Patent Grant
10839734
The claimed invention was made by, on behalf of, and/or in connection with one or more of the following parties to a joint university corporation research agreement: Regents of the University of Michigan, Princeton University, University of Southern California, and the Universal Display Corporation. The agreement was in effect on and before the date the claimed invention was made, and the claimed invention was made as a result of activities undertaken within the scope of the agreement.
The present invention relates to techniques and systems for operating devices such as OLEDs using various and variable driving schemes, and devices such as organic light emitting diodes and other devices, including the same.
Opto-electronic devices that make use of organic materials are becoming increasingly desirable for a number of reasons. Many of the materials used to make such devices are relatively inexpensive, so organic opto-electronic devices have the potential for cost advantages over inorganic devices. In addition, the inherent properties of organic materials, such as their flexibility, may make them well suited for particular applications such as fabrication on a flexible substrate. Examples of organic opto-electronic devices include organic light emitting devices (OLEDs), organic phototransistors, organic photovoltaic cells, and organic photodetectors. For OLEDs, the organic materials may have performance advantages over conventional materials. For example, the wavelength at which an organic emissive layer emits light may generally be readily tuned with appropriate dopants.
OLEDs make use of thin organic films that emit light when voltage is applied across the device. OLEDs are becoming an increasingly interesting technology for use in applications such as flat panel displays, illumination, and backlighting. Several OLED materials and configurations are described in U.S. Pat. Nos. 5,844,363, 6,303,238, and 5,707,745, which are incorporated herein by reference in their entirety.
One application for phosphorescent emissive molecules is a full color display. Industry standards for such a display call for pixels adapted to emit particular colors, referred to as “saturated” colors. In particular, these standards call for saturated red, green, and blue pixels. Color may be measured using CIE coordinates, which are well known to the art.
One example of a green emissive molecule is tris(2-phenylpyridine) iridium, denoted Ir(ppy)3, which has the following structure:
In this, and later figures herein, we depict the dative bond from nitrogen to metal (here, Ir) as a straight line.
As used herein, the term “organic” includes polymeric materials as well as small molecule organic materials that may be used to fabricate organic opto-electronic devices. “Small molecule” refers to any organic material that is not a polymer, and “small molecules” may actually be quite large. Small molecules may include repeat units in some circumstances. For example, using a long chain alkyl group as a substituent does not remove a molecule from the “small molecule” class. Small molecules may also be incorporated into polymers, for example as a pendent group on a polymer backbone or as a part of the backbone. Small molecules may also serve as the core moiety of a dendrimer, which consists of a series of chemical shells built on the core moiety. The core moiety of a dendrimer may be a fluorescent or phosphorescent small molecule emitter. A dendrimer may be a “small molecule,” and it is believed that all dendrimers currently used in the field of OLEDs are small molecules.
As used herein, “top” means furthest away from the substrate, while “bottom” means closest to the substrate. Where a first layer is described as “disposed over” a second layer, the first layer is disposed further away from substrate. There may be other layers between the first and second layer, unless it is specified that the first layer is “in contact with” the second layer. For example, a cathode may be described as “disposed over” an anode, even though there are various organic layers in between.
As used herein, “solution processible” means capable of being dissolved, dispersed, or transported in and/or deposited from a liquid medium, either in solution or suspension form.
A ligand may be referred to as “photoactive” when it is believed that the ligand directly contributes to the photoactive properties of an emissive material. A ligand may be referred to as “ancillary” when it is believed that the ligand does not contribute to the photoactive properties of an emissive material, although an ancillary ligand may alter the properties of a photoactive ligand.
As used herein, and as would be generally understood by one skilled in the art, a first “Highest Occupied Molecular Orbital” (HOMO) or “Lowest Unoccupied Molecular Orbital” (LUMO) energy level is “greater than” or “higher than” a second HOMO or LUMO energy level if the first energy level is closer to the vacuum energy level. Since ionization potentials (IP) are measured as a negative energy relative to a vacuum level, a higher HOMO energy level corresponds to an IP having a smaller absolute value (an IP that is less negative). Similarly, a higher LUMO energy level corresponds to an electron affinity (EA) having a smaller absolute value (an EA that is less negative). On a conventional energy level diagram, with the vacuum level at the top, the LUMO energy level of a material is higher than the HOMO energy level of the same material. A “higher” HOMO or LUMO energy level appears closer to the top of such a diagram than a “lower” HOMO or LUMO energy level.
