Patent Application
20070059624
This application claims the benefit of Korean Patent Application No. 10-2005-0084419, filed on Sep. 10, 2005, in the Korean Intellectual Property Office, the disclosure of which is hereby incorporated by reference in its entirety.
1. Field of the Invention
The present invention relates to a toner and to a method of preparing the toner. More particularly, the invention relates to a method of preparing a toner using a macromonomer, a reactive emulsifying agent, and a multifunctional polyester in an emulsion polymerization process and the resulting toner.
2. Description of the Related Art
In an electrophotographic process or an electrostatic recording process, a developer used to form an electrostatic image or an electrostatic latent image may be a two-component developer formed of a toner and carrier particles or a one-component developer formed of a toner only, without carrier particles. The one-component developer may be a magnetic one-component developer having magnetic properties or a nonmagnetic one-component developer not having magnetic properties. Plasticizers such as colloidal silica are often added independently into the nonmagnetic one-component developer to increase the flowability of the toner. Generally, coloring particles obtained by dispersing a colorant, such as carbon black, or other additives in a binding resin are used in the toner.
Methods of preparing toners include pulverization or polymerization. In pulverization, the toner is obtained by melt mixing synthetic resins with colorants and, if needed, other additives, pulverizing the mixture and classifying the particles until a desired size of particles is obtained. In polymerization, a polymerizable monomer composition is manufactured by uniformly dissolving or dispersing a polymerizable monomer, a colorant, a polymerization initiator and, if needed, various additives such as a cross-linking agent and an antistatic agent. Next, the polymerizable monomer composition is dispersed in an aqueous dispersive medium which includes a dispersion stabilizer using an agitator to form minute liquid drop particles. Subsequently, the temperature is increased and suspension polymerization is performed to obtain a polymerized toner having coloring polymer particles of a desired size.
In an image forming apparatus such as an electrophotographic apparatus or an electrostatic recording apparatus, an electrostatic latent image is formed through light-exposure on the surface of a photoreceptor which is uniformly charged. A toner is attached to the electrostatic latent image, and a resulting toner image is transferred to a transfer medium such as a paper through several processes such as heating, pressing, solvent steaming, etc. In most fixing processes, the transfer medium with the toner image passes between fixing rollers and pressing rollers, and the toner image is fused to the transfer medium by heating and pressing.
Improvements in preciseness and minuteness are required for images formed by an image forming apparatus such as an electrophotocopier. Conventionally, a toner used in an image forming apparatus is usually obtained using pulverization. When using pulverization, it is likely to form coloring particles with a wide range of particle sizes. Hence, to obtain satisfactory developer properties, there is a need to classify the coloring particles obtained through pulverization according to size to narrow the particle size distribution. However, it is difficult to precisely control the particle size distribution using a conventional mixing/pulverizing process in the manufacture of toner particles suitable for an electrophotographic process or electrostatic recording process. Also when preparing a minute particle toner, a toner preparation yield is low due to the classification process. In addition, there is a limit to the change/adjustment of the toner design for obtaining desirable charging and fixing properties. Accordingly, polymerized toners, in which the size of particles is easy to control and which do not need to go through a complex manufacturing process such as classification, have recently become of interest.
When a toner is prepared using polymerization, the desired size distribution of particles is obtained without performing pulverization or classification.
U.S. Pat. No. 6,033,822 to Hasegawa et al. discloses a polymerized toner including a core formed of colored polymer particles and a shell covering the core in molecules. The polymerized toner is prepared by suspension polymerization. However, it is still difficult to adjust the shape of the toner and the sizes of the particles. Also, the resulting toner has a wide particle size distribution.
U.S. Pat. No. 6,258,911 to Michael et al. discloses a bi-functional polymer having a narrow polydispersity and an emulsion-condensation polymerization process for manufacturing a polymer having covalently bonded free radicals on each of its ends. However, even when this method is used, a surfactant can cause an adverse effect, and it is difficult to control the size of latex.
Accordingly, there is a continuing need in the industry for improved methods of producing toners
The present invention provides a method of preparing a toner in which the size of a toner particle is controlled freely and where a narrow particle size distribution is obtained.
The present invention also provides a toner having a small particle size and excellent storage property and durability, in which the particle size of the toner can be easily controlled and produced in a high yield.
The present invention also provides an image forming method in which a high quality image can be fixed at a low temperature by using a toner having superior properties in particle size control, storage property, and durability.
The present invention also provides an image forming apparatus in which a high quality image can be fixed at a low temperature by using a toner having superior properties in particle size control, storage property, and durability.
