Non-fat, reduced fat and low fat cheeses and method of making

Information

  • Patent Grant
  • 5679396
  • Patent Number
    5,679,396
  • Date Filed
    Wednesday, June 7, 1995
    29 years ago
  • Date Issued
    Tuesday, October 21, 1997
    26 years ago
Abstract
Fat free, reduced fat and low fat cheeses, including natural cheese and processed cheese, and method for making the cheeses are described. The natural cheeses and processed cheeses contain a pregelatinized, high amylose starch based texturizing agent that can partially or totally replace fat and/or fillers which are traditionally incorporated into cheese formulations. The natural cheeses and processed cheeses have the textural and organoleptic mouthfeel properties of full fat, conventional natural cheeses and processed cheeses.
Description

BACKGROUND OF THE INVENTION
Natural cheese is generally prepared by the following steps: setting the milk, typically by treating with proteolytic enzymes and acidifying directly with acidulants or with lactic acid cultures, cutting or breaking the curd, cooking the curds, draining or dipping the whey, knitting and transforming the curds, salting the curds, and pressing. The substantial milk fat content of natural cheese not only contributes to the overall cheese yields but also provides a soft body and texture with desirable melt characteristics. Elimination or substantial reduction of the fat content of natural cheese results in a more expensive cheese product with a relatively high percentage of protein. Without the disruptive effect of the fat globules, the cheese also tends to be tough and rubbery in texture with poor melt characteristics.
Processed cheese is conventionally prepared by blending milkfat-containing cheeses and other dairy products such as whey solids and other milk protein isolates with emulsifying salts, such as disodium phosphate and sodium citrate, at elevated temperatures to produce a homogeneous, pumpable, fluid cheese material which maybe formed into sheets, slices or other forms, and packaged for consumer use. The substantial milkfat content of processed cheeses not only provides a soft body and texture as well as desirable melt characteristics, but also facilitates the processing of the natural cheese components at elevated temperatures in the manufacturing process. Elimination or even substantial reduction of the fat content of processed cheese may have a detrimental effect on the body, texture and melt characteristics of the resulting product as well as the processing of the cheese melt.
The consumer's demand for low-fat foods that retain the quality of the corresponding full-fat formulation has led to the development of a large number of potential texturizing agents and fat replacers based on proteins, polyesters, and a variety of other approaches. Several examples of fat replacers derived from starch include: a partially debranched starch used for providing fat-like texture, forming opaque clouds and producing thermoreversible gels (EP Application 0 372 184 A1 and U.S. Pat. No. 4,971,723 issued to Chiu); cold-water soluble and pregelatinized converted starches (by acid, enzyme or oxidation treatment) for use as fat or oil replacement in ice cream and mayonnaise (U.S. Pat. No. 4,510,166 issued to Lenchin et al.); enzyme-hydrolyzed thermoreversible starch gels as fat substitutes in mayonnaise, cream cheese, whipped cream and meat applications (U.S. Pat. Nos. 3,962,465 and 3,986,890 issued to Richter et al.); aqueous dispersion of granular starch hydrolysate (EP Application 0 443 844 A1 issued to Chiu et al.); macrocolloid carbohydrate particles for use in ice cream, yogurt, salad dressings, mayonnaise, coffee whitener and sour cream (PCT Application WO 89/12403 to Singer et al.); two-phase protein and carbohydrate fat substitute for use in salad dressings and cookie fillings (EP Application 0 441 494 A1 to Reimer); fat substitute comprising hydrated alginate and a complex carbohydrate (PCT Application WO 92/02147 to Shemer and Shemer); and insoluble modified starch used as a bulking agent, filler or texturizing agent in low-fat formulations (U.S. Pat. 5,051,271 issued to Iyengar et al.).
A number of methods have been developed to modify starches for use in food formulations and include: subjecting defatted amylose-containing starch to high temperature and shear to disrupt the starch granules thereby producing a gel (U.S. Pat. No. 3,666,557 issued to Jensen and Long); cooking high amylose starch at 140.degree.-170.degree. C. to produce a solubilized cold water dispersible starch (U.S. Pat. No. 3,515,591 issued to Feldman et al.); cooking high amylose starch under shear at a temperature higher than the gelatinization temperature to produce a yellow gel (U.S. Pat. No. 3,836,677 issued to Freck et al.); and subjecting high amylose starches to a jet cooking/spray drying process to produce a pregelatinized starch (E.P. Application 0 366 898 A1 and U.S. Pat. No. 5,131,953 issued to Kasica and Eden).
Reduced fat processed cheese and cream cheese products have been previously described. See U.S. Pat. No. 5,215,778 issued to Davidson et al. which describes a substantially fat free processed cheese containing microreticulated microcrystalline cellulose that enhances the textural and mouthfeel characteristics; U.S. Pat. Nos. 5,171,603 and 5,098,728 issued to Singer et al. which disclose the use of non-aggregated particles of denatured protein to make reduced fat processed cheese.
It is desirable to produce non-fat, reduced fat and low fat natural cheeses and processed cheeses which have the texture and mouthfeel characteristics of conventional, full fat natural cheeses and processed cheeses, as well as desirable stability and functional characteristics.
SUMMARY OF THE INVENTION
This invention relates to fat free, reduced fat and low fat cheeses, including natural cheese and processed cheese, that have the taste, mouthfeel, textural properties and curd yield of a full fat natural or processed cheese, and to methods for making the cheeses. The natural cheeses and processed cheeses comprise a starch based texturizing agent that is derived from pregelatinized, high amylose starch which has a dextrose equivalent (DE) value for the starch component of less than about 5, with less than about 1.5 being preferred. A preferred starch based texturizing agent is one which is derived from high amylose starch that has been pregelatinized and spray dried into a powder which is retrograded and crystalline; partially retrograded and crystalline; or nonretrograded and noncrystalline.
The starch based texturizing agent is incorporated into traditional cheese formulations to yield a natural cheese or processed cheese that has the sensory and visual attributes, including the melt down properties, of equivalent full fat formulations. The starch based texturizing agent can be effectively used to replace fat-containing ingredients, as well as fillers which are traditionally incorporated into cheese formulations, such as microcrystalline cellulose (MCC), non-fat dry milk (NFDM), skim cheese, sweet whey and other milk protein isolates.
The texturizing agent is easily incorporated into milk, thereby allowing the use of traditional cheese-making techniques to yield a natural cheese that has the sensory and visual attributes, including the melt down properties, of equivalent full fat products. The texturizing agent partitions into the curd, most likely disrupting the casein microstructure, and unexpectedly enhances the texture and moisture retention of the natural cheese. The retention of moisture in the cheese curd is a key requirement in offsetting the cost and textural problems associated with higher non-fat solids in low and reduced fat natural cheeses.