As used herein, and as would be generally understood by one skilled in the art, a first work function is “greater than” or “higher than” a second work function if the first work function has a higher absolute value. Because work functions are generally measured as negative numbers relative to vacuum level, this means that a “higher” work function is more negative. On a conventional energy level diagram, with the vacuum level at the top, a “higher” work function is illustrated as further away from the vacuum level in the downward direction. Thus, the definitions of HOMO and LUMO energy levels follow a different convention than work functions.
More details on OLEDs, and the definitions described above, can be found in U.S. Pat. No. 7,279,704, which is incorporated herein by reference in its entirety.
According to an embodiment, an OLED display device may operate by receiving an input signal indicating an apparent luminance to be generated by at least one OLED in the display during a first frame time. A first drive signal may be provided to the at least one OLED, which includes a waveform specifying an output for the OLED during the first frame time. The first drive signal may produce a momentary luminance greater than the apparent luminance for at least a portion of the first frame time. The waveform may be selected from among a plurality of predefined waveforms, which may be stored by the display device. A waveform may be selected based upon, for example, an expected degradation of the OLED, the age of the OLED, in order to activate a selected region of an emissive layer within the at least one OLED, based upon a measurement of an operating parameter of the OLED, based upon a known relationship of luminance efficacy to luminance of the OLED, in order to activate one of a multiple regions of an emissive region of the OLED based upon a desired color of light, to activate an emissive material from of several emissive materials in the OLED, and/or based upon a temperature of the OLED, or the like. The drive signal may specify a voltage and/or a current at which to drive the at least one OLED during the frame time. The total integrated luminance resulting from the waveform during the first frame time may be equivalent to a total integrated luminance of the apparent luminance over the first frame time. The first frame time may be defined, for example, by a single frame of a video provided for display on the OLED display, such as via the input signal. The waveform may be periodic within the first frame time, and may include forms such as square, sawtooth, triangle, sine, peak waveforms, and/or combinations thereof. The waveform may have a frequency equal to or greater than a frame frequency of the input signal, such as the frequency at which individual frames are provided for display on a display device, such as at least 60 Hz, 100 Hz-1 MHz, or the like. The drive signal may specify a current density of not more than 200 mA/cm2, not more than 500 mA/cm2, or the like. The drive signal may include a basic drive voltage, such as a constant DC mode type drive voltage, that is applied concurrently with the waveform. For example, a second drive signal may be provided to the OLED during a second frame time, occurring before or after the initial frame time, which produces a momentary luminance equal to the apparent luminance. The second frame time may occur during receipt of a second input signal different than the first input signal. Each input signal may include multiple image frames, each of which is displayed by the display device for a frame time.
In an embodiment, a display device may include an OLED, a receiver configured to receive a display signal indicating an apparent luminance for the OLED during a first frame time, and a drive circuit in signal communication with the OLED, which is configured to provide a first drive signal to the OLED based upon a waveform generated by a processor. The waveform may define a momentary luminance during at least a portion of the first frame time that is greater than the apparent luminance. The OLED may include multiple emissive layers, each of which may be separated from adjacent emissive layers by a blocking layer. Alternatively or in addition, the OLED may include an emissive region containing multiple regions, each of which is configured to emit light having a peak wavelength different than the other. The display device may include a memory to store multiple waveforms that are selected by the processor, as previously described. The display device may operate according to some or all of the embodiments disclosed herein. The display device can be a consumer product, an organic light-emitting device, and/or a lighting panel or the like.
Generally, an OLED comprises at least one organic layer disposed between and electrically connected to an anode and a cathode. When a current is applied, the anode injects holes and the cathode injects electrons into the organic layer(s). The injected holes and electrons each migrate toward the oppositely charged electrode. When an electron and hole localize on the same molecule, an “exciton,” which is a localized electron-hole pair having an excited energy state, is formed. Light is emitted when the exciton relaxes via a photoemissive mechanism. In some cases, the exciton may be localized on an excimer or an exciplex. Non-radiative mechanisms, such as thermal relaxation, may also occur, but are generally considered undesirable.
The initial OLEDs used emissive molecules that emitted light from their singlet states (“fluorescence”) as disclosed, for example, in U.S. Pat. No. 4,769,292, which is incorporated by reference in its entirety. Fluorescent emission generally occurs in a time frame of less than 10 nanoseconds.
