This application relates to spin torque transfer magnetic tunnel junction devices.
Various multilayer magnetic materials include at least one ferromagnetic layer configured as a “free” layer whose magnetic direction can be changed by an external magnetic field or a spin-polarized control current. Magnetic memory devices may be constructed using such multilayer structures where information is stored based on the magnetic direction of the free layer.
One example for such a multilayer structure is a magnetic or magnetoresistive tunnel junction (MTJ) which includes at least three layers: two ferromagnetic layers and a thin layer of a non-magnetic insulator as a barrier layer between the two ferromagnetic layers. The insulator material for the middle barrier layer is not electrically conductive and hence functions as a barrier between the two ferromagnetic layers. When the thickness of the insulator is sufficiently thin, e.g., a few nanometers or less, electrons in the two ferromagnetic layers can “penetrate” through the thin layer of the insulator due to a tunneling effect under a bias voltage applied to the two ferromagnetic layers across the barrier layer. The resistance to the electrical current across the MTJ structure varies with the relative direction of the magnetizations in the two ferromagnetic layers. When the magnetizations of the two ferromagnetic layers are parallel to each other, the resistance across the MTJ structure is at a minimum value Rp. When the magnetizations of the two ferromagnetic layers are opposite to or anti-parallel with each other, the resistance across the MTJ is at a maximum value RAP. The magnitude of this effect can be characterized by a tunneling magnetoresistance (TMR) defined as (RAP−Rp)/Rp.
The relationship between the resistance to the current flowing across the MTJ and the relative magnetic direction between the two ferromagnetic layers in the TMR effect can be used for nonvolatile magnetic memory devices to store information in the magnetic state of the MTJ. Magnetic random access memory (MRAM) and other magnetic memory devices based on the TMR effect, for example, may be an alternative to and compete with electronic RAM devices in various applications. In such magnetic memory devices, one ferromagnetic layer is configured to have a fixed magnetic direction and the other ferromagnetic layer is a “free” layer whose magnetic direction can be changed to be either parallel or opposite to the fixed direction. Information is stored based on the relative magnetic direction of the two ferromagnetic layers on two sides of the barrier of the MTJ. For example, binary bits “1” and “0” may be recorded as the parallel and anti-parallel orientations of the two ferromagnetic layers in the MTJ. Recording or writing a bit in the MTJ can be achieved by switching the magnetization direction of the free layer, e.g., by a writing magnetic field generated by supplying currents to write lines disposed in a cross stripe shape, by a current flowing across the MTJ based on the spin torque transfer effect, or by other means.
In the spin torque transfer switching, the current required for changing the magnetization of the free layer can be small (e.g., 0.5 mA or lower in some MTJs) and significantly less than the current used for the field switching. Therefore, the spin torque transfer switching in an MTJ cell can be used to significantly reduce the power consumption of the cell. In addition, conductor wires for carrying currents that generate the sufficient magnetic field for switching the magnetization of the free layer may be eliminated. This allows a spin torque transfer switching MTJ cell to be smaller than a field switching MTJ cell. Accordingly, the MTJ cells for the spin torque transfer switching may be fabricated at a higher areal density on a chip than that of field switching MTJ cells and have potential in high density memory devices and applications.
This application describes magnetic or magnetoresistive tunnel junctions (MTJs) and techniques associated with devices having MTJ cells configured to operate based on spin torque transfer switching. On-plug MTJ designs and fabrication techniques are described.
In one implementation, a device is described to include a substrate; a conductive via formed over the substrate and vertically extended substantially perpendicular to the substrate; a metal plug formed on top of the conductive via; a dielectric material embedding the metal plug and exposing a top surface of the metal plug; and a magnetic tunnel junction (MTJ) cell formed on the top surface of the metal plug.
In another implementation, a device is described to include a substrate and a magnetic tunnel junction (MTJ) cell formed over the substrate. The MTJ cell includes a free ferromagnetic layer having a magnetization direction that is changeable between a first direction and a second substantially opposite direction, a fixed ferromagnetic layer having a magnetization direction fixed along substantially the first direction, and an insulator barrier layer formed between the free and fixed ferromagnetic layers to effectuate tunneling of electrons between the free and fixed ferromagnetic layers. The magnetic tunnel junction cell is shaped to be elongated along the first direction. This device also includes a conductor line formed over the substrate and positioned to have a portion which spatially overlaps with the MTJ cell and is parallel to the first direction of the MTJ cell and is electrically coupled to supply a current across the MTJ cell, and a control circuit to control the current to the MTJ cell from the conductor line to change the magnetization direction of the free ferromagnetic layer of the MTJ cell via spin torque transfer.
This application also describes a method for forming an MTJ cell device. This method includes forming a dielectric layer over a substrate; subsequently forming a contiguous metal structure to include at least one metal plug which is embedded in the dielectric layer and a metal layer which is atop and covers a top surface of the dielectric layer; partially removing the metal layer of the contiguous metal structure to leave a remaining metal layer of the metal layer that is atop and covers the top surface of the dielectric layer without exposing the dielectric layer; forming magnetic tunnel junction (MTJ) layers on the remaining metal layer; and patterning the MTJ layers to form at least one MTJ cell on top of the remaining metal layer.
