This U.S. National stage application claims priority under 35 U.S.C. ยง119(a) to Japanese Patent Application No. 2009-112893, filed in Japan on May 7, 2009, the entire contents of Japanese Patent Application No. 2009-112893 are hereby incorporated herein by reference.
The present invention relates to a method of manufacturing a pneumatic tire, and more particularly to a method of manufacturing a pneumatic tire, which enables a pneumatic tire having excellent uniformity to be manufactured efficiently, the pneumatic tire having an inner layer which is light in weight and excels in air penetration preventing performance.
Various methods of manufacturing a pneumatic tire, in which a green tire is molded on the outer peripheral surface of a metal rigid inner mold, and the molded green tire is placed inside a curing mold along with the rigid inner mold for curing, have been proposed as described, for example, in Japanese patent application Kokai publication No. 2001-88143 and Japanese patent application Kokai publication No. 2003-340824. The manufacturing method using such a rigid inner mold does not require a conventionally used bladder made of rubber, and can eliminate the process of, for example, detaching the molded green tire from a making drum. Moreover, compared with the case where a bladder is used for manufacturing, there is an advantage in that the inner peripheral surface of the cured tire can be formed into a predetermined shape with high precision.
However, because the green tire is pressed by the curing mold from only the outside during the curing, the pressing force acting on the inner peripheral surface of the green tire is small. Accordingly, for example, even when non-uniformity in the volume of the tire constituting members exists on the inner peripheral surface of the tire, it is difficult to correct the non-uniformity, and thus improvement in uniformity of the cured tire is limited.
In addition, when the inner peripheral surface of the green tire is pressed by the outer peripheral surface of the rigid inner mold, spaces between divided bodies forming the rigid inner mold leave marks on the inner peripheral surface of the cured tire, and thus there is a problem of reduced appearance quality.
Moreover, although butyl rubber is mainly used for an inner layer (innermost peripheral surface) of the green tire, an additional work of, for example, applying release agent is needed in order to easily release the inner layer from the outer peripheral surface of the rigid inner mold.
Furthermore, using an inner layer formed of butyl rubber is disadvantageous in reducing the tire weight because an inner layer formed of butyl rubber needs a certain thickness to secure sufficient air penetration preventing performance. For this reason, an inner layer which is light in weight and excels in air penetration preventing performance has been demanded.
An object of the present invention is to provide a method of manufacturing a pneumatic tire, which enables a pneumatic tire having excellent uniformity to be manufactured efficiently, the pneumatic tire having an inner layer which is light in weight and excels in air penetration preventing performance.
A method of manufacturing a pneumatic tire according to the present invention to achieve the above-described object is characterized in that a primary molded body is formed by fitting bead rings on opposite ends, in a width direction, of a cylindrically-shaped body in which at least a carcass material is mounted on an outer peripheral side of a film formed of a thermoplastic resin or a thermoplastic elastomer composition obtained by blending a thermoplastic resin with an elastomer; the primary molded body is set to be sucked and held to an inner peripheral surface of a transfer and holding mold; a cylindrically-shaped rigid inner mold including multiple divided bodies is inserted inside the primary molded body; thereafter suction by the transfer and holding mold is stopped, and the primary molded body is transferred to an outer peripheral surface of the rigid inner mold; next, opposite ends of the carcass material in a width direction thereof are turned up on the rigid inner mold, while other tire constituting members are stacked on an outer peripheral surface of the primary molded body so that a green tire is molded; the green tire is disposed, together with the rigid inner mold, inside a curing mold installed in a curing apparatus; and the rigid inner mold and the curing mold are heated to a predetermined temperature and the film is pressurized from an inner peripheral side to be inflated, so that the green tire is cured and the film is brought into close contact with and bonded to an inner peripheral surface of the tire; next the cured tire is taken out of the curing apparatus; and the rigid inner mold is detached from the cured tire.
Here, when the primary molded body is sucked and held to the inner peripheral surface of the transfer and holding mold, it is also possible that the transfer and holding mold is disposed at an outer peripheral side of the primary molded body, and the primary molded body is pressurized from an inner peripheral side of the primary molded body, while the primary molded body is sucked by the transfer and holding mold from an outer peripheral side of the primary molded body. When the green tire is cured, the film is pressurized to be inflated from an inner peripheral side with a pressure of 0.01 MPa to 3.0 MPa. Moreover, for example, air is sucked from an inside of the curing mold to an outside, while the green tire disposed inside the curing mold is cured.
