Optical cell cleaner

Information

  • Patent Grant
  • 11988598
  • Patent Number
    11,988,598
  • Date Filed
    Tuesday, December 29, 2020
    3 years ago
  • Date Issued
    Tuesday, May 21, 2024
    7 months ago
Abstract
Systems, devices, and methods for an optical head enclosure of a sensor; one or more imbedded nozzles disposed on a surface of the optical head enclosure; an inlet of the one or more imbedded nozzles, where the inlet comprises a nozzle channel for receiving a cleaning solution; a flow channel internal to the optical head enclosure, where the nozzle channel is connected to the flow channel, and where the flow channel comprises an outlet for dispersing the cleaning solution received from the nozzle channel; wherein the inlet comprises a break to stop a nozzle of a cleaning device from reaching a mirror of the sensor; where the outlet directs the cleaning solution from the inlet onto the mirror.
Description
TECHNICAL FIELD

Embodiments relate generally to cell optics, and more particularly to cleaning cell optics.


BACKGROUND

Methane (CH4) is an odorless and colorless naturally occurring organic molecule, which is present in the atmosphere at average ambient levels of approximately 1.85 ppm as of 2018 and is projected to continually climb. While methane is found globally in the atmosphere, a significant amount is collected or “produced” through anthropogenic processes including exploration, extraction, and distribution of petroleum in the form of natural gas. Natural gas, an odorless and colorless gas, is a primary source of energy used to produce electricity and heat. The main component of natural gas is methane (93.9 mol % CH4 typ.). While extraction of natural gas is a large source of methane released to atmosphere, major contributors of methane also include livestock farming (enteric fermentation), and solid waste and wastewater treatment (anaerobic digestion). Optical cells may be used to detect methane and other trace gasses.


SUMMARY

A system embodiment may include: an optical head enclosure of a sensor; one or more imbedded nozzles disposed on a surface of the optical head enclosure; an inlet of the one or more imbedded nozzles, where the inlet comprises a nozzle channel for receiving a cleaning solution; a flow channel internal to the optical head enclosure, where the nozzle channel may be connected to the flow channel, and where the flow channel comprises an outlet for dispersing the cleaning solution received from the nozzle channel; where the inlet may comprise a break to stop a nozzle of a cleaning device from reaching a mirror of the sensor; where the outlet may direct the cleaning solution from the inlet onto the mirror.


In additional system embodiments, the cleaning solution may be compressed air. In additional system embodiments, the cleaning solution may be a liquid. In additional system embodiments, the inlet may be disposed at an angle relative to the surface of the optical head enclosure. In additional system embodiments, the inlet may extend outward from the surface of the optical head enclosure. In additional system embodiments, a length or width of the outlet may be greater than a length or width of the nozzle channel.


In additional system embodiments, the break may be a change in angle between the nozzle channel and the flow channel. In additional system embodiments, the break may be a physical barrier between the nozzle channel and the flow channel. In additional system embodiments, the break may be a change in width or length between the nozzle channel and the flow channel.


In additional system embodiments, the sensor may be a trace-gas sensor. In additional system embodiments, the sensor may be an open path Herriot cell. In additional system embodiments, the nozzle of the cleaning device may be a straw.


A method embodiment may include: inserting a nozzle of a cleaning device into a nozzle channel of an inlet of one or more imbedded nozzles disposed on a surface of a optical head enclosure; and dispersing a cleaning solution from the cleaning device onto a mirror disposed within the optical head enclosure.


In additional method embodiments, the dispersed cleaning solution dusts the mirror. In additional method embodiments, the nozzle channel may be connected to a flow channel, where the flow channel may comprise an outlet for dispersing the cleaning solution received from the nozzle channel, and where the outlet may direct the cleaning solution from the inlet onto the mirror. In additional method embodiments, the inlet may comprise a break to stop the nozzle of the cleaning device from reaching the mirror.


A device embodiment may include an optical head enclosure of a sensor, comprising: an outer surface comprising one or more apertures for allowing ambient gas to enter the sensor disposed in the interior of the optical head enclosure; one or more imbedded nozzles disposed on an outer surface of the optical head enclosure; and an inlet of the one or more imbedded nozzles, wherein the inlet comprises a nozzle channel for receiving a cleaning solution to be directed toward the sensor disposed in the interior of the optical head enclosure.


Additional device embodiments may include: a flow channel connected to the nozzle channel, where the flow channel comprises an outlet for dispersing the cleaning solution received from the nozzle channel. In additional device embodiments, the outlet directs the cleaning solution from the inlet onto a mirror of the sensor. Additional device embodiments may include: a break disposed in the inlet to stop a nozzle of a cleaning device from reaching a mirror of the sensor.





