The present invention relates to methods of manufacturing plate-like members, intermediate bodies for plate-like members, and plate-like members.
Recently, attention has been increasingly focused on light-emitting devices and the like using LEDs or LDs, as next-generation light sources to replace fluorescence lamps and incandescent lamps. As an example of such a next-generation light source, a light-emitting device is disclosed in which an LED capable of emitting a blue light is combined with a wavelength conversion member capable of absorbing part of the light from the LED to convert it to a yellow light. This light-emitting device emits a white light which is a synthesized light of the blue light emitted from the LED and having passed through the wavelength conversion member and the yellow light emitted from the wavelength conversion member.
Patent Literature 1 below describes an example of a light-emitting device using a wavelength conversion member. In obtaining a wavelength conversion member in the production of a light-emitting device, there may be adopted a method of dividing a base material for a wavelength conversion member into parts to obtain a plurality of wavelength conversion members at one time. Patent Literature 1 below describes, as an example of such a dividing process, forming breaking grooves in a grid-like pattern in a base material for wavelength conversion members and then breaking the base material into parts along the breaking grooves. This dividing process is implemented by breaking the base material for wavelength conversion members into separate parts along the breaking grooves extending in one direction (for example, an X direction) of the grid-like pattern and then breaking the separate parts into smaller parts along the breaking grooves extending in the other direction (for example, a Y direction) of the grid-like pattern. The wavelength conversion member obtained by the dividing process is attached to a light source, such as an LED.
In dividing a base material for plate-like members, such as wavelength conversion members, cracks are formed to originate at the breaking grooves and extend in the thickness direction of the base material for plate-like members and, thus, the base material for plate-like members is broken into separate parts. However, cracks may occur which originate at the breaking grooves but extend in directions deviating from the above thickness direction. Therefore, shape defects, such as burrs, may occur in the plate-like members obtained by dividing process.
The present invention aims at providing: a method of manufacturing plate-like members and an intermediate body for plate-like members whereby the occurrence of shape defects in the plate-like members can be prevented; and a plate-like member in which shape defects are prevented.
A method of manufacturing a plate-like member according to the present invention includes the steps of: providing a first breaking groove in a first principal surface of a base material for plate-like members, the base material having the first principal surface and a second principal surface opposed to each other, and then providing a second breaking groove in the second principal surface of the base material for plate-like members in a direction crossing the first breaking groove in plan view to form an intermediate body for plate-like members; and breaking the intermediate body for plate-like members into separate parts along one of the first breaking groove and the second breaking groove and then breaking the intermediate body for plate-like members into separate parts along the other of the first breaking groove and the second breaking groove, wherein in breaking the intermediate body for plate-like members into separate parts along the first breaking groove, the intermediate body for plate-like members is broken into separate parts along the first breaking groove by pressing the intermediate body for plate-like members from the second principal surface side, and in breaking the intermediate body for plate-like members into separate parts along the second breaking groove, the intermediate body for plate-like members is broken into separate parts along the second breaking groove by pressing the intermediate body for plate-like members from the first principal surface side.
A method of manufacturing a plate-like member according to the present invention is a method of manufacturing a plurality of plate-like members by breaking an intermediate body for plate-like members into separate parts, the intermediate body body being provided with a first breaking groove and a second breaking groove, wherein the intermediate body for plate-like members is obtained by providing the first breaking groove in a first principal surface of a base material for plate-like members, the base material having the first principal surface and a second principal surface opposed to each other, and then providing the second breaking groove in the second principal surface of the base material for plate-like members in a direction crossing the first breaking groove in plan view, the method includes the step of breaking the intermediate body for plate-like members into separate parts along one of the first breaking groove and the second breaking groove and then breaking the intermediate body for plate-like members into separate parts along the other of the first breaking groove and the second breaking groove, in breaking the intermediate body for plate-like members into separate parts along the first breaking groove, the intermediate body for plate-like members is broken into separate parts along the first breaking groove by pressing the intermediate body for plate-like members from the second principal surface side, and in breaking the intermediate body for plate-like members into separate parts along the second breaking groove, the intermediate body for plate-like members is broken into separate parts along the second breaking groove by pressing the intermediate body for plate-like members from the first principal surface side.
The first breaking groove and the second breaking groove are preferably orthogonal to each other in plan view.