According to a method of manufacturing a pneumatic tire of the present invention, a primary molded body is formed by fitting bead rings on opposite ends, in the width direction, of a cylindrically-shaped body in which at least a carcass material is mounted on the outer peripheral side of a film formed of a thermoplastic resin or a thermoplastic elastomer composition; the primary molded body is set to be sucked and held to the inner peripheral surface of a transfer and holding mold; a cylindrically-shaped rigid inner mold including multiple divided bodies is inserted inside the primary molded body; thereafter, suction by the transfer and holding mold is stopped; whereby the primary molded body can be smoothly transferred to the outer peripheral surface of the rigid inner mold without damaging the film on the inner peripheral surface.
Next, the opposite ends of the above-mentioned carcass material in the width direction thereof are turned up on the rigid inner mold, while other tire constituting members are stacked on the outer peripheral surface of the primary molded body so that the green tire is molded; the green tire is disposed, together with the rigid inner mold, inside the curing mold installed in the curing apparatus; the rigid inner mold and the curing mold are heated to a predetermined temperature and the film is pressurized from an inner peripheral side to be inflated, so that the green tire is cured. Accordingly, unvulcanized rubber of the tire constituting members is pressed against the inner peripheral surface of the curing mold and flows in the circumferential direction, whereby even when non-uniformity in the volume of the tire constituting members exists, the non-uniformity can be corrected. Hence, uniformity of the tires to be manufactured can be improved.
The film is made to serve as a conventional bladder as described above, and moreover, at the time of curing the green tire, the film is brought into close contact with and bonded to the inner peripheral surface of the tire to form an inner layer. This film is formed with a thermoplastic resin or a thermoplastic elastomer composition. For this reason, compared with the conventional inner layer which is formed of butyl rubber, the film is light in weight and has good gas barrier property, and thus manufactured tires are light in weight and have excellent air penetration preventing performance.
In addition, the green tire is disposed inside the curing mold together with the rigid inner mold, whereby a conventional work of detaching the green tire from the making drum is not required, and thus the green tire can be easily disposed at a predetermined position inside the curing mold. Further, the film which serves as the inner layer also functions as a release material between the inner peripheral surface of the tire and the outer peripheral surface of the rigid inner mold, whereby an additional work of, for example, applying release agent is not required. In this manner, the number of work processes can be reduced, and thus the productivity can be improved.
Hereinafter, a method of manufacturing a pneumatic tire according to the present invention is described based on the embodiments shown in the drawings. The same reference numerals are used for the same members before and after curing.
A belt layer 27 is provided over the entire periphery in the tire circumferential direction on the outer peripheral side of the carcass material 24 of the tread portion 28. A reinforcing cord forming the belt layer 27 is disposed so as to be inclined to the tire circumferential direction, and stacked upper and lower belt layers 27 are disposed so that reinforcing cords thereof cross each other. A pneumatic tire 21 manufactured by the present invention is not limited to the structure shown in
The pneumatic tire 21 has a major structural feature in that the inner layer is formed of the film 22 in place of a conventional butyl rubber. The thickness of the film 22 is, for example, 0.005 mm to 0.2 mm.
The film 22 used in the present invention includes a thermoplastic resin or a thermoplastic elastomer composition obtained by blending a thermoplastic resin with an elastomer.
