The field of this invention is a method of making polishing pads having more than one endpoint detection windows.
Chemical Mechanical Planarization (CMP) is a variation of a polishing process that is widely used to flatten, or planarize, the layers of construction of an integrated circuit or similar structure. The process is often used as part of the manufacture when using lithography with multiple deposition steps, in order to precisely build multilayer three-dimensional structure or circuitry. The layer to be polished is typically a thin film (e.g. less than 10,000 Angstroms) that has been deposited on an underlying substrate. The objectives of CMP are to remove excess material on the substrate (e.g. wafer) surface to produce an extremely flat layer of a uniform thickness, the uniformity extending across the entire substrate (e.g. wafer) area.
CMP utilizes a liquid, often called slurry, which can contain nano-sized particles. The slurry is fed onto the surface of a rotating multilayer polymer pad (sometimes referred to as polishing sheet), the pad being mounted on a rotating platen. Substrates (e.g. wafers) are mounted into a separate fixture, or carrier, which has a separate means of rotation, and pressed against the surface of the pad under a controlled load. This can lead to a high rate of relative motion between the substrate (e.g. wafer) and the polishing pad and a resulting high rate of shear or abrasion at both the substrate and the pad surface. The shear in combination with the slurry particles trapped at the pad/substrate junction abrade the substrate (e.g. wafer) surface, leading to removal of material from the substrate surface. Control of removal rate and the uniformity of removal are important.
Commercial CMP pads are multilayer composites. In addition to an upper polishing layer, which contacts the substrate (e.g. wafer) to be polished, one or more subpad layers are employed to adjust the compliance of the pad under pressure, particularly over the full area of the pad, to better achieve the required film uniformity across the full substrate (e.g. wafer) surface. Controlled increase in compliance can be achieve by using a subpad material of lower modulus than the upper layer and adjusting the relative thicknesses of both layers to achieve the desired result.
In order to precisely control the final thickness of the polished film (the endpoint), film measurement during polishing is widely employed. There are two main metrology approaches for endpointing. One approach for endpoint detection uses transmittance of desired wavelengths of light through the polishing pad, the light reflects from the substrate being polished, and the reflected light signal then passes back to the interferometer, which processes the reflectance signal to determine if the polishing has reached its desired goal (e.g., film thickness, intended reveal of an underlying structure). The metrology equipment can be located within the body of the platen that holds the pad. In some instances, the optical equipment may extend above the platen into the plane of the subpad layers of the CMP pad. Thus, a recess may be desired in the subpad where the window is placed.
This method requires the polishing pad to have at least a portion to be transparent to the wavelengths of light being used in the interferometer. In some pad designs this is achieved by providing a window material of a different composition than the upper pad layer is disposed in an aperture within the pad since many polishing layer materials are opaque. Use of such windows requires alignment of apertures in both the polishing layer and the subpad layer(s).
As integrated circuit dimensions scale down, increasingly accurate real-time film thickness measurements are critical for process control. This has led to the adoption of multiple endpoint units per platen and the use of multispectral optics to allow accurate real-time measurements of film thickness profiles via triangulation and signal processing. Further, to avoid reducing the area for polishing, it can be desirable to reduce the aperture size (window size). As a result, the manufacturing tolerances of current CMP pad windows are becoming more stringent. In addition, maintaining alignment of windows with respect to polishing layer and subpad layer apertures can be challenging. For instance, when forming the multi-layer pad (e.g. by lamination or the like) the differing materials of the polishing and subpad layers may shrink or stretch in different proportions causing misalignment such that the aperture in the subpad does not align with the window or does not align with the aperture in the polishing layer. Also, in forming separate apertures in each layer and then laminating, the pre-formed apertures may not have been in completely consistent locations to enable full alignment of more than two apertures or the aperture and windows in the layers. For example, if there are two apertures in each of the polishing layer and the subpad layer(s) if those are formed at a slightly distinct distance in each layer, then it will be impossible to have full alignment. Total misalignment—e.g., where there is no overlap of the apertures of the subpad and polishing layer or no overlap of the window with one of the apertures—would prevent any use of the window. Partial misalignment—e.g., where the subpad aperture overlaps partially with the window—can narrow the transparent region enough to make it difficult to use for end detection (for example by producing attenuation and noise during measurements that can lead to endpoint detection errors). The misalignment issues can be particularly problematic in pads with multiple windows with smaller aperture sizes. Accordingly, a pad manufacturing process capable of producing a multilayer window pad in a simplified manufacturing process with increased window location precision in all dimensions that is useful for a wide variety of top pad materials would represent a significant improvement in the art.
