Patent Application
20200108351
The present invention relates to water filtration, and particularly to a filtration membrane to separate oil from water.
The petroleum industry faces a variety of challenges relating to the efficient extraction of oil from water, as well as oils and grease from municipal wastewater. Conventional separation devices and methods, such as gravity separation, skimming, dissolved air floatation, centrifugation, and hydro-cyclone, are either too costly, environmentally unfriendly, energy intensive, and/or low in separation efficiency. For example, liquid chemical dispersant(s) tend to cause secondary environmental pollution, and solid absorbents are limited in their absorption capacity, resulting in additional waste for removal. Cyclone separators normally require high energy input for the oil/water separation process.
Filtration membranes have drawn more attention as a promising technology for the separation of various oil/water mixtures, given their high quality of treated effluents and relatively simple operation process. However, the conventional filtration membranes continue to face the problems of high membrane fouling, incomplete oil/water separation, high energy consumption for operation, and high manufacturing cost. Additionally, these conventional filtration membranes normally suffer from low permeation flux, due to their phase-inversion fabrication process that tends to lead to relatively small pore sizes. Therefore, developing new filtration membranes with high permeation flux, low fouling, and high separation efficiency is critical and highly desirable for treating large amounts of oily wastewater.
Thus, a membrane for oil/water separation solving the aforementioned problems is desired.
The multi-layered membrane for separating oil from water can include one or more porous top layers, one or more porous bottom layers, and a middle layer including a particulate material between the one or more top layers and the one or more bottom layers, the middle layer being hydrophobic. The top and bottom layers can be formed from a hydrophilic and oleophobic woven or non woven-fabric. The particulate materials of the middle layer can include hydrophobic or hydrophilic powders. The one or more top layers retain oils, particularly non-emulsified oils, and allows water to pass through. The middle particulate layer adsorbs trace amounts of oil that may pass through the top layer and allows water to pass through. The one or more bottom layers provide mechanical support/strength for the middle layer and the entire membrane. While the membrane does not require any external pressure other than the gravitational forces to filter an oil/water mixture through the membrane, the filtration can be driven by a vacuum or other type of external pressure.
These and other features of the present invention will become readily apparent upon further review of the following specification and drawings.
Unless otherwise indicated, similar reference characters denote corresponding features consistently throughout the attached drawings.
Referring to
The membrane 100 includes a top layer 110 having a plurality of pores 115, a bottom layer 130 having a plurality of pores 135, and a middle particulate layer 120 positioned between the top layer 110 and the bottom layer 130, the middle layer 120 being hydrophobic and adapted for absorbing oil, such as trace amounts of oil, that passes through the top layer 110. The top layer 110 and bottom layer 130 have hydrophilic and oleophobic fibers. While the membrane 100 does not require any external pressure other than the gravitational forces exerted on the oil/water mixture W to drive the filtration of the oil/water mixture W through the membrane 100, the filtration can be driven by a vacuum or other type of external pressure.
The top layer 110 is configured for retaining an amount of oil from the oil/water mixture W and allowing water to pass (
The hydrophilic and underwater oleophobic properties of the top layer 110 may make the top layer 110 less subject to oil fouling. The fabric structure of the top layer 110 can also provide high water permeate flux, due to the big pore size (e.g., over 1 micron), while at the same time provide high mechanic strength. It is to be noted, however, that the big pore size of the top layer 110 cannot effectively retain all the oils in the oil/water mixture W, namely the emulsified oils that are smaller than 1 micron in size.