The addition of the texturizing agent as a fat and/or filler replacer does not compromise the flavor, color or melt down properties of the resultant natural cheeses or processed cheeses. The natural cheeses and processed cheeses prepared according to this invention have desirable finished moistures and/or curd yield, with textures equivalent to their full fat counterparts. The finished moistures enable the natural cheese or processed cheese to be shredded or sliced. The natural cheese or processed cheese has good melt down properties that are well suited for cooking and food preparation in which melted cheese is employed. The processed cheese further has the ability to heat up and cool down quickly, which may increase the rate at which non-fat and low fat processed cheeses can be manufactured. The reduction and potential elimination of some traditional ingredients may provide an overall savings in manufacturing cost.





DETAILED DESCRIPTION OF THE INVENTION
This invention relates to fat free, reduced fat and low fat cheeses, including natural cheeses and processed cheeses, that have textural and organoleptic mouthfeel properties of a full fat, conventional natural cheese or processed cheese, and to methods for making the cheeses. The natural cheese or processed cheese comprises traditional cheese ingredients and a starch based texturizing agent that is derived from pregelatinized, high amylose starch which has a DE value of less than about 5, with less than 1.5 being preferred. Traditional ingredients comprise non-fat and/or fat containing dairy ingredient(s), optional emulsifying salt(s) and adjunct ingredients, such as hydrocolloids, gums and carbohydrate products, and one or more flavoring agents. The non-fat, reduced fat and low fat natural and processed cheeses have the sensory and visual attributes, as well as the melt down properties, of equivalent full fat products. The reduction in fat translates into reduction in overall calories of the finished cheese.
The terms "cheese" or "cheeses" shall include both natural and processed cheeses, and shall include any form of natural and processed cheeses, including but not limited to slices, blocks, grated cheese and cheese spreads.
The present invention can be used to prepare any type of reduced fat or non-fat natural cheese, including but not limited to blue cheese, cheddar cheese, camembert cheese, colby cheese, gouda cheese, jack cheese, mozzarella cheese, muenster cheese, parmesan cheese, cottage cheese, ricotta cheese and romano cheese. The term "natural cheese" shall include these cheeses, as well as other cheeses made by concentrating the insoluble components of milk and transforming or curing these components.
The term "processed cheese" shall embrace processed cheese food, processed cheese spreads and imitation cheese, all of which can optionally be pasteurized.
A processed cheese can be made from a reduced fat or non-fat natural cheese of this invention. The reduced fat/non-fat processed cheese can be made by mechanically reducing the reduced fat or non-fat natural cheese to a uniform mixture of fine particle size, and then dry blending a mixture of the appropriate functional processed cheese ingredients, such as emulsifying agents, preservatives, gelling agents, proteins, sweeteners and acidifying agents.
The terms "non-fat" and "fat free" are intended to mean herein a natural cheese or processed cheese that contains less than 0.5 gram total fat per 30 gram serving. The term "reduced fat" is intended to mean herein a natural cheese or processed cheese having greater then or equal to a 25% reduction in fat compared to the full fat equivalent. The term "low fat" is intended to mean a natural cheese or processed cheese that contains 3 grams total fat per 50 gram serving. These levels of fat are consistent with the definitions of "fat free", "reduced fat" and "low fat" as set forth by the Nutrition Labeling and Education Act (NLEA), Federal Register, Jan. 6, 1993.
For purposes of the present invention, the term "starch based texturizing agent" will be used to describe products derived from pregelatinized, high amylose (greater than about 30% by weight amylose as determined by iodine binding) starch which has been processed under specific conditions of temperature, pressure and shear, and has a dextrose equivalent (DE) value for the starch component itself of less than about 5, with about 1.5 being preferred, as determined by the Luff-Schoorl method, Procedure D52, Corn Industry's Research Foundation, 6th Edition. Methods for making the texturizing agents are described in detail in U.S. Pat. No. 5,470,391, published PCT Application No. WO 95/10196, and U.S. Pat. No. 5,584,937. The teachings of these documents are incorporated herein by reference in their entirety. According to these methods, excipients can be incorporated into the final texturizing agent. When an excipient is incorporated into the starch based texturizing agent, the DE value will vary depending upon the amount and type of excipient that is used. Incorporation of about 25% by weight maltodextrin as excipient results in a product with good properties for this application. Examples of commercially available maltodextrins include M040 (DE value of 4-8) and M100 (DE of 10), both of which are produced by Grain Processing Corporation.
According to this invention, in natural cheese making the starch based texturizing agent is dispersed into milk having a butter fat content of from about 0.05% to about 1.5%. The exact butter fat content will be dictated by the amount of fat desired in the final product. The amount of texturizing agent used will depend upon the desired end product. Preferably the texturizing agent will be added in amount of from about 0.1% to about 1.0% by weight, with from about 0.2% to about 0.4% by weight being preferred. The starch based texturizing agent can be used in conjunction with other adjunct ingredients such as hydrocolloids, gums and carbohydrate products (e.g., carrageenan, microcrystalline cellulose, carboxymethyl cellulose, alginate, guar gum and modified starch).
The milk dispersion is heated to a temperature of 61.degree. F. to 200.degree. F. (72.2.degree. C. to 93.degree. C.) to pasteurize the milk. Heating time will depend on the temperature selected and is not critical, provided sufficient time is allowed to complete the pasteurization.
Following pasteurization, calcium chloride (preferably about 0.02% by weight based on weight of liquid milk) is optionally added. The addition of calcium chloride is not essential but can be desirable since it provides additional calcium and also assists in the interaction between the gelling polysaccharides, such as carrageenan, and the milk proteins, thereby providing a more desirable curd structure.
A cheese culture or a mixture of cheese cultures is then added with stirring to the milk. The choice of the cheese culture is determined by the type of end product cheese that is desired. For example, for the production of Mozzarella cheese the culture Streptococcus thermophilus and Lactobacillus bulgaricus can be used. Cultures employed for reduced fat natural cheeses include but are not limited to Streptococcus lactis, Streptococcus cremoris, Streptococcus thermophilus, Lactobacillus helveticus, Lactobacillus bulgaricus and Lactobacillus casei. Pure strains of these cultures can be obtained commercially. The milk dispersion containing the culture or cultures is incubated as needed to achieve the propagation of the cultures in the milk dispersion. The incubation time and temperature will depend on the culture. Generally, a temperature of from about 80.degree. F to about 100.degree. F. (26.7.degree. C. to 37.8.degree. C.) for 30 to 60 minutes is desirable, provided the temperature chosen does not inactivate or interfere With the propagation of the bacteria. The cheese cultures typically cause a slight decrease in the pH of the milk.
