An optoelectronic component and a method for producing an optoelectronic component are specified herein. For example, the optoelectronic component is suitable for emitting electromagnetic radiation, for example in the visible to infrared spectral range.
Various methods such as photolithography or so-called spacer technology, in which a spacer layer is structured in a self-adjusting manner, are used for structuring layers, for example passivation layers, in optoelectronic components. Spacer technology is used in particular at step-like junctions of semiconductor layer sequences of optoelectronic components. While photolithography is relatively cost-intensive, for spacer technology only a limited selection of so-called spacer materials, for example TEOS (tetraethyl orthosilicate), can be used with which the necessary requirements, such as conformal edge coverage and sufficient layer thickness at an acceptable growth rate, can be met. While a relatively thick spacer layer is desirable during processing, a spacer produced from it takes up a relatively large amount of space in the finished component, which is lost, for example, as a contact area for electrical connections, which can lead to higher contact resistance and reduced performance of the optoelectronic components.
Embodiments provide a high-performance optoelectronic component. Further embodiments provide an efficient method for producing such an optoelectronic component.
According to at least one embodiment of an optoelectronic component, the optoelectronic component comprises a structured region.
The structured region may include a semiconductor body comprising a first semiconductor region and a second semiconductor region, which have different conductivities. For example, the semiconductor body may have an active zone between the first and second semiconductor regions, the active zone being provided for receiving or generating electromagnetic radiation. In particular, the optoelectronic component is a radiation-emitting component. The semiconductor body can be structured, having a structuring corresponding to the structured region.
The first and second semiconductor regions and the active zone can each be formed from one or more semiconductor layers. The semiconductor layers can be layers epitaxially deposited on a growth substrate. The growth substrate can remain in the semiconductor body after the semiconductor layers have grown or can be at least partially removed.
Materials based on arsenide, phosphide or nitride compound semiconductors, for example, can be considered for the semiconductor regions or semiconductor layers of the semiconductor body. “Based on arsenide, phosphide or nitride compound semiconductors” in the present context means that the semiconductor layers contain AlnGamIn1-n-mAs, AlnGamIn1-n-mP or AlnGamIn1-n-mN, with 0≤n≤1, 0≤m≤1 and n+m≤1. This material does not necessarily have to have a mathematically exact composition according to the above formula. Rather, it can include one or more dopants as well as additional constituents that essentially do not change the characteristic physical properties of the AlnGamIn1-n-mAs, AlnGamIn1-n-mP or AlnGamIn1-n-mN material. For the sake of simplicity, however, the above formula only contains the essential constituents of the crystal lattice (Al, Ga, In, As or P or N), even if these may be partially replaced by small amounts of other substances.
Furthermore, the structured region may have a first main surface and a second main surface, which delimit the structured region on two opposite sides, for example. The first semiconductor region can be arranged on a side of the second semiconductor region facing the first main surface, and the second semiconductor region can be arranged on a side of the first semiconductor region facing the second main surface.
The structured region can have at least one structured layer that is arranged on the semiconductor body. This may, for example, be a contact layer, a reflective layer or a dielectric layer. The at least one structured layer can be arranged on a surface of the semiconductor body facing the first main surface.
Furthermore, the structured region may have at least one first delimiting surface and at least one second delimiting surface, wherein the at least one first delimiting surface laterally delimits a recess extending from the first main surface into the structured region, and the at least one second delimiting surface delimits the recess on a side facing the second main surface. The recess may be open on one or more sides. Alternatively, the recess may be closed on all sides. In other words, the recess may be partially or completely delimited laterally by one or more first delimiting surfaces.
In the present case, a recess means, for example, a space between a raised partial region and a lower partial region of the structured region.
For example, the second delimiting surface can be formed by a surface of the second semiconductor region of the semiconductor body. The surface can be arranged essentially parallel to the second main surface, i.e. within the usual manufacturing tolerances. Furthermore, at least a part of the first delimiting surface can be formed by a surface of the semiconductor body arranged transversely to the first and/or second main surface.
Further, the optoelectronic component may comprise an electrically weakly conductive or non-conductive protective layer arranged on the at least one first delimiting surface and covering a junction between the first semiconductor region and the second semiconductor region in the recess. The protective layer may be provided to electrically insulate a p-n junction, for example present in the active zone, from the environment. For example, the protective layer can serve as a spacer between the junction or the active zone and an electrical contact means of the optoelectronic component. The protective layer can be arranged on all first delimiting surfaces that laterally delimit the recess.
