The described examples relate generally to systems, devices, and techniques for nuclear energy integrated oil and gas operations.
Oil and gas operations may include the production of certain hydrocarbons from subsurface reservoirs using wells that are drilled into the reservoir. In some cases, hydrocarbons may be produced from the subsurface reservoir using one or more enhanced recovery operations, including hydraulic fracturing. Broadly, hydraulic fracturing uses a pressurized fluid (often including a fracturing slurry composed of water, a proppant, and a chemical additive) that is injected into the subsurface reservoir—“production zone”—to increase a permeability of the reservoir, and thereby support the flow of hydrocarbons therein to the surface. Hydrocarbon well drilling, completion, production, fracturing, and/or other associated operations (collectively, “hydrocarbon operations”) often requires a substantial input of electrical power, e.g., to support the operation of pumps, compressors, drilling equipment, mixers, accumulators, and other equipment. Diesel generators can provide such power needs, but can be costly and unreliable. Hydrocarbon production operations may further generate substantial quantities of off-gas or casing gas (e.g., methane—CH4) and/or produced water (e.g., a recirculated fluid from the well casing and/or other fluid that is cut from produced hydrocarbon) that may represent potential waste streams. Conventional techniques for dealing with off-gas and produced water include flaring and waste-water well injection, respectively, among other techniques. However, flaring and waste-water injection techniques both fail to repurpose the waste stream for further commercial or industrial use, and regardless, such repurposing generally requires a substantial energy input. Conventional nuclear energy systems are known for affordable, clean, and reliable energy; however, such conventional systems may be impractical or infeasible for use in support of hydrocarbon operations. Accordingly, there is a need for systems and techniques to support the power consumption and waste stream processing needs of hydrocarbon operations, such as by leveraging nuclear energy systems.
In one example, a system is disclosed. The system includes a well site having a subsurface hydrocarbon well configured to produce a produced water output. The system further includes a deployable nuclear reactor system configured to produce a heat output. The system further includes a deployable desalination unit configured to produce a desalinated water output using the produced water output of the subsurface hydrocarbon well and the heat output of the deployable nuclear reactor and/or an electrical output derived therefrom.
In another example, the well site includes a hydraulic fracturing system configured to introduce pressurized fluids into the subsurface hydrocarbon well. The produced water output may at least partially include a recirculated form of the pressurized fluids.
In another example, the pressurized fluid may include a fracturing fluid slurry including one or more of a water, a proppant, and a chemical additive.
In another example, the system further includes a desalinated water offtake network having a network of temporary piping configured to deliver the desalinated water output to one or more municipalities adjacent the well site.
In another example, the system further includes a produced water pond configured to receive the produced water output and hold the produced water output for processing. The deployable desalination unit may be configured to receive the produced water output form the produced water pond.
In another example, the subsurface hydrocarbon well may be configured to produce an off-gas output. In this regard, the system may further include a deployable off-gas processing system configured to produce an industrial chemical using the off-gas output of the subsurface hydrocarbon well and the heat output of the deployable nuclear reactor and/or an electrical output derived therefrom.
In another example, the deployable off-gas processing system may include a deployable hydrogen production unit configured to produce a hydrogen output using the off-gas output of the subsurface hydrocarbon well and the heat output of the deployable nuclear reactor and/or an electrical output derived therefrom.
In another example, the deployable off-gas processing system may include a deployable chemical production unit configured to produce the industrial chemical using the hydrogen output of the hydrogen production module and the heat output of the deployable nuclear reactor and/or an electrical output derived therefrom.
In another example, the industrial chemical may include ammonia.
In another example, the deployable hydrogen production unit may include a steam methane refining processing unit. Further, the deployable chemical production unit may include a Haber-Bosch processing unit and/or a Fischer-Tropsch processing unit.
In another example, the system may further include a deployable electrical generation unit configured to produce an electrical power output using the heat output from the deployable nuclear reactor. In this regard, the well site may include one or more hydraulic fracturing systems, drilling systems, completion systems, or productions systems that are powered by the electrical power output of the deployable electrical generation unit.
In another example, a micro-grid is disclosed. The micro-grid includes a plurality of well sites clustered in a first geographic location. Each well site of the plurality of well sites may include a subsurface hydrocarbon well configured to produce a produced water output and an off-gas output. The micro-grid further includes a deployable plant deployed proximal the first geographic location. The deployable plant may further include a deployable nuclear reactor system configured to produce a heat output. The micro-grid may further include a network of pipes configured to deliver the produced water output and the off-gas output from each well site of the plurality of well sites to the deployable plant. The deployable plant may be configured to produce a desalinated water output and an industrial chemical output using the produce water output and the off-gas output, respectively, and the heat output from the nuclear reactor system and/or an electrical output derived therefrom.
In another example, the deployable plant may further include a deployable electrical generation unit configured to produce an electrical power output using the heat output from the deployable nuclear reactor. Further, the micro-grid may include a network of power lines configured to deliver the electrical power output to each well site of the plurality of well sites. The electrical power may be adapted to power at said well site one or more hydraulic fracturing systems, drilling systems, completion systems, or productions systems.
In another example, the plant may further include a deployable desalination unit. The plant may further include a deployable hydrogen production unit configured to perform steam methane refining. The plant may further include a deployable chemical production unit configured to perform a Haber-Bosch process and/or a Fischer-Tropsch process.