BRIEF DESCRIPTION OF THE DRAWINGS

The components in the figures are not necessarily to scale, emphasis instead being placed upon illustrating the principals of the invention. Like reference numerals designate corresponding parts throughout the different views. Embodiments are illustrated by way of example and not limitation in the figures of the accompanying drawings, in which:



FIG. 1 depicts an optical head enclosure with one or more imbedded nozzles, according to one embodiment;



FIG. 2 depicts a close-up view of an imbedded nozzle on a surface of the optical head enclosure of FIG. 1, according to one embodiment;



FIG. 3 depicts a close-up view of a nozzle channel on the optical head enclosure, according to one embodiment;



FIG. 4 depicts an airflow channel internal to the optical head enclosure, according to one embodiment;



FIG. 5 depicts a fixture for dusting of a mirror of a sensor showing the air outlet, according to one embodiment;



FIG. 6 depicts the fixture of FIG. 5 for dusting of the mirror of the sensor showing the air inlet, according to one embodiment;



FIG. 7 depicts a cleaning device for dusting a mirror of an optical head enclosure, according to one embodiment;



FIG. 8 depicts a high-level flowchart of a method embodiment for dusting a mirror of a sensor, according to one embodiment; and



FIG. 9 depicts a system for detecting trace gasses with the disclosed gas sensor, according to one embodiment.





DETAILED DESCRIPTION

There exists a need to clean particulate matter that collects on sensitive optics within a trace gas sensor gently and noninvasively. The trace gas sensor may include one or more mirrors, such as in an open path Herriot cell optics. The reflective surface of the mirrors may be easily scratched by foreign bodies. Cleaning the mirrors in an external environment, such as an oil field, is challenging.


In the disclosed system and method, compressed air may be used to “dust” the mirrors and remove accumulated particulates from the reflective surface of the mirrors. By imbedding a nozzle within the housing of the optical head, particulate matter can be removed quickly and easily while minimizing the risk of damaging the reflective surface of the mirrors. An imbedded nozzle may be built into a sidewall of the optical head enclosure. The imbedded nozzle may channel allow the airflow to be directed towards the mirror surface at an optimal angle for maximizing dust removal. This optimal angle may vary based on the dimensions of the optical cell, mirrors, housing, or the like. This imbedded nozzle serves dual purposes. The imbedded nozzle channels airflow from the compressed air canister towards the mirror or reflective surface. The imbedded surface also prevents a straw from the canister from becoming a projectile that may scratch the mirror's reflective surface.



FIG. 1 depicts an optical head enclosure 100 with one or more imbedded nozzles 102, 104, according to one embodiment. The optical head enclosure 100 may contain a sensor, such as a trace-gas sensor. In some embodiment, the sensor may be an open path Herriot cell. The surface 110 of the optical head enclosure 100 may include one or more apertures 106 or openings for allowing ambient gas to enter the sensor disposed in the interior of the optical head enclosure 100. During use, such as in an oil field, the optics of the sensor may become dirty, covered with dust, or the like. Dust may impede the accuracy of the sensor to detect trace-gasses. Regular cleaning of the optics of the sensor may ensure that the trace-gas detection is accurate and allow for prolonged use of the sensor. The optical head enclosure 100 may be attached to a handle, aerial vehicle, unmanned aerial vehicle (UAV), or the like, such as shown in FIG. 9, via one or more enclosure attachments 108. One or more imbedded nozzles 102, 104 may be disposed on and through the surface of the optical head enclosure 100 to allow for cleaning of the optics of the sensor within the optical head enclosure 100.



FIG. 2 depicts a close-up view of an imbedded nozzle 102 on a surface 110 of the optical head enclosure 100 of FIG. 1, according to one embodiment. The imbedded nozzle 102 includes an inlet 200. The inlet 200 may be a portion that extends outward from the outer surface 110 of the optical head enclosure 100. The inlet 200 may be disposed at an angle relative to the surface 100 of the optical head enclosure 100 in some embodiments. The inlet 200 may include a nozzle channel 202 for receiving a nozzle of a cleaning device and/or a cleaning solution from the cleaning device. The nozzle channel 202 may be sized to receive a nozzle from a cleaning device, such as shown in FIG. 7.



FIG. 3 depicts a close-up view of a nozzle channel 202 on the optical head enclosure 100, according to one embodiment. Each imbedded nozzle 104 may include the nozzle channel 202 extending from the surface 110 of the optical head enclosure 100.



FIG. 4 depicts an airflow channel 400 internal to the optical head enclosure 100, according to one embodiment. The flow channel 400 may be connected to the nozzle channel 202 to transfer a cleaning solution from the cleaning device, through the nozzle, to the nozzle channel, through the flow channel 400, through an outlet 404 of the flow channel 400, and onto a mirror 406. An inner surface 402 of the optical head enclosure 100 may contain a portion of the nozzle channel 202, the flow channel 400, and outlet 404, in some embodiments.



