Patent Application
20100055371
This invention relates to dry paint transfer laminates, particularly decorative laminates for applying a layer of color to an architectural surface, such as a wall.
Thin sheets of decorative, multi-layer laminates are used as an alternative to paint on a number of substrate surfaces, including walls and other architectural surfaces. A typical laminate includes a paint transfer film, one side of which is releasably adhered to a protective liner, the other side being adhered to an adhesive capable of securing the laminate to a substrate surface, such as a wall. The dry paint transfer film typically includes a number of individual layers, including an opaque color coat layer, a top coat layer (which can impart a matte-like finish, abrasion resistance, and/or other properties to the final paint laminate), a decorative print layer (which allows a pattern to be provided, such a wood grain or other faux finish), and optionally one or more additional layers. A barrier layer is sometimes provided, e.g., between the adhesive layer and the paint transfer layer, to reduce migration of color-degrading compounds through the adhesive layer into the paint layer. Designed to mimic paint in both appearance and feel, such laminates are quite thin, yet have enough structural integrity to allow the laminate to be handled as it is dispensed from a roll, applied to a surface, repositioned if necessary, and secured to the substrate surface.
In the past, dry paint transfer laminates have often used solvent-borne polymeric binders as a medium for carrying a pigment within the paint coat layer. However, solvent-based systems have a number of disadvantages, including odor, higher viscosities, the need for specialized coating equipment (which can be slower to operate), etc. In addition, known release systems for protecting the paint transfer portion of the laminate have not fully utilized useful techniques for applying an opaque color coat layer to a release liner, such as direct casting, by coating or printing, of an opaque color coat layer onto an olefinic release surface. Despite the advances made in the field of dry paint transfer laminates, there remains a need for improved laminates and methods of manufacture.
The present invention provides a multi-layer laminate for applying a layer of color to a substrate surface, such as an architectural surface. The laminate comprises an improved release liner, a flexible, dry paint transfer layer that includes a water-based color coat layer, and a pressure-sensitive adhesive layer. In one embodiment, the release liner comprises a flexible carrier and an olefinic release layer adhered to or integral with the carrier; the dry paint transfer layer has an inner surface and an outer surface and is coated on and releasably adhered to the olefinic release layer, and comprises, as at least one component, an opaque color coat layer formed from a pigmented, water-based latex; and a pressure-sensitive adhesive layer overlays the inner surface of the dry paint transfer layer. The olefinic release layer is adapted to separate from and expose the outer surface of the dry paint transfer layer when the release liner is peeled away from the dry paint transfer layer. The release liner surface opposite the olefinic release layer functions as a PSA release layer, and protects the PSA when the laminate is self-wound into roll form, until the laminate is applied to a substrate surface.
Advantageously, the water-based latex allows the color coat layer to be coated on the release liner using high speed coating equipment and techniques, potentially even simultaneously with the adhesive layer. In addition, water-based pigment dispersions are less expensive than organic solvent-based pigment dispersions and, since no plasticizer is needed, the resulting laminate should have better dimensional stability. Compared to some decorative laminates, the laminate of the present invention should have lower residual solvents, even in the top coat layer, which is physically constrained by the olefinic release layer until use. In addition, the olefinic release layer permits the paint transfer layer to be coated directly onto a polyester release liner, such as a polyethylene terephthalate (PET) carrier film.
These and other aspects of the invention will be more fully understood by referring to the following detailed description and the accompanying drawings.
Referring to
In
The portions of the multi-layer laminate applied to the substrate surface (i.e., the opaque color coat layer 26, top coat 28, decorative print layer 30, and PSA layer 32) are sufficiently thin, individually and in combination, to minimize visible seams if adjacent multi-layer laminate films are overlapped during use. In general, the overall film thickness of the laminate as applied to the wall in its finished state (omitting the release liner 12) is, preferably, less than about 3.0 mils and, more preferably, less than about 2.0 mils. In one embodiment, the multi-layer laminate has a total thickness of less than about 1.6 mils.