According to an aspect of the present invention, a method is provided for preparing a toner, including: preparing a colorant dispersion by mixing a reactive emulsifying agent and a colorant; preparing a toner composition by mixing a macromonomer having hydrophilic group, hydrophobic group and at least one reactive functional group, at least one polymerizable monomer, a multifunctional polyester, and the colorant dispersion; emulsion polymerizing the toner composition in a medium; and separating and drying the polymerized toner.
According to another aspect of the present invention, a toner is provided including a copolymer of a macromonomer and a polymerizable monomer obtained by emulsion-polymerizing a toner composition in a medium, the toner composition including the macromonomer having a hydrophilic group, a hydrophobic group and at least one reactive functional group, at least one polymerizable monomer, a multifunctional polyester, and a colorant dispersion, wherein the colorant dispersion is prepared by mixing a reactive emulsifying agent and a colorant.
According to another aspect of the present invention, an image forming method is provided including the steps of: forming a visible image by disposing a toner on an photoreceptor surface where an electrostatic latent image is formed; and transferring the visible image to a transfer medium, wherein the toner includes a copolymer of a macromonomer and a polymerizable monomer obtained by emulsion-polymerizing a toner composition in a medium, the toner composition including the macromonomer having a hydrophilic group, a hydrophobic group and at least one reactive functional group, at least one polymerizable monomer, a multifunctional polyester, and a colorant dispersion, wherein the colorant dispersion is prepared by mixing a reactive emulsifying agent and a colorant.
According to another aspect of the present invention, an image forming apparatus is provided including: an organic photoreceptor; a unit electrifying a surface of the organic photoreceptor; a unit for containing a toner including a copolymer of a macromonomer and a polymerizable monomer obtained by emulsion-polymerizing a toner composition in a medium. The toner composition includes the macromonomer having a hydrophilic group, a hydrophobic group and at least one reactive functional group, at least one polymerizable monomer, a multifunctional polyester, and a colorant dispersion. The colorant dispersion is prepared by mixing a reactive emulsifying agent and a colorant. The apparatus also includes a unit for supplying the toner to the surface of the organic photoreceptor to develop an electrostatic latent image on the surface of the organic photoreceptor into a toner image; and a unit for transferring the toner image on the surface of the organic photoreceptor to a transfer medium.
According to the present invention, a toner is prepared having a small particle size and excellent storage property and durability. The particle size of the toner can be easily controlled. The toner is environment-friendly and can be produced through simplified processes. Therefore, the production cost is low.
These and other aspects of the invention will become apparent from the following detailed description of the invention in conjunction with the annexed drawings which disclose various embodiments of the invention.
The above and other features and advantages of the present invention will become more apparent by describing in detail exemplary embodiments thereof with reference to the attached drawing in which:
According to the present invention, a colorant dispersion is prepared by mixing a reactive emulsifying agent and a colorant. A toner composition is prepared by mixing a macromonomer, at least one polymerizable monomer, and a multifunctional polyester with the colorant dispersion, and then the emulsion polymerizing the toner composition.
The multifunctional polyester includes polyester moiety and at least two reactive groups selected from the group consisting of a vinyl group, an acrylate group, and a methacrylate group. In detail, the multifunctional polyester, although not limited to the following example, may be formed of at least one material selected from the group consisting of multifunctional polyester methacrylate, multifunctional polyester acrylate, dendritic polyester methacrylate, dendritic polyester acrylate, carboxy polyester methacrylate, and carboxy polyester acrylate.
The amount of the multifunctional polyester may be in the range of 0.1 to 5 parts by weight based on 100 parts by weight of the macromononer. When the amount of the multifunctional polyester is less than 0.1 part by weight, the durability and anti-offset of the toner do not improve. When it exceeds 5 parts by weight, the fixation of toner particles decreases due to excessively increased cross linkage density.
The weight average molecular weight of the multifunctional polyester may be in the range of 300 to 8,000, and preferably, in the range of 500 to 5,000. When the weight average molecular weight is less than 300, the multifunctional polyester is not effective and when it exceeds 8,000, the reactivity thereof decreases.
The multifunctional polyester participates in the reaction as a comonomer of the copolymer and may form a hybrid resin. For high resolution printing, polyester, etc. used as a binder resin for pulverized toner may be modified and used.
