This application claims priority to and the benefit of Korean Patent Application No. 10-2011-0066125, filed on Jul. 4, 2011, in the Korean Intellectual Property Office, the disclosure of which is incorporated herein in its entirety by reference.
1. Field
One or more aspects of embodiments according to the present invention relate to an organic layer deposition apparatus and a method of manufacturing an organic light-emitting display device by using the same.
2. Description of Related Art
Organic light-emitting display devices have a larger viewing angle, better contrast characteristics, and a faster response speed than other display devices, and thus have drawn attention as next-generation display devices.
An organic light-emitting display device includes an intermediate layer, which includes an emission layer, between a first electrode and a second electrode that are arranged opposite to each other. The electrodes and the intermediate layer may be formed via various methods, one of which is to perform a separate deposition method for each of the electrodes and the intermediate layer. When an organic light-emitting display device is manufactured by using the separate deposition method, a fine metal mask (FMM) having the same pattern as an organic layer to be formed is typically disposed to closely contact a substrate, and an organic material is deposited over the FMM in order to form the organic layer having a desired pattern.
In order to address the drawback of the separate deposition method using an FMM, one or more aspects of embodiments according to the present invention provide an organic layer deposition apparatus that may be simply applied to produce large-sized display devices on a mass scale and that may be precisely aligned with respect to a substrate during a deposition process.
According to an aspect according to embodiments of the present invention, there is provided an organic layer deposition apparatus for forming an organic layer on a substrate. The apparatus includes a deposition source configured to discharge a deposition material; a deposition source nozzle unit located at a side of the deposition source and including a plurality of deposition source nozzles arranged in a first direction; and a patterning slit sheet located opposite to the deposition source nozzle unit and having a plurality of patterning slits arranged in a second direction perpendicular to the first direction. The patterning slit sheet is smaller in at least one of the first and second directions than the substrate. Deposition is performed while the substrate is spaced from the patterning slit sheet, and is moved relative to the organic layer deposition apparatus in the first direction. The patterning slit sheet includes a first alignment mark and a second alignment mark that are located apart from each other. The substrate includes a first alignment pattern and a second alignment pattern that are located apart from each other. The organic layer deposition apparatus further includes a first camera assembly for photographing the first alignment mark and the first alignment pattern, and a second camera assembly for photographing the second alignment mark and the second alignment pattern. A moving speed of the substrate is synchronized with shooting speeds of the first and second camera assemblies so that when the substrate is appropriately aligned with the organic layer deposition apparatus, images of the first alignment pattern captured by the first camera assembly are substantially the same as each other, and images of the second alignment pattern captured by the second camera assembly are substantially the same as each other.
The deposition source, the deposition source nozzle unit, and the patterning slit sheet may be integrally formed as one body.
The deposition source and the deposition source nozzle unit, and the patterning slit sheet may be integrally connected as one body by connection members for guiding movement of the deposition material.
The connection members may be formed to seal a space between the deposition source, the deposition source nozzle unit, and the patterning slit sheet.
The plurality of deposition source nozzles may be tilted at an angle.
The plurality of deposition source nozzles may include deposition source nozzles arranged in two rows in the first direction. The deposition source nozzles in the two rows may be tilted to face each other.
The plurality of deposition source nozzles may include deposition source nozzles arranged in two rows in the first direction. The deposition source nozzles of a row located at a first side of the patterning slit sheet from among the two rows may be arranged to face a second side of the patterning slit sheet. The deposition source nozzles of the other row located at a second side of the patterning slit sheet from among the two rows may be arranged to face a first side of the patterning slit sheet.
The first alignment pattern may include a plurality of first marks arranged along the first direction, the second alignment pattern may include a plurality of second marks arranged along the first direction, and the first alignment pattern and the second alignment pattern may be spaced apart from each other in the second direction.
Shapes and sizes of the plurality of first marks and the plurality of second marks may be the same.
Distances between the plurality of first marks may be substantially equal to distances between the plurality of second marks.
Each of the plurality of first marks and the plurality of second marks may have a shape of a cross.
Each of the plurality of first marks or the plurality of second marks may have a polygonal shape.
Each of the plurality of first marks or the plurality of second marks may have a triangular shape.
The first alignment pattern and the second alignment pattern may have a sawtooth shape.
The substrate may be moved at a substantially uniform velocity in the first direction, the first and second camera assemblies may respectively photograph the first alignment pattern and the second alignment pattern at time intervals, the first camera assembly may capture a number of images each containing the first alignment patterns, and the second camera assembly may capture a number of images each containing the second alignment patterns, which is equal to the number of images each containing the first alignment pattern.
The first camera assembly and the second camera assembly may be positioned over the substrate to respectively correspond to the first alignment mark and the second alignment mark.
The organic layer deposition apparatus may further include a controller for determining a degree to which the substrate and the patterning slit sheet are aligned with each other, based on information captured by the first camera assembly and the second camera assembly.
The controller may determine the degree to which the substrate and the patterning slit sheet are aligned with each other in the second direction perpendicular to the first direction, by comparing a first distance between images of the first alignment pattern and the first alignment mark photographed by the first camera assembly, with a second distance between images of the second alignment pattern and the second alignment mark photographed by the second camera assembly.
The controller may determine whether or not the patterning slit sheet is tilted in the first direction, by comparing an image of the first alignment mark captured by the first camera assembly, with an image of the second alignment mark captured by the second camera assembly.
The controller may determine a difference between locations of the captured image of the first alignment mark and the captured image of the second alignment mark in the first direction, may determine that the patterning slit sheet is tilted toward the first alignment mark in the first direction when the captured image of the second alignment mark is located ahead of the captured image of the first alignment mark, and may determine that the patterning slit sheet is tilted toward the second alignment mark in the first direction when the captured image of the second alignment mark is located behind the captured image of the first alignment mark.
The controller may determine whether or not the substrate is tilted in the first direction, by comparing an image of the first alignment pattern captured by the first camera assembly, with an image of the second alignment pattern captured by the second camera assembly.