In another example, the micro-grid may include a second plurality of well sites clustered in a second geographic location. Each well site of the second plurality of well sites may include a subsurface hydrocarbon well configured to produce a produced water output and an off-gas output. The deployable plant may be redeployable proximal the second geographic location. The deployable plant may further be configured to produce a desalinated water output and an industrial chemical output using the produce water output and the off-gas output, respectively, of the second plurality of well sites and the heat output from the nuclear reactor system and/or an electrical output derived therefrom.
In another example, a method of treating an output of a well site using nuclear reactors is disclosed. The method includes operating a well site. The well site has a subsurface hydrocarbon well. The method further includes producing a produced water output from the hydrocarbon well. The method further includes operating a deployable plant deployed proximal to the well site. The deployable plant has a deployable nuclear reactor system and a deployable desalination unit. The method further includes producing a heat output from the deployable nuclear reactor system. The method further includes producing a desalinated water output from the desalination unit using the produced water output of the subsurface hydrocarbon well and the heat output of the nuclear reactor system and/or an electrical output derived therefrom.
In another example, the deployable plant may include a deployable electrical generation unit. Accordingly, the method may further include producing an electrical power output from the deployable electrical generation unit using the heat output from the deployable nuclear reactor system. The well site may include one or more hydraulic fracturing systems, drilling systems, completion systems, or productions systems. In this regard, the method may further include powering one or more of the hydraulic fracturing systems, drilling systems, completion systems, or productions systems using the electrical power output from the deployable electrical generation unit.
In another example, the method may further include producing an off-gas output from the subsurface hydrocarbon well. The deployable plant may further include a deployable hydrogen production unit and a deployable chemical production unit. Accordingly, the method may further include producing, by the deployable hydrogen production unit, a hydrogen output by performing a steam methane refining process using the off-gas output from the subsurface hydrocarbon well and the heat output from the deployable nuclear reactor and/or an electrical output derived therefrom. Further, the method may include producing, by the deployable chemical production unit, a chemical output by performing a Haber-Bosch processing using the hydrogen output from the deployable hydrogen production unit and the heat output from the deployable nuclear reactor and/or an electrical output derived therefrom.
In another example, operating the well site may further include performing one or more hydraulic fracturing operations that includes introducing pressurized fluids into the subsurface hydrocarbon well.
In another example, the produced water output may at least partially include a recirculated from of the pressurized fluids. The pressurized fluid may include a fracturing fluid slurry including one or more of a water, a proppant, and a chemical additive.
In another example, a system is disclosed. The system includes well site having a subsurface hydrocarbon well configured to produce an off-gas output. The system further includes a deployable nuclear reactor system configured to produce a heat output. The system further includes a deployable off-gas processing system configured to produce an industrial chemical using the off-gas output of the subsurface hydrocarbon well and the heat output of the deployable nuclear reactor and/or an electrical output derived therefrom.
In another example, the deployable off-gas processing system may further include a deployable hydrogen production unit configured to produce a hydrogen output using the off-gas output of the subsurface hydrocarbon well and the heat output of the deployable nuclear reactor and/or an electrical output derived therefrom.
In another example, the deployable off-gas processing system may further include a deployable chemical production unit configured to produce the industrial chemical using the hydrogen output of the hydrogen production module and the heat output of the deployable nuclear reactor and/or an electrical output derived therefrom.
In another example, the industrial chemical includes ammonia.
In addition to the example aspects described above, further aspects and examples will become apparent by reference to the drawings and by study of the following description.
The use of cross-hatching or shading in the accompanying figures is generally provided to clarify the boundaries between adjacent elements and also to facilitate legibility of the figures. Accordingly, neither the presence nor the absence of cross-hatching or shading conveys or indicates any preference or requirement for particular materials, material properties, element proportions, element dimensions, commonalities of similarly illustrated elements, or any other characteristic, attribute, or property for any element illustrated in the accompanying figures.
Additionally, it should be understood that the proportions and dimensions (either relative or absolute) of the various features and elements (and collections and groupings thereof) and the boundaries, separations, and positional relationships presented therebetween, are provided in the accompanying figures merely to facilitate an understanding of the various embodiments described herein and, accordingly, may not necessarily be presented or illustrated to scale, and are not intended to indicate any preference or requirement for an illustrated embodiment to the exclusion of embodiments described with reference thereto.
The description that follows includes sample systems, methods, and apparatuses that embody various elements of the present disclosure. However, it should be understood that the described disclosure may be practiced in a variety of forms in addition to those described herein.
The following disclosure relates generally to nuclear reactor integrated oil and gas production systems and methods of operation. Oil and gas production systems, or “hydrocarbon operations” may generally include any operations associated with extracting hydrocarbons (e.g., oil and gas) from a subsurface reservoir, including, without limitation, well site preparation, well drilling, completion, production, enhanced recovering operations including hydraulic fracturing and/or other associated operations. Broadly, hydrocarbon operations often require a substantial input of electrical power, including for the operation of pumps, compressors, drilling equipment, mixers, accumulators, controls and actuators, and any other associated equipment. Diesel generators can provide such power needs, but can be costly and unreliable. Hydrocarbon operations may further generate substantial quantities of off-gas or casing gas (e.g., methane—CH4) and/or produced water (e.g., a recirculated fluid from the well casing and/or other fluid that is cut from produced hydrocarbon) that may represent potential waste streams. Conventional techniques for dealing with off-gas and produced water include flaring and waste-water well injection, respectively, among other techniques. However, flaring and waste-water injection techniques both fail to repurpose the waste stream for further commercial or industrial use, and regardless, such repurposing generally requires a substantial energy input.