The method of preparing the toner according to the present invention will now be explained in detail. The reaction emulsifying agent and the colorant are put into ultra-high pure water and dispersed by a dispersing apparatus. Examples of the dispersing apparatus include an ultrasonic homogenizer, a bead milling machine, and a microfluidizer. The dispersed aqueous colorant is injected and stirred in the reactor with an appropriate amount of water and purged with nitrogen gas. To control the degree of ionization of the reactive medium, an electrolyte such as NaCl or an ionic salt may be added. When the temperature inside the reactor reaches an appropriate value, an organic solvent, i.e., a mixture of at least one polymerizable monomer, a macromonomer, and a multifunctional polyester, is injected in the reactor semicontinuously. During this time, a wax and a chain transfer agent may be injected together. The amount and the time of injection of each material are controlled according to the reaction time of the monomer and the macromonomer. The added monomer diffuses from the center of the colorant dispersed in the reactive emulsifying agent, and the dispersed particles of colorant swell and form droplets of monomer including the colorant. When the dispersed particles of the colorant swell appropriately, a water soluble free radical initiator may be injected to initiate the free radical reaction.
The reactive emulsifying agent includes polyoxyethylene alkylphenyl ether moiety and may be at least one material selected from the group consisting of an anionic reactive emulsifying agent having a vinyl group, an acrylate group and a methacrylate group. The reactive emulsifying agent contains a reactive group such as a radical-polymerizable unsaturated bond and a hydrophilic group such as a polyethylene oxide group, hydroxyl group, carboxyl group or sulfonic acid group and a hydrophobic group such as an alkyl or phenyl group. An example of a suitable reactive emulsifying agent is HS-10 by Dai-Ichi Kogyo Seiyaku Co. Ltd which has a propenyl group on a phenyl group and a polyoxyethylene nonyl phenyl ether sulfate ester group. Other reactive emulsifiers include an allyl ether group, a polyethylene oxide group and a nonylphenyl group; an allyl ether group, a polyethylene oxide group, a sulfuric acid group and a nonylphenyl group; and a propenyl group on a phenyl group and a polyoxyethylene nonyl phenyl ether group. Other suitable reactive emulsifying agents as known in the art can also be used. Another example of a suitable reactive emulsifying agent is BC-10 by Dai-Ichi Kogyo Seiyaku Co. Ltd. which is a polyoxyethylene alkylphenyl ether ammonium sulfate.
The weight average molecular weight of the reactive emulsifying agent may be in the range of 100 to 1,000. When the weight average molecular weight of the reactive emulsifying agent is less than 100, the function of the emulsifying agent is reduced and when it exceeds 1,000, the reactivity thereof is low.
The amount of the reactive emulsifying agent may be in the range of 5 to 50 parts by weight, and preferably, in the range of 10 to 20 parts by weight based on 100 parts by weight of the colorant. When the amount of the reactive emulsifying agent is less than 5 parts by weight, the dispersibilities of the colorant and latex are reduced and particle configuration deteriorates and when it exceeds 50 parts by weight, the reactivity of the emulsifying agent to the monomer is low.
The present invention does not use conventional emulsifying agents during the dispersion of the colorant, but uses a reactive emulsifying agent. The reactive emulsifying agents anchor to latex resins during the reaction of particle formation, so the adverse effects on toner properties due to emulsifying agent can be minimized since there is no migration of remaining emulsifying agent.
Since the present invention does not use a conventional non-reactive emulsifying agent used for emulsion polymerization, a cleaning process during separation and filtration processes of the toner particles prepared may be minimized or eliminated. Thus, the preparation process is simplified, production cost is reduced, and generation of polluted water and waste water is decreased, which is very advantageous environmentally. In addition, characteristics such as low friction electric charge and low toner storage stability can be improved and image deterioration due to the emulsifying agents can be prevented.
The present invention stabilizes the particles during the reaction or after the reaction by using a macromonomer. The macromonomer according to the present invention is an amphipathic material having both a hydrophilic group and a hydrophobic group, and a polymer or an oligomer having at least one reactive functional group. The hydrophilic group reacts with a medium which improves the water dispersion of the monomer, and the hydrophobic group promotes the emulsion polymerization by lying on the surface of toner particles. The macromonomer can form a copolymer by binding with a polymerizable monomer in the toner composition in various ways, such as grafting, branching or cross-linking. By using the macromonomer according to an embodiment of the present invention, the durability and anti-offset of toner particles can be improved. Also, the macromonomer can act as a stabilizer by forming stabilized micelles during the emulsion polymerization.
The weight average molecular weight of the macromonomer is in the range of 100 to 100,000, and preferably in the range of 1,000 to 10,000. When the weight average molecular weight of the macromonomer is less than 100, the properties of the toner may not be improved or the macromonomer may not operate properly as a stabilizer. Also, when the weight average molecular weight of the macromonomer is greater than 100,000, a reaction conversion rate may be low.