The controller may determine a difference between locations of the captured image of the first alignment mark and the captured image of the second alignment mark in the first direction, may determine that the substrate is tilted toward the first alignment mark in the first direction when the captured image of the second alignment mark is located ahead of the captured image of the first alignment mark, and may determine that the substrate is tilted toward the second alignment mark in the first direction when the captured image of the second alignment mark is located behind the captured image of the first alignment mark.
The substrate and the patterning slit sheet may be aligned with each other by moving the substrate or the patterning slit sheet, based on the degree of alignment, determined by the controller.
The patterning slit sheet may further include a third alignment mark spaced apart from the first alignment mark in the first direction, and a fourth alignment mark spaced apart from the second alignment mark in the first direction.
A distance between the first and third alignment marks may be equal to a distance between the second and fourth alignment marks.
The first and second alignment marks may be spaced apart from each other in the second direction, and the third and fourth alignment marks may be spaced apart from each other in the second direction.
A distance between the first and second alignment marks may be substantially equal to a distance between the third and fourth alignment marks.
The organic layer deposition apparatus may further include a third camera assembly and a fourth camera assembly. The third and fourth camera assemblies may be positioned over the substrate to respectively correspond to the third and fourth alignment marks.
According to another aspect of the present invention, there is provided an organic layer deposition apparatus for forming an organic layer on a substrate, the apparatus including a deposition source configured to discharge a deposition material; a deposition source nozzle unit located at a side of the deposition source and including a plurality of deposition source nozzles arranged in a first direction; a patterning slit sheet located opposite to the deposition source nozzle unit and having a plurality of patterning slits arranged in the first direction, the patterning slit sheet being smaller than the substrate in at least one of the first direction or a second direction substantially perpendicular to the first direction; and a barrier plate assembly including a plurality of barrier plates that are located between the deposition source nozzle unit and the patterning slit sheet in the first direction and that partition a space between the deposition source nozzle unit and the patterning slit sheet into a plurality of sub-deposition spaces. The organic layer deposition apparatus and the substrate are spaced apart from each other. The organic layer deposition apparatus or the substrate is moved relative to the other during deposition. The substrate includes a first alignment pattern and a second alignment pattern that are disposed apart from each other. The organic layer deposition apparatus further includes a first camera assembly for photographing the first alignment mark and the first alignment pattern, and a second camera assembly for photographing the second alignment mark and the second alignment pattern. A moving speed of the substrate is synchronized with shooting speeds of the first and second camera assemblies so that when the substrate is appropriately aligned with the organic deposition apparatus, images of the first alignment pattern captured by the first camera assembly are substantially the same as each other, and images of the second alignment pattern captured by the second camera assembly are substantially the same as each other.
The plurality of barrier plates may extend in the second direction substantially perpendicular to the first direction.
The barrier plate assembly may include a first barrier plate assembly including a plurality of first barrier plates, and a second barrier plate assembly including a plurality of second barrier plates.
The plurality of first barrier plates and the plurality of second barrier plates may extend in the second direction substantially perpendicular to the first direction.
The plurality of first barrier plates may be arranged to respectively correspond to the plurality of second barrier plates.
The first alignment pattern may include a plurality of first marks arranged along the first direction. The second alignment pattern may include a plurality of second marks arranged along the first direction. The first alignment pattern and the second alignment pattern may be spaced apart from each other in the second direction.
Shapes and sizes of the plurality of first marks and the plurality of second marks may be the same.
Distances between the plurality of first marks may be equal to distances between the plurality of second marks.
Each of the plurality of first marks and the plurality of second marks may have a shape of a cross.
Each of the plurality of first marks or the plurality of second marks may have a polygonal shape.
The substrate may be moved at a substantially uniform velocity in the first direction, the first and second camera assemblies may respectively photograph the first alignment pattern and the second alignment pattern at time intervals, the first camera assembly may capture a number of images each containing the first alignment patterns, and the second camera assembly may capture a number of images each containing the second alignment patterns, which is equal to the number of images each containing the first alignment pattern.
The first camera assembly and the second camera assembly may be positioned over the substrate to respectively correspond to the first alignment mark and the second alignment mark.
The organic layer deposition apparatus may further include a controller for determining a degree to which the substrate and the patterning slit sheet are aligned with each other, based on information captured by the first camera assembly and the second camera assembly.
The controller may determine the degree to which the substrate and the patterning slit sheet are aligned with each other in the second direction substantially perpendicular to the first direction, by comparing a first distance between images of the first alignment pattern and the first alignment mark photographed by the first camera assembly, with a second distance between images of the second alignment pattern and the second alignment mark photographed by the second camera assembly.
The controller may determine whether or not the patterning slit sheet is tilted in the first direction, by comparing an image of the first alignment mark captured by the first camera assembly, with an image of the second alignment mark captured by the second camera assembly.
The controller may determine a difference between locations of the captured image of the first alignment mark and the captured image of the second alignment mark in the first direction, may determine that the patterning slit sheet is tilted toward the first alignment mark in the first direction when the captured image of the second alignment mark is located ahead of the captured image of the first alignment mark, and may determine that the patterning slit sheet is tilted toward the second alignment mark in the first direction when the captured image of the second alignment mark is located behind the captured image of the first alignment mark.
The controller may determine whether or not the substrate is tilted in the first direction, by comparing an image of the first alignment pattern captured by the first camera assembly, with an image of the second alignment pattern captured by the second camera assembly.
The controller may determine a difference between locations of the captured image of the first alignment mark and the captured image of the second alignment mark in the first direction, may determine that the substrate is tilted toward the first alignment mark in the first direction when the captured image of the second alignment mark is located ahead of the captured image of the first alignment mark, and may determine that the substrate is tilted toward the second alignment mark in the first direction when the captured image of the second alignment mark is located behind the captured image of the first alignment mark.
The substrate and the patterning slit sheet may be aligned with each other by moving the substrate or the patterning slit sheet, based on the degree of alignment, determined by the controller.
The patterning slit sheet may further include a third alignment mark spaced apart from the first alignment mark in the first direction, and a fourth alignment mark spaced apart from the second alignment mark in the first direction.
The organic layer deposition apparatus may further include a third camera assembly and a fourth camera assembly. The third and fourth camera assemblies may be positioned over the substrate to respectively correspond to the third and fourth alignment marks.
