The present invention relates to the field of polymers suitable for generating films, notably the sizing of fibers for facilitating handling thereof and for making composite materials.
Presently, most composite materials used in high performance applications are based on carbon fibers and thermosetting matrices such as polyepoxy resins. However, these thermosetting matrices suffer from low chemical resistance and low mechanical impact resistance causing complexity of formulation which complicates their application. Further, these composite materials are not recyclable because of their three-dimensional chain architecture.
These drawbacks therefore explain the potential benefit of thermoplastic matrices which would further satisfy the criteria for respecting the environment. Thermostable thermoplastic matrices may be used in high-tech activity fields such as aeronautics and the space industry.
Regardless of the nature of the matrix, the interface of the matrix with the carbon fiber remains a crucial point. For this, the fiber is covered with a thin layer called size. This size is generally of an oligomeric or polymeric nature which may be adapted depending on the matrix used. It has the role of facilitating handling of the fibers during application but especially of promoting interactions between the fiber and the matrix. Given that the majority of high performance composites presently used are based on thermosetting matrices, most of the sizings consist of epoxy resin. Consequently, there does not exist any sizing adapted to thermoplastic matrices, notably to thermostable thermoplastic matrices, the sizing of which should resist to high application temperatures, sometimes above 300° C.
From a practical point of view, sizing is ideally accomplished by soaking or by spraying on the fibers, from a polymer in a solution or dispersion in a solvent.
For health, safety reasons and also in order to preserve the environment, it is desirable to use water as a solvent. However, high performance thermoplastic polymers are generally insoluble in water and their polymerization method is often incompatible with the latter. It is therefore desirable to make available stable aqueous dispersions of thermostable thermoplastic polymers.
Obtaining stable aqueous dispersions of nanoparticles of polymers may be achieved in different ways:
Methods b)-d) are widely used, notably in the agrifood and pharmaceutical industry for encapsulating active ingredients, notably for controlling the release rate and for avoiding degradation of the active ingredient.
However, no stable aqueous dispersion of high performance thermoplastic polymers having physico-chemical characteristics notably allowing sizing has been developed.
The object of the invention is the elaboration of stable and long term storage aqueous dispersions of nanoparticles of polymers having physical properties compatible with thermoplastic sizing.
According to a first object, the present invention therefore relates to a stable aqueous dispersion of nanoparticles of a high performance thermoplastic polymer or of mixtures of high performance thermoplastic polymers.
The dispersions according to the invention are stable for at least six months under normal storage conditions at room temperature.
In an advantageous aspect of the invention, the polymers to be dispersed will be selected according to their physical properties (temperature resistance, solubility) compatible with thermoplastic sizing, as well as with the previously selected dispersion techniques.
Said thermoplastic polymers suitable for the invention are selected from the family of polyetherimides and polyaryletherketones as well as from their mixtures such as for example, polyetherimide (PEI), polyetherketoneketone (PEKK).
The polyetherimide (PEI) may be illustrated by the following formula:
Polyetherketoneketone (PEKK) may be illustrated by the following formula:
In the sense of the present invention, by polymers are meant compounds having a polymerization degree comprised between 2 and 100.
According to the present invention, the PEI preferentially has an average polymerization degree comprised between 10 and 50, notably about 20 i.e., an average molecular mass of 12,000 g/mol and PEKK preferentially has an average polymerization degree comprised between 1 and 10, advantageously about 3, i.e. an average molecular mass of 1,000 g/mol.
The stable aqueous dispersions according to the invention essentially consist of nanoparticles of said polymer(s) having an average diameter comprised between 10 and 1000 nm, preferentially between 50 et 150 nm.
The mass percentage of said polymer(s) in the dispersions according to the invention is generally comprised between 0.01 et 0.1%, preferentially between 0.03 et 0.06%. These ranges of sizes and concentrations are advantageous, notably for a sizing deposit.
The dispersions according to the invention may further comprise one or more emulsifying agents and/or dispersants. These agents may notably be selected from the family of surfactants and/or water-soluble or amphiphilic polymers.
