Patent Application
20120003382
A variety of situations require hydrophilic articles. One example is within the fuel cell art. Many fuel cell arrangements include water transport plates for controlling water, air and fuel flow within a fuel cell assembly in a known manner. Traditionally, water transport plates have included porous, hydrophilic flow fields that include flow channels for directing fluid in a desired manner. Many such flow fields comprise graphite, a resin and a wettability component. For example, it is known to treat porous graphite plates with a metal oxide post-treatment to impart wettability to the plate. It is also known to add a metal oxide as one of the components for making a water transport plate. Another example includes adding hydrophilic carbon black. In many of those instances, the wettability component is added as a separate component in a mixture containing resin such that the resin binds the wettability component in place. There is no effect on the graphite, itself, using the traditional approach.
U.S. Pat. No. 5,942,347 shows one example technique where a porous bi-polar separator plate has at least one electronically conductive material, at least one resin and at least one hydrophilic agent. Each of these components is substantially uniformly distributed throughout the separator plate of that document. The hydrophilic agent in that document is selected from material such as oxides of Ti, Al, Si and mixtures of them. There are at least two difficulties with this approach. First, it is very difficult to uniformly distribute materials as suggested in that patent. Secondly, because the oxides are dielectric, using hydrophilic or wetting agents of the type described there can increase the electrical resistance of such a separator plate, which is undesirable. Therefore, it is difficult to achieve uniform distribution as suggested in that document without increasing electrical resistance.
Such wettability treatments or additives have been required because the graphite is generally hydrophobic. Without the wettability agent or treatment, traditional graphite based water transport plates are hydrophobic and not suitable for their intended use. Graphite particles comprise carbon atoms arranged in a manner that typically provides a relatively low surface energy such that the graphite particles are essentially hydrophobic. Carbon atoms within a graphite crystal are arranged in a plurality of generally parallel planes. The bonds between the carbon atoms within the planes are very strong. Graphite particle surfaces that are aligned with such planes (i.e., basal plane surfaces) have a relatively low surface energy.
It is desirable to provide an improved process for making hydrophilic articles such as water transport plates. For example, it would be useful to make the fabrication process less complicated and to reduce costs by taking a different approach that does not include the traditional wettability additives or wettability enhancing agents. This invention addresses that need.
An exemplary method of treating a material to render at least some surfaces of the material hydrophilic includes coating at least a portion of the at least some surfaces with an oxygenated element and controlling a rate of a breakdown of the oxygenated element to leave a corresponding elemental oxide on the surfaces.
In one example, the material is treated before being incorporated into an article comprising the material. Another example method includes treating an article comprising the material. Disclosed examples include precipitation or decomposition as the breakdown of the oxygenated element. Disclosed examples include carbon and graphite as the material that is treated.
The various features and advantages of the disclosed examples will become apparent to those skilled in the art from the following detailed description. The drawings that accompany the detailed description can be briefly described as follows.
Disclosed example methods of treating a normally hydrophobic material such as carbon or graphite renders at least some surfaces of the material hydrophilic, which is useful for establishing a hydrophilicity or wettability for an article including that material.
One example use of such an article is in a fuel cell.
The anode water transport plate 12 includes a plurality of fuel flow channels 32 that are in fluid communication with each other and with a fuel inlet 34 that receives the reducing fluid so that the fuel inlet 34 and flow channels 32 cooperate to pass the reducing fluid fuel through the fuel cell 10 in fluid communication with the anode catalyst 20. Similarly, the cathode water transport plate 14 includes a plurality of oxidant flow channels 36 that are in fluid communication with each other and with an oxidant inlet 38 that receives the process oxidant so that the oxidant inlet 38 and oxidant flow channels 36 cooperate to pass the process oxidant through the fuel cell 12 in fluid communication with the cathode catalyst 22.
Water transport plates serve many functions in a fuel cell. Namely, they deliver reactants to membrane electrode assembly catalysts; transport product water away from the cathode to prevent flooding; humidify the anode and/or cathode reactant streams; provide a wet seal barrier between reactants and/or coolants; and act as an electrical conductor to carry electrical current to the collectors. Accordingly, the pore structure must be designed to provide the desired capillary action and assure sufficient hydrophilicity to facilitate water movement. Some arrangements include porous and non-porous sections, but the porous sections must have sufficient hydrophilicity.
