The present application is a U.S. national stage application of International patent application PCT/IB2015/059821 filed on Dec. 21, 2015 designating the United States, and claims foreign priority to European patent application EP 14199873.2 filed on Dec. 22, 2014, the contents of both documents being herewith incorporated by reference in their entirety.
The invention relates to micro-embossing with an embossing roller on thin industry papers such as inner liners, i.e., cigarette pack inner liner. Micro-embossing relates to the creation of embossment with sizes—periodicity of diffraction gratings—in the range smaller than 30 μm.
Micro-embossing of paper is commonly known and described, for example in U.S. Pat. No. 5,862,750 to Dell'Olmo.
In Dell'Olmo, the embossing parameters are as follows:
The embossing parameters of Dell'Olmo limit the production rate and speed because of the heating, humidifying and de-humidifying cycle. This production rate typically reaches approximately 60 m per minute.
The embossing processing device of Dell'Olmo has outer dimensions comparable to that of a room because the device requires a humidifying station and a drying station to reach the required humidity parameters for the paper.
The international publication WO 2006/016004 A1 describes a complex alternative to what is known from U.S. Pat. No. 5,862,750. However to the knowledge of the inventors, this has never been realized in production.
In this prior art reference, embossing parameters may be as follows:
While the embossing parameters are much easier to realize than in U.S. Pat. No. 5,862,750, e.g., less heating, less pressure, the process of Avantone remains prohibitively complicated due to the process of photolithography employed.
Publication U.S. Pat. No. 7,624,609 B2 discloses a system for roll embossing of discrete features. Various embodiments of the system are discussed in which a patterning feature is left displaced from the remaining cylindrical part of the work roll, thereby creating a localized surface region in the form of a plateau feature. The system allows to cause an intensification of the pressure that is localized to the surface region in form of the plateau feature, this local increase in pressure resulting in an improved pattern transfer across the plateau feature. According to the applicant the contact pressures are then sufficient to allow the transfer of very fine scale topographic features, for example diffraction gratings.
The described process omits to disclose essential parameters such as quality of bulk foil or inner liner material and requires a plurality of roller stands, hence preventing useful application for industrial applications.
Items to be embossed may generally be either inner liners—cigarette pack inner liners—or foils, which may generally be called thin foils.
Foils typically may have a thickness from about 5 μm to about 400 μm and may be thin metal foils, e.g., aluminum foils, laminates made out of paper and/or plastic layers and metal foils, and metallized paper or metallized laminates similar substances.
Such foils may in some cases be used as inner liners, which are used, e.g., in cigarette packaging—cigarette pack inner liners—and may be made out of metal coated paper, e.g., vapor coated base paper or aluminum layered paper.
Such foils may be metallic pieces in shape of eleongated stripes to be microembossed and subsequently processed.
These foils and inner liners are thus thin and relatively un-elastic, i.e, very hard. They are often particularly adapted for food safe packaging because they are to a high degree impermeable to water vapor.
Foils and inner liners can be directly and quickly embossed using rollers with hard steel surfaces, such as is the case in the above cited Dell'Olmo prior art.
In addition to the embossing problems encountered in Dell'Olmo, a number of further problems are found when producing custom shaped patterns on inner liners by means of embossing, which result in an insufficient quality.
Custom shaped patterns may occupy a relatively large surface, and high pressure required for the embossing of such patterns may affect the sandwiched layer structure of the inner liners. At high temperature the affected sandwiched layer structure becomes damaged and causes a lacquer stain to occur on the back side of the paper.
In case a plurality of custom shaped patterns are embossed on the same surface of the inner liner, the paper may easily wrinkle due to a variable local extension of the paper. This is particularly troublesome as the density of custom shaped patterns increases.
Various solutions have been proposed in prior art to address the problem of a constant esthetically pleasing embossing of custom patterns and the problem of wrinkling. For example, US patent publication US 2008060405 A1 and international publication WO 93 23197 A1 disclose solutions that allow obtaining a desirable density of patterns which is relatively high. However these solutions restrict themselves to niche applications, such as the embossing of bank notes, but are inadequate for an industrial use, such as for example in the tobacco industry.
It is an aim of the present invention to address the problems encountered in prior art embossing methods and devices. This is in particular achieved through an appropriate adjustment of the embossing parameters—particularly relatively low embossing forces and pressures at room temperature to avoid pre-heating, accordingly choosing adequate roller manufacturing and surface technology and adequate inner lining or foil materials, and also choosing specific geometries and sizes of gratings to obtain good quality embossing results.