The macromonomer according to the present invention may be, for example, a material selected from the group consisting of polyethylene glycol (PEG)-methacrylate, PEG-ethyl ether methacrylate, PEG-dimetacrylate, PEG-modified urethane, PEG-modified polyester, polyacrylamide (PAM), PEG-hydroxyethyl methacrylate, hexafunctional polyester acrylate, dendritic polyester acrylate, carboxy polyester acrylate, fatty acid modified epoxy acrylate and polyester methacrylate, but is not limited thereto.
The amount of the macromonomer used in the present invention may be in the range of 1 to 50 parts by weight based on 100 parts by weight of the toner composition. When the amount of the macromonomer is less than 1 part by weight based on 100 parts by weight of the toner composition, the stability of the particle distribution is low, and when the amount of the macromonomer exceeds 50 parts by weight based on 100 parts by weight of the toner composition, the property of the toner deteriorates.
The polymerizable monomer used in the present invention is a material having at least one unsaturated group, and may be a monomer selected from the group consisting of a vinyl monomer, a polar monomer having a carboxyl group, a monomer having an unsaturated polyester group and a monomer having a fatty acid group.
The polymerizable monomer, may be formed of at least one material selected from the group consisting of styrene-based monomer such as styrene, vinyltoluene, and α-methylstyrene; acrylic acid and methacrylic acid; (meth)acrylic acid derivative such as methylacrylate, ethylacrylate, propylacrylate, butylacrylate, 2-ethylhexylacrylate, dimethylaminoethylacrylate, methylmethacrylate, ethylmethacrylate, propylmethacrylate, butylmethacrylate, 2-ethylhexylmethacrylate, dimethylaminoethylmethacrylate; (meth)acrylic acid derivative of amide selected from the group consisting of acrylonitrile, methacrylonitrile, acrylamide and methacrylamide; ethylenically unsaturated monoolefin such as ethylene, propylene and butylene; halogenated vinyl such as vinyl chloride, vinylidene chloride and vinyl fluoride; vinyl ester such as vinyl acetate and vinyl propionate; vinyl ether such as vinyl methyl ether and vinyl ethyl ether; vinyl ketone such as vinyl methyl ketone and methyl isopropenyl ketone; vinyl compound having nitrogen such as 2-vinyl pyridine, 4-vinyl pyridine and N-vinyl pyrrolidone, but is not limited thereto.
The amount of the polymerizable monomer used in the present invention is in the range of 3 to 50 parts by weight based on 100 parts by weight of the toner composition. When the amount of the polymerizable monomer is less than 3 parts by weight based on 100 parts by weight of the toner composition, the yield is low. When the amount of the polymerizable monomer exceeds 50 parts by weight based on 100 parts by weight of the toner composition, the stability of the toner composition is low.
The medium used in the present invention may be an aqueous solution or a mixture of water and an organic solvent.
An amphipathic macromonomer can act not only as a comonomer but also as a stabilizer. The reaction between initial radicals and monomers forms oligomer radicals, and provides an in situ stabilizing effect. The initiator decomposed by heat forms a radical, reacts with a monomer unit in an aqueous solution to form an oligomer radical, and increases hydrophobicity. The hydrophobicity of the oligomer radical accelerates the diffusion inside the micelle, accelerates the reaction with polymerizable monomers and facilitates a copolymerization reaction with a macromonomer.
Owing to the hydrophilicity of an amphipathic macromonomer, a copolymerization reaction can more easily occur in the vicinity of the surface of the toner particles. The hydrophilic portion of the macromonomer located on the surface of the particle increases the stability of the toner particle by providing steric stability, and can control the particle size according to the amount or molecular weight of the injected macromonomer. Also, the functional group which reacts on the surface of the particle can improve the frictional electricity properties of the toner.
Radicals in the toner composition are formed by the initiator, and the radical may react with the polymerizable monomer. The radical reacts with the polymerizable monomer and the reactive functional group of the macromonomer to form a copolymer.