Generally, the mass percentage of emulsifier and/or dispersing agents is comprised between 0.01 and 20%, preferentially between 0.01 and 5%, and advantageously about 0.5%.
Among the surfactants, mention may be made of non-ionic, cationic, anionic, zwitterionic, hydrogenated or fluorinated amphiphilic molecules, such as for example sodium cholate, sodium deoxycholate, sodium glycocholate, sodium taurocholate, sodium taurodeoxycholate, lecithins, phospholipids, Tween 20, Tween 40, Tween 60, Tween 80, Span 20, Span 40, Span 60, Span 80, sodium dioctylsulfosuccinate, sodium dodecylsulfate, ammonium salts with long chains such as hexadecyltrimethylammonium bromide as well as all the combinations of these molecules.
In an advantageous aspect of the invention, the surfactant is selected from sodium dodecylsulfate and/or sodium dioctylsulfosuccinate.
The dispersant polymers suitable for the application of the present invention may be selected from macromolecules of natural or synthetic origin, homopolymers or copolymers, charged homopolymers or charged copolymers, amphiphilic homopolymers or amphiphilic copolymers, hyper-branched polymers or copolymers, dendrimers, polysaccharides, as well as all the combinations of these macromolecules, emulsifiers such as gelatin, as well as all the combinations of these polymers.
According to the invention, the dispersions are prepared from an emulsion or from an emulsion/dispersion of oil in water by an evaporation method or by diffusion in water of a polymer solution or by dispersion in the oil phase.
According to another object, the present invention therefore also relates to the method for preparing a dispersion according to the invention, said method comprising the transfer of said polymer(s) of a solution or dispersion in an organic solvent or a mixture of organic solvents to an aqueous phase, such that:
In the sense of the present invention, by volatile solvent non-miscible with water under normal pressure and temperature conditions, are meant compounds advantageously formed by chloroform, methylene chloride, dichloromethane, dichloroethane, aliphatic hydrocarbons, halogenated aliphatic hydrocarbons, aromatic hydrocarbons, cyclohexane, halogenated aromatic hydrocarbons, ethers, ethyl acetate, ethyl formate and their mixtures. More advantageously, the solvent is chloroform.
In the sense of the present invention, by solvent miscible with water are meant compounds advantageously selected from the group comprising methanol, ethanol, isopropanol, dimethylformamide, dimethylsulfoxide, acetonitrile, acetone, dioxane and N-methyl-2-pyrrolidone. More advantageously, the solvent is N-methyl-2-pyrrolidone.
The mass percentage of polymer(s) in said organic solvent(s) is generally comprised between 0.1 and 10%, preferentially comprised between 1 and 5%, advantageously about 3%.
The method according to the invention generally comprises the following steps:
The volume fraction of solvent(s) in the solvent(s)+water mixture (step (a)) is generally comprised between 0.05 and 0.5, advantageously about 0.1.
According to whether said polymer(s) is(are) soluble or dispersible in said organic solvent(s) and whether said organic solvent(s) is(are) miscible or non-miscible with water, four possible embodiments (numbered from P1 to P4) for applying the method according to the invention are therefore distinguished:
P1:
When said polymer(s) is(are) soluble in said organic solvent(s) and said organic solvent(s) is(are) volatile, non-miscible with water, the dispersion according to the invention may be made by emulsion and evaporation.
Thus, according to this embodiment the method according to the invention comprises the evaporation step from an emulsion of said soluble polymer(s) in said volatile organic solvent(s) non-miscible with water.
More specifically, the method P1 comprises the following successive steps:
P2:
When said polymer(s) is(are) soluble in said organic solvent(s) and said organic solvent(s) is(are) miscible with water, the dispersion according to the invention may be made by diffusion.
Thus, according to this embodiment, the method according to the invention comprises the step for diffusing a solution of said polymer(s) in said organic solvent(s) miscible with water.