Disclosed herein is a method of manufacturing a chemical mechanical polishing pad having two or more end point detection windows comprising providing a structure that includes a polishing layer having a top surface defining a horizontal direction, a bottom surface, and two or more apertures extending from the top surface to the bottom surface wherein each of the two or more apertures has a transparent window located in the aperture, wherein each of the windows has a portion extending outward from the bottom surface of the polishing layer, wherein the two or more apertures are located at select distance from each other, applying a subpad material on the bottom surface of the polishing layer and wherein the two or more apertures remain at the select distance from each other and the portion of the windows extending outward from the bottom surface, and revealing the windows by removing a portion of the subpad material.
Referring now to the figures, which are exemplary embodiments, and wherein the like elements are numbered alike.
The present application is a method of forming a pad that allows for precise locating of more than one window in the pad. The method avoids the problems of misalignment of apertures in the subpad with the apertures in the polishing layer and misalignment of the windows in the apertures. Such misalignment may be caused for example by one or more of the following: by different coefficients of thermal expansion in the layers, different stretching of deformation of the layers during manufacture, imprecise location of apertures in two different layers, imprecise alignment of apertures during lamination, or the like, or a combination of two or more of those causes.
Thus, the method comprises providing a polishing layer having a top surface defining a horizontal direction, a bottom surface (also referred to herein as an interface surface), and two or more apertures extending from the top surface to the bottom surface, wherein each of the two or more apertures is located at a select distance from the other aperture(s). Located in the aperture, is a transparent window. The windows each include a portion extending outward from the bottom surface of the polishing layer. The method includes applying a subpad material on the bottom surface and the portion of the windows extending outward from the bottom surface, and then removing a portion of the subpad material to expose the windows. This method ensures alignment of the windows with the apertures in the polishing layer as each window is located in one of such apertures. This method further ensures alignment of the polishing layer aperture windows with the aperture in the subpad.
The subpad layer 06 can comprise one or more layers. The subpad layer(s) can comprise a material that is more compliant than the material of the polishing layer 05. The subpad layer(s) 06 can comprise a polymeric material. The subpad 06 can comprise a porous layer. Examples of polymeric materials for the subpad layer(s) include polyurethanes, polycarbonates, polysulfones, nylons, epoxy resins, polyethers, polyesters, polystyrenes, acrylic polymers, polymethyl methacrylates, polyvinylchlorides, polyvinyl fluorides, polyethylenes, polypropylenes, polybutadienes, polyethylene imines, polyether sulfones, polyamides, polyether imides, polyketones, silicones, copolymers thereof (such as, polyether-polyester copolymers), and combinations or blends thereof.
After forming the polishing layer 205 (before or after any needed reveal step), the polishing layer with at least two windows in two apertures formed in the preceding steps is removed from the mold 208 exposing an interface surface 205i and the lower portion of the windows 204. (See
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This disclosure further encompasses the following aspects.
Aspect 1: A method of manufacturing a chemical mechanical polishing pad having two or more end point detection windows comprising providing a structure that includes a polishing layer having a top surface defining a horizontal direction, a bottom surface, and two or more apertures extending from the top surface to the bottom surface wherein each of the two or more apertures has a transparent window located in the aperture, where each of the windows has a portion extending outward from the bottom surface of the polishing layer, wherein the two or more apertures are located at select distance from each other, applying a subpad material on the bottom surface and the portion of the windows extending outward from the bottom surface, and revealing the windows by removing a portion of the subpad material.