More recently, OLEDs having emissive materials that emit light from triplet states (“phosphorescence”) have been demonstrated. Baldo et al., “Highly Efficient Phosphorescent Emission from Organic Electroluminescent Devices,” Nature, vol. 395, 151-154, 1998; (“Baldo-I”) and Baldo et al., “Very high-efficiency green organic light-emitting devices based on electrophosphorescence,” Appl. Phys. Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), which are incorporated by reference in their entireties. Phosphorescence is described in more detail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporated by reference.
More examples for each of these layers are available. For example, a flexible and transparent substrate-anode combination is disclosed in U.S. Pat. No. 5,844,363, which is incorporated by reference in its entirety. An example of a p-doped hole transport layer is m-MTDATA doped with F4-TCNQ at a molar ratio of 50:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. Examples of emissive and host materials are disclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which is incorporated by reference in its entirety. An example of an n-doped electron transport layer is BPhen doped with Li at a molar ratio of 1:1, as disclosed in U.S. Patent Application Publication No. 2003/0230980, which is incorporated by reference in its entirety. U.S. Pat. Nos. 5,703,436 and 5,707,745, which are incorporated by reference in their entireties, disclose examples of cathodes including compound cathodes having a thin layer of metal such as Mg:Ag with an overlying transparent, electrically-conductive, sputter-deposited ITO layer. The theory and use of blocking layers is described in more detail in U.S. Pat. No. 6,097,147 and U.S. Patent Application Publication No. 2003/0230980, which are incorporated by reference in their entireties. Examples of injection layers are provided in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety. A description of protective layers may be found in U.S. Patent Application Publication No. 2004/0174116, which is incorporated by reference in its entirety.
The simple layered structure illustrated in
Structures and materials not specifically described may also be used, such as OLEDs comprised of polymeric materials (PLEDs) such as disclosed in U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated by reference in its entirety. By way of further example, OLEDs having a single organic layer may be used. OLEDs may be stacked, for example as described in U.S. Pat. No. 5,707,745 to Forrest et al, which is incorporated by reference in its entirety. The OLED structure may deviate from the simple layered structure illustrated in
Unless otherwise specified, any of the layers of the various embodiments may be deposited by any suitable method. For the organic layers, preferred methods include thermal evaporation, ink-jet, such as described in U.S. Pat. Nos. 6,013,982 and 6,087,196, which are incorporated by reference in their entireties, organic vapor phase deposition (OVPD), such as described in U.S. Pat. No. 6,337,102 to Forrest et al., which is incorporated by reference in its entirety, and deposition by organic vapor jet printing (OVJP), such as described in U.S. Pat. No. 7,431,968, which is incorporated by reference in its entirety. Other suitable deposition methods include spin coating and other solution based processes. Solution based processes are preferably carried out in nitrogen or an inert atmosphere. For the other layers, preferred methods include thermal evaporation. Preferred patterning methods include deposition through a mask, cold welding such as described in U.S. Pat. Nos. 6,294,398 and 6,468,819, which are incorporated by reference in their entireties, and patterning associated with some of the deposition methods such as ink-jet and OVJD. Other methods may also be used. The materials to be deposited may be modified to make them compatible with a particular deposition method. For example, substituents such as alkyl and aryl groups, branched or unbranched, and preferably containing at least 3 carbons, may be used in small molecules to enhance their ability to undergo solution processing. Substituents having 20 carbons or more may be used, and 3-20 carbons is a preferred range. Materials with asymmetric structures may have better solution processability than those having symmetric structures, because asymmetric materials may have a lower tendency to recrystallize. Dendrimer substituents may be used to enhance the ability of small molecules to undergo solution processing.
Devices fabricated in accordance with embodiments of the present invention may further optionally comprise a barrier layer. One purpose of the barrier layer is to protect the electrodes and organic layers from damaging exposure to harmful species in the environment including moisture, vapor and/or gases, etc. The barrier layer may be deposited over, under or next to a substrate, an electrode, or over any other parts of a device including an edge. The barrier layer may comprise a single layer, or multiple layers. The barrier layer may be formed by various known chemical vapor deposition techniques and may include compositions having a single phase as well as compositions having multiple phases. Any suitable material or combination of materials may be used for the barrier layer. The barrier layer may incorporate an inorganic or an organic compound or both. The preferred barrier layer comprises a mixture of a polymeric material and a non-polymeric material as described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos. PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporated by reference in their entireties. To be considered a “mixture”, the aforesaid polymeric and non-polymeric materials comprising the barrier layer should be deposited under the same reaction conditions and/or at the same time. The weight ratio of polymeric to non-polymeric material may be in the range of 95:5 to 5:95. The polymeric material and the non-polymeric material may be created from the same precursor material. In one example, the mixture of a polymeric material and a non-polymeric material consists essentially of polymeric silicon and inorganic silicon.
Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of electronic component modules (or units) that can be incorporated into a variety of electronic products or intermediate components. Examples of such electronic products or intermediate components include display screens, lighting devices such as discrete light source devices or lighting panels, etc. that can be utilized by the end-user product manufacturers. Such electronic component modules can optionally include the driving electronics and/or power source(s). Devices fabricated in accordance with embodiments of the invention can be incorporated into a wide variety of consumer products that have one or more of the electronic component modules (or units) incorporated therein. Such consumer products would include any kind of products that include one or more light source(s) and/or one or more of some type of visual displays. Some examples of such consumer products include flat panel displays, computer monitors, medical monitors, televisions, billboards, lights for interior or exterior illumination and/or signaling, heads-up displays, fully or partially transparent displays, flexible displays, laser printers, telephones, cell phones, tablets, phablets, personal digital assistants (PDAs), laptop computers, digital cameras, camcorders, viewfinders, micro-displays, 3-D displays, vehicles, a large area wall, theater or stadium screen, or a sign. Various control mechanisms may be used to control devices fabricated in accordance with the present invention, including passive matrix and active matrix. Many of the devices are intended for use in a temperature range comfortable to humans, such as 18 C to 30 C, and more preferably at room temperature (20-25 C), but could be used outside this temperature range, for example, from −40 C to +80 C.
Many OLED devices and types of devices, such as multi-layer phosphorescent OLED devices, may not age uniformly when operated or aged under a constant DC current. The charge balance and/or recombination rate profile across the emissive layer or layers of the OLED components may change as a result of device aging, which often leads to undesirable effects such as color alteration, efficiency decreases, and “image sticking”.
The charge balance and/or recombination rate profile also may change in response to a change in driving current. Thus, according to embodiments disclosed herein, the profile of OLED device recombination zones may be modified by changing the device structure, and/or by adjusting the driving conditions. Specifically, driving such a device using different current/voltage profiles can be used to modify the recombination profile of an aged device and, in some cases, partially or entirely recover efficiency losses due to aging. Techniques as disclosed herein may be continuous during operation of a device, and may be interactive based upon operation of the device, specific input signals, and the like. The application of non-DC driving schemes also may extend the device relative lifetime, though in some cases such gains may come at the expense of luminous efficiency. Driving waveforms also may be designed to minimize the image sticking effect in OLED-based displays.
According to embodiments disclosed herein, a waveform generated by the processor 330 may define a momentary luminance that is greater than the apparent luminance indicated by an input signal for at least a portion of the frame time for which the apparent luminance is indicated. That is, an OLED in the display 310 may be driven at a higher luminance for a portion of a frame than the luminance indicated for that frame by an input signal. The waveform may have various shapes and properties, and may have a frequency greater than the frame frequency of a signal that indicates the apparent luminance for the OLED being driven. As described in further detail below, various preconfigured waveforms may be used, which may be stored in a memory 340 in or accessible by the display device 300. Such operation may be contrasted to conventional operation in which an OLED in the display 300 is driven at a constant luminance corresponding to the apparent luminance indicated by an input signal. Such operation, in which a constant luminance is used, may be referred to as a “DC mode” since typically a constant DC current and/or voltage is used to drive the OLED. In contrast, the use of a selected and/or varying waveform to drive an OLED as disclosed herein may be referred to as a “pulsed mode” of operation, because waveforms used in such modes may resemble a “pulse” more than a constant applied current or voltage. However, it will be understood that a “pulsed mode” operation may, but need not, use a regular, repeated waveform having uniform pulses applied at regular intervals over a period of time. In fact, as described in further detail herein, the specific waveforms applied during a pulsed mode operation as disclosed may vary with time, such as where different waveforms are selected and/or applied based upon a lifetime of an OLED in a display, and different pulsed modes may be applied to the OLED at different times.