In a first aspect, the invention provides a method for embossing optically diffracting microstructures in a thin foil, such as used to pack at least one of the list comprising food, chocolate, chewing gum, gifts, jewellery, clothes, tobacco products, pharmaceutical products, the embossing being produced with an embossing rollers set-up comprising at least one cylindrical embossing roller and a cambered counter roller. The method comprises confining the at least one cylindrical embossing roller and the cambered counter roller in a single roller stand of relatively small outer dimensions designed to withstand a pressure for the at least one cylindrical embossing roller and the cambered counter roller; using on a surface of a first one of the at least one cylindrical embossing rollers at least one raised embossing element adapted for microstructure embossing, whereby one of the at least one raised embossing elements comprises a platform distant at a height in a range between 5 μm and 30 μm above a surrounding surface of the first cylindrical embossing roller adjacent to it, and a pattern engraved on top of the platform, whereby the pattern comprises the optically diffracting microstructures with periodicity of gratings in the range smaller than 30 μm that produce from a diffuse or directed source of light in the visible wavelength range diffraction images with high contrast and high luminosity in a defined observation angle; and adjusting the pressure for the at least one cylindrical embossing roller on the thin foil in a range less than 80 bar relative to a platform area of approximately 100 mm2.
In a preferred embodiment the method further comprises selecting the thin foil from one or more of the list comprising: thin metal foil, laminate made out of a paper and/or at least a plastic layers and a least a metal foil having different dielectric behavior.
In a further preferred embodiment the thin foil is a laminate that comprises paper and a metal foil or plastic film, and has a grammage of about 20 to 90 g/m2.
In a further preferred embodiment the thin foil is a laminate that comprises a metallized paper or a metallized plastic film, and has a grammage of about 40 to 90 g/m2.
In a further preferred embodiment the thin foil is made of aluminum.
In a further preferred embodiment the method further comprises providing on the surface of a further one of the at least one cylindrical embossing rollers, a macro-pattern arranged to emboss satinating macro-structures on the thin foil.
In a further preferred embodiment the macro-pattern is obtained by a pin-up, pin-up embossing.
In a second aspect the invention provides a use of a thin foil from one of the list at least comprising thin metal foil, laminate made out of paper and/or at least a plastic layer and at least a metal foil, in an embossing process with at least one cylindrical embossing roller and a cambered counter roller. The use comprises confining the at least one cylindrical embossing roller and the cambered counter roller in a single roller stand enclosure of relatively small outer dimensions designed to withstand a pressure for the at least one cylindrical embossing roller and the cambered counter roller; using on a surface of the at least one cylindrical embossing rollers at least one raised embossing element adapted for microstructure embossing, whereby one of the at least one raised embossing elements comprises a platform distant at a height in a range between 5 μm and 30 μm above a surrounding surface of the at least one cylindrical embossing roller adjacent to it, and a pattern engraved on top of the platform, whereby the pattern comprises optically diffracting microstructures with periodicity of gratings in the range smaller than 30 μm that produce from a diffuse or directed source of light in the visible wavelength range diffraction images with high contrast and high luminosity in a defined observation angle; and adjusting the pressure for the at least one cylindrical embossing roller on the thin foil in a range less than 80 bar relative to a platform area of approximately 100 mm2.
The invention will be better understood in light of the description of preferred embodiment and in view of the appended drawings, wherein
A surface of a micro-embossing roller for embossing a thin foil comprises at least one raised embossing element. The raised embossing element comprises a platform that is distant from the surface of the embossing roller adjacent to the raised embossing element by a distance between 5 μm and 30 μm. A pattern intended to be embossed on the thin foils is engraved on top of the platform. This pattern is typically a light diffracting one using gratings.
The effect of using the raised embossing element is that the total force required to be applied on the embossing roller may be reduced for a same local embossing pressure—as compared to having the pattern directly on the surface of the embossing roller.
Optionally it is possible to have on the surface of the embossing roller surrounding the raised embossing element, or between a plurality of raised embossing elements, additional structures with the aim of glazing the thin foil. This has the effect, when looking at light reflected from the embossed thin foil, on one hand of providing an improved difference of contrast between parts embossed with the raised embossing elements and parts glazed, and on the other hand of improving the perceived brilliance of diffracted patterns.
The invention requires a hard and elastic embossing surface in order to perform high speed rotational embossing. An example of speeds to be achieved corresponds to the embossing of inner liners for approximately 1000 packs of cigarettes per minute.
International publication WO 2010/111798 A1 and International publication WO 2010/111799 A1—both to the applicant of the present invention, and incorporated herein by reference—disclose to use the super hard material ta-C as layer for embossing rollers, the layer being deposited as a coating, whereby the super hard material ta-C stands for hard materials representatively.