Pure liquid rennet is then added with stirring to the cultured milk product. After addition of the rennet or other clotting enzymes, the milk dispersion is allowed to stand quiescently until coagulation occurs, usually from about 30 to about 45 minutes. During the curd clotting, the texturizing agent is entrapped uniformly within the curd structure.
The coagulum is then processed to obtain the reduced fat natural cheese using techniques known to those skilled in the art of cheese making (see Kosikowski, "Cheese and Fermented Milk Foods", 2nd edition, (F. V. Kosikowski and Associates, Brooktondale, N.Y., 1982). The following standard steps in the processing of the coagulum are:
1. The coagulum (curd) is cut into at least 1/4inch cubes and allowed to heal for 15 to 30 minutes.
2. The cubed curd is cooked by raising the temperature to 100.degree. F. (37.8.degree. C.) over a 30 minute period with gentle agitation and then held at 100.degree. F. (37.8.degree. C.) format least 30 minutes.
3. The curd is allowed to re-knit and the whey drained.
4. The curd is washed.
5. The curd is matted and cut into slabs.
6. The curd is milled with salt.
7. The milled natural cheese is hooped and pressed for about 16 hours.
Dairy flavors can be added initially to the liquid milk before or after pasteurization but before processing of the curd. The addition of such flavors at an early stage of the cheese manufacturing enhances flavor in the end product. Natural cheeses produced by this method have a non-fat or reduced fat content and have the textural and organoleptic mouthfeel properties of their full fat natural cheese counterparts.
According to this invention, no special processing modifications are required to produce non-fat, reduced fat or low fat processed cheeses. The starch based texturizing agent is blended into traditional cheese ingredients (e.g., non-fat, reduced fat and low fat dairy ingredients, optional emulsifiers, and flavoring agents) to produce a processed cheese. However, it is desirable to completely hydrate the texturizing agent in order to uniformly distribute the texturizing agent in the cheese ingredients. The texturizing agent can be mixed into the liquid ingredients under high shear to form a slurry or paste. Alternatively, the powdered texturizing agent can be blended with the dry cheese ingredients and then mixed with the remaining ingredients using a direct steam injection auger mixer/cooker commonly used in the processed cheese industry. The resultant cheese melt can be packaged in accordance with conventional packaging procedures into blocks, slices, spreads or cold packs, or it can be shredded. See Cheese and Fermented Milk Foods by F.V. Kosikowski, pp 382-406, the entire teachings or which are incorporated herein by reference.
The amount of texturizing agent used will depend upon the desired end product. Preferably the texturizing agent can be added in amounts of from about 1.0% to about by weight, with from about 1.5% to about 2.5% by weight being preferred.
The starch based texturizing agent can effectively replace fat containing ingredients as well as partially or totally replace fillers which are traditionally incorporated into cheese formulations. The texturizing agent can be used in place of or in combination with skim milk cheese, dry cottage cheese, whey, whey protein concentrate, skim milk, non-fat dry milk, microcrystalline cellulose, carrageenan, carboxymethyl cellulose, hydrolyzed oat and corn flours, xanthan gum, guar gum, casein, maltodextrin, cellulose and milk proteins.
A fat free processed cheese will comprise the starch based texturizing agent, non-fat dairy ingredient(s), optional emulsifying salt and one or more flavoring agents. Non-fat dairy ingredient(s) include, but are not limited to, skim milk cheese, non-fat dry milk, skim milk, skim butter milk and milk protein isolates (e.g., caseinates, whey protein isolates and/or concentrates). Low fat dairy ingredient(s) or fat containing dairy ingredient(s) can be incorporated into the formulation, such as whole milk, whole milk cheese, reduced fat milk and non-fat milk cheese.
Suitable flavoring agents such as buttermilk solids, natural and artificial butter and dairy flavor components, enzyme modified cheese, and mixtures thereof, may be incorporated into the cheese formulations of this invention. Flavoring ingredients containing fats should not be used in amounts which would increase the total fat content of the finished non-fat product above the desired levels of 1.6%. Fruits, vegetables, meats and spices, such as pimento, peppers, fat free natural or analog bacon bits and the like, may also be provided as adjunct components in a matrix of the processed cheese. The amount of these components will depend upon the desired end product.
The processed cheese can also be made from a reduced fat or non-fat natural cheese of this invention. The reduced fat or non-fat natural cheese can be mechanically reduced to a uniform mixture of fine particle size and blended with the appropriate functional processed cheese ingredients, such as emulsifying agents, preservatives, gelling agents, proteins, sweeteners and acidifying agents, to produce a reduced fat or non-fat processed cheese.
Non-fat, reduced fat and low fat processed cheese containing the starch based texturizing agent can be made without the need for any emulsifying salts. However, conventional emulsifying salts utilized in fat-containing processed cheese can be optionally used in the formulations of this invention. One or more emulsifying salts can be used and include monosodium phosphate, disodium phosphate, dipotassium phosphate, trisodium phosphate, sodium metaphosphate (sodium hexametaphosphate), sodium acid pyrophosphate, tetrasodium pyrophosphate, sodium aluminum phosphate, sodium citrate, potassium citrate, calcium citrate, sodium tartrate and sodium potassium tartrate. Preferred examples of suitable emulsifying salts include disodium phosphate in an amount of from about 0.5 to about 2.5 percent by weight; sodium citrate in an amount of from about 0.25 to about 1.5 weight percent; trisodium phosphate in an amount of from about 0.5 to about 2.0 weight percent.
It is not critical to monitor the pH during the manufacture of the cheese. However, an acceptable finished cheese will have a pH in the range of from about 5.1 to about 5.9.
Natural cheeses and processed cheeses produced according to this invention have good finished moistures but yield firm, cohesive cheese blocks. These finished moistures enable the cheese to be shredded or sliced. Retention of water in the final natural cheese or processed cheese further results in an overall increased weight of the product. Due to increased water content, compared to a similar product that does not contain the texturizing agent, the natural cheese or processed cheese has a better body. The natural cheese or processed cheese also has good melt down properties that are well suited for cooking and food preparation in which melted cheese is employed. The processed cheese further has the ability to heat up and cool down quickly, which may increase the rate at which non-fat, reduced fat and low fat processed cheeses can be manufactured. The reduction and potential elimination of some traditional ingredients and increased product weight may provide an overall savings in manufacturing cost.
The invention is further illustrated by the following examples which are not to be construed as limiting in any way. All percentages used herein are by weight based on the final weight of the product.
EXAMPLES
Natural Cheese Formulations
Ingredients
Maltodextrin M100 (DE=10) manufactured by Grain Processing Corporation.
Pregelatinized, high amylose starch based texturizing agent (OPTAGRADE.RTM.) manufactured by Opta Food Ingredients, Inc., prepared by spray drying hot pregelatinized, high amylose starch and 25% maltodextrin (M040 from Grain Processing Corporation).