The above and other features of the present invention will become more apparent by describing in detail exemplary embodiments thereof with reference to the attached drawings in which:
The present invention will now be described more fully with reference to the accompanying drawings in which exemplary embodiments of the invention are shown. In the drawings, the thicknesses of layers and regions are exaggerated for clarity. Like reference numerals in the drawings denote like elements, and thus redundant or duplicate descriptions may be omitted.
In general, a deposition method using a fine metal mask (FMM) is not suitable for manufacturing larger devices using a mother glass having a size of 5G, i.e., 1100 mm×1300 mm, or greater. In other words, when such a large mask is used, the mask may bend due to its own weight, thereby distorting a pattern. This is not conducive for the recent trend towards high-definition patterns.
Referring to
The loading unit 710 may include a first rack 712, a transport robot 714, a transport chamber 716, and a first inversion chamber 718.
A plurality of substrates 500 onto which a deposition material is not applied are stacked up on the first rack 712. The transport robot 714 picks up one of the substrates 500 from the first rack 712, places it on an electrostatic chuck 600 transferred by the second conveyor unit 620, and moves the electrostatic chuck 600 on which the substrate 500 is disposed, into the transport chamber 716.
The first inversion chamber 718 is located adjacent to the transport chamber 716. A first inversion robot 719 located in the first inversion chamber 718 inverts the electrostatic chuck 600 and then loads it onto the first conveyer unit 610 of the deposition unit 730.
Referring to
The unloading unit 720 is constituted to operate in an opposite manner to the loading unit 710 described above. Specifically, a second inversion robot 729 in a second inversion chamber 728 inverts the electrostatic chuck 600 having the substrate 500 thereon, which has passed through the deposition unit 730, and then moves the electrostatic chuck 600 having the substrate 500 disposed thereon, into an ejection chamber 726. Then, an ejection robot 724 removes the electrostatic chuck 600 having the substrate 500 disposed thereon from the ejection chamber 726, separates the substrate 500 from the electrostatic chuck 600, and then loads the substrate 500 onto the second rack 722. The electrostatic chuck 600 separated from the substrate 500 is returned back into the loading unit 710 via the second conveyer unit 620.
However, the present invention is not limited to the above description. For example, when the substrate 500 is initially disposed on the electrostatic chuck 600, the substrate 500 may be fixed onto a bottom surface of the electrostatic chuck 600 and then be moved into the deposition unit 730. In this case, for example, the first inversion chamber 718, the first inversion robot 719, the second inversion chamber 728, and the second inversion robot 729 are not used.
The deposition unit 730 may include at least one deposition chamber. Referring to
Referring to
In the embodiment illustrated in
Referring to
Specifically, the first chamber 731 of
The substrate 500 that is a deposition target substrate is disposed in the first chamber 731. The substrate 500 may be a substrate for flat panel displays. A large substrate, such as a mother glass, for manufacturing a plurality of flat panel displays may be used as the substrate 500. Other substrates may also be employed.
In the current embodiment, deposition is performed while the substrate 500 is moved (e.g., continuously moved) relative to the organic layer deposition apparatus 100.
In particular, in a typical FMM deposition method, the size of an FMM is generally equal to the size of a substrate. Thus, since the size of the FMM is increased as the substrate becomes larger, it is neither straightforward to manufacture a large FMM nor to extend an FMM to be accurately aligned with a pattern.
In order to overcome this problem, in the organic layer deposition apparatus 100 according to the current embodiment, deposition may be performed while the organic layer deposition apparatus 100 or the substrate 500 is moved relative to the other. In other words, deposition may be continuously performed while the substrate 500, which is disposed such as to face the organic layer deposition apparatus 100, is moved in a Y-axis direction. That is, deposition may be performed in a scanning manner while the substrate 500 is moved in a direction indicated with an arrow P in
In the organic layer deposition apparatus 100 according to the current embodiment, the patterning slit sheet 150 may be smaller (e.g., significantly smaller) than an FMM used in the conventional deposition method. In other words, in the organic layer deposition apparatus 100, deposition is continuously performed, i.e., in a scanning manner while the substrate 500 is moved in the Y-axis direction. Thus, lengths of the patterning slit sheet 150 in the X-axis and/or Y-axis directions may be significantly less than the lengths of the substrate 500 in the X-axis and/or Y-axis directions. As described above, since the patterning slit sheet 150 may be formed to be smaller (e.g., significantly smaller) than an FMM used in the conventional deposition method, it is relatively easy to manufacture the patterning slit sheet 150 used in embodiments of the present invention. In other words, using the patterning slit sheet 150, which is smaller than an FMM used in the conventional deposition method, is more convenient in all processes, including etching and other subsequent processes, such as precise extension, welding, moving, and cleaning processes, compared to the conventional deposition method using the larger FMM. This can be more advantageous for a relatively large display device, for example.
The deposition source 110 that contains and heats the deposition material 115 is located at an opposite side of the first chamber 731 to a side at which the substrate 500 is located. While being vaporized in the deposition source 110, the deposition material 115 is deposited on the substrate 500.
For example, the deposition source 110 includes a crucible 112 filled with the deposition material 115, and a cooling block 111 that heats the crucible 112 to vaporize the deposition material 115 in the crucible 112 towards a side of the crucible 112, and in particular, towards the deposition source nozzle unit 120. The cooling block 111 prevents or reduces radiation of heat from the crucible 112 outside, i.e., into the chamber. The cooling block 111 may include a heater (not shown) that heats the crucible 112.
The deposition source nozzle unit 120 is located at a side of the deposition source 110, and in particular, at the side of the deposition source 110 facing the substrate 500. The deposition source nozzle unit 120 includes a plurality of deposition source nozzles 121 that may be arranged at equal intervals in the Y-axis direction, i.e., a scanning direction of the substrate 500. The deposition material 115 that is vaporized in the deposition source 110, passes through the deposition source nozzle unit 120 towards the substrate 500. As described above, when the deposition source nozzle unit 120 includes the plurality of deposition source nozzles 121 arranged in the Y-axis direction, that is, in the scanning direction of the substrate 500, the size of a pattern formed of the deposition material 115 discharged through each of a plurality of patterning slits 151 of the patterning slit sheet 150 is affected by the size of one of the deposition source nozzles 121 (since there is only one deposition source nozzle 121 in the X-axis direction). Thus, no shadow zone may be formed on the substrate 500. In addition, since the plurality of deposition source nozzles 121 are arranged in the scanning direction of the substrate 500, even if there is a difference in flux between the deposition source nozzles 121, the difference may be compensated for and deposition uniformity may be maintained constantly or substantially constantly.