This application further describes another method for forming an MTJ cell device. This method includes forming a dielectric layer over a substrate; subsequently forming at least one metal plug embedded in the dielectric layer; polishing the dielectric layer and the metal plug embedded in the dielectric layer to form a polished surface which exposes a top surface of the metal plug; forming a conductive buffer layer over the polished surface to cover the dielectric layer and the metal plug; forming magnetic tunnel junction (MTJ) layers on the conductive buffer layer; and patterning the MTJ layers to form at least one MTJ cell on the conductive buffer layer and on top of the metal plug.
These and other implementations, their variations and modifications are described in greater detail in the attached drawings, the detailed description, and the claims.
The magnetization of the ferromagnetic layer 112 is not pinned and can be freely changed to be either parallel to or anti-parallel to the fixed magnetization of the pinned layer 111. For this reason, the ferromagnetic layer 112 is a free layer (FL) and has its magnetic easy axis substantially along the fixed magnetization direction of the pinned layer 111 and its magnetically hard axis substantially perpendicular to the easy axis. The control of the magnetization of the ferromagnetic layer 112 can be through an external write magnetic field in a field switching design, or a write current perpendicularly flowing through the MTJ in a spin torque transfer switching design. A magnetic field in the field operating range, or an applied current across the junction in the current operating range, can force the magnetization of the free layer 112 to be substantially parallel to or substantially opposite to the fixed magnetization of the pinned layer 111. Many magnetic systems have competing energy contributions that prevent a perfect parallel or antiparallel alignment of the magnetic domains or nanomagnets in each ferromagnetic layer. In MTJs, the dominant contribution to the energy state of the nanomagnets within the free layer 112 tends to force the nanomagnets into the parallel or antiparallel alignment, thus producing a substantial parallel or antiparallel alignment. In an actual device, each cell may be elliptically shaped and elongated to provide the shape anisotropy in the magnetic recording layer of the MTJ cell to spatially favor a particular magnetization direction as the easy axis in order to increase the stability of the MTJ cell against perturbations to the magnetization of the MTJ cell, e.g., thermal fluctuation.
In MTJ devices under the field switching design where a write magnetic field is applied to each MTJ cell to write the MTJ cell, each MTJ cell can be positioned at or near the cross point of two separate and mutually orthogonal conductor lines carrying currents. The write magnetic field is jointly generated by the sum of the two magnetic fields that are produced by the currents in the two crossed conductor lines, respectively. This design of using two separate and crossed conductor lines provide a selection mechanism for selecting and addressing MTJ cells for writing data, where the magnetic field from each conductor line alone is controlled to be insufficient to change the magnetization direction of the free layer of an MTJ cell and only provides a half selection for any MTJ cell under its magnetic field. In order to fully select an MTJ cell for switching, the magnetic fields of both crossed conductor lines must be present at a selected MTJ cell at the same time to effectuate the switching of the free layer. In some implementations, the two conductor lines can be configured so that one is located below the MTJ cell and the other is above the MTJ cell. It is also possible to place both conductor lines on one side of the MTJ cell. The two conductor lines sometimes are referred to as a word line (WL) and a bit line (BL). Other terms have also been used for the word line such as the write word line or a digit line. Because these two crossed conductor lines for generating the switching write magnetic field are present and one of the two cross conductor lines is usually placed between the underlying substrate and the MTJ cell layer, each MTJ is usually not directly positioned on top of a metal plug that forms a conductive path for the current flowing through the MTJ but is spatially shifted from the metal plug and is electrically connected to the metal plug via an “in-cell” local interconnecting conductor in an “off-plug” configuration.
In various field-switching MRAM device designs, one of the two orthogonal conductor lines, such as the bit line, is used to provide a bi-directional switching field to switch the magnetization of the MTJ cell while the other conductor line, such as the word line, is used to supply a uni-direction constant current for the switching so that the total magnetic field of the two magnetic fields from the word and bit lines exceeds the switching threshold on the astroid curve in
In the field-switching MTJ device shown in
An MTJ device with an MTJ cell array based on the spin-transfer switching for recording bits in the cells do not require the above two orthogonal conductor lines in each MTJ cell for writing the bit. A single conductor line can be electrically coupled to the MTJ cell to supply a write current that flows through the tunnel junction in the MTJ cell to switch the free layer without an external magnetic field generated by two orthogonal conductor lines. The switching by the spin torque transfer arises from the spin-dependent electron transport properties of ferromagnetic-normal metal multilayers. When a spin-polarized current traverses a magnetic multilayer structure in a direction perpendicular to the layers, the spin angular momentum of electrons incident on a ferromagnetic layer interacts with magnetic moments of the ferromagnetic layer near the interface between the ferromagnetic and normal-metal layers. Through this interaction, the electrons transfer a portion of their angular momentum to the ferromagnetic layer. As a result, a spin-polarized current can switch the magnetization direction of the ferromagnetic layer if the current density is sufficiently high, e.g., approximately 106-108 A/cm2 in some MTJ cells.