The plate-like member is preferably a wavelength conversion member. In this case, the wavelength conversion member is preferably formed so that phosphor particles are dispersed in an inorganic matrix.
The plate-like member is preferably a brittle material substrate. In this case, the brittle material substrate is more preferably a glass plate, a glass-ceramic plate or a ceramic plate.
An intermediate body for plate-like members according to the present invention is an intermediate body for plate-like members for use to obtain a plurality of plate-like members by breaking the intermediate body into separate parts, wherein the intermediate body for plate-like members has a first principal surface and a second principal surface opposed to each other, the first principal surface is provided with a first breaking groove, and the second principal surface is provided with a second breaking groove crossing the first breaking groove in plan view.
A plate-like member according to the present invention includes: a first principal surface and a second principal surface opposed to each other; a first side surface and a second side surface connected directly or indirectly to the first principal surface and the second principal surface and opposed to each other; a third side surface and a fourth side surface connected directly or indirectly to the first principal surface and the second principal surface and opposed to each other; a first inclined surface provided to connect between the first principal surface and the first side surface; a second inclined surface provided to connect between the first principal surface and the second side surface; a third inclined surface provided to connect between the second principal surface and the third side surface; and a fourth inclined surface provided to connect between the second principal surface and the fourth side surface.
The present invention enables provision of: a method of manufacturing plate-like members and an intermediate body for plate-like members whereby the occurrence of shape defects in the plate-like members can be prevented; and a plate-like member in which shape defects are prevented.
Hereinafter, a description will be given of a preferred embodiment. However, the following embodiment is merely illustrative and the present invention is not limited to the following embodiment. Throughout the drawings, members having substantially the same functions may be referred to by the same reference characters.
[Plate-Like Member]
The first principal surface 1a is connected via the first inclined surface 1g indirectly to the first side surface 1c. The first principal surface 1a is connected via the second inclined surface 1h indirectly to the second side surface 1d. On the other hand, the second principal surface 1b is connected directly to the first side surface 1c and the second side surface 1d. The cross-sectional shapes of the first inclined surface 1g and the second inclined surface 1h are linear. However, the cross-sectional shape of at least a portion of the first inclined surface 1g may be a curved shape. The cross-sectional shape of at least a portion of the second inclined surface 1h may also be a curved shape.
The second principal surface 1b is connected via the third inclined surface 1i indirectly to the third side surface 1e. The second principal surface 1b is connected via the fourth inclined surface 1j indirectly to the fourth side surface 1f. On the other hand, the first principal surface 1a is connected directly to the third side surface 1e and the fourth side surface 1f. The cross-sectional shapes of the third inclined surface 1i and the fourth inclined surface 1j are linear. However, the cross-sectional shape of at least a portion of the third inclined surface 1i may be a curved shape. The cross-sectional shape of at least a portion of the fourth inclined surface 1j may also be a curved shape.
Herein, the term “plan view” refers to a direction of view from the upper side in
As shown in
The type of the phosphor particles 2 is not particularly limited so long as they can emit fluorescence upon incidence of excitation light A. Specific examples of the type of the phosphor particles 2 include one or more selected from the group consisting of an oxide phosphor, a nitride phosphor, an oxynitride phosphor, a chloride phosphor, an oxychloride phosphor, a sulfide phosphor, an oxysulfide phosphor, a halide phosphor, a chalcogenide phosphor, an aluminate phosphor, a halophosphoric acid chloride phosphor, and a garnet-based compound phosphor. In using a blue light as the excitation light A, for example, a phosphor capable of emitting a green light, a yellow light or a red light as fluorescence can be used.
The average particle diameter of the phosphor particles 2 is preferably 1 μm to 50 μm and more preferably 5 μm to 30 μm. If the average particle diameter of the phosphor particles 2 is too small, the luminescence intensity may decrease. On the other hand, if the average particle diameter of the phosphor particles 2 is too large, the luminescent color may be uneven.
