A variety of articles are at least partially formed from textiles. As examples, apparel (e.g., shirts, pants, socks, footwear, jackets and other outerwear, briefs and other undergarments, hats and other headwear), containers (e.g., backpacks, bags), and upholstery for furniture (e.g., chairs, couches, car seats) are often formed from various textile elements that are joined through stitching or adhesive bonding. Textiles may also be utilized in bed coverings (e.g., sheets, blankets), table coverings, towels, flags, tents, sails, and parachutes. Textiles utilized for industrial purposes are commonly referred to as technical textiles and may include structures for automotive and aerospace applications, filter materials, medical textiles (e.g. bandages, swabs, implants), geotextiles for reinforcing embankments, agrotextiles for crop protection, and industrial apparel that protects or insulates against heat and radiation. Accordingly, textiles may be incorporated into a variety of articles for both personal and industrial purposes.
Textiles may be defined as any manufacture from fibers, filaments, or yarns having a generally two-dimensional structure (i.e., a length and a width that are substantially greater than a thickness). In general, textiles may be classified as non-woven textiles or mechanically-manipulated textiles. Non-woven textiles are webs or mats of filaments that are bonded, fused, interlocked, or otherwise joined. As an example, a non-woven textile may be formed by randomly depositing a plurality of polymer filaments upon a surface, such as a moving conveyor. Mechanically-manipulated textiles are often formed by weaving or interlooping (e.g., knitting) a yarn or a plurality of yarns, usually through a mechanical process involving looms or knitting machines. Whereas woven textiles include yarns that cross each other at right angles (i.e., warp and weft yarns), knitted textiles include one or more yarns that form a plurality of intermeshed loops arranged in courses and wales.
Although some products are formed from one type of textile, many products are formed from two or more types of textiles in order to impart different properties to different areas. As an example, shoulder and elbow areas of a shirt may be formed from a textile that imparts durability (e.g., abrasion-resistance) and stretch-resistance, whereas other areas may be formed from a textile that imparts breathability, comfort, stretch, and moisture-absorption. As another example, an upper for an article of footwear may have a structure that includes numerous layers formed from various types of textiles and other materials (e.g., polymer foam, leather, synthetic leather), and some of the layers may also have areas formed from different types of textiles to impart different properties. As yet another example, straps of a backpack may be formed from non-stretch textile elements, lower areas of a backpack may be formed from durable and water-resistant textile elements, and a remainder of the backpack may be formed from lightweight and compliant textile elements. Accordingly, many products may incorporate various types of textiles in order to impart different properties to different portions of the products.
In order to impart the different properties to different areas of a product, textile elements formed from the materials must be cut to desired shapes and then joined together, usually with stitching or adhesive bonding. As the number and types of textile elements incorporated into a product increases, the time and expense associated with transporting, stocking, cutting, and joining the textile elements may also increase. Waste material from cutting and stitching processes also accumulates to a greater degree as the number and types of textile elements incorporated into a product increases. Moreover, products with a greater number of textile elements and other materials may be more difficult to recycle than products formed from few elements and materials. By decreasing the number of elements and materials utilized in a product, therefore, waste may be decreased while increasing the manufacturing efficiency and recyclability.
A yarn may include a plurality of substantially aligned filaments, with at least ninety-five percent of a material of the filaments being a thermoplastic polymer material.
A thread may include a first yarn and a second yarn. The first yarn includes a plurality of substantially aligned filaments, with at least ninety-five percent of a material of the filaments being a thermoplastic polymer material. The second yarn is twisted with the first yarn.
A woven textile may include a warp strand and a weft strand. The warp strand extends in a first direction and includes a plurality of substantially aligned filaments, with at least ninety-five percent of a material of the filaments being a thermoplastic polymer material. The weft strand extends in a second direction that is substantially perpendicular to the first direction.
A knitted textile may include at least one strand that forms a plurality of interlocked loops arranged in courses and wales. The strand includes a plurality of substantially aligned filaments, with at least ninety-five percent of a material of the filaments being a thermoplastic polymer material.
An article may include a first material element, a second material element, and a seam. The first material element is at least partially formed from a first thermoplastic polymer material, and the first material element is one of a woven textile and a knitted textile. At the seam, a strand extends through each of the first material element and the second material element, the strand being at least partially formed from a second thermoplastic polymer material. The first material element is thermal bonded to the second material element with the first thermoplastic polymer material at the seam. Additionally, the strand is thermal bonded to the first material element and the second material element with the second thermoplastic polymer material at the seam.
A method of joining includes stitching a pair of textile elements together with a strand to form a seam. The textile elements and the strand are heated and compressed at the seam to (a) form a thermal bond between the textile elements and (b) melt the strand.
An article of apparel includes a plurality of textile elements joined to each other at seams to form a structure for receiving a part of a wearer. The textile elements include strands that have a plurality of substantially aligned filaments formed from a thermoplastic polymer material.
The advantages and features of novelty characterizing aspects of the invention are pointed out with particularity in the appended claims. To gain an improved understanding of the advantages and features of novelty, however, reference may be made to the following descriptive matter and accompanying figures that describe and illustrate various configurations and concepts related to the invention.
The foregoing Summary and the following Detailed Description will be better understood when read in conjunction with the accompanying figures.
The following discussion and accompanying figures disclose various yarns, threads, and textiles formed from thermoplastic polymer materials. Although the yarns, threads, and textiles are disclosed below as being incorporated into various articles of apparel (e.g., shirts and footwear) for purposes of example, the yarns, threads, and textiles may also be incorporated into a variety of other articles. For example, the yarns, threads, and textiles may be utilized in other types of apparel, containers, and upholstery for furniture. The yarns, threads, and textiles may also be utilized in bed coverings, table coverings, towels, flags, tents, sails, and parachutes. Various configurations of the yarns, threads, and textiles may also be utilized for industrial purposes, as in automotive and aerospace applications, filter materials, medical textiles, geotextiles, agrotextiles, and industrial apparel. Accordingly, the yarns, threads, and textiles may be utilized in a variety of articles for both personal and industrial purposes.
A section of a yarn 100 is depicted in
Yarn 100 includes a plurality of filaments 101 that are bundled or otherwise gathered to form a generally thin and elongate structure. The number of filaments 101 that are incorporated into yarn 100 may vary significantly and may range between two and three-hundred or more. Fibers are often defined, in textile terminology, as having a relatively short length that ranges from one millimeter to a few centimeters or more, whereas filaments are often defined as having a longer length than fibers or even an indeterminate length. As utilized within the present document, the term “filament” or variants thereof is intended to encompass lengths of both fibers and filaments from the textile terminology definitions. Accordingly, filaments 101 or other filaments referred to herein may generally have any length. As an example, therefore, filaments 101 may have a length that ranges from one millimeter to hundreds of meters or more. Individual filaments 101 may also have lengths that extend through an entire length of yarn 100.
Filaments 101 are substantially aligned in yarn 100. As utilized herein, the term “substantially aligned” is intended to convey that filaments 100 generally extend in a common direction, which corresponds with a longitudinal axis of yarn 100. When substantially aligned, some of filaments 101 or portions of filaments 101 may be parallel with each other, but other filaments 101 or other portions of filaments 101 may cross each other or may extend in directions that are offset by a few degrees (e.g., offset in a range of zero to seven degrees) when yarn 100 is tensioned, stretched, or otherwise arranged to have a linear or straight structure.
Although filaments 101 are substantially aligned, yarn 100 is depicted as exhibiting twist, thereby imparting a rotational aspect to various filaments 101. More particularly, filaments 101 may be twisted around each other such that some filaments 101 or sections of filaments 101 have a helical structure that repeatedly wraps around the longitudinal axis of yarn 100. Although sections of filaments 101 may be generally straight, other sections may have a spiral or helical configuration that imparts the twist. In some configurations, portions of filaments 100 located in a central area of yarn 100 may be generally straight, whereas portions of filaments 100 located closer to a periphery or exterior of yarn 100 may have the spiral or helical configuration. Either an S-twist or a Z-twist may be utilized in yarn 100. An advantage of the twist is that filaments 101 are bundled more closely than in non-twist yarns to effectively reduce the size of spaces between individual filaments 101. As such filaments 101 lay against and contact each other, as depicted in
Filaments 101 are primarily formed from a thermoplastic polymer material. In general, a thermoplastic polymer material softens or melts when heated and returns to a solid state when cooled. More particularly, a thermoplastic polymer material transitions from a solid state to (a) a softened state when heated to a glass transition temperature of the thermoplastic polymer material and (b) a generally liquid state when heated to a melting temperature of the thermoplastic polymer material. Then, when sufficiently cooled, the thermoplastic polymer material transitions from the softened or liquid state to the solid state. As such, the thermoplastic polymer material may be softened or melted, molded, cooled, re-softened or re-melted, re-molded, and cooled again through multiple cycles. When heated to at least the glass transition temperature, thermoplastic polymer materials may also be welded, fused, or thermal bonded, as described in greater detail below, to join an element formed from the thermoplastic polymer material to another object, item, or element. In contrast with thermoplastic polymer materials, many thermoset polymer materials do not melt when heated, simply degrading or burning instead.
Although a wide range of thermoplastic polymer materials may be utilized for filaments 101, examples of suitable thermoplastic polymer materials include thermoplastic polyurethane, polyamide, polyester, polypropylene, and polyolefin. Although filaments 101 may be formed from any of the thermoplastic polymer materials mentioned above, utilizing thermoplastic polyurethane imparts various advantages. For example, various formulations of thermoplastic polyurethane are elastomeric and stretch over one-hundred percent, while exhibiting relatively high stability or tensile strength. In comparison with some other thermoplastic polymer materials, thermoplastic polyurethane readily forms thermal bonds with other elements, as discussed in greater detail below. Also, thermoplastic polyurethane may form foam materials and may be recycled to form a variety of products.
In many configurations of yarn 100, each of filaments 101 are entirely or substantially formed from one or more thermoplastic polymer materials. That is, at least ninety-five percent, ninety-nine percent, or one-hundred percent of a material of filaments 101 is a thermoplastic polymer material. Advantages of substantially forming filaments 101 from a thermoplastic polymer material are uniform properties, the ability to form thermal bonds, efficient manufacture, elastomeric stretch, and relatively high stability or tensile strength Although a single thermoplastic polymer material may be utilized, individual filaments 101 may be formed from multiple thermoplastic polymer materials. As an example, an individual filament 101 may have a sheath-core configuration, wherein an exterior sheath of the individual filament 101 is formed from a first thermoplastic polymer material, and an interior core of the individual filament 101 is formed from a second thermoplastic polymer material. As a similar example, an individual filament 101 may have a bi-component configuration, wherein one half of the individual filament 101 is formed from a first thermoplastic polymer material, and an opposite half of the individual filament 101 is formed from a second thermoplastic polymer material. Although each of filaments 101 may be formed from a common thermoplastic polymer material, different filaments 101 may also be formed from different materials. As an example, some of filaments 101 may be formed from a first type of thermoplastic polymer material, whereas other filaments 101 may be formed from a second type of thermoplastic polymer material.
The thermoplastic polymer material of filaments 101 may be selected to have various stretch properties, and the material may be considered elastomeric. Depending upon the specific properties desired for yarn 100, filaments 101 may stretch between ten percent to more than eight-hundred percent prior to tensile failure. As a related matter, the thermoplastic polymer material utilized for filaments 101 may be selected to have various recovery properties. That is, yarn 100 or filaments 101 may be formed to return to an original shape after being stretched. Many products that incorporate yarn 100, such as textiles and articles of apparel formed from the textiles, may benefit from properties that allow yarn 100 to return or otherwise recover to an original shape after being stretched by one-hundred percent or more. Although many thermoplastic polymer materials exhibit stretch and recovery properties, thermoplastic polyurethane exhibits suitable stretch and recovery properties for various textiles and articles of apparel.
The weight of yarn 100 may vary significantly depending upon the thicknesses of individual filaments 101, the number of filaments 101, and the specific material selected for filaments 101, for example. In general, weight is measured by the unit tex, which is the weight in grams of a kilometer of yarn. Yarn 100 may range from fifty to one-thousand denier or more.
A variety of conventional processes may be utilized to manufacture yarn 100. In general, a manufacturing process for yarn 100 includes (a) extruding or otherwise forming a plurality of filaments 101 from a thermoplastic polymer material and (b) collecting or bundling filaments 101. Once bundled, filaments 101 may be twisted. Depending upon the specific characteristics desired, yarn 100 may also be subjected to an air texturing operation or other post-processing operations. Fusing processes, as discussed below, may also be performed to form thermal bonds between adjacent filaments 101.