Furthermore, the first main surface of the structured region can be uncovered by the protective layer. An initial layer used to produce the protective layer can first be applied to the first main surface and then structured so that it no longer covers the first main surface.
According to at least one embodiment, the optoelectronic component comprises
According to at least one embodiment or configuration, the protective layer is a layer conformally deposited on the structured region. In the case of conformal deposition, layer growth on vertical edges is just as high as on horizontal surfaces. A conformally deposited layer can therefore have a constant thickness. For example, the thickness of the protective layer can be relatively small compared to spacer layers and can be between a few nanometers and a few hundred nanometers.
According to at least one embodiment or configuration, the protective layer contains an oxide or nitride. For example, the protective layer may contain at least one of the following materials: Al2O3, Ta2O5, HfO2, SiO2, SiN, AlN. The protective layer can be multilayered and contain a combination of the materials mentioned. Such materials are characterized, for example, by their passivation properties. Advantageously, the materials used for the protective layer can be selected relatively freely based on the method described herein.
According to at least one embodiment or configuration, the protective layer is retracted from the first main surface and has a vertical distance from a plane of the first main surface that is greater than or equal to zero. The vertical distance is determined along a vertical direction that is transverse to a main extension plane of the structured region.
Furthermore, the protective layer can extend from the at least one first delimiting surface to or onto the second delimiting surface and have a vertical distance from the second delimiting surface which is essentially zero, i.e. within the scope of usual manufacturing tolerances. Here, regions of the first delimiting surface arranged between the junction between the semiconductor regions and the second delimiting surface can be at least largely covered by the protective layer.
Alternatively, the protective layer can be retracted from the second delimiting surface and have a vertical distance therefrom which is greater than zero. In this case, the at least one first delimiting surface can be largely uncovered by the protective layer. For example, the protective layer can be delimited to the junction between the semiconductor regions.
According to at least one embodiment or configuration, the protective layer has an opening region at the second delimiting surface, in which the second delimiting surface is uncovered by the protective layer. The uncovered region of the second delimiting surface can form a contact area of the semiconductor body.
According to at least one embodiment or configuration, the optoelectronic component comprises an electrical contact means which is arranged in the opening region of the protective layer. The electrical contact means can extend from the first main surface of the structured region through the recess to the second delimiting surface and form a second electrode of the optoelectronic component.
According to at least one embodiment or configuration, the optoelectronic component comprises a further electrical contact means arranged at the first main surface. For example, the further electrical contact means may be arranged on a side of the semiconductor body facing the first main surface and form a first electrode of the optoelectronic component. The two electrical contact means or the first and second electrodes can be electrically insulated from each other by an insulating layer.
According to at least one embodiment or configuration, the optoelectronic component comprises a further protective layer, which is arranged on the protective layer and has a greater thickness than the protective layer arranged underneath. The further protective layer may contain an oxide, for example SiO2, or nitride, for example SiNx. Furthermore, the further protective layer can be a conformally deposited layer. The thickness of the further protective layer can be between 200 nm and 10 μm, in particular between 400 nm and 2 μm. The further protective layer can be produced using CVD (chemical vapor deposition) or PECVD (plasma-enhanced CVD). The further protective layer, together with the protective layer on which it is arranged, can serve as a spacer between the junction between the semiconductor regions and the electrical contact means arranged in the recess.
The method described below is suitable for producing an optoelectronic component of the above-mentioned type. Features described in connection with the optoelectronic component therefore also apply to the method and vice versa.
According to at least one embodiment of a method for producing an optoelectronic component of the above-mentioned type, the method comprises:
The structured, second initial layer therefore has the function of a mask layer, in particular the function of an etching mask. This means that no photolithographic processes are required for structuring the first initial layer.
Furthermore, the structured second initial layer can be completely removed and thus serve as a sacrificial layer. Due to the function of the structured second initial layer as a mask or sacrificial layer, a surface of the first initial layer covered by the structured second initial layer is advantageously less attacked during structuring, so that the protective layer has a lower surface roughness, which has a positive effect on the reflective properties of reflective means arranged thereon and thus on the brightness of the component.