More specifically, the method P2 comprises the following successive steps:
Advantageously, the method P2 is used for obtaining stable dispersions of PEI, by preferentially using N-methyl-2-pyrrolidone as a solvent miscible with water.
P3:
When said polymer(s) is(are) dispersible in said organic solvent(s) and said organic solvent(s) is(are) volatile, non-miscible with water, the dispersion according to the invention may be made by emulsion/dispersion and evaporation.
Thus, according to this embodiment, the method according to the invention comprises the evaporation step from an oil-in-water emulsion/dispersion of said polymer(s) dispersible in said volatile organic solvent(s) non-miscible with water.
More specifically, the method P3 comprises the following successive steps:
Advantageously, the method P3 is used for obtaining stable PEKK dispersions, by preferentially using chloroform as a volatile solvent non miscible with water.
P4:
When said polymer(s) is(are) dispersible in said organic solvent(s) and said organic solvent(s) is(are) miscible with water, the dispersion according to the invention may be achieved by diffusion.
Thus, according to this embodiment, the method according to the invention comprises the diffusion step for a dispersion of said polymer(s) in said organic solvent(s) miscible with water.
More specifically, the method P4 comprises the following successive steps:
Advantageously, the method P4 is used for obtaining stable PEKK dispersions, while preferentially using N-methyl-2-pyrrolidone as a solvent miscible with water.
The thereby obtained stable aqueous dispersions may be used for forming coating films, preferentially for sizing of fibers or carbon nanotubes or of other morphologies based on carbon, as well as of aromatic polyamides, in order to elaborate thermoplastic composite materials.
Thus, according to another object, the present invention relates to a method for generating a film on a support comprising:
Said support may notably be selected from carbon fibers or nanotubes, fibers of aromatic polyamides, aramide fibers.
The present invention also aims at sized fibers which may be obtained by the method according to the invention.
According to another object, the present invention also relates to sizing comprising nanoparticles of a high performance thermoplastic polymer or of mixtures of high performance thermoplastic polymers as defined hereinbefore.
The particular sizing made by the deposited film of nanoparticles allows improvement in the application of the fibers and in the adhesion between fibers and matrix, particularly with polyaryletherketones (PAEK) matrices such as polyetheretherketone (PEEK) or polyetherketones (PEKs).
According to another object, the present invention also relates to a composite material comprising:
Said thermoplastic matrix is notably a polyaryletherketone (PAEK) matrix such as polyetheretherketone (PEEK) or polyetherketones (PEKs).
The following examples and figures to which reference is made, are given as an illustration and not as a limitation of the present invention.
Dissolve 0.0922 g of polyetherimide (n=20) (PEI) in 2 mL of chloroform.
In a beaker containing 0.1005 g of sodium dodecylsulfate (SDS) solubilized in 20 mL of distilled water, pour the PEI solution dissolved in chloroform.
Place the beaker in a water bath at room temperature and emulsify with ultrasound, continuous power 4 for 5 minutes (Vibra Cell, Bioblock Scientific, 600 W, 20 kHz).
Totally evaporate the chloroform under magnetic stirring at 1,000 revolutions per minute at room temperature and under atmospheric pressure.
The suspended PEI particles are of a homogeneous size of the order of 65 nm with a polydispersity index of 0.33 (
The obtained aqueous suspension is stable for 6 months at room temperature.
Dissolve 0.0922 g of polyetherimide (n=20) (PEI) in 2 mL of chloroform.
In a beaker containing 0.1005 g of sodium dioctylsulfosuccinate (SDOS) dissolved in 20 mL of distilled water, pour the solution of PEI dissolved in chloroform.
Place the beaker in a water bath at room temperature and emulsify with ultrasound, continuous power 4 for 5 minutes (Vibra Cell, Bioblock Scientific, 600 W, 20 kHz).
Totally evaporate the chloroform with magnetic stirring at 1,000 revolutions per minute at room temperature and at atmospheric pressure.
The suspended PEI particles are of a homogeneous size of the order of 50 nm with a polydispersity index of 0.29.
