 34 and is also used as a reflective surface for trapping the light in photovoltaic layer 4. However, this invention is not limited to this but can also be applied to the case when an intermediate reflective layer is provided between photovoltaic layer 4 and back contact 16 to enhance the internal reflection at surface 34. By way of example and not limitation, the intermediate reflective layer may include a Bragg reflector formed by a stack of alternating porous Si layers of high and low porosity defined by the quarter-wavelength principle. The porous Si layers can be electrochemically etched into a highly doped Si substrate to create constructive interference for the efficient reflection of the incident light for a pre-selected wavelength range and thus enhance the reflectivity of surface 34 and light trapping in photovoltaic layer 4.
The foregoing embodiments are described upon the case when focusing array 6 was configured as an array of imaging lenses. However, this invention is not limited to this but can also be applied to the case when focusing array 6 may comprise any desired optical structures or surface relief features distributed over its frontal surface and adapted for collecting or concentrating the impinging light. Any known light focusing structure which collects the energy from a larger area and focuses it to a smaller focal area can be used to form the individual focusing elements of focusing array 6. By way of example and not limitation, focusing elements of the array can be selected from the group of optical elements consisting essentially of spherical or aspherical refractive lenses, Fresnel lenses, TIR lenses, gradient index lenses, diffraction lenses, lens arrays, mirrors, Fresnel mirrors, mirror arrays, trough mirrors, and the like.
It should be understood that while the preceding embodiments were illustrated by depicting only a few exemplary rays, system 2 can operate with any number of rays within a selected acceptance angle and in a desired spectral range of the incident light. It should also be understood that focusing array 6 can collect a beam of light emanated by a distant source, focus the beam and communicate it to light input ports 14. Accordingly, light input ports 14 can be configured to receive a convergent or divergent beam of focused light having a predetermined angular spread and redirect the beam into photovoltaic layer 4 at a sufficient bend angle so that each ray of the redirected beam becomes trapped in photovoltaic layer 4 and further propagates in it by means transmission and reflection until absorbed. It will be appreciated by those skilled in the art that system 2 can be used to effectively capture a quasi-parallel beam of monochromatic or broad-spectrum electromagnetic energy, trap and guide it through its photovoltaic element or layer so that substantially all of the beam can be absorbed and converted into the electric current using a much thinner layer of photoabsorptive material than in conventional devices.
Furthermore, it should be understood that, as illustrated by foregoing embodiments, the surfaces confining the captured light within photovoltaic layer 4 can be located anywhere within the structure forming system 2 and/or at any of its external edges or faces. They can also be configured to reflect light by means of specular reflection, TIR, or scattering. It should also be understood that photovoltaic layer 4 can be located anywhere between such surfaces so as to provide for the multiple passage of the trapped light through the photoresponsive material of the photovoltaic layer 4 and promote absorption.
The present invention is not limited to the case when focusing array 6 and photovoltaic layer 4 are disposed in a stationary position with respect to each other and can also be applied to the case when focusing array 6 and photovoltaic layer 4 can be disposed in any one of a translated, a reversed and/or a rotated orientation relative to each other in order, for example, to adjust the optical paths of the incident rays or to track the source of light. Furthermore, focusing array 6 and photovoltaic layer 4 can be made movable with respect to each other to adjust the positions of light input ports 14 with respect of the focal areas of respective lenses 10. Furthermore, a tracking device can be provided to facilitate pointing of system 2 to the light source. Single or multiple instances of system 2 can be provided in the form of panels or plates and installed on an individual tracking unit. When system 2 is used to collect sunlight and convert it to electricity, the tracking device may include mechanical, hydraulic, electric and electronic components such as are those well-known in the art. The tracking device can be implemented as a single-axis or two-axis tracker to follow the diurnal motion of the sun and maintain the prevailing plane of system 2 generally perpendicular to the direction to the sun at least in one angular dimension.
