None.
Pulsed-neutron nuclear logging tools operate by releasing high energy neutrons, on the order of 14 Million electron Volts (MeV), into the borehole and formation. The neutrons create gamma particles or gamma rays (hereafter just gammas) by one of several of interactions with the surrounding atoms: 1) the neutrons inelastically collide with atomic nuclei and thereby create gammas (known as inelastic gammas); and 2) when a neutron loses energy (possibly through the inelastic collisions or by other means) the neutron is captured by the nucleus of a nearby atom and in the process a gamma is emitted (known as a capture gamma). The atoms with which the neutrons collide and/or the neutrons are captured can be determined by the energy (or frequency) of the gammas produced.
When using a pulsed-neutron nuclear logging tool as a bulk density measurement device, inelastic gammas carry most of the information as to the formation bulk density. When using a pulsed-neutron nuclear logging tool to determine formation lithology or the macroscopic capture cross-section, it is often the capture gammas that carry most of the information. However, elements of the various components that are in, or which form, the borehole (e.g., drilling fluid, casing, cement, production tubing, or the logging tool itself) also interact with neutrons, and thus it is difficult in the related art to distinguish gammas originating within the borehole from those originating within the formation.
For a detailed description of exemplary embodiments, reference will now be made to the accompanying drawings in which:
Certain terms are used throughout the following description and claims to refer to particular system components. As one skilled in the art will appreciate, different companies may refer to a component by different names. This document does not intend to distinguish between components that differ in name but not function.
In the following discussion and in the claims, the terms “including” and “comprising” are used in an open-ended fashion, and thus should be interpreted to mean “including, but not limited to . . . .” Also, the term “couple” or “couples” is intended to mean either an indirect or direct connection. Thus, if a first device couples to a second device, that connection may be through a direct connection, or through an indirect connection via other devices and connections.
“Gamma” or “gammas” shall mean energy created and/or released due to neutron interaction with atoms, and in particular atomic nuclei, and shall include such energy whether such energy is considered a particle (i.e., gamma particle) or a wave (i.e., gamma ray or wave).
“Enriched boron” shall mean boron where the boron 10 isotope present is greater than 21% by weight of the total boron present.
“Energetic neutrons” shall mean free neutrons having energy above thermal energy of about 0.025 electron Volts (eV), and energetic neutrons include epithermal neutrons (having energy of about 0.024 to 1 eV) and fast neutrons (having energy of about 1.0 Mega eV (MeV)).
“Substantially free” in relation to received gammas and a listed element shall mean that received gammas comprise not more than 1.5 times the number of gammas characteristic of the listed element that would be received at a logging tool using MP35N for the pressure vessel. This definition shall not require use of MP35N, as the results may be achieved with metallic components having greater percentages of the listed elements than MP35N, but with neutron absorptive coatings.
“Lithology” relates to mineralogy as inferred from elemental constituency.
The following discussion is directed to various embodiments of the invention. Although one or more of these embodiments may be preferred, the embodiments disclosed should not be interpreted, or otherwise used, as limiting the scope of the disclosure, including the claims. In addition, one skilled in the art will understand that the following description has broad application, and the discussion of any embodiment is meant only to be exemplary of that embodiment, and not intended to intimate that the scope of the disclosure, including the claims, is limited to that embodiment.
The various embodiments are directed to systems and related methods of nuclear logging tools for determining parameters of formations surrounding a borehole. In some cases, the embodiments perform neutron-induced gamma spectroscopy for performing geochemical evaluations of formations. However, the various embodiments are also useful in other neutron-induced logging, such as neutron decay and carbon-oxygen logging.
The nuclear logging tool 10 further comprises a gamma detector 34. While the gamma detector 34 is shown above the neutron source 38, in other embodiments the gamma detector 34 is below the neutron source 38. In some embodiments, the gamma detector is 14.5 inches from the neutron source 38, but other distances may be equivalently used. The gamma detector 34 detects arrival of, and energy of, gammas created by interactions of neutrons with atoms both in the formation 14, as well as atoms that make up the various components of the logging tool 10. In at least some embodiments, the gamma detector 34 comprises a metallic Dewar flask 40 sealed by a stopper 41, and within the Dewar flask 40 resides a crystal 42 (e.g., a 3 inch by 4 inch bismuth germinate scintillation crystal), a photomultiplier tube 44 in operational relationship to the crystal 42, a processor 46 coupled to the photomultiplier tube 44, and eutectic material 47. As gammas are incident upon/within the crystal 42, the gammas interact with the crystal 42 and flashes of light are emitted. Each flash of light itself is indicative of an arrival of a gamma, and the intensity of the light is indicative of the energy of the gamma. The output of the photomultiplier tube 44 is proportional to the intensity of the light associated with each gamma arrival, and the processor 46 quantifies the output as gamma energy and relays the information to the surface computer 22 by way of the telemetry module 30.