The patterning slit sheet 150 and a frame 155 are located between the deposition source 110 and the substrate 500. A shape of the frame 155 is similar to a window frame. The patterning slit sheet 150 is bound inside the frame 155. The patterning slit sheet 150 has the plurality of patterning slits 151 arranged in the X-axis direction. The deposition material 115 that is vaporized in the deposition source 110, passes through the deposition source nozzle unit 120 and the patterning slit sheet 150 towards the substrate 500. The patterning slit sheet 150 may be manufactured by etching, which is the same method as used in a conventional method of manufacturing an FMM, and in particular, a striped FMM. In this regard, the total number of patterning slits 151 may be greater than the total number of deposition source nozzles 121.
In addition, the deposition source 110 and the deposition source nozzle unit 120 coupled to the deposition source 110 may be arranged to be separated from the patterning slit sheet 150 by a distance (e.g., a predetermined distance). The deposition source 110 and the deposition source nozzle unit 120 coupled to the deposition source 110 may be connected to the patterning slit sheet 150 by connection members 135. That is, the deposition source 110, the deposition source nozzle unit 120, and the patterning slit sheet 150 may be integrally formed as one body by being connected to each other via the connection members 135. The first connection members 135 may guide the deposition material 115 discharged through the deposition source nozzles 121 to move straight and not to flow in the X-axis direction. Referring to the embodiment illustrated in
As described above, the organic layer deposition apparatus 100 according to the current embodiment performs deposition while being moved relative to the substrate 500. In order to move the organic layer deposition apparatus 100 relative to the substrate 500, the patterning slit sheet 150 is located apart from the substrate 500 by a distance (e.g., a predetermined distance).
In particular, in the conventional deposition method using an FMM, deposition is performed with the FMM in close contact with a substrate in order to prevent formation of a shadow zone on the substrate. However, when the FMM is used in close contact with the substrate, the contact may cause defects. In addition, in the typical deposition method, the size of the mask is the same as the size of the substrate since the mask cannot be moved relative to the substrate. Thus, the size of the mask becomes increased as display devices become larger. However, it is not easy to manufacture such a large mask.
In order to overcome this problem, in the organic layer deposition apparatus 100 according to the current embodiment, the patterning slit sheet 150 is arranged to be located (or positioned) apart from the substrate 500 by a distance (e.g., a predetermined distance).
As described above, according to embodiments of the present invention, a mask is formed to be smaller than a substrate, and deposition is performed while the mask is moved relative to the substrate. Thus, the mask can be easily manufactured. In addition, defects caused due to the contact between a substrate and an FMM, which may occur in the conventional deposition method, may be prevented. Furthermore, since it is unnecessary to position the patterning slit sheet 150 (unlike the FMM) in close contact with the substrate during a deposition process, the manufacturing time may be reduced.
In an embodiment of the present invention, the organic layer deposition apparatus 100 may further include first and second alignment patterns 502 and 503, first and second alignment marks 152 and 153, first and second camera assemblies 161 and 162, and a controller 170 so as to align the substrate 500 and the patterning slit sheet 150 with each other.
The first and second alignment patterns 502 and 503 are formed on the substrate 500 along a moving direction P of the substrate 500. The first and second alignment patterns 502 and 520 may be formed at both ends of the substrate 500 to be disposed apart from each other. The first alignment pattern 502 may include a plurality of first marks 502a arranged along the moving direction P of the substrate 500, and the second alignment pattern 503 may include a plurality of second marks 503a arranged along the moving direction P of the substrate 500. Each of the plurality of first marks 502a and the plurality of second marks 503a may have a shape of a cross, for example. The distances between two immediately adjacent ones (e.g., closest ones) of the plurality of first marks 502a may be the same, and the distances between two immediately adjacent ones of the plurality of second marks 503a may also be the same. Additionally and/or alternatively, the distances between two immediately adjacent ones of the plurality of first marks 502a may be equal to those between two immediately adjacent ones of the plurality of second marks 503a.
The first and second alignment marks 152 and 153 may be located at or near respective ends (e.g., ends in a longitudinal or lengthwise direction) of the patterning slit sheet 150. The first and second alignment marks 152 and 153 may be positioned apart from each other in a direction (a second direction) perpendicular to the moving direction P. Each of the first and second alignment marks 152 and 153 may have a circular shape. However, the present invention is not limited thereto, and each of the first and second alignment marks 152 and 153 may have a polygonal shape or any other suitable shape. For example, if each of the first and second alignment marks 152 and 153 has a right-angled triangle (e.g., right triangle) shape, then oblique sides of the first and second alignment marks 152 and 153 may face the patterning slits 151.
When the substrate 500 and the patterning slit sheet 150 are appropriately aligned with each other, then the first and second alignment marks 152 and 153 are located between the first and second alignment patterns 502 and 503. This will be described later.
The first and second camera assemblies 161 and 162 may be located on or above the substrate 500 to respectively correspond to the first and second alignment marks 152 and 153. The first camera assembly 161 may photograph the first alignment pattern 502 and the first alignment mark 152 on the substrate 500, and the second camera assembly 162 may photograph the second alignment pattern 503 and the second alignment mark 153 on the substrate 500. Since the substrate 500 is transparent, the first and second camera assemblies 161 and 162 may respectively photograph the first and second alignment marks 152 and 153, viewed from the substrate 500. The first and second camera assemblies 161 and 162 are aligned in the second direction perpendicular to the moving direction P.
The controller 170 may determine a degree to which the substrate 500 and the patterning slit sheet 150 are aligned to each other by analyzing information captured by the first and second camera assemblies 161 and 162, and may control a driver (not shown) to move the substrate 500 or the patterning slit sheet 150, based on the degree of alignment.