To mitigate these and other challenges associated with hydrocarbon operations, the systems and methods of the present disclosure integrate a nuclear reactor system into such hydrocarbon operations. For example, a nuclear reactor system may include an integral-type reactor, which is generally a deployable, modular unit that is capable of generating thermal energy from fission reactions. Such integral-type reactor may be a fully contained or standalone unit that is transportable to a first remote site (such as a hydrocarbon well site) at which the reactor may operate for a period of time, and may be subsequently redeployed to a second remote site for operation, upon conclusion of the operations at the first remote site. Integral-type or “deployable reactors” of the present disclosure may include substantially any type of nuclear reactor, including, without limitation, certain molten salt reactors, super critical water reactors, liquid sodium cooled reactors, helium or other gas cooled reactors, liquid metal cooled reactors, certain pressurized water reactors, among others.
The deployable reactors of the present disclosure may be used to provide for the thermal and electrical needs of the various hydrocarbon operations described herein. Further, the deployable reactors may be used to treat and/or repurpose one or more waste streams of the hydrocarbon operations, including treating and/or repurposing off-gas and/or produced water. For example, the deployable nuclear reactor may be used to produce ammonia (NH3) or other chemical product from the off-gas using one or more heat or electrical outputs derived from the fission reactions of the reactor. Further, the deployable nuclear reactor may be used to produce desalinated water from the produced water also using one or more heat or electrical outputs derived from the fission reactions of the reactor. In other cases, the waste streams of the hydrocarbon operations may be repurposed into different products.
To facilitate the foregoing, in one example, disclosed herein is a deployable plant including the deployable nuclear reactor. The deployable plant may be deployable to a hydrocarbon well or more generally to any region proximal a cluster of well sites. For example, the entire deployable plant may be capable of remote deployment and redeployment to any number of locations. In this regard, the deployable plant may include a plurality of trucks, tractor-trailers, and/or other moveable skids or components that are readily transportable between locations. One such tractor-trailer or moveable skid may include the deployable nuclear reactor. Other tractor-trailer or moveable skids may include one or more of a deployable desalination unit, a deployable electrical generation unit, a deployable hydrogen production unit, a deployable chemical production unit, and/or other deployable equipment, including certain equipment to facilitate the offtake of desalinated water, electricity, and/or chemical produced using the various deployable units.
In operation, such deployable plant may be configured to receive one or both of a produced water input or a casing gas input from certain hydrocarbon operations. In one example, the deployable plant may use the deployable desalination unit to produce desalinated water using the produced water input of the hydrocarbon operations and a heat output from the deployable nuclear reactor of the deployable plant. In another example, the deployable plant may use the deployable hydrogen production unit to produce hydrogen using the casing gas input of the hydrocarbon operations and a heat output from the deployable nuclear reactor. In another example, the deployable plant may use the deployable chemical production unit to produce a chemical output (e.g., ammonia, NH3) from the produced hydrogen of the deployable hydrogen production unit and a heat output from the deployable nuclear reactor (e.g., via a Haber-Bosch process, a Fischer-Tropsch process and/or other process). In another example, the deployable plant may use the deployable electrical generation unit to produce an electricity output from a heat output of the deployable nuclear reactor. Such electricity output may, in turn, be used to power one or more hydrocarbon operations, among other uses.
While many types of integral, or deployable-type nuclear reactors are possible and contemplated herein, in one example, the deployable nuclear reactor system includes an integral molten salt reactor (“MSR”). Broadly, an integral MSR may reduce or eliminate leaks and/or other failure mechanisms by fully enclosing the functional components (e.g., the heat exchanger, the reactor core, the pump (if used), and so on) within a common, integrally constructed vessel. For example, an integral MSRs may house a reactor core and one or more heat exchangers in a “critical region” of a common vessel, and cause a fuel salt to circulate within the common vessel between the reactor core (at which the fuel salt may undergo a fission reaction that heats the salt) and a heat exchanger (at which the heat is removed from the fuel salt). The heat that is removed from the salt may be used for or may form the various “heat outputs” of the deployable nuclear reactor described above that are provided to the deployable desalination unit, the deployable electrical generation unit, the deployable hydrogen production unit, and/or the deployable chemical production unit. In some cases, as described herein, the integral MSR may further include a subcritical region at which the fuel salt may be kept away from the reactor core and heat exchanger in a subcritical state, as may be needed to facilitate shutdown of the integral MSR. In other configurations, other components and features of the integral MSR are contemplated herein.
Turning to the Drawings,
In operation, the rig 104 may use the drive 108 to push a drill head (not shown) through hydrocarbon well 114 in order to clear a well bore in a subsurface hydrocarbon reservoir below. The rig 104 and/or other associated rigs (e.g., a completions rig) may subsequently engage in one or more completion operations in order to prepare the well bore for hydrocarbon production. For example, a cement liner may be poured to establish an impermeable annulus about the well bore for some or all of a depth of the well. Additionally, metal casing and other equipment may be put into the well bore, which may further serve to establish flow paths for hydrocarbons produced by the well, in addition to establishing certain flow paths for off-gas, and/or other produced fluids of the well 114. As described in greater detail herein in reference to
With continued reference to
Turning to
As generally shown in
The integrally constructed vessel 204 is shown in
Fuel salt may be selectively held within the critical volume 210 and/or the subcritical volume 214 based on the maintenance of an inert gas pressure within each volume. For example, the critical volume 210 may be held at a pressure Pr (reactor section pressure) or Pht (heat exchange section pressure) and the subcritical volume 214 may be held at a pressure Pdt (drain tank section pressure). In the example of
Further, the drain tank section 220 is shown configured to hold the fuel salt in the subcritical volume 214, which may generally be defined collectively by the internal barrier 222, drain tank walls 226, and floors 228. With reference the internal barrier 222, the internal barrier 222 may be a structural component that establishes a physical barrier and physical separation between fuel salt held in the critical volume 210 and fuel salt held in the subcritical volume 214. In this regard, the internal barrier 222 may have a sufficient strength and rigidity in order to support a weight of the fuel salt within the critical region 208 without undue deformation or encroachment of the internal barrier 222 into or toward the subcritical volume 214.