Pasteurized skim milk (retail grade)
Distilled vinegar (50 grain, retail grade)
Chymogen Enzyme (single strength liquid, Chris Hansen, Milwaukee, Wis.)
Direct Cheddar Mesophilic Homofermentative Culture (DVS 970 pellets: STC4 and LHBO1, Chris Hansen, Milwaukee, Wis.)
Direct Mozzarella Mesophilic Homofermentative Culture (DVS pellets STC4 and LHBO1, Chris Hansen, Milwaukee, Wis.)
Annatto Color (Marshall Products, Madison, Wis.)
Example 1
Non-fat Ricotta Cheese
______________________________________ Weight/WeightIngredients Percentage______________________________________Skim milk 99.70Texturizing Agent 0.30Distilled vinegar (to pH 5.7) 100.00______________________________________
Process
1. Milk was heated to 200.degree. F. (93.degree. C.) and placed in preheated glass jar of a standard kitchen blender. Texturizing agent was added while mixing on medium speed. Once the powdered texturizing agent was dispersed, the mixture was mixed on high speed for five minutes.
2. The texturizing agent/milk mixture was cooled to 40.degree. F. (4.4.degree. C.).
3. The acid was slowly added while mixing with an overhead stirrer. The contents were transferred to a hot-water bath and heated to 190.degree. F. (87.7.degree. C.) with occasional gentle stirring. Once at the target temperature, the gel was allowed to set for 30 minutes without agitation.
4. The resultant curd was filtered through 4 layers of cheese cloth and chilled in refrigeration for at least 4 hours. The resultant curd was rinsed in 40.degree. F. (4.4.degree. C.) water to remove excess acetic acids.
The non-fat ricotta cheese containing the texturizing agent represented a significant improvement in quality and cheese yield compared to the skim ricotta prepared without the texturizing agent. The presence of the texturizing agent resulted in a smoother and creamier texture versus the dry and crumbly texture without the texturizing agent. Table 1 gives the cheese yield and sensory data.
TABLE 1______________________________________ Cheese Yield Total SolidsProduct (%) (%) Texture______________________________________Skim ricotta 12.9 27.0 dry, crumblyFull fat 17.9 31.0 smooth,ricotta creamyNon-fat 18.9 22 softricotta with creamytexturizingagent______________________________________
Example 2
Non-fat Cheddar Cheese
______________________________________ Weight/WeightIngredients Percentage______________________________________Pasteurized skim milk 99.70Texturizing Agent 0.30 100.00Annatto Color (1 ml/gal)Chymogen (diluted 1:10 v/v in water) (10 ml/gal)Bacterial Culture (DVS 970 pellets) (0.70 g/gal)Salt (0.025 lb/lb wet curd)______________________________________
Process
1. Powdered texturizing agent was dispersed into 200.degree. F. (93.degree. C.) milk with the aid of a kitchen blender. Once dispersed, the mixture was mixed for five minutes on high speed. The mixture was cooled to 90.degree. F. (32.2.degree. C.), and then the annatto color was added while mixing.
2. The starter culture, DVS 970 pellets, was introduced, with slow overhead stirring. After waiting about 45 minutes for some acid development, the chymogen enzyme was mixed in, with gentle overhead stirring.
3. The product was allowed to sit quiescently at 90.degree. F. (32.2.degree. C.) until smooth curd developed (30-45 minutes).
4. The body of the curd was cut through with a metal spatula. Cross-sectional cuts produced 1/3 to 1/2 inch curds. The cut curds were left undisturbed until the pH reached 6.1.
5. The mixture was slowly heated, with occasional gentle stirring with a spatula, to 100.degree. F. (37.8.degree. C.) over a 30 minute time period. This temperature was maintained for an additional 30 minutes with only intermittent stirring of curds (once every 5 minutes).
6. The whey was drained from the curds by passing through four layers of cheesecloth. 0.025 lb table salt per one pound of curd was added. The salt was sifted over the curds until uniformly dispersed.
7. The salted curds were transferred into a sterile flat square of cheesecloth. Both ends of the filled cloth were tied to form a tight bag and placed on a clean board. Another board was placed over this, and a pail of water was placed on top (five gallons fill volume).
8. The bag of curd was pressed overnight in a 70.degree. F. (21.degree. C.) room.
9. The next day the molded cheese was removed from the press and the cloth was carefully peeled off. The curd was carefully patted dry with clean cheesecloth or sterile towels.
10. The cheese was totally immersed for five seconds in hot melted food wax. The cheese can be optionally covered tightly with Saran wrap. The cheese was removed and placed on a clean board. The cheese should be stored in refrigeration for two to six months.
The non-fat cheddar cheese containing the texturizing agent was soft and creamy in texture in contrast to the rubbery and dry texture of the skim cheddar without the texturizing agent. The presence of the texturizing agent increased the cheese yield of skim cheddar by 12.4%. Table 2 gives the cheese yield and the sensory data.
TABLE 2______________________________________ Cheese Yield Total SolidsProduct (%) (%) Texture______________________________________Skim cheddar 7.3 44.1 dry, firm, rubberyFull fat 10.9 46.8 soft,cheddar creamySkim cheddar 9.7 36.3 softwith creamytexturizingagent______________________________________
Example 3
No-fat Mozzarella Cheese
______________________________________ Weight/WeightIngredients Percentage______________________________________Pasteurized skim milk 99.70Texturizing Agent 0.30 100.00Chymogen (diluted 1:10 v/v in water) (10 ml/gal)STC4 Culture (0.40 g/gal)LHBO1 Culture (0.40 g/gal)Salt (0.025 lb/lb wet curd)______________________________________
Process
Day 1
1. Powdered texturizing agent was dispersed into 200.degree. F. (93.degree. C.) milk with the aid of a kitchen blender. Once dispersed, mixing was continued on high speed for five minutes. The mixture was cooled to 93.degree. F. (33.9.degree. C.).
2. The starter culture was introduced with slow overhead stirring. The chymogen enzyme was mixed in, with gentle overhead stirring.
3. The product was allowed to sit quiescently at 93.degree. F. (33.9.degree. C.) until a smooth curd developed (30-45 minutes).
4. The body of the curd was cut through with a metal spatula. Cross-sectional cuts produced 1/3to 1/2inch curds. The cut curds were left undisturbed for 15 minutes.
5. The whey was drained from curds by passing through four layers of cheesecloth. Both ends of the cloth were tied off, the bag was rinsed twice with cold clean water.