The super hard ta-C layer is an amorphous carbon film, which has shown to be very suitable for various applications, more particularly for tribological applications but also for optical diffraction applications. In particular the ta-C layer enables laser engraving to be made without deterioration of the surface by heat conduction or the like.
The publications discuss machining parameters appropriate for structuring the ta-C layer on the embossing roller, whereby lasers are used.
More precisely two lasers are used for micro- and nanostructuring the ta-C layers on the embossing rollers. The first laser, e.g., a KrF excimer laser having a wave-length of 248 nm, produces microstructures in the ta-C layer according to the mask projection technique, and the second laser, a femtosecond laser having a center wavelength of 775 nm, produces nanostructures in the ta-C layer according to the focus technique.
The microstructures produced may be, e.g., trench-shaped grating structures having grating periods of 1 to 2 μm, and the nanostructures may be, e.g., self-organized ripple structures having periods of approximately 700 nm which act as an optical diffraction grating. In this respect, any periodic array of the optical diffraction active structures is possible that produces angular-dependent dispersion, i.e., a separation into spectral colors, by diffraction upon irradiation with poly-chromatic or white light.
For the microstructures, the following machining parameters are disclosed, e.g., appropriate for structuring the ta-C layer on the embossing roller: pulse repetition frequency of the excimer laser 30 Hz, laser beam fluence on the layer 8 J/cm2, number of laser pulses per basic area 10. The term basic area is used here to designate the surface on the embossing roller or embossing die that is structured by the laser beam shaped by the mask and the diaphragm and imaged onto the ta-C coated embossing roller surface in a laser beam pulse train (pulse sequence) without a relative movement of the laser beam and the roller surface.
Microstructured ripples are produced in the ta-C layer on the embossing roller by scanning the surface line-by-line, the line offset being preferably chosen such that the line spacing corresponds to the spacing of the individual pulses along the line. More precisely, ripples result from a self-organizing effect caused by laser irradiation at a determined wavelength. The width and depth of the ripple related microstructures depend on the wavelength but also other parameters.
Microstructures may further be produced by means of direct writing with a laser beam.
The invention requires a method for producing a structured surface on a steel embossing roller.
International publication WO 2013/041430 A1—to the applicant of the present invention, and incorporated herein by reference—discloses such method for producing the structured surface the steel embossing roller.
More precisely the problem addressed in WO 2013/041430 A1 is to produce fine surfaces with macrostructures on steel embossing rollers fast and precisely, thereby allowing a great diversity of design possibilities, e.g., variable tooth spacing and shapes, as well as the industrial manufacture of male-female rollers as well as a versatile application for the most diverse foil materials.
The invention described in WO 2013/041430 A1 indicates which particular parameters may be adopted for a suitable control of the ablation process under specific conditions. WO 2013/041430 A1 describes a parameter combination that enables one skilled in the art to implement the engraving of steel rollers in the reproduction accuracy and quality required for micro-embossing technology.
For example WO 2013/041430 A1 describes a method for producing a structured surface on a steel embossing roller by means of short pulse laser, the structuring being a micro-structuring with dimensions of about 20 μm.
The invention requires a housing with a set of embossing rollers wherein very high pressures may be achieved.
Embossing housings normally lodge the embossing rollers that stand under mutual pressure. The housing may also be designated either as roller stand, roller frame or embossing head. Throughout the description the term roller stand will be used.
International publication WO 2014/045176 A2—to the applicant of the present invention, and incorporated herein by reference—discloses a roller stand and set of embossing rollers, and a method for obtaining such a set of cooperating embossing rollers.
In the method for producing a set of cooperating embossing rollers, a modeling device is used for parameterizing the embossing rollers, the device comprising a test bench having a pair of rollers which are put under hydraulic pressure that can be measured and set, in order to determine from the measurement data the parameters for producing the embossing rollers. The use of the modeling device for obtaining the parameters for producing the set of embossing rollers makes it possible to use a very large variety of embossing patterns and foils with diverse properties as a basis and, by conducting tests on this very test bench, be able to efficiently narrow down and predetermine the properties of a final embossing device, preferably operated without hydraulics.
One embodiment of the modeling device in WO 2014/045176 A2 has two rollers with hardened metal axis that have hydrostatic bearings and pressure bags, and makes it possible by adjusting the hydraulic pressure exerted on the bearings and pressure bags, to determine the bending of the axis. The optimal contact pressure is esthetically adjusted through trial with a pattern corresponding to the embossing roller and the foil to be used, and the hydraulic counter pressure is measured in the bearings and pressure bag. From this obtained data about the embossing roller stand it is possible to compute the parameters for the geometry of the embossing and counter rollers of the commercial embossing head to be realized. The assessment of the quality and the rating of the embossing is made by optical means by comparing the desired optical effect on the embossing roller and the esthetic result at the embossing on the foil.