The obtained aqueous suspension is stable for six months at room temperature.
Homogeneously disperse 0.0922 g of polyetherketoneketone (n=3) (PEKK) as described in the literature (Y. Sakaguchi et al., SEN'I GAKKAISHI, Vol. 62, No. 7 (2006), p. 141; M. G. Zolotukhin et al., Polymer, Vol. 38, No 6 (1997), p. 1471), in 2 mL of chloroform by using an ultrasound bath.
In a beaker containing 0.1005 g of sodium dodecylsulfate (SDS) dissolved in 20 mL of distilled water, pour the PEKK dispersion prepared in chloroform.
Place the beaker in a water bath at room temperature and emulsify/disperse with ultrasound, continuous power 4 for 5 minutes (Vibra Cell, Bioblock Scientific, 600 W, 20 kHz).
Totally evaporate the chloroform with magnetic stirring at 1,000 revolutions per minute at room temperature and at atmospheric pressure.
The suspended PEKK particles are of a homogeneous size of the order of 100 nm with a polydispersity index of 0.28. Electron microscopy (
The obtained aqueous suspension is stable for six months at room temperature.
Thoroughly disperse 0.0922 g of polyetherketoneketone (n=3) (PEKK) as described in the literature (Y. Sakaguchi et al., SEN'I GAKKAISHI, Vol. 62, No. 7 (2006), p. 141; M. G. Zolotukhin et al., Polymer, Vol. 38, No 6 (1997), p. 1471) in 2 mL of chloroform by using an ultrasound bath.
In a beaker containing 0.1005 g of sodium dioctylsulfosuccinate (SDOS) dissolved in 20 mL of distilled water, pour the PEKK dispersion prepared in chloroform.
Place the beaker in a water bath at room temperature and emulsify/disperse with ultrasound, continuous power 4 for 5 minutes (Vibra Cell, Bioblock Scientific, 600 W, 20 kHz).
Totally evaporate the chloroform with magnetic stirring at 1,000 revolutions per minute at room temperature and at atmospheric pressure.
The suspended PEKK particles are of a homogeneous size of the order of 150 nm with a polydispersity index of 0.46.
The obtained aqueous suspension is stable for 6 months.
Thoroughly dissolve 0.0922 g of polyetherimide (n=20) (PEI) in 2 mL of N-methyl-2-pyrrolidone (NMP).
In a beaker containing 0.1005 g of sodium dodecylsulfate (SDS) dissolved in 20 mL of distilled water, pour dropwise and with ultrasound the solution of PEI dissolved in NMP by means of a glass syringe.
Continue stirring with ultrasound for 10 minutes in order to obtain an opalescent solution.
Control the temperature by means of a cold water bath for the whole duration of the stirring.
The suspended PEI particles are of a homogeneous size of the order of 170 nm with polydispersity index of 0.55.
The obtained aqueous suspension is stable for six months.
Thoroughly dissolve 0.0922 g of polyetherimide (n=20) (PEI) in 2 mL of N-methyl-2-pyrrolidone (NMP).
In a beaker containing 0.1005 g of sodium dodecylsulfate (SDOS) dissolved in 20 mL of distilled water, pour dropwise and with ultrasound the solution of PEI dissolved in NMP by means of a glass syringe.
Continue the stirring with ultrasound for 10 minutes in order to obtain an opalescent solution.
Control the temperature by means of a cold water bath during the whole duration of the stirring.
The suspended PEI particles are of a homogeneous size of the order of 130 nm with a polydispersity index of 0.45.
The obtained aqueous suspension is stable for 6 months.
The sizing obtained according to example 1 is sprayed on a non-sized rove of carbon fibers of the type AS4 12000 filaments (Hexcell, USA), which after evaporation leads to a homogeneous PEI film (
The same procedure was used for sizing carbon fibers with the aqueous dispersions obtained according to Examples 2 to 6.
Number | Date | Country | Kind |
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10 54437 | Jun 2010 | FR | national |