Examples of the thermoplastic resin include: polyamide-based resins [for example, nylon 6 (N6), nylon 66 (N66), nylon 46 (N46), nylon 11 (N11), nylon 12 (N12), nylon 610 (N610), nylon 612 (N612), nylon 6/66 copolymers (N6/66), nylon 6/66/610 copolymers (N6/66/610), nylon MXD6, nylon 6T, nylon 6/6T copolymers, nylon 66/PP copolymers, and nylon 66/PPS copolymers]; polyester-based resins [for example, aromatic polyesters such as polybutylene terephthalate (PBT), polyethylene terephthalate (PET), polyethylene isophthalate (PEI), polybutylene terephthalate/tetramethylene glycol copolymer, PET/PEI copolymers, polyarylate (PAR), polybutylene naphthalate (PBN), liquid crystal polyester, and polyoxyalkylene diimide diacid/polybutylene terephthalate copolymers]; polynitrile-based resins [for example, polyacrylonitrile (PAN), polymethacrylonitrile, acrylonitrile/styrene copolymers (AS), methacrylonitrile/styrene copolymers, and methacrylonitrile/styrene/butadiene copolymer]; poly (meth) acrylate-based resin, [for example, poly methyl methacrylate (PMMA), polymethylmethacrylate, ethylene ethyl acrylate copolymer (EEA), ethylene acrylic acid copolymer (EAA), and ethylene methyl acrylate resin (EMA)]; polyvinyl-based resins [for example, vinyl acetate (EVA), polyvinyl alcohol (PVA), vinyl alcohol/ethylene copolymers (EVOH), polyvinylidene chloride (PVDC), polyvinyl chloride (PVC), vinyl chloride/vinylidene chloride copolymers, and vinylidene chloride/methyl acrylate copolymers]; cellulose-based resins [for example, cellulose acetate, and cellulose acetate butyrate]; fluororesins [for example, polyvinylidene fluoride (PVDF), polyvinyl fluoride (PVF), polychlorotrifluoroethylene (PCTFE), and tetrafluoroethylene/ethylene copolymers (ETFE)]; imide-based resins [for example, aromatic polyimide (PI)].
Examples of the elastomer include: diene rubbers and their hydrogenated products [for example, NR, IR, epoxidized natural rubbers, SBR, BR (high-cis BR and low-cis BR), NBR, hydrogenated NBR, and hydrogenated SBR]; olefin-based rubbers [for example, ethylene propylene rubbers (EPDM and EPM), and maleic acid-modified ethylene propylene rubber (M-EPM); butyl rubber (IIR); copolymers of isoprene and aromatic vinyl or diene monomer; acrylic rubber (ACM); ionomers; halogen-containing rubbers [for example, Br-IIR, CI-IIR, brominated isobutylene para-methylstyrene copolymers (Br-IPMS), chloroprene rubber (CR), hydrin rubber (CHC and CHR), chlorosulfonated polyethylene (CSM), chlorinated polyethylene (CM), and maleic acid-modified chlorinated polyethylene (M-CM)]; silicone rubbers [for example, methyl vinyl silicone rubber, dimethyl silicone rubber, and methylphenylvinyl silicone rubber]; sulfur-containing rubbers [for example, polysulfide rubber]; fluororubbers [for example, vinylidene fluoride-based rubbers, fluorine-containing vinyl ether-based rubbers, tetrafluoroethylene propylene-based rubbers, fluorine-containing silicone-based rubbers, and fluorine-containing phosphazene-based rubbers]; thermoplastic elastomers [for example, styrene-based elastomers, olefin-based elastomers, polyester-based elastomers, urethane-based elastomers, and polyamide-based elastomers].
In the thermoplastic elastomer composition used in the present invention, the weight ratio between a thermoplastic resin component (A) and an elastomer component (B) is determined as appropriate by the balance of the thickness and the flexibility of the film. For example, the weight ratio of the thermoplastic resin component (A) to the total weight of the thermoplastic resin component (A) and the elastomer component (B) is preferably 10% to 90%, and more preferably 20% to 85%.
A compounding agent and other polymers such as a compatibilizer can be mixed to the thermoplastic elastomer composition used in the present invention as a third component in addition to the above-mentioned essential components (A) and (B). The purposes of mixing other polymers include: improvement of the compatibility between the thermoplastic resin component and the elastomer component, improvement of processability and formability of material into a film, improvement of heat resistance, and cost reduction. Examples of the materials used for these purposes include polyethylene, polypropylene, polystyrene, ABS, SBS, and polycarbonate.
The film 22 formed of the above-mentioned thermoplastic resin or the thermoplastic elastomer composition has excellent gas barrier property because it excels in the surface orientation of high-polymer chains. As shown above, in the pneumatic tire 21 manufactured by the present invention, the film 22 which has better gas barrier property than butyl rubber serves as the inner layer. Accordingly, compared with the conventional pneumatic tire, excellent air penetration preventing performance can be obtained.