It will be appreciated that, in accordance with preferred embodiments, lenses 10 are provided for pre-focusing of at least the direct beam component of the incident light into a number of smaller beams and injecting said beams into photovoltaic layer 4 through a plurality of small designated areas rather than through the entire surface area. Light input ports 14 are provided to facilitate the injection of the focused beams and can also be located anywhere in system 2 provided they are located in the vicinity of the focal areas of the respective lenses 10 and are optically coupled to photovoltaic layer 4. Various examples and configurations of focusing array 6 and light input ports 14 have been described and provided by way of examples and not limitations. Further examples and configurations will become apparent to those skilled in the art without departing from the scope and spirit of this invention.
Further details of operation of system 2 shown in the drawing figures as well as its possible variations will be apparent from the foregoing description of preferred embodiments. Although the description above contains many details, these should not be construed as limiting the scope of the invention but as merely providing illustrations of some of the presently preferred embodiments of this invention. Therefore, it will be appreciated that the scope of the present invention fully encompasses other embodiments which may become obvious to those skilled in the art, and that the scope of the present invention is accordingly to be limited by nothing other than the appended claims, in which reference to an element in the singular is not intended to mean “one and only one” unless explicitly so stated, but rather “one or more.” All structural, chemical, and functional equivalents to the elements of the above-described preferred embodiment that are known to those of ordinary skill in the art are expressly incorporated herein by reference and are intended to be encompassed by the present claims. Moreover, it is not necessary for a device or method to address each and every problem sought to be solved by the present invention, for it to be encompassed by the present claims. Furthermore, no element, component, or method step in the present disclosure is intended to be dedicated to the public regardless of whether the element, component, or method step is explicitly recited in the claims. No claim element herein is to be construed under the provisions of 35 U.S.C. 112, sixth paragraph, unless the element is expressly recited using the phrase “means for.”
This application is a continuation of application Ser. No. 18/126,353, filed Mar. 24, 2023, which is a continuation of application Ser. No. 17/687,639, filed Mar. 5, 2022, which is a continuation of application Ser. No. 17/119,487, filed Dec. 11, 2020, which is a continuation of application Ser. No. 16/585,550, filed Sep. 27, 2019, which is a division of application Ser. No. 16/368,272, filed Mar. 28, 2019, which is a division of application Ser. No. 15/442,645, filed Feb. 25, 2017, which is a continuation of application Ser. No. 14/222,588, filed Mar. 22, 2014, which is a continuation of application Ser. No. 13/181,482, filed Jul. 12, 2011, which claims priority from U.S. provisional application Ser. No. 61/399,552 filed on Jul. 13, 2010 and from U.S. provisional application Ser. No. 61/402,061 filed on Aug. 21, 2010, each of which is incorporated by reference herein in its entirety.
Not Applicable Not Applicable A portion of the material in this patent document is subject to copyright protection under the copyright laws of the United States and of other countries. The owner of the copyright rights has no objection to the facsimile reproduction by anyone of the patent document or the patent disclosure, as it appears in the United States Patent and Trademark Office publicly available file or records, but otherwise reserves all copyright rights whatsoever. The copyright owner does not hereby waive any of its rights to have this patent document maintained in secrecy, including without limitation its rights pursuant to 37 C.F.R. § 1.14.