The internal barrier 222 may be adapted to permit the passage of fuel salt between the critical volume 210 and the subcritical volume 214 only via the fuel salt passage 224 defined through the internal barrier 222. In order to permit the transfer of fuel salt between the critical volume 210 and the subcritical volume 214, the drain tank section 220 may further include a transfer pipe 230. The transfer pipe 230 may extend from the fuel salt passage 222 toward floors 228 of the drain tank section 220. As shown in
With further reference to the reactor section 240, the reactor section 240 may be configured to receive a volume of fuel salt from the drain tank section 220 and cause fission reactions that heat the fuel salt. For example, the reactor section 240 may generally include a reactor core 242 formed at least partially from a moderator material, such as a graphite material. The reactor core 242 may cause or otherwise facilitate the undergoing fission reactions in the critical region 208. Accordingly, the reactor core 242 may be constructed in a manner to receive the fuel salt and to cause the fuel salt to be heated therein. In this regard, the reactor core 242 is shown as having one or more fuel salt passages that extends generally from a core bottom side to a core top side. As described herein, the fuel salt may be encouraged to travel through the fuel salt passage, and in so doing, the fuel salt may be heated by fission reactions. In turn, the peripheral sides of the reactor core 242 may be arranged in order to define an annulus between the reactor core 242 and the vessel 204, through which the fuel salt may travel upon removal of heat from the fuel salt at the heat exchange section 260, and for subsequent recirculation into the core 242.
With further reference to the heat exchange section 260, the heat exchange section 260 may be configured to receive a flow of the heated fuel salt from the reactor section 240 and remove heat therefrom. For example, the heat exchange section 260 is shown as having a heat exchanger 262. The heat exchanger 262 may generally take of any of variety of forms in order to transfer heat from fuel salt of the critical volume 210 to a coolant salt or other medium that is held by the heat exchanger 262. Fuel salt (such as that which has been heated from one or more fission reactions) may be routed to the heat exchanger 262 and exposed to a cooler medium therein to remove heat from the fuel salt. In this regard, the coolant pipe run therein (including a cold leg 268a and a hot leg 268b shown in
The integral MSR 200 may further include a variety of other components to support the operation of the reactor. With continued reference to
As further shown in
With reference to
In the example of the
With reference to
In connection with the foregoing operations, the well 400 is shown functionally associated with an injection module 420, an off-gas module 424, and a produced water module 428. The injection module 420 may include one or more processes and associated equipment that are configured to deliver a flow of fluid to the well 400 for a variety of purposes. In one example, the injection module 420 may include a hydraulic fracturing operation (such as that described above with reference to
The deployable nuclear reactors described herein may be integrated with various hydrocarbon operations in a manner to treat waste streams from a well site, and to repurpose the waste stream into a higher use. For example, the deployable nuclear reactors may be integrated with the well 404 to treat and repurpose any produced water or other produced fluids from the produced water module 428. Further, the deployable nuclear reactors may be integrated with the well 404 to treat and repurpose and off-gasses from the off-gas module 424. However, the well 404 may be arranged in a generally remote location, such as being dozens or even hundred of miles from municipal services, which may hinder the ability to treat such waste streams.
To mitigate such concerns and to facilitate the treatment of the produced water, off-gas and/or other waste stream,
The deployable plant 500 includes a deployable nuclear reactor system 504. The deployable nuclear reactor system 504 may be or include any of the nuclear reactor systems described herein, such as the integral MSR described in relation to
With further reference to
With continued reference to
In order to facilitate the foregoing operation, the deployable desalination unit 508 may use the heat output 506a from the deployable nuclear reactor system 504. For example, the deployable desalination unit 508 may require receiving the heat output 506a in the range of around 30 to 40 MWth, although other levels of thermal energy may be utilized Additionally or alternatively, the deployable desalination unit 508 may use the electrical output 522c from the deployable electric generation unit 520 in support of the production of the desalinated water output 510.
With continued reference to
As further depicted in
The deployable plant 500 may further include a chemical offtake 540. The chemical offtake 540 may include any appropriate components and systems to prepare the chemical product 538 for delivery to and offtake to an end customer. For example, the chemical offtake 540 may include certain tanks, vessels, piping, pumps, and so on that facilitate the transfer of the chemical product 538 off of the deployable plant 500 via the chemical flow 542. For the purposes of illustration, the chemical product 538 may be removed from the deployable plant 500 via a series of trucks that receive the chemical product 538 from holding tanks of the chemical offtake 540. In this regard, the chemical flow 542 may represent the output of the chemical product via said trucks. Whereas, in other cases, the chemical flow 542 may be indicative of other outputs of the chemical product 538, including via a direct piping connecting to another processing or holding facility external to the deployable plant 500.