As mentioned above, the traditional approach for making water transport plates renders them hydrophobic unless a wettability agent has been incorporated as a raw material ingredient in the manufacturing process or in a post-treatment process. The graphite as used in many previous water transport plates is hydrophobic, or insufficiently hydrophilic, which has made it necessary to include a separate wettability agent.
There are other articles for which wettability and water transport properties are required. For example, some fuel cell applications utilize evaporative cooling. Some portions of such fuel cell arrangements require sufficient wettability to accomplish the desired water transport from the liquid zone to the evaporative zone. Another example article within a fuel cell that may need to be wettable or hydrophilic is the gas diffusion layer such as the layers 24 and 28. The carbon used for many previous gas diffusion layers is hydrophobic, or insufficiently hydrophilic, which has required adding a separate wettability agent to make a hydrophilic gas diffusion layer.
The hydrophilicity of an object is a surface property characteristic that describes wetting behavior, which is the interaction of a liquid with a solid. For example, wetting is observed in the spreading of a liquid over a surface, in penetration of a liquid into a porous medium, or in displacement of one liquid by another. Wetting refers to the macroscopic manifestation of molecular interaction between liquids and solids in direct contact at the interface between them. Increased wettability ensures uniform spreading of a liquid over a solid surface or better penetration of a liquid through a porous medium, for example.
Wettability is typically determined by the balance between adhesive forces between the liquid and solid and cohesive forces in the liquid. Adhesive forces cause a liquid drop to spread. Cohesive forces cause the liquid drop to remain balled up.
The contact angle between the liquid and the solid is determined by competition between the adhesive and cohesive forces. When a surface is wettable or hydrophilic, the contact angle with water is less than 90°. Hydrophilic materials possess high surface energy values and the ability to form “hydrogen bonds” with water. By contrast, hydrophobic or non-wettable materials have little or no tendency to absorb water so that water tends to “bead up” on the surface in the form of discrete droplets. The contact angle with water for hydrophobic surfaces is greater than 90°. Hydrophobic materials possess low surface energy values and lack active groups in the surface chemistry for forming “hydrogen bonds” with water.
We consider graphite as one example type of carbon for discussion purposes. To understand the wettability of graphite, it is useful to consider its structure. Graphite is composed of infinite layers of carbon atoms arranged in the form of hexagons (or rings) lying in planes. The layers are stacked parallel to each other. Each carbon atom within the plane is covalently bonded (e.g., is tightly bound) to three other carbon atoms. The atoms in alternative planes align with each other and are loosely bonded by van der Waals forces.
Surface areas on the graphite particle aligned with the planes (e.g., generally parallel to the first plane 56) are referred to as a basal plane surface such as that schematically shown at 62. Ideal basal plane surfaces, which means defect free and contamination free, are homogenous, generally “smooth” and consist only of carbon atoms. Each graphite particle will have at least one basal plane surface 62 and at least one prismatic surface 64. The usual shape of graphite powder is platelets or flakes with basal sites that have a low surface energy. Flake graphite has a majority of the overall graphite particle surface area within a basal plane surface.
The strong bonds between the carbon atoms 54 within the basal planes yields a relatively low basal plane surface energy and a resulting hydrophobic surface.
The relatively weaker bonds (from van der Waals forces) between carbon atoms in different planes provides a higher surface energy along prismatic surfaces 64. The prismatic surfaces are distinguishable from basal plane surfaces 62 because the prismatic surfaces are arranged at least partially oblique to the orientation of the planes 56, 58 and 60, for example. It is sufficient for purposes of discussion to understand that normally there is a different surface energy on the basal plane surfaces 62 compared to the surface energy on the prismatic surfaces 64.
The relatively weak links between carbon atoms along the prismatic surfaces 64 and the heterogeneous nature of the prismatic surfaces (e.g., prismatic surfaces typically include various, mostly oxygen-containing functional surface groups along with the carbon atoms) gives the prismatic surfaces 64 a higher surface energy. The prismatic surface 64 can be considered a polar surface. As a result, the prismatic surfaces 64 are hydrophilic and can form strong hydrogen bonds with water molecules.
The hydrophobic and hydrophilic character of the graphite surfaces on a graphite particle can be characterized by a wettability ratio, which can be expressed by the following relation:
According to this definition, the wettability ratio can vary significantly: from almost one (for theoretical, ideal, perfectly sphere shaped graphite which has all surface area formed by the prismatic surfaces) to a very low value for graphite with predominantly basal plane surface. The higher the wettability ratio of graphite, the better its wettability.