According to at least one embodiment or configuration, the second initial layer is produced thicker than the first initial layer. The second initial layer can be structured by means of an anisotropic etching process. For example, the second initial layer can be structured in a self-adjusting manner by anisotropic back-etching. “In a self-adjusting manner” in the present context means in particular that no lithographic processes are used for structuring. A layer or etch removal can correspond to the thickness of the second initial layer. For example, the second initial layer can be produced from SiO2 or SiNx by chemical vapor deposition, for example by CVD or PECVD. This allows a relatively conformal layer to be generated at an acceptable deposition rate.
According to at least one embodiment or configuration, the first initial layer is produced by one of the following methods: ALD (atomic layer deposition), PECVD (plasma-enhanced chemical vapor deposition), sputtering. Using these methods, it is possible to deposit the first initial layer conformally with a comparatively low thickness. It is possible to apply several first initial layers to the structured region to produce one or more protective layers. Advantageously, the materials used can be selected relatively freely. In particular, materials based on an oxide or nitride such as Al2O3, Ta2O5, HfO2, SiO2, SiN or AlN can be considered for the first initial layer.
According to at least one embodiment or configuration, the first initial layer is structured using a dry-chemical etching process. In this process, the first initial layer is etched selectively to the structured second initial layer. The structured first initial layer can be flush with the structured second initial layer. In other words, the first initial layer can be removed except for a region covered by the structured second initial layer.
Alternatively, the first initial layer can be structured using a wet-chemical etching process. This requires sufficient etching selectivity between the first initial layer and the second initial layer. The wet-chemical etching process is a gentler method than the dry-chemical etching process, as the etched material is less damaged. The structured second initial layer can be underetched. In other words, the first initial layer can also be removed in areas covered by the structured second initial layer.
According to at least one embodiment, the structured second initial layer is removed after structuring of the first initial layer. This can be done, for example, by a wet-chemical etching process, in particular selectively to the structured first initial layer.
Further advantages, advantageous embodiments and further developments will become apparent from the exemplary embodiments described below in conjunction with the figures.
In the exemplary embodiments and figures, identical, similar or similarly acting elements can each be provided with the same reference signs. The elements shown and their relative sizes are not necessarily to be regarded as true to scale; rather, individual elements may be shown exaggeratedly large for better visualization and/or better understanding.
First, a structured region 2′ having a structured semiconductor body 3′ is provided. The structured region 2′ has a recess 4′, so that the structured region 2′ has a step-like course from a first main surface 2A′ to a second delimiting surface 2D′ in the schematic cross-sectional view shown in
For example, a sufficiently thick initial layer 6′ is generated from TEOS on the structured region 2′ (see
Furthermore, a so-called spacer 8′ is generated by anisotropic etching of the initial layer 6′ (see
With reference to
First, a structured region 2 is provided (see
The semiconductor body 3 comprises a first semiconductor region 9 of a first conductivity and a second semiconductor region 11 of a second conductivity. An active zone 10 may be arranged at a junction 18 between the first and second semiconductor regions 9, 11, wherein the active zone 10 may be provided for generating or receiving electromagnetic radiation. For example, the first semiconductor region 9 is a p-doped region and the second semiconductor region 11 is an n-doped region.
The first and second semiconductor regions 9, 11 and the active zone 10 can each be formed from one or more semiconductor layers. The semiconductor layers may be layers epitaxially deposited on a growth substrate. The growth substrate can remain in the semiconductor body 3 after the semiconductor layers have grown or can be at least partially removed. For the semiconductor regions 9, 10, 11 or semiconductor layers of the semiconductor body 3, materials based on arsenide, phosphide or nitride compound semiconductors, for example, can be considered, as already explained in more detail above.
Furthermore, the structured region 2 has a first main surface 2A and a second main surface 2B. The first semiconductor region 9 is arranged on a side of the second semiconductor region 11 facing the first main surface 2A, and the second semiconductor region 11 is arranged on a side of the first semiconductor region 9 facing the second main surface 2B.
Furthermore, the structured region 2 has a first delimiting surface 2C and a second delimiting surface 2D, wherein the first delimiting surface 2C laterally delimits a recess 4 extending from the first main surface 2A into the structured region 2, and the second delimiting surface 2D delimits the recess 4 on a side facing the second main surface 2B. At the same time, a raised partial region 12 of the structured region 2 is delimited by the first delimiting surface 2C on a side facing the recess 4. Furthermore, a lower partial region 13 of the structured region 2 is delimited by the first delimiting surface 2C on a side facing the recess 4.