The deployable plant 500 of
For example, and with reference to
The deployable plants of the present disclosure may be movable, as needed, to subsequent clusters of wells. For example, and as shown in
In some cases, the deployable plants of the present disclosure may be adapted to provide outputs to neighboring municipalities. For example, the deployable plants may be configured to desalinate, filter, purify and/or otherwise treat produced water from one or more hydrocarbon wells to a standard that permits the treated produced water to enter a municipal drinking water system. For example, and as shown in
With reference to
With reference to
With reference to
At operation 1312, a deployable plant is operated proximal to the well site. For example, and with reference to
Other examples and implementations are within the scope and spirit of the disclosure and appended claims. For example, features implementing functions may also be physically located at various positions, including being distributed such that portions of functions are implemented at different physical locations. The foregoing description, for purposes of explanation, uses specific nomenclature to provide a thorough understanding of the described examples. However, it will be apparent to one skilled in the art that the specific details are not required in order to practice the described examples. Thus, the foregoing descriptions of the specific examples described herein are presented for purposes of illustration and description. They are not targeted to be exhaustive or to limit the examples to the precise forms disclosed. It will be apparent to one of ordinary skill in the art that many modifications and variations are possible in view of the above teachings.
This application is a continuation application of U.S. patent application Ser. No. 18/464,968, filed Sep. 11, 2023, which is incorporated herein in its entirety.
Number | Name | Date | Kind |
---|---|---|---|
2669465 | Newell | Feb 1954 | A |
3471181 | Fuentes | Oct 1969 | A |
3972547 | Itoya | Aug 1976 | A |
4539846 | Grossman | Sep 1985 | A |
5016920 | Anderson | May 1991 | A |
5630592 | Obara et al. | May 1997 | A |
6125912 | Branagan et al. | Oct 2000 | A |
6186159 | DeGood | Feb 2001 | B1 |
7160367 | Babicki | Jan 2007 | B2 |
7400697 | Carmack et al. | Jul 2008 | B1 |
7648792 | Kaschmitter | Jan 2010 | B2 |
7707987 | Guthrie | May 2010 | B2 |
7931080 | O'Brien | Apr 2011 | B2 |
7980304 | O'Brien | Jul 2011 | B2 |
8186430 | O'Brien | May 2012 | B2 |
8238509 | Moen et al. | Aug 2012 | B2 |
8636892 | Koehl et al. | Jan 2014 | B2 |
8703063 | Hottovy | Apr 2014 | B2 |
8746440 | Williamson et al. | Jun 2014 | B2 |
8767905 | Neeley et al. | Jul 2014 | B2 |
8771482 | Bailey et al. | Jul 2014 | B2 |
8900439 | Wiedmeyer et al. | Dec 2014 | B2 |
8956524 | Wiedmeyer et al. | Feb 2015 | B2 |
9008257 | Hyde et al. | Apr 2015 | B2 |
9017527 | Wiedmeyer et al. | Apr 2015 | B2 |
9074922 | Dayal et al. | Jul 2015 | B2 |
9150975 | Berger et al. | Oct 2015 | B2 |
9208909 | Runkle et al. | Dec 2015 | B2 |
9224507 | Heinold et al. | Dec 2015 | B2 |
9251920 | Loewen et al. | Feb 2016 | B2 |
9305673 | Heinold et al. | Apr 2016 | B2 |
9324465 | Splichal, Jr. | Apr 2016 | B2 |
9368238 | Theofanous et al. | Jun 2016 | B2 |
9368241 | Loewen et al. | Jun 2016 | B2 |
9376639 | Walter et al. | Jun 2016 | B2 |
9460818 | Bergman | Oct 2016 | B2 |
9475706 | Policke et al. | Oct 2016 | B2 |
9522462 | Baker et al. | Dec 2016 | B2 |
9691507 | Hyde et al. | Jun 2017 | B2 |
9691508 | Hyde et al. | Jun 2017 | B2 |
9728288 | Hyde et al. | Aug 2017 | B2 |
9748007 | Hyde et al. | Aug 2017 | B2 |
9761336 | Caine et al. | Sep 2017 | B2 |
9761337 | Hyde et al. | Sep 2017 | B2 |
9799417 | Hyde et al. | Oct 2017 | B2 |
9875817 | Edwards et al. | Jan 2018 | B2 |
9875818 | Reed et al. | Jan 2018 | B2 |
9881700 | LeBlanc | Jan 2018 | B2 |
9892807 | Hyde et al. | Feb 2018 | B2 |
9894802 | Loewen et al. | Feb 2018 | B2 |