In general, the total integrated luminance resulting from a pulsed mode waveform during a particular time may be equivalent to the total integrated luminance of an apparent luminance, such as specified by an input signal as previously disclosed, over the same time. Any suitable waveform may be used, and the waveform may be periodic over the time that it is used to drive an OLED. Example waveforms that may be used include a square wave, a sawtooth wave, a triangle wave, a sine wave, a single narrow peak, and combinations thereof.
More specifically, the same visible (integrated) luminance Li of a device such as an OLED, LED, or any other light source with fast response time, can be obtained either by driving the device in a DC mode at the desired apparent luminance Lo, or in pulsed mode as disclosed herein at a higher momentary luminance, which to the viewer appears the same as Lo. In general, for a conventional, non-tunable OLED, the integrated luminance is equal to the momentary luminance multiplied by the duty cycle factor. In contrast, according to embodiments disclosed herein, a combination of duty cycle and momentary luminance can be used to tune the resulting visible luminance. For example, at frequencies of 60 Hz or higher, a momentary luminance as disclosed herein typically will be indistinguishable or nearly indistinguishable to the human eye.
The specific waveform applied in a pulsed mode for a particular device may change over time. For example, a display device may generate or select a specific waveform based on the age and/or expected degradation of an OLED that the waveform is being used to drive. As another example, a device may use one waveform in which the apparent luminance is equal to the momentary luminance, or may operate in a DC mode for a period of time. At another point in time the device may operate using a waveform with a momentary luminance greater than the apparent luminance, for example due to the age of the OLED being driven.
Embodiments disclosed herein may reduce or eliminate the image “sticking” problem that occurs in some OLED displays, i.e., the difference between aged and non-aged devices due to changes in pixels in the OLED display.
Alternatively or in addition, tuning a device structure to obtain a desired luminous efficacy vs. luminance plot for an aged device, in combination with a pulsed driving mode, may provide an additional efficacy increase of the aged device, which is equivalent to improving the lifetime. Such a technique may be particularly effective if the device is operated at a relatively low luminance (See
The explanation of these phenomena likely is the changing of the recombination profile in the OLED device emissive layer or layers, in response to changing current density and age.
Such an effect may be demonstrated in an experiment in which two identical pixels are simultaneously aged, one driven in a DC mode and the other in a pulsed mode. Such an experiment is described herein. The experiment results show that the device aged using a constant-current DC mode becomes brighter when switched to a pulsed mode that uses parameters that generate the same Lo as the DC mode, as shown and described with respect to
These effects may be used advantageously by modifying the OLED device architecture. For example, a device with multiple emissive layers (EMLs) may be constructed in which each EML is separated by a thin blocking layer, such as a 1-5 nm layer. The blocking layer may block excitons from migrating from one EML zone to another, while also facilitating charge transport through the blocking layer, such as via tunneling. An example of such a device is shown in
Embodiments disclosed herein in which different waveforms are used as part of an OLED driving scheme are not limited to a set of fixed conditions with the main focus on slowing down the aging process that occurs during normal operation of the OLED-based devices. As described herein, such adjustments made via pulsed mode driving waveforms may be made as part of a dynamic process that extends the life and functionality of the devices, by responding to the changing recombination profile of an aged device over the lifetime of the device. That is, different pulsed modes may be applied to the same device at different times.
The range of parameters used in a particular pulsed mode, such as repetition frequency, the pulse width, and the duty factor, may be specific to an application using the OLED device. For example, specific values may be set dynamically or prior to operation of the device, based upon the lifetime, expected degradation of OLEDs, and/or other factors specific to an individual OLED display device. Similarly, the shape and size of the pulse itself may be optimized for a maximum response of an OLED device, depending on its luminance vs current characteristics, which is defined by the recombination profile.
The examples shown in
The amplitude of the pulse may be limited by the DC current capacity of the injection mechanism, and is typically less than 500 mA/cm2, with the upper limit being also related to the Joule heating of the substrate, depending on the duty factor of the waveform. A preferred operation current may be 200 mA/cm2 or less. Higher current density values may require higher voltage, potentially increasing the leakage current and eventually exceeding the device break-down voltage.
As another example, a saw-tooth or stepping voltage may be applied to widen the physical shape of the recombination profile during the device operation. The limitations of resulting RMS would be the same as in the DC case, but an additional limit may result from the device breakdown voltage, typically about 15V for devices with EML thickness of about 300 Å.