The dry paint transfer layer 20 has, in general, a thickness of about 0.5 to about 1.5 mils. In one embodiment, the dry paint transfer layer has a thickness of about 0.5 to about 1.2 mils, and in another embodiment a thickness of from about 0.5 to about 0.9 mils. The transparent top coat layer 28, in general, has a thickness of from about 0.05 to about 0.4 mils. In one embodiment, the top coat layer has a thickness of from about 0.05 to about 0.3 mil. The decorative print layer 28 has, in general, a thickness of about 0.02 to about 0.15 mil. In one embodiment, the decorative print layer 28 has a thickness of about 0.02 to about 0.08 mils.
In other embodiments of the invention, the laminate 10 comprises one or more additional layers of material, each with a particular function, character and thickness. For example, more than one top coat layer may be provided, in place of a single top coat layer 28. Alternatively, or in addition, two or more print coat layers, and/or even two or more color coat layers, may be provided, in place of the single decorative print coat and color coat layers 30, 26 depicted in
Dry Paint Transfer Layer
As noted earlier, the dry paint transfer layer comprises, in one embodiment, an opaque color coat layer, transparent top coat layer, and decorative print layer. The latter two layers are conventional and are described, for example, in the 2005/0196607 application (¶¶37, 44 (top coat)) and the '142 patent (Col. 6, 1.28-Col. 9, 1.51, esp. Col. 9, 1.34-51 (print layer)); Col. 6, 1.28-Col. 9, 1.14 and Col. 9, 1.52-Col. 10, 1.59 (top coat). The top coat layer provides enhanced scuff resistance, stain resistance, and/or recoatability to the dry paint transfer film layer underlying it. In addition, when formulated with a silica filler (e.g.), the top coat lowers the gloss of the matte finish on the paint transfer laminate. The decorative print layer may be used to provide a faux finish, such as a “ragged” or “sponged” effect and appearance, and may be used to provide a desired print or design image, such as wood grain, a flowered design, etc.
The opaque color coat layer provides the laminate with an overall color and opacity, and is formed by adding pigment (e.g., titanium dioxide, carbon black, colored pigments) to a water-based latex that serves as a binder for the pigment when the color coat layer is dried. Typically, the pigment is provided as a dispersion, which is added to the latex to formulate the opaque color coat. As the latex dries, the individual polymer particles coalesce and form a resulting paint layer. A single polymer, polymer blends, hybrid polymers, (one formed in the presence of another, e.g.) can be used to form the latex.
A number of polymers can be utilized in the practice of the invention. Examples include vinyl acetate polymers, acrylic polymers, styrene-butadiene resins, and hybrids and/or blends thereof, so long as the polymer(s) can be formed as a water-based latex—or included as a component of water-based latex. More specific examples include polyvinyl acetate (especially if a plasticizer is present), vinyl acetate copolymers, particularly ethylene-vinyl acetate and vinyl acetate ethylene copolymers (e.g., Airflex® vinyl acetate-ethylene copolymers, from Air Products Polymers, L.P.), ethylene-modified vinyl acetate polymers (e.g., Evocar latex DA 280, from Dow Chemical); acrylic polymers (including copolymers); copolymers of vinyl acetate and one or more acrylic monomers (e.g., acrylic acid, methyl methacrylate, butyl acrylate) and/or one or more maleic monomers (e.g., dibutyl maleate, dioctyl maleate); and acrylic-styrene copolymers. In the examples below, an ethylene-modified vinyl acetate (VAE) polymer is prepared by emulsion polymerization and an acrylic copolymer (buylacrylate/methylmethacrylate/acrylic acid) is formed in the presence of the VAE polymer, resulting in a VAE/acrylic hybrid polymer latex, which is then compounded with a pigment to form a coatable color coat layer. (In the Examples, the color coat layer comprises about 70% latex, 30% pigment, by weight, before drying.)
Pressure-Sensitive Adhesive Layer
The PSA layer 32 is provided as a conventional PSA used in wall surface films and similar paint transfer applications, and bonds the dry paint transfer layer to a substrate surface, under applied pressure, typically at room temperature. Nonlimiting examples include water-based, water-borne, solvent-based, ultraviolet cured, e-beam cured, hot melt, and other PSAs. Specific examples are provided in the '142 patent and US2005/0196607 application cited above. Optionally, the adhesive layer contains one or more pigments to increase the overall opacity of the laminate and to permit the use of thinner paint film layers to achieve a desired level of opacity.
