Patent Application
20230393468
The present disclosure relates to an on-press development type planographic printing plate precursor, a method of preparing a planographic printing plate, a planographic printing method, and a coloring agent.
Generally, a planographic printing plate consists of a lipophilic image area that receives ink in a printing process and a hydrophilic non-image area that receives dampening water. Planographic printing (lithographic printing) is a method exploiting the mutual repulsion of water and oil-based ink, in which the lipophilic image area and the hydrophilic non-image area of a planographic printing plate are used as an ink-receiving portion and a dampening water-receiving portion (non-ink-receiving portion) respectively, the adhesiveness of ink is varied within the surface of the planographic printing plate such that only the image area receives the ink, and then printing is performed by the transfer of the ink to a printing substrate such as paper.
In the related art, in order to prepare this planographic printing plate, a planographic printing plate precursor (PS plate) has been widely used which is obtained by providing a lipophilic photosensitive resin layer (image-recording layer) on a hydrophilic support. Generally, a planographic printing plate is obtained by a plate making method of exposing a planographic printing plate precursor through an original picture such as a lith film, then keeping a portion of an image-recording layer that will be an image area while removing other unnecessary portions of the image-recording layer by dissolving such portions in an alkaline developer or an organic solvent, and forming a non-image area by exposing a surface of the hydrophilic support.
In response to the intensifying interest in the global environment, an environmental issue of waste liquid generated by wet treatments such as a development treatment has gathered more attention.
Regarding the environmental issue described above, an attempt is made to simplify development or plate making or to remove treatments. As one of simple preparation methods, a method called “on-press development” is being carried out. That is, on-press development is a method of exposing a planographic printing plate precursor, then immediately mounting the precursor on a printer without performing development of the related art, and removing an unnecessary portion of the image-recording layer at an early stage of the ordinary printing step.
In the present disclosure, a planographic printing plate precursor that can be used for such on-press development is called “on-press development type planographic printing plate precursor”
Examples of the photosensitive composition in the related art include those described in US2005/0130064A.
US2005/0130064A describes a photosensitive composition containing 0.01% by mass to 5% by mass of curcumin.
An object of an embodiment of the present disclosure is to provide an on-press development type planographic printing plate precursor excellent in ink turbidity suppressiveness and temporal visibility.
An object of another embodiment of the present disclosure is to provide a method of preparing a planographic printing plate and a planographic printing method in which the on-press development type planographic printing plate precursor is used.
An object of a still another embodiment of the present disclosure is to provide a coloring agent that exhibits excellent coloring properties to an organic compound having a group 13 element.
Means for achieving the above objects include the following aspects.
In Formula 1 and Formula 2, each of R1 to R7 independently represents a hydrogen atom or a monovalent organic group, each of L1 and L2 represents a divalent organic group, two or more groups among L1, R2, and R3 may be linked to each other to form a ring structure, two or more groups among L2, R4, and R6 may be linked to each other to form a ring structure, and two or more groups among L2, R5, and R7 may be linked to each other to form a ring structure.
In Formula (II), XA represents a halogen atom, and RA represents an aryl group.
In Formula 1 and Formula 2, R1 to R7 each independently represent a hydrogen atom or a monovalent organic group, L1 and L2 represent a divalent organic group, two or more groups among L1, R2, and R3 may be linked to each other to form a ring structure, two or more groups among L2, R4, and R6 may be linked to each other to form a ring structure, and two or more groups among L2, R5, and R7 may be linked to each other to form a ring structure.
According to an embodiment of the present disclosure, it is possible to provide an on-press development type planographic printing plate precursor excellent in ink turbidity suppressiveness and temporal visibility.
According to another embodiment of the present disclosure, it is possible to provide a method of preparing a planographic printing plate and a planographic printing method using a planographic printing plate in which the on-press development type planographic printing plate precursor is used.
According to still another embodiment of the present disclosure, it is possible to provide a coloring agent that exhibits excellent coloring properties to an organic compound having a group 13 element.
Hereinafter, the contents of the present disclosure will be specifically described. The following configuration requirements will be described on the basis of typical embodiments of the present disclosure, but the present disclosure is not limited to such embodiments.
In the present specification, a numerical range expressed using “to” includes numerical values listed before and after “to” as the lower limit and the upper limit.
In addition, in the present specification, in a case where there is no description regarding whether a group (atomic group) is substituted or unsubstituted, such a group includes both a group having no substituent and a group having a substituent. For example, “alkyl group” includes not only an alkyl group having no substituent (unsubstituted alkyl group) but also an alkyl group having a substituent (substituted alkyl group).
In the present specification, “(meth)acryl” is a term used to explain a concept including both the acryl and methacryl, and “(meth)acryloyl” is a term used to explain a concept including both the acryloyl and methacryloyl.
In addition, the term “step” in the present specification means not only an independent step but also a step that cannot be clearly differentiated from other steps as long as the intended goal of the step is achieved. In the present disclosure, “% by mass” has the same definition as “% by weight”, and “part by mass” has the same definition as “part by weight”.
In the present disclosure, unless otherwise specified, as each component contained in a composition or each constitutional unit contained in a polymer, one component or one constitutional unit may be used alone, or two or more components or two or more constitutional units may be used in combination.
Furthermore, in the present disclosure, in a case where there is a plurality of substances corresponding to each component in a composition, or in a case where there is a plurality of constitutional units corresponding to each constitutional unit in a polymer, unless otherwise specified, the amount of each component in the composition or the amount of each constitutional unit in the polymer means the total amount of the plurality of corresponding substances present in the composition or the total amount of the plurality of corresponding constitutional units present in the polymer.
In the present disclosure, a combination of two or more preferred aspects is a more preferred aspect.
In addition, in the present disclosure, unless otherwise specified, each of the weight-average molecular weight (Mw) and number-average molecular weight (Mn) is a molecular weight that is detected using a gel permeation chromatography (GPC) analysis device using TSKgel GMHxL, TSKgel G4000HxL, and TSKgel G2000HxL (trade names, manufactured by Tosoh Corporation) as columns, tetrahydrofuran (THF) as a solvent, and a differential refractometer, and expressed in terms of polystyrene as a standard substance.
In the present disclosure, the term “planographic printing plate precursor” refers not only to a planographic printing plate precursor but also to a key plate precursor. In addition, the term “planographic printing plate” refers not only to a planographic printing plate prepared by performing operations such as exposure and development as necessary on a planographic printing plate precursor but also to a key plate. The key plate precursor is not necessarily subjected to the operations such as exposure and development. The key plate refers to a planographic printing plate precursor to be mounted on a plate cylinder that is not used, in a case where monochromatic or dichromatic printing is carried out on a part of paper during, for example, color newspaper printing.
In the present disclosure, “excellent in printing durability” means that a large number of sheets can be printed using a planographic printing plate, and printing durability exhibited in a case where an ultraviolet-curable ink (UV ink) used as a printing ink will be also described as “UV printing durability” hereinafter.
Hereinafter, the present disclosure will be specifically described.
(On-Press Development Type Planographic Printing Plate Precursor)
The on-press development type planographic printing plate precursor according to the present disclosure has a support and an image-recording layer on the support, in which the image-recording layer contains a compound represented by Formula 1 or Formula 2 and an organic compound having a group 13 element.
In Formula 1 and Formula 2, R1 to R7 each independently represent a hydrogen atom or a monovalent organic group, Lr and L2 represent a divalent organic group, two or more groups among L1, R2, and R3 may be linked to each other to form a ring structure, two or more groups among L2, R4, and R6 may be linked to each other to form a ring structure, and two or more groups among L2, R5, and R7 may be linked to each other to form a ring structure.
The on-press development type planographic printing plate precursor according to the present disclosure may be a negative tone planographic printing plate precursor or a positive tone planographic printing plate precursor, and is preferably a negative tone planographic printing plate precursor.
The inventors of the present invention have found that sometimes the on-press development type planographic printing plate precursor of the related art makes the color of an ink in a printed image turbid.
As a result of intensive studies, the inventors of the present invention have found that adopting the above constitution makes it possible to provide an on-press development type planographic printing plate precursor excellent in ink turbidity suppressiveness.
The detailed mechanism that brings about the aforementioned effect is unclear, but is assumed to be as below.
The compound represented by Formula 1 or Formula 2 is presumed to function as a coloring agent. However, being a non-conjugated keto-type compound, the compound itself represented by Formula 1 or Formula 2 is less colored. Therefore, presumably, even in a case where the compound represented by Formula 1 or Formula 2 contained in the image-recording layer is eluted into the ink, the tint of the ink may be little affected, and the turbidity of the ink could be suppressed.
In addition, presumably, in a case where the image-recording layer of the on-press development type planographic printing plate precursor according to the present disclosure contains the compound represented by Formula 1 or Formula 2 and the organic compound having a group 13 element, the compound represented by Formula 1 or Formula 2 may capture the organic compound having a group 13 element or a decomposition product generated from the organic compound having a group 13 element by exposure and may be altered into an enol-type compound to bring color, and color development or color-alteration may more significantly occur in exposed portions, which may also lead to excellent temporal visibility of the exposed portions.
Hereinafter, each of the configuration requirements in the planographic printing plate precursor according to the present disclosure will be specifically described.
<Image-Recording Layer>
The on-press development type planographic printing plate precursor according to the present disclosure has an image-recording layer, in which the image-recording layer contains a compound represented by Formula 1 or Formula 2 and an organic compound having a group 13 element.
The image-recording layer used in the present disclosure is preferably a negative tone image-recording layer and more preferably a water-soluble or water-dispersible negative tone image-recording layer.
In the planographic printing plate precursor according to the present disclosure, from the viewpoint of on-press developability, a non-exposed portion of the image-recording layer is preferably removable by at least any of dampening water or printing ink.
[Compound Represented by Formula 1 or Formula 2]
The image-recording layer contains a compound represented by Formula 1 or Formula 2.
The compound represented by Formula 1 or Formula 2 is preferably a coloring agent, and more preferably a compound that has a coloring reaction with the organic compound having a group 13 element or with a decomposition product generated from the organic compound having a group 13 element by exposure.
“Coloring reaction” in the present disclosure is a chemical reaction accompanying a phenomenon of color development or color-alteration.
The decomposition product generated by the exposure includes not only a decomposition product decomposed by the exposure but also a compound generated by the further decomposition or modification of the decomposition product.
From the viewpoint of visibility of exposed portions, the coloring reaction is preferably a complex-forming reaction, and more preferably a boron complex-forming reaction.
An example of the coloring reaction will be shown below. What is shown below is a coloring reaction that occurs in a case where C-1 is used as the compound represented by Formula 1 or Formula 2, and sodium tetraphenylborate, which is the compound having a group 13 element, decomposes to triphenylborane (BPh3) as a decomposition product generated by the exposure of the image-recording layer and generates boric acid. Due to keto-enol tautomerism, an enol tautomer of C-1 is generated as equilibrium. The reaction between the enol tautomer and the boric acid generates the following boron complex (Complex), and a coloring reaction from C-1 (colorless to pale yellow) to the following boron complex (orange to red) occurs.
What is shown below is an example where hydrolysis proceeds to generate boric acid. For example, C-1 may form a complex together with diphenyl monohydroxyborate, monophenyl dihydroxyborate, or the like, or triphenylborane may be coordinated as a zero-valent ligand to enol-type C-1 to form a complex.
From the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, the compound represented by Formula 1 or Formula 2 is preferably a compound that has one or more 1,3-diimine structures, one or more ketone structures having a heteroaromatic group with a nitrogen atom on an ortho position on a R position, or one or more methine structures having two or more heteroaromatic groups with a nitrogen atom on an ortho position, more preferably a compound that has one or more 1,3-diimine structures or one or more ketone structures having a heteroaromatic group with a nitrogen atom on an ortho position on a β position, and particularly preferably a compound that has one or more ketone structures having a heteroaromatic group with a nitrogen atom on an ortho position on a β position.
Examples of the compound represented by Formula 1 or Formula 2 also include a compound that has one or more enamine structures having a heteroaromatic group with a nitrogen atom on an ortho position or one or more imine structures having a heteroaromatic group with a nitrogen atom on an ortho position on a β position.
From the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, the heteroaromatic group having a nitrogen atom on an ortho position is preferably a 2-pyrazyl group, a 5-methyl-2-pyrazyl group, a 2-pyrimidyl group, a 2-pyridyl group, a 4-trifluoromethyl-2-pyridyl group, a 4-trifluoromethyl-6-chloro-2-pyridyl group, a 4,6-bistrifluoromethyl-2-pyridyl group, a 2-benzothiazolyl group, a 2-naphthothiazolyl group, a 2-quinoxalyl group, or a 3-methyl-2-quinoxalyl group, more preferably a 2-pyrazyl group, a 5-methyl-2-pyrazyl group, a 2-pyrimidyl group, a 2-pyridyl group, a 4-trifluoromethyl-2-pyridyl group, a 4-trifluoromethyl-6-chloro-2-pyridyl group, or a 4,6-bistrifluoromethyl-2-pyridyl group. It is more preferable, and it is particularly preferable that it is a 2-pyrazyl group, and particularly preferably a 5-methyl-2-pyrazyl group or a 2-pyrimidyl group.
In addition, the compound represented by Formula 1 or Formula 2 may be a salt or hydrate.
In a case where the compound represented by Formula 1 or Formula 2 reacts with a decomposition product generated by the exposure of the image-recording layer and forms a complex, in the complex, the compound represented by Formula 1 or Formula 2 may be a monodentate ligand or a polydentate ligand. From the viewpoint of complex forming properties, ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, the compound represented by Formula 1 or Formula 2 is preferably a polydentate ligand, more preferably a ligand having a denticity of 2 to 6, even more preferably a ligand having a denticity of 2 to 4, particularly preferably a ligand having a denticity of 2 or 3, and most preferably a bidentate ligand.
Furthermore, in the on-press development type planographic printing plate precursor according to the present disclosure, after exposure, the compound represented by Formula 1 or Formula 2 preferably reacts with the decomposition product generated by the exposure of the organic compound having a group 13 element and forms a complex that has the compound represented by Formula 1 or Formula 2 as a zero-valent ligand or an anion formed by the removal of one hydrogen atom from the compound represented by Formula 1 or Formula 2 as a monovalent ligand, and more preferably reacts with the decomposition product generated by the exposure of the image-recording layer and forms a complex that has an anion formed by the removal of one hydrogen atom from the compound represented by Formula 1 or Formula 2 as a monovalent ligand.
From the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, it is preferable that the compound represented by Formula 1 or Formula 2 include a compound having a ring structure.
Furthermore, from the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, it is more preferable that the compound represented by Formula 1 or Formula 2 include a compound having two or more ring structures.
In addition, from the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, it is more preferable that the compound represented by Formula 1 or Formula 2 include a compound having an aromatic ring on which an electron-donating group is attached.
In Formula 1, two or more groups among L1, R2, and R3 may be bonded to each other to form a ring structure.
In Formula 2, two or more groups among L2, R4, and R6 may be bonded to each other to form a ring structure, and two or more groups among L2, R5, and R7 may be bonded to each other to form a ring structure.
Furthermore, the ring structure is preferably an aromatic ring structure or a heteroaromatic ring structure.
From the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, R1 in Formula 1 is preferably a monovalent organic group having an aromatic ring, more preferably an aryl group, and particularly preferably a phenyl group, a 4-dialkylaminophenyl group, or a 4-diarylaminophenyl group.
In addition, from the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, R1 in Formula 1 is preferably an aryl group having an electron-donating group.
The carbon number (number of carbon atoms) of R1 in Formula 1 is preferably 6 to 50, more preferably 6 to 20, and particularly preferably 8 to 20.
From the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, it is preferable that R2 and R3 in Formula 1 be bonded to each other to form a ring structure.
From the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, the ring structure formed of R2 and R3 bonded to each other is preferably a pyridine ring structure, a pyrazine ring structure, a pyrimidine ring structure, a benzothiazole ring structure, or a naphthothiazole ring structure, more preferably a pyridine ring structure, a pyrazine ring structure, or a pyrimidine ring structure, even more preferably a pyrazine ring structure or a pyrimidine ring structure, and particularly preferably a pyrazine ring structure.
The ring structure may have a substituent, and examples thereof include a halogen atom, an alkyl group, an amino group, an alkylamino group, a dialkylamino group, an alkylarylamino group, a diarylamino group, an alkoxy group, a cyano group, an alkoxycarbonyl group, an acyl group, an acyloxy group, and the like. In addition, the above substituents may be substituted with substituents.
In a case where R2 and R3 in Formula 1 are not bonded to each other to form a ring structure, the following aspects are preferable.
From the viewpoint of visibility of exposed portions, R2 in Formula 1 is preferably a monovalent organic group, more preferably an alkyl group or an aryl group, and particularly preferably an aryl group.
From the viewpoint of visibility of exposed portions, R3 in Formula 1 is preferably a hydrogen atom, an alkyl group, or an aryl group.
The carbon number of R2 in Formula 1 is preferably 1 to 50, and more preferably 6 to 20.
The carbon number of R3 in Formula 1 is preferably 0 to 50, and more preferably 0 to 20.
From the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, L1 in Formula 1 is preferably an alkylene group or an alkylene group having an acyloxy group, more preferably a methylene group or a methylene group having an acyloxy group, and particularly preferably a methylene group.
From the viewpoint of visibility of exposed portions and temporal visibility of exposed portions, the acyloxy group is preferably an acyloxy group having a carbon number of 1 to 10, more preferably an acyloxy group having a carbon number of 1 to 4, and particularly preferably an acetoxy group.
From the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, R4 and R5 in Formula 2 preferably each independently represent a monovalent organic group having an aromatic ring, more preferably each independently represent an aryl group, and particularly preferably each independently represent a phenyl group, a 4-dialkylaminophenyl group, or a 4-trifluoromethylphenyl group.
In addition, from the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, the aryl group is preferably an aryl group having an electron-donating group.
R4 and R5 in Formula 2 preferably each independently have a carbon number of 6 to 50, more preferably each independently have a carbon number of 6 to 20, and particularly preferably each independently have a carbon number of 8 to 20.
From the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, in Formula 2, it is preferable that R4 and R6 be bonded to each other to form a ring structure and R5 and R7 be bonded to each other to form a ring structure.
From the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, the ring structure formed of R4 and R6 bonded to each other or the ring structure formed of R5 and R7 bonded to each other is preferably a pyridine ring structure, a pyrazine ring structure, a pyrimidine ring structure, a benzothiazole ring structure, or a naphthothiazole ring structure, more preferably a pyridine ring structure, a pyrazine ring structure, or a pyrimidine ring structure, and particularly preferably a pyridine ring structure.
In addition, the ring structures may have the substituents described above.
In a case where R4 and R6 or R5 and R7 in Formula 2 are not bonded to each other to form a ring structure, the following aspects are preferable.
R4 and R5 in Formula 2 preferably each independently represent a monovalent organic group, more preferably each independently represent an alkyl group or an aryl group, and particularly preferably each independently represent an aryl group.
From the viewpoint of visibility of exposed portions, R6 and R7 in Formula 2 preferably each independently represent a hydrogen atom, an alkyl group, or an aryl group.
R4 and R5 in Formula 2 preferably each independently have a carbon number of 1 to 50, and more preferably each independently have a carbon number of 6 to 20.
R6 and R7 in Formula 2 preferably each independently have a carbon number of 0 to 50, and more preferably each independently have a carbon number of 0 to 20.
From the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, L2 in Formula 2 is preferably an alkylene group or an alkylene group having a cyano group, and more preferably a methylene group or a methylene group having a cyano group.
The compound represented by Formula 1 may be a multimer, and in this case, R2 in the compound represented by Formula 1 is preferably -linking group-C(═NR3)-L1-C(═O)—R1. Furthermore, in a case where the compound represented by Formula 1 forms a multimer and preferably forms a dimer, two R2's and two R3's are preferably bonded to each other to form a heteroaromatic ring having two or more nitrogen atoms, and more preferably bonded to each other to form a pyrazine ring.
The compound represented by Formula 2 may be a multimer, and in this case, R5 in the compound represented by Formula 2 is preferably -linking group-C(═NR7)-L2-C(═NR6)—R4. Furthermore, in a case where the compound represented by Formula 2 forms a multimer and preferably forms a dimer, two R5's and two R7's are preferably bonded to each other to form a heteroaromatic ring having two or more nitrogen atoms, and more preferably bonded to each other to form a pyrazine ring.
From the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, 1 mol % or more of the compound represented by Formula 1 or Formula 2 at 25° C. is preferably a keto isomer or an imine isomer, and the proportion is more preferably 10 mol % or more, even more preferably 20 mol % or more, and particularly preferably 50 mol % or more and 100 mol % or less.
In the present disclosure, the proportion of a keto isomer or an imine isomer is measured by the following method.
A sample (1.0 mg) is dissolved in 0.5 mL of deuterochloroform CDCl3 (manufactured by FUJIFILM Wako Pure Chemical Corporation) and subjected to NMR (manufactured by Bruker) spectroscopy under the condition of 25° C. The CH2 or CHR group of the keto isomer (R represents an arbitrary group depending on the compound contained in the sample to be measured) and the CH group of the enol isomer have different peaks. Therefore, the proportion (mol %) of the keto isomer is calculated from the integration ratio of each group. The proportion of the imine isomer is also calculated by the same method.
From the viewpoint of complex forming properties, ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, the molecular weight of the compound represented by Formula 1 or Formula 2 is preferably 200 to 1,500, more preferably 200 to 800, even more preferably 200 to 600, and particularly preferably 250 to 600.
Specifically, suitable examples of the compound represented by Formula 1 or Formula 2 include the following C-1 to C-17. Note that Me represents a methyl group, Ph represents a phenyl group, and t-Bu represents a t-butyl group.
One compound represented by Formula 1 or Formula 2 may be used alone, or two or more compounds represented by Formula 1 or Formula 2 may be used in combination.
Furthermore, one complex described above may be formed, or two or more complexes described above may be formed.
From the viewpoint of complex forming properties, ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, the content of the compound represented by Formula 1 or Formula 2 with respect to the total mass of the image-recording layer is preferably from 0.001% by mass to 5% by mass, more preferably from 0.01% by mass to 3% by mass, even more preferably from 0.05% by mass to 2.5% by mass, and particularly preferably from 0.05% by mass to 1.0% by mass.
From the viewpoint of complex forming properties, ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, in the image-recording layer, a molar ratio of a content MC of the compound represented by Formula 1 or Formula 2 to a content MD1 of the organic compound having a group 13 element that will be described later is preferably MC/MD1=0.001 to 1.5, more preferably MC/MDI=0.01 to 1, and particularly preferably MC/MDI=0.05 to 0.8.
[Organic Compound Having Group 13 Element]
It is preferable that the image-recording layer in the planographic printing plate precursor according to the present disclosure contain an organic compound having a group 13 element, and contain an electron-donating polymerization initiator (also called “polymerization aid”) as the organic compound having a group 13 element.
The electron-donating polymerization initiator is a compound which donates one electron by intermolecular electron migration to an orbit of an infrared absorber that has lost one electron in a case where electrons of the infrared absorber are excited or perform intramolecular migration by exposure to infrared, and thus generates polymerization initiation species such as radicals.
The electron-donating polymerization initiator is preferably an electron-donating radical polymerization initiator.