Alignment of the substrate 500 with the patterning slit sheet 150 illustrated in
Referring to
The first and second alignment marks 152 and 153 located on the patterning slit sheet 150 may be spaced apart from each other in the second direction, and may be located between the first and second alignment patterns 502 and 503.
Referring to
Referring to
If the substrate 500 is moved in the X-axis direction, the controller 170 controls a driver (not shown) to move the substrate 500 by a distance (B′−B)/2 in the X-axis direction.
Referring to
Referring to
As described above, the organic layer deposition apparatus 100 of
Specifically, a patterning slit sheet 150′ of the organic layer deposition apparatus 100a may further include the third alignment mark 152′ and the fourth alignment mark 153′. The third alignment mark 152′ may be spaced apart from a first alignment mark 152 and the fourth alignment mark 153′ may be spaced apart from a second alignment mark 153, in a first direction (Y-axis direction). A distance between the first and third alignment marks 152 and 152′ may be equal to that between the second and fourth alignment marks 153 and 153′. The first and second alignment marks 152 and 153 are spaced apart from each other in a second direction (X-axis direction), and the third and fourth alignment marks 152′ and 153′ are also spaced apart from each other in the second direction (X-axis direction). A distance between the first and second alignment marks 152 and 153 may be equal to a distance between the third and fourth alignment marks 152′ and 153′.
The first to fourth camera assemblies 161, 162, 161′, and 162′ may be located on a substrate 500 to respectively correspond to the first to fourth alignment marks 152, 153, 152′, and 153′. Shooting speeds of the third and fourth camera assemblies 161′ and 162′ may be synchronized with a moving speed of the substrate 500. Thus, images of the first alignment pattern 502 captured by the third camera assembly 161′ may have the same (or substantially the same) shape and size, and images of the second alignment pattern 503 captured by the fourth camera assembly 162′ may have the same (or substantially the same) shape and size.
In the current embodiment, the plurality of deposition source nozzles 121′ formed on the deposition source nozzle unit 120 are tilted at an angle (e.g., a predetermined angle), unlike the organic layer deposition apparatus 100 of
In the current embodiment of the present invention, the deposition source nozzles 121a′ and 121b′ are arranged to tilt at an angle (e.g., a predetermined angle) to each other. The deposition source nozzles 121a′ in a first row and the deposition source nozzles 121b′ in a second row may tilt to face each other. That is, the deposition source nozzles 121a′ of the first row in a left part of the deposition source nozzle unit 120 may tilt to face a right side portion of the patterning slit sheet 150, and the deposition source nozzles 121b′ of the second row in a right part of the deposition source nozzle unit 121 may tilt to face a left side portion of the patterning slit sheet 150.
Due to the structure of the organic layer deposition apparatus 100′ according to the current embodiment, the deposition of the deposition material 115 may be adjusted to lessen a thickness variation between the center and the end portions of an organic layer on the substrate 500 and improve thickness uniformity of the organic layer. Moreover, utilization efficiency of the deposition material 115 may also be improved.
In particular, the organic layer deposition apparatus according to the current embodiment includes the first organic layer deposition apparatus 100, the second organic layer deposition apparatus 200, and the third organic layer deposition apparatus 300. The first to third organic layer deposition apparatuses 100 to 300 have substantially the same structure as the organic layer deposition apparatus 100 described with reference to
Deposition sources of the first to third organic layer deposition apparatuses 100 to 300 may contain different deposition materials, respectively. For example, the first organic layer deposition apparatus 100 may contain a deposition material for forming the red (R) emission layer, the second organic layer deposition apparatus 200 may contain a deposition material for forming the green (G) emission layer, and the third organic layer deposition apparatus 300 may contain a deposition material for forming the blue (B) emission layer.
In other words, in a conventional method of manufacturing an organic light-emitting display device, a separate chamber and mask are used to form each color emission layer. However, when the organic layer deposition apparatus according to the current embodiment is used, the R emission layer, the G emission layer, and the B emission layer may be formed at the same time with a single multi-deposition source unit. Thus, a time needed to manufacture an organic light-emitting display device is reduced (e.g., sharply reduced). In addition, the organic light emitting display device may be manufactured with a reduced number of chambers, so that equipment costs may also be reduced (e.g., markedly reduced).
Although not illustrated, a patterning slit sheet of the first organic layer deposition apparatus 100, a patterning slit sheet of the second organic layer deposition apparatus 200, and a patterning slit sheet of the third organic layer deposition apparatus 300 may be arranged to be offset by a constant distance with respect to each other, in order for deposition regions corresponding to the patterning slit sheets not to overlap on a substrate 500. In other words, if the first organic layer deposition apparatus 100, the second organic layer deposition apparatus 200, and the third organic layer deposition apparatus 300 are used to deposit the R emission layer, the G emission layer, and the B emission layer, respectively, then patterning slits of the first organic layer deposition apparatus 100, patterning slits of the second organic layer deposition apparatus 200, and patterning slits of the third organic layer deposition apparatus 300 are arranged not to be aligned with respect to each other, thereby respectively forming the R emission layer, the G emission layer, and the B emission layer in different regions of the substrate 500.
In addition, the deposition materials used to form the R emission layer, the G emission layer, and the B emission layer may have different deposition temperatures. Therefore, the temperatures of the deposition sources of the respective first, second, and third organic layer deposition apparatuses 100, 200, and 300 may be set to be different.
Although
As described above, a plurality of organic layers may be formed concurrently (e.g., at the same time) with a plurality of organic layer deposition apparatuses, and thus manufacturing yield and deposition efficiency may be improved. In addition, the overall manufacturing process may be simplified, and the manufacturing costs may be reduced.
Referring to
Although not illustrated in
In the chamber, a substrate 500 that is a deposition target substrate is transferred by an electrostatic chuck 600. The substrate 500 may be a substrate for flat panel displays. A large substrate, such as a mother glass, for manufacturing a plurality of flat panel displays, may be used as the substrate 500. Other substrates may also be employed.
In an embodiment of the present invention, the substrate 500 may be moved relative to the organic layer deposition apparatus 100″. For example, the substrate 500 may be moved in a direction of an arrow P, relative to the organic layer deposition apparatus 100″.