A thread 200 is depicted in
Given that two yarns 201 are twisted together, this configuration of thread 200 may be considered a two-ply thread. In other configurations, any number of yarns 201 or other yarns may be incorporated into thread 200. As an example of a three-ply threads,
As with yarn 100, the weight of thread 200 may vary significantly depending upon the thicknesses of individual filaments 202, the number of filaments 202 in each yarn 201, the material selected for filaments 202, and the number of yarns 100, for example. In general, weight is measured by the unit denier, which is the weight in grams of nine-thousand meters of thread. As examples, each of yarns 201 within thread 200 may range from 50 denier to 400 denier or more.
Various types of textiles may be formed from one or more strands, including either of yarn 100 and thread 200. For purposes of the following discussion, the term “strand” is defined as a generally elongate element having a length that is substantially greater than a width and thickness. Examples of various types of strands include filaments, yarns, threads, cables, cords, and ropes. As such, either of yarn 100 and thread 200 may be a strand that is incorporated into a textile.
As a first example of a textile, a woven textile 300 is depicted in
Although woven textile 300 is depicted as being formed from strands 301 and 302, one or more additional strands may be incorporated into the structure of woven textile 300. For example, different warp strands, weft strands, or portions of these strands may be formed from various types of strands having diverse materials, colors, or properties. Any of strands 301 and 302 may have the configuration of a filament, yarn, thread, cable, cord, or rope. Either or both of strands 301 and 302 may also exhibit the general configuration of yarn 100 or thread 200 discussed above. Strands 301 and 302 may include, therefore, a plurality of substantially aligned filaments that are substantially formed from a thermoplastic polymer material. As such, at least ninety-five percent, ninety-nine percent, or one-hundred percent of a material of the filaments or other material forming strands 301 and 302 may be a thermoplastic polymer material, such as thermoplastic polyurethane. When strands 301 and 302 are formed as a filament, cable, cord, or rope, such strands may also be substantially formed from a thermoplastic polymer material.
As a second example of a textile, a knitted textile 400 is depicted in
Although knitted textile 400 is depicted as being formed from strand 401, multiple strands may be incorporated into the structure of knitted textile 400. For example, different loops, different courses, different portions of a single course, different wales, and different portions of a single wale may be formed from strands having diverse materials, colors, and properties.
Strand 401 may have the configuration of a filament, yarn, thread, cable, cord, or rope. Strand 401 or other strands incorporated into knitted textile 400 may also exhibit the general configuration of yarn 100 or thread 200 discussed above. Strand 401 may include, therefore, a plurality of substantially aligned filaments that are substantially formed from a thermoplastic polymer material. As such, at least ninety-five percent, ninety-nine percent, or one-hundred percent of a material of the filaments or other material forming strand 401 may be a thermoplastic polymer material, such as thermoplastic polyurethane. When strand 401 is formed as a filament, cable, cord, or rope, such strands may also be substantially formed from a thermoplastic polymer material.
As a variation, knitted textile 400 may also incorporate an inlaid strand 402, as depicted in
Woven textile 300 and knitted textile 400 provide examples of textile structures that may incorporate yarn 100, thread 200, or other strands formed from thermoplastic polymer materials. A variety of other types of textiles may also incorporate similar strands. For example, textiles formed through crocheting or intertwining and twisting may have strands with a plurality of substantially aligned filaments that are substantially formed from a thermoplastic polymer material. Similarly, mesh textiles, spacer mesh textiles, jersey textiles, fleece textiles, and terry loop textiles may have strands with a plurality of substantially aligned filaments that are substantially formed from a thermoplastic polymer material.
Thermal bonding is an advantage of thermoplastic polymer materials not generally present in yarns, threads, and textiles, for example, formed from natural materials (e.g., cotton, silk) and thermoset polymer materials. As discussed above, a thermoplastic polymer material softens or melts when heated and returns to a solid state when cooled. In addition to permitting molding or shaping, an element formed from a thermoplastic polymer material may also be welded, fused, or thermal bonded to another object, item, or element. That is, the thermoplastic polymer material may be used to join two elements together through thermal bonding. As utilized herein, the term “thermal bonding” or variants thereof is defined as a securing technique between two elements that involves a softening or melting of a thermoplastic polymer material within at least one of the elements such that the elements are secured to each other when cooled. Similarly, the term “thermal bond” or variants thereof is defined as the bond, link, or structure that joins two elements through a process that involves a softening or melting of a thermoplastic polymer material within at least one of the elements such that the elements are secured to each other when cooled.
Examples of thermal bonding include (a) the melting or softening of two elements incorporating thermoplastic polymer materials such that the thermoplastic polymer materials intermingle with each other (e.g., diffuse across a boundary layer between the thermoplastic polymer materials) and are secured together when cooled; (b) the melting or softening of an element incorporating a thermoplastic polymer material such that the thermoplastic polymer material extends into or infiltrates the structure of a strand (e.g., extends around or bonds with filaments in the strand) to secure the elements together when cooled; (c) the melting or softening of an element incorporating a thermoplastic polymer material such that the thermoplastic polymer material extends into or infiltrates the structure of a textile element (e.g., extends around or bonds with filaments or fibers in the textile element) to secure the elements together when cooled; and (d) the melting or softening of an element incorporating a thermoplastic polymer material such that the thermoplastic polymer material extends into or infiltrates crevices or cavities formed in another element (e.g., polymer foam or sheet, plate, structural device) to secure the elements together when cooled. Thermal bonding may occur when only one element includes a thermoplastic polymer material or when both elements include thermoplastic polymer materials. In general, therefore, thermal bonding involves directly bonding elements to each other with heat. In some situations, however, stitching or adhesives may be utilized to supplement the thermal bond or the joining of elements through thermal bonding.
One of the factors affecting the degree of fusing is temperature. As noted above, a thermoplastic polymer material transitions from a solid state to (a) a softened state when heated to a glass transition temperature of the thermoplastic polymer material and (b) a generally liquid state when heated to a melting temperature of the thermoplastic polymer material. Thermal bonding may occur when the thermoplastic polymer material is heated to the glass transition temperature. Greater degrees of thermal bonding, as discussed below, may occur at elevated temperatures approaching or exceeding the melting temperature.
Given that yarn 100, thread 200, woven textile 300, and knitted textile 400 incorporate thermoplastic polymer materials, these elements may be subjected to thermal bonding processes. As an example,
Based upon comparisons between
Another example of thermal bonding is depicted in
A further example of thermal bonding is depicted in
Woven textile 300 may also exhibit thermal bonding in fused region 303 when each of strands 301 and 302 have different configurations or are formed from different materials. When, for example, warp strand 301 is a filament formed from a thermoplastic polymer material and weft strand 302 is a thread formed from a thermoset polymer material, the thermoplastic polymer material in warp strand 301 may infiltrate the structure of the thread forming weft strand 302 by extending around filaments in the thread to secure strands 301 and 302 together when cooled. As another example, when warp strand 301 is a cord formed from a thermoplastic polymer material and weft strand 302 is a filament formed from a thermoset polymer material, the thermoplastic polymer material in warp strand 301 may infiltrates crevices or cavities in the filament forming weft strand 302 to secure strands 301 and 302 together when cooled.
The degree to which strands 301 and 302 melt or transition from a filamentous to a non-filamentous state when forming the thermal bonds may also vary. Referring again to
A variety of factors relating to the configuration of woven textile 300 and the processes by which fused regions 303 and 304 are formed determine the degree to which strands 301 and 302 are thermal bonded. As examples, factors that determine the degree of fusing include (a) the particular thermoplastic polymer material forming strands 301 and 302, (b) the temperature (e.g., glass transition and melting temperatures) that fused regions 303 and 304 are exposed to, (c) the pressure that fused regions 303 and 304 are exposed to, and (d) the time at which fused regions 303 and 304 are exposed to the elevated temperature and/or pressure. By varying these factors, the degree of fusing or thermal bonding that results within fused regions 303 and 304 may also be varied. Similar factors also apply to the thermal bonding within yarn 100 and thread 200.
Another example of thermal bonding is depicted in
Knitted textile 400 may also exhibit thermal bonding in fused region 403 when strand 401 and one or more additional strands (e.g., inlaid strand 402) are incorporated into knitted textile 400. In this configuration, thermal bonding may be similar to the various examples provided above for different types of strands 301 and 302 in fused region 303 of woven textile 300. In effect, thermal bonding may join strands within fused region 403 that have different configurations or are formed from different materials.
The degree to which strand 401 melts or transitions from a filamentous to a non-filamentous state when forming the thermal bonds may also vary. Referring again to
As with woven textile 300, factors that determine the degree of fusing in knitted textile 400 include (a) the particular thermoplastic polymer material forming strand 401, (b) the temperature (e.g., glass transition and melting temperatures) that fused regions 403 and 404 are exposed to, (c) the pressure that fused regions 403 and 404 are exposed to, and (d) the time at which fused regions 403 and 404 are exposed to the elevated temperature and/or pressure. By varying these factors, the degree of fusing or thermal bonding that results within fused regions 403 and 404 may also be varied.
Based upon the above discussion, yarn 100, thread 200, other strands, textiles 300 and 400, and other textiles may exhibit fusing or may form thermal bonds due to the presence of a thermoplastic polymer material. As presented in the various examples, filaments 101 within yarn 100 may form thermal bonds with each other to various degrees, and filaments 202 or yarns 201 within thread 200 may form thermal bonds with each other to various degrees. Moreover, woven textile 300 may have a fused region 303 or 304 and a remaining unfused region, with warp strand 301 and weft strand 302 being thermal bonded to each other in fused regions 303 and 304 and being unbonded to each other in the unfused region. Similarly, knitted textile 400 may include a fused region 403 or 404 and a remaining unfused region, with a section of strand 401 being thermal bonded to a different section of strand 401 in fused regions 403 and 404. Although fused regions 303, 304, 403, and 404 are shown as being a relatively small part of textiles 300 and 400, a larger part or substantially all of textiles 300 and 400 may exhibit thermal bonding.
The properties of fused regions 303 and 304 may be different than the properties of unfused regions in woven textile 300. In configurations where woven textile 300 has multiple fused regions, the properties of one of the fused regions may be different than the properties of another of the fused regions. For example,
In manufacturing woven textile 300 and forming fused regions 303 and 304, specific properties may be applied to woven textile 300 in the areas of fused regions 303 and 304. More particularly, the shapes of fused regions 303 and 304, positions of fused regions 303 and 304, sizes of fused regions 303 and 304, degree to which strands 301 and 302 are fused within fused regions 303 and 304, and other aspects of woven textile 300 may be varied to impart specific properties to specific areas of woven textile 300. As an example, fused regions 303 and 304 have different shapes (e.g., square and circular) in
Examples of properties that may be varied through the addition or the configuration of fused regions 303 and 304 include permeability, durability, and stretch-resistance. By forming one of fused regions 303 and 304 in a particular area of woven textile 400, the permeability of that area generally decreases, whereas both durability and stretch-resistance generally increases. As discussed in greater detail below, the degree to which strands 301 and 302 are fused to each other has a significant effect upon the change in permeability, durability, and stretch-resistance. Other factors that may affect permeability, durability, and stretch-resistance include the shapes, positions, and sizes of fused regions 303 and 304, as well as the specific thermoplastic polymer material forming strands 301 and 302.
Permeability generally relates to ability of air, water, and other fluids (whether gaseous or liquid) to pass through or otherwise permeate woven textile 300. Depending upon the degree to which strands 301 and 302 are fused to each other, the permeability may vary significantly. In general, the permeability is highest in areas of woven textile 300 where strands 301 and 302 are fused the least, and the permeability is lowest in areas of woven textile 300 where strands 301 and 302 are fused the most. As such, the permeability may vary along a spectrum depending upon the degree to which strands 301 and 302 are fused to each other. Areas of woven textile 300 that are separate from fused regions 303 and 304 (i.e., unfused areas of woven textile 300) generally exhibit a relatively high permeability. Due to the openings between strands 301 and 302, fused region 303 may also exhibit a relatively high permeability, but the permeability is generally less than in areas separate from fused regions 303 and 304. Due to the non-filamentous state that effectively forms a solid polymer sheet, fused region 304 exhibits a relatively low permeability.
Durability generally relates to the ability of woven textile 300 to remain intact, cohesive, or otherwise undamaged, and may include resistances to wear, abrasion, and degradation from chemicals and light. Depending upon the degree to which strands 301 and 302 are fused to each other, the durability may vary significantly. Although the durability of any portion of woven textile 300 may be considered high, the durability is lowest in areas of woven textile 300 where strands 301 and 302 are fused the least, and the durability is highest in areas of woven textile 300 where strands 301 and 302 are fused the most. As such, the durability may vary along a spectrum depending upon the degree to which strands 301 and 302 are fused to each other. Moreover, fused region 303 may have lesser durability than fused region 304. Other factors that may affect the general durability of fused regions 303 and 304 and other areas of woven textile 300 include the initial thickness and density of woven textile 300 and the type of thermoplastic polymer material forming strands 301 and 302.