From the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, the organic compound having a group 13 element which is preferably the aforementioned electron-donating polymerization initiator preferably includes a boron compound, more preferably includes a borate compound, even more preferably includes a tetraaryl borate salt compound, and particularly preferably includes a tetraphenylborate salt compound.
From the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, it is preferable that the electron-donating polymerization initiator have an electron withdrawing group.
From the viewpoint of printing durability and visibility, the borate salt compound is preferably a tetraaryl borate salt compound or a monoalkyl triaryl borate salt compound, and more preferably a tetraaryl borate salt compound.
From the viewpoint of printing durability and visibility, the borate salt compound is preferably a tetraaryl borate salt compound having one or more electron withdrawing groups, and more preferably a tetraaryl borate salt compound having one electron withdrawing group in each aryl group.
From the viewpoint of decomposition properties and visibility, examples of the electron withdrawing group include a halogen atom, an alkyl halide group, an acyl group, a carboxy group, and the like.
A countercation that the borate salt compound has is not particularly limited, but is preferably an alkali metal ion or a tetraalkyl ammonium ion and more preferably a sodium ion, a potassium ion, or a tetrabutylammonium ion.
The countercation that the borate salt compound has may also be a cationic polymethine colorant in the infrared absorber described in the present specification. For example, the aforementioned borate salt compound may be used as the countercation of the cyanine dye.
Specifically, preferred examples of the borate salt compound include sodium tetraphenyl borate.
Specifically, as the electron-donating polymerization initiator, for example, the following B-1 to B-9 are preferable. It goes without saying that the present disclosure is not limited thereto. In the following chemical formulas, Ph represents a phenyl group, and Bu represents an n-butyl group.
From the viewpoint of sensitivity improvement, the highest occupied molecular orbital (HOMO) of the electron-donating polymerization initiator is preferably −6.00 eV or more, more preferably −5.95 eV or more, even more preferably −5.93 eV or more, and particularly preferably more than −5.90 eV.
The upper limit of HOMO is preferably −5.00 eV or less, and more preferably −5.40 eV or less.
One organic compound having a group 13 element may be used alone, or two or more organic compounds having group 13 elements may be used in combination.
From the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, the content of the organic compound having a group 13 element which is preferably the aforementioned electron-donating polymerization initiator with respect to the total mass of the image-recording layer is preferably from 0.01% by mass to 30% by mass, more preferably from 0.05% by mass to 25% by mass, and even more preferably from 0.1% by mass to 20% by mass.
From the viewpoint of UV printing durability, the content of the organic compound having a group 13 element in the image-recording layer, which is preferably the content of the aforementioned electron-donating polymerization initiator, is preferably higher than the content of the infrared absorber, more preferably 1.05 to 5 times the content of the infrared absorber, and particularly preferably 1.1 to 3 times the content of the infrared absorber.
In the present disclosure, the organic compound having a group 13 element may be a compound in the form of conjugate salt of an electron-donating polymerization initiator and the electron-accepting polymerization initiator that will be described later.
For example, in the present disclosure, the polymerization initiator is preferably a compound in the form of a conjugate salt of an anion in the electron-donating polymerization initiator and a cation in the electron-accepting polymerization initiator, more preferably a compound in the form of a conjugate salt of an onium cation and a borate anion, even more preferably a compound in the form of a conjugate salt of an iodonium cation or sulfonium cation and a borate anion, and particularly preferably a compound in the form of a conjugate salt of a diaryliodonium cation or a triarylsulfonium cation and a tetraarylborate anion.
Preferred aspects of the anion in the electron-donating polymerization initiator and the cation in the electron-accepting polymerization initiator are the same as the preferred aspects of the anion in the aforementioned electron-donating polymerization initiator and the cation in the aforementioned electron-accepting polymerization initiator.
In a case where the image-recording layer contains an anion as an electron-donating polymerization initiator and a cation as an electron-accepting polymerization initiator (that is, in a case where the image-recording layer contains a compound in the form of a conjugate salt described above), the image-recording layer is regarded as containing an electron-accepting polymerization initiator and an electron-donating polymerization initiator.
The compound in the form of a conjugate salt of an electron-donating polymerization initiator and an electron-accepting polymerization initiator may be used as an electron-donating polymerization initiator or an electron-accepting polymerization initiator.
The compound in the form of a conjugate salt of an electron-donating polymerization initiator and an electron-accepting polymerization initiator may be used in combination with the aforementioned electron-donating polymerization initiator or used in combination with the aforementioned electron-accepting polymerization initiator.
The image-recording layer of the present disclosure further contains an infrared absorber and an electron-donating polymerization initiator. From the viewpoint of sensitivity improvement and printing durability, HOMO of the infrared absorber—HOMO of the electron-donating polymerization initiator is preferably 0.70 eV or less, more preferably 0.60 eV or less, even more preferably 0.50 eV or less, and particularly preferably 0.50 eV to −0.10 eV.
The negative sign means that HOMO of the electron-donating polymerization initiator is higher than HOMO of the infrared absorber.
In the present disclosure, the energy of molecular orbital (MO) such as the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) is calculated by the following methods.
First, free counterions in the compound as a calculation object are excluded from the calculation object. For example, for a cationic electron-accepting polymerization initiator and a cationic infrared absorber, counteranions are excluded from the calculation object, and for an anionic electron-donating polymerization initiator, countercations are excluded from the calculation object. “Free” mentioned herein means that the compound as an object and the counterions thereof are not covalently linked to each other.
The structural optimization is carried out by DFT (B3LYP/6-31G(d)) using quantum chemical calculation software Gaussian 16.
The MO energy is calculated by DFT (B3LYP/6-31+G(d,p)/PCM (solvent=methanol)) with quantum chemical calculation software Gaussian16 by using the optimum structure obtained by the structural optimization. For an iodine-containing compound, the MO energy is calculated under the condition of DFT (B3LYP/DGDZVP/PCM (solvent=methanol)).
The optimum structure mentioned herein means a structure in which the total energy obtained by DFT calculation is the most stable. The most stable structure is found by repeating the structural optimization as necessary.
By the following formula, the MO energy Ebare (unit: hartree) obtained by the above MO energy calculation is converted into Escaled (unit: eV) used as the values of HOMO and LUMO in the present disclosure.
Escaled=0.823168×27.2114×Ebare−1.07634 [Calculation formula for HOMO]
Escaled=0.820139×27.2114×Ebare−1.086039 [Calculation formula for LUMO]
27.2114 is simply a coefficient for converting hartree into eV, and 0.823168 and −1.07634 used for calculating HOMO and 0.820139 and −1.086039 used for calculating LUMO are adjustment coefficients. These are determined such that the calculated values of HOMO and LUMO of the compound as a calculation object match the measured values.
[Electron-Accepting Polymerization Initiator]
The image-recording layer in the present disclosure preferably further contains a polymerization initiator and more preferably further contains an electron-accepting polymerization initiator as the polymerization initiator.
The electron-accepting polymerization initiator is a compound which accepts an electron by intermolecular electron migration in a case where electrons of an infrared absorber are excited by exposure to infrared, and generates a polymerization initiation species such as radicals.
The electron-accepting polymerization initiator is a compound that generates a polymerization initiation species such as a radical or a cation by either or both of light energy and heat energy, and can be appropriately selected from known thermal polymerization initiators, compounds having a bond that requires low bond dissociation energy, photopolymerization initiators, and the like.
The electron-accepting polymerization initiator is preferably a radical polymerization initiator and more preferably an onium salt compound.
In addition, as the electron-accepting polymerization initiator, an infrared-ray-sensitive polymerization initiator is preferable.
From the viewpoint of sensitivity improvement and UV printing durability, the electron-accepting polymerization initiator is preferably an iodonium salt compound or a compound having an alkyl halide group, and more preferably a compound having an alkyl halide group.
In addition, from the viewpoint of sensitivity improvement and UV printing durability, the compound having an alkyl halide group is preferably a compound having a perhalogenoalkylsulfonyl group, more preferably a compound having a trihalogenomethylsulfonyl group, and particularly preferably a compound having a tribromomethylsulfonyl group.
Among the above electron-accepting polymerization initiators, from the viewpoint of curing properties, an oxime ester compound and an onium salt compound are preferable. Particularly, from the viewpoint of printing durability, an iodonium salt compound, a sulfonium salt compound, or an azinium salt compound is preferable, an iodonium salt compound or a sulfonium salt compound is more preferable, and an iodonium salt compound is particularly preferable.
Specific examples of these compounds will be shown below, but the present disclosure is not limited thereto.
As the iodonium salt compound, for example, a diaryliodonium salt compound is preferable. Particularly, an electron-donating group, for example, a diphenyl iodonium salt compound substituted with an electron-donating group such as an alkyl group or an alkoxyl group is more preferable. Furthermore, an asymmetric diphenyl iodonium salt compound is preferable. Specific examples thereof include diphenyliodonium=hexafluorophosphate, 4-methoxyphenyl-4-(2-methylpropyl)phenyliodonium=hexafluorophosphate, 4-(2-methylpropyl)phenyl-p-tolyliodonium=hexafluorophosphate, 4-hexyloxyphenyl-2,4,6-trimethoxyphenyl iodonium=hexafluorophosphate, 4-hexyloxyphenyl-2,4-diethoxyphenyl iodonium=tetrafluoroborate, 4-octyloxyphenyl-2,4,6-trimethoxyphenyl iodonium=1-perfluorobutane sulfonate, 4-octyloxyphenyl-2,4,6-trimethoxyphenyliodonium=hexafluorophosphate, and bis(4-t-butylphenyl)iodonium=hexafluorophosphate.
Examples of counteranions of the iodonium salt compound and the sulfonium salt compound include a sulfonate anion, a carboxylate anion, a tetrafluoroborate anion, a hexafluorophosphate anion, a p-toluene sulfonate anion, a tosylate anion, a sulfonamide anion, and a sulfonimide anion.
Among the above, a sulfonamide anion or a sulfonimide anion is preferable, and a sulfonimide anion is more preferable.
As the sulfonamide anion, an aryl sulfonamide anion is preferable.
As the sulfonimide anion, a bisaryl sulfonimide anion is preferable.
Specific examples of the sulfonamide anion and the sulfonimide anion include those described in WO2019/013268A.
From the viewpoint of temporal visibility after exposure, developability, and UV printing durability of the planographic printing plate to be obtained, the aforementioned electron-accepting polymerization initiator preferably includes a compound represented by Formula (II) or Formula (III), and particularly preferably includes a compound represented by Formula (II).
In Formula (II) and Formula (III), XA represents a halogen atom, and RA, RA1, and RA2 each independently represent a monovalent hydrocarbon group having a carbon number of 1 to 20.
RA in Formula (II) is preferably an aryl group.
Examples of XA in Formula (II) and Formula (III) include a fluorine atom, a chlorine atom, a bromine atom, and an iodine atom. Among these, a chlorine atom or a bromine atom is preferable because these have excellent sensitivity, and a bromine atom is particularly preferable.
RA, RA1, and RA2 in Formula (II) and Formula (III) preferably each independently represent an aryl group. Particularly, from the viewpoint of excellent balance between sensitivity and storage stability, RA, RA1, and RA2 more preferably each independently represent an aryl group substituted with an amide group.
The aforementioned electron-accepting polymerization initiator particularly preferably includes a compound represented by Formula (IV).
In Formula (IV), XA represents a halogen atom, RA3 and RA4 each independently represent a hydrogen atom or a monovalent hydrocarbon group having a carbon number of 1 to 20, and pA and qA each independently represent an integer of 1 to 5. Here, pA+qA=2 to 6.
Specific examples of the electron-accepting polymerization initiator include compounds represented by the following formulas. However, the present disclosure is not limited thereto.
From the viewpoint of improving sensitivity, the lowest unoccupied molecular orbital (LUMO) of the electron-accepting polymerization initiator is preferably −3.00 eV or less, and more preferably −3.02 eV or less.
The lower limit of LUMO is preferably −3.80 eV or more, and more preferably −3.50 eV or more.
One electron-accepting polymerization initiator may be used alone, or two or more electron-accepting polymerization initiators may be used in combination.
The content of the electron-accepting polymerization initiator with respect to the total mass of the image-recording layer is preferably 0.1% by mass to 50% by mass, more preferably 0.5% by mass to 30% by mass, and particularly preferably 0.8% by mass to 20% by mass.
The image-recording layer of the present disclosure further contains an infrared absorber and an electron-accepting polymerization initiator. From the viewpoint of sensitivity improvement and printing durability, LUMO of the electron-accepting polymerization initiator—LUMO of the infrared absorber is preferably 1.00 eV or less, more preferably 0.80 eV or less, even more preferably 0.70 eV or less, particularly preferably 0.70 eV to −0.10 eV, and most preferably 0.70 eV to 0.30 eV.
The negative sign means that LUMO of the infrared absorber is higher than LUMO of the electron-accepting polymerization initiator.
[Infrared Absorber]
It is preferable that the image-recording layer in the present disclosure further contain an infrared absorber.
The infrared absorber is not particularly limited, and examples thereof include pigments and dyes.
As the dye that is used as the infrared absorber, it is possible to use commercially available dyes and known dyes described in publications, for example, “Dye Handbooks” (edited by the Society of Synthetic Organic Chemistry, Japan, 1970). Specific examples thereof include dyes such as an azo dye, a metal complex azo dye, a pyrazolone azo dye, a naphthoquinone dye, an anthraquinone dye, a phthalocyanine dye, a carbonium dye, a quinoneimine dye, a methine dye, a cyanine dye, a squarylium colorant, a pyrylium salt, and a metal thiolate complex.
Among these dyes, for example, a cyanine dye, a squarylium colorant, a pyrylium salt, a nickel thiolate complex, and an indolenine cyanine dye are preferable, and a cyanine dye or an indolenine cyanine dye is more preferable. Among these, a cyanine dye is particularly preferable.
The aforementioned infrared absorber is preferably a cationic polymethine colorant having an oxygen atom, a nitrogen atom, or a halogen atom at the meso-position. Preferred examples of the cationic polymethine colorant include a cyanine dye, a pyrylium colorant, a thiopyrylium colorant, an azulenium colorant, and the like. From the viewpoint of ease of availability, solubility in a solvent during an introduction reaction, and the like, a cyanine dye is preferable.
Specific examples of the cyanine dye include the compounds described in paragraphs “0017” to “0019” of JP2001-133969A and the compounds described in paragraphs “0016” to “0021” of JP2002-023360A and paragraphs “0012” to “0037” of JP2002-040638A. As the cyanine dye, for example, the compounds described in paragraphs “0034” to “0041” of JP2002-278057A and paragraphs “0080” to “0086” of JP2008-195018A are preferable, and the compounds described in paragraphs “0035” to “0043” of JP2007-90850A and the compounds described in paragraphs “0105” to “0113” of JP2012-206495A are particularly preferable.
Furthermore, the compounds described in paragraphs “0008” and “0009” of JP1993-5005A (JP-H05-5005A) and paragraphs “0022” to “0025” of JP2001-222101A can also be preferably used. As pigments, the compounds described in paragraphs “0072” and “0076” of JP2008-195018A are preferable.
In addition, as the aforementioned infrared absorber, a decomposable compound that decomposes due to exposure to infrared, which will be described later as a color-altering compound of the outermost layer, is also suitably used.
From the viewpoint of printing durability and visibility, the highest occupied molecular orbital (HOMO) of the infrared absorber is preferably −5.250 eV or less, more preferably −5.30 eV or less, even more preferably −5.80 eV or more and −5.35 eV or less, and particularly preferably −5.65 eV or more and −5.40 eV or less.
From the viewpoint of temporal stability, sensitivity improvement, and UV printing durability, the lowest unoccupied molecular orbital (LUMO) of the infrared absorber is preferably less than −3.70 eV, more preferably less than −3.80 eV, even more preferably −4.20 eV or more and less than −3.80 eV, and particularly preferably −4.00 eV or more and less than −3.80 eV.
One infrared absorber may be used alone, or two or more infrared absorbers may be used in combination.
In addition, as the infrared absorber, a pigment and a dye may be used in combination.
The content of the infrared absorber with respect to the total mass of the image-recording layer is preferably 0.1% by mass to 10.0% by mass, and more preferably 0.5% by mass to 5.0% by mass.
[Polymerizable Compound]
It is preferable that the image-recording layer in the present disclosure further contain a polymerizable compound.
In the present disclosure, a polymerizable compound refers to a compound having a polymerizable group.
The polymerizable group is not particularly limited and may be a known polymerizable group. As the polymerizable group, an ethylenically unsaturated group is preferable. The polymerizable group may be a radically polymerizable group or a cationically polymerizable group. The polymerizable group is preferably a radically polymerizable group.
Examples of the radically polymerizable group include a (meth)acryloyl group, an allyl group, a vinylphenyl group, a vinyl group, and the like. From the viewpoint of reactivity, a (meth)acryloyl group is preferable.
The molecular weight of the polymerizable compound (weight-average molecular weight in a case where the polymerizable compound has molecular weight distribution) is preferably 50 or more and less than 2,500.
The polymerizable compound used in the present disclosure may be, for example, a radically polymerizable compound or a cationically polymerizable compound. As the polymerizable compound, an addition polymerizable compound having at least one ethylenically unsaturated bond (ethylenically unsaturated compound) is preferable.
The ethylenically unsaturated compound is preferably a compound having at least one ethylenically unsaturated bond on a terminal, and more preferably a compound having two or more ethylenically unsaturated bonds on a terminal. The chemical form of the polymerizable compound is, for example, a monomer, a prepolymer which is in other words a dimer, a trimer, or an oligomer, a mixture of these, or the like.
Particularly, from the viewpoint of UV printing durability, the aforementioned polymerizable compound preferably includes a polymerizable compound having functionalities of 3 or more, more preferably includes a polymerizable compound having functionalities of 7 or more, and even more preferably includes a polymerizable compound having functionalities of 10 or more. Particularly, from the viewpoint of UV printing durability of the planographic printing plate to be obtained, the aforementioned polymerizable compound preferably includes an ethylenically unsaturated compound having functionalities of 3 or more (preferably having functionalities of 7 or more and more preferably having functionalities of 10 or more), and more preferably includes a (meth)acrylate compound having functionalities of 3 or more (preferably having functionalities of 7 or more and more preferably having functionalities of 10 or more).
From the viewpoint of on-press developability and contamination suppressiveness, the aforementioned polymerizable compound preferably includes a polymerizable compound having functionalities of 2 or less, more preferably includes a difunctional polymerizable compound, and particularly preferably includes a difunctional (meth)acrylate compound.
From the viewpoint of printing durability, on-press developability, and contamination suppressiveness, the content of the polymerizable compound having functionalities of 2 or less (preferably a difunctional polymerizable compound) with respect to the total mass of polymerizable compounds in the image-recording layer is preferably 5% by mass to 100% by mass, more preferably 10% by mass to 100% by mass, and even more preferably 50% by mass to 100% by mass.
<<Oligomer>>
As the polymerizable compound to be incorporated into in the image-recording layer, a polymerizable compound which is an oligomer (hereinafter, also simply called “oligomer”) is preferable.
In the present disclosure, an oligomer represents a polymerizable compound which has a molecular weight (weight-average molecular weight in a case where the compound has molecular weight distribution) of 600 or more and 10,000 or less and at least one polymerizable group.
From the viewpoint of excellent chemical resistance and excellent UV printing durability, the molecular weight of the oligomer is preferably 1,000 or more and 5,000 or less.
Furthermore, from the viewpoint of improving UV printing durability, the number of polymerizable groups in one molecule of the oligomer is preferably 2 or more, more preferably 3 or more, even more preferably 6 or more, and particularly preferably 10 or more.
The upper limit of the number of polymerizable groups in the oligomer is not particularly limited. The number of polymerizable groups is preferably 20 or less.
From the viewpoint of UV printing durability and on-press developability, an oligomer having 7 or more polymerizable groups and a molecular weight of 1,000 or more and 10,000 or less is preferable, and an oligomer having 7 or more and 20 or less polymerizable groups and a molecular weight of 1,000 or more and 5,000 or less is more preferable.
The oligomer may contain a polymer component which is likely to be generated in the process of manufacturing the oligomer.
From the viewpoint of UV printing durability, visibility, and on-press developability, the oligomer preferably has at least one compound selected from the group consisting of a compound having a urethane bond, a compound having an ester bond, and a compound having an epoxy residue, and more preferably has a compound having a urethane bond.
In the present disclosure, an epoxy residue refers to a structure formed of an epoxy group. For example, the epoxy residue means a structure similar to a structure established by the reaction between an acid group (carboxylic acid group or the like) and an epoxy group.
As the compound having a urethane bond, which is an example of the oligomer, for example, a compound having at least a group represented by Formula (Ac-1) or Formula (Ac-2) is preferable, and a compound having at least a group represented by Formula (Ac-1) is more preferable.
In Formula (Ac-1) and Formula (Ac-2), L1 to L4 each independently represent a divalent hydrocarbon group having a carbon number of 2 to 20, and the portion of the wavy line represents a bonding position with other structures.
L1 to L4 preferably each independently represent an alkylene group having a carbon number of 2 to 20, more preferably each independently represent an alkylene group having a carbon number of 2 to 10, and even more preferably each independently represent an alkylene group having a carbon number of 4 to 8. The alkylene group may have a branched structure or a ring structure. The alkylene group is preferably a linear alkylene group.
The portion of the wavy line in Formula (Ac-1) or Formula (Ac-2) is preferably each independently directly bonded to the portion of the wavy line in a group represented by Formula (Ae-1) or Formula (Ae-2).
In Formula (Ae-1) and Formula (Ae-2), R each independently represent an acryloyloxy group or a methacryloyloxy group, and the portion of the wavy line represents a bonding position with portion of the wavy line in Formula (Ac-1) and Formula (Ac-2).
As the compound having a urethane bond, a compound may also be used which is prepared by obtaining polyurethane by a reaction between a polyisocyanate compound and a polyol compound and introducing a polymerizable group into the polyurethane by a polymer reaction.
For example, the compound having a urethane bond may be obtained by reacting a polyol compound having an acid group with a polyisocyanate compound to obtain a polyurethane oligomer and reacting this polyurethane oligomer with a compound having an epoxy group and a polymerizable group.
The number of polymerizable groups in the compound having an ester bond, which is an example of oligomer, is preferably 3 or more, and more preferably 6 or more.
As the compound having an epoxy residue, which is an example of oligomer, a compound containing a hydroxy group is preferable.
The number of polymerizable groups in the compound having an epoxy residue is preferably 2 to 6, and more preferably 2 or 3.
The compound having an epoxy residue can be obtained, for example, by reacting a compound having an epoxy group with an acrylic acid.
Specific examples of oligomers will be shown below, but the oligomer used in the present disclosure is not limited thereto.
As the oligomer, commercially available products may also be used. Examples thereof include UA-510H, UA-306H, UA-306I, and UA-306T (manufactured by KYOEISHA CHEMICAL Co., LTD.), UV-1700B, UV-6300B, and UV7620EA (manufactured by The Nippon Synthetic Chemical Industry Co., Ltd.), U-15HA (manufactured by SHIN-NAKAMURA CHEMICAL Co., LTD.), EBECRYL450, EBECRYL657, EBECRYL885, EBECRYL800, EBECRYL3416, and EBECRYL860 (manufactured by DAICEL-ALLNEX LTD.), and the like. However, the oligomer is not limited to these.