FIG. 5 depicts a fixture 500 for dusting of a mirror 406 of a sensor showing the air outlet 404, according to one embodiment. The cleaning solution may exit the outlet 404 and be dispersed onto the mirror 406. The dimensions of the outlet 404, position of the outlet 404 relative to the mirror, and other dimensions may be varied based on the size of the mirror 406, amount of dust on the mirror 406, cleaning frequency, and the like.



FIG. 6 depicts the fixture 500 of FIG. 5 for dusting of the mirror of the sensor 500 showing the air inlet 200, according to one embodiment. The inlet 200 may receive the nozzle of the cleaning device.



FIG. 7 depicts a cleaning device 700 for dusting a mirror 406 of an optical head enclosure 100, according to one embodiment. The optical head enclosure 100 of the sensor may include one or more imbedded nozzles 102 disposed on a surface 110 of the optical head enclosure. The inlet 200 of the one or more imbedded nozzles 102 may include the nozzle channel 202 for receiving a cleaning solution 706 from a nozzle 702 of a cleaning device 700. In some embodiments, the cleaning solution 706 may be compressed air. In other embodiments, the cleaning solution 706 may be a liquid. In other embodiments, the cleaning solution 706 may be any gas, such as fluorocarbons. In some embodiments, the cleaning device 700 may be a compressed air canister. The nozzle 702 may be a straw in some embodiments. The inlet 202 may be sized to receive the nozzle 702.


The flow channel 400 may be internal to the optical head enclosure 100. In some embodiments, at least a portion of the flow channel 400 may be disposed between the outer surface 110 and inner surface 402 of the optical head enclosure 100. The nozzle channel 202 may be connected to the flow channel 400. The flow channel 400 may include the outlet 404 for dispersing the cleaning solution 706 received from the nozzle channel 202. The outlet 404 may direct the cleaning solution 706 from the inlet 202 onto the mirror 406. A length or width of the outlet 404 may be greater than a length or width of the nozzle channel 202.


The inlet 200 may include a break 704 to stop the nozzle 702 of the cleaning device 700 from reaching a mirror 406 of the sensor. The break 704 allows a user in the field, such as an oil field, to dust the mirror 406 of the sensor without risk of accidentally scratching the mirror 406 by contacting the mirror with the nozzle 702 of the cleaning device. The break 704 may be a change in angle between the nozzle channel 202 and the flow channel 400. The break 704 may be a physical barrier between the nozzle channel 202 and the flow channel 400. The break 704 may be a change in width or length between the nozzle channel 202 and the flow channel 400. The change in width or length between the nozzle channel 202 and the flow channel 400 may be such as to prevent the nozzle 702 of the cleaning device 700 from extending past the break 704 and into the flow channel 400.



FIG. 8 depicts a high-level flowchart of a method embodiment 800 for dusting a mirror of a sensor, according to one embodiment. The method 800 may include inserting a nozzle of a cleaning device into a nozzle channel of an inlet of one or more imbedded nozzles disposed on a surface of a optical head enclosure (step 802). The method 800 may then include stopping the nozzle of cleaning device from reaching a mirror disposed in the optical head enclosure via a break (step 804). The method 800 may then include dispersing a cleaning solution from the cleaning device onto the mirror disposed within the optical head enclosure (step 806). The nozzle channel may be connected to a flow channel. The flow channel may include an outlet for dispersing the cleaning solution received from the nozzle channel. The outlet may direct the cleaning solution from the inlet onto the mirror.



FIG. 9 depicts a system 2000 for detecting trace gasses utilizing the disclosed gas sensor, according to one embodiment. The use of these trace gas sensors may expose the trace gas sensors to dirt, dust, or other contaminants that should be removed using the system and method disclosed herein. The system may include one or more trace gas sensors located in one or more vehicles 2002, 2004, 2006, 2010. The one or more trace gas sensors may detect elevated trace gas concentrations from one or more potential gas sources 2020, 2022, such as a holding tank, pipeline, or the like. The potential gas sources 2020, 2022 may be part of a large facility, a small facility, or any location. The potential gas sources 2020, 2022 may be clustered and/or disposed distal from one another. The one or more trace gas sensors may be used to detect and quantify leaks of toxic gases, e.g., hydrogen disulfide, or environmentally damaging gases, e.g., methane, sulfur dioxide) in a variety of industrial and environmental contexts. Detection and quantification of these leaks are of interest to a variety of industrial operations, such as oil and gas, chemical production, and painting. Detection and quantification of leaks is also of value to environmental regulators for assessing compliance and for mitigating environmental and safety risks. In some embodiments, the at least one trace gas sensor may be configured to detect methane. In other embodiments, the at least one trace gas sensor may be configured to detect sulfur oxide, such as SO, SO2, SO3, S7O2, S6O2, S2O2, and the like. A trace gas leak 2024 may be present in a potential gas source 2020. The one or more trace gas sensors may be used to identify the trace gas leak 2024 and/or the source 2020 of the trace gas leak 2024 so that corrective action may be taken.