Similar to the previous embodiment described above with reference to
As described above, since the patterning slit sheet 150 may be formed to be smaller (e.g., significantly smaller) than an FMM used in the conventional deposition method, it is relatively easy to manufacture the patterning slit sheet 150 used in embodiments of the present invention. In other words, using the patterning slit sheet 150, which is smaller than an FMM used in the conventional deposition method, is more convenient in all processes, including etching and other subsequent processes, such as precise extension, welding, moving, and cleaning processes, compared to the conventional deposition method using the larger FMM. This may be more advantageous for a relatively large display device.
The deposition source 110″ that contains and heats a deposition material 115 is located at an opposite side of the chamber to a side at which the substrate 500 is located.
The deposition source 110″ includes a crucible 112 filled with the deposition material 115, and a cooling block 112 surrounding the crucible 112. The cooling block 111 prevents or reduces radiation of heat from the crucible 112 outside, for example, into the chamber. The cooling block 111 may include a heater (not shown) that heats the crucible 112.
The deposition source nozzle unit 120″ is located at a side of the deposition source 110″, and in particular, at the side of the deposition source 110″ facing the substrate 500. The deposition source nozzle unit 120″ includes a plurality of deposition source nozzles 121″ that may be arranged at equal intervals along the X-axis direction. The deposition material 115 that is vaporized in the deposition source 110″ passes through the deposition source nozzles 121″ of the deposition source nozzle unit 120″ towards the substrate 500 that is a deposition target.
The barrier plate assembly 130 is located at a side of the deposition source nozzle unit 120″. The barrier plate assembly 130 includes a plurality of barrier plates 131, and a barrier plate frame 132 that covers sides of the barrier plates 132. The plurality of barrier plates 131 may be arranged parallel to each other at equal intervals along the X-axis direction. In addition, each of the barrier plates 131 may be arranged parallel to an YZ plane in
The barrier plates 131 may be respectively located between adjacent deposition source nozzles 121″. In other words, each of the deposition source nozzles 121″ may be located between two adjacent barrier plates 131. Each of the deposition source nozzles 121″ may be located at the midpoint between two adjacent barrier plates 131. However, the present invention is not limited to this structure. For example, a plurality of deposition source nozzles 121″ may be located between two adjacent barrier plates 131. In this case, the plurality of deposition source nozzles 121″ may also be respectively located at the midpoint between two adjacent barrier plates 131.
As described above, since the barrier plates 131 partition the space between the deposition source nozzle unit 120″ and the patterning slit sheet 150 into the plurality of sub-deposition spaces S, the deposition material 115 discharged through each of the deposition source nozzles 121″ is not mixed with the deposition material 115 discharged through the other deposition source nozzles 121″, and passes through patterning slits 151 of the patterning slit sheet 150 so as to be deposited on the substrate 500. In other words, the barrier plates 131 guide the deposition material 115, which is discharged through the deposition source nozzles 121″, to move straight, i.e., to flow in the Z-axis direction.
As described above, the deposition material 115 is forced to move straight by installing the barrier plates 131, so that a smaller shadow zone may be formed on the substrate 500 compared to a case where no barrier plates are installed. Thus, the organic layer deposition apparatus 100″ and the substrate 500 may be separated from each other by a distance (e.g., predetermined distance). This will be described later in detail.
The barrier plate frame 132, which covers sides of the barrier plates 131, maintains the positions of the barrier plates 131, and guides the deposition material 115, which is discharged through the deposition source nozzles 121″, not to flow in the Y-axis direction.
The deposition source nozzle unit 120″ and the barrier plate assembly 130 may be spaced apart from each other by a distance (e.g., a predetermined distance). This may prevent heat radiated from the deposition source unit 110″ from being conducted to the barrier plate assembly 130. However, aspects of the present invention are not limited to this. For example, when an appropriate heat insulator (not shown) is positioned between the deposition source nozzle unit 120″ and the barrier plate assembly 130, the deposition source nozzle unit 120″ and the barrier plate assembly 130 may be bound together with the heat insulator therebetween.
In addition, the barrier plate assembly 130 may be constructed to be detachable from the organic layer deposition apparatus 100″. In the organic layer deposition apparatus 100″ according to the current embodiment, the deposition space is enclosed by using the barrier plate assembly 130, so that the deposition material 115 that remains undeposited is mostly located within the barrier plate assembly 130. Thus, since the barrier plate assembly 130 is constructed to be detachable from the organic layer deposition apparatus 100″, when a large amount of the deposition material 115 lies in the barrier plate assembly 130 after a long deposition process, the barrier plate assembly 130 may be detached from the organic layer deposition apparatus 100″ and then placed in a separate deposition material recycling apparatus in order to recover the deposition material 115. Due to the structure of the organic layer deposition apparatus 100″ according to the present embodiment, a reuse rate of the deposition material 115 may be increased, so that the deposition efficiency may be improved, and thus the manufacturing costs may be reduced.
The patterning slit sheet 150 and a frame 155 are disposed between the deposition source 110″ and the substrate 500. The shape of the frame 155 may be similar to a window frame. The patterning slit sheet 150 is bound inside the frame 155.
The patterning slit sheet 150 has the plurality of patterning slits 151 arranged in the X-axis direction. The patterning slits 151 extend in the Y-axis direction. The deposition material 115 that has been vaporized in the deposition source 110″ and passed through the deposition source nozzle 121″, passes through the patterning slits 151 towards the substrate 500.
The patterning slit sheet 150 may be formed of a metal thin film. The patterning slit sheet 150 is fixed to the frame 155 such that a tensile force is exerted thereon. In other words, the frame 150 may be pulled (e.g., stretched) in one or both opposite directions by the frame 155. The patterning slits 150 may be formed by etching the patterning slit sheet 150 to a stripe pattern.
In the organic layer deposition apparatus 100″ according to the current embodiment, the total number of patterning slits 151 may be greater than the total number of deposition source nozzles 121″. In addition, there may be a greater number of patterning slits 151 located between two adjacent barrier plates 131 than deposition source nozzles 121″ located between two adjacent barrier plates 131. The number of patterning slits 151 may be equal to the number of deposition patterns to be formed on the substrate 500.