| Number | Name | Date | Kind |
|---|---|---|---|
| 4053327 | Meulenberg, Jr. | Oct 1977 | A |
| 4282862 | Soleau | Aug 1981 | A |
| 4379202 | Chalmers | Apr 1983 | A |
| 4711972 | O'Neill | Dec 1987 | A |
| 4877301 | Yokomori | Oct 1989 | A |
| 4906070 | Cobb, Jr. | Mar 1990 | A |
| 4989972 | Braun | Feb 1991 | A |
| 5005108 | Pristash | Apr 1991 | A |
| 5110370 | Vogeli | May 1992 | A |
| 5126882 | Oe | Jun 1992 | A |
| 5220462 | Feldman, Jr. | Jun 1993 | A |
| 5261970 | Landis | Nov 1993 | A |
| 5280371 | McCartney, Jr. et al. | Jan 1994 | A |
| 5396350 | Beeson | Mar 1995 | A |
| 5396406 | Ketchpel | Mar 1995 | A |
| 5598281 | Zimmerman et al. | Jan 1997 | A |
| 5631750 | Minoura | May 1997 | A |
| 5714012 | Murata et al. | Feb 1998 | A |
| 5782993 | Ponewash | Jul 1998 | A |
| 5808784 | Ando et al. | Sep 1998 | A |
| 5854865 | Goldberg | Dec 1998 | A |
| 5897184 | Eichenlaub et al. | Apr 1999 | A |
| 6008449 | Cole | Dec 1999 | A |
| 6139162 | Masaki | Oct 2000 | A |
| 6231200 | Shinohara et al. | May 2001 | B1 |
| 6247826 | Funamoto | Jun 2001 | B1 |
| 6274860 | Rosenberg | Aug 2001 | B1 |
| 6333458 | Forrest et al. | Dec 2001 | B1 |
| 6440769 | Peumans et al. | Aug 2002 | B2 |
| 6474827 | Shinohara et al. | Nov 2002 | B2 |
| 6501091 | Bawendi et al. | Dec 2002 | B1 |
| 6522794 | Bischel | Feb 2003 | B1 |
| 6700632 | Taniguchi et al. | Mar 2004 | B2 |
| 6774361 | Bawendi et al. | Aug 2004 | B2 |
| 6846098 | Bourdelais et al. | Jan 2005 | B2 |
| 6854857 | Hara | Feb 2005 | B2 |
| 6891530 | Umemoto | May 2005 | B2 |
| 7046905 | Gardiner | Jun 2006 | B1 |
| 7102824 | Clark | Sep 2006 | B2 |
| 7113342 | Huang et al. | Sep 2006 | B2 |
| 7131764 | Hsu | Nov 2006 | B2 |
| 7160018 | Chen et al. | Jan 2007 | B2 |
| 7165867 | Long | Jan 2007 | B2 |
| 7199932 | Sugiura | Apr 2007 | B2 |
| 7228050 | Buretea | Jun 2007 | B1 |
| 7246933 | Kunimochi | Jul 2007 | B2 |
| 7369735 | Nyhart, Jr. | May 2008 | B2 |
| 7391939 | Williams | Jun 2008 | B1 |
| 7394841 | Konttinen et al. | Jul 2008 | B1 |
| 7481562 | Chua | Jan 2009 | B2 |
| 7503684 | Ueno et al. | Mar 2009 | B2 |
| 7518799 | Ha | Apr 2009 | B2 |
| 7527410 | Yoshizawa et al. | May 2009 | B2 |
| 7606456 | Nyhart, Jr. | Oct 2009 | B2 |
| 7614776 | Minobe et al. | Nov 2009 | B2 |
| 7649594 | Kim et al. | Jan 2010 | B2 |
| 7663713 | Saito | Feb 2010 | B2 |
| 7667786 | Nouchi | Feb 2010 | B2 |
| 7672549 | Ghosh | Mar 2010 | B2 |
| 7679828 | Munro | Mar 2010 | B2 |
| 7695150 | Dejima | Apr 2010 | B2 |
| 7706073 | Munro | Apr 2010 | B2 |
| 7736045 | Yamashita et al. | Jun 2010 | B2 |
| 7817885 | Moore et al. | Oct 2010 | B1 |
| 7819539 | Kim et al. | Oct 2010 | B2 |
| 7876489 | Gandhi | Jan 2011 | B2 |
| 7916221 | Daiku | Mar 2011 | B2 |
| 7918597 | Kunimochi | Apr 2011 | B2 |
| 7925129 | Ghosh | Apr 2011 | B2 |
| 7934862 | Anandan | May 2011 | B2 |
| 8011819 | Yue | Sep 2011 | B2 |