Furthermore, the thickness of the inner layer formed of the conventional butyl rubber is, for example, 0.5 mm to 5.0 mm, but the thickness of the film 22 is 0.005 mm to 0.2 mm. Thus, the weight of the inner layer can be significantly reduced, and this reduction greatly contributes to reduction of the weight of the pneumatic tire 21.
The process of manufacturing the pneumatic tire 21 is described below.
First, a primary molded body G1 is molded using a primary making drum 1 illustrated in
Fixing rings 2 are fitted on opposite ends, in the width direction, of the primary making drum 1, and each segment 1a is moved in a radially-outward direction to make the primary making drum 1 into a cylindrical shape. The film 22, the tie rubber 23, and the carcass material 24 are placed so as to be stacked in this order on the outer peripheral surface of the primary making drum 1 which is made into a cylindrical shape, whereby a cylindrically-shaped body is formed. The carcass material 24 projects out from the film 22 and the tie rubber 23 at both sides in the width direction.
In the case where the film 22 preformed in a tubular shape is used, the tubular film 22 is fitted on the primary making drum 1 to form a cylindrically-shaped body. In the case where strip-shaped film 22 is used, the strip-shaped film 22 is wrapped around the outer peripheral surface of the primary making drum 1 to form a cylindrically-shaped body. In the latter case, the strip-shaped film 22 and the tie rubber 23, or the strip-shaped film 22, the tie rubber 23, and the carcass material 24 are pre-stacked to form a stacked body, then the stacked body can be wrapped around the outer peripheral surface of the primary making drum 1 to form a cylindrically-shaped body.
Next, the bead rings 25 are disposed on the opposite ends of the carcass material 24 in the width direction thereof on the outer peripheral side. Then, the carcass fixing rings 3 are disposed on the opposite ends of the carcass material 24 in the width direction thereof on the outer peripheral side. Thus, the opposite ends of the carcass material 24 in the width direction thereof are fixed by being sandwiched between the fixing rings 2 and the carcass fixing rings 3. The bead rings 25 are fixed on the inner sides of the carcass fixing rings 3. In this manner, the primary molded body G1 is molded by fitting the bead rings 25 on the opposite ends, in the width direction, of a cylindrically-shaped body in which at least the carcass material 24 is mounted on the outer peripheral side of the film 22.
Next, both carcass fixing rings 3 are coupled with each other via a space adjusting plate 4 as illustrated in
Next, the segments 1a, 1b are moved in a radially-inward direction, and the primary making drum 1 is removed from the cylindrically-shaped primary molded body G1. Accordingly, the primary molded body G1 is in a state to be held by the fixing rings 2, the carcass fixing rings 3, and the space adjusting plate 4.
Next, a cylindrically-shaped inflation mold 5 is inserted inside the primary molded body G1 as illustrated in
The side plates 6 are moved in the width direction by cylinders 6a provided in the core portion 5a. Expandable and contractible sealing members 7 are provided in the outer peripheral edge portions of the side plates 6.
Each pressing plate 8 is configured to be moved in the radial direction by a cylinder 8a provided in the core portion 5a. The outer peripheral surface of the pressing plate 8 has approximately the same shape as the profile of the inner peripheral surface of the tire to be manufactured.
After the inflation mold 5 is inserted inside the primary molded body G1, the sealing members 7 are expanded so that the peripheral portions (the fixing rings 2 and the carcass fixing rings 3) of the bead rings 25 are securely fixed by the side plates 6. Subsequently, the space adjusting plate 4 is detached from the carcass fixing rings 3.
Next, as illustrated in
Next, as illustrated in
Next, the air a is further injected from the inner peripheral side of the primary molded body G1 to pressurize the primary molded body G1, while air A is sucked through the suction holes 10 of the transfer and holding mold 9 with the divided molds 9a assembled, so that the primary molded body G1 is sucked from the outer peripheral side. Thereby, the primary molded body G1 is in a state to be sucked and held to the inner peripheral surface of the transfer and holding mold 9. Subsequently, the rods of cylinders 8a are contracted to retreat the pressing plate 8 and the sealing members 7 are contracted, whereby the inflation mold 5 is removed from the primary molded body G1. Suction of the primary molded body G1 by the transfer and holding mold is continued until the primary molded body G1 is transferred to a rigid inner mold 11.