Stretch-resistance generally relates to the ability of woven textile 300 to resist stretching when subjected to a textile force. As with permeability and durability, the stretch-resistance of woven textile 300 may vary significantly depending upon the degree to which strands 301 and 302 are fused to each other. Although the stretch-resistance of any portion of woven textile 300 may be considered high, the stretch-resistance is lowest in areas of woven textile 300 where strands 301 and 302 are fused the least, and the stretch-resistance is highest in areas of woven textile 300 where strands 301 and 302 are fused the most. The thermoplastic polymer material or other materials utilized for woven textile 300 may be considered elastomeric or may stretch at least one-hundred percent prior to tensile failure. Although the stretch-resistance of woven textile 300 may be greater in areas where strands 301 and 302 are fused the most, fused region 304 may still be elastomeric or may stretch at least one-hundred percent prior to tensile failure. Other factors that may affect the general stretch properties of fused regions 303 and 304 and other areas of woven textile 300 include the initial thickness and density of woven textile 300 and the type of thermoplastic polymer material forming strands 301 and 302.
As discussed in greater detail below, woven textile 300 may be incorporated into a variety of products, including various articles of apparel (e.g., shirts, footwear). Taking a shirt as an example, woven textile 300 may form a majority of the shirt, including a torso region and two arm regions. Given that moisture may accumulate within the shirt from perspiration, a majority of the shirt may be formed from portions of woven textile 300 that do not include fused regions 303 and 304 in order to provide a relatively high permeability. Given that elbow areas of the shirt may be subjected to relatively high abrasion as the shirt is worn, some of fused regions 303 and 304 may be located in the elbow areas to impart greater durability. Additionally, given that the neck opening may be stretched as the shirt is put on an individual and taken off the individual, one of fused regions 303 and 304 may be located around the neck opening to impart greater stretch-resistance. Accordingly, one material (i.e., woven textile 300) may be used throughout the shirt, but by fusing different areas to different degrees, the properties may be advantageously-varied in different areas of the shirt.
The above discussion focused primarily on the properties of permeability, durability, and stretch-resistance. A variety of other properties may also be varied through the addition or the configuration of fused regions 303 and 304. For example, the overall density of woven textile 300 may be increased as the degree of fusing increases. The transparency of woven textile 300 may also be increased as the degree of fusing increases. Depending upon various factors, the saturation of a color of woven textile 300 may also increase as the degree of fusing increases. Fused regions 303 and 304 may also contrast visually with other areas. The overall thickness of woven textile 300 may decrease as the degree of fusing increases. The degree to which woven textile 300 recovers after being stretched, the overall flexibility of woven textile 300, and resistance to various modes of failure may also vary depending upon the degree of fusing. Accordingly, a variety of properties may be varied by forming fused regions similar to fused regions 303 and 304.
Although the above discussion focused upon woven textile 300, similar concepts apply to knitted textile 400. As such, the properties of fused regions 403 and 404 may be different than the properties of unfused regions in knitted textile 400. In configurations where knitted textile 400 has multiple fused regions 403 and 404, the properties of fused region 403 may be different than the properties of one of fused region 404. Moreover, the properties of one of fused regions 403 may be different than the properties of another of fused regions 403. In addition to varying the degree of fusing, the shapes of multiple fused regions 403 and 404 and other aspects of knitted textile 400 may be varied to impart specific properties to specific areas. Accordingly, knitted textile 400 may be engineered, designed, or otherwise structured to have particular properties in different areas, including the properties of permeability, durability, and stretch-resistance.
A composite element 500 is depicted in
In order to facilitate thermal bonding, at least one of components 501 and 502 includes a thermoplastic polymer material. Either or both of components 501 and 502 may be woven textile 300, knitted textile 400, other textiles that incorporate yarn 100 or thread 200, or other textiles that incorporate a thermoplastic polymer material. Moreover, one of components 501 and 502 may be another textile (e.g., knitted, woven, non-woven), an element of polymer foam, a polymer sheet, or a plate. As examples, (a) each of components 501 and 502 may be woven textile 300, (b) each of components 501 and 502 may be knitted textile 400, (c) first component 501 may be woven textile 300 and second component 502 may be knitted textile 400, (d) first component 501 may be woven textile 300 and second component 502 may be another textile formed from cotton, silk, thermoset polymer filaments, or other materials that do not include a thermoplastic polymer material, (e) first component 501 may be knitted textile 400 and second component 502 may be an element of polymer foam formed from either thermoplastic or thermoset polymer material, (f) first component 501 may be woven textile 300 and second component 502 may be a polymer sheet formed from either thermoplastic or thermoset polymer material, or (g) first component 501 may be knitted textile 400 and second component 502 may be a plate formed from metal, wood, or a rigid polymer formed from either thermoplastic or thermoset polymer material.
As a further example, first component 501 may be woven textile 300. If second component 502 is another textile that absorbs or wicks water, then the combination of woven textile 300 and second component 502 may be suitable for articles of apparel utilized during athletic activities where an individual wearing the apparel is likely to perspire. If second component 502 is a compressible material, such as an element of polymer foam, then the combination of woven textile 300 and second component 502 may be suitable for articles of apparel where cushioning (i.e., attenuation of impact forces) is advantageous, such as padding for athletic activities that may involve contact or impact with other athletes, equipment, or the ground. If second component 502 is a polymer sheet or plate, then the combination of woven textile 300 and second component 502 may be suitable for articles of apparel that impart protection from acute impacts. Similar combinations may be formed where first component 501 is knitted textile 400. Accordingly, a variety of materials or other components maybe joined through thermal bonding to either of textiles 300 and 400 form composite elements with additional properties.
A general manufacturing process for forming composite element 500 will now be discussed with reference to
Although the general process discussed above may be utilized to form composite element 500, other methods may also be utilized. Rather than components 501 and 502 through conduction, other methods that include radio frequency heating, ultrasonic heating, radiant heating, laser heating, or chemical heating may be utilized. In some processes, radiant heating may utilize to raise the temperature of at least one of components 501 and 502 prior to being compressed between platens 11. An advantage of utilizing radiant heating to elevate the temperature of only the surfaces forming the thermal bond is that the thermoplastic polymer material within other portions of components 501 and 502 may not heated significantly. In some processes, stitching or adhesives may also be utilized between components 501 and 502 to supplement the thermal bond.
Using the process discussed above, the thermoplastic polymer material in either of components 501 and 502 may be utilized to secure components 501 and 502 to each other. A thermoplastic polymer material melts when heated and returns to a solid state when cooled sufficiently. Based upon this property of thermoplastic polymer materials, thermal bonding processes may be utilized to form a thermal bond that joins components 501 and 502 to each other. The configuration of the thermal bond at least partially depends upon the materials and structure of components 501 and 502. As a first example, each of components 501 and 502 may be woven textile 300. Upon heating, the thermoplastic polymer material from each element of woven textile 300 may intermingle with each other to secure components 501 and 502 to each other when cooled. Similar processes may be utilized when each of components 501 and 502 are knitted textile 400 or when first component 501 is woven textile 300 and second component 502 is knitted textile 400. As a second example, first component 501 may be woven textile 300 and second component 502 may be another textile formed from cotton, silk, or thermoset polymer filaments. Upon heating, the thermoplastic polymer material of woven textile 300 may extend around or bond with filaments in the other textile to secure components 501 and 502 to each other when cooled. As a third example, first component 501 may be knitted textile 400 and second component 502 may be an element of polymer foam (or a polymer sheet or plate) formed from a thermoplastic polymer material. Upon heating, the thermoplastic polymer materials of knitted textile 400 and the polymer foam may intermingle with each other to secure components 501 and 502 to each other when cooled. If, however, the polymer foam has a glass transition temperature that is higher than the thermoplastic polymer material of knitted textile 400, then the thermoplastic polymer material of knitted textile 400 may extend into the structure, crevices, or cavities of the polymer foam to secure components 501 and 502 to each other when cooled. As a fourth example, first component 501 may be knitted textile 400 and second component 502 may be an element of polymer foam (or a polymer sheet or plate) formed from a thermoset polymer material. Upon heating, the thermoplastic polymer material of knitted textile 400 may extend into the structure, crevices, or cavities of the polymer foam to secure components 501 and 502 to each other when cooled. Accordingly, a thermal bond may be utilized to join components 501 and 502 even when components 501 and 502 have a variety of structures or are formed from a diverse range of materials.
In order to impart varying properties to composite element 500, either of components 501 and 502 may include various fused regions, similar to fused regions 303, 304, 403, and 404. Referring to
When incorporated into products, such as apparel, textile elements are often joined at various seams. Although stitching and adhesive bonding may be utilized to form a seam between the textile elements, the seam may also be formed through a thermal bonding process when at least one of the textile elements includes a thermoplastic polymer material. That is, a thermal bond may be utilized to form the seam in products that incorporate woven textile 300, knitted textile 400, or other textiles that incorporate a thermoplastic polymer material.
A seam element 600 is depicted in
In order to facilitate thermal bonding at seam 603, at least one of components 601 and 602 includes a thermoplastic polymer material. Either or both of components 601 and 602 may be woven textile 300, knitted textile 400, other textiles that incorporate yarn 100 or thread 200, or other textiles that incorporate a thermoplastic polymer material. Moreover, one of components 601 and 602 may be another textile (e.g., knitted, woven, non-woven), an element of polymer foam, or a polymer sheet, for example. As examples, (a) each of components 601 and 602 may be woven textile 300, (b) each of components 601 and 602 may be knitted textile 400, (c) first component 601 may be woven textile 300 and second component 602 may be knitted textile 400, (d) first component 601 may be woven textile 300 and second component 602 may be another textile formed from cotton, silk, thermoset polymer filaments, or other materials that do not include a thermoplastic polymer material, (e) first component 601 may be knitted textile 400 and second component 602 may be an element of polymer foam formed from either thermoplastic or thermoset polymer material, or (f) first component 601 may be woven textile 300 and second component 602 may be a polymer sheet formed from either thermoplastic or thermoset polymer material.
A general manufacturing process for forming seam 603 will now be discussed with reference to
As with the formation of fused regions 303, 304, 403, and 404, the formation of seam 603 involves softening or melting the thermoplastic polymer material in one or both of components 601 and 602. Depending upon the temperature and pressure applied to the edge areas of components 601 and 602, as well as the time that the edge areas are heated and compressed, for example, the degree to which the thermoplastic polymer material in components 601 and 602 softens or melts may vary significantly. As such, the thermal bond at seam 603 may range from (a) a state where filaments or strands in components 601 and 602 remain separate and identifiable, as in fused regions 303 and 403, to (b) a state where filaments or strands in components 601 and 602 form a larger mass of thermoplastic polymer material, as in fused regions 304 and 404.
Using the process discussed above, the thermoplastic polymer material in either of components 601 and 602 may be utilized to secure components 601 and 602 to each other at seam 603. The configuration of the thermal bond at seam 603 at least partially depends upon the materials and structure of components 601 and 602. As a first example, each of components 601 and 602 may be woven textile 300. Upon heating, the thermoplastic polymer material from each element of woven textile 300 may intermingle with each other to secure components 601 and 602 to each other when cooled. Similar processes may be utilized when each of components 601 and 602 are knitted textile 400 or when first component 601 is woven textile 300 and second component 602 is knitted textile 400. As a second example, first component 601 may be woven textile 300 and second component 602 may be another textile formed from cotton, silk, or thermoset polymer filaments. Upon heating, the thermoplastic polymer material of woven textile 300 may extend around or bond with filaments in the other textile to secure components 601 and 602 to each other when cooled. As a third example, first component 601 may be knitted textile 400 and second component 602 may be an element of polymer foam (or a polymer sheet) formed from a thermoplastic polymer material. Upon heating, the thermoplastic polymer materials of knitted textile 400 and the polymer foam may intermingle with each other to secure components 601 and 602 to each other when cooled. If, however, the polymer foam has a glass transition temperature that is higher than the thermoplastic polymer material of knitted textile 400, then the thermoplastic polymer material of knitted textile 400 may extend into the structure, crevices, or cavities of the polymer foam to secure components 601 and 602 to each other when cooled. As a fourth example, first component 601 may be knitted textile 400 and second component 602 may be an element of polymer foam (or a polymer sheet) formed from a thermoset polymer material. Upon heating, the thermoplastic polymer material of knitted textile 400 may extend into the structure, crevices, or cavities of the polymer foam to secure components 601 and 602 to each other when cooled. Accordingly, a thermal bond forming seam 603 may be utilized to join components 601 and 602 even when components 601 and 602 have a variety of structures or are formed from a diverse range of materials.