Examples of the radical polymerized initiator include persulfates, such as potassium persulfate, ammonium persulfate, etc.; azo compounds, such as 4,4-azobis (4-cyanovaleric acid), dimethyl-2,2′-azobis (2-methylpropionate), 2,2-azobis (2-amidinopropane)dihydrochloride, 2,2-azobis-2-methyl-N-1,1-bis (hydroxymethyl)-2-hydroxyethylpropionamide, 2,2′-azobis (2,4-dimethylvaleronitrile), 2,2′-azobisisobutyronitrile, 1,1′-azobis (1-cyclohexanecarbonitrile), etc.; peroxides, such as methylethylperoxide, di-t-butylperoxide, acetylperoxide, dicumylperoxide, lauroylperoxide, benzoylperoxide, t-butylperoxide-2-ethylhexanoate, di-isopropylperoxydicarbonate, di-t-butylperoxyisophthalate, etc. Also, an oxidation-reduction initiator, which is a combination of a polymerized initiator and a reducing agent, may be used.
A developer according to the present invention may include a colorant, and such a colorant may be carbon black or aniline black in the case of a black toner. Also, it is easy to produce a color toner with a nonmagnetic toner according to an embodiment of the present invention. In the case of a color toner, carbon black is used as a colorant for black, and a yellow colorant, a magenta colorant and a cyan colorant are further included as colorants for the colors.
The yellow colorant may be a condensed nitrogen compound, an isoindolinone compound, an anthraquinone compound, an azo metal complex, or an aryl imide compound. In detail, C.I. pigment yellow 12, 13, 14, 17, 62, 74, 83, 93, 94, 95, 109, 110, 111, 128, 129, 147, 168, 180, etc. may be used.
The magenta colorant may be a condensed nitrogen compound, anthraquinone, a quinacridone compound, a lake pigment of basic dye, a naphthol compound, a benzoimidazole compound, a thioindigo compound, or a perylene compound. In detail, C.I. pigment red 2, 3, 5, 6, 7, 23, 48:2, 48:3, 48:4, 57:1, 81:1, 122, 144, 146, 166, 169, 177, 184, 185, 202, 206, 220, 221, 254, etc. may be used.
The cyan colorant may be a copper phthalocyanine compound or a derivative thereof, an anthraquinone compound, or a lake pigment of basic dye. In detail, C.I. pigment blue 1, 7, 15, 15:1, 15:2, 15:3, 15:4, 60, 62, 66, etc. may be used.
These colorants may be used alone or in combinations of two or more types. A desired colorant is selected considering the desired color, saturation, brightness, weatherability, and dispersability in a toner.
The amount of the colorant may be in the range of 0.1 to 20 parts by weight based on the 100 parts by weight of a polymerizable monomer. The amount of the colorant is not particularly limited as long as it is sufficient to color the toner. When the amount of the colorant is less than 0.1 parts by weight, the coloring is insufficient. When the amount of the colorant exceeds 20 parts by weight, the production costs of the toner increases and the toner is unable to obtain enough triboelectric charge.
The toner composition according to the present invention may include at least one material selected from the group consisting of wax, a charge control agent and a release agent.
The release agent protects a photoreceptor and prevents deterioration of developing properties, and thus may be used for the purpose of obtaining a high quality image. A release agent according to an embodiment of the present invention may use a solid fatty acid ester material with high purity. In detail, a low molecular weight polyolefin, such as low molecular weight polyethylene, low molecular weight polypropylene, low molecular weight polybutylene, etc.; paraffin wax; or a multifunctional ester compound, etc. may be used. The release agent used in an embodiment of the present invention may be a multifunctional ester compound formed of an alcohol having at least three functional groups and a carboxylic acid.
The charge control agent may be formed of a material selected from the group consisting of a salicylic acid compound containing a metal, such as zinc or aluminum, a boron complex of bisdiphenylglycolic acid, and silicate. More particularly, dialkyl salicylic acid zinc or borobis (1,1-diphenyl-1-oxo-acetyl potassium salt) may be used.
A suitable wax which provides a desired characteristic of the final toner compound may be used. The wax may be polyethylene wax, polypropylene wax, silicon wax, paraffin wax, ester wax, camauba wax or metallocene wax, but is not limited thereto. The melting point of the wax may be in the range of about 50 to about 150° C. Wax components physically adhere to the toner particles, but do not covalently bond with the toner particles. The toner fixes to a final image receptor at a low fixation temperature and has superior final image durability and antiabrasion property.
The polymerizing reaction may be performed for 3 to 12 hours according to the temperature. Particles obtained as a product of the reaction are filtered, separated and dried. At this time, an agglomeration process may be performed to control the particle size. An additive may be further added to the dried toner for use in a laser printer. The average volumetric particle size of the toner prepared according to the present invention may be in the range of 0.5 to 20 μm, and preferably, in the range of 5 to 10 μm.