As another example, a high frequency waveform may be used to lower the movement of the space charge affecting device stability. The limit of such a waveform may be in the single MHz range, which is primarily limited by the capacitance of the pixel. Smaller pixels of the size of less than 1 mm2 may be driven at higher frequencies. Typically such pixels may be driven at up to about 20 MHz.
As another example, in OLED displays typically driven at a 60 Hz refresh rate, the gray scale digital signal may be preserved by using an increased amplitude and shortened duration. In this case, each pixel on-time may be considered as the DC signal, and may be replaced with a square-wave signal of increased amplitude and frequency, limited by the driving circuit. An appropriate frequency limit typically is approximately the same as in a DC-mode, i.e., about 300 Hz to 10 MHz.
A display device as disclosed herein may use multiple waveforms in a pulsed mode at different points in time, for example based upon the age of the OLED being driven. As previously described, a display device may store multiple waveforms, such as in a computer-readable memory, within the display device. The specific waveforms stored may be pre-calculated. For example, a particular OLED structure may be fabricated and tested to determine an expected lifetime and/or degradation profile over time, a relationship between luminous efficacy and luminance of the OLED, or the like. Waveforms may be selected that correspond to the expected profile. Thus, as the OLED ages, different waveforms may be used based upon the OLEDs age, expected degradation, or the like. As described in further detail below, a pulsed mode waveform also may be selected based upon a desired region of one or more emissive layers, emissive materials, or the like within the OLED that are to be activated, i.e., caused to emit light, when the OLED is driven with the waveform. During operation of a device such as a display device as disclosed herein, a waveform also may be selected based upon various operating characteristics of the OLED. For example, an OLED may be expected to degrade faster or to exhibit certain color, luminance, or other characteristics at a given temperature. Thus, a current or historical temperature of the OLED may be used to select a waveform.
DC mode aging appears not to uniformly affect the EML. Thus, a waveform may be crafted to gradually address wider zones of the EML, allowing access to areas of the EML with a more favorable concentration of undamaged emitters and smaller concentrations of quenchers. For example, a waveform may be used in which every square, or essentially DC-like pulse starts with a high voltage, very short pulse, thus pulling the injection and drift of the carriers beyond the narrow damaged zone near the EML interface.
The use of pulsed mode driving schemes as disclosed herein may provide several advantages in addition to those previously described. For example, the same visible luminance may be achieved in many different ways. As a specific example, changing the duty factor of a standard square wave may result in the same luminance under very different transient voltage. However, the different voltages applied to the device may change the local carrier densities by affecting both the injection and transport processes and resulting in different profiles of recombination as previously described.
As another example, the efficiency drop due to device aging can be changed by varying the operation mode of the device, such as by switching from a low luminance DC mode to a high luminance pulsed mode, as previously described. The relative difference between aged and non-aged devices may be smaller, as shown, for example, in
As another example, the shape of a device's efficiency curve may be designed to obtain additional efficiency for an aged device by driving it in a pulsed mode with higher momentary luminance and the same apparent luminance.
As another example, the practical lifetime of a device operated at a specific luminance may be extended by using a pulse mode after driving in a DC mode for a period of time, and thus moving the recombination profile to include the less damaged areas of the device EML
Another example advantage of a pulsed mode is that the device may have time to dissipate power between pulses, and thus can be driven with relatively high transient luminance. This may provide the possibility of electronically modifying the color or other features of a display or a single light source. In fact, the color of an OLED, such as a multi-EML device, may be tuned by changing the recombination profile and/or the recombination zone (RZ) position within the device EML, separately from any considerations related to the lifetime, efficacy, or other previously-described aspects of device operation.
For example, a device EML may include at least 2 regions emitting light with different colors. In certain device architectures, the RZ position may be moved by changing the device luminance by increasing the driving current or field, i.e., driving the OLED at a higher DC mode current or voltage. In this case the color may be changeable; however, the device luminance would change as well. However, driving the device in a pulsed mode with high momentary luminance and a low integrated luminance as previously described, may provide a means to tune the device color without changing the emission intensity. Similarly, the same structure may be color tuned at the same luminance by changing the driving pulse width and or waveform frequency.