The content of phosphor particles 2 in the wavelength conversion member 1 is preferably not less than 1% by volume, more preferably not less than 1.5% by volume, and still more preferably not less than 2% by volume. The content of phosphor particles 2 in the wavelength conversion member 1 is preferably not more than 70% by volume, more preferably not more than 50% by volume, and still more preferably not more than 30% by volume. If the content of phosphor particles 2 is too small, it is necessary to increase the thickness of the wavelength conversion member 1 in order to obtain a desired luminescent color. This results in increased internal scattering of the resultant wavelength conversion member, which may decrease the light extraction efficiency. On the other hand, if the content of phosphor particles 2 is too large, it is necessary to decrease the thickness of the wavelength conversion member 1 in order to obtain the desired luminescent color, which may decrease the mechanical strength of the wavelength conversion member 1.
No particular limitation is placed on the type of inorganic material for use in the inorganic matrix 3 so long as it can be used as a dispersion medium for the phosphor particles 2, and an example that can be used is glass. Examples of the glass for use in the inorganic matrix 3 include a borosilicate-based glass, a phosphate-based glass, a tin-phosphate-based glass, and a bismuthate-based glass. Examples of the borosilicate-based glass include those containing, in terms of % by mass, 30% to 85% SiO2, 0% to 30% Al2O3, 0% to 50% B2O3, 0% to 10% Li2O+Na2O+K2O, and 0% to 50% MgO+CaO+SrO+BaO. Examples of the tin-phosphate-based glass include those containing, in terms of % by mole, 30% to 90% SnO and 1% to 70% P2O5.
In this embodiment, the wavelength conversion member 1 as a plate-like member is formed so that the phosphor particles 2 are dispersed in the inorganic matrix 3. However, the wavelength conversion member may be a phosphor ceramic plate. The plate-like member is not limited to the wavelength conversion member. Examples of the plate-like member include, other than the wavelength conversion member, a brittle material substrate made of inorganic material, such as a glass plate, a glass-ceramic plate or a ceramic plate, and a plate-like semiconductor device.
The wavelength conversion member 1 according to this embodiment is obtained by breaking a base material for wavelength conversion members as a base material for plate-like members into separate parts. More specifically, the wavelength conversion member is obtained by breaking an intermediate body for wavelength conversion members, which is formed from the base material for wavelength conversion members and is an intermediate body for plate-like members according to an embodiment of the present invention, into separate parts.
[Intermediate Body for Plate-Like Members]
The intermediate body 11 for wavelength conversion members has a first principal surface 11a and a second principal surface 11b opposed to each other. The intermediate body 11 for wavelength conversion members has a rectangular plate-like shape. However, the shape of the intermediate body 11 for wavelength conversion members is not limited to the rectangular plate-like shape.
The first principal surface 11a of the intermediate body 11 for wavelength conversion members has a plurality of first breaking grooves 12a extending in an X direction. The second principal surface 11b thereof has a plurality of second breaking grooves 13a extending in a Y direction. In this embodiment, the first breaking grooves 12a are orthogonal to the second breaking grooves 13a in plan view. The first breaking grooves 12a may not necessarily be orthogonal to the second breaking grooves 13a in plan view and it is sufficient that the former crosses the latter in plan view. Herein, “extending in the X direction” includes extending substantially in parallel with the X direction without impairing the effects of the invention. Likewise, “extending in the Y direction” includes extending substantially in parallel with the Y direction without impairing the effects of the invention.
In this embodiment, the pattern of the first breaking grooves 12a and the second breaking grooves 13a is formed in a grid-like manner in plan view. However, the pattern of the breaking grooves is not limited to the grid-like manner and a pattern to meet the shape of finally manufactured plate-like members can be appropriately selected.
The depths of the first breaking grooves 12a and the second breaking grooves 13a are not particularly limited, but each of them is preferably in a range of 0.1% to 10% and more preferably in a range of 0.5% to 5% of the thickness of the intermediate body 11 for wavelength conversion members. If the depth of the breaking grooves is too small, breaking along the breaking grooves may be difficult to achieve. If the depth of the breaking grooves is too large, the load for forming the breaking grooves becomes too large, so that cracks may develop in unintended directions, resulting in failure to break the intermediate body into separate parts in a direction perpendicular to the first principal surface 11a.
The width of each of the first breaking grooves 12a and the second breaking grooves 13a is preferably not less than 0.001 mm and more preferably not less than 0.002 mm. On the other hand, the width of each of the first breaking grooves 12a and the second breaking grooves 13a is preferably not more than 0.010 mm and more preferably not more than 0.005 mm. If the width is too large, missing portions may occur during the breaking. If the width is too small, breaking along the breaking grooves may be difficult to achieve.