From the viewpoint of improving chemical resistance and UV printing durability and further suppressing the residues of on-press development, the content of the oligomer with respect to the total mass of polymerizable compounds in the image-recording layer is preferably 30% by mass to 100% by mass, more preferably 50% by mass to 100% by mass, and even more preferably 80% by mass to 100% by mass.
<<Low-Molecular-Weight Polymerizable Compound>>
The polymerizable compound may further include a polymerizable compound other than the oligomer described above.
From the viewpoint of chemical resistance, the polymerizable compound other than the oligomer is preferably a low-molecular-weight polymerizable compound. The low-molecular-weight polymerizable compound may take a chemical form such as a monomer, a dimer, a trimer, or a mixture of these.
From the viewpoint of chemical resistance, the low-molecular-weight polymerizable compound is preferably at least a polymerizable compound selected from the group consisting of a polymerizable compound having three or more ethylenically unsaturated groups and a polymerizable compound having an isocyanuric ring structure.
In the present disclosure, a low-molecular-weight polymerizable compound refers to a polymerizable compound having a molecular weight (weight-average molecular weight in a case where the compound has molecular weight distribution) of 50 or more and less than 600.
From the viewpoint of excellent chemical resistance, excellent UV printing durability, and excellently suppressing the residues of on-press development, the molecular weight of the low-molecular-weight polymerizable compound is preferably 100 or more and less than 600, more preferably 300 or more and less than 600, and even more preferably 400 or more and less than 600.
In a case where the polymerizable compound includes a low-molecular-weight polymerizable compound as the polymerizable compound other than an oligomer (total amount in a case where the polymerizable compound includes two or more low-molecular-weight polymerizable compounds), from the viewpoint of chemical resistance and UV printing durability and suppressing the residues of on-press development, the ratio of the oligomer to the low-molecular-weight polymerizable compound (oligomer/low-molecular-weight polymerizable compound) is preferably 10/1 to 1/10, more preferably 10/1 to 3/7, and even more preferably 10/1 to 7/3, based on mass.
As the low-molecular-weight polymerizable compound, the polymerizable compounds described in paragraphs “0082” to “0086” of WO2019/013268A can also be suitably used.
The details of how to use the polymerizable compound, such as the structure of the compound, whether the compound is used alone or used in combination with other compounds, and the amount of the compound to be added, can be randomly set.
Particularly, from the viewpoint of UV printing durability, the image-recording layer preferably contains two or more polymerizable compounds.
The content of the polymerizable compound (total content of polymerizable compounds in a case where the image-recording layer contains two or more polymerizable compounds) with respect to the total mass of the image-recording layer is preferably 5% by mass to 75% by mass, more preferably 10% by mass to 70% by mass, and even more preferably 15% by mass to 60% by mass.
[Polar Organic Solvent]
From the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, it is preferable that the image-recording layer in the present disclosure further contain a polar organic solvent.
Moreover, it is preferable that the polar organic solvent be an aprotic polar organic solvent.
The aprotic polar organic solvent is preferably at least one solvent selected from the group consisting of N-methylpyrrolidone, N-ethylpyrrolidone, γ-butyrolactone, dimethyl sulfoxide, dimethyl acetamide, dimethyl formamide, methylene chloride, tetrahydrofuran, dioxane, and 1,3-dioxolane, more preferably at least one solvent selected from the group consisting of N-methylpyrrolidone, N-ethylpyrrolidone, γ-butyrolactone, dimethyl sulfoxide, dimethyl acetamide, dimethyl formamide, tetrahydrofuran, dioxane, and 1,3-dioxolane, and particularly preferably at least one solvent selected from the group consisting of dimethyl sulfoxide and N-methylpyrrolidone.
One polar organic solvent may be used alone, or two or more polar organic solvents may be used in combination.
From the viewpoint of ink turbidity suppressiveness, visibility of exposed portions, and temporal visibility of exposed portions, the content of the polar organic solvent with respect to the total mass of the image-recording layer is preferably 0.001% by mass to 5.0% by mass, and more preferably 0.005% by mass to 2.0% by mass. The content of the polar organic solvent is particularly preferably 0.01% by mass to 1.0% by mass.
[Particles]
From the viewpoint of developability and UV printing durability, it is preferable that the image-recording layer in the present disclosure further contain particles. The particles may be inorganic particles or organic particles.
Particularly, the image-recording layer preferably contains organic particles as particles, and more preferably contains resin particles as particles.
Known inorganic particles can be used as inorganic particles, and metal oxide particles such as silica particles and titania particles can be suitably used.
<<Resin Particles>>
Examples of the resin particles include particles containing an addition polymerization-type resin (that is, addition polymerization-type resin particles), particles containing a polyaddition-type resin (that is, polyaddition-type resin particles), particles containing a polycondensation-type resin (that is, polycondensation-type resin particles), and the like. Among these, addition polymerization-type resin particles or polyaddition-type resin particles are preferable.
From the viewpoint of enabling thermal fusion, the resin particles may also be particles containing a thermoplastic resin (that is, thermoplastic resin particles).
The resin particles may be in the form of microcapsules, microgel (that is, crosslinked resin particles), or the like.
The resin particles are preferably selected from the group consisting of thermoplastic resin particles, thermal reactive resin particles, resin particles having a polymerizable group, microcapsules encapsulating a hydrophobic compound, and microgel (crosslinked resin particles). Among these, resin particles having a polymerizable group are preferable.
In a particularly preferable embodiment, the resin particles have at least one ethylenically unsaturated group. The presence of such resin particles brings about effects of improving the printing durability of an exposed portion and improving the on-press developability of a non-exposed portion.
As the thermoplastic resin particles, the thermoplastic resin particles described in Research Disclosure No. 33303 published in January 1992, JP1997-123387A (JP-H09-123387A), JP1997-131850A (JP-H09-131850A), JP1997-171249A (JP-H09-171249A), JP1997-171250A (JP-H09-171250A), EP931647B, and the like are preferable.
Specific examples of resins constituting the thermoplastic resin particles include homopolymers or copolymers of monomers of ethylene, styrene, vinyl chloride, methyl acrylate, ethyl acrylate, methyl methacrylate, ethyl methacrylate, vinylidene chloride, acrylonitrile, vinylcarbazole, acrylates or methacrylates having polyalkylene structures, and the like and mixtures of these.
From the viewpoint of ink receptivity and UV printing durability, the thermoplastic resin particles preferably contain a resin that has a constitutional unit formed of an aromatic vinyl compound and a nitrile group-containing constitutional unit.
The aforementioned aromatic vinyl compound may have a structure composed of an aromatic ring and a vinyl group bonded thereto. Examples of the compound include a styrene compound, a vinylnaphthalene compound, and the like. Among these, a styrene compound is preferable, and styrene is more preferable.
Examples of the styrene compound include styrene, p-methylstyrene, p-methoxystyrene, β-methylstyrene, p-methyl-β-methylstyrene, α-methylstyrene, p-methoxy-β-methylstyrene, and the like. Among these, for example, styrene is preferable.
From the viewpoint of ink receptivity, the content of the constitutional unit formed of an aromatic vinyl compound is preferably higher than the content of the nitrile group-containing constitutional unit that will be described later. The content of the constitutional unit formed of an aromatic vinyl compound with respect to the total mass of the resin is more preferably 15% by mass to 85% by mass, and even more preferably 30% by mass to 70% by mass.
The nitrile group-containing constitutional unit is preferably introduced using a monomer having a nitrile group.
Examples of the monomer having a nitrile group include an acrylonitrile compound. As the monomer having a nitrile group, for example, (meth)acrylonitrile is suitable.
As the nitrile group-containing constitutional unit, a constitutional unit formed of (meth)acrylonitrile is preferable.
From the viewpoint of ink receptivity, the content of the nitrile group-containing constitutional unit is preferably lower than the content of the aforementioned constitutional unit formed of an aromatic vinyl compound. The content of the nitrile group-containing constitutional unit with respect to the total mass of the resin is more preferably 55% by mass to 90% by mass, and even more preferably 60% by mass to 85% by mass.
In a case where the resin contained in the thermoplastic resin particles has the constitutional unit formed of an aromatic vinyl compound and the nitrile group-containing constitutional unit, the content ratio between the constitutional unit formed of an aromatic vinyl compound and the nitrile group-containing constitutional unit (constitutional unit formed of aromatic vinyl compound:nitrile group-containing constitutional unit) is preferably 5:5 to 9:1, and more preferably 6:4 to 8:2, based on mass.
From the viewpoint of UV printing durability and chemical resistance, the resin contained in the thermoplastic resin particles preferably further has a constitutional unit formed of an N-vinyl heterocyclic compound.
Examples of the N-vinyl heterocyclic compound include N-vinylpyrrolidone, N-vinylcarbazole, N-vinylpyrrole, N-vinylphenothiazine, N-vinylsuccinic acid imide, N-vinylphthalimide, N-vinylcaprolactam, and N-vinylimidazole. Among these, N-vinylpyrrolidone is preferable.
The content of the constitutional unit formed of an N-vinyl heterocyclic compound with respect to the total mass of the thermoplastic resin is preferably 5% by mass to 50% by mass, and more preferably 10% by mass to 40% by mass.
The resin contained in the thermoplastic resin particles may contain an acidic group-containing constitutional unit. From the viewpoint of on-press developability and ink receptivity, it is preferable that the resin do not contain an acidic group-containing constitutional unit.
Specifically, in the thermoplastic resin, the content of the acidic group-containing constitutional unit is preferably 20% by mass or less, more preferably 10% by mass or less, and even more preferably 5% by mass or less. The lower limit of the content is not particularly limited, and may be 0% by mass.
The acid value of the thermoplastic resin is preferably 160 mg KOH/g or less, more preferably 80 mg KOH/g or less, and even more preferably 40 mg KOH/g or less. The lower limit of the acid value is not particularly limited, and may be 0 mg KOH/g.
In the present disclosure, the acid value is determined by the measurement method based on JIS K0070: 1992.
From the viewpoint of ink receptivity, the resin contained in the thermoplastic resin particles may contain a hydrophobic group-containing constitutional unit.
Examples of the hydrophobic group include an alkyl group, an aryl group, an aralkyl group, and the like.
As the hydrophobic group-containing constitutional unit, a constitutional unit formed of an alkyl (meth)acrylate compound, an aryl (meth)acrylate compound, or an aralkyl (meth)acrylate compound is preferable, and a constitutional unit formed of an alkyl (meth)acrylate compound is more preferable.
In the resin contained in the thermoplastic resin particles, the content of the hydrophobic group-containing constitutional unit with respect to the total mass of the resin is preferably 5% by mass to 50% by mass, and more preferably 10% by mass to 30% by mass.
From the viewpoint of UV printing durability and on-press developability, the thermoplastic resin contained in the thermoplastic resin particles preferably has a hydrophilic group.
The hydrophilic group is not particularly limited as long as it has a hydrophilic structure, and examples thereof include an acid group such as a carboxy group, a hydroxy group, an amino group, a nitrile group, a polyalkylene oxide structure, and the like.
From the viewpoint of UV printing durability and on-press developability, the hydrophilic group is preferably a group having a polyalkylene oxide structure, a group having a polyester structure, or a sulfonic acid group, more preferably a group having a polyalkylene oxide structure or a sulfonic acid group, and even more preferably a group having a polyalkylene oxide structure.
From the viewpoint of on-press developability, the polyalkylene oxide structure is preferably a polyethylene oxide structure, a polypropylene oxide structure, or a poly(ethylene oxide/propylene oxide) structure.
From the viewpoint of on-press developability, among the above hydrophilic groups, groups having a polypropylene oxide structure as a polyalkylene oxide structure are preferable, and groups having a polyethylene oxide structure and a polypropylene oxide structure are more preferable.
From the viewpoint of on-press developability, the number of alkylene oxide structures in the polyalkylene oxide structure is preferably 2 or more, more preferably 5 or more, even more preferably 5 to 200, and particularly preferably 8 to 150.
From the viewpoint of on-press developability, as the aforementioned hydrophilic group, a group represented by Formula Z, which will be described later, is preferable.
Among the hydrophilic groups that the thermoplastic resin has, a group represented by Formula PO is preferable.
In Formula PO, LP each independently represent an alkylene group, RP represents a hydrogen atom or an alkyl group, and n represents an integer of 1 to 100.
In Formula PO, LP preferably each independently represent an ethylene group, a 1-methylethylene group, or a 2-methylethylene group, and more preferably each independently represent an ethylene group.
In Formula PO, RP is preferably a hydrogen atom or an alkyl group having a carbon number of 1 to 18, more preferably a hydrogen atom or an alkyl group having a carbon number of 1 to 10, even more preferably a hydrogen atom or an alkyl group having a carbon number of 1 to 4, and particularly preferably a hydrogen atom or a methyl group.
In Formula PO, n is preferably an integer of 1 to 10, and more preferably an integer of 1 to 4.
The content of the hydrophilic group-containing constitutional unit with respect to the total mass of the resin is preferably 5% by mass to 60% by mass, and more preferably 10% by mass to 30% by mass.
The resin contained in the thermoplastic resin particles may further contain other constitutional units. The resin can contain, as those other constitutional units, constitutional units other than the constitutional units described above without particular limitations. Examples thereof include constitutional units formed of an acrylamide compound, a vinyl ether compound, and the like.
In the resin contained in the thermoplastic resin particles, the content of other constitutional units with respect to the total mass of the resin is preferably 5% by mass to 50% by mass, and more preferably 10% by mass to 30% by mass.
Examples of the thermal reactive resin particles include resin particles having a thermal reactive group. The thermal reactive resin particles form a hydrophobic region through crosslinking by a thermal reaction and the accompanying change in functional groups.
The thermal reactive group in the resin particles having a thermal reactive group may be a functional group that causes any reaction as long as chemical bonds are formed. The thermal reactive group is preferably a polymerizable group. Preferred examples of the polymerizable group include an ethylenically unsaturated group that causes a radical polymerization reaction (for example, an acryloyl group, a methacryloyl group, a vinyl group, an allyl group, and the like), a cationically polymerizable group (for example, a vinyl group, a vinyloxy group, an epoxy group, an oxetanyl group, and the like), an isocyanato group or a blocked isocyanato group that causes an addition reaction, an epoxy group, a vinyloxy group, an active hydrogen atom-containing functional group that is a reaction partner thereof (for example, an amino group, a hydroxy group, a carboxy group, and the like), a carboxy group that causes a condensation reaction, a hydroxy group or an amino group that is a reaction partner of the carboxy group, an acid anhydride that causes a ring-opening addition reaction, an amino group or a hydroxy group which is a reaction partner of the acid anhydride, and the like.
The resin having a thermal reactive group may be an addition polymerization-type resin, a polyaddition-type resin, or a polycondensation-type resin or may be a thermoplastic resin.
As the microcapsules, for example, microcapsules are preferable which encapsulate at least some of the constituent components (preferably a hydrophobic compound) of the image-recording layer as described in JP2001-277740A and JP2001-277742A. In a preferred aspect of the image-recording layer containing microcapsules as resin particles, the image-recording layer is composed of microcapsules that encapsulate a hydrophobic component (that is, a hydrophobic compound) among the constituent components of the image-recording layer and a hydrophilic component (that is, a hydrophilic compound) that is on the outside of the microcapsules.
The microgel (crosslinked resin particles) can contain some of the constituent components of the image-recording layer, in at least one of the surface or the interior of the microgel. From the viewpoint of sensitivity of the planographic printing plate precursor to be obtained and printing durability of the planographic printing plate to be obtained, reactive microgel having a polymerizable group on the surface thereof is particularly preferable.
In order to obtain microcapsules containing a constituent component of the image-recording layer, known synthesis methods can be used.
The microgel (crosslinked resin particles) can contain some of the constituent components of the image-recording layer, in at least one of the surface or the interior of the microgel. From the viewpoint of sensitivity of the planographic printing plate precursor to be obtained and printing durability of the planographic printing plate to be obtained, reactive microgel having a polymerizable group on the surface thereof is particularly preferable.
In order to obtain microgel containing a constituent component of the image-recording layer, known synthesis methods can be used.
As the resin particles, from the viewpoint of printing durability, antifouling properties, and storage stability of the planographic printing plate to be obtained, polyaddition-type resin particles are preferable which are obtained by a reaction between a polyvalent isocyanate compound that is an adduct of a polyhydric phenol compound having two or more hydroxy groups in a molecule and isophorone diisocyanate and a compound having active hydrogen.
As the polyhydric phenol compound, a compound having a plurality of benzene rings having a phenolic hydroxyl group is preferable.
As the compound having active hydrogen, a polyol compound or a polyamine compound is preferable, a polyol compound is more preferable, and at least one compound selected from the group consisting of propylene glycol, glycerin, and trimethylolpropane is even more preferable. As the aforementioned active hydrogen compound, water can also be used. In a case where water is used, the amine generated by the reaction between an isocyanato group and water can form a urea bond to form particles.
Preferred examples of the resin particles obtained by the reaction between a polyvalent isocyanate compound that is an adduct of a polyhydric phenol compound having two or more hydroxy groups in a molecule and isophorone diisocyanate and a compound having active hydrogen include the resin particles described in paragraphs “0230” to “0234” of WO2018043259A.
As the resin particles, from the viewpoint of printing durability and solvent resistance of the planographic printing plate to be obtained, addition polymerization-type resin particles are preferable which have a hydrophobic main chain and include both i) constitutional unit having a nitrile group directly bonded to the hydrophobic main chain and ii) constitutional unit having a pendant group including a hydrophilic polyalkylene oxide segment. Specifically, the particles described in paragraph “0156” of JP2019-64269A are preferable.
<<Group Represented by Formula Z>>
It is preferable that the resin particles in the present disclosure have a group represented by Formula Z as a hydrophilic group.
*-Q-W—Y Formula Z
In Formula Z, Q represents a divalent linking group, W represents a divalent group having a hydrophilic structure or a divalent group having a hydrophobic structure, and Y represents a monovalent group having a hydrophilic structure or a monovalent group having a hydrophobic structure, either W or Y has a hydrophilic structure, and * represents a bonding site with another structure.
Furthermore, it is preferable that any of the hydrophilic structures included in Formula Z include a polyalkylene oxide structure.
Q in Formula Z is preferably a divalent linking group having a carbon number of 1 to 20, and more preferably a divalent linking group having a carbon number of 1 to 10.
Furthermore, Q in Formula Z is preferably an alkylene group, an arylene group, an ester bond, an amide bond, or a group formed by combining two or more of these, and more preferably a phenylene group, an ester bond, or an amide bond.
The divalent group having a hydrophilic structure represented by W in Formula Z is preferably a group having a polyalkylene oxide structure, and more preferably a polyalkyleneoxy group or a group in which —CH2CH2NRW— is bonded to one terminal of a polyalkyleneoxy group. RW represents a hydrogen atom or an alkyl group.
The divalent group having a hydrophobic structure represented by W in Formula Z is preferably —RWA—, —O—RWA—O—, —RWN—RWA—NRW—, —OC(═O)—RWA—O—, or —OC(═O)—RWA—O—. RWA's each independently represent a linear, branched, or cyclic alkylene group having a carbon number of 6 to 120, a haloalkylene group having a carbon number of 6 to 120, an arylene group having a carbon number of 6 to 120, an alkarylene group having a carbon number of 6 to 120 (divalent group formed by removing one hydrogen atom from an alkylaryl group), or an aralkylene group having a carbon number of 6 to 120.
The monovalent group having a hydrophilic structure represented by Y in Formula Z is preferably —OH, —C(═O)OH, a polyalkyleneoxy group having a hydrogen atom or an alkyl group on a terminal, or a group in which —CH2CH2N(RW)— is bonded to one terminal of a polyalkyleneoxy group having a hydrogen atom or an alkyl group on the other terminal. Particularly, the monovalent group having a hydrophilic structure is preferably a group having a polyalkylene oxide structure, a polyalkyleneoxy group having a hydrogen atom or an alkyl group on a terminal, or a group in which —CH2CH2N(RW)— is bonded to one terminal of a polyalkyleneoxy group having a hydrogen atom or an alkyl group on the other terminal.
The monovalent group having a hydrophobic structure represented by Y in Formula Z is preferably a linear, branched, or cyclic alkyl group having a carbon number of 6 to 120, a haloalkyl group having a carbon number of 6 to 120, an aryl group having a carbon number of 6 to 120, an alkaryl group having a carbon number of 6 to 120 (alkylaryl group), an aralkyl group having a carbon number of 6 to 120, —ORWB, —C(═O)ORWB, or —OC(═O)RWB. RWB represents an alkyl group having a carbon number of 6 to 20.
From the viewpoint of printing durability, receptivity, and on-press developability, in the resin particles having a group represented by formula Z, W is more preferably a divalent group having a hydrophilic structure, Q is more preferably a phenylene group, an ester bond, or an amide bond, W is more preferably a polyalkyleneoxy group, and Y is more preferably a polyalkyleneoxy group having a hydrogen atom or an alkyl group on a terminal.
The group represented by Formula Z may function as a dispersible group for improving the dispersibility of the resin particles.
From the viewpoint of printing durability and on-press developability, the resin particles in the present disclosure preferably have a polymerizable group (preferably an ethylenically unsaturated group). Particularly, the resin particles more preferably include resin particles having a polymerizable group on the surface thereof. In a case where the resin particles having a polymerizable group are used, printing durability (preferably UV printing durability) is improved.
From the viewpoint of printing durability, it is preferable that the resin particles in the present disclosure be resin particles having a hydrophilic group and a polymerizable group.
The polymerizable group may be a cationically polymerizable group or a radically polymerizable group. From the viewpoint of reactivity, the polymerizable group is preferably a radically polymerizable group.
The aforementioned polymerizable group is not particularly limited as long as it is a polymerizable group. From the viewpoint of reactivity, an ethylenically unsaturated group is preferable, a vinylphenyl group (styryl group), a (meth)acryloxy group, or a (meth)acrylamide group is more preferable, and a (meth)acryloxy group is particularly preferable.
In addition, it is preferable that the resin constituting the resin particles having a polymerizable group have a polymerizable group-containing constitutional unit.
The polymerizable group may be introduced into the surface of the resin particles by a polymer reaction.
Furthermore, from the viewpoint of printing durability, receptivity, on-press developability, and suppression of the occurrence of development residues during on-press development, the resin particles preferably contain a polyaddition-type resin having a urea bond, more preferably contain a polyaddition-type resin having a structure obtained by reacting at least an isocyanate compound represented by Formula (Iso) with water, and particularly preferably contain a polyaddition-type resin that has a structure obtained by reacting at least an isocyanate compound represented by Formula (Iso) with water and has a polyethylene oxide structure and a polypropylene oxide structure as polyoxyalkylene structures. Furthermore, the particles containing the polyaddition-type resin having a urea bond are preferably microgel.
In Formula (Iso), n represents an integer of 0 to 10.
An example of the reaction between the isocyanate compound represented by Formula (Iso) and water is the reaction shown below. In the following example, a 4,4-isomer in which n=0 is used.
As shown below, in a case where the isocyanate compound represented by Formula (Iso) is reacted with water, the isocyanate group is partially hydrolyzed by water and generates an amino group. The generated amino group reacts with the isocyanate group and generates a urea bond, and a dimer is consequently formed. Furthermore, the following reaction is repeated to form a polyaddition-type resin having a urea bond.