In order to impart varying properties to seam element 600, either of components 601 and 602 may include various fused regions. Moreover, the fused regions may extend across seam 603 As an example of this,
During the thermal bonding process discussed above, the edge areas of components 601 and 602 are heated and compressed. In addition to forming seam 603, the heating and compression may also cause the edge areas of components 601 and 602 to compress or reduce in thickness. More particularly, processes that form a thermal bond, as at seam 603, may effectively cause thinning in the area of the thermal bond. This effect may be seen in
Whereas components 601 and 602 curve at seam 603 and protrude outward, other seam configurations may have a more planar or flat configuration. Referring to
A general manufacturing process for forming seam 604 will now be discussed with reference to
Thermal bonding is utilized to join components 601 and 602 at the various seams 603 and 604 discussed above. Although thermal bonding alone is sufficient, stitching or adhesive bonding may also be utilized to reinforce seams 603 and 604. Moreover, stitching may be utilized to temporarily join or otherwise pre-join components 601 and 602 prior to thermal bonding. When the stitching (e.g., yarn, thread, monofilament) incorporates a thermoplastic polymer material, the stitching may also form a thermal bond with each of components 601 and 602. Depending upon the temperature at which thermal bonding occurs, the stitching may also melt into the structure of components 601 and 602.
Referring to
Stitching strand 605 may be a yarn, thread, or monofilament, for example. In some configurations, stitching strand 605 may have the general configuration of thread 200. As such, stitching strand 605 may include two or more yarns (e.g., yarns 201) that are twisted with each other. Moreover, the yarns may include a plurality of substantially aligned filaments (e.g., filaments 202) that are substantially formed from the second thermoplastic polymer material. As such, at least ninety-five percent, ninety-nine percent, or one-hundred percent of a material of the filaments in stitching strand 605 may be the second thermoplastic polymer material. Although stitching strand 605 is depicted as forming a zigzag stitch, other stitch configurations may be used for joining components 601 and 602 with stitching strand 605.
Based upon the discussion above, seam 603 effectively includes two thermal bonds. The first thermal bond is formed by the first thermoplastic polymer material from one or both of components 601 and 602. Although the first thermal bond primarily joins components 601 and 602 to each other, thereby forming seam 603, the first thermal bond may also join stitching strand 605 to components 601 and 602. The second thermal bond is formed by the second thermoplastic polymer material from stitching strand 605. Although the second thermal bond primarily joins stitching strand 605 to components 601 and 602, the second thermal bond may also join (a) sections of stitching strand 605 to each other or (b) components 601 and 602 to each other. An advantage of utilizing the first and second thermal bonds relates to strength. That is, seam 603 may exhibit greater strength than seams that are only utilize one of stitching or thermal bonding.
The first thermoplastic polymer material and the second thermoplastic polymer material may be the same thermoplastic polymer material. That is, the thermoplastic polymer materials of components 601 and 602 and stitching strand 605 may be the same thermoplastic polymer material (e.g., both being thermoplastic polyurethane) with common glass transition and melting temperatures. Similarly, the first thermoplastic polymer material and the second thermoplastic polymer material may be the same thermoplastic polymer material (e.g., both being thermoplastic polyurethane), but with different glass transition and melting temperatures. As an example, the first and second thermoplastic polymer materials may be thermoplastic polyurethane, with the first thermoplastic polymer material having higher glass transition and melting temperatures than the second thermoplastic polymer material. Additionally, the first thermoplastic polymer material and the second thermoplastic polymer material may be different thermoplastic polymer materials, such as thermoplastic polyurethane and thermoplastic polyolefin.
An advantage of incorporating the same thermoplastic polymer material into components 601 and 602 and stitching strand 605 relates to thermal bonding compatibility. Although different thermoplastic polymer materials may form thermal bonds with each other, thermal bonds may form more easily and with greater strength when components 601 and 602 and stitching strand 605 are formed from the same thermoplastic polymer material. A further advantage may be gained when components 601 and 602 and stitching strand 605 include the same thermoplastic polymer material, but with different glass transition and melting temperatures. More particularly, by configuring components 601 and 602 to have a different glass transition and melting temperature than stitching strand 605, the degree to which the first thermoplastic polymer material in components 601 and 602 softens or melts may be less than the degree to which the second thermoplastic polymer material in stitching strand 605 softens or melts when forming (a) the first thermal bond between components 601 and 602 and (b) the second thermal bond between stitching strand 605 and components 601 and 602.
The degree to which individual yarns or filaments within stitching strand 605 soften or melt when heated to form the second thermal bond with components 601 and 602 may vary significantly. Referring again to
Comparisons between
In order to ensure that the first thermoplastic polymer material of components 601 and 602 melts or softens to a lesser degree than the second thermoplastic polymer material of stitching strand 605, different melting and glass transition temperatures may be selected for each of the first and second thermoplastic polymer materials. More particularly, the melting and glass transition temperatures of the first thermoplastic polymer material may be higher than the respective melting and glass transition temperatures of the second thermoplastic polymer material. That is, the melting temperature of the first thermoplastic polymer material is higher than the melting temperature of the second thermoplastic polymer material, and the glass transition temperature of the first thermoplastic polymer material is higher than the glass transition temperature of the second thermoplastic polymer material. Depending upon the desired degree of melting or softening of the second thermoplastic polymer material, as in
Although the temperatures may vary significantly, examples values for the melting and glass transition temperatures of the first and second thermoplastic polymer materials will now be discussed. As an example, the first thermoplastic polymer material of components 601 and 602 may be thermoplastic polyurethane with a glass transition temperature of 180 degrees Celsius and a melting temperature of 210 degrees Celsius, and the second thermoplastic polymer material of stitching strand 605 may be thermoplastic polyurethane with a glass transition temperature of 140 degrees Celsius and a melting temperature of 160 degrees Celsius. With these temperatures, the melting temperature of the second thermoplastic polymer material is lower than the glass transition temperature of the first thermoplastic polymer material. As another example, the first thermoplastic polymer material of components 601 and 602 may be thermoplastic polyurethane with a glass transition temperature of 170 degrees Celsius and a melting temperature of 210 degrees Celsius, and the second thermoplastic polymer material of stitching strand 605 may be thermoplastic polyurethane with a glass transition temperature of 150 degrees Celsius and a melting temperature of 190 degrees Celsius. With these temperatures, the melting temperature of the second thermoplastic polymer material is higher than the glass transition temperature of the first thermoplastic polymer material.
A general manufacturing process for forming seam 603 with stitching strand 605 will now be discussed with reference to
Once properly joined with stitching strand 605, the edge areas of components 601 and 602 that include stitching strand 605 are located between the pair of seam-forming dies 12, as depicted in
Upon separating seam-forming dies 12, as depicted in
The degree of thermal bonding in seam 603 may vary significantly. In some configurations, as discussed above, advantages may be gained with a lesser degree of melting or softening of the first thermoplastic polymer material in components 601 and 602. In order to ensure that (a) the fibrous or filamentous structure of components 601 and 602 remains intact or otherwise coherent and (b) stitching strand 605 melts or softens to a greater degree, the melting and glass transition temperatures of the first thermoplastic polymer material are higher than the respective melting and glass transition temperatures of the second thermoplastic polymer material. That is, the melting temperature of the first thermoplastic polymer material is higher than the melting temperature of the second thermoplastic polymer material, and the glass transition temperature of the first thermoplastic polymer material is higher than the glass transition temperature of the second thermoplastic polymer material. Moreover, the melting temperature of the second thermoplastic polymer material may be higher or lower than the glass transition temperature of the first thermoplastic polymer material.
Although the glass transition temperatures and the melt temperatures of the first and second thermoplastic polymer materials may conform to the relationships discussed above, other relationships may also be utilized. For example, the melting temperature of the second thermoplastic polymer material may be higher than the melting temperature of the first thermoplastic polymer material, and the glass transition temperature of the second thermoplastic polymer material may be between the glass transition and melting temperatures of the first thermoplastic material. As another example, the glass transition and melting temperatures of the second thermoplastic polymer material may be higher than the melting temperature of the first thermoplastic polymer material.
The various concepts discussed above relating to the use of stitching strand 605 in seam 603 also applies to the configuration of seam 604. As an example,
The above discussion and associated
Although the various elements may be utilized in a variety of products, the following discussion provides examples of articles of apparel. That is, the following discussion demonstrates numerous ways in which the various elements may be incorporated into a shirt 700 and footwear 800. More particularly, examples of various configurations of shirt 700 and footwear 800 are provided in order to demonstrate products utilizing yarns, threads, and textiles that incorporate thermoplastic polymer materials, as well as the manner in which thermal bonding may impart advantages to the products. Accordingly, while the concepts outlined below are specifically applied to various articles of apparel, the concepts may be applied to a variety of other products.
A first configuration of shirt 700 is depicted in
Torso region 701 and arm regions 702 are formed from various textile elements 706 that are joined at a plurality of seams 707. Textile elements 706 are generally formed to have the configuration of woven textile 300, knitted textile 400, or any other textile that incorporates a thermoplastic polymer material. As such, textile elements 706 may incorporate strands (e.g., yarn 100, thread 200) that have a plurality of substantially aligned filaments formed from a thermoplastic polymer material. Although each of textile elements 706 may be woven or knitted, other textile elements 706 may be a non-woven textile or a polymer sheet, for example, that incorporates a thermoplastic polymer material. Some of textile elements 706 may also be formed from cotton, silk, thermoset polymer filaments, or other materials that do not include a thermoplastic polymer material. Shirt 700 may also include elastic components, zippers, hook-and-loop fasteners, or other closure devices, for example.
Two of seams 707 extend between torso region 701 and arm regions 702 in order to join various textile elements 706 together. Although not depicted, additional seams 707 may extend along (a) side areas of torso region 701 to join front and back textile elements 706 and (b) rear areas of arm regions 702 to join edge areas of the textile element 706 forming each arm region 702, for example. In general, seams 707 define regions where edge areas of textile elements 706 are joined with each other, possibly through thermal bonding. Referring to
Many of the edge areas of textile elements 706 are joined at seams 707. Other edge areas are present at openings 703, 704, and 705. In order to prevent fraying or unraveling of strands forming textile elements 706 at openings 703, 704, and 705, various types of thermal bonds may be employed. Referring to
A second configuration of shirt 700 is depicted in
In order to impart different properties to specific areas of shirt 700, various fused regions 708 are formed in textile elements 706. More particularly, fused regions 708 are formed around neck opening 703, waist opening 704, and each of arm openings 705. Given that each of openings 703-705 may be stretched as shirt 700 is put on an individual and taken off the individual, fused regions 708 are located around openings 703-705 in order to impart greater stretch-resistance to these areas. Strands incorporating a thermoplastic polymer material in fused regions 708 are generally fused to a greater degree than in other areas of shirt 700. Similar to the discussion of
Given that elbow areas of shirt 700 may be subjected to relatively high abrasion as shirt 700 is worn, some of fused regions 708 may be located in the elbow areas to impart greater durability. Also, backpack straps that extend over shoulder areas of shirt 700 may abrade and stretch the shoulder areas. Additional fused regions 708 are, therefore, located in the shoulder areas of shirt 200 to impart both durability and stretch-resistance. Portions of textile elements 706 that are located in the shoulder areas and around seams 707 effectively form both seams 707 and fused regions 708 in the shoulder areas. Two separate processes may be utilized to form these areas. That is, one thermal bonding process may form seams 707, and another thermal bonding process may form fused regions 708 in the shoulder areas. In some processes, however, seams 707 and fused regions 708 in the shoulder areas may be formed through a single thermal bonding process.
During the thermal bonding that forms fused regions 708, areas of textile elements 706 are heated and compressed. In addition to fusing strands within textile elements 706, the heating and compression may also cause fused regions 708 to compress or reduce in thickness. More particularly, processes that form a fused regions 708 may effectively cause thinning in the areas of fused regions 708. This effect may be seen in
A third configuration of shirt 700 is depicted in
Components 709 may have various configurations. If component 709 is another textile that absorbs or wicks water, then the combination of textile elements 706 and the other textile may be suitable for configurations of shirt 700 utilized during athletic activities where an individual wearing shirt 700 is likely to perspire. If component 709 is a compressible material, such as an element of polymer foam, then the combination of textile elements 706 and the compressible material may be suitable for configurations of shirt 70 where cushioning (i.e., attenuation of impact forces) is advantageous, such as padding for athletic activities that may involve contact or impact with other athletes, equipment, or the ground. If component 709 is a polymer sheet or plate, then the combination of textile elements 706 and the polymer sheet or plate may be suitable for articles of apparel that impart protection from acute impacts. Accordingly, a variety of materials or other components maybe joined through thermal bonding to textile elements 706 of shirt 700.