Next, as illustrated in
Subsequently, suction by the transfer and holding mold 9 is stopped, and the primary molded body G1 is transferred to the outer peripheral surface of the rigid inner mold 11. After the primary molded body G1 is transferred, the transfer and holding mold 9 is separated into divided molds 9a, and detached from the primary molded body G1.
In this way, according to the present invention, the primary molded body G1 is set to be sucked and held to the inner peripheral surface of the transfer and holding mold 9, then is transferred to the outer peripheral surface of the rigid inner mold 11, and thus transfer operation can be performed smoothly without damaging the film 22 which serves as the inner layer.
The rigid inner mold 11 is in a cylindrical shape as illustrated in
These divided bodies 12 are fixed to peripheral edge portions of opposed disc-shaped supporting plates 15a, 15b via the rotation mechanisms 13, and are formed in a cylindrical shape. That is to say, out of the divided bodies 12 divided in half in the width direction of the cylindrically-shaped peripheral surface, those on one side in the width direction are disposed in an annular shape along the peripheral edge portion of the supporting plate 15a on one side out of the opposed supporting plates 15a, 15b, and out of the divided bodies 12 divided in half in the width direction of the cylindrically-shaped peripheral surface, those on the other side in the width direction are disposed in an annular shape along the peripheral edge portion of the supporting plate 15b on the other side.
A central shaft 14 is fixed at the circle center position of the opposed supporting plates 15a, 15b to pass therethrough. The central shaft 14 and a pair of the supporting plates 15a, 15b are fixed to each other via a supporting rib 16 fixed on the outer peripheral surface of the central shaft 14. As described later, the rigid inner mold 11 including the multiple divided bodies 12 formed in a cylindrical shape is moved so that each divided body 12 is rotated in a diameter expanding or reducing direction around the rotation mechanism 13 as the rotation center.
Next, as illustrated in
The opposite ends of the carcass material 24 in the width direction thereof are turned up on the rigid inner mold 11, while other tire constituting members such as the rubber member of the sidewall portion 26, the belt layers 27, the rubber member of the tread portion 28 are stacked on the outer peripheral surface of the primary molded body G1 so that the green tire G is molded as illustrated in
Next, as illustrated in
The lower side plate 18b is fixed in a bottom housing 17b in which each sector 18a is placed. A back segment 19 having an inclined surface is mounted on the rear surface of the sector 18a. A guide member 20 having an inclined surface and the upper side plate 18b are fixed in a top housing 17a.
After the lower end portion of the central shaft 14 of the rigid inner mold 11 holding the green tire G is inserted into the central hole of the bottom housing 17b, the top housing 17a is moved downward. Along with this downward movement, the guide member 20 moves downward, and the inclined surface of the guide member 20 comes in contact with the inclined surface of the back segment 19. As the guide member 20 moves downward, the sector 18a along with the back segment 19 gradually moves toward the central shaft 14. That is to say, the sectors 18a in a state of expanded diameter are moved in a radially-inward direction and are assembled to form an annular shape. Then the upper side plate 18b, which is moved downward, is disposed at the upper inner peripheral edge portions of the sectors 18a assembled in an annular shape. The upper end portion of the central shaft 14 is inserted into the central hole of the top housing 17a.
In this manner, the molded green tire G is disposed inside the curing mold together with the rigid inner mold 11. Thus, a conventional work of detaching the green tire G from the making drum is not required, and this work process can be omitted. In addition, the central holes of the top housing 17a and the bottom housing 17b are formed with a predetermined precision, whereby positioning can be made by only inserting the central shaft 14 of the rigid inner mold 11 into the central holes, and the green tire is easily disposed at a predetermined position inside the curing mold with high precision. Accordingly, the productivity improves and the pneumatic tire 21 can be manufactured efficiently.
Next, as illustrated in
As illustrated in
Note that the pressurizing by supplying the air a from the inner peripheral side of the film 22 may be performed after the sectors 18a and the upper and lower side plates 18b, 18b are assembled. The pressurizing may be performed to some extent before the assembly, or may be performed during the assembly.