In the following reaction, by adding a compound (compound having active hydrogen) such as an alcohol compound or an amine compound reactive with an isocyanate group, it is possible to introduce the structure of an alcohol compound, an amine compound, or the like to the polyaddition-type resin having a urea bond.
Preferred examples of the compound having active hydrogen include the aforementioned compound having active hydrogen.
The polyaddition-type resin having a urea bond preferably has an ethylenically unsaturated group, and more preferably has a group represented by Formula (PETA).
In Formula (PETA), the portion of the wavy line represents a binding position with other structures.
<<Synthesis of Resin Particles>>
The synthesis method of the resin particles is not particularly limited, and may be a method that makes it possible to synthesize particles with various resins described above. Examples of the synthesis method of the resin particles include known synthesis methods of resin particles, such as an emulsion polymerization method, a suspension polymerization method, a dispersion polymerization method, a soap-free polymerization method, and a microemulsion polymerization method.
In addition, for the synthesis of the resin particles, a known microcapsule synthesis method, a known microgel (crosslinked resin particle) synthesis method, and the like may be used.
<<Average Particle Diameter of Particles>>
The average particle diameter of the particles is preferably 0.01 μm to 3.0 μm, more preferably 0.03 μm to 2.0 μm, and even more preferably 0.10 μm to 1.0 μm. In a case where the average particle diameter is in this range, excellent resolution and temporal stability are obtained.
The average particle diameter of the particles is measured using a light scattering method or by capturing an electron micrograph of the particles, measuring the particle diameter of a total of 5,000 particles in the photograph, and calculating the average thereof. For nonspherical particles, the equivalent circular diameter of the particles in a photograph is adopted.
Note that unless otherwise specified, the average particle diameter of the particles in the present disclosure means a volume average particle diameter.
As the particles (preferably resin particles), only one kind of particles may be used, or two or more kinds of particles may be used in combination.
From the viewpoint of developability and printing durability, the content of the particles (preferably resin particles) with respect to the total mass of the image-recording layer is preferably 5% by mass to 90% by mass, more preferably 10% by mass to 90% by mass, even more preferably 20% by mass to 90% by mass, and particularly preferably 50% by mass to 90% by mass.
[Other Components]
The image-recording layer in the present disclosure may contain other components in addition to the components described above.
Examples of those other components include a binder polymer, an oil agent, a chromogenic agent, a chain transfer agent, a low-molecular-weight hydrophilic compound, an oil sensitizing agent, a surfactant, other additives, and the like.
Examples of those other components include a surfactant, a colorant, a bakeout agent, a polymerization inhibitor, a higher fatty acid derivative, a plasticizer, inorganic particles, and a low-molecular-weight hydrophilic compound disclosed in paragraphs “0174” to “0190” of JP2009-255434A, and the like.
Examples of other compounds also include a hydrophilic precursor (fine particles capable of converting the image-recording layer into a hydrophobic image-recording layer in a case where heat is applied thereto), a low-molecular-weight hydrophilic compound, an oil sensitizing agent (for example, a phosphonium compound, a nitrogen-containing low-molecular-weight compound, or an ammonium group-containing polymer), and a chain transfer agent disclosed in paragraphs “0191” to “0217” of JP2012-187907A.
In addition, it is preferable that the surfactant include an anionic surfactant and a fluorine-based surfactant.
—Binder Polymer—
As necessary, the image-recording layer may contain a binder polymer.
The binder polymer refers to a polymer other than resin particles, that is, a polymer that is not in the form of particles.
In addition, the binder polymer excludes an ammonium salt-containing polymer in an oil sensitizing agent and a polymer used as a surfactant.
As the binder polymer, known binder polymers (for example, a (meth) acrylic resin, polyvinyl acetal, a polyurethane resin, and the like) used for the image-recording layer of a planographic printing plate precursor can be suitably used.
As an example, a binder polymer that is used for an on-press development type planographic printing plate precursor (hereinafter, also called binder polymer for on-press development) will be specifically described.
As the binder polymer for on-press development, a binder polymer having an alkylene oxide chain is preferable. The binder polymer having an alkylene oxide chain may have a poly(alkylene oxide) moiety in a main chain or side chain. In addition, the binder polymer may be a graft polymer having poly(alkylene oxide) in a side chain or a block copolymer of a block composed of a poly(alkylene oxide)-containing repeating unit and a block composed of an (alkylene oxide)-free repeating unit.
As a binder polymer having a poly(alkylene oxide) moiety in the main chain, a polyurethane resin is preferable.
In a case where the binder polymer has a poly(alkylene oxide) moiety in the side chain, examples of polymers of the main chain include a (meth)acrylic resin, a polyvinyl acetal resin, a polyurethane resin, a polyurea resin, a polyimide resin, a polyamide resin, an epoxy resin, a polystyrene resin, a novolac-type phenol resin, a polyester resin, synthetic rubber, and natural rubber. Among these, a (meth)acrylic resin is particularly preferable.
In addition, as the binder polymer, for example, a polymer compound is also preferable which has a polyfunctional thiol having functionalities of 6 or more and 10 or less as a nucleus and a polymer chain that is bonded to the nucleus by a sulfide bond and has a polymerizable group (hereinafter, this compound will be also called star-shaped polymer compound).
As the star-shaped polymer compound, for example, the compounds described in JP2012-148555A can be preferably used.
Examples of the star-shaped polymer compound include the compound described in JP2008-195018A that has a polymerizable group such as an ethylenically unsaturated bond for improving the film hardness of an image area in a main chain or side chain and preferably in a side chain. The polymerizable group of the star-shaped polymer compound forms crosslinks between the molecules of the star-shaped polymer compound, which facilitates curing.
As the polymerizable group, an ethylenically unsaturated group such as a (meth)acryloyl group, a vinyl group, an allyl group, or a vinyl phenyl group (styryl group), an epoxy group, or the like is preferable, a (meth)acryloyl group, a vinyl group, or a vinyl phenyl group (styryl group) is more preferable from the viewpoint of polymerization reactivity, and a (meth)acryloyl group is particularly preferable. These groups can be introduced into the polymer by a polymer reaction or copolymerization. Specifically, for example, it is possible to use a reaction between a polymer having a carboxy group in a side chain and glycidyl methacrylate or a reaction between a polymer having an epoxy group and an ethylenically unsaturated group-containing carboxylic acid such as methacrylic acid.
The molecular weight of the binder polymer that is a polystyrene-equivalent weight-average molecular weight (Mw) determined by GPC is preferably 2,000 or more, more preferably 5,000 or more, and even more preferably 10,000 to 300,000.
As the binder polymer, as necessary, a hydrophilic polymer, such as polyacrylic acid, polyvinyl alcohol, or polyvinyl acetal described in JP2008-195018A, can be used in combination. In addition, a lipophilic polymer and a hydrophilic polymer can be used in combination.
Particularly, from the viewpoint of on-press developability, the image-recording layer preferably contains polyvinyl acetal. Suitable examples of the polyvinyl acetal include polyvinyl butyral and the like.
One binder polymer may be used alone, or two or more binder polymers may be used in combination.
The content of the binder polymer to be incorporated into the image-recording layer can be randomly set. The content of the binder polymer with respect to the total mass of the image-recording layer is preferably 1% by mass to 90% by mass, and more preferably 5% by mass to 80% by mass.
—Oil Agent—
It is preferable that the image-recording layer further contains an oil agent.
In the present disclosure, an oil agent refers to a hydrophobic compound that is in a liquid state at 80° C. and is not mixed with water and separates in a case where the compound is mixed with water of the same mass.
In a case where two or more oil agents are used, the oil agents may include a compound having a melting point of 80° C. or higher as long as the two or more oil agents are in a liquid state at 80° C. in a mixed state.
In addition, from the viewpoint of on-press developability and dampening water turbidity suppressiveness, the oil agent is preferably a compound having a molecular weight less than 1,000, more preferably a compound having a molecular weight of 200 to 800, and particularly preferably a compound having a molecular weight of 300 to 500.
Furthermore, from the viewpoint of on-press developability and dampening water turbidity suppressiveness, the oil agent is preferably a compound having a boiling point of 200° C. or higher at 1 atm, more preferably a compound having a boiling point of 250° C. or higher at 1 atm, even more preferably a compound having a boiling point of 300° C. or higher at 1 atm, and particularly preferably a compound having a boiling point of 400° C. or higher and 500° C. or lower at 1 atm.
In the present disclosure, unless otherwise specified, “boiling point” means a boiling point at 1 atm.
In addition, from the viewpoint of on-press developability and dampening water turbidity suppressiveness, the melting point of the oil agent at 1 atm is preferably 50° C. or lower, more preferably 30° C. or lower, and particularly preferably −200° C. or higher and 25° C. or lower.
In the present disclosure, unless otherwise specified, “melting point” means a melting point at 1 atm.
Examples of the oil agent include a phosphoric acid ester compound, an aromatic hydrocarbon compound, a glyceride compound, a fatty acid compound, an aromatic ester compound, and the like.
Among the above, from the viewpoint of UV printing durability, receptivity, on-press developability, and dampening water turbidity suppressiveness, at least one compound selected from the group consisting of a phosphoric acid ester compound, an aromatic hydrocarbon compound, a glyceride compound, and an aromatic ester compound is preferable, at least one compound selected from the group consisting of a phosphoric acid ester compound, an aromatic hydrocarbon compound, and a glyceride compound is more preferable, at least one compound selected from the group consisting of a phosphoric acid ester compound and an aromatic hydrocarbon compound is even more preferable, and a phosphoric acid ester compound is particularly preferable.
As the phosphoric acid ester compound, from the viewpoint of UV printing durability, receptivity, on-press developability, and dampening water turbidity suppressiveness, a phosphoric acid triester compound is preferable, a phosphoric acid triaryl ester compound is more preferable, tricresyl phosphate is even more preferable, and a mixture of two or more isomers among ortho, meta, and para isomers of tricresyl phosphate is particularly preferable.
As the aromatic hydrocarbon compound, from the viewpoint of on-press developability and dampening water turbidity suppressiveness, a compound having two or more aromatic rings is preferable, and a compound having two or more unfused benzene rings is more preferable.
As the glyceride compound, from the viewpoint of on-press developability and dampening water turbidity suppressiveness, a triglyceride compound is preferable, a fatty oil is more preferable, and a fatty oil which is a liquid at 25° C., such as castor oil, is particularly preferable.
As the fatty acid compound, from the viewpoint of on-press developability and dampening water turbidity suppressiveness, an unsaturated fatty acid is preferable, an unsaturated fatty acid having a carbon number of 8 to 30 is more preferable, and an unsaturated fatty acid having a carbon number of 12 to 24 is particularly preferable.
As the aromatic ester compound, from the viewpoint of on-press developability and dampening water turbidity suppressiveness, an aromatic diester compound is preferable, and an aromatic diester compound having an aliphatic ring is more preferable.
As the aliphatic ester compound, from the viewpoint of on-press developability and dampening water turbidity suppressiveness, an aliphatic ester compound having a branched alkyl group is preferable, and an aliphatic ester compound having a branched alkyl group and a carbon number of 10 to 24 is more preferable.
From the viewpoint of UV printing durability, receptivity, on-press developability, and dampening water turbidity suppressiveness, the oil agent preferably includes an oil agent having a phosphorus atom, and is more preferably an oil agent having a phosphorus atom.
In addition, from the viewpoint of on-press developability and dampening water turbidity suppressiveness, the oil agent preferably includes an oil agent having an aromatic ring, more preferably includes an oil agent having two or more aromatic rings, and particularly preferably includes an oil agent having two or more unfused benzene rings.
From the viewpoint of UV printing durability, receptivity, on-press developability, and dampening water turbidity suppressiveness, a C log P value of the oil agent is preferably 5.0 or more, more preferably 5.50 or more, even more preferably 5.50 or more and 10.0 or less, and particularly preferably 5.60 or more and 7.00 or less.
The C log P value is a value obtained by calculating the common logarithm log P of the 1-octanol/water partition coefficient P. For calculating the C log P value, known methods and software can be used. In the present disclosure, unless otherwise specified, the C log P program incorporated into ChemBioDraw Ultra 12.0 from CambridgeSoft is used.
Specific examples of the oil agent include tricresyl phosphate, dimethyl(1-phenylethyl) benzene, 2,4-diphenyl-4-methyl-1-pentene, dicyclohexylphthalate, castor oil, α-linolenic acid, tri(2-ethylhexyl) phosphate, and the like.
One oil agent may be used alone, or two or more oil agents may be used in combination. From the viewpoint of on-press developability and dampening water turbidity suppressiveness, it is preferable that the image-recording layer contain two or more oil agents having different structures.
The content of the oil agent with respect to the total mass of the image-recording layer is preferably 0.0001% by mass to 10.0% by mass, more preferably 0.0002% by mass to 1.0% by mass, even more preferably 0.0005% by mass to 0.5% by mass, and particularly preferably 0.001% by mass to 0.05% by mass.
—Chromogenic Agent—
The image-recording layer in the present disclosure preferably further contains a chromogenic agent, and more preferably further contains an acid chromogenic agent. Furthermore, the chromogenic agent preferably includes a leuco compound.
“Chromogenic agent” used in the present disclosure means a compound that develops or removes color by a stimulus such as light or acid and thus changes the color of the image-recording layer. Furthermore, “acid chromogenic agent” means a compound that develops or removes color by being heated in a state of accepting an electron accepting compound (for example, a proton of an acid or the like) and thus changes the color of the image-recording layer. The acid chromogenic agent is particularly preferably a colorless compound which has a partial skeleton such as lactone, lactam, sultone, spiropyran, an ester, or an amide and allows such a partial skeleton to rapidly open the ring or to be cleaved when coming into contact with an electron accepting compound.
Examples of such an acid chromogenic agent include the compounds described in paragraphs “0184” to “0191” of JP2019-18412A.
Particularly, from the viewpoint of visibility, the chromogenic agent used in the present disclosure is preferably at least one compound selected from the group consisting of a spiropyran compound, a spirooxazine compound, a spirolactone compound, and a spirolactam compound.
From the viewpoint of visibility, the color of a colorant after color development preferably has maximum absorption wavelength in the range of 450 to 650 nm. The tint is preferably red, purple, blue, or dark green.
From the viewpoint of visibility and visibility of exposed portions, the acid chromogenic agent is preferably a leuco colorant.
The aforementioned leuco colorant is not particularly limited as long as it has a leuco structure. The leuco colorant preferably has a spiro structure, and more preferably has a spirolactone ring structure.
From the viewpoint of visibility and visibility of exposed portions, the leuco colorant is preferably a leuco colorant having a phthalide structure or a fluoran structure.
Furthermore, from the viewpoint of visibility and visibility of exposed portions, the leuco colorant having a phthalide structure or a fluoran structure is preferably a compound represented by any of Formula (Le-1) to Formula (Le-3), and more preferably a compound represented by Formula (Le-2).
In Formula (Le-1) to Formula (Le-3), ERG's each independently represent an electron-donating group, X1 to X4 each independently represent a hydrogen atom, a halogen atom, or dialkylanilino group, X5 to X10 each independently represent a hydrogen atom, a halogen atom, or a monovalent organic group, Y1 and Y2 each independently represent C or N, X1 does not exist in a case where Y1 is N, X4 does not exist in a case where Y2 is N, Ra1 represents a hydrogen atom, an alkyl group, or an alkoxy group, and Rb1 to Rb4 each independently represent a hydrogen atom, an alkyl group, an aryl group, or a heteroaryl group.
From the viewpoint of color developability and visibility of exposed portions, the electron-donating group represented by ERG in Formula (Le-1) to Formula (Le-3) is preferably an amino group, an alkylamino group, an arylamino group, a heteroarylamino group, a dialkylamino group, a monoalkyl monoarylamino group, a monoalkyl monoheteroarylamino group, a diarylamino group, a diheteroarylamino group, a monoaryl monoheteroarylamino group, an alkoxy group, an aryloxy group, a heteroaryloxy group, or an alkyl group, more preferably an amino group, an alkylamino group, an arylamino group, a heteroarylamino group, a dialkylamino group, a monoalkyl monoarylamino group, a monoalkyl monoheteroarylamino group, a diarylamino group, a diheteroarylamino group, a monoaryl monoheteroarylamino group, an alkoxy group, or an aryloxy group, even more preferably a monoalkyl monoarylamino group, a diarylamino group, a diheteroarylamino group, or a monoaryl monoheteroarylamino group, and particularly preferably a monoalkyl monoarylamino group.
From the viewpoint of color developability and visibility of exposed portions, the electron-donating group represented by ERG is preferably a disubstituted amino group having an aryl group that has a substituent on at least one ortho position or a heteroaryl group that has a substituent on at least one ortho position, more preferably a disubstituted amino group having a substituent on at least one ortho position and a phenyl group having an electron-donating group at a para position, even more preferably an amino group having a substituent on at least one ortho position and a phenyl group having an electron-donating group at a para position and an aryl group or a heteroaryl group, and particularly preferably an amino group having a substituent on at least one ortho position, a phenyl group having an electron-donating group at a para position, and an aryl group having an electron-donating group or a heteroaryl group having an electron-donating group.
In the present disclosure, in a case where a bonding position of an aryl group or a heteroaryl group with other structures is defined as 1-position, the ortho position in the aryl group or heteroaryl group other than a phenyl group is called a bonding position (for example, 2-position or the like) adjacent to the 1-position.
From the viewpoint of color developability and visibility of exposed portions, the electron-donating group that the aforementioned aryl group or heteroaryl group has is preferably an amino group, an alkylamino group, an arylamino group, a heteroarylamino group, a dialkylamino group, a monoalkyl monoarylamino group, a monoalkyl monoheteroarylamino group, a diarylamino group, a diheteroarylamino group, a monoaryl monoheteroarylamino group, an alkoxy group, an aryloxy group, a heteroaryloxy group, or an alkyl group, more preferably an alkoxy group, an aryloxy group, a heteroaryloxy group, or an alkyl group, and particularly preferably an alkoxy group.
From the viewpoint of color developability and visibility of exposed portions, X1 to X4 in Formula (Le-1) to Formula (Le-3) preferably each independently represent a hydrogen atom or a chlorine atom, and more preferably each independently represent a hydrogen atom.
From the viewpoint of color developability and visibility of exposed portions, X5 to X10 in Formula (Le-2) or Formula (Le-3) preferably each independently represent a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an amino group, an alkylamino group, an arylamino group, a heteroarylamino group, a dialkylamino group, a monoalkyl monoarylamino group, a monoalkyl monoheteroarylamino group, a diarylamino group, a diheteroarylamino group, a monoaryl monoheteroarylamino group, a hydroxy group, an alkoxy group, an aryloxy group, a heteroaryloxy group, an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a heteroaryloxycarbonyl group, or a cyano group, more preferably each independently represent a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an alkoxy group, or an aryloxy group, even more preferably each independently represent a hydrogen atom, a halogen atom, an alkyl group, or an aryl group, and particularly preferably each independently represent a hydrogen atom.
From the viewpoint of color developability and visibility of exposed portions, it is preferable that at least one of Y1 or Y2 in Formula (Le-1) to Formula (Le-3) be C, and it is more preferable that both of Y1 and Y2 be C.
From the viewpoint of color developability and visibility of exposed portions, Ra1 in Formula (Le-1) to Formula (Le-3) is preferably an alkyl group or an alkoxy group, more preferably an alkoxy group, and particularly preferably a methoxy group.
From the viewpoint of color developability and visibility of exposed portions, Rb1 to Rb4 in Formula (Le-1) to Formula (Le-3) preferably each independently represent a hydrogen atom or an alkyl group, more preferably each independently represent an alkyl group, and particularly preferably each independently represent a methyl group.
Furthermore, from the viewpoint of color developability and visibility of exposed portions, the leuco colorant having a phthalide structure or a fluoran structure is more preferably a compound represented by any of Formula (Le-4) to Formula (Le-6), and even more preferably a compound represented by Formula (Le-5).
In Formula (Le-4) to Formula (Le-6), ERG's each independently represent an electron-donating group, X1 to X4 each independently represent a hydrogen atom, a halogen atom, or a dialkylanilino group, Y1 and Y2 each independently represent C or N, X1 does not exist in a case where Y1 is N, X4 does not exist in a case where Y2 is N, Ra1 represents a hydrogen atom, an alkyl group, or an alkoxy group, and Rb1 to Rb4 each independently represent a hydrogen atom, an alkyl group, an aryl group, or a heteroaryl group.
ERG, X1 to X4, Y1, Y2, Ra1, and Rb1 to Rb4 in Formula (Le-4) to Formula (Le-6) have the same definitions as ERG, X1 to X4, Y1, Y2, Ra1, and Rb1 to Rb4 in Formula (Le-1) to Formula (Le-3) respectively, and preferred aspects thereof are also the same.
Furthermore, from the viewpoint of color developability and visibility of exposed portions, the leuco colorant having a phthalide structure or a fluoran structure is more preferably a compound represented by any of Formula (Le-7) to Formula (Le-9), and particularly preferably a compound represented by Formula (Le-8).
In Formula (Le-7) to Formula (Le-9), X1 to X4 each independently represent a hydrogen atom, a halogen atom, or a dialkylanilino group, Y1 and Y2 each independently represent C or N, X1 does not exist in a case where Y1 is N, X4 does not exist in a case where Y2 is N, Ra1 to Ra4 each independently represent a hydrogen atom, an alkyl group, or an alkoxy group, Rb1 to Rb4 each independently represent a hydrogen atom, an alkyl group, an aryl group, or a heteroaryl group, and Rc1 and Rc2 each independently represent an aryl group or a heteroaryl group.
X1 to X4, Y1, and Y2 in Formula (Le-7) to Formula (Le-9) have the same definition as X1 to X4, Y1, and Y2 in Formula (Le-1) to Formula (Le-3) respectively, and preferred aspects thereof are also the same.
From the viewpoint of color developability and visibility of exposed portions, Ra1 to Ra4 in Formula (Le-7) or Formula (Le-9) preferably each independently represent an alkyl group or an alkoxy group, more preferably each independently represent an alkoxy group, and particularly preferably each independently represent a methoxy group.
From the viewpoint of color developability and visibility of exposed portions, Rb1 to Rb4 in Formula (Le-7) to Formula (Le-9) preferably each independently represent a hydrogen atom, an alkyl group, or an aryl group substituted with an alkoxy group, more preferably each independently represent an alkyl group, and particularly preferably each independently represent a methyl group.
From the viewpoint of color developability and visibility of exposed portions, Rc1 and Rc2 in Formula (Le-8) preferably each independently represent a phenyl group or an alkylphenyl group, and more preferably each independently represent a phenyl group.
From the viewpoint of color developability and visibility of exposed portions, Rc1 and Rc2 in Formula (Le-8) preferably each independently represent an aryl group having a substituent on at least one ortho position or a heteroaryl group having a substituent on at least one ortho position, more preferably each independently represent an aryl group having a substituent on at least one ortho position, even more preferably each independently represent a phenyl group having a substituent on at least one ortho position, and particularly preferably each independently represent a phenyl group having a substituent on at least one ortho position and having an electron-donating group at the para position. Examples of the substituent in Rc1 and Rc2 include substituents that will be described later.