The one or more vehicles 2002, 2004, 2006, 2010 may include an unmanned aerial vehicle (UAV) 2002, an aerial vehicle 2004, a handheld device 2006, and a ground vehicle 2010. In some embodiments, the UAV 2002 may be a quadcopter or other device capable of hovering, making sharp turns, and the like. In other embodiments, the UAV 2002 may be a winged aerial vehicle capable of extended flight time between missions. The UAV 2002 may be autonomous or semi-autonomous in some embodiments. In other embodiments, the UAV 2002 may be manually controlled by a user. The aerial vehicle 2004 may be a manned vehicle in some embodiments. The handheld device 2006 may be any device having one or more trace gas sensors operated by a user 2008. In one embodiment, the handheld device 2006 may have an extension for keeping the one or more trace gas sensors at a distance from the user 2008. The ground vehicle 2010 may have wheels, tracks, and/or treads in one embodiment. In other embodiments, the ground vehicle 2010 may be a legged robot. In some embodiments, the ground vehicle 2010 may be used as a base station for one or more UAVs 2002. In some embodiments, one or more aerial devices, such as the UAV 2002, a balloon, or the like, may be tethered to the ground vehicle 2010. In some embodiments, one or more trace gas sensors may be located in one or more stationary monitoring devices 2026. The one or more stationary monitoring devices may be located proximate one or more potential gas sources 2020, 2022. In some embodiments, the one or more stationary monitoring devices may be relocated.


The one or more vehicles 2002, 2004, 2006, 2010 and/or stationary monitoring devices 2026 may transmit data including trace gas data to a ground control station (GCS) 2012. The GCS may include a display 2014 for displaying the trace gas concentrations to a GCS user 2016. The GCS user 2016 may be able to take corrective action if a gas leak 2024 is detected, such as by ordering a repair of the source 2020 of the trace gas leak. The GCS user 2016 may be able to control movement of the one or more vehicles 2002, 2004, 2006, 2010 in order to confirm a presence of a trace gas leak in some embodiments.


In some embodiments, the GCS 2012 may transmit data to a cloud server 2018. In some embodiments, the cloud server 2018 may perform additional processing on the data. In some embodiments, the cloud server 2018 may provide third party data to the GCS 2012, such as wind speed, temperature, pressure, weather data, or the like.


It is contemplated that various combinations and/or sub-combinations of the specific features and aspects of the above embodiments may be made and still fall within the scope of the invention. Accordingly, it should be understood that various features and aspects of the disclosed embodiments may be combined with or substituted for one another in order to form varying modes of the disclosed invention. Further, it is intended that the scope of the present invention is herein disclosed by way of examples and should not be limited by the particular disclosed embodiments described above.