Therefore, an MTJ device with an MTJ cell array based on the spin-transfer switching for recording bits in the cells can eliminate the two orthogonal conductor lines in each MTJ cell in the field-switching devices and eliminates the need for spatially separating the MTJ from the underlying metal plug as part of the conductive path for directing a current through the MTJ. In addition, because the switching is caused by the write electric current flowing through the MTJ rather than the external magnetic field at the MTJ, the direction of the conductor line that supplies the write current can be in any orientation and may be chosen in way to minimize the size of the MTJ cell without affecting the switching operation. The examples for MTJ devices based on the spin-transfer switching explore these and other aspects of spin-transfer switching MTJ devices and provide an on-plug MTJ design that directly places each MTJ cell on top of a respective metal plug to minimize the size of each unit cell and thus increase the cell density. This on-plug design simplifies the unit cell design and eliminates the local interconnecting conductor between the MTJ cell and the metal plug in various field-switching MTJ devices based on the off-plug design. Therefore, the minimum size of each unit cell can be reduced for a given technology node to achieve higher unit cell density than what is possible in various field-switching MTJ devices based on the off-plug design.
In such on-plug MTJ devices based on the spin-transfer switching, a single conductor line, e.g., the bit line, is sufficient for supplying the write current for switching each MTJ cell and can be oriented in any direction relative to the long axis of the MTJ cell as the designer desires. In one implementation, the single bit line for each cell may be oriented to be parallel to the long axis of the MTJ cells in order to further reduce the size of each unit cell in an on-plug design.
In fabrication of the above MTJ and other MTJ devices based on the on-plug MTJ design, one technical issue is to form a substantially flat surface over a region with different materials displaced from each other parallel to the flat surface. One example for such a situation is a flat surface over an inter level dielectric (ILD) layer that has at least one embedded metal region such as a metal plug. In fabrication of such a flat surface, the ILD layer and the embedded metal plug are first formed. Next, the ILD layer and the embedded metal plug are polished at the same time by a polishing process such as the chemical mechanical polishing (CMP) to form the flat surface. On top of each polished metal plug, the MTJ is then fabricated.
Various fabrication processes may be used to fabricate the on-plug MTJ devices described in this application.
In the above process, the metal plugs and the ILD layer are planarized at the same time by the same CMP process. However, the metal material for the metal plugs and the dielectric material for the ILD material are different and thus the amounts of the removal of the metal plugs and the ILD material are different. This difference causes a gap at the interface between the metal plug and the ILD material and thus creates a top surface that is uneven at each interface.
Such gaps at the borders of metal plugs can be problematic for fabricating on-plug MTJ cells on top of the metal plugs. In the fabrication process in
It is well known that MTJs are sensitive to any lateral spatial variation in the thickness of the junction layers along the layers and the properties and performance of an MTJ cell, such as the TMR, interlayer coupling field and the MTJ breakdown voltage, may be significantly degraded by such lateral spatial variation. For this reason, it is desirable to locate an on-plug MTJ over an ultra-smooth surface and place the MTJ away from an interface between the metal plug and the ILD material so that the effect of an underlying gap at an interface on the MTJ cell is not significant to the MTJ film performance.
The surface on which the MTJ layers are fabricated can be characterized by the surface flatness and the surface smoothness. In some implementations of the on-plug MTJ design, the top surface of each metal plug needs to meet some threshold for the surface smoothness. For example, the top surface of each metal plug may be required to have a surface roughness less than 3 Å for the root-mean-square (RMS) value in some device designs. In addition, independent from the smoothness requirement, the top surface of each metal plug needs to meet some threshold for the surface flatness. For example, the top surface may be required to have a minimal dishing or warping to be less than 200 Å and preferably less than 100 Å. The process shown in
Therefore, in implementing the fabrication process in
In recognition of the above, an alternative fabrication process for fabricating on-plug MTJ devices is described below to avoid planarizing two different materials in forming the planarized surface on which the MTJ cells or other profile sensitive structures are built on top of the planarized surface. This alternative fabrication process essentially eliminates the cause for the gaps in the process in
In one implementation of this alternative process, a metallization process is performed to construct metal plugs embedded in an ILD layer and a metal layer integrally connected with the embedded metal plugs on top of the ILD layer to cover both the metal plugs and the ILD layer. Next, the metal layer is thinned by, e.g., CMP, to form a thin and polished metal layer on top of the ILD layer and the underlying and connected metal plugs. This thinning process is conducted without exposing the ILD layer so that only the same metal material is lapped during the CMP process. As a result, the thin and polished metal layer on top of the metal plugs and the ILD material is smooth and is free of any gaps caused by polishing the metal and the ILD material at the same time. Next, the MTJ layers are deposited on top of the entire thin and polished metal layer. The MTJ layers and the underlying metal layer on top of the ILD and metal plugs are subsequently patterned to form separated MTJ cells that are directly located on top of the metal plugs, respectively. The bit line and other structures are also formed.