The present invention provides a toner including a copolymer of a macromonomer and a polymerizable monomer obtained by emulsion-polymerizing a toner composition in a medium, the toner composition including the macromonomer having a hydrophilic group, a hydrophobic group and at least one reactive functional group, at least one polymerizable monomer, a multifunctional polyester, and a colorant dispersion, wherein the colorant dispersion is prepared by mixing a reactive emulsifying agent and a colorant.
A radical formed by an initiator reacts with the polymerizable monomer, the reactive functional group of the macromonomer, and the multifunctional polyester to form a copolymer. The weight average molecular weight of the copolymer may be in the range of 2,000 to 200,000.
The average volumetric particle size of the toner particles prepared according to the present invention may be in the range of 0.5 to 20 μm and preferably, in the range of 5 to 10 μm.
The toner composition may further include at least one material selected from the group consisting of wax, a charge control agent and a release agent, the details of which are as described above.
The present invention also provides an image forming method including: forming a visible image by disposing a toner on an photoreceptor surface where an electrostatic latent image is formed; and transferring the visible image to a transfer medium, wherein the toner includes a copolymer of a macromonomer and a polymerizable monomer obtained by emulsion-polymerizing a toner composition in a medium, the toner composition including the macromonomer having a hydrophilic group, a hydrophobic group and at least one reactive functional group, at least one polymerizable monomer, a multifunctional polyester, and a colorant dispersion, wherein the colorant dispersion is prepared by mixing a reactive emulsifying agent and a colorant.
An electrophotographic image forming process includes a charging process, a light-exposing process, a developing process, a transferring process, a fusing process, a cleaning process and an erasing process, which are series of processes to form an image on an image receptor.
In the charging process, the photoreceptor is covered with electric charges of desired polarity, either negative or positive, by a corona or a charging roller. In the light-exposing process, an optical system, generally a laser scanner or an array of diodes, forms a latent image corresponding to a final visual image to be formed on an image receptor by selectively discharging the charging surface of the photoreceptor in an imagewise manner. Electromagnetic radiation (hereinafter, “light”) may include infrared radiation, visible rays and ultraviolet radiation.
In the developing process, in general, the toner particles with suitable polarity contact the latent image on the photoreceptor, and typically, an electrically biased developer which has a potential with the same polarity as the toner is used. The toner particles move to the photoreceptor, selectively adhere to the latent image through static electricity and form a toner image on the photoreceptor.
In the transferring process, the toner image is transferred from the photoreceptor to a desired final image receptor. Sometimes an intermediate transferring element is used to effect the transfer of the tone image from the photoreceptor to the final image receptor.
In the fusing process, the toner image is fused to the final image receptor by melting or softening the toner particles by heating the toner image on the final image receptor. Alternatively, the toner can be fixed to the final image receptor under high pressure while being heated or without heating. In the cleaning process, the toner particles remaining on the photoreceptor are removed. In the erasing process, an electric charge on the photoreceptor is exposed to light of a certain wavelength, and the electric charge is substantially decreased to a uniform low value. Consequentially, a residue of the latent image is removed and the photoreceptor is prepared for the next image forming cycle.
The present invention also provides an image forming apparatus including: an organic photoreceptor; a unit for electrifying a surface of the organic photoreceptor; a unit for containing a toner including a copolymer of a macromonomer and a polymerizable monomer obtained by emulsion-polymerizing a toner composition in a medium, the toner composition including the macromonomer having a hydrophilic group, a hydrophobic group and at least one reactive functional group, at least one polymerizable monomer, a multifunctional polyester, and a colorant dispersion, wherein the colorant dispersion is prepared by mixing a reactive emulsifying agent and a colorant; a unit for supplying the toner to the surface of the organic photoreceptor to develop an electrostatic latent image on the surface of the organic photoreceptor into a toner image; and a unit for transferring the toner image on the surface of the organic photoreceptor to a transfer medium.
A developer 8, which is a nonmagnetic one-component developer, is supplied to a developing roller 5 through a feeding roller 6 formed of an elastic material such as polyurethane form and sponge. The developer 8 supplied to the developing roller 5 reaches a contact point between the developing roller 5 and a developer regulation blade 7 as the developing roller 5 rotates. The developer regulation blade 7 is formed of an elastic material such as metal, rubber, etc. When the developer 8 passes the contact point between the developing roller 5 and the developer regulation blade 7, the developer 8 is smoothed to form a thin layer and the developer 8 is sufficiently charged. The developing roller 5 transfers the thin layer of the developer 8 to a developing domain where the developer 8 is developed on the electrostatic latent image of a photoreceptor 1, which is a latent image carrier.