| 8016445 | Sugita et al. | Sep 2011 | B2 |
| 8017972 | Lee et al. | Sep 2011 | B2 |
| 8033706 | Kelly et al. | Oct 2011 | B1 |
| 8039800 | Soma | Oct 2011 | B2 |
| 8066393 | Takahashi | Nov 2011 | B2 |
| 8070346 | Maeda | Dec 2011 | B2 |
| 8075148 | Nada | Dec 2011 | B2 |
| 8118467 | Teng et al. | Feb 2012 | B2 |
| 8153888 | Smith | Apr 2012 | B2 |
| 8158450 | Sheats | Apr 2012 | B1 |
| 8317693 | Grey | Nov 2012 | B2 |
| 8325297 | Uehara | Dec 2012 | B2 |
| 8343575 | Dubrow | Jan 2013 | B2 |
| 8346048 | Bita | Jan 2013 | B2 |
| 8405063 | Kazlas | Mar 2013 | B2 |
| 8436964 | Kim et al. | May 2013 | B2 |
| 8459855 | Anandan et al. | Jun 2013 | B2 |
| 8496367 | Anandan | Jul 2013 | B2 |
| 8498505 | Moore et al. | Jul 2013 | B2 |
| 8684546 | Ninan | Apr 2014 | B2 |
| 8718437 | Coe-Sullivan | May 2014 | B2 |
| 8849087 | Breen | Sep 2014 | B2 |
| 8879024 | Suzuki et al. | Nov 2014 | B2 |
| 9099046 | Whitehead et al. | Aug 2015 | B2 |
| 9207386 | Kim et al. | Dec 2015 | B2 |
| 9274266 | Ford | Mar 2016 | B2 |
| 9464769 | Ninan et al. | Oct 2016 | B2 |
| 9478182 | Whitehead et al. | Oct 2016 | B2 |
| 10269999 | Vasylyev | Apr 2019 | B2 |
| 10444423 | Dubrow et al. | Oct 2019 | B2 |
| 11616157 | Vasylyev | Mar 2023 | B2 |
| 20010007507 | Iimura | Jul 2001 | A1 |
| 20020018632 | Pelka | Feb 2002 | A1 |
| 20020079485 | Stintz et al. | Jun 2002 | A1 |
| 20020094159 | Goldberg | Jul 2002 | A1 |
| 20040071437 | Tamura | Apr 2004 | A1 |
| 20040103938 | Rider | Jun 2004 | A1 |
| 20040130912 | Miyashita | Jul 2004 | A1 |
| 20040207995 | Park | Oct 2004 | A1 |
| 20040246697 | Yamashita | Dec 2004 | A1 |
| 20050011549 | Miyoshi | Jan 2005 | A1 |
| 20050166957 | Imoto | Aug 2005 | A1 |
| 20060001036 | Jacob | Jan 2006 | A1 |
| 20060056166 | Yeo | Mar 2006 | A1 |
| 20060077687 | Higashiyama | Apr 2006 | A1 |
| 20060103589 | Chua et al. | May 2006 | A1 |
| 20060109682 | Ko et al. | May 2006 | A1 |
| 20060269213 | Hwang | Nov 2006 | A1 |
| 20060272698 | Durvasula | Dec 2006 | A1 |
| 20060279296 | Lee et al. | Dec 2006 | A1 |
| 20070002452 | Munro | Jan 2007 | A1 |
| 20070002583 | Lee | Jan 2007 | A1 |
| 20070018558 | Chua et al. | Jan 2007 | A1 |
| 20070069978 | Daiku | Mar 2007 | A1 |
| 20070070265 | Jung | Mar 2007 | A1 |
| 20070081329 | Chua et al. | Apr 2007 | A1 |
| 20070109811 | Krijn et al. | May 2007 | A1 |
| 20070125415 | Sachs | Jun 2007 | A1 |
| 20070126329 | Chuang et al. | Jun 2007 | A1 |
| 20070146569 | Nouchi | Jun 2007 | A1 |
| 20070201234 | Ottermann | Aug 2007 | A1 |
| 20070242334 | Selbrede | Oct 2007 | A1 |
| 20070274098 | Wheatley et al. | Nov 2007 | A1 |
| 20070279727 | Gandhi | Dec 2007 | A1 |
| 20080012031 | Jang et al. | Jan 2008 | A1 |
| 20080037131 | Steenblik | Feb 2008 | A1 |
| 20080048102 | Kurtz | Feb 2008 | A1 |
| 20080084706 | Roshan et al. | Apr 2008 | A1 |
| 20080101087 | Hwang | May 2008 | A1 |
| 20080158912 | Chang | Jul 2008 | A1 |