Color tuning may be also performed for a device containing more than one emitter each with different EL transient decay times. This may be single EML device. In this case driving the device with short pulses results in enhancing the slow emitter component in the device emission, whereas the driving the device with long pulses enhances the fast component emission. The same luminance with different color can be achieved by a combination of pulse width and duty factor. This technique utilizes the decaying luminance at the end of the pulse which is dominated by the slow emitter. Different shapes of waveforms are demonstrated for this device color tuning.
For both types of color tunable structures, the device luminance level may be changed while maintaining the same CIE at two different colors. For example, the luminance may be changed for the same device which emits red or yellow. Such effects may be achieved through variation of driving parameters as disclosed herein, such as momentary current density, duty factor (DF), pulse width and frequency. When used for display devices, such techniques may result in simpler fabrication techniques, since the device fabrication may require less use of high precision masks and fewer deposition steps.
In general, an OLED having multiple EMLs or emissive regions may be color tuned by driving the OLED using different pulsed mode waveforms, to change the location of recombination within the device and thereby change the color of light emitted by the device. Thus, the recombination zone may be moved between regions of the OLED, which then may cause different emissive materials to predominantly emit within the OLED. For example, in a device having two EMLs, a first waveform may be applied that causes recombination to occur primarily or exclusively within the first of the two EMLs. A second waveform then may be applied to move some or all of the recombination within the device to the second EML. Where the EMLs include materials that emit light of different colors, this change will cause the ultimate color of light emitted by the device to change as well. Thus, the color output of the device may be modified solely by applying different pulsed mode waveforms. Similarly, the structure of the device may be selected in advance and matched to one or more waveforms, to allow for a range of colors to be emitted. For example, a device structure may be selected that has multiple emissive regions or areas that will produce light of different color. Concurrently or consecutively, appropriate waveforms may be selected that will move the primary recombination zone or zones between the emissive regions. The waveforms may be selected based upon the specific structure of the device, or may be determined by operating the device or an equivalent device using various DC and/or pulsed modes and observing the change in light emitted by the device. Specific examples of device structures and waveforms are disclosed herein. According to some embodiments, additional structural variations may be used. For example, one or more color filters or other color altering layers may be used in combination with the techniques disclosed herein, so as to obtain acceptable or desirable color purity. Such a configuration may be desirable in configurations in which the color obtained from a particular waveform is not a specific desired color. Such a configuration also may be used with white devices with color filters.
As a specific example,
As previously disclosed, color tuning by applying a variable current density in a DC driving mode may result in the device luminance changing in addition to the color emitted by the device being changed. Thus, it may not be practical to use such a technique to change the color in a display due to potentially dramatic differences in luminance when the display emits a different color. For a display to maintain the same color over a wide luminance range, it may be desirable for the display to have many levels of grey scale available.
Driving a device in a pulsed mode with variable momentary current density and variable duty factor as previously disclosed may solve this issue, i.e., allow the color of the device to be tuned by variation of momentary current density, while the integrated visible device luminance is kept the same by manipulating the duty factor.
This technique allows for the same integrated luminance in a pulsed mode to be achieved by various driving methods, such as DC or pulsed mode, with various momentary current density and duty factor values. Increasing the momentary current density and decreasing the duty factor can result in the same device radiance, as illustrated by the data shown in Table 8. Thus, the device may be driven at a device at high current density, which results in changing the RZ within the device EML and emitting a different color, while not increasing or controlling the overall device radiance. Notably, the measured luminance shown in Table 8 changes due to changes in the emitted spectrum; however, the radiance (total emission energy from the device) and photon count stays nearly constant.
As another example technique, a device may be driven using a pulsed mode with a variable frequency and pulse width waveform.
Color tuning by this method may be explained by the EL spectrum time response for certain structures. When a voltage is applied to the device, the emission starts at the ETL interface and then propagates inside the EML toward the HTL interface. For a narrow pulse width such as 1 μs (i.e., a short emission time), the majority of recombination occurs in the red part of the EML next to the blocking layer. At a wide pulse width, such as 50 μs (i.e., a long emission time), the recombination zone has sufficient time to shift to the green part of the EML toward the HTL interface. As a result, predominantly green emission is observed for a 50 μs long pulse, and more red emission is observed with a narrow pulse width, as shown in Table 9.