In one example, the wettability ratio equals the ratio of prismatic surface area to the total surface area.
Prismatic (e.g., hydrophilic) surface area and total surface area can be determined experimentally. The hydrophilic (and hydrophobic) character of graphite surfaces can be determined by absorption calorimetry, or by flow microcalorimetry. The total surface area can be determined by the Brunauer, Emmett and Teller (BET) method. A very exact method useful in breaking down the total surface area of graphite into fractions of basal plane surfaces and prismatic surfaces is krypton gas absorption.
The relative hydrophilicity between differing graphites can be determined using known techniques such as the Washburn method (or Capillary Rise Method), which is well known from published literature. This technique allows for obtaining the values of contact angles, which indicates in a relative manner whether a surface is hydrophilic (i.e., wettable) or hydrophobic.
One example embodiment of this invention includes the realization that increasing the amount of prismatic surface area within graphite used for forming a hydrophilic article establishes sufficient wettability for the article to meet the hydrophilicity needs of a particular situation. It has been found, for example, that using sufficiently wettable graphite particles as at least a portion of the graphite used to make the article can establish a sufficient wettability to meet the needs for many fuel cell applications.
One example includes selecting graphite particles having a wettability ratio, which is the ratio of the hydrophilic surface area to the total surface area, within a range sufficient to make the resulting article hydrophilic. In other words, selecting enough of the graphite particles to have a particular physical characteristic results in enough wettable (e.g., prismatic) surface area compared to the hydrophobic (e.g., basal plane) surface area to render the resulting article hydrophilic. By appropriately selecting graphite particles, the wettability of a hydrophilic structure can be established purely by the graphite particles.
In one example, the selected graphite particles have a wettability ratio that is more than about 0.10. This is achieved in one example, by selecting graphite particles that have at least about 10% prismatic surface area with a remaining percentage basal surface area.
One example includes selecting graphite particles having a wettability ratio greater than 0.18. In this example, provided that there are enough graphite particles having at least about 18% wettable (e.g., prismatic) surface area, sufficient wettability can be obtained for many fuel cell water transport plate applications. One example includes selecting graphite particles that are generally spheroidal. Such particles have more prismatic surface area than flake graphite. One particular example includes spheroidal graphite particles as the majority of the graphite. Another example includes spheroidal graphite particles, exclusively. Strategically controlling the amount and type of graphite particles that are included will provide wettability in an amount sufficient to meet the needs of a given situation.
A variety of commercially available spheroidal graphite materials are known. Prior to this invention, however, no one has considered the wettability aspects of such particles. Instead, they have been always used with a wettability agent. U.S. Pat. No. 6,746,982, for example, mentions the use of Timcal KS75 and KS150 graphite, both of which are spheroidal. That patent teaches adding a wettability treatment. U.S. Pat. No. 6,926,995 suggests using natural or synthetic graphite for a porous separator plate and teaches that the graphite is not subject to any particular limitation. That patent is another example of the traditional thinking that adding a hydrophilic agent is necessary to achieve wettability.
Wettability agents typically have been introduced along with resin and graphite particles. In those instances, wettability agents have been secured to the structure or made part of the structure by the binding action of the resin. In other words, the wettability agents did not directly impact the graphite because they were present within the composite and typically held in position by the resin.
As mentioned above, one example implementation of this invention includes using generally spheroidal graphite particles because of their relatively higher percentage of prismatic surface area compared to flake graphite, for example. Another example includes using expanded graphite particles to achieve the desired wettability ratio. Expanded graphite particles are known. Expanded graphite particles have larger distances between the parallel plane of carbon atoms, which provides an increased prismatic surface area compared to non-expanded graphite particles. One embodiment of this invention includes using at least some expanded graphite particles within the graphite to provide hydrophilicity to a resulting article.
Another example includes pretreated graphite particles that have increased wettable surface area compared to pure or untreated graphite. In one example, the basal plane surface of the pretreated graphite particles have some wettability along with the wettability of the prismatic surfaces such that a higher percentage of hydrophilic surface area exists compared to pure or untreated graphite.
One example includes treating the basal surfaces of the graphite to create defects on the basal planes using a plasma, laser or other surface treatment. Defects on the basal planes will interrupt or interfere with the otherwise present strong covalent bonds between the carbon atoms, which will increase the surface energy and the wettability of a basal surface. In such an example, at least some of the basal plane surface area can be considered as part of the hydrophilic surface area along with the already hydrophilic prismatic surface area.