Release Liner
Another notable feature of the invention is the use of a release liner having as one surface an olefinic release layer, and, in some embodiments, an opposite surface having PSA release properties. Referring again to
One surface of the carrier is coated, treated, or otherwise formed with a composition having PSA release properties, i.e., that surface functions as a release material for a PSA. In one embodiment the PSA release material is a conventional silicone material. In this embodiment, the outer surface 34 of the release liner can be said to be siliconized.
The opposite surface of the flexible carrier is coated, formed with, or treated with an olefinic release layer. As used herein, the term “olefinic” simply refers to a material comprising, derived from, or based on an olefin resin, or other olefin-containing material. Nonlimiting examples include polyethylene, polypropylene, ethylene-propylene copolymers, etc. More specific examples include low density polyethylene, such as linear low density polyethylene. Yet another example is a blend of low density polyethylene and an ethylene hexene copolymer plastomer. Such a blend can be formed, e.g., as a 50/50 blend of low density polyethylene (Chevron Phillips Marflex 1017) and ethylene hexene copolymer plastimer (Exxon Mobile Exact 3139) with a coating thickness of about 0.4 mil or 6 lbs-ream.
The olefinic release layer is adhered to or integral with the flexible carrier of the release liner. In one embodiment, the olefinic release layer is coextruded onto the carrier.
As another aspect of the invention, a method of making a multi-layer laminate for use in applying a layer of color to a substrate surface is provided, and comprises the steps of providing a release liner comprising a flexible carrier and an olefinic release layer adhered to or integral with the carrier; coating onto the olefinic release layer, by casting or printing, a dry paint transfer layer having an inner surface and an outer surface and comprising, as at least one component thereof, an opaque color coat layer, the dry paint transfer layer in dry film form being releasable from the olefinic release layer; drying the dry paint transfer layer; and applying a pressure-sensitive adhesive layer to the inner surface of the dry paint transfer layer.
One embodiment of such a method is depicted in
In an alternate embodiment, both the opaque color coat layer and the PSA are die-coated simultaneously, one on top of another, using a dual-die coater, such as described in Avery Dennison's U.S. Pat. No. 5,7281,430, the entire contents of which are incorporated herein by reference.
Once the laminate has been made, it can be wound up on itself to form a roll, thereby bringing the silicone release coating 18 in contact with the PSA 32, effectively protecting the PSA until the laminate is to be applied to a substrate surface, such as a wall or other architectural surface.
In another embodiment of the invention, the silicone release coating (or other PSA release material) is provided as a separate PSA release liner adhered to the PSA on the surface opposite the surface that will ultimately contact the opaque color coat layer. In this embodiment, the release liner 12 does not need to include a silicone release coating 18. Instead, the silicone release coating is provided with the PSA layer. The PSA is brought into contact with the balance of the laminate (including a dried opaque color coat layer), completing the laminate.
The following are nonlimiting examples of the invention.
Materials
Starting Solutions and Other Materials
Polymerization Process:
Formulation of a Pigmented Latex
In separate containers, the following mixtures were prepared:
Laminate Preparation:
A solution containing polyethyl methacrylate and silica in propyl acetate was coated as a top coat layer on an extrusion-coated LDPE at 2 micron thickness. On top of this layer, a layer of pigmented latex was coated at about 1 mil. After removing the LDPE-layer, the resulting laminate has the following properties: tensile stress 12.7 Mpa, tensile strain 36%, 400 modulus, opacity 92.2% (with pigmented PSA, the opacity is 99.2%); gloss at 60 and 85 degree: 5.2 and 6.8, respectively.
A pigmented latex was prepared as in Example 1 but with a mixture of 1 gm of Zama 7 in 1 gm of water also included. A laminate was prepared as described in Example 1.
Various properties of the laminate and its subcomponents are presented in Table 1, for Examples 1 and 2.