The developing roller 5 and the photoreceptor 1 face each other with a constant distance therebetween without contact. The developing roller 5 rotates counterclockwise and the photoreceptor 1 rotates clockwise. The developer 8 transferred to the developing domain forms an electrostatic latent image on the photoreceptor 1 according to the intensity of an electric charge generated due to a difference between a voltage applied to the developing roller 5 and a latent image potential of the photoreceptor 1.
The developer 8 developed on the photoreceptor 1 reaches a transferring device 9 as the photoreceptor 1 rotates. The developer 8 developed on the photoreceptor 1 is transferred through corona discharging or by a roller to a printing paper 13 as the printing paper 13 passes between the photoreceptor 1 and the transferring device 9 by the transferring device 9 to which a high voltage with an opposite polarity to the developer 8 is applied, and thus forms an image.
The image transferred to the printing paper 13 passes through a fusing device (not shown) that provides high temperature and high pressure, and the image is fused to the printing paper 13 as the developer 8 is fused to the printing paper 13. Meanwhile, any remaining developer 8 on the developing roller 5 which is not developed is returned to the feeding roller 6 contacting the developing roller 5. The above processes are repeated.
The present invention will now be described in greater detail with reference to the following examples. The following examples are for illustrative purposes only and are not intended to limit the scope of the invention.
16 g of cyan pigment, PB15:3 and 4 g of reactive emulsifying agent, HS-10 (available from DAI-ICHI KOGYO) were mixed in 100 g of ultra-high pure water which was deoxidized by ultra-high pure nitrogen. The mixture was put into a dispersing mixer (Dispermat Milling) and rotated at 5,000 RPM for about an hour to prepare colorant dispersion. An aqueous solution was prepared by mixing 500 g of ultra-high pure water and 5 g of polyethyleneglycol ethyl ether methacrylate (PEG-EEM) and introduced into the reactor. 50 g of the pigment solution obtained by the above process was diluted with 600 g of ultra-high pure water and was homogenized in a one liter reactor. The homogenization time was two minutes at a rotation speed of 7,000 RPM. After the homogenization, the pigment solution was stirred at 300 RPM and heated to 80° C. When the temperature inside the reactor reached the appropriate value, 1 g of potassium persulfate and 0.5 g of 2,2′-azobisisobutyronitrile were added as an initiator, and the inside of the reactor was purged with nitrogen gas. Immediately, a monomer compound formed of 100 g of monomer mixture of styrene, butylacrylate, methylacrylate and PEG-EEM at the rate of 7:1.5:0.5:1 respectively, 1 g of hexafunctional polyester acrylate (PS610, available from Miwon Co.), 2.5 g of chain transfer agent, 1-dodecanethiol and 10 g of release agent, ester wax were introduced slowly using a dropwise adding funnel for about an hour. During this process, the reaction time was 3 hours. Thereafter, 2 g of NaCl was dissolved in 20 g of ultra-high pure water and dropwise added to the reactor. Again, 110 g of the monomer mixture of above rate was introduced for an hour. The total reaction time was 6 hours and after the reaction, the product was naturally cooled while stirring it. The average volumetric particle size of obtained particles was 7.2 μm.
A toner composition was prepared in the same manner as in Example 1 except that, tetrafunctional polyester acrylate (PS450, available from Miwon Co.) was used instead of hexafunctional polyester acrylate. The average volumetric particle size of the manufactured toner particles was 7.8 μm and the number average size was 7.3 μm.
A toner composition was prepared in the same manner as in Example 1 except that, dendritic polyester (SP1013, available from Miwon Co.) was used instead of hexafunctional polyester acrylate. The average volumetric particle size of the manufactured toner particles was 6.9 μm and the number average size was 6.5 μm.
A toner composition was prepared in the same manner as in Example 1 except that, 4 g of BC-10 (available from DAI-ICHI KOGYO) was used for the reactive emulsifying agent instead of HS-10. The average volumetric particle size of the manufactured toner particles was 7.3 μm and the number average size was 7.1 μm.
A toner composition was prepared in the same manner as in Example 1 except that, 1 g of tetrafunctional polyester acrylate (PS450, available from Miwon Co.) was used for the multifunctional polyester and 4 g of BC-10 (available from DAI-ICHI KOGYO) was used for the reactive emulsifying agent. The average volumetric particle size of the manufactured toner particles was 7.2 μm and the number average size was 6.9 μm.