The barrier plate assembly 130 and the patterning slit sheet 150 may be spaced apart from each other by a distance (e.g., a predetermined distance), and may be connected by second connection members 133. The temperature of the barrier plate assembly 130 may increase to 100° C. or higher due to the deposition source 110″ whose temperature is high. Thus, in order to prevent the heat of the barrier plate assembly 130 from being conducted to the patterning slit sheet 150, the barrier plate assembly 130 and the patterning slit sheet 150 are separated from each other by a distance (e.g., a predetermined distance).
As described above, the organic layer deposition apparatus 100″ according to the current embodiment performs deposition while being moved relative to the substrate 500. In order to move the organic layer deposition apparatus 100″ relative to the substrate 500, the patterning slit sheet 150 is spaced apart from the substrate 500 by a distance (e.g., a predetermined distance). In addition, in order to prevent the formation of a relatively large shadow zone on the substrate 500 when the patterning slit sheet 150 and the substrate 500 are spaced apart from each other, the barrier plates 131 are arranged between the deposition source nozzle unit 120″ and the patterning slit sheet 150 to force the deposition material 115 to move in a straight direction. Thus, the size of the shadow zone that may be formed on the substrate 500 is reduced (e.g., sharply reduced).
In a typical deposition method using an FMM, deposition is performed with the FMM in close contact with a substrate in order to reduce or prevent formation of a shadow zone on the substrate. However, when the FMM is used in close contact with the substrate, the contact may cause defects, such as scratches on patterns formed on the substrate. In addition, in the typical deposition method, the size of the mask is the same as the size of the substrate since the mask cannot be moved relative to the substrate. Thus, the size of the mask becomes increased as display devices become larger. However, it is not easy to manufacture such a large mask.
In order to overcome this problem, in the organic layer deposition apparatus 100″ according to the current embodiment, the patterning slit sheet 150 is spaced apart from the substrate 500 by a distance (e.g., a predetermined distance). This may be facilitated by installing the barrier plates 131 to reduce the size of the shadow zone formed on the substrate 500.
As described above, when the patterning slit sheet 150 is manufactured to be smaller than the substrate 500, the patterning slit sheet 150 may be moved relative to the substrate 500 during deposition. Thus, it is no longer necessary to manufacture a large FMM as used in the conventional deposition method. In addition, since the substrate 500 and the patterning slit sheet 150 are separated from each other, defects caused due to contact therebetween may be prevented. In addition, since it is unnecessary to contact the substrate 500 with the patterning slit sheet 150 during a deposition process, the manufacturing speed may be improved.
Referring to
Although not illustrated in
The substrate 500 which is a deposition target substrate is located in the chamber. The deposition source 110″ that contains and heats the deposition material 115 is located at an opposite side of the chamber to a side at which the substrate 500 is located.
Structures of the deposition source 110″ and the patterning slit sheet 150 are substantially the same as those in the embodiment described with reference to
In the current embodiment, the second barrier plate assembly 140 is located at a side of the first barrier plate assembly 130. The second barrier plate assembly 140 includes a plurality of second barrier plates 141, and a second barrier plate frame 141 that covers sides of the second barrier plates 142.
The plurality of second barrier plates 141 may be arranged parallel to each other at equal intervals along the X-axis direction. In addition, each of the second barrier plates 141 may be formed to extend in the YZ plane in
The plurality of first barrier plates 131 and the plurality of second barrier plates 141 arranged as described above, partition a deposition space between the deposition source nozzle unit 120″ and the patterning slit sheet 150. The deposition space is divided by the first barrier plates 131 and the second barrier plates 141 into sub-deposition spaces that respectively correspond to the deposition source nozzles 121″ through which the deposition material 115 is discharged.
The second barrier plates 141 may be positioned to correspond respectively to the first barrier plates 131. In other words, the second barrier plates 141 may be aligned with the first barrier plates 131, respectively. Each pair of the corresponding first and second barrier plates 131 and 141 may be located on the same plane. Although the first barrier plates 131 and the second barrier plates 141 are respectively illustrated as having the same width in the X-axis direction, aspects of the present invention are not limited thereto. In other words, the second barrier plates 141, which should be accurately aligned with the patterning slits 151, may be formed to be relatively thin, whereas the first barrier plates 131, which may not need to be precisely aligned with the patterning slits 151, may be formed to be relatively thick. This makes it easier to manufacture the organic layer deposition apparatus 100′″.
As illustrated in
Referring to
A thin-film transistor (TFT) 40, a capacitor 50, and an organic light-emitting diode (OLED) 60 are disposed on the insulating layer 31, as illustrated in
A semiconductor active layer 41 is formed on an upper surface of the insulating layer 31 (e.g., formed in a predetermined pattern). A gate insulating layer 32 is formed to cover the semiconductor active layer 41. The semiconductor active layer 41 may include a p-type or n-type semiconductor material.
A first capacitor electrode 51 of the capacitor 50, and a gate electrode 42 of the TFT 40 are formed on upper portions of the gate insulating layer 32 corresponding to the semiconductor active layer 41. An interlayer insulating layer 33 is formed to cover the first capacitor electrode 51 and the gate electrode 42. Then, the interlayer insulating layer 33 and the gate insulating layer 32 are etched by, for example, dry etching, to form a contact hole exposing parts of the semiconductor active layer 41.
Then, a second capacitor electrode 52 and a source/drain electrode 43 are formed on the interlayer insulating layer 33. The source/drain electrode 43 contacts the semiconductor active layer 41 through the contact hole. A passivation layer 34 is formed to cover the second capacitor 52 and the source/drain electrode 43, and is etched to expose a part of the drain electrode 43. An insulating layer (not shown) may be further formed on the passivation layer 34 so as to planarize the passivation layer 34.
In addition, the OLED 60 displays image information (e.g., predetermined image information) by emitting red, green, or blue light as current flows therethrough. The OLED 60 includes a first electrode 61 located on the passivation layer 34. The first electrode 61 is electrically connected to the drain electrode 43 of the TFT 40.
A pixel defining layer 35 is formed to cover the first electrode 61. An opening 64 is formed in the pixel defining layer 35, and an organic emission layer 63 is formed in a region defined by the opening 64. A second electrode 62 is formed on the organic emission layer 63.