Various fused regions 708 are also formed in textile elements 706 and adjacent to some of components 709. As an example, two fused regions 708 extend around the areas where components 709 are located in the side areas of torso region 701. A pair of fused regions 708 extend over the areas where components 709 are located in the elbow areas of arm regions 702. These fused regions 708 may be utilized to reinforce or add stretch-resistance to areas surrounding components 709 or provide greater durability to areas over components 709, for example.
A fourth configuration of shirt 700 is depicted in
Based upon the above discussion, textile elements (e.g., textiles 300 and 400) including a thermoplastic polymer material may be utilized in shirt 700. Given that many other types of apparel have constructions that are similar to shirt 700. That is, pants, socks, outerwear, undergarments, and headwear are all formed from one or more textile elements joined at seams. These other types of apparel may, therefore, incorporate structures that are substantially similar to seams 707 (i.e., seams 603, 604). In order to impart different properties to areas of the apparel, various structures that are substantially similar to fused regions 708 (i.e., fused regions 303, 304, 403, 404) may also be utilized. Similarly, the other types of apparel may also incorporate structures that are substantially similar to components 709 (i.e., components 501, 502). By forming fused regions and combining the textile elements with other components, various properties and combinations of properties may be imparted to different areas of the apparel. That is, the various concepts disclosed herein may be utilized individually or in combination to engineer the properties of apparel to a specific purpose.
A first configuration of footwear 800 is depicted in
Sole structure 810 includes a midsole 811, an outsole 812, and an sockliner 813. Midsole 811 is secured to a lower surface of upper 820 and may be formed from a compressible polymer foam element (e.g., a polyurethane or ethylvinylacetate foam) that attenuates ground reaction forces (i.e., provides cushioning) when compressed between the foot and the ground during walking, running, or other ambulatory activities. In further configurations, midsole 811 may incorporate fluid-filled chambers, plates, moderators, or other elements that further attenuate forces, enhance stability, or influence the motions of the foot, or midsole 811 may be primarily formed from a fluid-filled chamber. Outsole 812 is secured to a lower surface of midsole 811 and may be formed from a wear-resistant rubber material that is textured to impart traction. Sockliner 813 is located within upper 820, as depicted in
Upper 820 may be formed from a variety of elements that are joined together to form a structure for receiving and securing the foot relative to sole structure 810. As such, upper 820 extends along opposite sides of the foot, over the foot, around a heel of the foot, and under the foot. Moreover, upper 820 defines a void 821, which is a generally hollow area of footwear 800, that has a general shape of the foot and is intended to receive the foot. Access to void 821 is provided by an ankle opening 822 located in at least a heel region. A lace 823 extends through various lace apertures 824 and permits the wearer to modify dimensions of upper 820 to accommodate the proportions of the foot. More particularly, lace 823 permits the wearer to tighten upper 820 around the foot, and lace 823 permits the wearer to loosen upper 820 to facilitate entry and removal of the foot from the void (i.e., through ankle opening 822). As an alternative to lace apertures 824, upper 820 may include other lace-receiving elements, such as loops, eyelets, hooks, and D-rings. In addition, upper 820 includes a tongue 825 that extends between void 821 and lace 823 to enhance the comfort and adjustability of footwear 800. In some configurations, upper 820 may also incorporate other elements, such as reinforcing members, aesthetic features, a heel counter that limits heel movement, a wear-resistant toe guard, or indicia (e.g., a trademark) identifying the manufacturer. Accordingly, upper 820 is formed from a variety of elements that form a structure for receiving and securing the foot.
Portions of upper 820 that extend along sides of the foot, over the foot, and under the foot include various textile elements 826, which are generally formed to have the configuration of woven textile 300, knitted textile 400, or any other textile that incorporates a thermoplastic polymer material. As such, textile elements 826 may incorporate strands (e.g., yarn 100, thread 200) that have a plurality of substantially aligned filaments formed from a thermoplastic polymer material. Although each of textile elements 826 may be woven or knitted, other textile elements 826 may be a non-woven textile or a polymer sheet, for example, that incorporates a thermoplastic polymer material. Some of textile elements 826 may also be formed from cotton, silk, thermoset polymer filaments, or other materials that do not include a thermoplastic polymer material. Tongue 825 may also incorporate one or more of textile elements 826.
Although a single textile element 826 may form a relatively large area of upper 820, multiple textile elements 826 are joined at various seams 827. In general, seams 827 define regions where edge areas of textile elements 826 are joined with each other, possibly through thermal bonding. As an example, two seams 827 are located on opposite sides of upper 820 and join a textile element 826 that forms lace apertures 824 with a textile element 826 that extends along sides of the foot. These seams 827 exhibit the general configuration of seam 603, but may also have the general configuration of seam 604. An advantage to the configuration of seam 604 is that the edge areas of textile element 826 do not protrude inward, which may cause discomfort for the wearer. As another example, two seams 827 are located on opposite sides of upper 820 and join the textile element 826 that extends along sides of the foot with a textile element 826 that extends under the foot, which may be a strobel material. These seams 827 exhibit the general configuration of seam 604, but may also have the general configuration of seam 603. Accordingly, various textile elements 826 may be joined with seams 827, which may be formed through the various thermal bonding processes discussed above for forming seams 603 and 604.
Two of seams 707 extend between torso region 701 and arm regions 702 in order to join various textile elements 706 together. Although not depicted, additional seams 707 may extend along (a) side areas of torso region 701 to join front and back textile elements 706 and (b) rear areas of arm regions 702 to join edge areas of the textile element 706 forming each arm region 702, for example. Referring to
A relatively large percentage of footwear 800 may be formed from thermoplastic polymer materials. As discussed above, textile elements 826 may be at least partially formed from thermoplastic polymer materials. Although lace 823 is not generally joined to upper 820 through bonding or stitching, lace 823 may also be formed from a thermoplastic polymer material. Similarly, each of midsole 811 and outsole 812 may be formed from a thermoplastic polymer material. Depending upon the number of elements of footwear 800 that incorporate thermoplastic polymer materials or are entirely formed from thermoplastic polymer materials, the percentage by mass of footwear 800 that is formed from the thermoplastic polymer materials may range from thirty percent to one-hundred percent. In some configurations, at least sixty percent of a combined mass of sole structure 810 and upper 820 may be from thermoplastic polymer materials. Accordingly, a majority or even all of footwear 400 may be formed from one or more thermoplastic polymer materials.
Adhesives are conventionally utilized to join uppers to sole structures and midsoles to outsoles. An advantage of forming various elements of footwear 800 from thermoplastic polymer materials is that a thermal bond may be utilized to join upper 820 to sole structure 810 and midsole 811 to outsole 812. In addition to reducing the environmental effects of utilizing adhesives, the recyclability of footwear 800 may also be enhanced.
A second configuration of footwear 800 is depicted in
During the thermal bonding process that forms fused regions 828, areas of textile elements 826 are heated and compressed. In addition to fusing strands within textile elements 826, the heating and compression may also cause fused regions 828 to compress or reduce in thickness. More particularly, processes that form a fused regions 828 may effectively cause thinning in the areas of fused regions 828. This effect may be seen in
Although upper 820 may be formed to have a thickness of a single layer of textile elements 826, upper 820 may also have a thickness of multiple layers. Referring again to
On each side of upper 820, textile element 826 may be thermal bonded to component 830. If one or both of components 829 and 830 incorporate a thermoplastic polymer material, then components 829 and 830 may also be thermal bonded to each other. The process for joining textile element 826 and components 829 and 830 in a layered configuration may, therefore, be similar to the thermal bonding process discussed above for composite element 500.
A third configuration of footwear 800 is depicted in
A fourth configuration of footwear 400 is depicted in
As an alternative to forming indicia with fused regions 828, other elements may be thermal bonded to upper 820 to form indicia. For example, a polymer sheet may be cut to form the letters “A,” “B,” and “C” and then joined with the sides of upper 820 through thermal bonding to textile elements 826. As a related matter, elements of woven textile 300 or knitted textile 400, for example, may be thermal bonded or otherwise joined to various products to form indicia. For example, elements of woven textile 300 or knitted textile 400 with the shapes of the letters “A,” “B,” and “C” may be thermal bonded to the sides of an article of footwear where the upper is primarily formed from leather, synthetic leather, or any other material. Given that woven textile 300, knitted textile 400, or other textiles incorporating a thermoplastic polymer material may be thermal bonded to a variety of other materials, elements these elements may be thermal bonded to a variety of products in order to form indicia.
Based upon the above discussion, textile elements (e.g., textiles 300 and 400) including a thermoplastic polymer material may be utilized in footwear 800. Other types of footwear may also incorporate structures that are substantially similar to seams 827 (i.e., seams 603, 604). In order to impart different properties to areas of the footwear, various structures that are substantially similar to fused regions 828 (i.e., fused regions 303, 304, 403, 404) may also be utilized. Similarly, other types of footwear may also incorporate structures that are substantially similar to components 829 and 830 (i.e., components 501, 502). By forming fused regions and combining the textile elements with other components, various properties and combinations of properties may be imparted to footwear. That is, the various concepts disclosed herein may be utilized individually or in combination to engineer the properties of footwear to a specific purpose.
Woven textile 300 and knitted textile 400, as respectively depicted in
A variety of processes may be utilized to form a three-dimensional configuration in shaped textile 900. In general, however, the processes involve forming thermal bonds within shaped textile 900 to impart the non-planar configuration. Referring to
Based upon the above discussion, a textile incorporating a thermoplastic polymer material may be shaped or molded to exhibit a three-dimensional or non-planar configuration. When incorporated into products (e.g., shirt 700, footwear 800), these features may provide both structural and aesthetic enhancements to the products. For example, the three-dimensional configurations may provide enhanced impact force attenuation and greater permeability by increasing surface area.
Woven textile 300 and knitted textile 400 are substantially formed from a thermoplastic polymer material. Given that textile elements 706 of shirt 700 may have the configuration of either of woven textile 300 and knitted textile 400, for example, a majority or substantially all of shirt 700 may be formed from the thermoplastic polymer material. Similarly, a relatively large percentage of footwear 800 may also be formed from a thermoplastic polymer material. Unlike many articles of apparel, therefore, the materials within shirt 700 and footwear 800 may be recycled following their useful lives.
Utilizing shirt 700 as an example, the thermoplastic polymer material from shirt 700 may be extracted, recycled, and incorporated into another product (e.g., apparel, container, upholstery) as a non-woven textile, a woven textile, a knitted textile, a polymer foam, or a polymer sheet. This process is generally shown in
Yarn 100, thread 200, woven textile 300, knitted textile 400, composite element 500, seam element 600, shirt 700, and footwear 800 all are at least partially formed from a thermoplastic polymer material. Various fused regions may be formed in these elements through thermal bonding processes to modify various properties that include permeability, durability, and stretch-resistance. Various components (textiles, polymer sheets, foam layers, strands) may also be secured to or combined with these elements through thermal bonding processes to impart additional properties or advantages. Seams may be formed to join these elements with thermal bonding processes. Accordingly, the various structures and techniques discussed above combined to form numerous products and impart a variety of properties to the products.
The invention is disclosed above and in the accompanying figures with reference to a variety of configurations. The purpose served by the disclosure, however, is to provide an example of the various features and concepts related to the invention, not to limit the scope of the invention. One skilled in the relevant art will recognize that numerous variations and modifications may be made to the configurations described above without departing from the scope of the present invention, as defined by the appended claims.