With the multi-EML OLED device operated in a pulse mode, the time constants of various regions of device recombination profile can be very different. The shape of the pulse of light coming from different sections of the device can vary in terms of the pulse rise and the fall times. Knowing the device time response characteristics allows the utilization of another mechanism to control the output color. For example, if the rise or fall time of the red emission is longer from that of a green component, the color change can be achieved by changing the pulse width, promoting faster or slower components. This time-resolved color change may cause a change of the overall brightness, which can then be corrected by other parameters of the waveform, such as amplitude or frequency. An electronic driving circuit can be used to provide the necessary modifications of the waveform on demand of the user, a display input, based upon a provided input or configuration signal, or the like.
As another example, a device having multiple emitters may be color tuned using the techniques disclosed herein. An example schematic structure of such a device is shown in
Enhancement of a slow emission component, such as a red emissive component, can be achieved with a gradual or stepped increase pulse to suppress the fast emission in the pulse rise, which improves the conditions for the decay component of the emission which is predominantly slow emission. In this way the slow emission contribution may be enhanced, as shown in
As previously indicated, when color tunable OLED devices are used in a display application such as a full-color display, it may be preferred that the display device can be driven at the same color at several grey scales, i.e., at various brightness levels. This may be achieved by using multiple device structures with different driving schemes including variation of momentary current density, frequency, pulse width, duty factor as disclosed herein. Two examples below describe the same device driven with variable luminance levels maintaining the same color.
Ranges and parameters other than those used in the specific illustrative examples may be used. For example, momentary current densities may be used in the range of from 0.1-1,000 mA/cm2. Frequencies of 20 Hz to 1 MHz may be used for phosphorescent OLEDs, and 20 Hz to 1 GHz for fluorescent devices. Pulse widths of 0.1 to 1000 μs may be used for phosphorescent OLEDs and 0.1 ns to 1000 μs for fluorescent devices. Duty factors of 0.01% to 100% may be used. Specific illustrative ranges include momentary current densities in the range of 0.39 to 753 mA/cm2, frequencies in the range of 35 Hz to 200 kHz, pulse widths of 0.35 to 990 μs, and duty factors of 0.04 to 100% may be used.
Although many examples disclosed herein are described in terms of a full-color display that includes OLEDs as, for example, pixels and sub-pixels, it will be understood that the principles, techniques, and arrangements apply equally to lighting applications where it may be desirable to adjust the color and/or luminance in a similar device. For example, an OLD lighting panel may use the techniques disclosed herein to adjust luminance and/or color, such as to achieve a longer lifetime. In applications that do not inherently include a frame time, frame times may be used that correspond to a desired frequency of pulsed mode signals. As a specific example, a continuously-lit lighting panel may be operated in a pulsed mode at a frequency of 60 Hz, 80 Hz, 120 Hz, or the like, or at any other suitable frequency, even though the panel may not be configured to display a video or other signal that includes such a frequency.
2-2.4
931
931
The advantage of DC/pulse aging modes switch is demonstrated on 2 OLED dots of the same device structure driven in 2 different modes using the driving conditions described in Table 5. The example device structure used is: ITO(800 Å)/HAT-CN(100 Å)/HTL 1(450 Å)/Host2:Irppy 12%(300 Å)/Host2(50 Å)/Liq:ET 1 (40% 400 Å)/Liq(10 Å)/Al(1000 Å).
Dot 1 was driven at 10 mA/cm2 for the first 115 hours and then switched to pulsed mode at 27 mA/cm2 with a 37% duty factor. Dot 2 was driven in a pulsed mode of 27 mA/cm2 with 37% duty factor for the first 115 hours and then switched to a 10 mA/cm2 DC mode. Pulsed conditions were selected to provide the same integrated luminance as achieved at 10 mA/cm2 DC mode of a non-aged device. The device driving schemes are shown in Table 5.
The opposite effect of an additional loss of luminance (aging) was observed on dot 2 when the device was aged in the pulsed mode for 115 hours and then switched to DC mode, as shown in
It is understood that the various embodiments described herein are by way of example only, and are not intended to limit the scope of the invention. For example, many of the materials and structures described herein may be substituted with other materials and structures without deviating from the spirit of the invention. The present invention as claimed may therefore include variations from the particular examples and preferred embodiments described herein, as will be apparent to one of skill in the art. It is understood that various theories as to why the invention works are not intended to be limiting.
This application claims the benefit of U.S. Provisional Patent Application Ser. No. 61/919,937, filed Dec. 23, 2013 and U.S. Provisional Patent Application Ser. No. 62/077,423, filed Nov. 10, 2014, the entire contents of each of which is incorporated herein by reference.
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