The present disclosure relates to optical structures.
A tool (e.g., a mold) can be used to imprint a multi-level pattern into a layer on a substrate in which optical elements are to be formed. Such tools can be used, for example, as part of a mass production manufacturing process. Manufacturing the optical elements may take place in some instances at a wafer-level in which tens, hundreds, or even thousands of optical elements are formed in parallel using the same tool.
The present disclosure describes multi-level optical structures and methods of fabricating such multi-level optical structures. The techniques include using a tool that has a multi-level structured surface that corresponds, for example, to a pixel layout design for optical elements, and that is transferred by imprinting to an imprint material on a substrate. Various etching operations then can be performed to cause the imprinted pattern to be transferred into an optical sublayer in the substrate.
In one aspect, for example, the present disclosure describes a method that includes imprinting a multi-level structured surface of a tool into an imprint material that is disposed on a substrate so that the imprint material is imprinted with a multi-level structure corresponding to the multi-level structured surface of the tool. The substrate includes sublayers disposed on a support. The sublayers are disposed one atop another and include an optical sublayer on the support, a first hard mask sublayer on the optical sublayer, a spacer sublayer on the first hard mask sublayer, and a second hard mask sublayer on the spacer sublayer. The method further includes subsequently performing etching operations to cause the imprinted multi-level structure to be transferred into the optical sublayer of the substrate.
Some implementations include one or more of the following features. For example, in some implementations, the multi-level structured surface of the tool corresponds to a pixel layout design for optical elements. The optical elements can include, for example, at least one of diffractive optical elements of meta optical elements.
In some implementations, the optical sublayer is composed of amorphous silicon, crystalline silicon, silicon nitride, titanium oxide, aluminum zinc oxide, a niobium oxide (e.g., NbO, NbO2 or Nb2O5) or zinc oxide. The support may be composed, for example, of glass. In some instances, each of the hard mask sublayers is composed of a metal. For example, at least one of the hard mask sublayers can be composed of chrome, aluminum or titanium. In some instances, the spacer sublayer is composed of silicon dioxide. In some cases, the imprint material is a resist.
In some implementations, each of the etching operations is a selective etch. For example, in some implementations, performing the etching operations includes performing the following etches sequentially: a first etch to remove a residual layer of the imprint material; a second etch to remove exposed portions of the second hard mask sublayer; a third etch to remove exposed portions of the spacer sublayer; a fourth etch to remove exposed portions of the first hard mask sublayer; a fifth etch to remove, at least partially, exposed portions of the optical sublayer; a sixth etch to remove a remainder of the imprint material and exposed portions of the spacer sublayer; a seventh etch to remove a remainder of the second hard mask sublayer and exposed portions of the first hard mask sublayer; an eighth etch to remove exposed portions of the optical sublayer; a ninth etch to remove a remainder of the spacer sublayer; and a tenth etch to remove a remainder of the first hard mask sublayer.
In some instances, the multi-level structured surface of the tool is imprinted into the imprint material by nanoimprint lithography. In some cases, the third etch also reduces a height of the imprint material. In some implementations, at least one of the etch operations is an inductively coupled plasma (ICP) etch.
In some implementations, the multi-level structure imprinted into the imprint material and transferred into the optical sublayer of the substrate includes at least three different levels.
Various advantages may be provided by some implementations. For example, in some implementations, the multi-level structured surface of the tool is transferred to the optical sublayer of the substrate through a process that uses only a single imprint.
Other aspects, features and advantages will be readily apparent from the following detailed description, the accompanying drawings and the claims.
The present disclosure describes techniques for fabricating multi-level optical structures that include optical elements such as meta optical elements (MOEs) or diffractive optical elements (DOEs). MOEs, for example, can include a metasurface having a distributed array of meta-atoms (e.g., nanostructures). The meta-atoms may, individually or collectively, interact with light waves. For example, the nanostructures or other meta-atoms may change a local amplitude, a local phase, or both, of an incoming light wave.