Claims
  • 1. A system comprising: an optical head enclosure including an outer surface that has a wall surrounding a sensor and comprising one or more apertures formed thereon, wherein the sensor includes an open path with a first mirror and a second mirror disposed at each end of the open path;one or more imbedded nozzles that penetrate through and are imbedded in the outer surface of the optical head enclosure and disposed between the first mirror and the second mirror inside the outer surface of the optical head enclosure, wherein at least one of the one or more imbedded nozzles is disposed closer to the first mirror than the second mirror;an inlet of each of the one or more imbedded nozzles, wherein the inlet comprises a nozzle channel for receiving a cleaning solution;a flow channel internal to the optical head enclosure, wherein the nozzle channel is connected to the flow channel, and wherein the flow channel comprises an outlet for dispersing the cleaning solution received from the nozzle channel;a break disposed in the inlet to stop a nozzle of a cleaning device from reaching the first mirror of the sensor;wherein the outlet directs the cleaning solution from the inlet onto the first mirror.
  • 2. The system of claim 1, wherein the cleaning solution is at least one of: compressed air and a liquid.
  • 3. The system of claim 1, wherein the wall is a cylindrical wall.
  • 4. The system of claim 1, wherein the inlet is disposed at an angle relative to the surface of the optical head enclosure.
  • 5. The system of claim 1, wherein the inlet extends outward from the surface of the optical head enclosure.
  • 6. The system of claim 1, wherein a length or width of the outlet is greater than a length or width of the nozzle channel.
  • 7. The system of claim 1, wherein the break is at least one of: a change in angle between the nozzle channel and the flow channel, and a change in width or length between the nozzle channel and the flow channel.
  • 8. The system of claim 1, wherein the break is a physical barrier between the nozzle channel and the flow channel.
  • 9. The system of claim 1, wherein the flow channel widens as it approaches the outlet.
  • 10. The system of claim 1, wherein the sensor is a trace-gas sensor.
  • 11. The system of claim 1, wherein the sensor is an open path Herriot cell.
  • 12. The system of claim 1, wherein the nozzle of the cleaning device is a straw.
  • 13. A method comprising: preparing a system comprising an optical head enclosure including an outer surface that has a wall surrounding a sensor and comprises one or more apertures formed thereon, and one or more imbedded nozzles that penetrate through and are imbedded in the outer surface of the optical head enclosure;inserting a nozzle of a cleaning device into a nozzle channel of an inlet of the one or more imbedded nozzles, wherein the sensor includes an open path with a first mirror and a second mirror disposed at each end of the open path, wherein the inlet is disposed between the first mirror and the second mirror, and wherein the inlet of the one or more imbedded nozzles is disposed closer to the first mirror than the second mirror; anddispersing a cleaning solution from the cleaning device onto the first mirror disposed within the optical head enclosure.
  • 14. The method of claim 13, wherein the dispersed cleaning solution dusts the first mirror, and wherein the wall is a cylindrical wall.
  • 15. The method of claim 13, wherein the nozzle channel is connected to a flow channel, wherein the flow channel comprises an outlet for dispersing the cleaning solution received from the nozzle channel, wherein the outlet directs the cleaning solution from the inlet onto the first mirror, and wherein the flow channel widens as it approaches the outlet.
  • 16. The method of claim 13, wherein the inlet comprises a break to stop the nozzle of the cleaning device from reaching the first mirror.
  • 17. An optical head enclosure of a sensor, comprising: an outer surface having a wall surrounding a sensor and comprising one or more apertures formed thereon for allowing ambient gas to enter the sensor disposed in the interior of the optical head enclosure, wherein the sensor includes an open path with a first mirror and a second mirror disposed at each end of the open path;one or more imbedded nozzles that penetrate through and are imbedded in the outer surface and that are disposed inside the outer surface of the optical head enclosure, wherein at least one of the one or more imbedded nozzles is disposed between the first mirror and the second mirror, and wherein at least one of the one or more imbedded nozzles is disposed closer to the first mirror than the second mirror; andan inlet of each of the one or more imbedded nozzles, wherein the inlet comprises a nozzle channel for receiving a cleaning solution to be directed toward the first mirror of the sensor disposed in the interior of the optical head enclosure.
  • 18. The optical head enclosure of the sensor of claim 17, further comprising: a flow channel connected to the nozzle channel, wherein the flow channel comprises an outlet for dispersing the cleaning solution received from the nozzle channel, and wherein the flow channel widens as it approaches the outlet.
  • 19. The optical head enclosure of the sensor of claim 18, wherein the outlet directs the cleaning solution from the inlet onto the first mirror of the sensor, and wherein the wall is a cylindrical wall.
  • 20. The optical head enclosure of the sensor of claim 18, further comprising: a break disposed in the inlet to stop a nozzle of a cleaning device from reaching the first mirror of the sensor.
CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims priority to and the benefit of U.S. Provisional Patent Application No. 62/955,536, filed Dec. 31, 2019, the contents of which are hereby incorporated by reference herein for all purposes.