6. The bag was hung up to drain overnight in the refrigerator.
Day 2
7. The bag was removed and placed in a 90.degree. F. (32.2.degree. C.) oven. It was tested for stretching by dipping a small portion of curd into 170.degree. F. (77.degree. C.) water. The curd was stirred with a spatula for several minutes, then removed and stretched. The dipping and pulling was repeated until the curd could be stretched into a long smooth plastic length with a bright sheen. Once the curd was ready, 1/2 lb portions were formed by dicing and immersing the cubes into a gallon of 170.degree. F. (77.degree. C.) water and stirring gently with a spatula for three to five minutes. Portions of the hot mass were removed from the water and pulled by hand. The hot water immersion was repeated, pulling several times until a smooth curd of bright sheen developed. At that point, it was mold into a finished round ball and then placed into ice water to harden.
8. One pound of table salt was stirred into one gallon of chilled clean water. The cheeses were removed from the unsalted cold water bath and placed into the brine solution so that they were covered completely. They were left in salt brine for three to six hours and then removed, briefly dried, and packaged in Saran wrap.
The no-fat mozzarella containing the texturizing agent was less rubbery in texture with improved "stretch" when melted compared to the no-fat mozzarella prepared without the texturizing agent. A 31% increase in cheese yield was noted in the sample with the texturizing agent versus without the texturizing agent. Table 3 gives the cheese yield and the sensory data.
TABLE 3______________________________________ Cheese Yield Total SolidsProduct (%) (%) Texture______________________________________Skim 6.7 44.9 rubbery;mozzarella translucent appearance; poor stretch when meltedFull fat 14.0 47.9 smoothmozzarellaSkim 8.8 42.4 Less rubbery,mozzarella improved meltwithtexturizingagent______________________________________
Processed Cheese Formulations
Ingredients
Maltodextrin M100 (DE=10) manufactured by Grain Processing Corporation.
Pregelatinized, high amylose starch based texturizing agent (OPTAGRADE.RTM.) manufactured by Opta Food Ingredients, Inc., prepared by spray drying hot pregelatinized, high amylose starch and 25% maltodextrin (M040 from Grain Processing Corporation).
Microcrystalline cellulose (Novagel RCN-10) manufactured by the FMC Corporation.
Carrageenans (Gelcarin GP 911 and Seakem GP 418) manufactured by the FMC Corporation.
High flavored, enzyme modified cheddar cheese prepared with a blend of enzymes and comprising cheddar cheese, water, inactivated enzymes, sodium citrate, disodium phosphate and starter distillate (27% fat; 43% moisture). Commercially available under the name Chedr POW'R from Chris Hansen's Laboratory Inc.
Example 4
Preparation of Processed Cheese Under High Shear/High Temperature
Processed cheese was prepared with and without microcrystalline cellulose (FMC Novagel RCN-10) and with and without the starch based texturizing agent.
The ingredients are as follows:
______________________________________ Hi Shear Hi Shear w/TexturizingINGREDIENTS w/MCC Agent______________________________________Skim Cheese 55.00 55.00Disodium Phosphate 1.00 1.00Sodium Citrate 1.50 1.50Salt 0.50 0.50Nonfat Dry milk 3.50 3.50Sweet Whey 6.00 6.00Maltodextrin(DE = 10) 2.40 2.4034% whey protein conc. 1.00 1.00Novagel RCN-10 2.00Gelcarin GP 911 0.30 0.30Seakem GP 418 0.10 0.10Texturizing Agent 2.00Water 15.44 15.44Steam 9.60 9.6020% Lactic acid 1.30 1.30Chedr Pow'r 1.00 1.00Carot 73-color 0.06 0.06Total 100.70 100.70Target Moisture 57.10 57.10______________________________________
The dry ingredients were blended together and then liquid (preferably buttermilk) was added and mixed until smooth. The slurry was added to a small two pound Stephen Mixer/Cooker which was preheated to 90.degree. C. The slurry was heated to 60.degree. C. while mixing at 300 r.p.m. Shredded skim milk cheese was then added and a vacuum was applied to 80%. The slurry was then mixed for 7.5 minutes at 500 r.p.m. and heated to 75.degree. C. At that temperature the vacuum was released, acid was added to the mixture and stirred at 700 r.p.m. for 45 seconds. The mixture was cooled and refrigerated overnight at 5.degree. C.
The products were evaluated for moisture, pH, melt (Schreiber melt test), flavor, texture (mouthfeel and touch), color, slicability (knife and mechanical), shred (ease of shred, dryness, balling on compression, release after compression) and ability to release from plastic packaging after cooling.
The Schreiber melt test was performed by cutting the cheese into 2 inch circles (1/8inch thick) and melting the cheese circles in a preheated oven at 450.degree. F. for 3 minutes. The degree of melt was measured using a template having a number of concentric rings. This test is well known to those skilled in the art.
The results are shown in Table 4. Processed cheese produced under high shear with microcrystalline cellulose was smooth but soft. Processed cheese produced under high shear with texturizing agent contained white particulates.
Example 5
Preparation of Processed Cheese Under Low Shear/High Temperature
Cheese formulations as described in Example 4 were processed in a small five pound pilot plant Hobart Cooker. The cooker applies mild shear and has been found to correlate highly to 35 pound auger pilot plant cooker.
The dry ingredients were blended together and then water was added under agitation to yield a smooth slurry. The slurry was added to the Hobart cooker and slowly agitated. The cooker was heated with steam to 80-85.degree. C. and held for 5 minutes under agitation. Shredded skim milk cheese was added with agitation and steam injection continued until the temperature was 80-85.degree. C. Acid was mixed into the slurry for one minute at high speed. The slurry was removed from the cooker, cooled and stored overnight at 5.degree. C. prior to evaluation.
The ingredients are as follows:
______________________________________ Hi Shear Hi Shear w/TexturizingINGREDIENTS w/MCC Agent______________________________________Skim Cheese 55.00 55.00Disodium Phosphate 1.00 1.00Sodium Citrate 1.50 1.50Salt 0.50 0.50Nonfat Dry milk 3.50 3.50Sweet Whey 6.00 6.00Maltodextrin(DE = 10) 2.40 2.4034% whey protein conc. 1.00 1.00Novagel RCN-10 2.00Gelcarin GP 911 0.30 0.30Seakem GP 418 0.10 0.10Texturizing Agent 2.00Water 15.44 15.44Steam 9.60 9.6020% Lactic acid 1.30 1.30Chedr Pow'r 1.00 1.00Carot 73-color 0.06 0.06Total 100.70 100.70Target Moisture 57.10 57.10______________________________________
The products were evaluated for the parameters described in Example 4. The results are reported in Table 4. Processed cheese produced under low shear with microcrystalline cellulose was better in quality compared to similar cheese produced under high shear. Processed cheese produced under low shear with texturizing agent was better than similar cheese produced under high shear and slightly better than the processed cheese containing microcrystalline cellulose produced under low shear. It had a reduced perfumy flavor.