Along with the curing of the green tire G, the film 22 which serves as a conventional bladder in this manner is brought into close contact with and bonded to the inner peripheral surface of the tire (rubber members disposed on the outer peripheral side of the film 22), so that the pneumatic tire 21 having the film 22 as the inner layer is manufactured.
In order to increase the bonding power between the film 22 and the inner peripheral surface of the tire, an adhesive layer may be previously provided on the outer peripheral surface of the film 22. The tie rubber 23 is disposed to cover the entire outer peripheral surface of the film 22, but the tie rubber 23 may be disposed to cover apart of the outer peripheral surface of the film 22. If a certain bonding strength between the film 22 and the members on the outer peripheral side of the film 22 can be secured, the tie rubber 23 may be omitted.
In the present invention, a conventional bladder is not used, and thus maintenance of the bladder is not needed, which is advantageous to the improvement of productivity.
The rigid inner mold 11 and the curing mold can be heated by various heat sources. For example, an electric heating body embedded in the rigid inner mold 11 and the curing mold may be used. Heating by an electric heating body enables a precise temperature control. In addition, a cooling device may be provided to the rigid inner mold 11.
In this curing process, the outer peripheral surface of the green tire G is molded into a predetermined shape by the sector 18a, whereas the inner peripheral surface is brought into contact with and molded by the inflated film 22. Accordingly, unlike the manufacturing method which uses a conventional bladder made of rubber, or the manufacturing method which presses the green tire on the outer peripheral surface of the rigid inner mold, no undesired marks are left on the inner peripheral surface of the cured pneumatic tire, whereby a smooth surface is created, and accordingly appearance quality is improved.
It is also possible that the air A is forcibly sucked from the inside of the curing mold to the outside so that the green tire G is cured in a negative pressure state. For example, vacuum is drawn by a vacuum pump through a communication hole provided in the outer peripheral surface of the curing mold. In this manner, the air between the stacked tire constituting members, or the air in the tire constituting members (rubber members) can be removed, and thus a problem due to trapped air in the manufactured pneumatic tire 21 can be prevented, and thereby its quality can be improved.
Next, the cured pneumatic tire 21, together with the rigid inner mold 11, is taken out of the curing apparatus 17, and then the rigid inner mold 11 is detached from the cured pneumatic tire 21. In order to detach the rigid inner mold 11, first, as illustrated in
Next, as illustrated in
The film 22 can be easily separated from the divided body 12. For this reason, compared with a pneumatic tire whose inner layer is formed of butyl rubber, the rigid inner mold 11 can be detached smoothly. Due to excellent release characteristics of the film 22, an additional work of, for example, applying release agent between the inner peripheral surface of the tire and the rigid inner mold 11 (the divided bodies 12) is not required, which is further advantageous to the improvement of productivity.
In order to assemble the rigid inner mold 11 in a cylindrical shape, the process reverse to the process of dividing the rigid inner mold 11 illustrated in
As described above, in the present invention, the film 22 formed of a thermoplastic resin or a thermoplastic elastomer composition is effectively used, and is made to serve as a release material among the bladder, the inner layer of the tire, and the rigid inner mold 11 (divided bodies 12). Accordingly, the pneumatic tire 21 with excellent uniformity, having an inner layer which is light in weight and excels in air penetration preventing performance can be efficiently manufactured.
In the above-mentioned embodiments, the cases where radial tires are manufactured are taken as examples; however, the present invention can be even applied to cases of manufacturing bias tires.
Number | Date | Country | Kind |
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2009-112893 | May 2009 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2009/061054 | 6/17/2009 | WO | 00 | 10/28/2011 |
Publishing Document | Publishing Date | Country | Kind |
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WO2010/128566 | 11/11/2010 | WO | A |
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Number | Date | Country |
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922396 | Aug 1959 | GB |
2001-088143 | Apr 2001 | JP |
2003-340824 | Dec 2003 | JP |
2235641 | Jul 2003 | RU |
WO-2004048075 | Jun 2004 | WO |
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WO-2009081656 | Jul 2009 | WO |
Entry |
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Machine generated English language translation of RU 2235641 (original document dated Jul. 2003). |
International Search Report of corresponding International Application No. PCT/JP2009/061054, dated on Aug. 25, 2009. |
Number | Date | Country | |
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20120049398 A1 | Mar 2012 | US |