US Referenced Citations (150)
Number Name Date Kind
3780566 Smith et al. Dec 1973 A
4135092 Milly Jan 1979 A
4233564 Kerbel Nov 1980 A
4507558 Bonne Mar 1985 A
4988833 Lai Jan 1991 A
5047639 Wong Sep 1991 A
5075619 Said Dec 1991 A
5173749 Tell et al. Dec 1992 A
5291265 Kebabian Mar 1994 A
5317156 Cooper et al. May 1994 A
5822058 Adler-Golden et al. Oct 1998 A
6064488 Brand et al. May 2000 A
6509566 Wamsley et al. Jan 2003 B1
6549630 Bobisuthi Apr 2003 B1
7800751 Silver et al. Sep 2010 B1
7833480 Blazewicz et al. Nov 2010 B2
8294899 Wong Oct 2012 B2
8451120 Johnson, Jr. et al. May 2013 B2
8730461 Andreussi May 2014 B2
9183371 Narendra et al. Nov 2015 B2
9183731 Bokhary Nov 2015 B1
9235974 Johnson, Jr. et al. Jan 2016 B2
9250175 McManus Feb 2016 B1
9494511 Wilkins Nov 2016 B2
9599529 Steele et al. Mar 2017 B1
9599597 Steele et al. Mar 2017 B1
10023311 Lai et al. Jul 2018 B2
10023323 Roberts et al. Jul 2018 B1
10126200 Steele et al. Nov 2018 B1
10268198 Mantripragada et al. Apr 2019 B2
10325485 Schuster Jun 2019 B1
10365646 Farnsworth et al. Jul 2019 B1
10429546 Ulmer Oct 2019 B1
10830034 Cooley et al. Nov 2020 B2
10962437 Nottrott et al. Mar 2021 B1
11299268 Christensen et al. Apr 2022 B2
11519855 Black et al. Dec 2022 B2
20020005955 Kramer et al. Jan 2002 A1
20030160174 Grant et al. Aug 2003 A1
20030189711 Orr et al. Oct 2003 A1
20030230716 Russell et al. Dec 2003 A1
20040012787 Galle et al. Jan 2004 A1
20040017762 Sogawa et al. Jan 2004 A1
20040212804 Neff et al. Oct 2004 A1
20060015290 Warburton et al. Jan 2006 A1
20060044562 Hagene et al. Mar 2006 A1
20060232772 Silver Oct 2006 A1
20060234621 Desrochers et al. Oct 2006 A1
20070137318 Desrochers et al. Jun 2007 A1
20080169934 Lang et al. Jul 2008 A1
20080243372 Bodin et al. Oct 2008 A1
20090201507 Kluczynski et al. Aug 2009 A1
20090263286 Isomura et al. Oct 2009 A1
20090326792 McGrath Dec 2009 A1
20100004798 Bodin et al. Jan 2010 A1
20100131207 Lippert et al. May 2010 A1
20100140478 Wilson et al. Jun 2010 A1
20100147081 Thomas Jun 2010 A1
20110074476 Heer et al. Mar 2011 A1
20110150035 Hanson et al. Jun 2011 A1
20110164251 Richter Jul 2011 A1
20110242659 Eckles Oct 2011 A1
20110257944 Du et al. Oct 2011 A1
20120120397 Furtaw et al. May 2012 A1
20130044314 Koulikov et al. Feb 2013 A1
20130076900 Mrozek et al. Mar 2013 A1
20130208262 Andreussi Aug 2013 A1
20140172323 Marino Jun 2014 A1
20140204382 Christensen Jul 2014 A1
20140236390 Mohamadi Nov 2014 A1
20140336957 Hanson et al. Nov 2014 A1
20150072633 Massarella et al. Mar 2015 A1
20150275114 Tumiatti et al. Oct 2015 A1
20150295543 Brown et al. Oct 2015 A1
20150316473 Kester et al. Nov 2015 A1
20160018373 Pagé et al. Jan 2016 A1
20160104250 Allen et al. Apr 2016 A1
20160146696 Steele et al. May 2016 A1
20160161456 Risk et al. Jun 2016 A1
20160202225 Feng et al. Jul 2016 A1
20160214715 Meffert Jul 2016 A1
20160307447 Johnson et al. Oct 2016 A1
20160357192 McGrew et al. Dec 2016 A1
20170003684 Knudsen et al. Jan 2017 A1
20170057081 Krohne et al. Mar 2017 A1
20170089829 Bartholomew et al. Mar 2017 A1
20170093122 Bean et al. Mar 2017 A1
20170097274 Thorpe et al. Apr 2017 A1
20170115218 Huang et al. Apr 2017 A1
20170134497 Harter et al. May 2017 A1
20170158353 Schmick Jun 2017 A1
20170199647 Richman et al. Jul 2017 A1
20170206648 Marra et al. Jul 2017 A1
20170235018 Foster et al. Aug 2017 A1
20170259920 Lai et al. Sep 2017 A1
20170307519 Black et al. Oct 2017 A1
20170336281 Waxman et al. Nov 2017 A1
20170339820 Foster et al. Nov 2017 A1
20180023974 Otani et al. Jan 2018 A1
20180045561 Leen et al. Feb 2018 A1
20180045596 Prasad et al. Feb 2018 A1
20180050798 Kapuria Feb 2018 A1
20180059003 Jourdainne et al. Mar 2018 A1
20180067066 Giedd et al. Mar 2018 A1
20180109767 Li et al. Apr 2018 A1
20180127093 Christensen et al. May 2018 A1
20180188129 Choudhury et al. Jul 2018 A1
20180259955 Noto Sep 2018 A1
20180266241 Ferguson et al. Sep 2018 A1
20180266946 Kotidis et al. Sep 2018 A1
20180209902 Myshak et al. Oct 2018 A1
20180284088 Verbeck, IV Oct 2018 A1
20180292374 Dittberner et al. Oct 2018 A1
20180321692 Castillo-Effen et al. Nov 2018 A1
20180322699 Gray et al. Nov 2018 A1
20190011920 Heinonen et al. Jan 2019 A1