A toner composition was prepared in the same manner as in Example 1 except that, 1 g of dendritic polyester acrylate (PS450, available from Miwon Co.) was used for the multifunctional polyester and 4 g of BC-10 (available from DAI-ICHI KOGYO) was used for the reactive emulsifying agent. The average volumetric particle size of the manufactured toner particles was 7.5 μm and the number average size was 7.1 μm.
A toner composition was prepared in the same manner as in Example 1 except that as the polymerizable monomer, acrylic acid was used instead of methacrylic acid. The average volumetric particle size of the manufactured toner particles was 6.8 μm and the number average size was 6.5 μm.
A toner composition was prepared in the same manner as in Example 1 except that, PY 180 was used instead of PB 15:3 for the pigment. The average volumetric particle size of the manufactured toner particles was 7.8 μm and the number average size was 7.5 μm.
A toner composition was prepared in the same manner as in Example 1 except that, PR122 was used instead of PB 15:3 for the pigment. The average volumetric particle size of the manufactured toner particles was 7.5 μm and the number average size was 7.3 μm.
A toner composition was prepared in the same manner as in Example 1 except that, carbon black (Nipex 70) was used instead of PB 15:3 for the pigment. The average volumetric particle size of the manufactured toner particles was 7.2 μm and the number average size was 6.9 μm.
Preparation of Latex
0.5 g of sodium dodecyl sulfate (SDS) as an anionic surfactant, was mixed in 400 g of ultra-high pure water that was deoxidized. The aqueous solution was introduced into a reactor and heated to 80° C. When the temperature reached 80° C., an initiator, which was a solution of 0.2 g of potassium persulfate in 30 g of ultra-high pure water, was added. After 10 minutes, 105.5 g of styrene, butylacrylate and methacrylic acid (each 81 g, 22 g, 2.5 g respectively) were dropwise added for about 30 minutes. After allowing a reaction to occur for 4 hours, the heating was stopped and the product was allowed to cool naturally. 30 g of the resultant seed solution was removed and added to 351 g of ultra-high pure water, and the result was heated to 80° C. 17 g of ester wax was heated and dissolved together with 18 g of monomer styrene, 7 g of butylacrylate, 1.3 g of methacrylic acid, and 0.4 g of dodecanethiol. The prepared wax/mixed monomer was added to 220 g of ultra-high pure water in which 1 g of SDS was dissolved, and the result was homogenized for about 10 minutes in an ultrasonic homogenizer. The homogenized emulsified solution was put into the reactor and after about 15 minutes, 5 g of the initiator and 40 g of ultra-high pure water were mixed and added to the reactor. During this time, the reaction temperature was maintained at 82° C. and the reaction was allowed to continue thereafter for about 2 hours and 30 minutes. After the reaction was performed for 2 hours and 30 minutes, 1.5 g of the initiator and 60 g of ultra-high pure water were again added together with a monomer for shell layer formation. The monomer was composed of 56 g of styrene, 20 g of butylacrylate, 4.5 g of methacrylic acid, and 3 g of dodecanethiol. The monomer was dropwise added to the reactor for about 80 minutes. After the reaction was performed for two hours, the reaction was stopped and the product was allowed to cool naturally.
Toner Aggregation/Melting Process
318 g of latex particles prepared as described above were mixed with ultra-high pure water in which 0.5 g of an SDS emulsifier was dissolved. 18.2 g of pigment particles (cyan 15:3, 40 solidity %) dispersed by the SDS emulsifier were added to obtain a latex pigment dispersed aqueous solution. While stirring at 250 RPM, the pH of the latex pigment dispersed aqueous solution was titrated to pH 10 using a 10% NaOH buffer solution. 30 g of ultra-high pure water was dissolved in 10 g of MgCl2 as an aggregating agent, and the result was dropwise added to the latex pigment aqueous solution for about 10 minutes. The temperature of the resulting mixture was increased to 95° C. at a rate of 1° C./min. After about 3 hours of heating, the reaction was stopped and the product was allowed to cool naturally. The average volumetric particle size was about 6.5 μm.
According to the present invention, by using the reactive emulsifying agent, the cleaning process is simplified, and generation of polluted water and waste water is decreased, which is very advantageous environmentally. The formation and size of toner particles can be easily controlled. The anti-offset properties, triboelectric charge properties and storage stability of the toner are superior and allow the realization of high quality images. Also, a polymerized toner with superior properties can be prepared under a high humidity condition.
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope of the present invention as defined by the following claims.
| Number | Date | Country | Kind |
|---|---|---|---|
| 10-2005-0084419 | Sep 2005 | KR | national |