Aspect 2. The method of Aspect 1 wherein the providing of the structure comprises providing a mold with a surface and two or more recesses in the surface each recess formed to receive a portion of one of the windows, the recesses being located at the select distance from each other, inserting the windows into the recesses such that a top portion of each the windows extends above the mold surface, forming the polishing layer on the mold surface and around a periphery of the top portion of the windows, and removing the polishing layer with the windows from the mold.
Aspect 3. The method of Aspect 2 wherein in forming the polishing layer a top surface of the windows is covered by a portion of the polishing layer and further comprising revealing the top surface of the windows by removal of a portion of the polishing layer.
Aspect 4. The method of Aspect 1 wherein the providing of the structure comprises forming the two or more apertures in the polishing layer at the select distance from each other, providing the windows for each aperture, each window having a top portion and a flange portion, wherein the top portion has an area in the horizontal direction that is smaller than an area of the flange portion in the horizontal direction such that the second portion forms a rim, applying adhesive to the bottom surface of the polishing layer adjacent the aperture, to the rim of the windows, or both, and inserting into each of the two or more the apertures one of the windows such that the polishing layer surrounds a periphery of the top portion of each of the windows in the horizontal direction.
Aspect 5. The method of Aspect 4 wherein at least a segment the flange portion of the windows forms the portion of the window that extends from the bottom surface of the polishing layer.
Aspect 6. The method of Aspect 4 wherein the flange portion of the windows is between the top portion of the windows and a bottom portion of the windows, wherein the bottom portion has an area in the horizontal direction that is smaller than the area of the flange portion in the horizontal direction, wherein the bottom portion, or the bottom portion and at least a segment of the flange portion form the portion of the windows extending outward from the bottom surface of the polishing layer and the area of the flange portion in the horizontal direction is larger than the area of the portion of the window extending outward from the bottom surface of the polishing layer.
Aspect 7. The method of any one of Aspects 1-6 wherein the subpad material is applied by coating, injection molding, printing.
Aspect 8. The method of any one of Aspects 1-7 wherein an amount of the portion of the window extending outward from the bottom surface of the polishing layer is removed during or after the removing of a portion of the subpad material to form a recessed window.
Aspect 9. The method of any one of Aspects 1-8 wherein there are three or more apertures and windows and the select distance between adjacent apertures is the same or different.
Aspect 10. The method of any one of Aspects 1-9 wherein the select distance corresponds to a distance of placement of endpoint detectors in a chemical mechanical polishing apparatus having two or more endpoint detectors.
Aspect 11: The method of any one of Aspects 1-10 wherein each of the apertures in the polishing layer and each of the windows in the pad are at a distance from a center of the polishing layer, preferably a radial distance, which is the same for each aperture and equidistant from the center.
Aspect 12: The method of any one of Aspects 1-11 wherein there are three windows that are equidistant from each other.
Aspect 13: The method of any one of Aspects 1-12 wherein the windows are of the same size.
All ranges disclosed herein are inclusive of the endpoints, and the endpoints are independently combinable with each other (e.g., ranges of “up to 25 wt. %, or, more specifically, 5 wt. % to 20 wt. %”, is inclusive of the endpoints and all intermediate values of the ranges of “5 wt. % to 25 wt. %,” etc.). Moreover, stated upper and lower limits can be combined to form ranges (e.g. “at least 1 or at least 2 weight percent” and “up to 10 or 5 weight percent” can be combined as the ranges “1 to 10 weight percent”, or “1 to 5 weight percent” or “2 to 10 weight percent” or “2 to 5 weight percent”).
The disclosure may alternately comprise, consist of, or consist essentially of, any appropriate components herein disclosed. The disclosure may additionally, or alternatively, be formulated so as to be devoid, or substantially free, of any components, materials, ingredients, adjuvants or species used in the prior art compositions or that are otherwise not necessary to the achievement of the function or objectives of the present disclosure.
All cited patents, patent applications, and other references are incorporated herein by reference in their entirety. However, if a term in the present application contradicts or conflicts with a term in the incorporated reference, the term from the present application takes precedence over the conflicting term from the incorporated reference.
Unless specified to the contrary herein, all test standards are the most recent standard in effect as of the filing date of this application, or, if priority is claimed, the filing date of the earliest priority application in which the test standard appears.
References numerals stand for the element/component as listed below: