Method of using variably sized coating particles in a mono component developing system

Information

  • Patent Grant
  • 6605402
  • Patent Number
    6,605,402
  • Date Filed
    Tuesday, August 21, 2001
    23 years ago
  • Date Issued
    Tuesday, August 12, 2003
    21 years ago
Abstract
The present invention is directed to a non-contact, single-component developing system for electrophotographic machines that effectively reduces the impact of adhesion forces on the development process. The developing system of the present invention utilizes a single-component toner that tends to reduce the adhesion forces that hold the toner particles on a toner support member. Preferably, the toner is combined with large and small silica particles having a concentration by weight that results in an optimum surface coverage of toner particles by large and small silica particles that facilitates a reduction in the adhesion forces holding the toner particles on the toner support member.
Description




FIELD OF THE INVENTION




The present invention relates generally to electrophotography, more particularly, to a non-contact, single-component developing system and single-component toner that facilitates efficient development of an electrostatic image and consistent high quality image output.




BACKGROUND OF THE INVENTION




Electrophotographic imaging process (or xerography) is a well-known method of copying or otherwise printing documents. In general, electrophotographic imaging uses a charge-retentive, photosensitive surface (known as a photoreceptor) that is initially charged uniformly. The photoreceptor is then exposed to a light image representation of a desired image that discharges specific areas of the photoreceptor surface creating a latent image. Toner powder is applied by using a developing system, which carries the toner from a toner container to the latent image, forming a developed image. This developed image is then transferred from the photoreceptor to a substrate (e.g. paper, transparency, and the like).




A color electrophotographic imaging process is typically achieved by repeating the same process described above for each color or tone of toner desired and storing each developed image to an accumulator until all desired colors or tones are achieved and then transferred to a substrate (e.g. paper, transparency, and the like).




There are several developing systems known in the art that carry the toner to the developing region and develop the latent image. One process is known as a “non-contact” or “jump” developing system. In operation, a thin layer of toner is adhered to a toner support member in spaced relation with respect to the latent image-bearing surface of the photoreceptor. When the toner is carried to the developing region between the toner support member and the photoreceptor, a bias voltage associated with the latent image areas of the photoreceptor tends to exert electrostatic forces that direct the toner particles towards the latent image areas on the surface of the photoreceptor. The electrostatic forces are often of insufficient magnitude to overcome the adhesion forces holding the toner particles in the thin layer on the toner support member. One solution is to apply high AC voltage to the developing region. The AC voltage agitates the toner particles to free them from the toner support member, enabling the toner particles to “jump” the gap between the toner support member and the photoreceptor. The toner particles that jump the gap adhere to the latent image areas on the surface of the photoreceptor to form a developed image. For color or “tone-on-tone” developing, this process is repeated and the developed images containing individual colors are transferred to and stored on an accumulator until all desired colors or tones are achieved and than transferred to a substrate (e.g. paper, transparency, and the like). Although this process will produce color and tone-on-tone images with sufficient efficiency, the addition of an accumulator increases the complexity and cost of the electrophotographic imaging system.




Although previous efforts have been made to produce a non-contact developing system for multi-color imaging utilizing a single component toner and accumulation of the image on a single photoconductor (i.e., no accumulator), none of these efforts appear to have resulted in a system that effectively develops color toner particles to a photoreceptor with sufficient efficiency.




Also, previous efforts have been made to produce a non-contact developing system for monochrome imaging utilizing a single component toner and using DC bias only. None of these efforts appear to have resulted in a system that effectively develops toner particles to a photoreceptor with sufficient efficiency.




SUMMARY OF THE INVENTION




The present invention is directed to a non-contact, single-component developing system for electrophotographic machines that effectively reduces the impact of toner adhesion forces on the development process and facilitates toner jump while eliminating the need for AC voltages and, thus, an accumulator or some other intermediate transfer member. In a particularly innovative aspect, the developing system of the present invention utilizes a single-component toner that tends to reduce adhesion forces that tend to adhere toner particles to a toner support member. More particularly, the toner in accordance with the present invention includes large and small extraparticulate particles having concentrations by weight that preferably optimize surface coverage of the toner particles by the extraparticulate particles. In referring to surface coverage by area (surface coverage, surface coverage area), the total area of toner surface=πD


T




2


and the projected area of silica=D


si




2


, as shown in FIG.


14


. The extraparticulate particles of the present invention are preferably comprised of silica particles but may be comprised of an extraparticulate with similar physical characteristics to silica including material such as titanium dioxide, polymer microspheres, polymer beads, cerium oxide, zinc stearate, alumnina, and the like. In a preferred embodiment, surface coverage of toner particles by large extraparticulate particles is in a range of about 5 to 50 percent and surface coverage of toner particles by small extraparticulate particles is in a range of about 50 to 150 percent.




A toner may be prepared with the required calculated surface area coverage of extraparticulate particles by incorporation of a specific weight percent of each of the large and small extraparticulate particles by taking into account the mean diameter of the toner, the specific gravity of the toner and mean diameters and densities of each of the large and small extraparticulate particles. For example, for a 12 μ mean diameter toner with specific gravity of 1.1 g/cm


3


combined with large extraparticulate particles having a mean diameter of 40 nm and a specific gravity of 2.2 g/cm


3


and small extraparticulate having a mean diameter of 10 nm and specific gravity of 2.2 g/cm


3


, the surface area coverage of the large extraparticulate of 5 to 50 percent corresponds to a concentration by weight of 0.16 percent to 1.6 percent and the surface area coverage of the small extraparticulate of 50 to 150 percent corresponds to a concentration by weight of 0.45 to 1.35 percent.




In a further innovative aspect, the toner in accordance with the present invention has a development efficiency in a range of about 80 to 99 percent over a wide range of bias voltages.




In a preferred embodiment, a development system of the present invention preferably comprises a toner support member and a photoreceptor positioned in spaced relation. In operation, the photoreceptor is initially charged uniformly and then exposed to a light image representative of a desired image that discharges specific areas of the image bearing surface of the photoreceptor. Toner, which is carried to the developing region by the toner support member, is caused to jump the gap between the toner support member and the photoreceptor to the latent image, forming a developed image. Significantly, the electrostatic forces resulting from the DC bias voltage are sufficient to overcome toner adhesion forces without the use of AC voltages or some other means of freeing the toner free from the toner support member. This advantageously enables the development of color or “tone-on-tone” images without the need for an accumulator or some other intermediate transfer member.




Other innovative aspects of the invention include the preceding aspects individually or in combination.











Other aspects and features of the present invention will become apparent from consideration of the following description taken in conjunction with the accompanying drawings.




BRIEF DESCRIPTION OF THE DRAWINGS





FIG. 1

is a schematic of a non-contact, single-component developing system of the present invention.





FIG. 2

is a schematic illustrating the forces acting upon a toner particle during the development process.





FIG. 3



a


is a schematic of a non-contact, single-component color developing system in accordance with the present invention.





FIG. 3



b


is a partial schematic of the non-contact, single-component color developing system shown in

FIG. 3



a.







FIG. 4

is a plan view of a toner particle with silica particles adhered thereto.





FIG. 5

is a graph showing a typical particle size distribution for silica.





FIG. 6

is a graph showing a typical particle size distribution for toner particles having a mean diameter of 16 μm.





FIG. 7

is a graph showing development efficiency.





FIG. 8

is a graph showing development efficiency.





FIG. 9

is a graph showing development efficiency.





FIG. 10

is a graph showing development efficiency.





FIG. 11

is a graph showing development efficiency.





FIG. 12

is a graph showing development efficiency.





FIG. 13

is a graph showing development efficiency.





FIG. 14

is a schematic illustrating the calculated surface area coverage.











DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS




The non-contact, single-component developing system of the present invention tends to facilitate efficient development of an electrostatic image and the consistent production of high quality output images. More particularly, the system of the present invention tends to reduce adhesion forces that hold toner particles to a toner support member to enable toner particles to more easily and efficiently jump from the toner support member to an image-bearing member such as a photoreceptor.




Referring in detail to the figures,

FIG. 1

shows a non-contact or jump developing system


10


for use with a single-component toner in accordance with the present invention. The developing system


10


preferably includes a toner support member


20


, such as a roller, and a photoreceptor


30


, such as a photosensitive drum or belt. The toner roller


20


and photoreceptor


30


are aligned in spaced relation to form a gap


28


at the “developing region”


29


. Preferably, the gap


28


is approximately 150 microns. A metering bar


24


contacts the toner roller


20


and acts to create a thin layer and to charge the toner particles


22


on the toner support member


20


from a toner reservoir or supply. The developing system


10


also includes an electrically coupled charger element


32


and an array of light emitting diodes (LEDs)


34


.




In operation, the surface


31


of the photoreceptor


30


is initially uniformly charged by the charger element


32


to a potential preferably in the range of approximately −700 to −750 V (DC). The photoreceptor


30


is constructed of a material that is conductive (i.e., allows a charge to dissipate) only when exposed to light. To create the desired electrostatic latent image on the photoreceptor


30


, light is radiated from the arrays of LEDs


34


onto the surface


31


of the photoreceptor


30


to dissipate the charge on the surface


31


in a pattern to form a latent image corresponding to a desired image. After exposure of the photoreceptor


30


to light the potential of the latent image areas on the photoreceptor


30


is reduced to a range of approximately −50 V (DC).




The toner roller


20


is preferably biased to a potential approximately equal to the potential of the non-image areas on the image-bearing surface


31


, but between the potential of the image and non-image areas. Preferably, the potential of the toner support member has a value of approximately the same as the non-image areas.




As the toner roller


20


carries the toner


22


into the developing region


29


, the difference between the bias voltage on the toner roller and the potential difference associated with the latent electrostatic image areas on the surface


31


of the photoreceptor


30


, which is approximately 650 V (DC), preferably exerts a force of sufficient magnitude on the toner particles


22


to cause the toner particles


22


to jump the gap


28


between the toner roller


20


and the photoreceptor


30


and adhere to the latent electrostatic image areas on the surface


31


of the photoreceptor


30


. The voltage difference between the non-image areas of the surface


31


and the toner support member which is approximately zero V (DC), tends to exert zero force on the toner particles on the toner support member


20


.




As shown in

FIG. 2

, for toner particles


22


to jump the gap


28


during the development process, the electrostatic, or Coulombic, force C acting upon the toner particle


22


must be sufficient to overcome the adhesion force A that adheres the toner particle


22


to the toner roller


20


. If not, development efficiency and, thus, image quality tend to suffer. To reduce the impact of the adhesion forces, conventional methods tend to include the use of AC voltage or some other means of agitating the toner. Significantly, as discussed in greater detail below, the toner in the development system of the present invention advantageously reduces the impact of adhesion forces on the development process without resort to AC voltage or other means to agitate the toner. This tends to be of particular significance with regard to color or “tone-on-tone” developing because it enables the simplification and reduction in size and, thus, cost of the development system by eliminating the need for an accumulator or some other intermediate transfer means.




Turning to

FIG. 3



a


, a non-contact, single-component color or “tone-on-tone” developing system


100


in accordance with the present invention is shown to preferably include a photoreceptor, e.g., an image-bearing belt


130


, and four toner support members


120




y


,


120




m


,


120




c


, and


120




k


for delivery of toners preferably comprising toner of four different color pigments. The toner support members


120




y


,


120




m


,


120




c


, and


120




k


, respectively, preferably deliver yellow toner particles


122




y


, magenta toner particles


122




m


, cyan toner particles


122




c


, and black toner particles


122




k


to the developing region


128




y


,


128




m


,


128




c


, and


128




k


interposing the toner support members


120




y


,


120




m


,


120




c


, and


120




k


and the image-bearing belt


130


. The developing system


100


preferably includes four charger elements


132




y


,


132


m,


132




c


, and


132




k


, respectively, and four LED arrays


134




y


,


134




m


,


134




c


, and


134




k


, respectively, positioned along the belt


130


prior to a corresponding toner support members


120




y


,


120




m


,


120




c


, and


120




k


. By including four charger elements and four LED arrays, the developing system


100


of the present invention is preferably capable of developing a color image in a single pass of the photoreceptor


130


. Alternatively, the developing system


100


may include two charger elements and two LED arrays to enable a color image to be developed in two passes of the photoreceptor


130


, or one charge and one LED array to enable a color image to be developed in four passes of the photoreceptor


130


.




In operation, as shown in greater detail in

FIG. 3



b


, the first charger element


132




y


initially uniformly charges the image-bearing belt


130


to a potential in the range of approximately −700 V (DC) to −750 V (DC). Next, the first LED array


134




y


radiates light onto the image-bearing belt


130


in a specific pattern corresponding to portions of a desired image that require the inclusion of the color yellow. The charge on the areas of the belt


130


exposed to the light dissipates to a potential of approximately −50 V (DC). After the image-bearing belt


130


passes the first developing region


128




y


adjacent the first toner support member


120




y


where toner is directed to the latent electrostatic areas along the surface of the belt, the belt


130


is again uniformly-charged to a potential in the range of approximately −700 V (DC) to −750 V (DC) by the second charger element


132




m


. Light is then radiated from the second LED array


134




m


onto the belt


130


in a specific pattern corresponding to portions of a desired image that require the inclusion of the color magenta, including portions that already have yellow toner deposited thereon. The charge on portions of the belt


130


that do not already have toner deposited thereon dissipates, causing those portions of the belt


130


to have a potential of approximately −50 V (DC); however, the charge on portions of the belt


130


that already have toner deposited thereon tends to dissipate less, causing those portions of the belt


130


to have a potential in a range of approximately −150 V to −250 V (DC). After the image-bearing belt


130


passes the second developing region


128




m


adjacent the second toner support member


120




m


where toner is directed to the latent electrostatic areas along the surface of the belt, the process is repeated for the two remaining colors (e.g., cyan and black).




Because the charge on portions of the belt


130


already having toner deposited thereon may only dissipate to a potential of approximately −150 V to −250 V (DC), the voltage difference applied to the toner particles to cause the toner particles to jump the gap


128


and adhere to these portions of the belt


130


is significantly reduced to approximately 450 V to 600 V (DC). The reduction in the voltage difference results in a reduction of the electrostatic forces acting on the toner particles. As described more fully below, the present invention effectively reduces the impact of adhesion forces on the development process advantageously over a wide range of bias voltages. As a result, development efficiency and, thus, image quality tend to be enhanced.




Referring back to

FIG. 2

, the adhesion force A tends to be distributed over and directly proportional to the size of a contact area between the toner particle


22


. Thus, the larger the contact area between the toner particle


22


and the toner roller


20


, the greater the magnitude of the adhesion force A. Accordingly, the present invention effectively reduces the negative impact of adhesion forces on the development process by altering or manipulating the formulation of extraparticulate particles in a toner to reduce the contact area between the toner particles


22


and the toner support member


20


. As shown in

FIG. 4

, large and small extraparticulate particles


202


and


201


, which are mixed with toner particles such that they are well dispersed onto the surface of the toner particles,


200


in a manner known in the art, adhere to the surface of a toner particle


200


. The extraparticulate particles


202


,


201


provide much smaller contact points with the toner support member


20


, thus reducing the adhesion force between the toner particle


200


and the toner support member


20


.




Extraparticulate particles such as silica are commonly combined with toner particles in electrophotographic machines to improve the flowability and durability of the toner. The large particles of silica


202


, which are typically in the range of approximately 20-50 nm in diameter, are typically mixed with toner particles


200


. The small particles of silica


201


, which are typically in the range of 6-12 nm in diameter, are typically mixed with toner particles


200


to improve or enhance the flowability of the toner particles. The graph in

FIG. 5

shows a typical particle size distribution for silica particles with mean diameters of approximately 10 nm (curve A), 30 nm (curve B) and 40 nm (curve C).




In a preferred embodiment, a single-component toner of the present invention preferably combines extraparticulate particles with toner particles. Alternatively, particles of extraparticulates such as titanium dioxide, polymer microspheres, polymer beads, cerium oxide, zinc stearate, alumina, and the like, may be combined with the toner particles and produce the same result. The silica particles are preferably formed from fumed silica in a manner known in the art and include both large and small silica particles


202


,


201


of sizes in the ranges discussed above. The toner particles


200


may be formed from a variety of formulations known in the art. The concentration by weight of the small silica particles


201


and large silica particles


202


relative to the toner particles


200


is preferably manipulated to optimize the coverage of toner particle surface area by the silica particles. Referring to

FIG. 4

, the surface coverage of the toner particle


200


by large silica particles is preferably in a range of about 5 to 50 percent, and most preferably about 15 percent, while the surface coverage of the toner particle


200


by small silica particles


201


is preferably in a range of about 50 to 150 percent, and most preferably about 100 percent surface coverage. As shown in

FIG. 4

, a surface coverage greater than 100 percent is realizable because the small silica particles tend to adhere to both the toner particle


200


and the large silica particles


202


.




The relationship between silica concentration by weight and toner surface coverage is provided by the following equations:




where








C




m




=n




Si


ρ


Si


(


D




Si


)


3





T


(


D




T


)


3








and








S




c


=(1/π)


n




Si


(


D




Si


)


2


/(


D




T


)


2








Where the percent surface coverage (S


c


) is defined as the number of silica particles (n


Si


) times their projected area (D


Si


)


2


divided by the area of a spherical toner particle π(D


T


)


2


, as shown in FIG.


14


.




The equation,








S




c


=(


C




m


/π)(ρ


T





Si


)(


D




T




/D




Si


)






describes the surface coverage for single sized spherical particles. To take into account non-spherical particles, size distributions, and agglomerations this equation should be modified by adding an empirically obtained term beta=0.6 to the above equation. Therefore







S




c


=(β


Cm


/π)(ρ


T





Si


) (


D




T




/D




Si


)




C


m


is the calculated concentration by weight of silica particles relative to toner particles;




S


c


is the percentage of surface coverage of the toner particle by silica particles;




n


Si


is the mean number of silica particles;




ρ


Si


is the specific gravity of silica (2.2);




D


Si


is the mean diameter of the silica particles (nm);




ρ


T


is the specific gravity of a toner particle (1.1); and




D


T


is the mean diameter of the toner particles (μm).




Tables 1 below provide the corresponding values of silica concentration and surface coverage for small and large silica particles.

















TABLE 1











Toner




Silica









Diameter




Diameter




Concentration




S


c









(μ)




(nm)




(%)




(%)





























12




10




0.9




100







12




40




0.5




14







16




10




0.7




93







16




40




0.4




15















The following experiments were conducted to evaluate the development efficiency of the toner over a wide range of bias voltages. The having a mean diameter particle size of 16 μm (see

FIG. 6

for a typical diameter particle size distribution for toner) was combined with silica particles and subjected to bias voltages ranging from approximately 100 V to 800 V (DC). The experiments were conducted in accordance with the meters appearing in Table 2 below:


















TABLE 2










small





% by wt.









Exp.




silica




large silica




small




% by wt.




T/RH




Q/M






No.




size (nm)




size (nm)




silica




large silica




(° F./%)




(μC/g)











1




10




40




0.3




0.4




73/53




7.5






2




10




40




0.7




0.4




70/55




5.0






3




10




40




0.9




0.4




71/60




5.6






4




10




40




1.1




0.4




73/53




6.6






5




10




40




0.7




0.2




74/57




5.7






6




10




40




0.7




0.6




73/54




5.8














The silica particle size depicted in Table 2 corresponds to the mean diameter of the silica particles having a size distribution (see FIG.


5


).




The development efficiency, which is shown as a percentage in

FIGS. 7 through 13

, was measured as the ratio of the mass per unit area of the developed toner transferred to the surface of the photoreceptor to the combined mass per unit area of the developed toner and the residual toner carried on the toner support member following the development process. Alternatively, the development efficiency may be measured as the ratio of the mass per unit area of the developed toner transferred to the surface of the photoreceptor to the mass per unit area of the toner carried on the toner support member prior to development.




The toner support member and image-bearing surface were positioned in spaced relation in accordance with the prescribed gap discussed above and rotated at the same speed. After a prescribed voltage was applied, the mass per unit area of the toner particles that jumped the gap and adhered to the image-bearing surface was measured by aspirating a portion of toner layer from the surface of the photoreceptor, weighing the aspirated toner, measuring the aspirated area, and then dividing the weight of the aspirated toner by the aspirated area. The mass per unit area of the residual toner left on the toner support member was measured in the same fashion. The development efficiency was preferably calculated as follows:






Efficiency
=


Developed





Mass





Per





Unit





Area





(


Developed





Mass





Per





Unit





Area

+








Residual





Mass





Per





Unit





Area

)















These steps were carried out for each prescribed bias voltage for each tested toner.




The results of experiments 1 through 6 (shown in Table 2) appear in

FIGS. 7 through 12

, respectively, as graphs wherein the percentage development efficiency is plotted against the applied bias voltage. As shown in

FIG. 8

, the silica concentration of 0.4 percent by weight of large silica and 0.7 percent by weight of small silica resulted in the highest and most consistent development efficiency over a wide range of bias voltages. More particularly, this concentration resulted in over 90 percent development efficiency, i.e., development efficiency in a range of about 90 to 98 percent, when the toner support member was subjected to bias voltages ranging from 400 V (DC) to 800 V (DC).




As shown in

FIGS. 7

,


9


, and


10


, the development efficiency tends to decrease as the concentration by weight of small silica particles increases or decreases from 0.7 percent by weight. Similarly, as shown in

FIGS. 11 and 12

, the development efficiency also tends to decrease as the concentration by weight of large silica particles increases or decreases from 0.4 percent by weight.




Those of skill in the art will appreciate that by adhering to the surface coverage values for extraparticulate particles provided herein, the optimum concentration by weight of extraparticulate particles can be determined for a variety of silica and toner particle sizes (e.g., toner particles in a range of about 6 to 24 μm). For example, the calculated silica concentrations for a toner having a mean diameter particle size of 12 μm, and small and large silica having mean diameter particle sizes of 10 and 40 nm, are 0.5 percent and 0.9 percent respectively.




A toner comprising toner particles having a mean diameter particle size of 12 μm was tested in accordance with the procedure described above to determine its development efficiency across a wide range of bias voltages. The test parameters included small and large silica particles having mean diameters of 10 and 40 nm, respectively, a mean Q/M value of 5.86 μC/g, as measured by the Torrey Pines Research's aspirator, for the toner and environmental conditions of 75° F. and 52 percent RH. As shown in

FIG. 13

, the development efficiency of this toner was comparable to the development efficiency of the toner having a mean diameter particle size of


16


Am shown in FIG.


9


. The development efficiency ranges from nearly 90 percent to nearly 99 percent over a range of applied bias voltages of approximately 400 V (DC) to 800 V (DC). As indicated above, these efficiencies tend to insure the consistent production of high quality images over a wide range of bias voltages.




While the invention is susceptible to various modifications and alternative forms, a specific example thereof has been shown in the drawings and is herein described in detail. It should be understood, however, that the invention is not to be limited to the particular form disclosed, but to the contrary, the invention is to cover all modifications, equivalents, and alternatives falling within the spirit and scope of the appended claims.



Claims
  • 1. A non-contact, single-component developing system comprising:a photoreceptor capable of having an electrostatic latent image recorded thereon; and a toner support member disposed in opposing relationship with the photoreceptor with a gap therebetween defining a developing region, the toner support member adapted to carry a toner thereon to the developing region; wherein the developing region is without AC voltage and wherein the toner comprises toner mixed with large and small extraparticulate particles, a weight concentration of small extraparticlate particles resulting in a first surface coverage of the toner in a range of about 50 to 150 percent and a weight concentration of large extraparticulate particles resulting in a second surface coverage of the toner in a range of about 5 to 50 percent.
  • 2. The developing system of claim 1 wherein the toner has a mean diameter particle size by volume in a range of about 5 to 20 μm.
  • 3. The developing system of claim 1 wherein the extraparticulate is formed from silica.
  • 4. The developing system of claim 3 wherein the toner includes small silica having a mean diameter particle size in a range of about 6 nm to 14 nm.
  • 5. The developing system of claim 3 wherein the toner includes large silica having a mean diameter particle size in a range of about 20 nm to 60 nm.
  • 6. The developing system of claim 1 wherein the gap between the image bearing member and the toner support member is 75 to 250 μm.
  • 7. The developing system of claim 1 comprising a charge source electrically coupled to the photoreceptor and a light source.
  • 8. The developing system of claim 7 wherein the charge source comprises a plurality of charger elements and the light source comprises a plurality of light emitting diodes (LED), and wherein the toner support member comprises a plurality of toner supports.
  • 9. The developing system of claim 8 wherein the plurality of light sources comprises four LED arrays, the plurality of charger elements comprises four charger elements, and the plurality of toner support members comprise four toner support members.
  • 10. The developing system of claim 9 wherein the toner comprises first, second, third and fourth color toners.
  • 11. An electrophotographic machine comprising a developing system as described in claim 1, the developing system being adapted to jump develop an image without applying AC voltage.
  • 12. An electrophotographic machine comprising a plurality of developing systems as described in claim 1, each of the plurality of developing systems adapted to develop a different color toner image.
  • 13. The electrophotographic machine of claim 12 adapted to jump develop an image without applying AC voltage.
  • 14. The electrophotographic machine of claim 13 adapted to develop a composite color image comprising each different color toner image without transferring each developed color toner image to an accumulator.
  • 15. The electrophotographic machine of claim 14 adapted to develop a developed image on a photoreceptor in a single cycle of the photoreceptor, the developed image comprising toner of four distinct colors.
  • 16. The developing system of claim 1, wherein the efficiency of toner transfer from the toner support member to a latent image formed on the image bearing member is greater than 80 percent.
  • 17. A single component toner comprisinga plurality of toner particles; a first plurality of extraparticulate particles; and a second plurality of extaparticulate particles; wherein the first and second plurality of extraparticulate particles are mixed with the plurality of toner particles at a concentration of first plurality of extraparticulate particles resulting in a first surface coverage of the plurality of toner particles in a range of about 50 to 150 percent and a concentration of second plurality of extraparticulate particles resulting in a second surface coverage of the plurality of toner particles in a range of about 5 to 50 percent such that said single component toner is capable of working in a non-contact developing system having a developing region without AC voltage.
  • 18. The toner of claim 17 wherein the extraparticulate is formed from silica.
  • 19. The toner of claim 17 wherein the plurality of toner particles having a mean diameter size by volume in a range of about 5 to 20 μm.
  • 20. The developing system of claim 18 wherein the first plurality of silica particles having a mean diameter size in a range of about 6 nm to 14 nm.
  • 21. The developing system of claim 20 wherein the second plurality of silica particles having a mean diameter particle size in a range of about 20 nm to 60 nm.
  • 22. A non-contact single pass electrophotographic imaging process comprising the steps ofcreating a latent image on a surface of a photoreceptor, and developing the latent image into a developed image by forcing toner particles across a gap between a toner support member and the photoreceptor without AC voltage.
  • 23. The imaging process of claim 22 wherein the toner is comprisinga plurality of toner particles; a first plurality of extraparticulate particles; and a second plurality of extraparticulate particles; wherein the first and second plurality of extraparticulate particles are mixed with the plurality of toner particles at a concentration of first plurality of extraparticulate particles resulting in a first surface coverage of the plurality of toner particles in a range of about 50 to 150 percent and a concentration of second plurality of extraparticulate particles resulting in a second surface coverage of the plurality of toner particles in a range of about 5 to 50 percent.
  • 24. The imaging process of claim 23 wherein the extraparticulate is formed from silica.
  • 25. The imaging process of claim 24 wherein the plurality of toner particles having a mean diameter size in a range of about 5 to 20 μm.
  • 26. The imaging process of claim 25 wherein the first plurality of silica particles having a mean diameter size in a range of about 6 nm to 14 nm.
  • 27. The imaging process of claim 26 wherein the second plurality of silica particles having a mean diameter particle size in a range of about 20 nm to 60 nm.
US Referenced Citations (33)
Number Name Date Kind
3166432 Gundlach Jan 1965 A
3627682 Hall, Jr. et al. Dec 1971 A
3720617 Chatterji et al. Mar 1973 A
3939087 Vijayendran et al. Feb 1976 A
4067295 Parker et al. Jan 1978 A
4233382 Edwards et al. Nov 1980 A
4296192 Gruber et al. Oct 1981 A
4608328 Schwarz et al. Aug 1986 A
4618556 Takenouchi Oct 1986 A
4680245 Suematsu et al. Jul 1987 A
4699865 Mitsuhashi Oct 1987 A
4845004 Kobayashi Jul 1989 A
4906548 Uchide et al. Mar 1990 A
5041351 Kitamori et al. Aug 1991 A
5066558 Hikake et al. Nov 1991 A
5143811 Itakura et al. Sep 1992 A
5212037 Julien et al. May 1993 A
5215845 Yusa et al. Jun 1993 A
5307122 Ohno et al. Apr 1994 A
5312711 Tavernier et al. May 1994 A
5534981 Ohno et al. Jul 1996 A
5547796 Kohtaki et al. Aug 1996 A
5620823 Kambayashi et al. Apr 1997 A
5633108 Christy et al. May 1997 A
5691097 Bortfeldt Nov 1997 A
5804351 Takano et al. Sep 1998 A
5925446 Matsuda et al. Jul 1999 A
6025106 Azuma et al. Feb 2000 A
6087056 Toyoshima et al. Jul 2000 A
6117607 Shimizu et al. Sep 2000 A
6287739 Kawakami et al. Sep 2001 B1
6298211 Stockman et al. Oct 2001 B1
6338929 Hagi et al. Jan 2002 B1