Example 6
Preparation of Processed Cheese--Partial Replacement of Fillers
The process of Example 5 was followed to prepare processed cheese having the following ingredients:
______________________________________ SampleINGREDIENTS A B C D E______________________________________Skim Cheese 64.84 64.84 64.84 64.84 64.84Disodium Phosphate 2.00 2.00 2.00 2.00 2.00Trisodium Phosphate 0.60 0.60 0.60 0.60 0.60Sweet Whey 4.00 4.00 4.00 4.00 4.00Maltodextrin(DE = 10) 2.00 2.00Nonfat Dry milk 4.00 6.00 3.00Texturizing Agent 2.00 2.00 2.00Chedr Pow'r 1.00 1.00 1.00 1.00 1.00Water 9.50 11.50 9.50 10.50 13.50Steam 8.00 8.00 8.00 8.00 8.0020% Lactic acid 4.00 4.00 4.00 4.00 4.00Carot 73-color 0.60 0.60 0.60 0.60 0.60Total 100.00 100.00 100.00 100.00 100.00Target Moisture 55.87 57.77 55.87 56.81 59.67______________________________________
The results as evaluated according to Example 4 are shown in Table 5. The Sample B processed cheese was slightly soft whereas the Sample D formulation yielded a processed cheese well suited for block/shred formats.
Example 7
Preparation of Processed Cheese--Partial Replacement of Skim Milk Cheese
The process of Example 5 was followed to prepare processed cheese having the following ingredients:
______________________________________ SampleINGREDIENTS A B C D______________________________________Skim Cheese 50.00 55.00 60.00 64.84Disodium Phosphate 1.50 1.50 1.75 2.00Trisodium Phosphate 0.50 0.50 0.50 0.60Sweet Whey 8.00 6.25 4.00 4.00Maltodextrin(DE = 10) 3.00 3.00 3.00Nonfat Dry milk 2.94 2.19 2.19 3.00Texturizing Agent 2.00 2.00 2.00 2.00Chedr Pow'r 1.00 1.00 1.00 1.00Water 19.50 16.50 13.50 9.50Steam 8.00 8.00 8.00 8.0020% Lactic acid 4.00 4.00 4.00 4.00Carot 73-color 0.06 0.06 0.06 0.06Total 100 100 100 100Target Moisture 57.92 57.89 57.39 56.81______________________________________
Skim milk levels from 50-65 of the finished product were evaluated and the results shown in Table 6. Sample A cheese contained a high percentage of white particulates, indicating that hydration of starch was inadequate. Formulation for Sample B resulted in a poor processed cheese. The formulation for Sample C resulted in a soft, wet processed cheese.
Example 8
Preparation of Processed Cheese with Varying Amounts of Texturizing Agent and Carrageenan
The process of Example 5 was followed to prepare processed cheese having the following ingredients:
______________________________________ SampleINGREDIENTS A B C D E F______________________________________Skim Cheese 55.00 55.00 55.00 55.00 55.00 55.00Disodium Phosphate 1.00 1.00 1.00 1.00 1.00Sodium Citrate 1.50 1.50 1.50 1.50 1.50Sweet Whey 6.50 6.50 6.50 6.50 6.50Maltodextrin(DE = 10) 1.49 1.89 1.99 2.39 0.99Nonfat Dry milk 3.00 3.00 3.00 3.00 3.00Texturizing Agent 2.00 2.00 1.50 1.50 2.50Gelcarin GP 911 0.30 0.30 0.30Seakem GP 418 0.10 0.10 0.10Salt 0.50 0.50 0.50 0.50 0.50Chedr Powr 1.00 1.00 1.00 1.00 1.00Water 18.25 18.25 18.25 18.25 18.25Steam 8.00 8.00 8.00 8.00 8.0020% Lactic acid 1.30 1.30 1.30 1.30 1.30Carot 73-color 0.06 0.06 0.06 0.06 0.06TotalTarget Moisture 56.99 56.99 56.99 56.99 56.99______________________________________
The results are reported in Table 7. Formulations for Samples A, B and C yield processed cheeses of excellent quality. Sample D was soft and similar to VELVEETA.TM. brand processed cheese and was not pasty. Sample E lacked flavor but had the best mechanical slice characteristics compared to the other samples.
TABLE 4__________________________________________________________________________ MELT SLICABILITY**PRODUCT MOISTURE pH 0-10 SHRED* KNIFE MECHANIC WIRE COLOR FLAVOR TEXTURE__________________________________________________________________________Hi Shear 57.40 5.90 4.00 Not good Smooth OK, but soft Feathers Not mottled Clean Only sl. dryw/MCC Hi fines OK Perfumy Sl. firm Hi wet/soft Pasty Balling+ Low chew Release-Hi Shear 58.51 5.92 5.00 Sl. tacky OK OK Sl. "feather" Mottled Clean Dry, mealyw/Texturizing OK fines White No Acid Soft, but OKAgent No ball particulates for slices Good for chill rolls Good Release after ball goodLow Shear 59.42 5.90 4.50 Nice OK OK Sl. "feather" Reduced mottle Cheesy V. firmw/MCC Lo fines Resists cut Long, dry Ball+ Release++Low Shear 59.95 5.82 4.25 Very firm OK OK OK Little mottle Clean Firmw/Texturizing Lo fines Translucent Cheesy Little mot.Agent Ball++ No white Moist Release++ particulates Lo "feather" Dry__________________________________________________________________________ *SHRED = LOOKING FOR DRY, LONG SHREDS; FEW FINES, NO OR LITTLE BALLING ON COMPRESSION, IF BALLING EASY RELEASE **SLICIABILITY = LOOKING FOR FIRM, DRY SLICE VIA KNIFE, MECHANICAL, WIRE; ABILITY TO TRANSLATE TO "CHILL ROLL" SLICE PROCESS
TABLE 5__________________________________________________________________________ MELT SLICABILITY**PRODUCT MOISTURE pH 0-10 SHRED* KNIFE MECHANIC WIRE COLOR FLAVOR TEXTURE__________________________________________________________________________A 59.50 5.66 10+ Long Firm OK Feathers Burnt Clean Smooth Some fines Clean cut Uniform Sl. tart Feels dry Lo mat Sweet Hi release PerfumyB 61.26 5.56 5.75 Equal to A Sl. firmer OK Hi OK Clean Lo fines than A feather White Strong dry, meally Lo mat Partic. Tart Pasty Good release mouthfeelC 58.93 5.70 10+ Long Much better Clean Lo feather Good Sl. cheese Dry, firm few fines than A, B & OK Uniform Lo acid Not meally Best of Grp. Nice Clean smooth Lo mat Hi releaseD 59.92 5.56 5.75 Nice shred V. Firm V. Good Sl. feather Few white Good Firm Long Smooth particul. Clean Elastic Lo fines Lo fines Good Sl. acid Tough Lo mat Long chew Hi release Good for block/shredE 61.38 5.57 4.50 Soft OK Too soft? Clean Very hi Acid/tart Good Short No feath. white Not fine Soft Not as good as particul. cheese Wet, but not C Dry aftertaste tacky Hi mat Pasty, mealy Lo release__________________________________________________________________________ *SHRED = LOOKING FOR DRY, LONG SHREDS; FEW FINES, NO OR LITTLE BALLING ON COMPRESSION, IF BALLING EASY RELEASE **SLICABILITY = LOOKING FOR FIRM, DRY SLICE VIA KNIFE, MECHANICAL, WIRE; ABILITY TO TRANSLATE TO "CHILL ROLL" SLICE PROCESS
