The present application and the resultant patent relate generally to gas turbine engines and more particularly relate to a mobile selective catalyst reduction system for controlling nitrogen oxides and other types of emission in hot combustion gases produced by a gas turbine.
In the combustion process of a gas turbine engine, nitrogen oxides and other types of regulated emissions are produced. Specifically, a simple cycle gas turbine emits hot flue gases that contain unacceptable levels of nitrogen oxides. One solution for reducing the overall levels of nitrogen oxide emissions is the use of a selective catalyst reduction system. Generally described, the selective catalyst reduction system adds a reductant, typically ammonia or urea, to the hot combustion gas stream before passing the combustion gas stream through a catalyst bed so as to absorb selectively the nitrogen oxides and the reducing agent. The absorbed components undergo a chemical reaction on the catalyst surface and the reaction products are desorbed. Specifically, the reactant reacts with the nitrogen oxides in the combustion gas stream to form water and nitrogen. Other types of catalysts and other types of reductants may be used.
The overall efficiency of the selective catalyst reduction system may depend at least in part on the temperature of the hot combustion gas stream. Specifically, the efficient temperature range of the selective catalyst reduction system may be relatively narrow. As such, the hot combustion gas stream generally should be sufficiently cooled before reaching the catalyst bed. Moreover, careful metering and distribution of the reductant to the combustion gas stream upstream of the catalyst bed may be required for the selective catalyst reduction system to convert and remove a sufficient level of the nitrogen oxides.
Mobile, simple cycle combustion turbine-generators may be delivered and operated at remote locations with immediately power needs. These combustion turbine-generators may require emission control systems to minimize nitrogen oxide emissions from the combustion turbine so as to meet applicable emission requirements. The exhaust gas quality and the overall design of the exhaust systems in these simple cycle combustion turbines, however, may not be suitable for treatment by known types of selective catalyst reduction technology. Specifically, selective catalyst reduction technology generally may be applied to simple cycle turbine exhaust after cooling treatments also have been applied. Selective catalyst reduction technology also may require ammonia reagent delivery systems and catalyst layers. The common delivery of a selective catalyst reduction system thus generally requires substantial erection, assembly, and other basic construction activities at the final turbine-generator location. Often, there may be limited skilled labor available at the remote location to perform the construction and it may be expensive to bring sufficient skilled labor to such a remote location. The design and construction methods used for these common selective catalyst reduction systems thus may make them substantially unsuitable for transport.
The present application and the resultant patent thus provide a mobile selective catalyst reduction system for use at a remote location. The mobile selective catalyst reduction system may include a first trailer with an ammonia delivery system and a tempering air system mounted thereon in whole or in part and a second trailer with a selective catalyst reduction section mounted thereon in whole or in part. The ammonia delivery system, the tempering air system, and/or the selective catalyst reduction section are permanently mounted on the first trailer or the second trailer for use at the remote location.
The present application and the resultant patent further provide a method of providing selective catalyst reduction to a flow of combustion gases produced by a turbine engine. The method may include the steps of mounting an ammonia delivery system and a tempering air system of a selective catalyst reduction system on a first trailer, mounting a selective catalyst reduction section of the selective catalyst reduction system on a second trailer, transporting the first trailer and the second trailer to the turbine engine, connecting the selective catalyst reduction section, the ammonia delivery system, and the tempering air system at the turbine engine, and connecting the selective catalyst reduction system to the turbine engine.
The present application and the resultant patent further provide a mobile selective catalyst reduction system for use at a remote location. The mobile selective catalyst reduction system may include a first trailer with an ammonia skid and a tempering air skid mounted thereon and a second trailer with a selective catalyst reduction section and an exhaust duct mounted thereon in whole or in part.
These and other features and improvements of the present application and the resultant patent will become apparent to one of ordinary skill in the art upon review of the following detailed description when taken in conjunction with the several drawings and the appended claims.