In Formula (Le-8), from the viewpoint of color developability and visibility of exposed portions, X1 to X4 preferably each represent a hydrogen atom, and Y1 and Y2 preferably each represent C.
Furthermore, from the viewpoint of color developability and visibility of exposed portions, in Formula (Le-8), Rb1 and Rb2 preferably each independently represent an alkyl group or an aryl group substituted with an alkoxy group.
From the viewpoint of color developability and visibility of exposed portions, Rb1 and Rb2 in Formula (Le-8) preferably each independently represent an aryl group or a heteroaryl group, more preferably each independently represent an aryl group, even more preferably each independently represent an aryl group having an electron-donating group, and particularly preferably each independently represent a phenyl group having an electron-donating group at the para position.
From the viewpoint of color developability and visibility of exposed portions, the electron-donating group in Rb1, Rb2, Rc1, and Rc2 is preferably an amino group, an alkylamino group, an arylamino group, a heteroarylamino group, a dialkylamino group, a monoalkyl monoarylamino group, a monoalkyl monoheteroarylamino group, a diarylamino group, a diheteroarylamino group, a monoaryl monoheteroarylamino group, an alkoxy group, an aryloxy group, a heteroaryloxy group, or an alkyl group, more preferably an alkoxy group, an aryloxy group, a heteroaryloxy group, or an alkyl group, and particularly preferably an alkoxy group.
From the viewpoint of color developability and visibility of exposed portions, the acid chromogenic agent preferably includes a compound represented by Formula (Le-10).
In Formula (Le-10), Ar1 each independently represent an aryl group or a heteroaryl group, and Ar2 each independently represent an aryl group having a substituent on at least one ortho position or a heteroaryl group having a substituent on at least one ortho position.
Ar1 in Formula (Le-10) has the same definition as Rb1 and Rb2 in Formula (Le-7) to Formula (Le-9), and preferred aspects thereof are also the same.
Ar2 in Formula (Le-10) has the same definition as Rc1 and Rc2 in Formula (Le-7) to Formula (Le-9), and preferred aspects thereof are also the same.
The alkyl group in Formula (Le-1) to Formula (Le-9) may be linear or branched or may have a ring structure.
The carbon number of the alkyl group in Formula (Le-1) to Formula (Le-9) is preferably 1 to 20, more preferably 1 to 8, even more preferably 1 to 4, and particularly preferably 1 or 2.
The carbon number of the aryl group in Formula (Le-1) to Formula (Le-10) is preferably 6 to 20, more preferably 6 to 10, and particularly preferably 6 to 8.
Specific examples of the aryl group in Formula (Le-1) to Formula (Le-10) include a phenyl group, a naphthyl group, an anthracenyl group, a phenanthrenyl group, and the like which may have a substituent.
Specific examples of the heteroaryl group in Formula (Le-1) to Formula (Le-10) include a furyl group, a pyridyl group, a pyrimidyl group, a pyrazoyl group, a thiophenyl group, and the like which may have a substituent.
Each of the groups in Formula (Le-1) to Formula (Le-10), such as a monovalent organic group, an alkyl group, an aryl group, a heteroaryl group, a dialkylanilino group, an alkylamino group, and an alkoxy group, may have a substituent. Examples of the substituent include an alkyl group, an aryl group, a heteroaryl group, a halogen atom, an amino group, an alkylamino group, an arylamino group, a heteroarylamino group, a dialkylamino group, a monoalkyl monoarylamino group, a monoalkyl monoheteroarylamino group, a diarylamino group, a diheteroarylamino group, a monoaryl monoheteroarylamino group, a hydroxy group, an alkoxy group, an aryloxy group, a heteroaryloxy group, an acyl group, an alkoxycarbonyl group, an aryloxycarbonyl group, a heteroaryloxycarbonyl group, a cyano group, and the like. These substituents may be further substituted with these substituents.
Examples of the leuco colorant having the phthalide structure or the fluoran structure that are suitably used include the following compounds.
As the acid chromogenic agent, commercially available products can be used. Examples thereof include ETAC, RED500, RED520, CVL, S-205, BLACK305, BLACK400, BLACK100, BLACK500, H-7001, GREEN300, NIRBLACK78, BLUE220, H-3035, BLUE203, ATP, H-1046, and H-2114 (all manufactured by Fukui Yamada Chemical Co., Ltd.), ORANGE-DCF, Vermilion-DCF, PINK-DCF, RED-DCF, BLMB, CVL, GREEN-DCF, and TH-107 (all manufactured by Hodogaya Chemical Co., Ltd.), ODB, ODB-2, ODB-4, ODB-250, ODB-BlackXV, Blue-63, Blue-502, GN-169, GN-2, Green-118, Red-40, and Red-8 (all manufactured by Yamamoto Chemicals, Inc.), crystal violet lactone (manufactured by Tokyo Chemical Industry Co., Ltd.), and the like. Among these commercially available products, ETAC, S-205, BLACK305, BLACK400, BLACK100, BLACK500, H-7001, GREEN300, NIRBLACK78, H-3035, ATP, H-1046, H-2114, GREEN-DCF, Blue-63, GN-169, and crystal violet lactone are preferable because these form a film having excellent visible light absorbance.
From the viewpoint of visibility and visibility of exposed portions, examples of suitably used a leuco colorant include the following compounds.
Each of these chromogenic agents may be used alone. Alternatively, two or more components can be used in combination.
The content of the chromogenic agent with respect to the total mass of the image-recording layer is preferably 0.5% by mass to 10% by mass, and more preferably 1% by mass to 5% by mass.
[Formation of Image-Recording Layer]
The image-recording layer in the planographic printing plate precursor according to the present disclosure can be formed, for example, by preparing a coating liquid by dispersing or dissolving the necessary components described above in a known solvent, coating a support with the coating liquid by a known method such as bar coating, and drying the coating liquid, as described in paragraphs “0142” and “0143” of JP2008-195018A. The coating amount (solid content) of the image-recording layer after coating and drying varies with uses, but is preferably 0.3 g/m2 to 3.0 g/m2. In a case where the coating amount is in this range, excellent sensitivity and excellent film characteristics of the image-recording layer are obtained.
As the solvent, known solvents can be used. Specific examples thereof include water, acetone, methyl ethyl ketone (2-butanone), cyclohexane, ethyl acetate, ethylene dichloride, tetrahydrofuran, toluene, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, ethylene glycol dimethyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether, acetylacetone, cyclohexanone, diacetone alcohol, ethylene glycol monomethyl ether acetate, ethylene glycol ethyl ether acetate, ethylene glycol monoisopropyl ether, ethylene glycol monobutyl ether acetate, 1-methoxy-2-propanol, 3-methoxy-1-propanol, methoxy methoxyethanol, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, 3-methoxypropyl acetate, N,N-dimethylformamide, dimethyl sulfoxide, γ-butyrolactone, methyl lactate, ethyl lactate, and the like. One solvent may be used alone, or two or more solvents may be used in combination. The concentration of solid contents in the coating liquid is preferably 1% by mass to 50% by mass.
The coating amount (solid content) of the image-recording layer after coating and drying varies with uses. However, from the viewpoint of obtaining excellent sensitivity and excellent film characteristics of the image-recording layer, the coating amount is preferably 0.3 g/m2 to 3.0 g/m2.
The film thickness of the image-recording layer in the planographic printing plate precursor according to the present disclosure is preferably 0.1 μm to 3.0 μm, and more preferably 0.3 μm to 2.0 μm.
In the present disclosure, the film thickness of each layer in the planographic printing plate precursor is checked by preparing a slice by cutting the planographic printing plate precursor in a direction perpendicular to the surface of the precursor and observing the cross section of the slice with a scanning electron microscope (SEM).
<Outermost Layer>
It is preferable that the on-press development type planographic printing plate precursor according to the present disclosure has an outermost layer on the image-recording layer.
From the viewpoint of visibility, the outermost layer preferably contains a color-altering compound.
In the on-press development type planographic printing plate precursor, the outermost layer is the outermost layer on the side of the image-recording layer that is on the support.
The outermost layer may have a function of suppressing the reaction inhibiting image formation by blocking oxygen, a function of preventing the damage of the image-recording layer, a function of preventing ablation during exposure to high-illuminance lasers, and the like.
—Color-Altering Compound—
Furthermore, the outermost layer preferably contains a color-altering compound.
The outermost layer may contain other components, such as a water-soluble polymer, a hydrophobic polymer, an oil sensitizing agent, an acid generator, and an infrared absorber, in addition to a color-altering compound. The outermost layer preferably contains a color-altering compound and a water-soluble polymer, and more preferably contains a color-altering compound, a water-soluble polymer, and a hydrophobic polymer.
In the present disclosure, “color-altering compound” refers to a compound which undergoes change in absorption in the visible light region (wavelength: 400 nm or more and less than 750 nm) due to the exposure to infrared. That is, in the present disclosure, “color-altering” means that the absorption in the visible light region (wavelength: 400 nm or more and less than 750 nm) changes due to the exposure to infrared.
Specifically, examples of the color-altering compound in the present disclosure include (1) compound that absorbs more light in the visible light region due to the exposure to infrared than before the exposure to infrared, (2) compound that is made capable of absorbing light in the visible light region due to the exposure to infrared, and (3) compound that is made incapable of absorbing light in the visible light region due to the exposure to infrared.
The infrared in the present disclosure is a ray having a wavelength of 750 nm to 1 mm, and preferably a ray having a wavelength of 750 nm to 1,400 nm.
The color-altering compound preferably includes a compound that develops color due to the exposure to infrared.
Furthermore, the color-altering compound preferably includes a decomposable compound that decomposes due to the exposure to infrared, and particularly preferably includes a decomposable compound that decomposes by either or both of heat and electron migration due to the exposure to infrared.
More specifically, the color-altering compound in the present disclosure is preferably a compound that decomposes due to the exposure to infrared (more preferably, decomposes by either or both of heat or electron migration due to the exposure to infrared) and absorbs more light in the visible light region than before the exposure to infrared or is made capable of absorbing light of shorter wavelengths and thus capable of absorbing light in the visible light region.
“Decomposes by electron migration” mentioned herein means that electrons excited to the lowest unoccupied molecular orbital (LUMO) from the highest occupied molecular orbital (HOMO) of the color-altering compound by exposure to infrared move to electron accepting groups (groups having potential close to LUMO) in a molecule by means of intramolecular electron migration and thus result in decomposition.
Hereinafter, as an example of the color-altering compound, a decomposable compound will be described.
There are no limitations on the decomposable compound as long as it absorbs at least a part of light in the infrared wavelength region (wavelength region of 750 nm to 1 mm, preferably a wavelength region of 750 nm to 1,400 nm) and decomposes. The decomposable compound is preferably a compound having maximum absorption wavelength in a wavelength region of 750 nm to 1,400 nm.
More specifically, the decomposable compound is preferably a compound that decomposes due to the exposure to infrared and generates a compound having maximum absorption wavelength in a wavelength region of 500 nm to 600 nm.
From the viewpoint of improving visibility of exposed portions, the decomposable compound is preferably a cyanine dye having a group that decomposes by exposure to infrared (specifically, R1 in Formula 1-1 to Formula 1-7).
From the viewpoint of improving visibility of exposed portions, the decomposable compound is more preferably a compound represented by Formula 1-1.
In Formula 1-1, R1 represents a group that is represented by any of Formula 2-1 to Formula 4-1, R11 to R18 each independently represent a hydrogen atom, a halogen atom, —Ra, —ORb, —SRc, or —NRdRe, Ra to Re each independently represent a hydrocarbon group, A1, A2, and a plurality of R1 to R18 may be linked to each other to form a monocyclic or polycyclic ring, A1 and A2 each independently represent an oxygen atom, a sulfur atom, or a nitrogen atom, n11 and n12 each independently represent an integer of 0 to 5, the sum of n11 and n12 is 2 or more, n13 and n14 each independently represent 0 or 1, L represents an oxygen atom, a sulfur atom, or —NR10—R10 represents a hydrogen atom, an alkyl group, or an aryl group, and Za represents a counterion that neutralizes charge.
In Formula 2-1 to Formula 4-1, R20, R30, R41, and R42 each independently represent an alkyl group or an aryl group, Zb represents a counterion that neutralizes charge, a wavy line represents a bonding site with a group represented by L in Formula 1-1.
In a case where the compound represented by Formula 1-1 is exposed to infrared, the R1-L bond is cleaved, L turns into ═O, ═S, or ═NR10, and the compound is discolored.
In Formula 1-1, R1 represents a group represented by any of Formula 2-1 to Formula 4-1.
Hereinafter, each of the group represented by Formula 2-1, the group represented by Formula 3-1, and the group represented by Formula 4-1 will be described.
In Formula 2-1, R20 represents an alkyl group or an aryl group, and the portion of the wavy line represents a bonding site with the group represented by L in Formula 1-1.
As the alkyl group represented by R20, an alkyl group having a carbon number of 1 to 30 is preferable, an alkyl group having a carbon number of 1 to 15 is more preferable, and an alkyl group having a carbon number of 1 to 10 is even more preferable.
The alkyl group may be linear or branched, or may have a ring structure.
The aryl group represented by R20 is preferably an aryl group having a carbon number of 6 to 30, more preferably an aryl group having a carbon number of 6 to 20, and even more preferably an aryl group having a carbon number of 6 to 12.
From the viewpoint of visibility, R20 is preferably an alkyl group.
From the viewpoint of decomposition properties and visibility, the alkyl group represented by R20 is preferably a secondary alkyl group or a tertiary alkyl group, and more preferably a tertiary alkyl group.
Furthermore, from the viewpoint of decomposition properties and visibility, the alkyl group represented by R20 is preferably an alkyl group having a carbon number of 1 to 8, more preferably a branched alkyl group having a carbon number of 3 to 10, even more preferably a branched alkyl group having a carbon number of 3 to 6, particularly preferably an isopropyl group or a tert-butyl group, and most preferably a tert-butyl group.
Specific examples of the group represented by Formula 2-1 will be shown below. However, the present disclosure is not limited thereto. In the following structural formulas, ● represents a bonding site with the group represented by L in Formula 1-1.
In Formula 3-1, R30 represents an alkyl group or an aryl group, and the portion of the wavy line represents a bonding site with the group represented by L in Formula 1-1.
The alkyl group and aryl group represented by R30 are the same as the alkyl group and aryl group represented by R20 in Formula 2-1, and the preferred aspects thereof are also the same.
From the viewpoint of decomposition properties and visibility, the alkyl group represented by R30 is preferably a secondary alkyl group or a tertiary alkyl group, and more preferably a tertiary alkyl group.
Furthermore, from the viewpoint of decomposition properties and visibility, the alkyl group represented by R30 is preferably an alkyl group having a carbon number of 1 to 8, more preferably a branched alkyl group having a carbon number of 3 to 10, even more preferably a branched alkyl group having a carbon number of 3 to 6, particularly preferably an isopropyl group or a tert-butyl group, and most preferably a tert-butyl group.
In addition, from the viewpoint of decomposition properties and visibility, the alkyl group represented by R30 is preferably a substituted alkyl group, more preferably a fluoro-substituted alkyl group, even more preferably a perfluoroalkyl group, and particularly preferably a trifluoromethyl group.
From the viewpoint of decomposition properties and visibility, the aryl group represented by R30 is preferably a substituted aryl group. Examples of the substituent include an alkyl group (preferably an alkyl group having a carbon number of 1 to 4), an alkoxy group (preferably an alkoxy group having a carbon number of 1 to 4), and the like.
Specific examples of the group represented by Formula 3-1 will be shown below. However, the present disclosure is not limited thereto. In the following structural formulas, ● represents a bonding site with the group represented by L in Formula 1-1.
In Formula 4-1, R41 and R42 each independently represent an alkyl group or an aryl group, Zb represents a counterion that neutralizes charge, and the portion of the wavy line represents a bonding site with the group represented by L in Formula 1-1.
The alkyl group and aryl group represented by R41 or R42 are the same as the alkyl group and aryl group represented by R21 in Formula 2, and preferred aspects thereof are also the same.
From the viewpoint of decomposition properties and visibility, R41 is preferably an alkyl group.
From the viewpoint of decomposition properties and visibility, R42 is preferably an alkyl group.
From the viewpoint of decomposition properties and visibility, the alkyl group represented by R41 is preferably an alkyl group having a carbon number of 1 to 8, more preferably an alkyl group having a carbon number of 1 to 4, and particularly preferably a methyl group.
From the viewpoint of decomposition properties and visibility, the alkyl group represented by R42 is preferably a secondary alkyl group or a tertiary alkyl group, and more preferably a tertiary alkyl group.
Furthermore, from the viewpoint of decomposition properties and visibility, the alkyl group represented by R42 is preferably an alkyl group having a carbon number of 1 to 8, more preferably a branched alkyl group having a carbon number of 3 to 10, even more preferably a branched alkyl group having a carbon number of 3 to 6, particularly preferably an isopropyl group or a tert-butyl group, and most preferably a tert-butyl group.
Zb in Formula 4-1 may be a counterion that neutralizes charge, and may be included in Za in Formula 1-1 in the entirety of the compound.
Zb is preferably a sulfonate ion, a carboxylate ion, a tetrafluoroborate ion, a hexafluorophosphate ion, a p-toluenesulfonate ion, or a perchlorate ion, and more preferably a tetrafluoroborate ion.
Specific examples of the group represented by Formula 4-1 will be shown below. However, the present disclosure is not limited thereto. In the following structural formulas,● represents a bonding site with the group represented by L in Formula 1-1.
L in Formula 1-1 is preferably an oxygen atom or —NR10—, and particularly preferably an oxygen atom.
Furthermore, R10 in —NR10— is preferably an alkyl group. The alkyl group represented by R10 is preferably an alkyl group having a carbon number of 1 to 10. The alkyl group represented by R10 may be linear or branched, or may have a ring structure.
Among the alkyl groups, a methyl group or a cyclohexyl group is preferable.
In a case where R10 in —NR10— represents an aryl group, the aryl group is preferably an aryl group having a carbon number of 6 to 30, more preferably an aryl group having a carbon number of 6 to 20, and even more preferably an aryl group having a carbon number of 6 to 12. These aryl groups may have a substituent.
In Formula 1-1, R11 to R18 preferably each independently represent a hydrogen atom, —Ra, —ORb, —SRc, or —NRdRe.
The hydrocarbon group represented by Ra to Re is preferably a hydrocarbon group having a carbon number of 1 to 30, more preferably a hydrocarbon group having a carbon number of 1 to 15, and even more preferably a hydrocarbon group having a carbon number of 1 to 10.
The hydrocarbon group may be linear or branched or may have a ring structure.
As the hydrocarbon group, an alkyl group is particularly preferable.
The aforementioned alkyl group is preferably an alkyl group having a carbon number of 1 to 30, more preferably an alkyl group having a carbon number of 1 to 15, and even more preferably an alkyl group having a carbon number of 1 to 10.
The alkyl group may be linear or branched, or may have a ring structure.
Specific examples of the alkyl group include a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, a nonyl group, a decyl group, an undecyl group, a dodecyl group, a tridecyl group, a hexadecyl group, an octadecyl group, an eicosyl group, an isopropyl group, an isobutyl group, an s-butyl group, a tert-butyl group, an isopentyl group, a neopentyl group, a 1-methylbutyl group, an isohexyl group, a 2-ethylhexyl group, a 2-methylhexyl group, a cyclohexyl group, a cyclopentyl group, and a 2-norbornyl group.
Among these alkyl groups, a methyl group, an ethyl group, a propyl group, or a butyl group is preferable.
The above alkyl group may have a substituent.
Examples of the substituent include an alkoxy group, an aryloxy group, an amino group, an alkylthio group, an arylthio group, a halogen atom, a carboxy group, a carboxylate group, a sulfo group, a sulfonate group, an alkyloxycarbonyl group, an aryloxycarbonyl group, groups obtained by combining these, and the like.
R11 to R14 in Formula 1-1 preferably each independently represent a hydrogen atom or —Ra (that is, a hydrocarbon group), more preferably each independently represent a hydrogen atom or an alkyl group, and even more preferably each independently represent a hydrogen atom except in the cases described below.
Particularly, each of R11 and R13 bonded to the carbon atom that is bonded to the carbon atom to which L is bonded is preferably an alkyl group. It is more preferable that R11 and R13 be linked to each other to form a ring. The ring to be formed in this way may be a monocyclic or polycyclic ring. Specifically, examples of the ring to be formed include a monocyclic ring such as a cyclopentene ring, a cyclopentadiene ring, a cyclohexene ring, or a cyclohexadiene ring, and a polycyclic ring such as an indene ring or an indole ring.
Furthermore, it is preferable that R11 bonded to the carbon atom to which A1+ is bonded be linked to R15 or R16 (preferably R16) to form a ring, and R14 bonded to the carbon atom to which A2 is bonded be linked to R17 or R18 (preferably R18) to form a ring.
In Formula 1-1, n13 is preferably 1, and R16 is preferably —Ra (that is, a hydrocarbon group).
Furthermore, it is preferable that R16 be linked to R12 bonded to the carbon atom, to which A1+ is bonded, to form a ring. As the ring to be formed, an indolium ring, a pyrylium ring, a thiopyrylium ring, a benzoxazoline ring, or a benzimidazoline ring is preferable, and an indolium ring is more preferable from the viewpoint of improving visibility of exposed portions. These rings may further have a substituent.
In Formula 1-1, n14 is preferably 1, and R18 is preferably —Ra (that is, a hydrocarbon group).
Furthermore, it is preferable that R18 be linked to R14 bonded to the carbon atom, to which A2 is bonded, to form a ring. As the ring to be formed, an indole ring, a pyran ring, a thiopyran ring, a benzoxazole ring, or a benzimidazole ring is preferable, and an indole ring is more preferable from the viewpoint of improving visibility of exposed portions. These rings may further have a substituent.
It is preferable that R16 and R18 in Formula 1-1 be the same group. In a case where R16 and R18 each form a ring, it is preferable that the formed rings have the same structure except for A1+ and A2.
It is preferable that R15 and R17 in Formula 1-1 be the same group. Furthermore, R15 and R17 are preferably —Ra (that is, a hydrocarbon group), more preferably an alkyl group, and even more preferably a substituted alkyl group.
From the viewpoint of improving water solubility, R15 and R17 in the compound represented by Formula 1-1 are preferably a substituted alkyl group.
Examples of the substituted alkyl group represented by R15 or R17 include a group represented by any of Formula (a1) to Formula (a4).
In Formula (a1) to Formula (a4), RW0 represents an alkylene group having a carbon number of 2 to 6, W represents a single bond or an oxygen atom, and nW1 represents an integer of 1 to 45, RW1 represents an alkyl group having a carbon number of 1 to 12 or —C(═O)—RW5, RW5 represents an alkyl group having a carbon number of 1 to 12, RW2 to RW4 each independently represent a single bond or an alkylene group having a carbon number of 1 to 12, and M represents a hydrogen atom, a sodium atom, a potassium atom, or an onium group.
Specific examples of the alkylene group represented by RW0 in Formula (a1) include an ethylene group, a n-propylene group, an isopropylene group, a n-butylene group, an isobutylene group, a n-pentylene group, an isopentylene group, a n-hexyl group, an isohexyl group, and the like. Among these, an ethylene group, a n-propylene group, an isopropylene group, or a n-butylene group is preferable, and a n-propylene group is particularly preferable.
nW1 is preferably 1 to 10, more preferably 1 to 5, and particularly preferably 1 to 3.