The aim of the computing is to determine the geometry of the rollers in the final pure mechanical roller stand, corresponding to the embossing rollers in such a manner that when a determined foil is embossed with a determined embossing structure, even if very small embossing elements and high embossing pressures are used, a homogenous embossing is achieved across the whole width of the foil. A camber of one of the embossing rollers will help compensate the mechanically caused bending of the rotation axis. This way a continuous pressure may be achieved throughout the whole surface of the embossing rollers.
The technology described in WO 2014/045176 A2 enables very high pressures, no required heating of the roller, relatively small outer dimensions of the roller stand that makes it possible to use this in industrial production chains, e.g., in the tobacco industry. In a preferred embodiment, the relatively small outer dimensions of the roller stand are approximately 20×40×60 cm.
The desired pressure for realizing the present invention lies around 15000 N for each bearing on a surface of 150 mm long and 1 mm wide—the roller would have a diameter of about 700 mm.
The invention provides a method for embossing thin foils with at least a diffraction pattern engraved on a raised embossing element of the embossing roller. The thin foils to emboss may be packaging material consisting of foils or cigarette pack inner liner. The embossed thin foils may be used to pack food, chocolate, chewing gum, gifts, jewelry, clothes, tobacco products, pharmaceutical products, etc.
The inventive method for embossing operates at room temperature. The embossing roller device used to implement the method for embossing comprises in a preferred embodiment a pair of rollers, whereby
The embossing roller device can for example be modeled and realized by making use of the technology known from WO 2014/045176 A2, which is briefly discussed in a section herein above. This allows in particular to model and realize the first roller and the second roller, such that the pressure required for embossing the pattern may be obtained. In a preferred embodiment the second roller may be the driving motorized roller.
The pattern on top of the at least one raised embossing element may be realized using technology from WO 2010/111798 A1, WO 2010/111799 A1 and WO 2013/041430 A1, which is also briefly discussed in corresponding section herein above. In particular this includes providing a hard material surface on top of the raised embossing element, made for example of a ta-C layer. Also this includes engraving the hard material surface by making use of mask projection technique and/or focus technique for microscopic structures, and/or macro structuring techniques, as described and known from WO 2010/111798 A1, WO 2010/111799 A1 and WO 2013/041430 A1.
The raised embossing element's platform has a height in a range between 5 μm and 30 μm above the adjacent surrounding surface of the roller.
The pattern obtained by engraving the hard material surface of the platform comprises optically diffracting micro-structure, examples of which are described in a dedicated section of the present description.
However
The following describes examples configuration of embossing rollers and roller stands.
U.S. Pat. No. 6,176,819 B1 which is incorporated herein by reference illustrates an other possible embodiment of a device for embossing that enables the embossing of macroscopic structures according to the pin-up/pin-up embossing method. The embossing process is effected between a pair of embossing rollers provided with tooting of the same kind which comprises rows of pyramidal teeth extending in the axial and the circumferential directions. The device described in U.S. Pat. No. 6,176,819 B1 may very well be used as example to derive an adapted configuration for macroscopic embossing in the present invention.
In a preferred embodiment partially represented in the figures, the embossing results may be obtained from a configuration of rollers departing from that shown in
The present section describes examples of grating structures to be achieved through roller embossing of foils and inner liners surfaces, by making use of rollers with raised embossing elements that are obtained through processes as explained in the present description.
The grating structures to be achieved are to be used as reflective structures, and comprise ripple gratings, groove-land—see for example
The gratings structure are used to create patterns, which are optical diffractive microstructures. The latter produce when illuminated by diffuse or directed light in the visible spectrum, diffraction images with high contrast and high brilliance if observed in a determined angle.
The Gratings
In the following the terms contrast, luminosity and perception of color are defined for the sake of clarity as to the meaning they have throughout the present description.
Contrast
Noticeable optical effects can be obtained and enhanced according to the following facts:
The patterns to be embossed in the foils and inner liners comprise various gratings with a variety of different geometries. In the following we will review a number of preferred embodiments of patterns and/or gratings that constitute the patterns. It is to be noted that the optical resolution of the human eye is approximately 200 μm. However, in case the colors that occur from the diffraction at the reflective gratings are perceived as very brilliant, it has been found that the limit of optical resolution may be raised in the range of 70 μm to 100 μm.