Referring now to the drawings, in which like numerals refer to like elements throughout the several views,
The gas turbine engine 10 may use natural gas, various types of syngas, liquid fuels, and/or other types of fuels and blends thereof. The gas turbine engine 10 may have different configurations and may use other types of components. Other types of gas turbine engines also may be used herein. Multiple gas turbine engines, other types of turbines, and other types of power generation equipment also may be used herein together.
The gas turbine engine 10 also may include a selective catalyst reduction system 45. The selective catalyst reduction system 45 may be positioned downstream of the turbine 40. As described above, the selective catalyst reduction system 45 may include a catalyst 50 therein so as to react with the combustion gas stream 35. The catalyst 50 may be of conventional design and may be manufactured from suitable carrier and active catalytic components. Different types of catalysts 50 may be used herein. The catalyst 50 may have any suitable size, shape, or configuration. The selective catalyst reduction system 45 may extend from an inlet 55 to a stack 60 or other type of exhaust. An ammonia injection grid 65 may be positioned about the catalyst 50 so as to inject a reductant such as ammonia into the combustion gas stream 35. The ammonia injection grid 65 may be in communication with an ammonia source 70. The ammonia injection grid 65 may be in communication with the ammonia source 70 via an extensive piping system to produce an adequate ammonia distribution into the incoming combustion gas stream 35. The stack 60 or other type of exhaust may be positioned downstream of the catalyst 50.
The selective catalyst reduction system 45 also may include a tempering air system 75. The tempering air system 75 may reduce the temperature of the combustion gas stream 35 with the introduction of ambient air 20 and the like before the stream 35 reaches the catalyst 50. The tempering air system 75 may include a tempering air grid 80 positioned about the inlet 55 of the selective catalyst reduction system 45 and upstream of the ammonia injection grid 65 and the catalyst 50. The tempering air grid 80 may be in communication with a source of ambient air 20 via a tempering air fan 85 or other type of air movement device. A gas mixer 90 may be positioned downstream of the tempering air grid 80. The gas mixer 90 may include a series of baffles and the like. The gas mixer 90 may mix the incoming combustion gas stream 35 and the ambient air 20 so as to obtain an adequate temperature distribution therein. The now cooled flow then may flow past the ammonia injection grid 65 and the catalyst 50 for reaction therewith. The selective catalyst reduction system 45 described herein is for the purpose of example only. Many other types of selective catalyst reduction systems and components may be used herein.
The mobile selective catalyst reduction system 100 may include one or more inlet ducts 130 in communication with the hot combustion gas steam 35 from the gas turbine engine 10. In this example, a first inlet duct 140 and a second inlet duct 150 in a perpendicular orientation are shown, although any number or configuration may be used. The inlet ducts 130 may be substantially assembled prior to transport with only minor connections required on site. The inlet ducts 130 may have any suitable size, shape, or configuration.
A selective catalyst reduction section 160 may be positioned downstream of the inlet ducts 130. The selective catalyst reduction section 160 may include an SCR inlet transition section 170 and an SCR outlet transition section 180. A rectifier layer 190 and a catalyst 200 may be positioned between the SCR inlet transition section 170 and the SCR outlet transition section 180. The rectifier layer 190 and the catalyst 200 may be of conventional design and may be manufactured from suitable carrier and active catalytic components. Different types of catalysts 200 may be used herein in any suitable size, shape, or configuration. In this example, the SCR transition sections 170, 180 may have substantially opposing triangular shapes with the SCR inlet transition section 170 narrowing along its length towards the rectifier layer 190 and the catalyst 200 and the SCR outlet transition section 180 expanding therealong. The SCR transition sections 170, 180 may have any suitable size, shape, or configuration. The SCR outlet transition section 180 and the catalyst 200 may be permanently mounted onto the SCR trailer 120 with the SCR inlet transition section 170 and the rectifier layer 190 being transported separately and assembled on site. Other components and other configurations may be used herein.