Specific examples of the alkyl group represented by RW1 include a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, an isobutyl group, a tert-butyl group, an n-pentyl group, an isopentyl group, a neopentyl group, an n-hexyl group, an n-octyl group, an n-dodecyl group, and the like. Among these, a methyl group, an ethyl group, an n-propyl group, an isopropyl group, an n-butyl group, or a tert-butyl group is preferable, a methyl group or an ethyl group is more preferable, and a methyl group is particularly preferable.
The alkyl group represented by RW5 is the same as the alkyl group represented by RW1. Preferred aspects of the alkyl group represented by RW5 are the same as preferred aspects of the alkyl group represented by RW1.
Specific examples of the group represented by Formula (a1) will be shown below. However, the present disclosure is not limited thereto. In the following structural formulas, Me represents a methyl group, Et represents an ethyl group, and * represents a bonding site.
Specific examples of the alkylene group represented by RW2 to RW4 in Formula (a2) to Formula (a4) include a methylene group, an ethylene group, a n-propylene group, an isopropylene group, a n-butylene group, an isobutylene group, a n-pentylene group, an isopentylene group, a n-hexyl group, an isohexyl group, a n-octylene group, a n-dodecylene group, and the like. Among these, an ethylene group, a n-propylene group, an isopropylene group, or a n-butylene group is preferable, and an ethylene group or a n-propylene group is particularly preferable.
In Formula (a3), two Ms may be the same as or different from each other.
Examples of the onium group represented by M in Formula (a2) to Formula (a4) include an ammonium group, an iodonium group, a phosphonium group, a sulfonium group, and the like.
All of CO2M in Formula (a2), PO3M2 in Formula (a2), and SO3M in Formula (a4) may have an anion structure from which M is dissociated. The countercation of the anion structure may be A1+ or a cation that can be contained in R1-L in Formula 1-1.
Among the groups represented by Formula (a1) to Formula (a4), the group represented by Formula (a1), Formula (a2), or Formula (a4) is preferable.
n11 and n12 in Formula 1-1 are preferably the same as each other, and preferably both represent an integer of 1 to 5, more preferably both represent an integer of 1 to 3, even more preferably both represent 1 or 2, and particularly preferably both represent 2.
A1 and A2 in Formula 1-1 each independently represent an oxygen atom, a sulfur atom, or a nitrogen atom. Among these, a nitrogen atom is preferable.
A1 and A2 in Formula 1-1 are preferably the same atoms.
Za in Formula 1-1 represents a counterion that neutralizes charge.
In a case where all of R11 to R18 and R1-L are groups having a neutral charge, Za is a monovalent counteranion. Here, R11 to R18 and R1-L may have an anion structure or a cation structure. For example, in a case where two or more among R11 to R18 and R1-L have an anion structure, Za can also be a countercation.
In a case where the cyanine dye represented by Formula 1-1 has such a structure that the overall charge of the compound is neutral except for Za, Za is unnecessary.
In a case where Za is a counteranion, examples thereof include a sulfonate ion, a carboxylate ion, a tetrafluoroborate ion, a hexafluorophosphate ion, a p-toluenesulfonate ion, a perchlorate ion, and the like. Among these, a tetrafluoroborate ion is preferable.
In a case where Za is a countercation, examples thereof include an alkali metal ion, an alkaline earth metal ion, an ammonium ion, a pyridinium ion, a sulfonium ion, and the like. Among these, a sodium ion, a potassium ion, an ammonium ion, a pyridinium ion, or a sulfonium ion is preferable, and a sodium ion, a potassium ion, or an ammonium ion is more preferable.
From the viewpoint of improving visibility of exposed portions, the decomposable compound is more preferably a compound represented by Formula 1-2 (that is, a cyanine dye).
In Formula 1-2, R1 represents a group that is represented by any of Formula 2-1 to Formula 4-1, R19 to R22 each independently represent a hydrogen atom, a halogen atom, —Ra, —ORb, —CN, —SRc, or —NRdRe, R23 and R24 each independently represent a hydrogen atom or —Ra, Ra to Re each independently represent a hydrocarbon group, R19 and R20, R21 and R22, or R23 and R24 may be linked to each other to form a monocyclic or polycyclic ring, L represents an oxygen atom, a sulfur atom, or —NR10—, R10 represents a hydrogen atom, an alkyl group, or an aryl group, Rd1 to Rd4, W1, and W2 each independently represent an alkyl group which may have a substituent, and Za represents a counterion that neutralizes charge.
R1 in Formula 1-2 has the same definition as R1 in Formula 1-1, and preferred aspects thereof are also the same.
In Formula 1-2, R19 to R22 preferably each independently represent a hydrogen atom, a halogen atom, —Ra, —ORb, or —CN.
More specifically, R19 and R21 are preferably a hydrogen atom or —Ra.
Furthermore, R20 and R22 are preferably a hydrogen atom, —Ra, —ORb, or —CN.
—Ra represented by R19 to R22 is preferably an alkyl group or an alkenyl group.
In a case where all of R19 to R22 are —Ra, it is preferable that R19 and R20 and R21 and R22 be linked to each other to form a monocyclic or polycyclic ring.
Examples of the ring formed of R19 and R20 or R21 and R22 linked to each other include a benzene ring, a naphthalene ring, and the like.
R23 and R24 in Formula 1-2 are preferably linked to each other to form a monocyclic or polycyclic ring.
The ring formed of R23 and R24 linked to each other may be a monocyclic or polycyclic ring. Specifically, examples of the ring to be formed include a monocyclic ring such as a cyclopentene ring, a cyclopentadiene ring, a cyclohexene ring, or a cyclohexadiene ring, and a polycyclic ring such as an indene ring.
Rd1 to Rd4 in Formula 1-2 are preferably an unsubstituted alkyl group. Furthermore, all of Rd1 to Rd4 are preferably the same group.
Examples of the unsubstituted alkyl group include unsubstituted alkyl groups having a carbon number of 1 to 4. Among these, a methyl group is preferable.
From the viewpoint of improving water solubility of the compound represented by Formula 1-2, W1 and W2 in Formula 1-2 preferably each independently represent a substituted alkyl group.
Examples of the substituted alkyl group represented by W1 and W2 include a group represented by any of Formula (a1) to Formula (a4) in Formula 1-1, and preferred aspects thereof are also the same.
From the viewpoint of on-press developability, W1 and W2 preferably each independently represent an alkyl group having a substituent. The alkyl group preferably has at least —OCH2CH2—, a sulfo group, a salt of a sulfo group, a carboxy group, or a salt of a carboxy group, as the substituent.
Za represents a counterion that neutralizes charge in the molecule.
In a case where all of R19 to R22, R23 and R24, Rd1 to Rd4, W1, W2, and R1-L are groups having a neutral charge, Za is a monovalent counteranion. Here, R19 to R22, R23 and R24, RE1 to Rd4, W1, W2, and R1-L may have an anion structure or a cation structure. For example, in a case where two or more among R19 to R22, R23 and R24, RE1 to Rd4, W1, W2, and R1-L have an anion structure, Za can be a countercation.
In a case where the compound represented by Formula 1-2 has such a structure that the overall charge of the compound is neutral except for Za, Za is unnecessary.
Examples of the case where Za is a counteranion are the same as such examples of Za in Formula 1-1, and preferred aspects thereof are also the same. Furthermore, examples of the case where Za is a countercation are the same as such examples of Za in Formula 1-1, and preferred aspects thereof are also the same.
From the viewpoint of decomposition properties and visibility, the cyanine dye as a decomposable compound is even more preferably a compound represented by any of Formula 1-3 to Formula 1-7.
Particularly, from the viewpoint of decomposition properties and visibility, the cyanine dye is preferably a compound represented by any of Formula 1-3, Formula 1-5, and Formula 1-6.
In Formula 1-3 to Formula 1-7, R1 represents a group that is represented by any of Formula 2-1 to Formula 4-1, R19 to R22 each independently represent a hydrogen atom, a halogen atom, —Ra, —ORb, —CN, —SRc, or —NRdRe, R25 and R26 each independently represent a hydrogen atom, a halogen atom, or —Ra, Ra to Re each independently represent a hydrocarbon group, R19 and R20, R21 and R22, or R25 and R26 may be linked to each other to form a monocyclic or polycyclic ring, L represents an oxygen atom, a sulfur atom, or —NR10—, R10 represents a hydrogen atom, an alkyl group, or an aryl group, RE1 to Rd4, W1, and W2 each independently represent an alkyl group which may have a substituent, and Za represents a counterion that neutralizes charge.
R1, R19 to R22, Rd1 to Rd4, W1, W2, and L in Formula 1-3 to Formula 1-7 have the same definitions as R1, R19 to R22, Rd1 to Rd4, W1, W2, and L in Formula 1-2, and preferred aspects thereof are also the same.
R25 and R26 in Formula 1-7 preferably each independently represent a hydrogen atom or an alkyl group, more preferably each independently represent an alkyl group, and particularly preferably each independently represent a methyl group.
Specific examples of the cyanine dye as a decomposable compound will be shown below. However, the present disclosure is not limited thereto.
Furthermore, as the cyanine dye which is a decomposable compound, the infrared absorbing compound described in WO2019/219560A can be suitably used.
The color-altering compound may include an acid chromogenic agent.
As the acid chromogenic agent, it is possible to use the compounds described above as acid chromogenic agents in the image-recording layer, and preferred aspects thereof are also the same.
One color-altering compound may be used alone, or two or more components may be combined and used as the color-altering compound.
As the color-altering compound, the decomposable compound described above and the acid generator that will be described later may be used in combination.
From the viewpoint of visibility, the content of the color-altering compound in the outermost layer with respect to the total mass of the outermost layer is preferably 0.10% by mass to 50% by mass, more preferably 0.50% by mass to 30% by mass, and even more preferably 1.0% by mass to 20% by mass.
From the viewpoint of visibility, MX/MY which is a ratio of a content MX of the color-altering compound in the outermost layer to a content MY of the infrared absorber in the image-recording layer is preferably 0.1 or more, more preferably 0.2 or more, and particularly preferably 0.3 or more and 3.0 or less.
—Water-Soluble Polymer—
From the viewpoint of development removability (more preferably on-press developability), the outermost layer preferably contains a water-soluble polymer.
In the present disclosure, a water-soluble polymer refers to a polymer that dissolves 1 g or more in 100 g of pure water at 70° C. and is not precipitated even though a solution of 1 g of the polymer in 100 g of pure water at 70° C. is cooled to 25° C.
Examples of the water-soluble polymer used in the outermost layer include polyvinyl alcohol, modified polyvinyl alcohol, polyvinylpyrrolidone, a water-soluble cellulose derivative, polyethylene glycol, poly(meth)acrylonitrile, and the like.
As the modified polyvinyl alcohol, acid-modified polyvinyl alcohol having a carboxy group or a sulfo group is preferably used. Specific examples thereof include modified polyvinyl alcohols described in JP2005-250216A and JP2006-259137A.
Preferred examples of the water-soluble polymer include polyvinyl alcohol.
Particularly, as the water-soluble polymer to be used, polyvinyl alcohol having a saponification degree of 50% or more is more preferable.
The saponification degree is preferably 60% or higher, more preferably 70% or higher, and even more preferably 85% or higher. The upper limit thereof of the saponification degree is not particularly limited, and may be 100% or less.
The saponification degree is measured according to the method described in JIS K 6726: 1994.
Preferred examples of the water-soluble polymer also include polyvinylpyrrolidone.
As the water-soluble polymer, it is also preferable to use polyvinyl alcohol and polyvinylpyrrolidone in combination.
One water-soluble polymer may be used alone, or two or more water-soluble polymers may be used in combination.
In a case where the outermost layer contains a water-soluble polymer, the content of the water-soluble polymer with respect to the total mass of the outermost layer is preferably 1% by mass to 99% by mass, more preferably 3% by mass to 97% by mass, and even more preferably 5% by mass to 95% by mass.
—Other Components—
The outermost layer may contain other components such as a hydrophobic polymer, an oil sensitizing agent, an acid generator, and an infrared absorber, in addition to the color-altering compound and water-soluble polymer described above.
Hereinafter, those other components will be described.
<<Hydrophobic Polymer>>
The outermost layer preferably contains a hydrophobic polymer.
The hydrophobic polymer refers to a polymer that dissolves less than 1 g or does not dissolve in 100 g of pure water at 70° C.
Examples of the hydrophobic polymer include polyethylene, polystyrene, polyvinyl chloride, polyvinylidene chloride, polyalkyl (meth)acrylate ester (for example, polymethyl (meth)acrylate, polyethyl (meth)acrylate, polybutyl (meth)acrylate, and the like), a copolymer obtained by combining raw material monomers of these polymers, and the like.
The hydrophobic polymer preferably includes a polyvinylidene chloride resin.
Furthermore, the hydrophobic polymer preferably includes a styrene-acrylic copolymer.
In addition, from the viewpoint of on-press developability, the hydrophobic polymer is preferably hydrophobic polymer particles.
One hydrophobic polymer may be used alone, or two or more hydrophobic polymers may be used in combination.
In a case where the outermost layer contains a hydrophobic polymer, the content of the hydrophobic polymer with respect to the total mass of the outermost layer is preferably 1% by mass to 80% by mass, and more preferably 5% by mass to 50% by mass.
<<Acid Generator>>
In a case where an acid chromogenic agent is used as a color-altering compound, the outermost layer preferably contains an acid generator.
“Acid generator” in the present disclosure is a compound that generates an acid by light or heat. Specifically, the acid generator refers to a compound that generates an acid by being decomposed by exposure to infrared.
The acid to be generated is preferably a strong acid having a pKa of 2 or less, such as sulfonic acid or hydrochloric acid. The acid generated from the acid generator enables the acid chromogenic agent to discolor.
Specifically, as the acid generator, from the viewpoint of sensitivity and stability, an onium salt compound is preferable.
Specific examples of onium salts suitable as the acid generator include the compounds described in paragraphs “0121” to “0124” of WO2016/047392A.
Particularly, sulfonate, carboxylate, BPh4−, BF4−, PF6−, ClO4− of triarylsulfonium or diaryliodonium, and the like are preferable. Ph represents a phenyl group.
One acid generator may be used alone, or two or more acid generators may be used in combination.
In a case where the outermost layer contains an acid generator, the content of the acid generator with respect to the total mass of the outermost layer is preferably 0.5% by mass to 30% by mass, and more preferably 1% by mass to 20% by mass.
The outermost layer may contain known additives such as an oil sensitizing agent, an inorganic lamellar compound, and a surfactant, in addition to the components described above.
The outermost layer is formed by coating by a known method and drying.
The coating amount of the outermost layer (solid content) is preferably 0.01 g/m2 to 10 g/m2, more preferably 0.02 g/m2 to 3 g/m2, and particularly preferably 0.1 g/m2 to 2.0 g/m2.
The film thickness of the outermost layer is preferably 0.1 μm to 5.0 μm, and more preferably 0.3 μm to 4.0 μm.
The film thickness of the outermost layer is preferably 0.1 times to 5.0 times the film thickness of the image-recording layer that will be described later, and more preferably 0.2 times to 3.0 times the film thickness of the image-recording layer that will be described later.
The outermost layer may contain known additives such as a plasticizer for imparting flexibility, a surfactant for improving coating properties, and inorganic particles for controlling surface sliding properties.
<Support>
The planographic printing plate precursor according to the present disclosure has a support.
The support to be used can be appropriately selected from known supports for a planographic printing plate precursor.
As the support, a support having a hydrophilic surface (hereinafter, also called “hydrophilic support”) is preferable.
As the support in the present disclosure, an aluminum plate is preferable which has been roughened using a known method and has undergone an anodization treatment. That is, the support in the present disclosure preferably has an aluminum plate and an aluminum anodic oxide film disposed on the aluminum plate.
The aforementioned support preferably has an aluminum plate and an anodic oxide film of aluminum disposed on the aluminum plate, the anodic oxide film is preferably at a position closer to a side of the image-recording layer than the aluminum plate and preferably has micropores extending in a depth direction from the surface of the anodic oxide film on the side of the image-recording layer, and the average diameter of the micropores within the surface of the anodic oxide film is preferably more than 10 nm and 100 nm or less.
Furthermore, the micropores are preferably each composed of a large diameter portion that extends to a position at a depth of 10 nm to 1,000 nm from the surface of the anodic oxide film and a small diameter portion that is in communication with a bottom portion of the large diameter portion and extends to a position at a depth of 20 nm to 2,000 nm from a communicate position, an average diameter of the large diameter portion within the surface of the anodic oxide film is preferably 15 nm to 100 nm, and an average diameter of the small diameter portion at the communicate position is preferably 13 nm or less.
The aluminum support 12a has a laminated structure in which an aluminum plate 18 and an anodic oxide film 20a of aluminum (hereinafter, also simply called “anodic oxide film 20a”) are laminated in this order. The anodic oxide film 20a in the aluminum support 12a is positioned such that the anodic oxide film 20a is closer to the image-recording layer side than the aluminum plate 18. That is, it is preferable that the planographic printing plate precursor according to the present disclosure have at least an anodic oxide film, an image-recording layer, and a water-soluble resin layer in this order on an aluminum plate.
—Anodic Oxide Film—
Hereinafter, preferred aspects of the anodic oxide film 20a will be described.
The anodic oxide film 20a is a film prepared on a surface of the aluminum plate 18 by an anodization treatment. This film has uniformly distributed ultrafine micropores 22a approximately perpendicular to the surface of the film. The micropores 22a extend from a surface of the anodic oxide film 20a on the image-recording layer side (a surface of the anodic oxide film 20a opposite to the aluminum plate 18) along the thickness direction (toward the aluminum plate 18).
The average diameter (average opening diameter) of the micropores 22a, which are in the anodic oxide film 20a, at the surface of the anodic oxide film 20a is preferably more than 10 nm and 100 nm or less. Particularly, from the viewpoint of balance between printing durability, antifouling properties, and image visibility, the average diameter of the micropores 22a is more preferably 15 nm to 60 nm, even more preferably 20 nm to 50 nm, and particularly preferably 25 nm to 40 nm. The internal diameter of the pores may be larger or smaller than the pore diameter within the surface layer.
In a case where the average diameter is more than 10 nm, printing durability and image visibility are excellent. Furthermore, in a case where the average diameter is 100 nm or less, printing durability is excellent.
The average diameter of the micropores 22a is a value determined by observing the surface of the anodic oxide film 20a with a field emission scanning electron microscope (FE-SEM) at 150,000× magnification (N=4), measuring the size (diameter) of 50 micropores existing in a range of 400 nm×600 nm2 in the obtained 4 images, and calculating the arithmetic mean thereof.
In a case where the shape of the micropores 22a is not circular, the equivalent circular diameter is used. “Equivalent circular diameter” is a diameter determined on an assumption that the opening portion is in the form of a circle having the same projected area as the projected area of the opening portion.
The shape of the micropores 22a is not particularly limited. In
In the support, the micropores may be each composed of a large diameter portion that extends to a position at a certain depth from the surface of the anodic oxide film and a small diameter portion that is in communication with a bottom portion of the large diameter portion and extends to a position at a certain depth from the communicate position.
For example, as shown in
For example, the micropores 22b in the anodic oxide film 20b are each composed of the large diameter portion 24 that extends to a position at a depth of 10 nm to 1,000 nm (depth D: see
—Manufacturing Method of Support—
As a manufacturing method of the support used in the present disclosure, for example, a manufacturing method is preferable in which the following steps are sequentially performed.
Hereinafter, the procedure of each step will be specifically described.
<<Roughening Treatment Step>>
The roughening treatment step is a step of performing a roughening treatment including an electrochemical roughening treatment on the surface of the aluminum plate. This step is preferably performed before the anodization treatment step which will be described later. However, in a case where the surface of the aluminum plate already has a preferable shape, the roughening treatment step may not be performed. This step can be carried out by the method described in paragraphs “0086” to “0101” of JP2019-162855A.
<<Anodization Treatment Step>>
The procedure of the anodization treatment step is not particularly limited as long as the aforementioned micropores can be obtained. Examples thereof include known methods.
In the anodization treatment step, an aqueous solution of sulfuric acid, phosphoric acid, oxalic acid, or the like can be used as an electrolytic cell. For example, the concentration of sulfuric acid is 100 g/L to 300 g/L.
The conditions of the anodization treatment are appropriately set depending on the electrolytic solution used. For example, the liquid temperature is 5° C. to 70° C. (preferably 10° C. to 60° C.), the current density is 0.5 A/dm2 to 60 A/dm2 (preferably 1 A/dm2 to 60 A/dm2), the voltage is 1 V to 100 V (preferably 5 V to 50 V), the electrolysis time is 1 second to 100 seconds (preferably 5 seconds to 60 seconds), and the film amount is 0.1 g/m2 to 5 g/m2 (preferably 0.2 g/m2 to 3 g/m2).
<<Pore Widening Treatment>>
The pore widening treatment is a treatment of enlarging the diameter of micropores (pore diameter) present in the anodic oxide film formed by the aforementioned anodization treatment step (pore diameter enlarging treatment).
The pore widening treatment can be carried out by bringing the aluminum plate obtained by the anodization treatment step into contact with an aqueous acid solution or an aqueous alkali solution. The contact method is not particularly limited, and examples thereof include a dipping method and a spraying method.
As necessary, the support may have a backcoat layer on the side opposite to the image-recording layer, the backcoat layer containing the organic polymer compound described in JP1993-045885A (JP-H5-45885A) or the alkoxy compound of silicon described in JP1994-035174A (JP-H6-35174A).
<Undercoat Layer>
The planographic printing plate precursor according to the present disclosure preferably has an undercoat layer (also called interlayer in some cases) between the image-recording layer and the support. The undercoat layer enhances the adhesion between the support and the image-recording layer in an exposed portion, and enables the image-recording layer to be easily peeled from the support in a non-exposed portion. Therefore, the undercoat layer contributes to the improvement of developability without deteriorating printing durability. Furthermore, in the case of exposure to infrared laser, the undercoat layer functions as a heat insulating layer and thus brings about an effect of preventing sensitivity reduction resulting from the diffusion of heat generated by exposure to the support.
Examples of compounds that are used in the undercoat layer include polymers having adsorbent groups that can be adsorbed onto the surface of the support and hydrophilic groups. In order to improve adhesiveness to the image-recording layer, polymers having adsorbent groups and hydrophilic groups plus crosslinking groups are preferable. The compounds that are used in the undercoat layer may be low-molecular-weight compounds or polymers. As necessary, as the compounds that are used in the undercoat layer, two or more compounds may be used by being mixed together.
In a case where the compound used in the undercoat layer is a polymer, a copolymer of a monomer having an adsorbent group, a monomer having a hydrophilic group, and a monomer having a crosslinking group is preferable.
As the adsorbent group that can be adsorbed onto the surface of the support, a phenolic hydroxyl group, a carboxy group, —PO3H2, —OPO3H2, —CONHSO2—, —SO2NHSO2—, and —COCH2COCH3 are preferable. As the hydrophilic groups, a sulfo group or salts thereof and salts of a carboxy group are preferable. As the crosslinking groups, an acryloyl group, a methacryloyl group, an acrylamide group, a methacrylamide group, an allyl group, and the like are preferable.