The intermediate body 11 for wavelength conversion members is formed so that phosphor particles are dispersed in an inorganic matrix. The intermediate body 11 for wavelength conversion members can be made of the same material as the above-described wavelength conversion member 1. However, the intermediate body for plate-like members may be, except for one in which phosphor particles are dispersed in an inorganic matrix, for example, a brittle material substrate made of inorganic material, such as a glass plate, a glass-ceramic plate, a phosphor ceramic plate or a ceramic plate other than the phosphor ceramic plate, or a plate-like semiconductor device.
[Method of Manufacturing Plate-Like Members]
(Step of Forming Intermediate Body for Plate-Like Members)
A description will be given below of an example of a method of manufacturing plate-like members according to one embodiment of the present invention. The plate-like member in this embodiment is the above-described plate-like wavelength conversion member.
First, a rectangular plate-like base material 21 for wavelength conversion members shown in
Next, as shown in
The first breaking grooves 12a and the second breaking grooves 13a are preferably formed by scribing. A specific method for forming the first breaking grooves 12a and the second breaking grooves 13a can be appropriately selected depending upon the material of the inorganic matrix. If the inorganic matrix is glass, the breaking grooves are preferably formed by a scriber or the like using diamond particles or the like. In the case of use of scribing, for example, it is possible to form the first breaking grooves 12a in the first principal surface 21a of the base material 21 for wavelength conversion members, then turn over the base material 21 for wavelength conversion members, and then form the second breaking grooves 13a in the second principal surface 21b. Alternatively, depending upon the material of the inorganic matrix, the first breaking grooves 12a and the second breaking grooves 13a may be formed by irradiation with laser light.
(Dividing Step)
As shown in
First, the intermediate body 11 for wavelength conversion members, which is an intermediate body for plate-like members, is divided in the Y direction. Specifically, as shown in
Next, with the support 26 placed as described above, the intermediate body 11 for wavelength conversion members is pressed from the support film 24A side, i.e., from the first principal surface 11a side, by the blade 25a of the pressing member 25. By applying pressure to the intermediate body 11 for wavelength conversion members while being pressed between the support 26 and the pressing member 25 in this manner, a crack originating at the second breaking groove 13a is developed in the thickness direction of the intermediate body 11 for wavelength conversion members as shown in
Next, the pressing member 25 and the support 26 are moved in the X direction and the intermediate body 11 for wavelength conversion members is broken into separate parts along an adjacent second breaking groove 13a. Alternatively, instead of the pressing member 25 and the support 26, the intermediate body 11 for wavelength conversion members may be moved in the X direction. By repeating the above procedure, the intermediate body 11 for wavelength conversion members is sequentially broken into separate parts along each of a plurality of second breaking grooves 13a arranged spaced apart in the X direction and substantially in parallel with each other and extending in the Y direction. Thus, the intermediate body 11 for wavelength conversion members are broken into a plurality of strip-shaped, separate parts.
Next, as shown in
Next, the intermediate body 11 for wavelength conversion members is divided in the X direction. Specifically, as shown in
Next, the pressing member 25 and the support 26 are moved in the Y direction and the intermediate body 11 for wavelength conversion members is broken into separate parts along an adjacent first breaking groove 12a. Alternatively, instead of the pressing member 25 and the support 26, the intermediate body 11 for wavelength conversion members may be moved in the Y direction. By repeating the above procedure, the intermediate body 11 for wavelength conversion members is sequentially broken into separate parts along each of a plurality of first breaking grooves 12a arranged spaced apart in the Y direction and substantially in parallel with each other and extending in the X direction. Thus, the intermediate body 11 for wavelength conversion members is divided into a plurality of wavelength conversion members 1.