20190011935 Ham et al. Jan 2019 A1
20190025199 Koulikov Jan 2019 A1
20190033194 DeFreez et al. Jan 2019 A1
20190049364 Rubin Feb 2019 A1
20190077506 Shaw et al. Mar 2019 A1
20190086202 Guan et al. Mar 2019 A1
20190095687 Shaw et al. Mar 2019 A1
20190154874 Shams et al. May 2019 A1
20190178743 Mcneil Jun 2019 A1
20190195789 Pan et al. Jun 2019 A1
20190204189 Mohr, Jr. et al. Jul 2019 A1
20190212419 Jeong et al. Jul 2019 A1
20190220019 Tan et al. Jul 2019 A1
20190228573 Sen et al. Jul 2019 A1
20190234868 Tanomura et al. Aug 2019 A1
20190331652 Ba et al. Oct 2019 A1
20200109976 Ajay et al. Apr 2020 A1
20200249092 Podmore et al. Aug 2020 A1
20200400635 Potyrailo et al. Dec 2020 A1
20210017926 Alkadi et al. Jan 2021 A1
20210109074 Smith et al. Apr 2021 A1
20210140934 Smith et al. May 2021 A1
20210190745 Buckingham et al. Jun 2021 A1
20210190918 Li et al. Jun 2021 A1
20210247369 Nottrott et al. Aug 2021 A1
20210255158 Smith et al. Aug 2021 A1
20210300591 Tian Sep 2021 A1
20210321174 Sun et al. Oct 2021 A1
20210364427 Smith et al. Nov 2021 A1
20210382475 Smith et al. Dec 2021 A1
20220113290 Smith et al. Apr 2022 A1
20220268952 Liang et al. Aug 2022 A1
20220341806 Miller et al. Oct 2022 A1
20230194487 Buckingham et al. Jun 2023 A1
Foreign Referenced Citations (37)
Number Date Country
3401499 Nov 1999 AU
104458588 Mar 2015 CN
205749271 Nov 2016 CN
106769977 May 2017 CN
107703075 Feb 2018 CN
109780452 May 2019 CN
211508182 Sep 2020 CN
112213443 Jan 2021 CN
29601472 May 1996 DE
69333010 Apr 2004 DE
102014013822 Mar 2016 DE
1371962 Jul 2011 EP
3047073 Aug 2019 FR
2538563 Nov 2016 GB
200975823 Apr 2009 JP
20170062813 Jun 2017 KR
101770254 Aug 2017 KR
522226 Mar 2003 TW
1999054700 Oct 1999 WO
02066950 Aug 2002 WO
2008021311 Feb 2008 WO
2015073687 May 2015 WO
2016045791 Mar 2016 WO
2016162673 Oct 2016 WO
2017069979 Apr 2017 WO
2018121478 Jul 2018 WO
2018227153 Dec 2018 WO
2019246280 Dec 2019 WO
2020007684 Jan 2020 WO
2020028353 Feb 2020 WO
2020086499 Apr 2020 WO
2020206006 Oct 2020 WO
2020206020 Oct 2020 WO
2021055902 Mar 2021 WO
2021158916 Aug 2021 WO
2022093864 May 2022 WO
2022211837 Oct 2022 WO
Non-Patent Literature Citations (42)
Entry
International Search Report and Written Opinion for PCT/US22/38951, mailed Nov. 28, 2022.
Kelly J F et al. “A capillary absorption spectrometer for stable carbon isotope ratio (C/C) analysis in very small samples”, Review of Scientific Instruments, American Institute of Physics, 2 Huntington Quadrangle, Melville, NY 11747, vol. 83, No. 2, Feb. 1, 2012 (Feb. 1, 2012), pp. 23101-23101, XP012161835, ISSN: 0034-6748, DOI: 10.1063/1.3680593.
Krings et al., Atmos. Meas. Tech., 11, 721-739, Feb. 7, 2018.
Lilian Joly, The evolution of AMULSE (Atmospheric Measurements by Ultra-Light Spectrometer) and its interest in atmospheric applications. Results of the Atmospheric Profiles of Greenhouse gasEs (APOGEE) weather balloon release campaign for satellite retrieval validation, p. 1-28, Sep. 25, 2019, Atmospheric Measurement Techniques Discussion (Joly).
International Search Report and Written Opinion for PCT/US23/13893, mailed Jun. 30, 2023.
U.S. Appl. No. 62/687,147, filed Jun. 19, 2018, Brendan James Smith.
International Search Report and Written Opinion for PCT/US19/38011 mailed Sep. 9, 2019.
International Search Report and Written Opinion for PCT/US19/38015, mailed Oct. 18, 2019.
International Search Report and Written Opinion for PCT/US19/44119, mailed Oct. 17, 2019.
International Search Report and Written Opinion for PCT/US20/26228 mailed Jul. 1, 2020.
International Search Report and Written Opinion for PCT/US20/26232 mailed Jun. 26, 2020.
International Search Report and Written Opinion for PCT/US20/26246 mailed Jun. 29, 2020.
International Search Report and Written Opinion for PCT/US20/51696, mailed Feb. 3, 2021.
International Search Report and Written Opinion for PCT/US2020/044978, mailed Oct. 26, 2020.
International Search Report and Written Opinion for PCT/US2021/016821 mailed Apr. 26, 2021.
International Search Report and Written Opinion for PCT/US2021/024177, mailed Jun. 23, 2021.
International Search Report and Written Opinion for PCT/US2021/056708, mailed Jan. 27, 2022.