In accordance with some implementations, a multi-level tool (e.g., a mold) can be used to imprint a multi-level structure into a layer on a substrate in which the optical elements are to be formed. The tool can include a multi-level structured surface that corresponds to the pixel layout design for the multi-level optical elements and that can be transferred (e.g., by imprinting) to an imprint material on a substrate. The multi-level tool can be used, for example, as part of a mass production manufacturing process. Manufacturing the optical elements may take place in some instances at a wafer-level in which tens, hundreds, or even thousands of optical elements are formed in parallel using the same tool.
As indicated by 10 in
As a result of additional processing, including various etching operations, the multi-level structure is transferred (12 in
The optical sublayer 22 can be selected to have particular optical properties such that the optical elements formed therein by the resulting multi-level structure have specified optical characteristics and optical functionality at the operating wavelength(s).
As further shown in
In some implementations, the support 20 can be, for example, a glass substrate having a thickness in the range of 0.5 mm-2.0 mm, a glass surface roughness Ra of less than 2 nm, and a scratch/dig ratio of 60/20. Optical sublayer 22 can be composed, for example, of silicon (e.g., amorphous, poly-crystalline, or crystalline silicon) with a thickness of in the range of 300 nm-2000 nm, and a surface roughness Ra of less than 2 nm. In some instances, the optical sublayer 22 has optical properties (at 940 nm) as follows: n=3.5±0.05, and k=6×10−5±4×10−5. The optical properties of the sublayer 22 may differ in other implementations. For example, in some cases, the refractive index n is in the range 3.4-3.9, and k<10−3. Each of the hard mask sublayers 24, 28 can be composed, for example, of a metal (e.g., chrome (Cr)) having a thickness in the range of 5 nm-50 nm. The hard mask chrome sublayers 24, 28 can be deposited, for example by e-beam evaporation or sputtering. The intervening spacer sublayer 26 can be composed, for example, of SiO2 having a thickness in the range of 5 nm-100 nm.
The foregoing materials, thicknesses and/or optical properties of the sublayers of the substrate 30, as well as deposition techniques, are examples. Thus, different materials, thicknesses and/or optical properties, as well as other deposition techniques, can be used in some implementations. For example, in some implementations, the optical sublayer 22 may be composed of silicon nitride (SiNx) or Titanium oxide (TiO2), and/or the hard mask sublayers 24, 28 may be composed of aluminum (Al) or titanium (Ti). In general, the hard mask sublayers 24, 28 and the spacer sublayer 26 should be chosen to allow for selective etching of the substrate's sublayers in a controlled manner.
In some implementations the imprint layer 32 is a UV-curable, microwave-curable, and/or thermally-curable epoxy or resin (e.g., a photoresist). As shown in the example of
As explained above, after transferring the pattern, by imprinting, to the imprint layer 32, various etching operations are performed, with the result that the multi-level pattern is transferred to the optical sublayer 22 on the glass or other support 20. In a particular example, explained in greater detail below, the process includes at least ten etching operations (see
A first etch is performed to remove the residual layer of the imprint material (e.g., the resist) 32. The result of this etch, according to an example implementation, is illustrated in
Next, a second etch is performed to remove the exposed portions of the second hard mask sublayer 28. During this etch, the imprint material 32 serves as a mask that substantially prevents etching of the portions of the second hard mask sublayer 28 that is directly under the imprint material 32. The result of this etch, according to an example implementation, is illustrated in
A third etch then is performed to remove exposed portions of the spacer sublayer 26 and reduce the height of the remaining imprint layer 32. During this etch, the second hard mask sublayer 28 serves as a mask that substantially prevents etching of the spacer (e.g., SiO2) sublayer 26 that is directly under second hard mask sublayer 28. The result of this etch, according to an example implementation, is illustrated in
A fourth etch then is performed to remove the exposed portions of the first hard mask sublayer 24. During this etch, the spacer (e.g., SiO2) sublayer 26 serves as a mask that substantially prevents etching of the portions of the first hard mask sublayer 24 that are directly under the spacer sublayer 26. The result of this etch, according to an example implementation, is illustrated in
A fifth etch then is performed to remove, at least partially, the exposed portions of the optical (e.g., amorphous silicon) sublayer 22. During this etch, the spacer sublayer (e.g., SiO2) 26 and/or the first hard mask sublayer 24 serve as a mask to substantially prevent etching of the portions of the optical sublayer 22 that are directly under those sublayers. The result of this etch, according to an example implementation, is illustrated in