| 20080191604 | Morris et al. | Aug 2008 | A1 |
| 20080213508 | Nagasawa | Sep 2008 | A1 |
| 20080225526 | Yoshizawa | Sep 2008 | A1 |
| 20080230112 | Barnham | Sep 2008 | A1 |
| 20080232135 | Kinder | Sep 2008 | A1 |
| 20080232136 | Yamashita et al. | Sep 2008 | A1 |
| 20080252986 | Ijzerman | Oct 2008 | A1 |
| 20080264483 | Keshner et al. | Oct 2008 | A1 |
| 20080264486 | Chen | Oct 2008 | A1 |
| 20080271776 | Morgan | Nov 2008 | A1 |
| 20080291140 | Kent et al. | Nov 2008 | A1 |
| 20080297697 | Kim et al. | Dec 2008 | A1 |
| 20090034292 | Pokrovskiy et al. | Feb 2009 | A1 |
| 20090059621 | Takahashi | Mar 2009 | A1 |
| 20090067170 | Bloemen | Mar 2009 | A1 |
| 20090067784 | Ghosh et al. | Mar 2009 | A1 |
| 20090091681 | Nishizawa | Apr 2009 | A1 |
| 20090097100 | Gally | Apr 2009 | A1 |
| 20090097229 | Wood et al. | Apr 2009 | A1 |
| 20090112068 | Grey | Apr 2009 | A1 |
| 20090114280 | Jensen | May 2009 | A1 |
| 20090116107 | Kindler et al. | May 2009 | A1 |
| 20090122533 | Brukilacchio | May 2009 | A1 |
| 20090126777 | Khazeni et al. | May 2009 | A1 |
| 20090126792 | Gruhlke | May 2009 | A1 |
| 20090129726 | Hyde | May 2009 | A1 |
| 20090135623 | Kunimochi | May 2009 | A1 |
| 20090139571 | Chen | Jun 2009 | A1 |
| 20090161383 | Meir | Jun 2009 | A1 |
| 20090180191 | Yamada | Jul 2009 | A1 |
| 20090195729 | Little et al. | Aug 2009 | A1 |
| 20090199900 | Bita | Aug 2009 | A1 |
| 20090214156 | Okubo | Aug 2009 | A1 |
| 20090215208 | Coe-Sullivan et al. | Aug 2009 | A1 |
| 20090229652 | Mapel et al. | Sep 2009 | A1 |
| 20090231831 | Hsiao et al. | Sep 2009 | A1 |
| 20090277496 | Khazeni | Nov 2009 | A1 |
| 20090296193 | Bita et al. | Dec 2009 | A1 |
| 20100002414 | Meir et al. | Jan 2010 | A1 |
| 20100002466 | Kim et al. | Jan 2010 | A1 |
| 20100006139 | Zahuranec | Jan 2010 | A1 |
| 20100015738 | Kim | Jan 2010 | A1 |
| 20100026703 | Parker et al. | Feb 2010 | A1 |
| 20100033989 | Teng | Feb 2010 | A1 |
| 20100051089 | Khazeni | Mar 2010 | A1 |
| 20100053992 | Krijn | Mar 2010 | A1 |
| 20100108056 | Lin | May 2010 | A1 |
| 20100110728 | Dubrow et al. | May 2010 | A1 |
| 20100116319 | Martinez Anton | May 2010 | A1 |
| 20100116336 | Martinez Anton | May 2010 | A1 |
| 20100139165 | Oyama | Jun 2010 | A1 |
| 20100139749 | Mapel | Jun 2010 | A1 |
| 20100155749 | Chen et al. | Jun 2010 | A1 |
| 20100180928 | Raymond | Jul 2010 | A1 |
| 20100180946 | Gruhlke | Jul 2010 | A1 |
| 20100186798 | Tormen | Jul 2010 | A1 |
| 20100193018 | Feist | Aug 2010 | A1 |
| 20100200044 | Zaban | Aug 2010 | A1 |
| 20100208493 | Choi et al. | Aug 2010 | A1 |
| 20100224242 | Chang | Sep 2010 | A1 |
| 20100231613 | Hamada | Sep 2010 | A1 |
| 20100259826 | Ji | Oct 2010 | A1 |
| 20100277950 | Shchekin | Nov 2010 | A1 |
| 20100278480 | Vasylyev | Nov 2010 | A1 |
| 20100283072 | Kazlas | Nov 2010 | A1 |
| 20100288352 | Ji | Nov 2010 | A1 |