An exhaust duct 210 may be positioned downstream of the selective catalyst reduction section 160. The exhaust duct 210 may have an exhaust inlet 220 and a perpendicular exhaust outlet 230. The exhaust duct 210 and the components thereof may have any suitable size, shape, or configuration. The exhaust inlet 220 of the exhaust duct 210 may be permanently mounted onto the SCR trailer 120. An exhaust silencer 240 may be positioned downstream of the exhaust duct 210. The exhaust silencer 240 may be of conventional design and may have any suitable size, shape, or configuration. Other components and other configurations may be used herein.
The mobile selective catalyst reduction system 100 may include an ammonia delivery system 250. The ammonia delivery system 250 may include an ammonia vaporization skid 260. The ammonia vaporization skid 260 may be permanently mounted on the skid trailer 110. An ammonia vaporizer 270 may be positioned on the ammonia vaporization skid 260. The ammonia vaporizer 270 may be of conventional design and may have any suitable size, shape, or configuration. One or more dilution air blowers 280 may be positioned on the ammonia vaporization skid 260. The dilution air blowers 280 may be of conventional design and may have any suitable size, shape, or configuration. The dilution air blowers 280 may receive a flow of dilution air from the selective catalyst reduction section 160 in a dilution air pipe 290 or elsewhere for use in the ammonia vaporizer 270. The components of the ammonia vaporization skid 260 may be permanently mounted onto the skid trailer 210.
The ammonia delivery system 250 may include an ammonia injection grid 300. The ammonia injection grid 300 may be positioned on the inlet duct 130 upstream of the catalyst 200. The ammonia injection grid 300 may be in communication with the ammonia vaporizer 270 via an ammonia inlet pipe 310 and the like. The ammonia injection grid 300 may include a number of ammonia nozzles 320 positioned within the inlet duct 130. The ammonia injection grid 270 and the ammonia nozzles 320 may have any suitable size, shape, or configuration. A number of mixing vanes 325 and the like may be positioned downstream of the ammonia nozzles 320. The mixing vanes 325 may include a series of baffles and the like. The mixing vanes 325 may have any suitable size, shape, or configuration. The ammonia injection grid 310 may be attached to the inlet duct 130 prior to transport and connected to the ammonia vaporization skid 260 and the components thereof on site. Other components and other configurations may be used herein.
The mobile selective catalyst reduction system 100 may include a tempering air system 330. The tempering air system 330 may include a tempering air skid 340. The tempering air skid 340 may be permanently attached to the skid trailer 110. The tempering air skid 340 may include an air filter 350 and one or more blowers 360 positioned thereon. The air filters 350 and the blowers 360 may be of conventional design and may have any suitable size, shape, or configuration. The tempering air system 330 may include a tempering air duct 370 and the like. The tempering air duct 370 may connect the air blowers 360 and the inlet duct 130 so at provide a flow of tempering air thereto. The tempering air duct 370 may have any suitable size, shape, or configuration. The tempering air duct 370 may be transported separately from the tempering air skid 340 and then may be connected on site. Other components and other configurations may be used herein.
In use, the ammonia injection skid 260 and the tempering air skid 340 may be permanently attached to the skid trailer 110. Likewise, the SCR outlet transition section 180 and the exhaust inlet 220 of the exhaust duct 210 may be permanently attached to the SCR trailer 120. In this example, the ammonia inlet piping 310 and the tempering air ducts 370 may be transported on a third trailer 380; the inlet ducts 130 may be transported on a fourth trailer 390; and the SCR inlet transition section 170 may be transported on a fifth trailer 400. Other components may be mounted in other configurations and/or on other trailers and/or other means of transport. Once on site, the components of the skid trailer 110 and the SCR trailer 120 may be connected and the remaining components may be attached thereto. The mobile selective catalyst reduction system 100 then may be connected to the gas turbine engine 10 and the like for emissions control operation as is described above. Other components and other configurations may be used herein.