The polymer may have a crosslinking group introduced by the formation of a salt of a polar substituent of the polymer and a compound that has a substituent having charge opposite to that of the polar substituent and an ethylenically unsaturated bond, or may be further copolymerized with monomers other than the monomers described above and preferably with hydrophilic monomers.
Specifically, for example, silane coupling agents having addition polymerizable ethylenic double bond reactive groups described in JP1998-282679A (JP-H10-282679A) and phosphorus compounds having ethylenic double bond reactive groups described in JP1990-304441A (JP-H02-304441A) are suitable. The low-molecular-weight compounds or polymer compounds having crosslinking groups (preferably ethylenically unsaturated bonding groups), functional groups that interact with the surface of the support, and hydrophilic groups described in JP2005-238816A, JP2005-125749A, JP2006-239867A, and JP2006-215263A are also preferably used.
For example, the high-molecular-weight polymers having adsorbent groups that can be adsorbed onto the surface of the support, hydrophilic groups, and crosslinking groups described in JP2005-125749A and JP2006-188038A are more preferable.
The content of ethylenically unsaturated bonding group in the polymer used in the undercoat layer is preferably 0.1 mmol to 10.0 mmol per gram of the polymer, and more preferably 0.2 mmol to 5.5 mmol per gram of the polymer.
The weight-average molecular weight (Mw) of the polymer used in the undercoat layer is preferably 5,000 or more, and more preferably 10,000 to 300,000.
—Hydrophilic Compound—
From the viewpoint of developability, it is preferable that the undercoat layer contain a hydrophilic compound.
The hydrophilic compound is not particularly limited, and known hydrophilic compounds used for the undercoat layer can be used.
Preferred examples of the hydrophilic compound include phosphonic acids having an amino group such as carboxymethyl cellulose and dextrin, an organic phosphonic acid, an organic phosphoric acid, an organic phosphinic acid, amino acids, a hydrochloride of an amine having a hydroxy group, and the like.
In addition, examples of preferable hydrophilic compounds include a compound having an amino group or a functional group capable of inhibiting polymerization and a group that interacts with the surface of the support (for example, 1,4-diazabicyclo[2.2.2]octane (DABCO), 2,3,5,6-tetrahydroxy-p-quinone, chloranil, sulfophthalic acid, ethylenediaminetetraacetic acid (EDTA) or a salt thereof, hydroxyethyl ethylenediaminetriacetic acid or a salt thereof, dihydroxyethyl ethylenediaminediacetic acid or a salt thereof, hydroxyethyl iminodiacetic acid or a salt thereof, and the like).
From the viewpoint of scratch and contamination suppressiveness, it is preferable that the hydrophilic compound include hydroxycarboxylic acid or a salt thereof.
Furthermore, from the viewpoint of scratch and contamination suppressiveness, it is preferable that the hydrophilic compound, which is preferably hydroxycarboxylic acid or a salt thereof, be contained in a layer on the aluminum support. The layer on the aluminum support is preferably a layer on the side where the image-recording layer is formed or a layer in contact with the aluminum support.
Preferred examples of the layer on the aluminum support include a layer in contact with the aluminum support, such as the undercoat layer or the image-recording layer. Furthermore, a layer other than the layer in contact with the aluminum support, for example, the outermost layer or the image-recording layer may contain a hydrophilic compound and preferably contains hydroxycarboxylic acid or a salt thereof.
In the planographic printing plate precursor according to the present disclosure, from the viewpoint of scratch and contamination suppressiveness, it is preferable that the image-recording layer contain hydroxycarboxylic acid or a salt thereof.
Moreover, regarding the planographic printing plate precursor according to the present disclosure, for example, an aspect is also preferable in which the surface of the aluminum support on the image-recording layer side is treated with a composition (for example, an aqueous solution or the like) containing at least hydroxycarboxylic acid or a salt thereof. In a case where the above aspect is adopted, at least some of the hydroxycarboxylic acid or a salt thereof used for treatment can be detected in a state of being contained in the layer on the image-recording layer side (for example, the image-recording layer or the undercoat layer) that is in contact with the aluminum support.
In a case where the layer on the side of the image-recording layer that is in contact with the aluminum support, such as the undercoat layer, contains hydroxycarboxylic acid or a salt thereof, the surface of the aluminum support on the image-recording layer side can be hydrophilized, and it is easy for the surface of the aluminum support on the image-recording layer side to have a water contact angle of 1100 or less measured by an airborne water droplet method, which result in excellent scratch and contamination suppressiveness.
“Hydroxycarboxylic acid” is the generic term for organic compounds having one or more carboxy groups and one or more hydroxy groups in one molecule. These compounds are also called hydroxy acid, oxy acid, oxycarboxylic acid, or alcoholic acid (see Iwanami Dictionary of Physics and Chemistry, 5th Edition, published by Iwanami Shoten, Publishers. (1998)).
The hydroxycarboxylic acid or a salt thereof is preferably represented by Formula (HC).
RHC(OH)mhc(COOMHC)mhc Formula (HC)
In Formula (HC), RHC represents an (mhc+nhc)-valent organic group, MHC each independently represent a hydrogen atom, an alkali metal, or an onium, and mhc and nhc each independently represent an integer of 1 or more. In a case where n is 2 or more, MHC may be the same as or different from each other.
Examples of the (mhc+nhc)-valent organic group represented by RHC in Formula (HC) include an (mhc+nhc)-valent hydrocarbon group and the like. The hydrocarbon group may have a substituent and/or a linking group.
Examples of the hydrocarbon group include an (mhc+nhc)-valent group derived from aliphatic hydrocarbon, such as an alkylene group, an alkanetriyl group, an alkanetetrayl group, an alkanepentayl group, an alkenylene group, an alkenetriyl group, an alkenetetrayl group, and alkenepentayl group, an alkynylene group, an alkynetriyl group, alkynetetrayl group, or an alkynepentayl group, an (mhc+nhc)-valent group derived from aromatic hydrocarbon, such as an arylene group, an arenetriyl group, an arenetetrayl group, or an arenepentayl group, and the like. Examples of the substituent include an alkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group, and the like. Specific examples of the substituent include a methyl group, an ethyl group, a propyl group, a butyl group, a pentyl group, a hexyl group, a heptyl group, an octyl group, a nonyl group, a decyl group, an undecyl group, a dodecyl group, a tridecyl group, a hexadecyl group, an octadecyl group, eicosyl group, isopropyl group, isobutyl group, s-butyl group, t-butyl group, isopentyl group, a neopentyl group, a 1-methylbutyl group, an isohexyl group, a 2-ethylhexyl group, a 2-methylhexyl group, a cyclohexyl group, a cyclopentyl group, a 2-norbornyl group, a methoxymethyl group, a methoxyethoxyethyl group, an allyloxymethyl group, a phenoxymethyl group, an acetyloxymethyl group, a benzoyloxymethyl group, a benzyl group, a phenethyl group, an α-methylbenzyl group, a 1-methyl-1-phenylethyl group, a p-methylbenzyl group, a cinnamyl group, an allyl group, a 1-propenylmethyl group, a 2-butenyl group, a 2-methylallyl group, a 2-methylpropenylmethyl group, a 2-propynyl group, a 2-butynyl group, a 3-butynyl group, a phenyl group, a biphenyl group, a naphthyl group, a tolyl group, a xylyl group, a mesityl group, a cumenyl group, a methoxyphenyl group, an ethoxyphenyl group, a phenoxyphenyl group, an acetoxyphenyl group, a benzoyloxyphenyl group, a methoxycarbonylphenyl group, an ethoxycarbonylphenyl group, a phenoxycarbonylphenyl group, and the like. Furthermore, the linking group is composed of at least one atom selected from the group consisting of a hydrogen atom, a carbon atom, an oxygen atom, a nitrogen atom, a sulfur atom, and a halogen atom, and the carbon number is preferably 1 to 50. Specific examples thereof include an alkylene group, a substituted alkylene group, an arylene group, a substituted arylene group, and the like. The linking group may have a structure in which a plurality of these divalent groups is linked through any of an amide bond, an ether bond, a urethane bond, a urea bond, and an ester bond.
Examples of the alkali metal represented by MHC include lithium, sodium, potassium, and the like. Among these, sodium is particularly preferable. Examples of the onium include ammonium, phosphonium, sulfonium, and the like. Among these, ammonium is particularly preferable.
From the viewpoint of scratch and contamination suppressiveness, MHC is preferably an alkali metal or an onium, and more preferably an alkali metal.
The sum of mhc and nhc is preferably 3 or more, more preferably 3 to 8, and even more preferably 4 to 6.
The molecular weight of the hydroxycarboxylic acid or a salt thereof is preferably 600 or less, more preferably 500 or less, and particularly preferably 300 or less. The molecular weight is preferably 76 or more.
Specifically, examples of the hydroxycarboxylic acid constituting the hydroxycarboxylic acid or a salt of the hydroxycarboxylic acid include gluconic acid, glycolic acid, lactic acid, tartronic acid, hydroxybutyrate (such as 2-hydroxybutyrate, 3-hydroxybutyrate, or γ-hydroxybutyrate), malic acid, tartaric acid, citramalic acid, citric acid, isocitric acid, leucine acid, mevalonic acid, pantoic acid, ricinoleic acid, ricineraidic acid, cerebronic acid, quinic acid, shikimic acid, a monohydroxybenzoic acid derivative (such as salicylic acid, creosotic acid (homosalicylic acid, hydroxy(methyl) benzoate), vanillic acid, or syringic acid), a dihydroxybenzoic acid derivative (such as pyrocatechuic acid, resorcylic acid, protocatechuic acid, gentisic acid, or orsellinic acid), a trihydroxybenzoic acid derivative (such as gallic acid), a phenyl acetate derivative (such as mandelic acid, benzilic acid, or atrolactic acid), a hydrocinnamic acid derivative (such as melilotic acid, phloretic acid, coumaric acid, umbellic acid, caffeic acid, ferulic acid, sinapic acid, cerebronic acid, or carminic acid), and the like.
Among these, as the aforementioned hydroxycarboxylic acid or a hydroxycarboxylic acid constituting a salt of the hydroxycarboxylic acid, from the viewpoint of scratch and contamination suppressiveness, a compound having two or more hydroxy groups is preferable, a compound having 3 or more hydroxy groups is more preferable, a compound having 5 or more hydroxy groups is even more preferable, and a compound having 5 to 8 hydroxy groups is particularly preferable.
Furthermore, as a hydroxycarboxylic acid having one carboxy group and two or more hydroxy groups, gluconic acid or shikimic acid is preferable.
As hydroxycarboxylic acid having two or more carboxy groups and one hydroxy group, citric acid or malic acid is preferable.
As hydroxycarboxylic acid having two or more carboxy groups and two or more hydroxy groups, tartaric acid is preferable.
Among these, gluconic acid is particularly preferable as the aforementioned hydroxycarboxylic acid.
One hydrophilic compound may be used alone, or two or more hydrophilic compounds may be used in combination.
In a case where the undercoat layer contains a hydrophilic compound, which is preferably hydroxycarboxylic acid or a salt thereof, the content of the hydrophilic compound, which is preferably hydroxycarboxylic acid or a salt thereof, with respect to the total mass of the undercoat layer is preferably 0.01% by mass to 50% by mass, more preferably 0.1% by mass to 40% by mass, and particularly preferably 1.0% by mass to 30% by mass.
In order to prevent contamination over time, the undercoat layer may contain a chelating agent, a secondary or tertiary amine, a polymerization inhibitor, and the like, in addition to the following compounds for an undercoat layer.
The undercoat layer is formed by known coating methods.
The coating amount (solid content) of the undercoat layer is preferably 0.1 mg/m2 to 300 mg/m2, and more preferably 5 mg/m2 to 200 mg/m2.
The planographic printing plate precursor according to the present disclosure may have other layers in addition to those described above.
Known layers can be adopted as those other layers without particular limitations. For example, as necessary, a backcoat layer may be provided on a surface of the support that is opposite to the image-recording layer side.
(Method of Preparing Planographic Printing Plate and Planographic Printing Method)
The method of preparing a planographic printing plate according to the present disclosure preferably includes a step of exposing the planographic printing plate precursor according to the present disclosure in the shape of an image (exposure step) and a step of removing the image-recording layer having undergone exposure in a non-image area by supplying at least one selected from the group consisting of a printing ink and dampening water on a printer (on-press development step).
The planographic printing method according to the present disclosure preferably includes a step of exposing the planographic printing plate precursor according to the present disclosure in the shape of an image (exposure step), a step of removing the image-recording layer in a non-image area by supplying at least one selected from the group consisting of a printing ink and dampening water on a printer such that a planographic printing plate is prepared (on-press development step), and a step of performing printing by using the obtained planographic printing plate (hereinafter, also called “printing step”).
<Exposure Step>
The method of preparing a planographic printing plate according to the present disclosure preferably includes an exposure step of exposing the planographic printing plate precursor according to the present disclosure in the shape of an image such that an exposed portion and a non-exposed portion are formed. The planographic printing plate precursor according to the present disclosure is preferably exposed to a laser through a transparent original picture having a linear image, a halftone dot image, or the like or exposed in the shape of an image by laser light scanning according to digital data or the like.
The wavelength of a light source to be used is preferably 750 nm to 1,400 nm. As the light source having a wavelength of 750 nm to 1,400 nm, a solid-state laser or a semiconductor laser that radiates infrared is suitable. In a case where an infrared laser is used, the output is preferably 100 mW or higher, the exposure time per pixel is preferably 20 microseconds or less, and the amount of irradiation energy is preferably 10 mJ/cm2 to 300 mJ/cm2. In addition, in order to shorten the exposure time, a multibeam laser device is preferably used. The exposure mechanism may be any one of an in-plane drum method, an external surface drum method, a flat head method, or the like.
The image exposure can be carried out by a common method using a platesetter or the like. In the case of on-press development, image exposure may be carried out on a printer after the planographic printing plate precursor is mounted on the printer.
<On-Press Development Step>
The method of preparing a planographic printing plate according to the present disclosure preferably includes an on-press development step of removing the image-recording layer in a non-image area by supplying at least one selected from the group consisting of printing ink and dampening water on a printer.
Hereinafter, the on-press development method will be described.
[On-Press Development Method]
In the on-press development method, the planographic printing plate precursor having undergone image exposure is preferably supplied with an oil-based ink and an aqueous component on a printer, such that the image-recording layer in a non-image area is removed and a planographic printing plate is prepared.
That is, in a case where the planographic printing plate precursor is subjected to image exposure and then directly mounted on a printer without being subjected to any development treatment, or in a case where the planographic printing plate precursor is mounted on a printer, then subjected to image exposure on the printer, and then supplied with an oil-based ink and an aqueous component for printing, at the initial stage in the middle of printing, in a non-image area, a non-cured image-recording layer is removed by either or both of the supplied oil-based ink and the aqueous component by means of dissolution or dispersion, and the hydrophilic surface is exposed in the non-image area. On the other hand, in an exposed portion, the image-recording layer cured by exposure forms an oil-based ink-receiving portion having a lipophilic surface. What is supplied first to the surface of the plate may be any of the oil-based ink or the aqueous component. However, in view of preventing the plate from being contaminated by the components of the image-recording layer from which aqueous components are removed, it is preferable that the oil-based ink be supplied first. In the manner described above, the planographic printing plate precursor is subjected to on-press development on a printer and used as it is for printing a number of sheets. As the oil-based ink and the aqueous component, ordinary printing ink and ordinary dampening water for planographic printing are suitably used.
As the laser used for performing image exposure on the planographic printing plate precursor according to the present disclosure, a light source having a wavelength of 750 nm to 1,400 nm is preferably used. As the light source having a wavelength of 750 nm to 1,400 nm, the light sources described above are preferably used.
<Printing Step>
The planographic printing method according to the present disclosure includes a printing step of printing a recording medium by supplying a printing ink to a planographic printing plate.
The printing ink is not particularly limited, and various known inks can be used as desired. In addition, preferred examples of the printing ink include oil-based ink or ultraviolet-curable ink (UV ink).
In the printing step, as necessary, dampening water may be supplied.
Furthermore, the printing step may be successively carried out after the on-press development step or the development step using a developer, without stopping the printer.
The recording medium is not particularly limited, and known recording media can be used as desired.
In the method of preparing a planographic printing plate from the planographic printing plate precursor according to the present disclosure and in the planographic printing method according to the present disclosure, as necessary, the entire surface of the planographic printing plate precursor may be heated as necessary before exposure, in the middle of exposure, or during a period of time from exposure to development. In a case where the planographic printing plate precursor is heated as above, an image-forming reaction in the image-recording layer is accelerated, which can result in advantages such as improvement of sensitivity and printing durability, stabilization of sensitivity, and the like. Heating before development is preferably carried out under a mild condition of 150° C. or lower. In a case where this aspect is adopted, it is possible to prevent problems such as curing of a non-image area. For heating after development, it is preferable to use an extremely severe condition which is preferably in a range of 100° C. to 500° C. In a case where this aspect is adopted, a sufficient image-strengthening action is obtained, and it is possible to inhibit problems such as the deterioration of the support or the thermal decomposition of the image area.
(Coloring Agent)
The coloring agent according to the present disclosure is a coloring agent represented by Formula 1 or Formula 2, preferably a coloring agent for a compound having a group 13 element, and more preferably a coloring agent for an organic compound having a group 13 element.
In addition, the coloring agent according to the present disclosure is preferably a coloring agent for a boron compound, and more preferably a coloring agent for an organic boron compound.
In Formula 1 and Formula 2, R1 to R7 each independently represent a hydrogen atom or a monovalent organic group, L1 and L2 represent a divalent organic group, two or more groups among L1, R2, and R3 may be linked to each other to form a ring structure, two or more groups among L2, R4, and R6 may be linked to each other to form a ring structure, and two or more groups among L2, R5, and R7 may be linked to each other to form a ring structure.
Preferred aspects of the coloring agent represented by Formula 1 or Formula 2 are the same as preferred aspects of the compound represented by Formula 1 or Formula 2, except for what will be described later.
The coloring agent according to the present disclosure may contain one coloring agent represented by Formula 1 or Formula 2 or may contain two or more coloring agents represented by Formula 1 or Formula 2.
From the viewpoint of coloring properties, in the coloring agent according to the present disclosure, the content of the coloring agent represented by Formula 1 or Formula 2 with respect to the total mass of the coloring agent is preferably 0.1% by mass to 100% by mass, more preferably 1% by mass to 100% by mass, and even more preferably 10% by mass to 100% by mass.
The coloring agent according to the present disclosure may further contain an additive.
As the additive, known additives can be used, and examples thereof include a solvent, an antioxidant, a dispersant, and the like.
Hereinafter, the present disclosure will be specifically described based on examples, but the present disclosure is not limited thereto. In the present examples, unless otherwise specified, “%” and “part” mean “% by mass” and “part by mass” respectively. Unless otherwise described, the molecular weight of a polymer compound is a weight-average molecular weight (Mw), and the ratio of repeating constitutional units of a polymer compound is expressed as molar percentage. The weight-average molecular weight (Mw) is a polystyrene-equivalent molecular weight measured by gel permeation chromatography (GPC).
In addition, C-1 to C-17 used in the present example are the same compounds as C-1 to C-17 described above, respectively.
In the following chemical structural formulas, Me represents a methyl group, and Ph represents a phenyl group.
<Method of Measuring Proportion of Keto Isomer or Imine Isomer>
A sample (1.0 mg) was dissolved in 0.5 mL of deuterochloroform CDCl3 (manufactured by FUJIFILM Wako Pure Chemical Corporation) and subjected to NMR (manufactured by Bruker) spectroscopy under the condition of 25° C. The CH2 or CHR group of the keto isomer (R represents an arbitrary group depending on the compound contained in the sample to be measured) and the CH group of the enol isomer had different peaks. Therefore, the proportion (mol %) of the keto isomer was calculated from the integration ratio of each group. The proportion of the imine isomer was also calculated by the same method.
<Synthesis of C-1>
2,5-Dimethylpyrazine (5.0 g, 46.3 mmol, manufactured by Tokyo Chemical Industry Co., Ltd.), 15.6 g of potassium-t-butoxide (t-BuOK, 138.8 mmol, manufactured by FUJIFILM Wako Pure Chemical Corporation), and 30 mL of dimethylformamide (DMF) (manufactured by FUJIFILM Wako Pure Chemical Corporation) were added to a 100 mL three-neck flask, and heated and stirred at 70° C. for 1 hour. Next, 13.4 g of ethyl 4-dimethylaminobenzoate (69.4 mmol, manufactured by FUJIFILM Wako Pure Chemical Corporation) was added thereto, and the mixture was heated and stirred at 70° C. for 4 hours. After the reaction ended, the mixture was cooled to room temperature (25° C., the same applies hereinafter). Subsequently, 100 mL of an aqueous ammonium chloride solution (manufactured by FUJIFILM Wako Pure Chemical Corporation) was added thereto, and extraction was performed three times by using 100 mL of diisopropyl ether (manufactured by FUJIFILM Wako Pure Chemical Corporation). Magnesium sulfate (20 g, manufactured by FUJIFILM Wako Pure Chemical Corporation) was added to the extracted diisopropyl ether layer, and the mixture was stirred for 10 minutes and then filtered to remove magnesium sulfate. Then, the solids obtained by concentration under reduced pressure with a rotary evaporator were separated by column chromatography (developing solvent: ethyl acetate/hexane=1/2), and the target fraction was concentrated again under reduced pressure with a rotary evaporator, thereby obtaining 2.0 g of a target substance at a yield of 16.9%.
<Synthesis of C-2 and C-6 to C-15>
C-2 and C-6 to C-15 were synthesized based on the synthesis of C-1, except that 2,5-dimethylpyrazine and ethyl 4-dimethylaminobenzoate were changed.
<Synthesis of C-3>
The Tebbe's reagent (6 mL, 3 mmol, manufactured by Tokyo Chemical Industry Co., Ltd.) as a 0.5 mol/L toluene solution and 6 mL of benzene (Benzene) were added to a three-neck flask. Then, 0.45 g of 4-dimethylaminonitrile (3.07 mmol, manufactured by Tokyo Chemical Industry Co., Ltd.) was added thereto, and the mixture was heated and stirred at 60° C. for 72 hours. The mixture was cooled to room temperature, 10 g of a sodium sulfate decahydrate (manufactured by FUJIFILM Wako Pure Chemical Corporation) was then added thereto, and the mixture was stirred for 30 minutes. The obtained solution was filtered, and the filtrate was concentrated under reduced pressure. The obtained solids were separated by column chromatography (developing solvent: diisopropyl ether/dichloromethane=1/1), and the target fraction was concentrated again under reduced pressure with a rotary evaporator, thereby obtaining 0.36 g of a target substance at a yield of 77.0%.
<Synthesis of C-4 and C-5>
C-4 and C-5 were synthesized based on the synthesis of C-3, except that 4-dimethylaminonitrile was changed.