TABLE 6__________________________________________________________________________ MELT SLICABILITY**PRODUCT MOISTURE pH 0-10 SHRED* KNIFE MECHANIC WIRE COLOR FLAVOR TEXTURE__________________________________________________________________________A 61.91 5.52 10+ Mealy Soft No Hi feather OK Cheesy Mealy Crumbles Sl acid/ Soft Hi fines acid Wet Hi matB 61.62 5.64 10+ Soft, but Soft No Wet Looks wet Mealy Very wet better than Lacks flavor Acid tartC 61.32 5.50 10+ Crumbly Feels No Wet Hi white Dirty Soft Short rough Feathery particulate No cheese Wet Soft Poor Sl. acid Tacky Mats w/o Pasty releaseD 59.92 5.56 5.75 Nice V. Firm V. Good OK Good Sl. cheese Dry Few fines Good Sl. feather Uniform Sl. tart Not mealy Long Clean firm dry Smooth__________________________________________________________________________ *SHREDS = LOOKING FOR DRY, LONG SHREDS; FEW FINES, NO OR LITTLE BALLING O COMPRESSION, IF BALLING EASY RELEASE **SLICABILITY = LOOKING FOR FIRM, DRY SLICE VIA KNIFE, MECHANICAL, WIRE; ABILITY TO TRANSLATE TO "CHILL ROLL" SLICE PROCESS
TABLE 7__________________________________________________________________________ MELT SLICABILITY**PRODUCT MOISTURE pH 0-10 SHRED* KNIFE MECHANIC WIRE COLOR FLAVOR TEXTURE__________________________________________________________________________A 61.38 5.78 10+ Nice Good Good Sl. feather Very good Clean Firm 61.48 5.82 10+ Few fines Lacks Not tacky Long cheese Clean Lo mat Sl. PastyB 61.48 5.82 10+ Sl. dry Good ?? Good Very good Sl. salty Soft Similar to Perfumy Not mealy A/B Same as A/B Long Few finesC 60.96 5.79 10+ Easy shred Very good Only sl. Good Clean Very Very clean few fines Very good feather Sl. cheese Not tacky Long Mats w/release mouthfeelD 60.93 5.78 10+ Wet Clean NO Nice w/o Good Mild Wetvor Sl. long feather OK Tacky Mats, but Moist good releaseE 59.90 5.78 10+ Excellent Great OK OK Good Flat Firm Long Even cut Not tacky Clean Mats w/ releaseF*** 61.52 5.80 10+ Great OK OK Sl feather Good Sl. cheese Soft Long Waters off Sl. salt Sl. wet Mats w/ Grainy release__________________________________________________________________________ *SHREDS = LOOKING FOR DRY, LONG SHREDS; FEW FINES, NO OR LITTLE BALLING O COMPRESSION, IF BALLING EASY RELEASE **SLICABILITY = LOOKING FOR FIRM, DRY SLICE VIA KNIFE, MECHANICAL, WIRE; ABILITY TO TRANSLATE TO "CHILL ROLL" SLICE PROCESS ***MISSED 5 MINUTE HOLD AT 80.degree. C.
Equivalents
Those skilled in the art will recognize, or be able to ascertain using no more than routine experimentation, many equivalents to the specific embodiments of the invention described herein. Such equivalents are intended to be encompassed by the following claims:
Claims
  • 1. A fat free natural or processed cheese comprising a non-fat dairy ingredient, one or more flavoring agents, and a starch based texturizing agent derived from pregelatinized, high amylose starch in which the starch has a dextrose equivalent value of less than five.
  • 2. The fat free cheese of claim 1 which is a natural cheese.
  • 3. The fat free cheese of claim 1 which is a processed cheese.
  • 4. The fat free cheese of claim 2, wherein the starch based texturizing agent is present in amount of from about 0.1% to about 1.0% by weight.
  • 5. The fat free cheese of claim 4, wherein the starch based texturizing agent is present in amount of from about 0.2% to about 0.4% by weight.
  • 6. The fat free cheese of claim 3, wherein the starch based texturizing agent is present in amount of from about 1.0% to about 4.0% by weight.
  • 7. The fat free cheese of claim 6, wherein the starch based texturizing agent is present in amount of from about 1.5% to about 2.5% by weight.
  • 8. The fat free cheese of claim 3, further comprising an emulsifying salt.
  • 9. The fat free cheese of claim 8, wherein the emulsifying salt is selected from the group consisting of disodium phosphate, trisodium phosphate, sodium citrate and combinations thereof.
  • 10. The fat free cheese of claim 1, wherein the non-fat dairy ingredient is selected from the group consisting of skim milk cheese, non-fat drymilk, skim milk, skim butter milk, milk protein isolates and combinations of these.
  • 11. The fat free cheese of claim 1, wherein the starch based texturizing agent comprises an excipient.
  • 12. The fat free cheese of claim 11, wherein the excipient is maltodextrin.
  • 13. The fat free cheese of claim 1, wherein the starch based texturizing agent comprises maltodextrin and high amylose starch that has been pregelatinized, wherein said texturizing agent is spray dried into a powder which is retrograded and crystalline, partially retrograded and crystalline, or nonretrograded and noncrystalline.
  • 14. The fat free cheese of claim 1, further comprising at least one gelling polysaccharide.
  • 15. The fat free cheese of claim 14, wherein the gelling polysaccharide is selected from the group consisting of carrageenan, alginate, guar gum, locust bean gum, konjac gum and combinations thereof.
  • 16. The fat free cheese of claim 1, further comprising a carbohydrate product.
  • 17. The fat free cheese of claim 16, wherein the carbohydrate product is selected from the group consisting of microcrystalline cellulose and carboxymethyl cellulose.
  • 18. A reduced fat or low fat natural or processed cheese comprising a low fat dairy ingredient, one or more flavoring agents, and a starch based texturizing agent derived from pregelatinized, high amylose starch in which the starch has a dextrose equivalent value of less than five.