9911514 | Edwards et al. | Mar 2018 | B2 |
9921158 | Rider | Mar 2018 | B2 |
9941025 | Ahlfeld et al. | Apr 2018 | B2 |
10041163 | Offer et al. | Aug 2018 | B1 |
10056160 | LeBlanc | Aug 2018 | B2 |
10141079 | Czerwinski et al. | Nov 2018 | B2 |
10144874 | Walter | Dec 2018 | B2 |
10147506 | Malloy, III et al. | Dec 2018 | B2 |
10176901 | Loewen | Jan 2019 | B2 |
10197200 | Kolb et al. | Feb 2019 | B2 |
10221499 | Miller et al. | Mar 2019 | B2 |
10229757 | Filippone | Mar 2019 | B2 |
10280527 | Loewen et al. | May 2019 | B2 |
10290381 | Caine et al. | May 2019 | B2 |
10311981 | Hackett et al. | Jun 2019 | B2 |
10343102 | Reasoner | Jul 2019 | B2 |
10438705 | Cheatham, III | Oct 2019 | B2 |
10497479 | Abbott | Dec 2019 | B2 |
10497480 | Cheatham, III et al. | Dec 2019 | B2 |
10515729 | Horn et al. | Dec 2019 | B2 |
10535437 | Hyde et al. | Jan 2020 | B2 |
10566096 | Czerwinski | Feb 2020 | B2 |
10573416 | Venneri | Feb 2020 | B2 |
10636532 | Anderson et al. | Apr 2020 | B2 |
10643754 | Venneri | May 2020 | B2 |
10650934 | Caine et al. | May 2020 | B2 |
10665356 | Abbott | May 2020 | B2 |
10685750 | Eichel et al. | Jun 2020 | B2 |
10734122 | Cisneros, Jr. | Aug 2020 | B2 |
10738367 | Hackett | Aug 2020 | B2 |
10741293 | Abbott | Aug 2020 | B2 |
10755822 | Gibbons et al. | Aug 2020 | B2 |
10760004 | Garcia-Perez et al. | Sep 2020 | B2 |
10787609 | Garcia-Perez et al. | Sep 2020 | B2 |
10787610 | Goodrich et al. | Sep 2020 | B2 |
10825571 | Edwards et al. | Nov 2020 | B2 |
10867710 | Cisneros, Jr. | Dec 2020 | B2 |
10923238 | Abbott | Feb 2021 | B2 |
10937557 | Sineath et al. | Mar 2021 | B2 |
10962461 | Linneen | Mar 2021 | B2 |
11028303 | Corbin et al. | Jun 2021 | B2 |
11031140 | Hunt et al. | Jun 2021 | B2 |
11043309 | Nygaard et al. | Jun 2021 | B2 |
11049624 | Loewen et al. | Jun 2021 | B2 |
11075013 | Abbott et al. | Jul 2021 | B2 |
11075015 | Cisneros, Jr. | Jul 2021 | B2 |
11133114 | Hackett et al. | Sep 2021 | B2 |
11136245 | Benson | Oct 2021 | B2 |
11145424 | Abbott | Oct 2021 | B2 |
11149623 | Kutsch | Oct 2021 | B2 |
11170901 | Cheatham, III | Nov 2021 | B2 |
11200991 | LeBlanc | Dec 2021 | B2 |
11205523 | Hyde et al. | Dec 2021 | B2 |
11257600 | Anderson et al. | Feb 2022 | B2 |
11264141 | Venneri | Mar 2022 | B2 |
11276503 | Cisneros, Jr. et al. | Mar 2022 | B2 |
11289212 | Inman et al. | Mar 2022 | B2 |
11342084 | Cheatham, III et al. | May 2022 | B2 |
11342085 | Hinds | May 2022 | B2 |
11367536 | Abbott | Jun 2022 | B2 |
11373765 | Czerwinski | Jun 2022 | B2 |
11373769 | Hinds | Jun 2022 | B2 |
11380450 | Sineath et al. | Jul 2022 | B2 |
11417435 | Nelson | Aug 2022 | B2 |
11417437 | Venneri | Aug 2022 | B2 |
11424041 | Fisher et al. | Aug 2022 | B2 |
11428564 | Dayal et al. | Aug 2022 | B2 |
11434429 | Goodrich et al. | Sep 2022 | B2 |
11437156 | Russell, II et al. | Sep 2022 | B2 |
11443859 | Bass et al. | Sep 2022 | B2 |
11482345 | Hunt et al. | Oct 2022 | B2 |
11488731 | Abbott | Nov 2022 | B2 |
11495363 | Gramlichii et al. | Nov 2022 | B2 |
11501883 | Eichel et al. | Nov 2022 | B2 |
11542437 | Garcia-Perez et al. | Jan 2023 | B2 |
11545274 | Bass et al. | Jan 2023 | B2 |
11569000 | Hinds | Jan 2023 | B2 |
11574094 | Pivovar et al. | Feb 2023 | B2 |
11746550 | Bass et al. | Sep 2023 | B2 |
11756698 | Reyes et al. | Sep 2023 | B2 |
11842819 | Corbin et al. | Dec 2023 | B2 |
11875906 | LeBlanc et al. | Jan 2024 | B2 |
11894155 | Freeman et al. | Feb 2024 | B2 |
11984231 | Keller et al. | May 2024 | B2 |
11990249 | Cheatham et al. | May 2024 | B2 |
11990815 | Stubsgaard et al. | May 2024 | B2 |
11996208 | Callaway et al. | May 2024 | B2 |
20060000007 | Lin | Jan 2006 | A1 |
20070001933 | Hoffmann | Jan 2007 | A1 |
20090046825 | Dulka et al. | Feb 2009 | A1 |
20090173491 | O'Brien | Jul 2009 | A1 |
20100258309 | Ayodele | Oct 2010 | A1 |
20120012330 | Botich | Jan 2012 | A1 |
20120082911 | Hyde et al. | Apr 2012 | A1 |
20120082913 | Hyde et al. | Apr 2012 | A1 |