Another example includes using a deposition process to effectively modify a surface of an otherwise hydrophobic material such as the basal surface of graphite particles. Examples include coating at least a portion of at least some surfaces of the hydrophobic material with an oxygenated element and controlling a rate of a breakdown of the oxygenated element to leave a corresponding elemental oxide on the surfaces. One example method includes decomposition as at least part of the breakdown of the oxygenated element. Another example method includes precipitation as at least part of the breakdown of the oxygenated element.
In one example, pure graphite is mixed with an organic titanate in an ethanol solution. One example includes using Tyzor® (tetra n-butyl titanate (TnBT)), which is available from Dupont. In one example, the amount of titania (TiO2) constitutes 0.4-0.5 mass % of the graphite.
Organic butyl titanate solution is mixed with a solvent (denatured ethanol) and graphite. The butyl titanate and solvent undergo a metathetical ligand exchange (room temperature decomposition) to form titanium tetraethanolate, butanol, and ethanol. The alcohols are then decanted, and the resulting slurry is then heated at 350° C. to completely decompose the remaining organic components, resulting in TiO2 being deposited on the basal plane surface of the graphite.
When such an organic butyl titanate solution is heated, ethanol will be evaporated and butyl titanate will be decomposed into TiO2 by the following reaction:
Ti(OCH4H9)4+4(C2H5OH)==>Ti(OC2H5)4+4(C4H9OH)==>Ti(OC2H5)4+heat (350° C.)==>TiO2
The result is the presence of TiO2 on surfaces of the graphite particles. The deposited TiO2 on the graphite particles renders those surfaces at least partially wettable. We believe the presence of unsaturated Ti atoms, which can be easily combined with oxygen atoms in water to form Ti—OH layers, renders such a surface hydrophilic or wettable. On some surfaces, 2-3 layers of physically absorbed water are further formed.
From one perspective, pretreating graphite as described above increases the surface energy of the surfaces where the TiO2 is deposited. In some example embodiments of this invention, the pretreated graphite particles include basal plane surfaces with a higher surface energy compared to untreated graphite such that the pretreated basal surfaces are hydrophilic.
In one particular example, 25 g of graphite powder KS5-75TT (d90=70 micron) was added to 40 ml of an ethyl solution and mixed at approximately 1000 rpm in a 3-propeller Barnant mixer. A selected amount of Tyzor® (0.5326 g of Tyzor® TnBT 23.5 mass % TiO2 in 25 g of graphite) was dissolved into 50 ml of the ethanol solution and added to the graphite slurry. The mixture was stirred for fifteen minutes and placed in a large glass dish. That was then placed into a nitrogen purged oven in which the temperature was slowly ramped to 200° C. at a rate of 10° C. per minute. The graphite resided isothermally at 200° C. for 20 minutes and then the temperature was ramped to 350° C. at a rate of 10° C. per minute. In this example, the temperature of 350° C. was maintained for 10 minutes before turning off the oven and letting it cool down slowly to room temperature.
In one example, deposited TiO2 was examined qualitatively using Energy Dispersive Spectroscopy (EDS) and quantitatively by Inductively Coupled Argon Plasma (ICP). The EDS results confirmed the presence of TiO2 on the graphite and the ICP results demonstrated that the amount of TiO2 was close to 0.5 mass % of graphite. The surface morphology of the deposited TiO2 was characterized using Scanning Electron Microscopy (SEM). White deposits of TiO2 were seen on the basal plane surface of graphite particles and their estimated dimensions were in a nanometer range.
In the just-described example, the graphite particles were treated to have TiO2 deposited on at least one basal surface of the graphite particles before they were used for making a hydrophilic article, such as a plate for use in a fuel cell. One example article into which such treated graphite particles are incorporated comprises a water transport plate for use in a fuel cell.
In another example, at least one other oxygenated element and corresponding elemental oxide is used for treating the graphite particles using the same controlled breakdown process (e.g., decomposition). One example includes using a zirconate and depositing ZrO2 on basal plane surfaces of at least some of the treated particles. Another example includes SiO2 based upon a silicate. Other examples include oxides based on at least one of a stannate, an aluminate or a tantalate.
Any of the above oxygenated elements used for forming the oxide to treat the graphite particle basal surfaces can be processed in the manner described above for the example that results in TiO2 deposits. Any one of the mentioned oxygenated elements could be used or a combination of them could be used to provide the oxides.