The middle layer 120 includes particulate materials, such as a solid powder. The solid powder can have a dimension of less than 100 microns. and a surface area greater than 10 m2/gram. The middle layer 120 can have a thickness in the ranging from about 1 micron to about 5000 microns. For example, the middle layer 120 can be formed by spreading 0.5 grams of granular activated carbon, such as by a glass rod (not shown), onto the surface of the middle layer 120 having a dimension of 5 cm by 5 cm. The particulate materials used to form the middle layer 120 are adapted for adsorbing trace amounts of oil, such as emulsified oils, that may pass through the top layer 110. As such, the middle layer 120 can aid the membrane 100 in achieving a high oil rejection rate (
The bottom layer 130, positioned beneath the middle layer 120, can include a porous, hydrophilic material. The material can be a woven or a non-woven fabric. The middle layer 120 can have any suitable thickness, such as from about 1 micron to about 1000 microns. The porous material 115 of the bottom layer 130 can include any suitable material, such as a micro-sized polymer fabric and, optionally, suitable inorganic particles, such as nanometer-sized inorganic particles. The main function of the bottom layer 130 is to both provide mechanic support for the middle layer 120, as well as to strengthen the entire membrane 100.
A woven mesh may optionally be included to impart more mechanical strength to the bottom layer 130 while, simultaneously, maintaining a high permeate flux through the membrane 100. It is to be noted that similar to the fibers of the top layer 110, the surface property of the fibers for the bottom layer 130 can either be intrinsically hydrophilic or turned from hydrophobic into hydrophilic, such as by coating the fiber surfaces of the hydrophobic material with a hydrophilic coating.
The membrane 100 can be formed in a various ways. For example, the top layer 110 of the membrane 100 and the bottom layer 130 of the membrane 130 can each be formed by first dissolving about two grams of chitosan, having a degree of deacetylation of 15% (i.e. 95.0%-80.0%), in 100 mL of acetic acid solution (2 wt %) to form a chitosan solution. Subsequently, the chitosan solution is stirred, such as on a magnetic stirrer plate, for approximately twenty-four hours. About 0.1 gram of Polyvinyl alcohol (low molecular weight, PVA) can then be dissolved in 10 ml of deionized (DI) water, such as in a beaker at about 95° C., for approximately twenty-four hours to make a PVA solution (1 wt %). Approximately 10 mL of the PVA solution can be added to 100 mL of the chitosan solution, such as under magnetic stirring, to form a composite solution. Subsequently, 1 gram of TiO2 nanoparticles (20 nm) can be added to the composite solution, such as under magnetic stirring, to better spread the nanoparticles into the solution uniformly. The composite solution can then be sonicated to remove air bubbles and form a coating solution.
Subsequently, a doctor blade method can be used to cast the coating solution on the fabric of the both the top layer 110 and the bottom layer 120. For example, the coating solution can be poured on the surface of a porous cotton fabric 115, 135. A glass rod (not shown) can be used to manually roll over the surface of the fabric and remove any excess coating solution of the surface of the fabric of each layer 110, 130. The membrane layer can be formed by evenly spreading about 0.5 gram of granular activated carbon onto the surface of the bottom layer using a glass rod. Once the middle layer 120 has been positioned in between the top layer 110 and the bottom layer 130, the membrane 100 can be blow dried.
The surface wettability of the membrane 100 was characterized by measuring the water contact angle and the underwater oil contact angle with Rame-hart precision contact angle goniometers. The membrane 100 was fixed between two glass tubes, wherein the top layer 110 of the membrane 100 faced upwards. The oil/water mixture W was made by shaking the oil/water mixture W (10% oil v/v) with vortex under 3000 rpm for 30 seconds. The oil/water mixture W was then poured onto the top layer 110 of the membrane 100, as illustrated in
After separation, the collected water was removed for oil content analysis. The oil concentration of the collected water after separation was measured by Jorin's Particle Analyzer (Jorin Ltd., Sandhurst, U.K.). Results of the performance tests are shown in
By way of operation, during the oil/water separation process, the oil/water mixture W first contacts the top layer 110 of the membrane 100. The water in the oil/water mixture W will penetrate and flow through the top layer 110 of the membrane 100 while the oil in the oil/water mixture W is retained on or within the membrane 100. As the water passes through the top layer 110, any oil that may pass through the top layer 110 will be retained by the middle layer 120 while water passes through the third layer 130. As mentioned above, the separation process can be driven by gravity, as well as a vacuum or pressure.
It is to be understood that the present invention is not limited to the embodiments described above, but encompasses any and all embodiments within the scope of the following claims.
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/QA2017/050001 | 3/30/2017 | WO | 00 |