The mobile selective catalyst reduction system 100 thus may be transported and assembled in a quick and efficient manner in any type of remote location that may be reached via conventional trailers, tractors, and the like. Moreover, transport via rail, sea, air, and/or combinations thereof also could be used herein. The mobile selective catalyst reduction system 100 provides for the assembly of complex or time consuming components where convenient with later transport to the remote location. The mobile selective catalyst reduction system 100 thus may provide efficient emissions control with a significant reduction in time and overall expense. We note that by stating that a component is “permanently” mounted to a trailer, we mean that the component is fixedly attached to the trailer such that the component does not need to be separated again from the trailer before operations begin.
It should be apparent that the foregoing relates only to certain embodiments of the present application and the resultant patent. Numerous changes and modifications may be made herein by one of ordinary skill in the art without departing from the general spirit and scope of the invention as defined by the following claims and the equivalents thereof.
Number | Name | Date | Kind |
---|---|---|---|
3441382 | Schreuders | Apr 1969 | A |
4131432 | Sato | Dec 1978 | A |
4726935 | Inatsune | Feb 1988 | A |
4925640 | Morii | May 1990 | A |
4992669 | Parmley | Feb 1991 | A |
5043146 | Ishikawa | Aug 1991 | A |
5330728 | Foster | Jul 1994 | A |
5431893 | Hug | Jul 1995 | A |
5881553 | Steenackers | Mar 1999 | A |
6334746 | Nguyen | Jan 2002 | B1 |
6571420 | Healy | Jun 2003 | B1 |
6765304 | Baten | Jul 2004 | B2 |
6786051 | Kristich | Sep 2004 | B2 |
6893487 | Alger | May 2005 | B2 |
7097814 | Shishido | Aug 2006 | B2 |
7122913 | Witten | Oct 2006 | B2 |
7303730 | Shishido | Dec 2007 | B2 |
7638107 | Wirt | Dec 2009 | B1 |
8092746 | Salasc | Jan 2012 | B2 |
8495869 | Beissler | Jul 2013 | B2 |
8516786 | Zhang | Aug 2013 | B2 |
8925470 | Hart | Jan 2015 | B2 |
9283520 | Ishikawa | Mar 2016 | B2 |
9677447 | Isada | Jun 2017 | B2 |
9694315 | Hjelmberg | Jul 2017 | B2 |
9840953 | Kulkarni | Dec 2017 | B2 |
10005016 | Kippel | Jun 2018 | B2 |
10092878 | Zhang | Oct 2018 | B2 |
20040057889 | Buzanowski | Mar 2004 | A1 |
20040104577 | Alger | Jun 2004 | A1 |
20040265198 | Biswas | Dec 2004 | A1 |
20060080971 | Smith | Apr 2006 | A1 |
20060225402 | Kierspe | Oct 2006 | A1 |
20110036066 | Zhang | Feb 2011 | A1 |
20110158876 | Buzanowski | Jun 2011 | A1 |
20120102929 | Beissler et al. | May 2012 | A1 |
20120153634 | Williams | Jun 2012 | A1 |
20120174586 | Alexander | Jul 2012 | A1 |
20160308419 | Sethi | Oct 2016 | A1 |
Number | Date | Country |
---|---|---|
1 426 307 | Jun 2004 | EP |
2 554 814 | Feb 2013 | EP |
2 687 700 | Jan 2014 | EP |
2 910 711 | Aug 2015 | EP |
20110111644 | Oct 2011 | KR |
Entry |
---|
International Search Report and Written Opinion issued in connection with corresponding PCT application No. PCT/EP2017/069807 dated Nov. 8, 2017. |
Tabikh et al., Tempering air system for gas turbine selective catalyst reduction system, GE co-pending U.S. Appl. No. 15/334,900, filed Oct. 26, 2016. |
Tabikh et al., Tempering air system for gas turbine selective catalyst reduction system, GE co-pending U.S. Appl. No. 15/158,873, filed May 19, 2016. |
Number | Date | Country | |
---|---|---|---|
20180058292 A1 | Mar 2018 | US |