An approximately square or rectangle surface with sides measuring in a range between 70 μm and 100 μm or an approximately circular or oval shaped surface having a diameter in the same range is the minimal size of surface to produce spectral or mixed colors with diffraction gratings.
In order to make these colors have a subjectively perceived brilliance of sufficient intensity, the surface observed by the user should be chosen to be much larger than the minimal size, for example by juxtaposing a plurality of such color pixels—a color pixel is a surface having the minimal size—that diffract the colors in the same direction of observation, or in the same plurality of directions of observation depending on the case.
The size of the surface to be observed should be in the range of at least one square millimeter up to one square centimeter in order to achieve a good, subjectively perceived brilliance. It is important for the brilliance subjectively perceived by the user to adjust the contrast in comparison to surrounding surface and to the size of the latter in proportion to the surface to be observed.
An embossed logo that needs to be perceived as brilliant should preferably be surrounded by areas of surface that diffract or scatter with a lesser intensity or in a different direction, or if a ta-C layer is used do not diffract at all. The surrounding areas of surface should thereby surround the surface to be observed, forming stripes and the proportion of surfaces to be observed vs surrounding areas of surface should be in the range of 1 to 3.
The indicated sizes of surfaces and proportion of surfaces have been determined under empirical measurements.
Possible basic geometries for diffractive gratings that may be produced through the mask projection technique—as explained in a section herein above—are listed here under:
It is also possible in the mask projection technique to use basic geometrical shapes as apertures, the latter being used in the mask projection technique to produce various shapes of surfaces as basic surface areas and may be positioned next to one another to make images. Such basic geometrical shapes include: square;
A number of the named geometries are illustrated in the figures.
First we will address aperture geometries.
The following
The following shapes in
Secondly we will address mask geometries.
The mask geometries are to shape laser intensity profiles—laser fluency profiles—to realize reflection-diffraction-gratings on solid matter surfaces. The mask is preferably to be positioned in the homogeneous spot of the laser beams mask projection system.
The areas in
A number of basic geometries for diffractive gratings that may be produced through the mask projection technique, i.e., laser ablation, are shown in the following list of
The illustrated examples are not exhaustive of images, patterns and gratings to be engraved on the platform of the raised embossing element and then embossed in the foil and/or inner liners.
For the purpose of producing an impress, raised (land) diffraction grating structures that are obtained with mask geometries according to
The mask geometries according to
The dimension of the structures of the mask geometries, e.g., grating periods of the groove structures, influence under which observation angle the orders of diffraction of individual wavelengths of the white light spectrum (the illumination of the grating) may appear. For example, to make the 3 visible parallelogram surfaces of a cube visible in various colors under the same observation angle and from a same observation direction, for a same orientation of the diffracting grating structure, for example of the grooves and lands, the period of the structure for the observation angle(s) and the desired color (for example red, green, blue) must be calculated for the respective visible surface of the cube, and accordingly differently be chosen at the time of structuring, so that the three parallelograms that make up the cube are perceived under different colors at the same angle of observation and same intensity.
When illuminating with white light of the whole structured surface, the color and intensity patterns/shapes that may be visible under same observation direction and same observation angle, are imposed by the orientations and periods of the structures of the diffracting mask structures in the surfaces of the simple or complex composed shapes of basic areas of diffraction. Herewith it is possible to generate a plurality of color patterns but also colored image representations. When inclining or rotating the whole structured surface, various corresponding color and intensity variations occur in the color patterns and the colored image representations—these can also be predetermined to some extent. It is hence possible in this manner by using linear of circular shaped arrangements of a plurality of successively moving structures of motives to make a movement of the motives appear when the whole structured surface is inclined or rotated.
According to the invention, the foils or inner liners need to be carefully selected to obtain the desired result. The latter may be described as the production of micro embossing in the foils or inner liners that enable good contrast and brilliance when the foil or inner liner is illuminated with normal daylight.
A solution has been found for the following relevant types of inner liners comprising:
With the use of raised embossing elements on rollers, and appropriately chosen patterns/logos—considering the size and the engraving—on the raised embossing elements, the invention produces best results when using for the foils and inner liners the following:
It is noted that for higher grammages, e.g., a foil/paper laminate of 6.3 μm/50 g/m2 and, e.g., 70 g/m2 metallized paper and embossing pressure of about 60 to 80 bar is sufficient to obtain a very good embossing result.
The following parameters are important to obtain a good quality of perceived color impression at the embossed foil and inner liner:
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14199873 | Dec 2014 | EP | regional |
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