In a further step, a first initial layer 5 for producing an electrically weakly conductive or non-conductive protective layer 7 is generated on the first main surface 2A, the first delimiting surface 2C and the second delimiting surface 2D (see
In conformal deposition, layer growth on vertical edges, i.e. for example on the first delimiting surface 2C, is just as high as on horizontal surfaces, i.e. for example on the first main surface 2A and the second delimiting surface 2D. The conformally deposited initial layer 5 can therefore have a constant thickness d1, which is between a few nanometers and a few hundred nanometers, for example.
The initial layer 5 can be formed from an oxide such as Al2O3, Ta2O5, HfO2 or SiO2 or a nitride such as SiN or AlN. Advantageously, the materials for the initial layer 5 are relatively freely selectable, since the initial layer 5 does not have to fulfill the requirements for a mask layer or sacrificial layer, which are instead fulfilled by a second initial layer 6 (see
In a further step, a second initial layer 6 is generated on the first initial layer 5 to produce a further protective layer 8 (see
In a further step, structuring of the second initial layer 6 is performed, wherein regions of the second initial layer 6 arranged on the first main surface 2A and regions arranged on the second delimiting surface 2D are removed (cf.
Subsequently, the first initial layer 5 is structured by means of the structured second initial layer 6, wherein regions that are uncovered by the structured second initial layer 6 are removed (see
The first initial layer 5 can be structured selectively to the second initial layer 6 by means of a dry-chemical etching process. The structured first initial layer 5 can then be flush with the structured second initial layer 6. In other words, the first initial layer 5 can be removed except for an area covered by the structured, second initial layer 6.
An optoelectronic component produced using this method can have a first protective layer 7 arranged on the first and second delimiting surfaces 2C, 2D which has an L-shape in cross-section and covers the junction 18 between the two semiconductor regions 9, 11 or the active zone 10 in the recess 4, the first main surface 2A being uncovered by the protective layer 7. Here, the first protective layer 7 can be identical to the structured first initial layer 5. Furthermore, the component produced in this way can have a further protective layer 8, which is identical to the structured second initial layer 6. The first and second protective layers 7, 8 can form a spacer between the junction 18 or the active zone 10 and an electrical contact means (see
As shown in
In a further step, the first initial layer 5 is structured by means of the structured second initial layer 6, which thus serves as a mask layer, in particular as an etching mask (see
In a further step, the structured second initial layer 6 is removed (see
Due to the function of the structured second initial layer 6 as a mask or sacrificial layer, a surface 5A of the first initial layer 5 covered by the structured second initial layer is advantageously less attacked during structuring, so that the protective layer 7 has a lower surface roughness, which has a positive effect on the reflective properties of reflective means arranged thereon and thus on the brightness of the component (see also
An optoelectronic component produced by this method can have a first protective layer 7 arranged on the first and second delimiting surfaces 2C, 2D which has an L-shape in cross-section and covers the junction 18 or the active zone 10 in the recess 4, the first main surface 2A being uncovered by the protective layer 7 and the protective layer 7 being retracted from the first main surface 2A. In this case, the first protective layer 7 can be substantially flush with the first main surface 2A, i.e. within the usual manufacturing tolerances, so that a vertical distance to a plane of the first main surface 2A is zero or tends towards zero. The protective layer 7 can be identical to the structured first initial layer 5. The first protective layer 7 can form a spacer between the p-n junction 18 or between the active zone 10 and an electrical contact means (see
As shown in
In a further step, the first initial layer 5 is structured by means of the structured second initial layer 6 (see
In a further step, the structured second initial layer 6 is removed (see
An optoelectronic component produced by this method can have a first protective layer 7 arranged on the first and second delimiting surfaces 2C, 2D which has an L-shape in cross-section and covers the junction 18 or the active zone 10 in the recess 4, wherein
With reference to
Here, a structured region 2 is provided, which comprises a structured semiconductor body 3 and at least one structured layer 14, which is arranged on the semiconductor body 3. The at least one structured layer 14 may be, for example, a contact layer, a reflective layer or a dielectric layer. The at least one structured layer 14 is arranged on a surface 3A of the semiconductor body 3 facing the first main surface 2A. Analogous to the steps shown in
The further steps are similar to the steps shown in
The structured second initial layer 6 is used for structuring the first initial layer 5. The structuring can be carried out, for example, by wet-chemical etching (see
The expansion of the structured first initial layer 5 or the first protective layer 7 is advantageously decoupled from the thickness of the second initial layer 6. The structured first initial layer 5 or first protective layer 7 is generated in a self-adjusting manner without the use of photo technology.