Number | Name | Date | Kind |
---|---|---|---|
1236323 | Graf | Jan 1881 | A |
610390 | Felbel | Sep 1898 | A |
1077556 | Sierra | Nov 1913 | A |
2536163 | Feild, Jr. et al. | Jan 1951 | A |
2763759 | Sanai | Sep 1956 | A |
3249129 | Renfroe | May 1966 | A |
3375156 | MacMillan, Jr. | Mar 1968 | A |
3415919 | Kippan | Dec 1968 | A |
3617417 | Olson | Nov 1971 | A |
3635625 | Voss | Jan 1972 | A |
3681826 | Bergwerk | Aug 1972 | A |
3689882 | Dessailly | Sep 1972 | A |
3785915 | Closson | Jan 1974 | A |
3790439 | Zosel et al. | Feb 1974 | A |
3912567 | Schwartz | Oct 1975 | A |
4016329 | Matsuyama et al. | Apr 1977 | A |
4041203 | Brock et al. | Aug 1977 | A |
4059114 | Richards | Nov 1977 | A |
4070217 | Smith, II et al. | Jan 1978 | A |
4100319 | Schwartz | Jul 1978 | A |
4107364 | Sisson | Aug 1978 | A |
4168606 | Callander | Sep 1979 | A |
4205397 | Bechis | Jun 1980 | A |
4228641 | O'Neil | Oct 1980 | A |
4265954 | Romanek | May 1981 | A |
4310373 | Schuhmacher et al. | Jan 1982 | A |
4355489 | Heyer et al. | Oct 1982 | A |
4410385 | Murphy et al. | Oct 1983 | A |
4445951 | Lind et al. | May 1984 | A |
4486200 | Heyer et al. | Dec 1984 | A |
4497099 | Scott | Feb 1985 | A |
4511615 | Ohta | Apr 1985 | A |
4576852 | Burgess | Mar 1986 | A |
4588630 | Shimalla | May 1986 | A |
4615188 | Hursh et al. | Oct 1986 | A |
4621013 | Holtrop et al. | Nov 1986 | A |
4647492 | Grant et al. | Mar 1987 | A |
4695501 | Robinson | Sep 1987 | A |
4741941 | Englebert et al. | May 1988 | A |
4747901 | Becker et al. | May 1988 | A |
4781296 | Morris et al. | Nov 1988 | A |
4938817 | Langley | Jul 1990 | A |
4980927 | Wawiluk et al. | Jan 1991 | A |
5003902 | Benstock et al. | Apr 1991 | A |
5102724 | Okawahara et al. | Apr 1992 | A |
5106678 | Abu-Isa | Apr 1992 | A |
5118550 | Baravian et al. | Jun 1992 | A |
5130178 | Zerfass et al. | Jul 1992 | A |
5132160 | Bird | Jul 1992 | A |
5150787 | Bird et al. | Sep 1992 | A |
5203939 | Sperling et al. | Apr 1993 | A |
5230701 | Meyer et al. | Jul 1993 | A |
5238733 | Joseph et al. | Aug 1993 | A |
5255833 | McAllister | Oct 1993 | A |
5282900 | McDonell et al. | Feb 1994 | A |
5306275 | Bryan | Apr 1994 | A |
5316838 | Crandall et al. | May 1994 | A |
5324277 | Daugan et al. | Jun 1994 | A |
5328758 | Markell et al. | Jul 1994 | A |
5380580 | Rogers et al. | Jan 1995 | A |
5415779 | Markell et al. | May 1995 | A |
5420794 | James | May 1995 | A |
5423783 | Battles et al. | Jun 1995 | A |
5458962 | Birch | Oct 1995 | A |
5470605 | Lundeen | Nov 1995 | A |
5478628 | Billingsley et al. | Dec 1995 | A |
5482756 | Berger et al. | Jan 1996 | A |
5496507 | Angadjivand et al. | Mar 1996 | A |
5501794 | Van de Graaf et al. | Mar 1996 | A |
5507968 | Palaikis | Apr 1996 | A |
5539042 | Birch | Jul 1996 | A |
5573619 | Benedict et al. | Nov 1996 | A |
5586563 | Newman | Dec 1996 | A |
5595649 | Markell et al. | Jan 1997 | A |
5603747 | Matuda et al. | Feb 1997 | A |
5604271 | Lundeen | Feb 1997 | A |
5609706 | Benedict et al. | Mar 1997 | A |
5624726 | Sanocki et al. | Apr 1997 | A |
5629079 | Battles et al. | May 1997 | A |
5639287 | Van de Graaf et al. | Jun 1997 | A |
5641563 | Truong et al. | Jun 1997 | A |
5651853 | Wrigley et al. | Jul 1997 | A |
5655833 | Raczynski | Aug 1997 | A |
5682618 | Johnson et al. | Nov 1997 | A |
5695853 | Billingsley et al. | Dec 1997 | A |
5714229 | Ogden | Feb 1998 | A |
5743273 | Newman | Apr 1998 | A |
5744207 | Bartusiak et al. | Apr 1998 | A |
5759659 | Sanocki et al. | Jun 1998 | A |
5783290 | Isaac et al. | Jul 1998 | A |
5803086 | Scholz et al. | Sep 1998 | A |
5858140 | Berger et al. | Jan 1999 | A |
5858515 | Stokes et al. | Jan 1999 | A |
5879493 | Johnson et al. | Mar 1999 | A |
5883019 | Troung et al. | Mar 1999 | A |
5888157 | Guenther et al. | Mar 1999 | A |
5928070 | Lux | Jul 1999 | A |
5939339 | Delmore et al. | Aug 1999 | A |
RE36323 | Thompson et al. | Oct 1999 | E |
5981033 | Haunschild et al. | Nov 1999 | A |
6004642 | Langford | Dec 1999 | A |
6013587 | Truong et al. | Jan 2000 | A |
6017831 | Beardsley et al. | Jan 2000 | A |
6069097 | Suzuki et al. | May 2000 | A |
6086911 | Godbey | Jul 2000 | A |
6090234 | Barone et al. | Jul 2000 | A |
6110572 | Groh et al. | Aug 2000 | A |
6119691 | Angadjivand et al. | Sep 2000 | A |
6123752 | Wu et al. | Sep 2000 | A |
6174964 | Jariwala et al. | Jan 2001 | B1 |
6251154 | Van Rossen | Jun 2001 | B1 |
6284843 | Jariwala et al. | Sep 2001 | B1 |
6288157 | Jariwala et al. | Sep 2001 | B1 |
6315130 | Olsen | Nov 2001 | B1 |
6332465 | Xue et al. | Dec 2001 | B1 |
6391200 | Pulek et al. | May 2002 | B2 |
6391807 | Jariwala et al. | May 2002 | B1 |
6395211 | Dettmer et al. | May 2002 | B1 |
6406576 | Benedict et al. | Jun 2002 | B1 |
6406577 | Benedict et al. | Jun 2002 | B1 |
6429159 | Watanabe et al. | Aug 2002 | B1 |
6492183 | Perman et al. | Dec 2002 | B1 |
6503855 | Menzies et al. | Jan 2003 | B1 |
6537930 | Middlesworth et al. | Mar 2003 | B1 |
6537935 | Seth et al. | Mar 2003 | B1 |
6558784 | Norton et al. | May 2003 | B1 |
6610390 | Kauschke et al. | Aug 2003 | B1 |
6645611 | Seth | Nov 2003 | B2 |
6715188 | Jackson et al. | Apr 2004 | B1 |
6719744 | Kinnear et al. | Apr 2004 | B2 |
6769202 | Luthi et al. | Aug 2004 | B1 |
6773718 | Seth et al. | Aug 2004 | B2 |
6783574 | Angadjivand et al. | Aug 2004 | B1 |
6784125 | Yamakawa et al. | Aug 2004 | B1 |
6784127 | Yamakawa et al. | Aug 2004 | B1 |
6835256 | Menzies et al. | Dec 2004 | B2 |
6875710 | Eaton et al. | Apr 2005 | B2 |
6880211 | Jackson et al. | Apr 2005 | B2 |
6910288 | Dua | Jun 2005 | B2 |
6942683 | Dunshee | Sep 2005 | B2 |
6942894 | Alberg et al. | Sep 2005 | B2 |
6967178 | Zhou et al. | Nov 2005 | B2 |
7066182 | Dunshee | Jun 2006 | B1 |
7147734 | Ogle et al. | Dec 2006 | B2 |
7147904 | Crawford | Dec 2006 | B1 |
7150774 | Kubokawa et al. | Dec 2006 | B2 |
7169202 | Kubokawa | Jan 2007 | B2 |
7195729 | Jackson et al. | Mar 2007 | B2 |
7230043 | Klun et al. | Jun 2007 | B2 |
7238314 | Jackson et al. | Jul 2007 | B2 |
7267681 | Dunshee | Sep 2007 | B2 |
7291236 | Guilhem et al. | Nov 2007 | B2 |
7293371 | Aveni | Nov 2007 | B2 |
7303805 | Seth et al. | Dec 2007 | B2 |
7311880 | Perman et al. | Dec 2007 | B2 |
7320719 | Van de Graaf et al. | Jan 2008 | B2 |
7390451 | Jackson et al. | Jun 2008 | B2 |
7393371 | O'Gary et al. | Jul 2008 | B2 |
7547650 | Keep | Jun 2009 | B2 |
7709075 | Suzuki | May 2010 | B2 |
7955549 | Noda et al. | Jun 2011 | B2 |
8850719 | Hawkinson et al. | Oct 2014 | B2 |
8906275 | Davis et al. | Dec 2014 | B2 |
20010008683 | Takai et al. | Jul 2001 | A1 |
20010035598 | Ampulski et al. | Nov 2001 | A1 |
20020070471 | Lee et al. | Jun 2002 | A1 |
20020090875 | Lasko et al. | Jul 2002 | A1 |
20020132121 | Palacio et al. | Sep 2002 | A1 |
20020137418 | Seth | Sep 2002 | A1 |
20020150610 | Kono et al. | Oct 2002 | A1 |
20030060858 | Kieval et al. | Mar 2003 | A1 |
20030091617 | Mrozinski et al. | May 2003 | A1 |
20030119411 | Yamakawa et al. | Jun 2003 | A1 |
20030124310 | Ellis et al. | Jul 2003 | A1 |
20030137221 | Radziemski et al. | Jul 2003 | A1 |
20030162458 | Tsujiyama et al. | Aug 2003 | A1 |
20030171051 | Bergsten et al. | Sep 2003 | A1 |
20040050506 | Haiber et al. | Mar 2004 | A1 |
20040060858 | Lucas et al. | Apr 2004 | A1 |
20040118018 | Dua | Jun 2004 | A1 |
20040186482 | Kolb et al. | Sep 2004 | A1 |
20040216329 | Evans | Nov 2004 | A1 |
20040224596 | Mathis et al. | Nov 2004 | A1 |
20040241399 | Marmon et al. | Dec 2004 | A1 |
20050084647 | Menzies et al. | Apr 2005 | A1 |
20050106326 | Audenaert et al. | May 2005 | A1 |
20050160629 | Jungkind | Jul 2005 | A1 |
20050188907 | D'Henin | Sep 2005 | A1 |
20050193592 | Dua et al. | Sep 2005 | A1 |
20050217226 | Sundet et al. | Oct 2005 | A1 |
20060009106 | Nishimura et al. | Jan 2006 | A1 |
20060036230 | Mills et al. | Feb 2006 | A1 |
20060081329 | Kikuchi | Apr 2006 | A1 |
20060121812 | Suzuki et al. | Jun 2006 | A1 |
20060141881 | Bergsten et al. | Jun 2006 | A1 |
20060143947 | Ellis et al. | Jul 2006 | A1 |
20060165939 | Hottner | Jul 2006 | A1 |
20060169387 | Nayar et al. | Aug 2006 | A1 |
20060180067 | Yamazaki | Aug 2006 | A1 |
20060204558 | Kantner et al. | Sep 2006 | A1 |
20060223403 | Mahboob | Oct 2006 | A1 |
20060246260 | Sundet et al. | Nov 2006 | A1 |
20060276095 | Dua et al. | Dec 2006 | A1 |
20070049148 | Chien | Mar 2007 | A1 |
20070049153 | Dunbar et al. | Mar 2007 | A1 |
20070049646 | Moore et al. | Mar 2007 | A1 |
20070129524 | Sunkara | Jun 2007 | A1 |
20070135008 | Hall et al. | Jun 2007 | A1 |
20070169379 | Hazenberg et al. | Jul 2007 | A1 |
20070176325 | Jackson et al. | Aug 2007 | A1 |
20070186482 | Sudo | Aug 2007 | A1 |
20070199210 | Vattes et al. | Aug 2007 | A1 |
20070212963 | Keep | Sep 2007 | A1 |
20070298671 | Noda et al. | Dec 2007 | A1 |
20070298697 | Charmoille et al. | Dec 2007 | A1 |
20080001431 | Thompson et al. | Jan 2008 | A1 |
20080022642 | Fox et al. | Jan 2008 | A1 |
20080022643 | Fox et al. | Jan 2008 | A1 |
20080026659 | Brandner et al. | Jan 2008 | A1 |
20080044622 | Noda et al. | Feb 2008 | A1 |
20080064279 | Browning et al. | Mar 2008 | A1 |
20080070464 | Alberg et al. | Mar 2008 | A1 |
20080134543 | Klein | Jun 2008 | A1 |
20080139067 | Mukai et al. | Jun 2008 | A1 |
20080148946 | Lotgerink-Bruinenberg | Jun 2008 | A1 |
20080241476 | Olguin | Oct 2008 | A1 |
20080245720 | Hutchinson et al. | Oct 2008 | A1 |
20080245725 | Patel et al. | Oct 2008 | A1 |
20080246182 | Patel et al. | Oct 2008 | A1 |
20080276805 | Lotgerink-Bruinenberg | Nov 2008 | A1 |
20090068908 | Hinchcliff | Mar 2009 | A1 |
20090140470 | Dua et al. | Jun 2009 | A1 |
20090277041 | Hubner | Nov 2009 | A1 |
20100035963 | Chajut et al. | Feb 2010 | A1 |
20100037483 | Meschter et al. | Feb 2010 | A1 |
20100077634 | Bell | Apr 2010 | A1 |
20100095554 | Gillespie | Apr 2010 | A1 |
20100147444 | Hsu et al. | Jun 2010 | A1 |
20100154256 | Dua et al. | Jun 2010 | A1 |
20100175276 | Dojan et al. | Jul 2010 | A1 |
20100186874 | Sussmann | Jul 2010 | A1 |