International Search Report and Written Opinion for PCT/US21/42061, mailed Nov. 26, 2021.
International Search Report and Written Opinion for PCT/US21/44532, mailed Jan. 11, 2022.
International Search Report and Written Opinion of PCT/US19/57305, mailed Jan. 2, 2020.
International Search Report and Written Opinion of PCT/US20/54117, mailed Dec. 22, 2020.
Joly, “Atmospheric Measurements by Ultra-Light Spectrometer (AMULSE) Dedicated to Vertical Profile In Situ Measurements of Carbon Dioxide (CO2) Under Weather Balloons: Instrumental Development and Field Application,” Sensors 2016, 16, 1609.
Khan, “Low Power Greenhouse Gas Sensors for Unmanned Aerial Vehicles”, Remote Snse. 2012, 4, 1355-1368.
Villa. “An Overview of Small Unmanned Aerial Vehicles for Air Quality Measurements: Present Applications and Future Prospectives”. Sensors. Web . Jul. 12, 2016.
White, “Development of an Unmanned Aerial Vehicle for the Measurement of Turbulence in the Atmospheric Boundary Layer”, Atmosphere, v.8, issue 10, 195, pp. 1-25.
“SAFESITE Multi-Threat Detection System”, Jul. 11, 2012 (Jul. 11, 2012), pp. 1-6, XP055245980.
International Search Report and Written Opinion for PCT/US21/56710, mailed Feb. 23, 2022.
Clilverd, Mark A. et al., Energetic particle injection, acceleration, and loss during the geomagnetic disturbances which upset Galaxy 15, Journal of Geophysical Research, vol. 117, A12213, doi: 10.1029/2012JA018175, 2012, pp. 1-16 (Year:2012).
Kem, Christoph et al., Spatial Distribution of Halogen Oxides in the Plume of Mount Pagan Volcano, Mariana Islands, Geophysical Research Letters 10.1029/2018GL079245, Sep. 27, 2018, pp. 9588-9596 (Year:2018).
Liao, J. et al. Observations of Inorganic bromine(HOBr, BrO, and Br2) speciation at Barrow, Alaska in spring 2009, Journal of Geophysical Research, vol. 117, D00R16, doi:10.1029/2011JD016641, 2012, pp. 1-11 (Year:2012).
Liu, Siwen et al., Development of a UAV-Based System to Monitor Air Quality over an Oil Field, Montana Technological University, Montana tech Library Digital Commons @ Montana Tech Graduate Theses & Non-Theses, Fall 2018, pp. 1-85 (Year:2018).
Miyama, Toru et al., Estimating allowable carbon emission for CO2 concentration stabilization using a GCM-based Earth system model, Geophysical Research Letters, vol. 36,L19709, doi:10.1029/2009GL039678, 2009, pp. 0094-8276 (Year:2009).
Oppenheimer Clive et al., Ultraviolet Sensing of Volcanic Sulfur Emissions, Elements (An Internatioknal Magazine of Mineralogy, Geochemistry, and Petrology), Apr. 2010, vol. 6, pp. 87-92 (Year: 2010).
Parazoo, Nicholas C. et al., Interpreting seasonal changes in the carbon balance of southern Amazonia using measurements of XCO2 and chlorophyll fluorescence from GOSAT, Geophysical Research Letters, vol. 40.2829-2833, doi: 10.1002/grl.50452, 2013 pp. 2829-2833 (Year:2013).
Queiber, Manuel et al., A new frontier in CO2 flux measurements using a highly portable DIAL laser system, Scientific Reports, DOI: 10.1038/srep33834 1, Sep. 22, 2016, pp. 1-13(Year:2016).
Queiber, Manuel et al., Large-area quantification of subaerial CO2 anomalies with portable laser remote sensing and 2d tomography, The Leading Edge Mar. 2018, pp. 306-313 (Year:2018).
International Search Report and Written Opinion for PCT/US2023/023933 mailed Sep. 26, 2023.
International Search Report and Written Opinion for PCT/US23/23905 mailed Oct. 5, 2023.
Development of a mobile tracer correlation method for assessment of air emissions from landfills and other area sources, Atmospheric Environment 102 (2015) 323-330. T.A. Foster-Wittig et. al. 2015.
Measurements of Methane Emissions from Landfills Using a Time Correlation Tracer Method Based on FTIR Absorption Spectroscopy, Environ. Sci. Technol. 2001, 35, 21-25, B. Galle et. al. 2001.
Cabreira et al. “Survey on Coverage Path Planning with Unmanned Aerial Vehicles”, published: Drones, published: Jan. 2019, pp. 1-38, year 2019.
Feng, Lingbing, Nowak, Gen, O'Neill, T.J., Welsh, A.H. “Cutoff; A spatio-temporal imputation method.” Journal of Hydrology 519 (2014) : 3591-3605 (Year:2014).
Related Publications (1)
Number Date Country
20210199565 A1 Jul 2021 US
Provisional Applications (1)
Number Date Country
62955536 Dec 2019 US