In one example, the article is made before the material (e.g., graphite or carbon) is treated. In one example, an article is first formed and then subsequently treated to increase the surface energy of surfaces on graphite particles by depositing TiO2 on the particles within the article. Wettability is also increased because the TiO2 is deposited on any existing binder such as a resin binder. Example articles treated in this manner include water transport plates and gas diffusion layers.
In one particular example, 1.0654 g of 0.5 mass % organic titanate (in the form known as Tyzor® TnBt) was weighed into a 100 mL beaker with 50 g of denatured ethanol (JT Baker, PSIII-Product No. 9287). A 2×2 inch sample of a porous graphite plate was placed into the solution and subjected to vacuum impregnation. The sample was subsequently dried at room temperature for 30 minutes. The sample was then backfilled by placement into a solution of 4.7 mass % of dionized water (36.03 g) in 764.5 g denatured ethanol for 30 minutes at room temperature. The sample was then placed into an oven at 115° C. (240° F.).
The resulting sample had an increased hydrophilicity compared to the sample before the example treatment process. The resulting deposition of TiO2 on at least some basal surfaces of graphite particles increase the hydrophilicity of those particles, which renders the article hydrophilic. The solvent (denatured ethanol) has the effect of slowing down a rate of precipitation (i.e., breakdown) of titania from the titanate. Without the solvent, mixing moisture from air and a titanate such as Tyzor®results in an essentially instantaneous reaction resulting in precipitated titania (TiO2) from the titanate. Using a solvent in one example allows for controlling the rate of precipitation. This allows for an article to be coated with the titanate before precipitation. In one example, this results in a much higher hydrophilicity because it is believed that the attachment of the oxygenated element to the graphite prior to the breakdown (i.e., precipitation) allows a far greater incidence of the elemental oxide (e.g., titania) deposited on the graphite.
One advantage to an approach for treating an article comprising graphite compared to pretreating the graphite particles themselves is that the article treatment approach can provide the intended hydrophilicity using lower temperatures, which requires less energy. Another advantage is that the associated cost, complexity and required time are reduced compared to pretreating graphite particles. Another advantage is that all constituents within the article will be rendered at least somewhat hydrophilic because the elemental oxide (e.g., TiO2) is deposited everywhere on the article.
The graphite from the supply 100 is mixed with a resin 102 and a mold 104 is used to form a resulting article 106.
Depending on the performance characteristics required for the resulting article and the type of graphite selected for forming the article, different wettability ratios will provide the intended results for different operating conditions. Given this description, those skilled in the art will be able to select appropriate wettability ratios and percentages of appropriate graphite particles to provide a hydrophilic article that meets their particular needs without requiring a wettability agent or additive in the graphite-resin mixture.
Graphite is used in the examples described above as one example type of carbon that can be treated in accordance with the disclosed methods. Another example includes carbon as the material that is treated to render at least some surfaces of the carbon hydrophilic. Untreated carbon is otherwise a generally hydrophobic material. In one particular example, a gas diffusion layer comprising carbon is treated by coating at least a portion of at least some surfaces of the carbon with an oxygenated element. Controlling a rate of a breakdown of the oxygenated element (e.g., by including one of the example solvents mentioned above in the mixture) allows for leaving deposits of the corresponding elemental oxide on the surfaces of the carbon. This renders the treated carbon hydrophilic enough to provide the desired wettability or hydrophilicity of the article (e.g., the gas diffusion layer) for its intended use in a fuel cell, for example.
The preceding description is exemplary rather than limiting in nature. Variations and modifications to the disclosed examples may become apparent to those skilled in the art that do not necessarily depart from the essence of this invention. The scope of legal protection given to this invention can only be determined by studying the following claims.
This application is a continuation-in-part of U.S. application Ser. No. 11/320,517, which was filed on Dec. 28, 2005, a continuation-in-part of U.S. application Ser. No. 11/567,480, which was filed on Dec. 6, 2006; and a continuation of U.S. application Ser. No. 11/769,294, which was filed on Jun. 27, 2007.
| Number | Date | Country | |
|---|---|---|---|
| Parent | 11769294 | Jun 2007 | US |
| Child | 13176309 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 11320517 | Dec 2005 | US |
| Child | 11769294 | US | |
| Parent | 11567480 | Dec 2006 | US |
| Child | 11320517 | US |