20120087455 | Hyde et al. | Apr 2012 | A1 |
20130083878 | Massie et al. | Apr 2013 | A1 |
20140185733 | Povirk et al. | Jul 2014 | A1 |
20150228363 | Dewan et al. | Aug 2015 | A1 |
20150310948 | Venneri | Oct 2015 | A1 |
20160189812 | Czerwinski | Jun 2016 | A1 |
20160189813 | Cisneros, Jr. | Jun 2016 | A1 |
20160217874 | Dewan et al. | Jul 2016 | A1 |
20160272903 | Walter et al. | Sep 2016 | A1 |
20170206984 | Lee et al. | Jul 2017 | A1 |
20170271033 | Dodson et al. | Sep 2017 | A1 |
20170292179 | Hackett | Oct 2017 | A1 |
20170294240 | Baglietto et al. | Oct 2017 | A1 |
20170294241 | Dodson et al. | Oct 2017 | A1 |
20170301413 | Cisneros, Jr. | Oct 2017 | A1 |
20170301418 | Dodson et al. | Oct 2017 | A1 |
20170316840 | Abbott | Nov 2017 | A1 |
20180030576 | Urza | Feb 2018 | A1 |
20180244535 | Russell, II et al. | Aug 2018 | A1 |
20180254109 | Cheatham, III et al. | Sep 2018 | A1 |
20180322968 | Cheatham, III et al. | Nov 2018 | A1 |
20190035510 | LeBlanc | Jan 2019 | A1 |
20190057783 | LeBlanc | Feb 2019 | A1 |
20190066857 | Hackett et al. | Feb 2019 | A1 |
20190139665 | Czerwinski et al. | May 2019 | A1 |
20190203614 | Loewen et al. | Jul 2019 | A1 |
20190371482 | Benson | Dec 2019 | A1 |
20200027581 | Hackett et al. | Jan 2020 | A1 |
20200087156 | Kelleher | Mar 2020 | A1 |
20200122109 | Kruizenga et al. | Apr 2020 | A1 |
20200161015 | Czerwinski et al. | May 2020 | A1 |
20200373024 | Gramlich | Nov 2020 | A1 |
20200393123 | Aly | Dec 2020 | A1 |
20210047199 | Russell, II et al. | Feb 2021 | A1 |
20210047568 | Goodrich et al. | Feb 2021 | A1 |
20210095645 | Cheatham, III | Apr 2021 | A1 |
20210130181 | Brown et al. | May 2021 | A1 |
20210170676 | Kitchen et al. | Jun 2021 | A1 |
20210210224 | Cisneros, Jr. | Jul 2021 | A1 |
20210272707 | Wardle | Sep 2021 | A1 |
20210272708 | Cisneros, Jr. | Sep 2021 | A1 |
20210287814 | Loewen et al. | Sep 2021 | A1 |
20210302295 | Linneen | Sep 2021 | A1 |
20210304909 | Gramlich et al. | Sep 2021 | A1 |
20210313081 | Nygaard et al. | Oct 2021 | A1 |
20210318673 | Kitchen et al. | Oct 2021 | A1 |
20210319920 | Nelson | Oct 2021 | A1 |
20210343431 | Cisneros, Jr. | Nov 2021 | A1 |
20220005619 | Cisneros, Jr. | Jan 2022 | A1 |
20220017382 | Russell, II et al. | Jan 2022 | A1 |
20220051814 | Freeman et al. | Feb 2022 | A1 |
20220051816 | Freeman | Feb 2022 | A1 |
20220051817 | Hejzlar et al. | Feb 2022 | A1 |
20220051818 | Cisneros, Jr. | Feb 2022 | A1 |
20220051820 | Corbin | Feb 2022 | A1 |
20220068512 | Russell, II et al. | Mar 2022 | A1 |
20220081317 | Russell, II et al. | Mar 2022 | A1 |
20220115149 | Barringer et al. | Apr 2022 | A1 |
20220115150 | Hackett et al. | Apr 2022 | A1 |
20220115152 | Barringer et al. | Apr 2022 | A1 |
20220139576 | Inman et al. | May 2022 | A1 |
20220139577 | Cisneros, Jr. et al. | May 2022 | A1 |
20220139578 | Venneri et al. | May 2022 | A1 |
20220250936 | Benson | Aug 2022 | A1 |
20220254524 | Cheatham, III et al. | Aug 2022 | A1 |
20220301729 | Cisneros, Jr | Sep 2022 | A1 |
20220301732 | Cisneros, Jr. et al. | Sep 2022 | A1 |
20220310278 | Choi et al. | Sep 2022 | A1 |
20220310281 | Czerwinski | Sep 2022 | A1 |
20220324066 | Argentine | Oct 2022 | A1 |
20220328202 | Venneri et al. | Oct 2022 | A1 |
20220328203 | Bass et al. | Oct 2022 | A1 |
20220328205 | Bass et al. | Oct 2022 | A1 |
20220336118 | Corbin et al. | Oct 2022 | A1 |
20220351870 | Fisher et al. | Nov 2022 | A1 |
20220363995 | Goodrich et al. | Nov 2022 | A1 |
20220375635 | LeBlanc | Nov 2022 | A9 |
20230024338 | Reed et al. | Jan 2023 | A1 |
20230096162 | Loewen et al. | Mar 2023 | A1 |
20230104365 | Eichel et al. | Apr 2023 | A1 |
20230290528 | Venneri et al. | Sep 2023 | A1 |
20230317306 | Botha et al. | Oct 2023 | A1 |
20230323695 | Johnson et al. | Oct 2023 | A1 |
20230326619 | Snead et al. | Oct 2023 | A1 |
20230377763 | Botha et al. | Nov 2023 | A1 |
20230392274 | Harb et al. | Dec 2023 | A1 |
20230395270 | Benson et al. | Dec 2023 | A1 |
20240013936 | Kim et al. | Jan 2024 | A1 |