In operation, the logging tool 10 is placed within a borehole 12 proximate to a formation of interest. The neutron source 38 releases energetic neutrons. In order to reduce the irradiation of the gamma detector 34 by energetic neutrons from the neutron source 38, the neutron shield 36 separates the neutron source 38 from the gamma detector 34, and the neutron shield 36 may be constructed of a high density material (e.g., a tungsten-based material, such as HEVIMET® available from General Electric Company of Fairfield, Conn. The energetic neutrons are focused to some extent toward the side of the tool 10 that contacts with the borehole wall, but because of the speed of energetic neutrons (e.g., 14,000 kilometers/second or more), and because of collisions of the neutrons with atomic nuclei that change the direction of movement of the neutrons, the neutrons may produce a neutron flux around the logging tool 10 that extends into the formation 14.
The neutrons interact with atoms by way of inelastic collisions and/or thermal capture. In the case of inelastic collisions, a neutron inelastically collides with an atomic nuclei, and in the process a gamma is created (an inelastic gamma) and the energy of the neutron is reduced. The neutron may have many inelastic collisions with atomic nuclei, each time creating an inelastic gamma and losing energy. At least some of the gammas created by the inelastic collisions are incident upon the gamma detector 34. One or both of the time of arrival of a particular gamma, and its intensity, may be used to determine the type of atom with which the neutron collided, and thus parameters of the formation 14. For example, gammas associated with inelastic collisions may be used to determine formation properties such as bulk density and carbon-oxygen ratio.
After one or more inelastic collisions (and corresponding loss of energy), a neutron reaches an energy known as thermal energy (i.e., a thermal neutron). At thermal energy, a neutron can be captured by atomic nuclei. In a capture event, however, the capturing atomic nucleus enters an excited stated, and the nucleus later transitions to a lower energy state by release of energy in the form a gamma (known as a thermal gamma). At least some of the thermal gammas created by thermal capture are also incident upon the gamma detector 34. One or both of the time of arrival of a particular gamma, and its intensity, may be used to determine the type of atom into which the neutron was captured, and thus parameters of the formation 14. In particular, the energy of capture gammas (as inferred from the intensity of the light in the detector) may be used to determine the formation lithology.
However, production of inelastic gammas and capture gammas is not limited to atoms residing within the formation. Atoms of the borehole fluid, and atoms that makeup the elements of the tool 10 also produce inelastic gammas and capture gammas, and which gammas may be incident upon the gamma detector 34. Still referring to
In the related art, the large metallic components of a nuclear logging tool, such as the pressure vessel, are selected to provide the strength and/or corrosion resistance deemed necessary by the tool designer. For example, the pressure vessel is selected to be of sufficient strength to withstand the pressures, temperatures and fluids encountered downhole, which may be on the order of several thousand pounds per square inch (PSI), 200° C. or more, and comprise corrosive environments. However, the selection of metallic materials for use in the nuclear logging tools of the related art is without regard to the components of the metallic materials in relation to the formations to be tested. While many elements may be of interest to a geologist in evaluating formation lithology, many such elements may likewise be present in the related art metallic materials. For example, a geologist may be interested in the amount of iron, manganese, aluminum and titanium (among others) present in the formation. The material of choice for the pressure vessel and other components (e.g., source deployment, insulating flask 40, eutectic 47) in the related art is typically a stainless steel, such as 17-4 stainless steel, which comprises approximately 73% iron, 17% chromium and 4% nickel, all by weight. Thus, in this illustrative case, a significant amount of iron is present in the tool, and iron within the formation is also of interest. Because of the amount of iron in the tool, the tool signals of related art nuclear logging tend to mask the components of the formation.
In order to reduce the undesirable tool signals that cover or mask determinations of formation lithology, a nuclear logging tool 10 in accordance with at least some embodiments implements one or both of enhanced shielding to reduce the number of thermal neutrons entering the tool, and use of particular materials for at least some of the large metallic components of the tool. Material selection is discussed first, followed by the enhanced shielding.
In accordance with at least some embodiments, material selection for the large metallic components (e.g., pressure vessel, insulating flasks, eutectics) is based on reducing constituent components of the selected materials that are also of interest in the formations. In particular, in accordance with the various embodiments at least some metallic materials are selected and/or used in the logging tool where the amount of iron, manganese, aluminum and titanium is reduced or eliminated. Consider, as an example, an alloy known as MP35N® available from SPS Technologies, Inc. of Jenkintown, Pa. The MP35N alloy comprises approximately 20% by weight chromium, approximately 35% by weight nickel, approximately 10% by weight molybdenum, and approximately 35% by weight cobalt. The illustrative MP35N alloy typically contains less than 1% iron, less than 0.15% manganese, less than 1% titanium, and no aluminum, and thus is substantially free of the elements important to geochemical evaluations of formations. Moreover, the illustrative MP35N has sufficient strength to be used as pressure housings in expected downhole conditions.