20100199406 | Dua | Aug 2010 | A1 |
20100199520 | Dua et al. | Aug 2010 | A1 |
20100251491 | Dojan et al. | Oct 2010 | A1 |
20100287790 | Sokolowski et al. | Nov 2010 | A1 |
20100325916 | Dua et al. | Dec 2010 | A1 |
20110098147 | Crane | Apr 2011 | A1 |
20120227282 | Hawkinson et al. | Sep 2012 | A1 |
20120291314 | Sokolowski et al. | Nov 2012 | A1 |
20130067639 | Dua et al. | Mar 2013 | A1 |
20130067768 | Dua et al. | Mar 2013 | A1 |
20130068378 | Dua et al. | Mar 2013 | A1 |
20130069266 | Dua et al. | Mar 2013 | A1 |
20130232815 | Meythaler et al. | Sep 2013 | A1 |
20130255103 | Dua et al. | Oct 2013 | A1 |
20130260104 | Dua et al. | Oct 2013 | A1 |
20130260629 | Dua et al. | Oct 2013 | A1 |
20130285294 | Huang et al. | Oct 2013 | A1 |
Number | Date | Country |
---|---|---|
85106873 | Mar 1987 | CN |
1190931 | Aug 1998 | CN |
1201846 | Dec 1998 | CN |
2354400 | Dec 1999 | CN |
1278424 | Jan 2001 | CN |
1451330 | Oct 2003 | CN |
1571871 | Jan 2005 | CN |
1802104 | Jul 2006 | CN |
101001546 | Jul 2007 | CN |
101125044 | Feb 2008 | CN |
101326212 | Dec 2008 | CN |
101500794 | Aug 2009 | CN |
101542032 | Sep 2009 | CN |
102137600 | Jul 2011 | CN |
102292487 | Dec 2011 | CN |
2109143 | Oct 1972 | DE |
19642253 | Aug 1997 | DE |
29911710 | Dec 1999 | DE |
102007004146 | Jul 2008 | DE |
102007035729 | Feb 2009 | DE |
0264132 | Apr 1988 | EP |
0304301 | Feb 1989 | EP |
0327402 | Aug 1989 | EP |
0370835 | May 1990 | EP |
0559969 | Sep 1993 | EP |
1068889 | Jan 2001 | EP |
1167606 | Jan 2002 | EP |
1264561 | Dec 2002 | EP |
1340848 | Sep 2003 | EP |
1342825 | Sep 2003 | EP |
1418092 | May 2004 | EP |
1491105 | Dec 2004 | EP |
1589140 | Oct 2005 | EP |
1884582 | Feb 2008 | EP |
2084981 | Aug 2009 | EP |
2397594 | Dec 2011 | EP |
2407302 | Jan 2012 | EP |
2453048 | May 2012 | EP |
2488685 | Aug 2012 | EP |
2393972 | Jan 2013 | EP |
2397593 | Jul 2013 | EP |
2683866 | Jan 2014 | EP |
1353183 | May 1974 | GB |
1384326 | Feb 1975 | GB |
1491602 | Nov 1977 | GB |
2115741 | Sep 1983 | GB |
S4703280 | Nov 1972 | JP |
S4732180 | Dec 1972 | JP |
S60-52237 | Nov 1985 | JP |
61000655 | Jan 1986 | JP |
S61655 | Jan 1986 | JP |
S61111993 | Jul 1986 | JP |
S62194030 | Aug 1987 | JP |
S62194030 | Dec 1987 | JP |
S62203211 | Dec 1987 | JP |
S62203212 | Dec 1987 | JP |
H0257993 | Feb 1990 | JP |
H0257993 | Apr 1990 | JP |
H02130206 | May 1990 | JP |
H02165942 | Jun 1990 | JP |
H02286225 | Nov 1990 | JP |
H03200885 | Sep 1991 | JP |
H03224421 | Oct 1991 | JP |
H04108152 | Apr 1992 | JP |
H054291 | Jan 1993 | JP |
H0522792 | Jan 1993 | JP |
H05200890 | Aug 1993 | JP |
H05321119 | Dec 1993 | JP |
H06126754 | May 1994 | JP |
H06158501 | Jun 1994 | JP |
H07157957 | Jun 1995 | JP |
H07197355 | Aug 1995 | JP |
3016014 | Sep 1995 | JP |
H07252762 | Oct 1995 | JP |
H08301 | Jan 1996 | JP |
H08104164 | Apr 1996 | JP |
H08503745 | Apr 1996 | JP |
H08296161 | Nov 1996 | JP |
H08323903 | Dec 1996 | JP |
H0913252 | Jan 1997 | JP |
H0958200 | Mar 1997 | JP |
H0965907 | Mar 1997 | JP |
H09188951 | Jul 1997 | JP |
H09267456 | Oct 1997 | JP |
H09275293 | Oct 1997 | JP |
H1077566 | Mar 1998 | JP |
H10245760 | Sep 1998 | JP |
H10273868 | Oct 1998 | JP |
H10292271 | Nov 1998 | JP |
H10323661 | Dec 1998 | JP |
H1112912 | Jan 1999 | JP |
H1161616 | Mar 1999 | JP |
H1190836 | Jul 1999 | JP |
H11217799 | Aug 1999 | JP |
H11320736 | Nov 1999 | JP |
H11320800 | Nov 1999 | JP |
2000503610 | Mar 2000 | JP |
2000248454 | Sep 2000 | JP |
2001058002 | Mar 2001 | JP |
2001179889 | Jul 2001 | JP |
2001181905 | Jul 2001 | JP |
2001523772 | Nov 2001 | JP |
2002234547 | Aug 2002 | JP |
2002317367 | Oct 2002 | JP |
2003117325 | Apr 2003 | JP |
3093555 | May 2003 | JP |
2003517950 | Jun 2003 | JP |
2003227060 | Aug 2003 | JP |
2003524534 | Aug 2003 | JP |
2003310331 | Nov 2003 | JP |
2004150008 | May 2004 | JP |
2004192182 | Jul 2004 | JP |
2004211258 | Jul 2004 | JP |
2004244791 | Sep 2004 | JP |
2004306149 | Nov 2004 | JP |
2005029907 | Feb 2005 | JP |
2005187954 | Jul 2005 | JP |
2005212055 | Aug 2005 | JP |
2006511306 | Apr 2006 | JP |
2006192723 | Jul 2006 | JP |
2006193881 | Jul 2006 | JP |
2006223403 | Aug 2006 | JP |
2006274453 | Oct 2006 | JP |
2006299425 | Nov 2006 | JP |
2007516046 | Jun 2007 | JP |
2007522908 | Aug 2007 | JP |
2007537372 | Dec 2007 | JP |
2008007930 | Jan 2008 | JP |
4785700 | May 2008 | JP |
2008101285 | May 2008 | JP |
2008513626 | May 2008 | JP |
2008517183 | May 2008 | JP |
2008138908 | Jun 2008 | JP |
2008-169506 | Jul 2008 | JP |
2009538197 | Nov 2009 | JP |
2010534535 | Nov 2010 | JP |
2011081082 | Apr 2011 | JP |
2012-517535 | Aug 2012 | JP |
5226844 | Jul 2013 | JP |
S5411906 | Nov 2013 | JP |
5615786 | Sep 2014 | JP |
2015522722 | Aug 2015 | JP |
10-2005-0088367 | Sep 2005 | KR |
10-2009-0023339 | Mar 2009 | KR |
0145927 | Jun 2001 | WO |
02054894 | Jul 2002 | WO |
03007864 | Jan 2003 | WO |
03021024 | Mar 2003 | WO |
2004060093 | Jul 2004 | WO |
2005000055 | Jan 2005 | WO |
2005063071 | Jul 2005 | WO |
2005082188 | Sep 2005 | WO |
2005112677 | Dec 2005 | WO |
2007103244 | Sep 2007 | WO |
2007139567 | Dec 2007 | WO |
2007140054 | Dec 2007 | WO |
2008069280 | Jun 2008 | WO |
2008077785 | Jul 2008 | WO |
2008111294 | Sep 2008 | WO |
2009027701 | Mar 2009 | WO |
WO 2010036557 | Apr 2010 | WO |
2011046762 | Apr 2011 | WO |
2013181082 | Dec 2013 | WO |
Entry |
---|
[NPL-1] Districo—Bonding Yarns—GRILON® Fusible bonding yarns (Jul. 16, 2016); <http://districo.com/page—gb/bondingyarn.htm>. |
International Search Report and Written Opinion dated Sep. 19, 2013 and cited in PCT/US2013/034916. |
European Search Report and Witten Opinion mailed Mar. 6, 2012 for European Application No. 11174751.5 filed Jan. 27, 2010. |
European Search Report mailed Nov. 25, 2011 for European Application No. 12001388.3 filed Jan. 27, 2010. |
Examination Report dated Oct. 31, 2014 in European Patent Application No. 11174747.3. |
Extended European Search Report for European Application No. 11175063.4, mailed on Jan. 30, 2012. |
Humphries, Mary. Fabric Reference. Prentice Hall, Upper Saddle River, NJ. 1996. pp. 84-85. |
International Search Report and the Written Opinion for Application No. PCT/US2013/034901, mailed on Dec. 2, 2013. |
Final Office Action mailed Dec. 24, 2014 in U.S. Appl. No. 13/426,349. |
Notice to Terminate Reconsideration by Examiner before Appeal & Result of Reconsideration by Examiner dated Oct. 16, 2014. |
Notification of Reason(s) for Refusal dated May 29, 2014 in Japanese Patent Application No. 2012-534219. |
Office Action mailed Oct. 1, 2014 in U.S. Appl. No. 13/426,290. |
Office Action mailed Sep. 30, 2014 in U.S. Appl. No. 12/579,838. |
Response to Office Action Mar. 1, 2012 for U.S. Appl. No. 12/367,274, filed Feb. 6, 2009. |
Response to Final Office Action mailed Jul. 25, 2012 for U.S. Appl. No. 12/367,274, filed Feb. 6, 2009. |
Notification of Reason(s) for Refusal mailed May 29, 2014 for Japanese Application No. 2012-534219. |
Office Action mailed Jan. 6, 2014 for U.S. Appl. No. 13/045,168. |
Office Action mailed Feb. 7, 2013 for Japanese Application No. 2011225849 filed Oct. 13, 2011. |
Office Action mailed Feb. 7, 2013 for Japanese Application No. 2011549186 filed Aug. 1, 2011. |
Office Action mailed May 9, 2013 for Japanese Application No. 2011225827 filed Oct. 13, 2011 and the English translation thereof. |
Office Action mailed Nov. 11, 2013 for European Application No. 10779359.8. |
Office Action mailed Jun. 13, 2013 for Japanese Application No. 2011534219 filed Apr. 11, 2012 and the English translation thereof. |
Office Action mailed Feb. 14, 2013 for Japanese Application No. 2011225838 filed Oct. 13, 2011. |
Office Action mailed Jun. 14, 2012 for U.S. Appl. No. 12/579,838, filed Oct. 15, 2009. |
Office Action mailed Feb. 21, 2013 for Japanese Application No. 2011225846 filed Oct. 13, 2011. |
Office Action mailed Jan. 22, 2013 for Chinese Application No. 20108005095.6 filed Dec. 12, 2012. |
Office Action mailed Jan. 24, 2013 for European Application No. 11174751.5 filed Jan. 27, 2010. |
Partial European Search Report mailed Nov. 4, 2011 for European Application No. 11174751.5 filed Jan. 27, 2010. |
Partial Search Report for European Application No. 11174750.7, mailed on Nov. 4, 2011. |
Partial Search Report for European Application No. 11175063.4, mailed on Nov. 4, 2011. |
Response to European Office Action for European Application No. 11174751.5 filed May 16, 2014. |
Response to European Search Report and Written Opinion filed Sep. 21, 2012 for European Application No. 11174751.5 filed Jan. 27, 2010. |
Response to European Search Report filed Jan. 11, 2013 for European Application No. 11174747.3 filed Jan. 27, 2010. |
Response to European Search Report filed Aug. 13, 2012 for European Application No. 11175063.4 filed Jan. 27, 2010. |
Response to European Search Report filed Aug. 6, 2012 for European Application No. 11174750.7 filed Jan. 27, 2010. |
Response to Office Action filed Aug. 6, 2013 for Japanese Application No. 2011225849 filed Oct. 13, 2011 and the English translation thereof. |
Response to Office Action filed Aug. 7, 2013 for Japanese Application No. 2011549186 filed Aug. 1, 2011 and the English translation thereof. |
Response to Office Action filed Jul. 20, 2013 for Japanese Application No. 2011225846 filed Oct. 13, 2011 and the English translation thereof. |
Response to Office Action filed Jun. 10, 2013 for Japanese Application No. 2011225838 filed Oct. 13, 2011 and the English translation thereof. |
Response to Office Action filed Sep. 10, 2013 for Japanese Application No. 2011534219 filed Apr. 11, 2012 and the English translation thereof. |
Response to Office Action filed Aug. 29, 2013 for Japanese Application No. 2011225827 filed Oct. 13, 2011 and the English translation thereof. |
Voluntary Amendment filed Jan. 10, 2013 for Chinese Application No. 201080046286.7 filed Apr. 13, 2012. |
Voluntary Amendment filed Apr. 12, 2012 for Chinese Application No. 20108005095.6 filed Jul. 21, 2011. |