When the intermediate body 11 for wavelength conversion members is divided, each of the torn surfaces 12b forms a first side surface 1c or a second side surface 1d of a wavelength conversion member 1 shown in
Likewise, when the intermediate body 11 for wavelength conversion members is divided, each of the torn surfaces 13b shown in
The torn surface 12b formed by breakage along the first breaking groove 12a is linear when viewed from the first principal surface 11a or the second principal surface 11b of the intermediate body 11 for wavelength conversion members. Likewise, the torn surface 13b formed by breakage along the second breaking groove 13a is also linear when viewed from the first principal surface 11a or the second principal surface 11b. The line of earlier formed one of the torn surface 12b and the torn surface 13b as viewed from the first principal surface 11a or the second principal surface 11b is assumed to be a first break line. The line of later formed one of the torn surface 12b and the torn surface 13b as viewed from the first principal surface 11a or the second principal surface 11b is assumed to be a second break line. In this embodiment, the above-described line of the torn surface 13b is the first break line, and the above-described line of the torn surface 12b is the second break line.
Alternatively, it is possible to break the intermediate body 11 for wavelength conversion member into separate parts along the first breaking grooves 12a and then break it into separate parts along the second breaking grooves 13a. In this case, the above-described line of the torn surface 12b is the first break line, and the above-described line of the torn surface 13b is the second break line.
(Details of Effects of Manufacturing Method of Plate-Like Members According to the Present Invention)
This embodiment is characterized by having the following features 1) to 4): 1) The method uses an intermediate body 11 for wavelength conversion members obtained by providing first breaking grooves 12a in the first principal surface 21a of the base material 21 for wavelength conversion members and then providing second breaking grooves 13a in the second principal surface 21b of the base material 21; 2) The method includes the step of breaking the intermediate body 11 for wavelength conversion members into separate parts along either one of the first breaking grooves 12a and the second breaking grooves 13a and then breaking the intermediate body for plate-like members into separate parts along the other; 3) In breaking the intermediate body 11 for wavelength conversion members into separate parts along the first breaking grooves 12a, the intermediate body 11 for wavelength conversion members is broken into separate parts along the first breaking grooves 12a by pressing it from the second principal surface 11b side; and 4) In breaking the intermediate body 11 for wavelength conversion members into separate parts along the second breaking grooves 13a, the intermediate body 11 for wavelength conversion members is broken into separate parts along the second breaking grooves 13a by pressing it from the first principal surface 11a side. Thus, shape defects in the plate-like members can be prevented. The details of this effect will be described below by comparison between this embodiment and a comparative example.
As shown in
Unlike the above, in the dividing process in the above embodiment as shown in
When the intermediate body 101 for wavelength conversion members in the comparative example shown in
Therefore, in the comparative example, shape defects of the wavelength conversion members 111 are likely to occur.
Unlike the above, in the intermediate body 11 for wavelength conversion members according to the above embodiment of the present invention, the first principal surface 11a is provided with the first breaking grooves 12a and the second principal surface 11b is provided with the second breaking grooves 13a. Thus, in forming the intermediate body 11 for wavelength conversion members, lateral cracks that would occur due to provision of the first breaking grooves 12a and the second breaking grooves 13a in the same principal surface do not occur. Therefore, a difference in timing of crack development that may occur in the comparative example is less likely to occur, so that crack development in the direction deviating from the thickness direction of the intermediate body 11 for wavelength conversion members can be prevented. Hence, in the above embodiment of the present invention, shape defects of wavelength conversion members 1 as plate-like members can be prevented.
In addition, the first principal surface 11a provided with the first breaking grooves 12a is a principal surface to which pressure is to be applied in breaking the intermediate body 11 for wavelength conversion members into separate parts along the second breaking grooves 13a. Therefore, in breaking the intermediate body 11 into separate parts along the second breaking grooves 13a, a compressive stress, not a tensile stress, is applied around the first breaking grooves 12a. Thus, it can be certainly prevented that cracks originating at the first breaking grooves 12a occur before the step of breaking the intermediate body 11 for wavelength conversion members into separate parts along the first breaking grooves 12a. Hence, crack development in the direction deviating from the thickness direction of the intermediate body 11 for wavelength conversion members can be more certainly prevented, so that shape defects of the wavelength conversion members 1 can be further prevented.
In the comparative example, shape defects are likely to occur when the break line pitch is relatively small (for example, less than 1 mm). Therefore, the method according to the present invention is particularly effective when the break line pitch is small as in the above case.
Number | Date | Country | Kind |
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2019-192758 | Oct 2019 | JP | national |
Filing Document | Filing Date | Country | Kind |
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PCT/JP2020/038127 | 10/8/2020 | WO |