In order to confirm the benefits of selecting metallic materials for the logging tool 10 as discussed above, Monte Carlo simulations were run for several different types of formation, different porosity values for each formation type, and different tool materials. In particular, the simulations modeled an eight inch fresh-water filled borehole, with surrounding formations of quartz sandstone, calcite, dolomite and mixed quartz sandstone-pyrite mineralogy. With the exception of mixed quartz sandstone-pyrite mineralogy, the simulated formations contained no iron, manganese, titanium or aluminum. Thus, received gammas from these elements in the simulations were directly a consequence of interactions with elements of the tool. The sandstone and calcite formations were simulated at 0 and 20 porosity units (p.u.), and the dolomite formation was modeled at 0 and 25 p.u. The simulations were carried out for the illustrative MP35N, as well as: INCONEL® 718 (iron content of approximately 17%); INCONEL® 925 (iron content of approximately 25%); and 17-4 stainless steel (iron content of approximately 73%).
Taking
Before proceeding, it is noted that all components that make up a nuclear logging tool produce gammas in inelastic collisions with energetic neutrons, and likewise produce gammas based on thermal neutron capture. The selection and use of any particular material for the tool 10 components does not stop such gamma creation; however, with carefully chosen tool 10 components, the gammas created by interaction of neutrons with the tool 10 components may be easily algorithmically separated from the overall gamma returns because the characteristics of the gammas (e.g., energy) identify the elements with which the neutrons interacted. When carefully chosen, such elements are either unimportant to geochemical evaluations of formations, or are present in the logging tool 10 in small enough quantities that the formation signal is not unduly masked.
The selection and use of particular metallic materials as described to this point may be implemented alone to achieve better nuclear logging tool performance compared to related art nuclear logging tools. In addition to, or in place of, such material selection, the various embodiments also utilize an enhanced shielding system and method. As mentioned with respect to
Unlike related-art nuclear logging tools which use a boron impregnated rubber sleeve telescoped over the pressure vessel as a thermal neutron shield, in accordance with at least some embodiments the neutron absorptive coating 26 is a boron-based component adhered to at least a portion of the outer surface of the pressure vessel 16. In particular, the boron-based component is thermally fused to the pressure vessel 16, such as by spray coating with the boron-based component in plasma form. In at least some embodiments the neutron absorptive coating 26 is boron carbide (with a nickel binder) adhered to at least a portion of outer surface of the pressure vessel 16. Alternatively, the neutron absorptive coating may consist of elemental boron in combination with a suitable binder, such as nickel.
Boron has two stable isotopes, boron 10 (having 5 neutrons in the nucleus) and boron 11 (having 6 neutrons in the nucleus). Naturally occurring boron is between approximately 19.1% and 20.3% boron 10, with the remaining being boron 11. Boron 10, however, is the isotope that is good at capturing thermal neutrons. Thus, in accordance with at least some embodiments, the neutron absorptive coating 26 uses enriched boron (that is, having a greater percentage of boron 10 than naturally occurring boron). More particularly, in accordance with at least some embodiments, the neutron absorptive coating 26 has 0.1 grams of boron-10 per square centimeter (g/cm2) or more of boron 10. In at least some embodiments, the neutron absorptive coating 26 comprises between 0.3 to 0.38 g/cm2 of enriched boron carbide.
Using enriched boron carbide for the neutron absorptive coating 26 not only provides enhanced thermal neutron shielding, but also decreases the shielding thickness (T in
In order to confirm the benefits of using enhanced boron for the logging tool 10 neutron absorptive coating 26, Monte Carlo simulations were run for several different boron 10 enriched boron carbide concentrations of the neutron absorptive coating 26, and different formation porosities. In particular, the simulations modeled an eight inch fresh-water filled borehole, with surrounding formations of sandstone simulated at 0 and 20 p.u.
Regardless of the precise nature of the logging tool placed, the next step is releasing energetic neutrons from the logging tool (block 1008). Responsive to the releasing, the method proceeds to receiving (at a detector within the logging tool) gamma returns indicative of interactions of the neutrons with elements of the logging tool and elements of the formation, and the gammas indicative of neutron interactions with elements of the logging tool are substantially free from gammas indicative of interactions with iron atoms (block 1012). Thereafter, the method ends (block 1016). The receiving may further be substantially free of gammas indicative of neutron interaction with elements of the logging tool such as manganese, aluminum and titanium atoms.
The above discussion is meant to be illustrative of the principles and various embodiments of the present invention. Numerous variations and modifications will become apparent to those skilled in the art once the above disclosure is fully appreciated. It is intended that the following claims be interpreted to embrace all such variations and modifications.
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Number | Date | Country | |
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20100019138 A1 | Jan 2010 | US |