Voluntary Amendment filed May 15, 2012 for Japanese Application No. 2012534219 filed Apr. 11, 2012. |
Voluntary Amendment filed Oct. 25, 2011 for Japanese Application No. 2011549186 filed Aug. 1, 2011. |
Non-Final Office Action mailed Aug. 27, 2014 in U.S. Appl. No. 13/426,323. |
Decision to Grant Patent dated Aug. 14, 2014 in Japanese Patent Application No. 2011-225838. |
Notification of Reasons for Refusal dated Aug. 21, 2014 in Japanese Patent Application No. 2013-164367. |
Non-Final Office Action mailed Aug. 4, 2014 in U.S. Appl. No. 13/426,349. |
Advisory Action mailed Aug. 1, 2012 for U.S. Appl. No. 12/367,274, filed Feb. 6, 2009. |
Final Office Action mailed May 9, 2012 for U.S. Appl. No. 12/367,274, filed Feb. 6, 2009. |
Office Action mailed Dec. 1, 2011 for U.S. Appl. No. 12/367,274, filed Feb. 6, 2009. |
Partial European Search Report mailed Nov. 28, 2011 for European Application No. 11177097 filed Aug. 10, 2011. |
Response to Final Office Action mailed Jul. 25, 2012 for U.S. Appl. No. 12/368,274, filed Feb. 6, 2009. |
Response to Office Action mailed Mar. 1, 2012 for U.S. Appl. No. 12/368,274, filed Feb. 6, 2009. |
Chinese Office Action mailed Nov. 15, 2014 in Chinese Application No. 201080046286.7. |
Chinese Office Action mailed Apr. 28, 2015 for Chinese Application No. 201410041109.X. |
Co-pending U.S. Appl. No. 14/528,491, filed Oct. 30, 2014. |
Decision of Refusal mailed Jan. 26, 2015 for Japanese Patent Application No. 2011225846 filed Oct. 13, 2011. |
Decision of Refusal mailed Mar. 26, 2015 for Japanese Application No. 2011225849 filed Oct. 13, 2011. |
European Office Action mailed Nov. 28, 2014 in European Application No. 11174751.5 filed Jan. 27, 2010. |
European Office Action mailed Mar. 31, 2015 for European Patent Application No. 12718759.9. |
Final Office Action mailed Dec. 4, 2014 for U.S. Appl. No. 12/367,274, filed Feb. 6, 2009. |
Final Office Action mailed Feb. 23, 2015 for U.S. Appl. No. 12/579,838, filed Oct. 15, 2009. |
Final Office Action mailed Feb. 23, 2015 for U.S. Appl. No. 13/426,290, filed Mar. 21, 2012. |
Japanese Office Action mailed May 21, 2015 for Japanese Application No. 2013-164367. |
Notice of Allowance mailed Feb. 11, 2013 in European Patent Application No. 11174750.7 filed Jul. 20, 2011. |
Office Action mailed Mar. 26, 2015 for U.S. Appl. No. 13/426,361, filed Mar. 21, 2012. |
Partial European Search Report for European Application No. EP11175063, mailed on Nov. 4, 2011, 5 pages. |
Peter R.L., “Handbook of Yarn Technology,” in: Science, Technology and Economics. Boca Raton, Fla, Woodhead Publishing, 2003, pp. 56-61. |
Response to European Search Report mailed on Dec. 23, 2011 in European Patent Application No. 11174747.3. |
Chinese Office Action mailed May 6, 2015 for Chinese Application No. 201280012038.X. |
Chinese Office Action mailed May 25, 2015 for Chinese Application No. 201080046286.7. |
Final Office Action mailed May 19, 2015 for U.S. Appl. No. 13/426,323, filed Mar. 21, 2012. |
Non-Final Office Action mailed May 12, 2015 for U.S. Appl. No. 13/426,349, filed Mar. 21, 2012. |
Office Action mailed Aug. 31, 2015 for European Patent Application No. 11174751.5. |
Notice of Allowance mailed Sep. 3, 2015 for European Patent Application No. 12718759.9. |
Notice of Allowance mailed Aug. 25, 2015 for Japanese Patent Application No. 2011-225849. |
Office Action mailed Aug. 27, 2015 for Chinese Patent Application No. 201380029215.X) and the English translation thereof. |
Notice of Allowance mailed Sep. 15, 2015 for European Patent Application No. 13723278.1. |
Office Action mailed Jul. 24, 2015 for Chinese Patent Application No. 201380028031.1 and the English translation thereof. |
Office Action mailed Jul. 9, 2015 for Japanese Patent Application No. 2011-549186 and the English translation thereof. |
Office Action mailed Jul. 31, 2015 for Chinese Patent Application No. 201380029220.0 and the English translation thereof. |
Office Action mailed Jul. 24, 2015 for Chinese Patent Application No. 201380029223.4and the English translation thereof. |
Office Action mailed Sep. 4, 2015 in U.S. Appl. No. 13/426,290. |
Office Action mailed Sep. 2, 2015 in U.S. Appl. No. 12/367,274. |
Office Action mailed Oct. 30, 2015 in U.S. Appl. No. 12/579,838. |
Office Action mailed Sep. 24, 2015 in U.S. Appl. No. 13/426,323. |
Notice of Allowance mailed Sep. 23, 2015 in U.S. Appl. No. 13/426,349. |
Final Office Action mailed Oct. 27, 2015 in U.S. Appl. No. 13/438,520. |
Office Action mailed Aug. 17, 2015 in U.S. Appl. No. 13/438,520. |
Chinese Office Action mailed Jan. 10, 2014 and corresponding Search Report mailed Nov. 26, 2013 for Chinese Application No. 201080046286.7. |
Decision of Refusal mailed Jan. 30, 2014 for Japanese Application No. 2011-225838. |
European Office Action mailed Jan. 22, 2014 for European Application No. 11174751.5. |
European Search Report mailed Mar. 6, 2012 for European Application No. 11174751.5 filed Jan. 27, 2010. |
European Search Report mailed Jun. 11, 2012 for European Application No. 11174747.3 filed Jan. 27, 2010. |
European Search Report mailed Apr. 17, 2012 for European Application No. 11174753.1 filed Jan. 27, 2010. |
European Search Report mailed Nov. 25, 2011 for European Application No. 11174747.3 filed Jan. 27, 2010. |
Notice of Allowance mailed Aug. 1, 2014 in U.S. Appl. No. 13/482,182. |
European Search Report mailed Jan. 30, 2012 for European Application No. 11174750.7 filed Jan. 27, 2010. |
European Search Report mailed Jan. 30, 2012 for European Application No. 11175063.4 filed Jan. 27, 2010. |
Final Office Action mailed Nov. 28, 2012 for U.S. Appl. No. 12/579,838, filed Oct. 15, 2009. |
International Preliminary Report and Written Opinion for Application No. PCT/US2010/051149, mailed Apr. 26, 2012. |
International Preliminary Report for Application No. PCT/US2010/022216, mailed Aug. 18, 2011. |
International Preliminary Report for Application No. PCT/US2012/027974, mailed on Sep. 19, 2013. |
International Search Report and Written Opinion for Application No. PCT/US2010/022216, mailed Dec. 6, 2010. |
International Search Report and Written Opinion for Application No. PCT/US2010/034779, mailed Jan. 14, 2011. |
International Search Report and Written Opinion for Application No. PCT/US2010/051149, mailed Mar. 18, 2011. |
International Search Report and Written Opinion for Application No. PCT/US2012/027974, mailed Jul. 4, 2012. |
International Search Report and Written Opinion for Application No. PCT/US2013/042581, mailed on Sep. 30, 2013. |
Notice of Allowance mailed Feb. 1, 2013 for European Application No. 11174753.1 filed Jan. 27, 2010. |
Notice of Allowance mailed Feb. 1, 2013 for European Application No. 11175063.4 filed Jan. 27, 2010. |
Notice of Allowance mailed Oct. 10, 2013 for Japanese Application No. 2011-225827 filed Oct. 13, 2011. |
Notice of Allowance mailed Apr. 11, 2014 for U.S. Appl. No. 13/045,168. |
Notice of Allowance mailed Feb. 1, 2013 for European Application No. 11174750.7 filed Jan. 27, 2010. |
Notice of Allowance mailed Nov. 11, 2013 for Chinese Application No. 201080005095.6 filed Jan. 27, 2010. |
Notice of Allowance mailed Feb. 21, 2013 for Japanese Application No. 2011225851 filed Jan. 13, 2011. |
Notice of Allowance mailed May 22, 2013 for European Application No. 11174753.1 filed Jul. 20, 2011. |
Notice of Allowance mailed Jul. 24, 2012 for European Application No. 10734588.6 filed Jan. 27, 2010. |
Notification of Reason(s) for Refusal mailed May 1, 2014 for Japanese Application No. 2011-225846. |
Notification of Reason(s) for Refusal mailed May 22, 2014 for Japanese Application No. 2011-225849. |
Non-Final Office Action mailed Jul. 21, 2014 in U.S. Appl. No. 12/367,274. |
Extended European Search Report dated Jul. 17, 2014 in European Patent Application No. 14166582.8. |
Response to European Search Report mailed Dec. 23, 2011 for European Application No. 11174747.3 filed Jan. 27, 2010. |
Response to Final Office Action mailed Nov. 18, 2012 for U.S. Appl. No. 12/579,838, filed Mar. 13, 2013. |
Response to Office Action mailed Jun. 14, 2012 for U.S. Appl. No. 12/579,838, filed Sep. 14, 2012. |
Response to Office Action mailed Aug. 2, 2013for European Application No. 11174751.5 filed Jan. 27, 2010. |
Response to Office Action mailed Aug. 6, 2013 for Chinese Application No. 201080005095.6 filed Jul. 21, 2011 and the English translation thereof. |
International Preliminary Report on Patentability for PCT Application No. PCT/US2013/034931, mailed Oct. 16, 2014. |
International Preliminary Report on Patentability for PCT Application No. PCT/US2013/034916, mailed Oct. 16, 2014. |
International Preliminary Report on Patentability for PCT Application No. PCT/US2013/034901, mailed Oct. 16, 2014. |
International Preliminary Report on Patentability mailed Dec. 11, 2014 for PCT Application No. PCT/US2013/042581. |
Response to Result of Reconsideration filed Dec. 19, 2014 in Japanese Patent Application No. 2011-549186. |
Chawla, Krishan Kumar, “Fibrous Materials,” Cambridge University Press, p. 42 (1998). |
Final Office Action mailed Oct. 27, 2015, in U.S. Appl. No. 13/426,361. |
Invitation to Pay Additional Fees and, Where Applicable, Protest Fee (with Search Report) for Application No. PCT/US2013/034901, mailed Aug. 28, 2013. |
Non-Final Office Action in U.S. Appl. No. 12/367,274, mailed Nov. 29, 2016 (18 pages). |
Office Action, mailed Mar. 16, 2016, with English translation, for Korean Application No. 10-2014-7031180, (11 pages). |
Office Action for U.S. Appl. No. 14/528,491, dated Dec. 5, 2016 (6 pages). |
Response to Office Action filed Sep. 14, 2012 in U.S. Appl. No. 12/579,838. |
Third Chinese Office Action (English translation of relevant portions only) for Chinese Patent Application No. 2013800292200, dated approximately Jan. 3, 2017 (10 pages). |
Number | Date | Country | |
---|---|---|---|
20130260629 A1 | Oct 2013 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 12367274 | Feb 2009 | US |
Child | 13438535 | US |