<Synthesis of C-16>
2-Cyanomethylpyridine (1.00 g, 8.46 mmol, manufactured by Tokyo Chemical Industry Co., Ltd.) and 50 mL of tetrahydrofuran (THF) (manufactured by FUJIFILM Wako Pure Chemical Corporation) were added to a three-necked flask, then 1.35 g of 60% sodium hydride (NaH) (33.9 mmol, manufactured by Tokyo Chemical Industry Co., Ltd.) was added thereto, and the mixture was stirred under the condition of room temperature for 1 hour. Subsequently, 1.33 g of 2-bromopyridine (2-bromopyridine, 8.46 mmol, manufactured by Tokyo Chemical Industry Co., Ltd.) was added thereto, and the mixture was heated under reflux for 8 hours. After the reaction ended, the mixture was cooled to room temperature, 500 mL of a 0.1 M (=mol/L) aqueous hydrochloric acid solution (manufactured by FUJIFILM Wako Pure Chemical Corporation) was added to make the mixture acidic, and then 50 mL of saturated saline was added thereto. Extraction was performed three times by using 50 mL of chloroform (manufactured by FUJIFILM Wako Pure Chemical Corporation), and the obtained solution was concentrated under reduced pressure, thereby obtaining solids. The obtained solids were separated by column chromatography (developing solvent: dichloromethane), and the target fraction was concentrated again under reduced pressure with a rotary evaporator, thereby obtaining 0.20 g of a target substance at a yield of 12.1%.
<Synthesis of C-17>
C-17 was synthesized based on the method described in paragraph 0298 of US2018/305552A.
<Preparation of Support 1>
An aluminum alloy plate made of a material 1S having a thickness of 0.3 mm was subjected to (A-a) Mechanical roughening treatment (brush grain method) to (A-i) Desmutting treatment in aqueous acidic solution described in paragraphs “0126” to “0134” of JP2012-158022A.
Then, an anodic oxide film was formed by performing (A-j) First-stage anodic oxidation treatment to (A-m) Third-stage anodic oxidation treatment described in paragraphs “0135” to “0138” of JP2012-158022A by appropriately adjusting the treatment conditions, and the obtained support was used as a support 1.
A rinsing treatment was performed between all the treatment steps. After the rinsing treatment, water was drained using a nip roller.
The details of the obtained support 1 are as below.
Support 1: value of brightness L* of surface of anodic oxide film having micropores in L*a*b* color system: 83, average diameter of large diameter portion of micropores within surface of oxide film: 35 nm (depth 100 nm), average diameter of small diameter portion of micropores at communicate position: 10 nm (depth 1,000 nm), ratio of depth of large diameter portion to average diameter of large diameter portion: 2.9
<Preparation of Support 2>
—Alkaline Etching Treatment—
An aqueous solution of caustic soda having a caustic soda concentration of 26% by mass and an aluminum ion concentration of 6.5% by mass was sprayed onto the aluminum plate at a temperature of 70° C., thereby performing an etching treatment. Then, rinsing was performed by means of spraying. The amount of dissolved aluminum within the surface to be subjected to the electrochemical roughening treatment later was 5 g/m2.
—Desmutting Treatment Using Aqueous Acidic Solution (First Desmutting Treatment)—
Next, a desmutting treatment was performed using an aqueous acidic solution. In the desmutting treatment, a 150 g/L aqueous sulfuric acid solution was used as the aqueous acidic solution. The liquid temperature was 30° C. The desmutting treatment was performed for 3 seconds by spraying the aqueous acidic solution onto the aluminum plate. Then, a rinsing treatment was performed.
—Electrochemical Roughening Treatment—
Next, an electrochemical roughening treatment was performed using alternating current and an electrolytic solution having a hydrochloric acid concentration of 14 g/L, an aluminum ion concentration of 13 g/L, and a sulfuric acid concentration of 3 g/L. The liquid temperature of the electrolytic solution was 30° C. The aluminum ion concentration was adjusted by adding aluminum chloride. The waveform of the alternating current was a sine wave in which positive and negative waveforms are symmetrical, the frequency was 50 Hz, the ratio of the anodic reaction time and the cathodic reaction time in one cycle of the alternating current was 1:1, and the current density was 75 A/dm2 in terms of the peak current value of the alternating current waveform. In addition, the quantity of electricity was 450 C/dm2 which was the total quantity of electricity used for the aluminum plate to have an anodic reaction, and the electrolysis treatment was performed 4 times by conducting electricity of 112.5 C/dm2 for 4 seconds at each treatment session. A carbon electrode was used as the counter electrode of the aluminum plate. Then, a rinsing treatment was performed.
—Desmutting Treatment Using Aqueous Acidic Solution—
Next, a desmutting treatment was performed using an aqueous acidic solution. Specifically, the desmutting treatment was performed for 3 seconds by spraying the aqueous acidic solution onto the aluminum plate. In the desmutting treatment, an aqueous solution having a sulfuric acid concentration of 170 g/L and an aluminum ion concentration of 5 g/L was used as aqueous acidic solution. The liquid temperature was 30° C.
—First-Stage Anodization Treatment—
By using the anodization device for direct current electrolysis having the structure shown in
In an anodization treatment device 610 shown in
—Pore Widening Treatment—
The aluminum plate having undergone the above anodic oxidation treatment was immersed in an aqueous solution of caustic soda at a temperature of 40° C. and having a caustic soda concentration of 5% by mass and an aluminum ion concentration of 0.5% by mass for 3 seconds, thereby performing a pore widening treatment. Then, rinsing was performed by means of spraying.
—Second-Stage Anodization Treatment—
By using the anodization device for direct current electrolysis having the structure shown in
<Preparation of Support 3>
—Alkaline Etching Treatment—
An aqueous solution of caustic soda having a caustic soda concentration of 26% by mass and an aluminum ion concentration of 6.5% by mass was sprayed onto the aluminum plate at a temperature of 70° C., thereby performing an etching treatment. Then, rinsing was performed by means of spraying. The amount of dissolved aluminum within the surface to be subjected to the electrochemical roughening treatment later was 5 g/m2.
—Desmutting Treatment Using Aqueous Acidic Solution (First Desmutting Treatment)—
Next, a desmutting treatment was performed using an aqueous acidic solution. In the desmutting treatment, a 150 g/L aqueous sulfuric acid solution was used as the aqueous acidic solution. The liquid temperature was 30° C. The desmutting treatment was performed for 3 seconds by spraying the aqueous acidic solution onto the aluminum plate. Then, a rinsing treatment was performed.
—Electrochemical Roughening Treatment—
Next, an electrochemical roughening treatment was performed using alternating current and an electrolytic solution having a hydrochloric acid concentration of 14 g/L, an aluminum ion concentration of 13 g/L, and a sulfuric acid concentration of 3 g/L. The liquid temperature of the electrolytic solution was 30° C. The aluminum ion concentration was adjusted by adding aluminum chloride. The waveform of the alternating current was a sine wave in which positive and negative waveforms are symmetrical, the frequency was 50 Hz, the ratio of the anodic reaction time and the cathodic reaction time in one cycle of the alternating current was 1:1, and the current density was 75 A/dm2 in terms of the peak current value of the alternating current waveform. In addition, the quantity of electricity was 450 C/dm2 which was the total quantity of electricity used for the aluminum plate to have an anodic reaction, and the electrolysis treatment was performed 4 times by conducting electricity of 112.5 C/dm2 for 4 seconds at each treatment session. A carbon electrode was used as the counter electrode of the aluminum plate. Then, a rinsing treatment was performed.
—Desmutting Treatment Using Aqueous Acidic Solution—
Next, a desmutting treatment was performed using an aqueous acidic solution. Specifically, the desmutting treatment was performed for 3 seconds by spraying the aqueous acidic solution onto the aluminum plate. In the desmutting treatment, an aqueous solution having a sulfuric acid concentration of 170 g/L and an aluminum ion concentration of 5 g/L was used as aqueous acidic solution. The liquid temperature was 30° C.
—Anodization Treatment—
By using an anodization device for direct current electrolysis, an anodization treatment was performed in a sulfuric acid solution such that a predetermined amount of oxide film was obtained.
<Preparation of Support 4>
A Hydro 1052 aluminum alloy strip or web (available from Norsk Hydro ASA, Norway) having a thickness of 0.28 mm was used as an aluminum-containing support.
Both the pre-etching and post-etching steps were performed in an alkaline solution under known conditions. Roughening (or graining) was performed by electrochemical means in a hydrochloric acid solution at about 23° C., such that a calculated average roughness (Ra) of 0.5 μm was obtained on the plane of the aluminum-containing support. These treatment steps were performed in a continuous process on a typical manufacturing line used for manufacturing a planographic printing plate precursor.
Then, the obtained aluminum-containing support having undergone graining and etching was washed with water, dried, and cut into aluminum-containing sheets having undergone graining and etching.
Each of the sheets was anodized twice. Each of the anodization treatment baths contained about 100 L of an anodization solution. During the first anodization, each sheet was treated for 21.3 seconds under the conditions of an electrolyte concentration of 175 g/L, a temperature of 60° C., and a current density of 5.8 A/dm2. During the second anodization, each sheet was treated for 18 seconds under the conditions of an electrolyte concentration of 280 g/L, a temperature of 23° C., and a current density of 10 A/dm2. The first anodization process for forming an outer aluminum oxide layer was performed using phosphoric acid as an electrolyte, and the second anodization process for forming an inner aluminum oxide layer was performed using sulfuric acid as an electrolyte.
<Method of Forming Undercoat Layer>
The supports described in Table 1 or Table 3 were coated with the coating liquid 1 for an undercoat layer described in Table 1 or Table 3 having the following compositions such that the dry coating amount of 80 mg/m2 was obtained, and the supports were dried in an oven at 100° C. for 30 seconds, thereby forming an undercoat layer. In Table 1 or Table 3, “-” listed in the column of “Type of coating liquid for undercoat layer” means that an undercoat layer was not formed.
—Composition of Coating Liquid 1 for Undercoat Layer—
<Formation of Image-Recording Layer>
The support or undercoat layer described in Table 1 or Table 3 was bar-coated with the coating liquid 1 for an image-recording layer having the composition described in Tables 1 to 4, followed by drying in an oven at 120° C. for 40 seconds, thereby forming an image-recording layer having a dry coating amount of 1.0 g/m2.
The coating liquid 1 for an image-recording layer is shown below.
<Composition of Coating Liquid 1 for Image-Recording Layer>
Infrared absorbers described in Table 1 or Table 3: amount described in Table 1 or Table 3
<Formation of Outermost Layer>
The image-recording layer was bar-coated with any of the coating liquids 1 to 5 for an outermost layer described in Table 1 or Table 3 and dried in an oven at 120° C. for 30 seconds, thereby forming an outermost layer with the dry coating amount described in Table 1 or Table 3.
<Coating Liquid 1 for Outermost Layer>
GOHSENX L3266 is the following sulfonic acid-modified polyvinyl alcohol having a weight-average molecular weight of 17,000.
FINE SPHERE FS102 is an aqueous dispersion of the following styrene-acrylic copolymer particles.
<Composition of Coating Liquid 2 for Outermost Layer>
<Composition of Coating Liquid 3 for Outermost Layer>
<Composition of Coating Liquid 4 for Outermost Layer>
A coating liquid 4 for an outermost layer was prepared, such that the coating liquid 4 contained the following components in amounts described below and had a solid content of 6% by mass adjusted with deionized water.
<Composition of Coating Liquid 5 for Outermost Layer>
A coating liquid 5 for an outermost layer was prepared, such that the coating liquid 5 contained the following components in amounts described below and had a solid content of 6% by mass adjusted with deionized water.
<Preparation of Planographic Printing Plate Precursor>
As shown in Tables 1 to 4, planographic printing plate precursors of Examples 1 to 52 and Comparative Examples 1 to 4 were prepared according to the methods of forming the support and each of the above layers.
<Evaluation of Planographic Printing Plate Precursor>
[Evaluation of Ink Turbidity Suppressiveness]
By using Magnus 800 Quantum manufactured by Kodak Japan Ltd. that was equipped with an infrared semiconductor laser, the obtained planographic printing plate precursor was exposed under the conditions of output of 27 W, an outer drum rotation speed of 450 rpm, and a resolution of 2,400 dots per inch (dpi, 1 inch is equal to 2.54 cm) (irradiation energy described in Table 2 or Table 4). The exposure was performed such that the exposed image included a solid image having an image area ratio of 5%.
The obtained exposed precursor was mounted on a Kikuban-sized cylinder of a printer SX-74 manufactured by Heidelberger Druckmaschinen AG without being developed. This printer was connected to a 100 L-capacity dampening water circulation tank having a non-woven fabric filter and a temperature control device. A circulation device was filled with 80 L of dampening water containing 3.5% dampening water S-Z1 (manufactured by FUJIFILM Corporation), the dampening water was supplied by dampening performed 12 times, then 200 g of Fusion-G MK medium N (manufactured by and DIC Corporation) used as a printing ink was supplied, and printing was performed on 300 sheets of TOKUBISHI art paper (manufactured by MITSUBISHI PAPER MILLS LIMITED., ream weight: 76.5 kg) at a printing rate of 10,000 sheets/hour. The printing was repeated 10 times, and the tint of the ink on the surface of the printing paper surface was compared with the tint of the ink to evaluate the coloring of the ink. The evaluation standard is shown below.
[Temporal Visibility Evaluation (Measurement of ΔL of Exposed Portion (Image Area) Before and After Exposure)]
In Trendsetter 3244VX manufactured by Creo that was equipped with a water cooling-type 40 W infrared semiconductor laser, each of the obtained planographic printing plate precursors was exposed under the conditions of an output of 11.5 W, an outer drum rotation speed of 220 rpm, and a resolution of 2,400 dots per inch (dpi, 1 inch=25.4 mm). The exposure was performed in an environment of 25° C. and 50% RH.
After exposure, the planographic printing plate precursor was stored for 72 hours in a dark place (30° C., 70% RH), and then color development thereof was measured. The measurement was performed by the specular component excluded (SCE) method by using a spectrocolorimeter CM2600d and operation software CM-S100W manufactured by Konica Minolta, Inc. The visibility was evaluated by a difference ΔL between an L* value of the exposed portion and an L* value of the non-exposed portion by using L* values (brightness) of the L*a*b* color system. The higher the value of ΔL, the better the temporal visibility.
The details of the abbreviations described in Table 1 to Table 4 other than those described above are described below.
IR-1 to IR-3: The Following Compounds
S-2, S-15 to S-17, S-22, and S-23: The Following Compounds
Int-1 and Int-2: The Following Compounds
Int-3: the following compound (a compound that is a photopolymerization initiator and has a group 13 element)
TPB and TPB-1 to TPB-3: the following compounds
Ct-1: The Following Compound
CC-1: The Following Compound
Molecular Weight: 278.35
M-1: Compound Synthesized by the Following Synthesis Method
<Synthesis Method of M-1>
A mixed solution of 4.7 parts by mass of TAKENATE D-160N (polyisocyanate trimethylolpropane adduct, manufactured by Mitsui Chemicals, Inc.), ARONIX M-403 (manufactured by TOAGOSEI CO., LTD.) in an amount yielding the ratio of NCO value of TAKENATE D-160N:hydroxyl number of ARONIX M-403=1:1, 0.02 parts by mass of t-butylbenzoquinone, and 11.5 parts by mass of methyl ethyl ketone was heated at 65° C. NEOSTANN U-600 (bismuth-based polycondensation catalyst, manufactured by NITTO KASEI CO., LTD., 0.11 parts by mass) was added to the reaction solution, and the reaction solution was heated at the same temperature for 4 hours. The reaction solution was cooled to room temperature (25° C.), and methyl ethyl ketone was added thereto, thereby synthesizing a urethane acrylate solution having a solid content of 50% by mass.
Then, by using recycling GPC (instrument: LC908-C60, column: JAIGEL-1H-40 and 2H-40 (manufactured by Japan Analytical Industry Co., Ltd.)) and tetrahydrofuran (THF) as an eluent, molecular weight fractionation of the urethane acrylate solution was performed. The weight-average molecular weight was 20,000.
M-2 to M-6: The Following Compounds
A-1: The Following Compound
HPC: hydroxypropyl cellulose, Klucel M, manufactured by Hercules, Inc.
W-1: The Following Compound
Microgel Liquid 1: Microgel Liquid Obtained by the Following Synthesis Method
<Synthesis Method of Microgel Liquid 1>
Microgel used in the aforementioned microgel liquid was prepared by the following method.
—Preparation of Polyvalent Isocyanate Compound—
Bismuth tris(2-ethylhexanoate) (NEOSTAN U-600, manufactured by NITTO KASEI CO., LTD., 0.043 parts) was added to an ethyl acetate (25.31 g) suspension solution of 17.78 parts (80 molar equivalents) of isophorone diisocyanate and 7.35 parts (20 molar equivalents) of the following polyhydric phenol compound (1), and the obtained solution was stirred. The reaction temperature was set to 50° C. at a point in time when heat release subsided, and the solution was stirred for 3 hours, thereby obtaining an ethyl acetate solution of the polyvalent isocyanate compound (1) (50% by mass).
—Preparation of Microgel—
The following oil-phase components and water-phase components were mixed together and emulsified at 12,000 rpm for 10 minutes by using a homogenizer. The obtained emulsion was stirred at 45° C. for 4 hours, a 10% by mass aqueous solution of 5.20 g of 1,8-diazabicyclo[5.4.0]undec-7-ene-octylate (U-CAT SA102, manufactured by San-Apro Ltd.) was added thereto, and the solution was stirred at room temperature for 30 minutes and left to stand at 45° C. for 24 hours. Distilled water was added thereto such that the concentration of solid contents was adjusted to 20% by mass, thereby obtaining an aqueous dispersion of a microgel (1). The average particle diameter thereof measured by a light scattering method was 0.28 μm.
˜Oil-Phase Component˜
˜Water-Phase Component˜
Microgel Liquid 2: Microgel Liquid Obtained by the Following Synthesis Method
<Preparation of Microgel Liquid 2>
—Preparation of Oil-Phase Component—
A polyfunctional isocyanate compound (PM-200: manufactured by Wanhua Chemical Group Co., Ltd.: 6.66 g, a 50% by mass ethyl acetate solution of “TAKENATE (registered trademark) D-116N (adduct of trimethylolpropane (TMP), m-xylylene diisocyanate (XDI), and polyethylene glycol monomethyl ether (EO90) (following structure)” manufactured by Mitsui Chemicals, Inc.: 5.46 g, a 65% by mass ethyl acetate solution of dipentaerythritol pentaacrylate (SR-399, manufactured by Sartomer Company Inc.): 11.24 g, ethyl acetate: 14.47 g, and PIONIN (registered trademark) A-41-C manufactured by TAKEMOTO OIL & FAT Co., Ltd.: 0.45 g were mixed together and stirred at room temperature (25° C.) for 15 minutes, thereby obtaining an oil-phase component.
—Preparation of Water-Phase Component—
As a water-phase component, 47.2 parts of distilled water was prepared.
—Preparation of Microgel—
The oil-phase component and the water-phase component were mixed together, and the obtained mixture was emulsified at 12,000 rpm for 16 minutes by using a homogenizer, thereby obtaining an emulsion.
Distilled water (16.8 parts) was added to the obtained emulsion, and the obtained liquid was stirred at room temperature for 10 minutes.
After stirring, the liquid was heated at 45° C., and stirred for 4 hours in a state of being kept at 45° C. such that ethyl acetate was distilled away from the liquid. Then, a 10% by mass aqueous solution of 5.12 g of 1,8-diazabicyclo[5.4.0]undec-7-ene-octylate (U-CAT SA102, manufactured by San-Apro Ltd.) was added thereto, and the solution was stirred at room temperature for 30 minutes and left to stand at 45° C. for 24 hours. Distilled water was added thereto such that the concentration of solid contents was adjusted to 20% by mass, thereby obtaining a microgel liquid 2. The microgel liquid 2 had a volume average particle diameter of 165 nm that was measured using a laser diffraction/scattering-type particle diameter distribution analyzer LA-920 (manufactured by HORIBA, Ltd.).
<Synthesis of Polymer Particles 1>
Dispersion unit: the following compound B-1 (n=45): 10.0 parts, 85.0 parts of distilled water, and 240.0 parts of n-propanol were added to a four-neck flask, and the mixture was heated and stirred at 70° C. in a nitrogen atmosphere.
Then, a mixture of the following compound A-1: 20.0 parts, the following compound A-2: 70.0 parts, and 0.7 parts of 2,2′-azobisisobutyronitrile that were mixed together in advance was added dropwise for 2 hours to the four-neck flask.
After the dropwise addition ended, the reaction continued for 5 hours, then 0.5 parts of 2,2′-azobisisobutyronitrile was added thereto, and the solution was heated to 80° C. The reaction was performed for a total of 19 hours by adding 0.4 parts of 2,2′-azobisisobutyronitrile every 6 hours.
The reaction solution was left to cool to room temperature (25° C.), thereby obtaining a dispersion (solid content 23%) of polymer particles 1.
The polymer particles 1 had a median diameter of 150 nm and a coefficient of variation of 23%.
Furthermore, the dispersibility of the polymer particles 1 was checked by the method described above. As a result, the polymer particles 1 were found to be water-dispersible and organic solvent-dispersible particles.
As is evident from the results shown in Table 1 to Table 4, compared to the planographic printing plate precursors according to comparative examples, the planographic printing plate precursors according to examples are better in ink turbidity suppressiveness and temporal visibility of exposed portions.
<Preparation of Coloring Reactant Using C-1>
C-1 (0.3 g, 1.2 mmol), 3.0 mL of THF, and 0.3 g of triphenylborane (1.3 mmol, manufactured by Sigma-Aldrich CO. LLC) were added to a 50 mL three-neck flask, and the mixture was stirred for 4 hours under the condition of room temperature. After the reaction ended, the solids obtained by concentration under reduced pressure with a rotary evaporator were separated by column chromatography (developing solvent: ethyl acetate/hexane=1/2), and the target fraction was concentrated again under reduced pressure with a rotary evaporator, thereby obtaining 0.45 g of a target substance at a yield of 91.3%.
C-1 formed a complex with the organic compound having a group 13 element or a decomposition product thereof, and was found to undergo color change due to the formation of the complex, which tells that C-1 functions as a coloring agent.
<Preparation of Coloring Reactant Using C-2 to C-17>
Coloring reactants were prepared based on the preparation of the coloring reactant using C-1, except that C-1 was changed to any one of C-2 to C-17.
All of C-2 to C-17 formed a complex with the organic compound having a group 13 element or a decomposition product thereof, and were found to undergo color change due to the formation of the complex, which tells that C-2 to C-17 function as a coloring agent.
The entire disclosure of Japanese Patent Application No. 2021-030880, filed Feb. 26, 2021, is incorporated into the present specification by reference.
All of documents, patent applications, and technical standards described in the present specification are incorporated into the present specification by reference to approximately the same extent as a case where it is specifically and respectively described that the respective documents, patent applications, and technical standards are incorporated by reference.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2021-030880 | Feb 2021 | JP | national |
This application is a Continuation of International Application No. PCT/JP2022/007742, filed Feb. 24, 2022, which claims priority to Japanese Patent Application No. 2021-030880, filed Feb. 26, 2021. Each of the above applications is hereby expressly incorporated by reference, in its entirety, into the present application.
| Number | Date | Country | |
|---|---|---|---|
| Parent | PCT/JP2022/007742 | Feb 2022 | US |
| Child | 18454439 | US |