  • 19. The reduced fat or low fat cheese of claim 18 which is a natural cheese.
  • 20. The reduced fat or low fat cheese of claim 18 which is a processed cheese.
  • 21. The reduced fat or low fat cheese of claim 19, wherein the starch based texturizing agent is present in amount of from about 0.1% to about 1.0% by weight.
  • 22. The reduced fat or low fat cheese of claim 21, wherein the starch based texturizing agent is present in amount of from about 0.2% to about 0.4% by weight.
  • 23. The reduced fat or low fat cheese of claim 20, wherein the starch based texturizing agent is present in amount of from about 1.0% to about 4.0% by weight.
  • 24. The reduced fat or low fat cheese of claim 23, wherein the starch based texturizing agent is present in amount of from about 1.5% to about 2.5% by weight.
  • 25. The reduced fat or low fat cheese of claim 20, further comprising an emulsifying salt.
  • 26. The reduced fat or low fat cheese of claim 25, wherein the emulsifying salt is selected from the group consisting of disodium phosphate, trisodium phosphate, sodium citrate and combinations thereof.
  • 27. The reduced fat or low fat cheese of claim 18, wherein the dairy ingredient is selected from the group consisting of skim milk cheese, non-fat drymilk, skim milk, milk protein isolates, skim butter milk and combinations thereof.
  • 28. The reduced fat or low fat cheese of claim 18, further comprising a fat-containing dairy ingredient selected from the group consisting of whole milk, whole milk cheese, reduced fat milk, reduced fat milk cheese and combinations thereof.
  • 29. The reduced fat or low fat cheese of claim 18, wherein the starch based texturizing agent comprises an excipient.
  • 30. The reduced fat or low fat cheese of claim 29, wherein the excipient is maltodextrin.
  • 31. The reduced fat or low fat cheese of claim 18, wherein the starch based texturizing agent comprises maltodextrin and high amylose starch that has been pregelatinized, wherein said texturizing agent is spray dried into a powder which is retrograded and crystalline, partially retrograded and crystalline, or nonretrograded and noncrystalline.
  • 32. The reduced fat or low fat cheese of claim 18, further comprising at least one gelling polysaccharide.
  • 33. The reduced fat or low fat cheese of claim 32, wherein the gelling polysaccharide is selected from the group consisting of carrageenan, alginate, guar gum, locust bean gum, konjac gum and combinations thereof.
  • 34. The reduced fat or low fat cheese of claim 18, further comprising a carbohydrate product.
  • 35. The reduced fat or low fat cheese of claim 34, wherein the carbohydrate product is selected from the group consisting of microcrystalline cellulose and carboxymethyl cellulose.
  • 36. A method of making a fat free or reduced fat natural or processed cheese, said method comprising replacing at least a portion of fat traditionally incorporated into a cheese with a starch based texturizing agent derived from pregelatinized, high amylose starch in which the starch has a dextrose equivalent value of less than five.
RELATED APPLICATIONS

This is a continuation-in-part of U.S. patent. application Ser. No. 08/324,513, filed Oct. 14, 1994, now abandoned, which is a continuation-in-part of U.S. patent application Ser. No. 08/138,541, filed Oct. 15, 1993, now U.S. Pat. No. 5,470,391, which is a continuation-in-part of U.S. patent application Ser. No. 07/900,899, filed Jun. 18, 1992, now abandoned. The entire teachings of each application are incorporated herein by reference.

US Referenced Citations (44)
Number Name Date Kind
3086890 Sarko et al. Apr 1963
3238064 Macarus et al. Mar 1966
3515591 Feldman et al. Jun 1970
3650770 Marcotta et al. Mar 1972
3666557 Jensen et al. May 1972
3836677 Freck et al. Sep 1974
3962465 Richter et al. Jun 1976
3986890 Richter et al. Oct 1976
4252900 Muller et al. Feb 1981
4280851 Pitchon et al. Jul 1981
4427709 Guhl et al. Jan 1984
4452978 Eastman Jun 1984
4499116 Zwiercan et al. Feb 1985
4510166 Lenchin et al. Apr 1985
4568555 Spanier Feb 1986
4594255 Wilson et al. Jun 1986
4608265 Zwiercan et al. Aug 1986
4623549 Katt et al. Nov 1986
4695475 Zwiercan et al. Sep 1987
4917915 Cain et al. Apr 1990
4937091 Zallie et al. Jun 1990
4956193 Cain et al. Sep 1990
4971723 Chiu Nov 1990
4992539 Portnoy et al. Feb 1991
5051271 Iyengar et al. Sep 1991
5108773 Smith et al. Apr 1992
5131953 Kasica et al. Jul 1992
5180604 Crane et al. Jan 1993
5208061 de Coninck et al. May 1993
5215778 Davison et al. Jun 1993
5250316 Harris Oct 1993
5275837 Eastman Jan 1994
5281432 Zallie et al. Jan 1994
5286510 Bauer et al. Feb 1994
5320860 Duval et al. Jun 1994
5324532 Stute et al. Jun 1994
5338560 Wesdorp et al. Aug 1994
5372835 Little et al. Dec 1994
5374442 Harris et al. Dec 1994
5387426 Harris et al. Feb 1995
5395630 Gamay Mar 1995
5395640 Harris et al. Mar 1995
5484618 Barz et al. Jan 1996
5584937 Finocchiaro Dec 1996
Foreign Referenced Citations (30)
Number Date Country
2047266 Nov 1992 CAX
0120498A3 Oct 1984 EPX
298561 A2 Jan 1989 EPX
0298561A2 Jan 1989 EPX
0366898A1 May 1990 EPX
0372184A1 Jun 1990 EPX
0441494A1 Aug 1991 EPX
0443844A1 Aug 1991 EPX
0480433A2 Apr 1992 EPX
0495407A1 Jul 1992 EPX
512249 A1 Nov 1992 EPX
519104 A1 Dec 1992 EPX
516107 A1 Dec 1992 EPX
0529892A1 Mar 1993 EPX
0554818A2 Aug 1993 EPX
558832 A2 Sep 1993 EPX
0590203A1 Apr 1994 EPX
590203 A1 Apr 1994 EPX
648425 A2 Apr 1995 EPX
1562275 Mar 1980 GBX
8912403 Dec 1989 WOX
9102463 Mar 1991 WOX
9202147 Feb 1992 WOX
9303630 Mar 1993 WOX
9303629 Mar 1993 WOX
9325084 Dec 1993 WOX
9405163 Mar 1994 WOX
9409645 May 1994 WOX
9514389 Jun 1995 WOX
9521534 Aug 1995 WOX
Continuation in Parts (3)
Number Date Country
Parent 324513 Oct 1994
Parent 138541 Oct 1993
Parent 900899 Jun 1992