Claims
- 1. A mixture of monomers comprising
- (1 ) at least one polymaleimide in an amount sufficient to provide higher thermal stability in a cured copolymer compared to that observed for polymaleimide homopolymers; and
- (2) an internal olefinic mono(cyclobutarene) in an amount sufficient to provide decreased water absorption in a cured copolymer compared to that observed for polymaleimide homopolymers.
- 2. The mixture of claim 1, wherein an optional free radical inhibitor is added in an amount sufficient to increase the molten monomer mixture's pot life, and to increase the cured resin's toughness compared to that observed for polymaleimide homopolymers.
- 3. The mixture of claim 2, wherein an optional monovinylidene mono(cyclobutarene) monomer component is added in an amount sufficient to lower the polymerization initiation temperature compared to that observed for polymaleimide homopolymers
- 4. A copolymer comprising, in copolymerized form, the polymaleimide and the internal olefinic mono(cyclobutarene) of claim 1.
- 5. The copolymer of claim 4, wherein an optional free radical inhibitor is added in an amount sufficient to increase the molten monomer mixture's pot life and to increase the cured resin's toughness compared to that observed for polymaleimide homopolymers.
- 6. The copolymer of claim 4 wherein the polymaleimide is represented by the formula: ##STR20## wherein n is an integer of 2 or greater;
- R.sup.1 is separately and independently in each occurrence, a monovalent moiety, provided that R.sup.1 does not interfere with polymerization;
- R.sup.3 is an n-valent bridging member comprising an n-valent organic or heteroatom containing organic moiety; and
- the mono(cyclobutarene) is represented by the formula: ##STR21## wherein Ar is a polyvalent aromatic moiety, an ar-poly-yl, having three or more valences, provided that two carbon atoms of the cyclobutane ring are bonded to adjacent carbon atoms on the same aromatic ring of Ar;
- Y is a covalent bond or a divalent organic or inorganic moiety;
- m is an integer of at least 1;
- R is a monovalent moiety;
- R.sup.6 and R.sup.7 are individually hydrogen or an alkyl moiety; and
- R.sup.8 is hydrogen or a monovalent organic moiety provided that when R.sup.7 is hydrogen, R.sup.8 is a monovalent organic moiety.
- 7. The copolymer of claim 6, wherein the polymaleimide is 1,1'-(methylenedi-4,1-phenylene) bismaleimide and the mono(cyclobutarene) is 3-(2-(4-methylphenyl)ethenyl)-bicyclo(4.2.0)octa-1,3,5-triene.
- 8. A process comprising combining the polymaleimide and the internal olefinic mono(cyclobutarene) of claim 1.
- 9. A mixture of monomers comprising
- (1) at least one polymaleimide in an amount sufficient to provide higher thermal stability in a cured copolymer than that observed for polymaleimide homopolymers; and
- (2) a monovinylidene mono(cyclobutarene) in an amount sufficient to provide a lower polymerization onset temperature and decreased water absorption in a cured copolymer compared to that observed for polymaleimide homopolymers.
- 10. The mixture of claim 9, wherein an optional free radical inhibitor is added in an amount sufficient to increase the molten monomer mixture's pot life, and to increase the cured resin's toughness compared to that observed for polymaleimide homopolymers.
- 11. A copolymer comprising, in copolymerized form, the polymaleimide and the monovinylidene mono(cyclobutarene) of claim 9.
- 12. The copolymer of claim 11, wherein an optional free radical inhibitor is added in an amount sufficient to increase the molten monomer mixture's pot life, and to increase the cured resin's toughness compared to that observed for polymaleimide homopolymers.
- 13. The copolymer of claim 11 wherein the polymaleimide is represented by the formula: ##STR22## wherein n is an integer of 2 or greater;
- R.sup.1 is separately and independently in each occurrence, a monovalent moiety, provided that R.sup.1 does not interfere with polymerization;
- R.sup.3 is an n-valent bridging member comprising an n-valent organic or heteroatom containing organic moiety; and
- the mono(cyclobutarene) is represented by the formula: ##STR23## wherein Ar is a polyvalent aromatic moiety having three or more valences provided that the carbons of the cyclobutane ring are bonded to adjacent carbon atoms on the same aromatic ring of Ar;
- Y is a covalent bond or a divalent organic or inorganic moiety;
- m is an integer of at least 1;
- R is a monovalent moiety; and
- R.sup.9 is a monovalent organic moiety or a heteroatom containing monovalent organic moiety.
- 14. The copolymer of claim 13, wherein the polymaleimide is 1,1'-(methylenedi-4,1-phenylene)-bismaleimide and the mono(cyclobutarene) is 3-(1-(4-methylphenyl)ethenyl)-bicyclo(4.2.0)octa-1,3,5-triene.
- 15. A process comprising combining the polymaleimide and the monovinylidene mono(cyclobutarene) of claim 9.
- 16. A mixture of monomers comprising at least one polymaleimide and an internal olefinic mono(cyclobutarene) in a mole ratio range of polymaleimide to internal olefinic mono(cyclobutarene) of about 80:20 to about 20:80.
- 17. A mixture of monomers comprising at least one polymaleimide and a monovinylidene mono(cyclobutarene) in a mole ratio range of polymaleimide to monovinylidene mono(cyclobutarene) of about 80:10 to about 20:80.
CROSS-REFERENCE TO RELATED APPLICATIONS
This Application is a combination and a continuation-in-part of U.S. patent application Ser. Nos. 07,630,596 and 07/630,902, both filed Dec. 20, 1990 and now abandoned.
US Referenced Citations (21)
Foreign Referenced Citations (2)
Number |
Date |
Country |
392354 |
May 1990 |
EPX |
402975 |
May 1990 |
EPX |
Continuation in Parts (1)
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Number |
Date |
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Parent |
630596 |
Dec 1990 |
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