| 20100302218 | Bita | Dec 2010 | A1 |
| 20100328654 | Verschuren | Dec 2010 | A1 |
| 20110048498 | Vaananen | Mar 2011 | A1 |
| 20110061717 | Kwon | Mar 2011 | A1 |
| 20110226332 | Ford | Sep 2011 | A1 |
| 20110227487 | Nichol et al. | Sep 2011 | A1 |
| 20110308611 | Morgan | Dec 2011 | A1 |
| 20120012741 | Vasylyev | Jan 2012 | A1 |
| 20120067402 | Kitai | Mar 2012 | A1 |
| 20120113671 | Sadasivan et al. | May 2012 | A1 |
| 20120113672 | Dubrow et al. | May 2012 | A1 |
| 20120182615 | Vasylyev | Jul 2012 | A1 |
| 20130028565 | Moore et al. | Jan 2013 | A1 |
| 20130160820 | Lin | Jun 2013 | A1 |
| 20230231067 | Vasylyev | Jul 2023 | A1 |
| Number | Date | Country |
|---|---|---|
| 1941421 | Apr 2007 | CN |
| 201029095 | Feb 2008 | CN |
| 2628291 | Dec 1977 | DE |
| 1998197 | Dec 2008 | EP |
| 2023039 | Feb 2009 | EP |
| 2061092 | May 2009 | EP |
| 2157366 | Feb 2010 | EP |
| 2202806 | Jun 2010 | EP |
| 06265732 | Jul 1996 | JP |
| 2001289515 | Oct 2001 | JP |
| 2002208306 | Jul 2002 | JP |
| 2002208308 | Jul 2002 | JP |
| 2003046103 | Feb 2003 | JP |
| 2003069067 | Mar 2003 | JP |
| 2003078151 | Mar 2003 | JP |
| 2003078156 | Mar 2003 | JP |
| 2003086823 | Mar 2003 | JP |
| 2003101059 | Apr 2003 | JP |
| 2003218378 | Jul 2003 | JP |
| 200447278 | Feb 2004 | JP |
| 2004111453 | Apr 2004 | JP |
| 2004111742 | Apr 2004 | JP |
| 2004221119 | Aug 2004 | JP |
| 08190095 | Nov 2004 | JP |
| 2004311388 | Nov 2004 | JP |
| 2005071928 | Mar 2005 | JP |
| 2005353406 | Dec 2005 | JP |
| 200640710 | Feb 2006 | JP |
| 2006114239 | Apr 2006 | JP |
| 2006114239 | Apr 2006 | JP |
| 2006261088 | Sep 2006 | JP |
| 2006261248 | Sep 2006 | JP |
| 2006302454 | Nov 2006 | JP |
| 200726878 | Feb 2007 | JP |
| 2007087647 | Apr 2007 | JP |
| 2007240686 | Sep 2007 | JP |
| 2007256575 | Oct 2007 | JP |
| 2008122977 | May 2008 | JP |
| 2008198376 | Aug 2008 | JP |
| 4170320 | Oct 2008 | JP |
| 2008270222 | Nov 2008 | JP |
| 2009043574 | Feb 2009 | JP |
| 2009115924 | May 2009 | JP |
| 2009277464 | Nov 2009 | JP |
| 2009277817 | Nov 2009 | JP |
| 2009301805 | Dec 2009 | JP |
| 201034017 | Feb 2010 | JP |
| 2010152370 | Jul 2010 | JP |
| 2010250987 | Nov 2010 | JP |
| 20000038594 | Jul 2000 | KR |
| 20040045482 | Jun 2004 | KR |
| 100671649 | Jan 2007 | KR |
| 20080015999 | Feb 2008 | KR |
| 20080038594 | May 2008 | KR |
| 20080113887 | Dec 2008 | KR |
| 100933213 | Dec 2009 | KR |
| 20110096561 | Aug 2011 | KR |
| 200941089 | Oct 2009 | TW |
| 2006039315 | Apr 2006 | WO |
| 2006104319 | Oct 2006 | WO |
| 2006126155 | Nov 2006 | WO |
| WO2007020820 | Feb 2007 | WO |
| WO2007036877 | Apr 2007 | WO |
| 2007111959 | Oct 2007 | WO |
| 2007125803 | Nov 2007 | WO |
| 2008045311 | Apr 2008 | WO |
| 2008092038 | Jul 2008 | WO |
| 2008099542 | Aug 2008 | WO |
| 2009002512 | Dec 2008 | WO |
| 2009011922 | Jan 2009 | WO |
| 2009014707 | Jan 2009 | WO |