20240017212 | Miller et al. | Jan 2024 | A1 |
20240035119 | Tilton et al. | Feb 2024 | A1 |
20240112822 | Lucas et al. | Apr 2024 | A1 |
20240120118 | Aleshin et al. | Apr 2024 | A1 |
20240124985 | Tsang et al. | Apr 2024 | A1 |
20240246023 | Tsang et al. | Jul 2024 | A1 |
Number | Date | Country |
---|---|---|
2967469 | Sep 2023 | CA |
3003498 | Jan 2024 | CA |
3018050 | May 2024 | CA |
102878109 | Nov 2014 | CN |
104214420 | Dec 2014 | CN |
102937090 | Apr 2015 | CN |
104862531 | Aug 2015 | CN |
105060914 | Nov 2015 | CN |
106425315 | Feb 2017 | CN |
105334138 | Jan 2018 | CN |
106180254 | Jun 2018 | CN |
108151567 | Jun 2018 | CN |
108172318 | Jun 2018 | CN |
108389634 | Aug 2018 | CN |
108511088 | Sep 2018 | CN |
108520785 | Sep 2018 | CN |
207850147 | Sep 2018 | CN |
108624839 | Oct 2018 | CN |
107034386 | Nov 2018 | CN |
107130242 | Mar 2019 | CN |
109509562 | Mar 2019 | CN |
106840765 | Apr 2019 | CN |
109671510 | Apr 2019 | CN |
105976879 | May 2019 | CN |
108198635 | Jul 2019 | CN |
110042434 | Jul 2019 | CN |
108206065 | Sep 2019 | CN |
109022921 | Sep 2019 | CN |
107469628 | Oct 2019 | CN |
107945887 | Oct 2019 | CN |
108389632 | Oct 2019 | CN |
109234573 | Oct 2019 | CN |
209496626 | Oct 2019 | CN |
110783010 | Feb 2020 | CN |
110842494 | Feb 2020 | CN |
210039648 | Feb 2020 | CN |
107238627 | Mar 2020 | CN |
108167195 | Jul 2020 | CN |
111508627 | Aug 2020 | CN |
211742680 | Oct 2020 | CN |
112111251 | Dec 2020 | CN |
112284170 | Jan 2021 | CN |
112322939 | Feb 2021 | CN |
110549697 | Apr 2021 | CN |
112609195 | Apr 2021 | CN |
212934166 | Apr 2021 | CN |
110444311 | May 2021 | CN |
112778012 | May 2021 | CN |
108417277 | Jun 2021 | CN |
110695091 | Jun 2021 | CN |
113202780 | Aug 2021 | CN |
113369652 | Sep 2021 | CN |
214529256 | Oct 2021 | CN |
113630582 | Nov 2021 | CN |
113658722 | Nov 2021 | CN |
111334258 | Dec 2021 | CN |
111421913 | Dec 2021 | CN |
113744900 | Dec 2021 | CN |
113851233 | Dec 2021 | CN |
214998262 | Dec 2021 | CN |
113936820 | Jan 2022 | CN |
113990535 | Jan 2022 | CN |
111627571 | Feb 2022 | CN |
113061781 | Feb 2022 | CN |
114074234 | Feb 2022 | CN |
114093529 | Feb 2022 | CN |
215770541 | Feb 2022 | CN |
111057993 | Mar 2022 | CN |
114774738 | Jul 2022 | CN |
112228853 | Aug 2022 | CN |
112259263 | Aug 2022 | CN |
112530614 | Aug 2022 | CN |
114917603 | Aug 2022 | CN |
114927242 | Aug 2022 | CN |
111627572 | Sep 2022 | CN |
111945171 | Sep 2022 | CN |
112174670 | Sep 2022 | CN |
115050490 | Sep 2022 | CN |
115076479 | Sep 2022 | CN |
111739665 | Oct 2022 | CN |
112992389 | Nov 2022 | CN |
115351276 | Nov 2022 | CN |
112587989 | Dec 2022 | CN |
113241200 | Dec 2022 | CN |
115436402 | Dec 2022 | CN |
3563389 | Jul 2021 | EP |
3646344 | Oct 2023 | EP |
4022649 | Dec 2023 | EP |
4297043 | Dec 2023 | EP |
4052274 | Feb 2024 | EP |
4314687 | Feb 2024 | EP |
4348684 | Apr 2024 | EP |
4352750 | Apr 2024 | EP |
4354460 | Apr 2024 | EP |
WO 2013077941 | Oct 2013 | WO |
WO 2014039641 | Jun 2014 | WO |
WO 2015017928 | Feb 2015 | WO |
WO 2015094450 | Oct 2015 | WO |
WO 2017032379 | Mar 2017 | WO |
WO 2017059360 | Apr 2017 | WO |
WO 2017192607 | Nov 2017 | WO |
WO 2018009433 | Jan 2018 | WO |
WO 2018013317 | Jan 2018 | WO |
WO 20180311 | Feb 2018 | WO |
WO 2017199059 | Feb 2018 | WO |
WO 2018026429 | Mar 2018 | WO |
WO 2018042216 | Apr 2018 | WO |
WO 2018064572 | Apr 2018 | WO |
WO 2018071081 | May 2018 | WO |
WO 2018084940 | Jun 2018 | WO |
WO 2018213669 | Jan 2019 | WO |
WO 2019152595 | Aug 2019 | WO |
WO 2019226218 | Jan 2020 | WO |
WO 2019231971 | Jan 2020 | WO |
WO 2020123513 | Aug 2020 | WO |
WO 2021151055 | Jul 2021 | WO |
WO 2021133952 | Sep 2021 | WO |
WO 2022022792 | Feb 2022 | WO |
WO 2022039795 | Feb 2022 | WO |
WO 2022039893 | Feb 2022 | WO |
WO 2022040116 | Mar 2022 | WO |
WO 2022061195 | Apr 2022 | WO |
WO 2022146446 | Jul 2022 | WO |
Number | Date | Country | |
---|---|---|---|
Parent | 18464968 | Sep 2023 | US |
Child | 18529630 | US |