A sixth etch then is performed to remove the remainder of the imprint layer (e.g., the resist) 32 as well as the exposed portions of the spacer (e.g., SiO2) sublayer 26. During this etch, the second hard mask sublayer 28 serves as a mask to substantially prevent etching of the portions of the spacer (e.g., SiO2) sublayer 26 that are directly under those sublayers. The result of this etch, according to an example implementation, is illustrated in
A seventh etch then is performed to remove the remainder of the second hard mask sublayer 28 and the exposed portions of the first hard mask sublayer 24. The spacer (e.g., SiO2) sublayer 26 serves as a mask to substantially prevent etching of the portions of the first hard mask sublayer 24 that are directly under the spacer sublayer. The result of this etch, according to an example implementation, is illustrated in
An eighth etch then is performed to remove the exposed portions of the optical (e.g., amorphous silicon) sublayer 22. The spacer (e.g., SiO2) sublayer 26 and the first hard mask sublayer 24 serve as a mask to substantially prevent etching of the portions of the optical (e.g., amorphous silicon) sublayer 22 that are directly under those sublayers. The result of this etch, according to an example implementation, is illustrated in
A ninth etch then is performed to remove the remainder of the spacer (e.g., SiO2) sublayer 26. The result of this etch, according to an example implementation, is illustrated in
A tenth etch then is performed to remove the remainder of the first hard mask sublayer 24. The result of this etch, according to an example implementation, is illustrated in
In some implementations, a cleaning operation is performed prior to dicing of optical elements and later characterizing the optical properties. In some implementations, the cleaning operation includes using a piranha solution of sulfuric acid (98%) and hydrogen peroxide (30%) in a ratio 4:1 for about ten minutes, followed by a water rinse for about 8 minutes. The substrate(s) then can be dried, for example, in a barrel dryer. Different or additional cleaning techniques can be used in some implementations.
The optical properties of the resulting optical elements then can be determined using, for example, known techniques. The glass or other support 20 then can be separated, for example by dicing, into individual optical elements (e.g., DOEs or MOEs), each of which includes a multi-level structure defined by at least three different levels. Depending on the materials of the multi-level structure, the optical element may be configured to be operable for use, e.g., with infra-red (IR) or visible radiation. The depths and positions of the various levels with respect to one other can be configured according to a predefined optical function.
In some implementations, an optical element having a multi-level structure as described above can be integrated into modules that house one or more optoelectronic devices (e.g., light emitting and/or light sensing devices). The optical element can be used to modify or redirect an emitted or incoming light wave as it passes through the optical element.
The foregoing techniques can facilitate manufacture of optical elements having multi-level structures whose features, in a top view (i.e., viewed perpendicular to the surface of the substrate 20), are circular, oval, square, rectangular, or some other shape. For example,
In some implementations, one of or more levels of the optical structure may be composed of more than one material. Likewise, the different levels of the optical structure may be composed of different materials from one another. For example, as shown in
Optical elements having a multi-level structures as described above can be integrated, for example, into a light sensing or light emitting module. For example, as shown in
In the single-channel module of
In some cases (e.g., where the optoelectronic component 802 is a light emitter), light generated by the optoelectronic component 802 passes through the optical element 804 and out of the module. In the single-channel module of
One or more optical elements having multi-level structures as described also can be integrated into multi-channel modules. As shown in
In some instances, one or more of the modules described above may be integrated, for example, into mobile phones, laptops, televisions, wearable devices, or automotive vehicles.
While this document contains many specific implementation details, these should not be construed as limitations on the scope of any inventions or of what may be claimed, but rather as descriptions of features specific to particular embodiments. Certain features that are described in this document in the context of separate embodiments can also can be implemented in combination in a single embodiment. Conversely, various features that are described in the context of a single embodiment can also can be implemented in multiple embodiments separately or in any suitable sub-combination. Various modifications can be made to the foregoing examples. Accordingly, other implementations also are within the scope of the claims.
Filing Document | Filing Date | Country | Kind |
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PCT/EP2023/055006 | 2/28/2023 | WO |
Number | Date | Country | |
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63316182 | Mar 2022 | US |