| 2009024509 | Feb 2009 | WO |
| WO2009031728 | Mar 2009 | WO |
| 2009064701 | May 2009 | WO |
| 2009065069 | May 2009 | WO |
| 2009066056 | May 2009 | WO |
| 2009073470 | Jun 2009 | WO |
| 2009035986 | Jul 2009 | WO |
| WO2009114620 | Sep 2009 | WO |
| 2009134552 | Nov 2009 | WO |
| 2009144650 | Dec 2009 | WO |
| 2010033002 | Mar 2010 | WO |
| 2009007832 | Apr 2010 | WO |
| 2010062713 | Jun 2010 | WO |
| WO2010029751 | Feb 2012 | WO |
| 2013067288 | May 2013 | WO |
| Entry |
|---|
| U.S. Appl. No. 60/951,775, Morgan. |
| U.S. Appl. No. 60/946,382, Coe-Sullivan. |
| Eugene Hecht. Optics. 2nd Edition, ISBN 0-201-11609-X. (1987), 132-135, 141. |
| Handbook of Plastic Optics. Ed. Stefan Baumer. WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim (2005). 1-189. |
| Mike Kelly. Innovative Solutions for Light Management and Visual Communication. 2008 3M Outlook Meeting. |
| Kristofer Tvingstedt, Simone Dal Zilio, Olle Inganas, Massimo Tormen, “Trapping light with micro lenses in thin film organic photovoltaic cells”, Optics Express, vol. 16, No. 26, Dec. 22, 2008. |
| Kristofer Tvingstedt, Massimo Tormen, Luca Businaro, Olle Inganas, “Light confinement in thin film organic photovoltaic cells”, Photonics for Solar Energy Systems, Ed. Andreas Gombert, Proc. of SPIE vol. 6197, 2006. |
| Defendant Asustek Computer Inc.s Preliminary Invalidity Contentions dated Sep. 30, 2022. |
| Information Display/Display Week—Newsletters and Directories, 2008-2009. |
| Defendants Micro-Star International Co., Ltd. (“MSI”), Acer, Inc., and ASUSTeK Computer Inc. Final Invalidity Contentions dated Jun. 16, 2023. |
| Simone Dal Zilio, Kristofer Tvingstedt, Olle Inganas, Massimo Tormen, Fabrication of a light trapping system for organic solar cells, Microelectronic Engineering 86 (2009), 1150-1154. |
| Jason H. Karp and Joseph E. Ford, Planar micro-optic solar concentration using multiple imaging lenses into a common slab waveguide, Proc. of SPIE vol. 7407 74070D-11, (2009). |
| LCD Backlights Shunsuke Kobayashi, Sigeo Mikoshiba, Sungkyoo Lim (John Wiley & Sons, Ltd.), 2009. pp. 82-86. |
| Number | Date | Country | |
|---|---|---|---|
| 20240322059 A1 | Sep 2024 | US |
| Number | Date | Country | |
|---|---|---|---|
| 61402061 | Aug 2010 | US | |
| 61399552 | Jul 2010 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 16368272 | Mar 2019 | US |
| Child | 16585550 | US | |
| Parent | 15442645 | Feb 2017 | US |
| Child | 16368272 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 18126353 | Mar 2023 | US |
| Child | 18593940 | US | |
| Parent | 17687639 | Mar 2022 | US |
| Child | 18593940 | US | |
| Parent | 17119487 | Dec 2020 | US |
| Child | 18126353 | US | |
| Parent | 16585550 | Sep 2019 | US |
| Child | 17119487 | US | |
| Parent | 14222588 | Mar 2014 | US |
| Child | 15442645 | US | |
| Parent | 13181482 | Jul 2011 | US |
| Child | 14222588 | US |