After structuring the first initial layer 5, the second initial layer can be removed in a manner analogous to the step shown in
In the comparative example shown in
In the exemplary embodiments shown in
In the exemplary embodiment shown in
In the exemplary embodiment shown in
In the exemplary embodiment shown in
In the exemplary embodiment shown in
With reference to
The optoelectronic component 1 comprises a structured region 2 which has a structured semiconductor body 3 with a first semiconductor region 9, an active zone 10 and a second semiconductor region 11 as well as structured layers 14A, 14B which are arranged on the semiconductor body 3. The structured layer 14A is, for example, a contact layer or a first electrical contact means that serves as a first electrode of the component 1. Furthermore, the structured layer 14B may be an insulating layer forming an electrical insulation between the first contact means and a second electrical contact means 16.
The structured region 2 has a first main surface 2A and a second main surface 2B, wherein the structured layers 14A, 14B are arranged on a surface 3A of the semiconductor body 3 which is located on a side of the semiconductor body 3 facing the first main surface 2A.
Furthermore, the structured region 2 has a plurality of first delimiting surfaces 2C and a second delimiting surface 2D, wherein the first delimiting surfaces 2C laterally delimit a recess 4 extending from the first main surface 2A into the structured region 2 or into the second semiconductor region 11, and the at least one second delimiting surface 2D delimits the recess 4 on a side facing the second main surface 2B. The recess 4 is thus closed on all sides. The second delimiting surface 2D is formed by a surface 11A of the second semiconductor region 11, which is arranged on a side facing the first main surface 2A. The surface 11A can be arranged substantially parallel to the second main surface 2B, i.e. within the scope of usual manufacturing tolerances. Furthermore, a part of each first delimiting surface 2C is formed by a surface 3C of the semiconductor body 3 arranged transversely to the first and second main surfaces 2A, 2B.
The recess 4 forms an intermediate space which is located between a raised partial region 12 and a lower partial region 13 of the structured region 2. The structured layers 14A, 14B, the first semiconductor region 9, the active zone 10 and a part of the second semiconductor region 11 are located in the raised partial region 12. A further part of the second semiconductor region 11 is located in the lower partial region 13.
The structured region 2 further comprises an electrically weakly conductive or non-conductive protective layer 7 arranged on the first delimiting surfaces 2C and covering the active zone 10 in the recess 4, wherein the first main surface 2A is uncovered by the protective layer 7. The uncovered main surface 2A can be obtained, for example, by structuring the second initial layer in a self-adjusting manner and structuring the first initial layer by means of the structured second initial layer, as described in connection with the various exemplary embodiments of a method. The protective layer 7 is essentially limited in its expansion to the region of the active zone 10, which can be achieved during production, for example, by long underetching of the second initial layer (cf.
The protective layer 7 is a layer conformally deposited on the structured region 2 and containing an oxide such as Al2O3, Ta2O5, HfO2 or SiO2 or a nitride such as SiN or AlN. The protective layer 7 can be multilayered and comprise a combination of the aforementioned materials. The protective layer 7 is characterized, for example, by advantageous passivation properties.
The protective layer 7 has an opening region 7A at the second delimiting surface 2D, in which the second electrical contact means 16 is arranged. The second electrical contact means 16 extends from the first main surface 2A through the recess 4 onto the second delimiting surface 2D and forms a second electrode of the optoelectronic component 1. Compared to the comparative example shown in
These improved optoelectronic properties lead to a greater freedom in terms of component design. For example, the second contact means 16 can be designed with smaller lateral dimensions, which reduces light-absorbing surfaces. In return, the component can have additional reflective layers, making the component brighter overall.
The invention is not limited by the description based on the exemplary embodiments. Rather, the invention includes any new feature as well as any combination of features, which includes in particular any combination of features in the patent claims, even if this feature or combination itself is not explicitly stated in the patent claims or embodiments.
Number | Date | Country | Kind |
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10 2021 130 159.9 | Nov 2021 | DE | national |
This patent application is a national phase filing under section 371 of PCT/EP2022/081401, filed Nov. 10, 2022, which claims the priority of German patent application 102021130159.9, filed Nov. 18, 2021, each of which is incorporated herein by reference in its entirety.
Filing Document | Filing Date | Country | Kind |
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PCT/EP2022/081401 | 11/10/2022 | WO |