The pixel defining layer 35, which defines individual pixels, is formed of an organic material. The pixel defining layer 35 also planarizes the surface of a region of the substrate 30 in which the first electrode 61 is formed, and in particular, the surface of the passivation layer 34.
The first electrode 61 and the second electrode 62 are insulated from each other, and respectively apply voltages of opposite polarities to the organic emission layer 63 to induce light emission.
The organic emission layer 63 may be formed of a low-molecular weight organic material or a high-molecular weight organic material. When a low-molecular weight organic material is used, the organic emission layer 63 may have a single or multi-layer structure including at least one selected from the group consisting of a hole injection layer (HIL), a hole transport layer (HTL), an emission layer (EML), an electron transport layer (ETL), and an electron injection layer (EIL). Examples of available organic materials may include copper phthalocyanine (CuPc), N,N′-di(naphthalene-1-yl)-N,N′-diphenyl-benzidine (NPB), tris-8-hydroxyquinoline aluminum (Alq3), and the like. Such a low-molecular weight organic material may be deposited using vacuum deposition by using an organic layer deposition apparatus, such as those illustrated in
After the organic emission layer 63 is formed, the second electrode 62 may be formed by the same deposition method as used to form the organic emission layer 63.
The first electrode 61 may function as an anode and the second electrode 62 may function as a cathode, or vice versa. The first electrode 61 may be patterned to correspond to individual pixel regions, and the second electrode 62 may be formed to cover all the pixels.
The first electrode 61 may be formed as a transparent electrode or a reflective electrode. Such a transparent electrode may be formed of indium tin oxide (ITO), indium zinc oxide (IZO), zinc oxide (ZnO), or indium oxide (In2O3). Such a reflective electrode may be formed by forming a reflective layer from silver (Ag), magnesium (Mg), aluminum (Al), platinum (Pt), palladium (Pd), gold (Au), nickel (Ni), neodymium (Nd), iridium (Ir), chromium (Cr) or a compound thereof, and forming a layer of ITO, IZO, ZnO, or In2O3on the reflective layer. The first electrode 61 may be formed by forming a layer by, for example, sputtering, and then patterning the layer by, for example, photolithography.
The second electrode 62 may also be formed as a transparent electrode or a reflective electrode. When the second electrode 62 is formed as a transparent electrode, the second electrode 62 functions as a cathode. To this end, such a transparent electrode may be formed by depositing a metal having a low work function, such as lithium (Li), calcium (Ca), lithium fluoride/calcium (LiF/Ca), lithium fluoride/aluminum (LiF/Al), aluminum (Al), silver (Ag), magnesium (Mg), or a compound thereof on a surface of the intermediate layer 63 and forming an auxiliary electrode layer or a bus electrode line thereon from ITO, IZO, ZnO, In2O3, or the like. When the second electrode 62 is formed as a reflective electrode, a reflective electrode may be formed by depositing Li, Ca, LiF/Ca, LiF/Al, Al, Ag, Mg, or a compound thereof on the entire surface of the organic emission layer 63. The second electrode 62 may be formed by using the same deposition method as used to form the organic emission layer 63 described above.
The organic layer deposition apparatuses according to the embodiments of the present invention described above may be applied to form an organic layer or an inorganic layer of an organic TFT, and to form layers from various materials.
As described above, the organic layer deposition apparatus according to aspects of the present invention may be easily manufactured and may be simply applied to the manufacture of large-sized display devices on a mass scale. The organic layer deposition apparatus may improve manufacturing yield and deposition efficiency, may allow a deposition material to be reused, and may allow a substrate and the organic layer deposition apparatus to be precisely aligned with each other.
While the present invention has been particularly shown and described with reference to exemplary embodiments thereof, it will be understood by those of ordinary skill in the art that various changes in form and details may be made therein without departing from the spirit and scope of the present invention as defined by the following claims and their equivalents.
Number | Date | Country | Kind |
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10-2011-0066125 | Jul 2011 | KR | national |
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1476279 | Feb 2004 | CN |
1489419 | Apr 2004 | CN |
1500904 | Jun 2004 | CN |
1556872 | Dec 2004 | CN |
1607868 | Apr 2005 | CN |
1682569 | Oct 2005 | CN |
1704501 | Dec 2005 | CN |
1814854 | Aug 2006 | CN |
1841696 | Oct 2006 | CN |
1 413 644 | Apr 2004 | EP |
1 418 250 | May 2004 | EP |
1 518 940 | Mar 2005 | EP |
2354270 | Aug 2011 | EP |
57-194252 | Nov 1982 | JP |
2-247372 | Oct 1990 | JP |
04-272170 | Sep 1992 | JP |
5-22405 | Mar 1993 | JP |
5-98425 | Apr 1993 | JP |
5-230628 | Sep 1993 | JP |
08-027568 | Jan 1996 | JP |
9-95776 | Apr 1997 | JP |
10-50478 | Feb 1998 | JP |
10-120171 | May 1998 | JP |
10-270535 | Oct 1998 | JP |
11-144865 | May 1999 | JP |
2000-068054 | Mar 2000 | JP |
2000-282219 | Oct 2000 | JP |
2000-323277 | Nov 2000 | JP |
2001-28325 | Jan 2001 | JP |
2001-052862 | Feb 2001 | JP |
2001-093667 | Apr 2001 | JP |
2002-75638 | Mar 2002 | JP |
2002-175878 | Jun 2002 | JP |
2002-348659 | Dec 2002 | JP |
2003-003250 | Jan 2003 | JP |
2003-077662 | Mar 2003 | JP |
2003-157973 | May 2003 | JP |
2003-197531 | Jul 2003 | JP |
2003-297562 | Oct 2003 | JP |
2003-321767 | Nov 2003 | JP |
2003-347394 | Dec 2003 | JP |
2004-035964 | Feb 2004 | JP |
2004-043898 | Feb 2004 | JP |
2004-76150 | Mar 2004 | JP |
2004-91858 | Mar 2004 | JP |
2004-103269 | Apr 2004 | JP |
2004-103341 | Apr 2004 | JP |
2004-107764 | Apr 2004 | JP |
2004-137583 | May 2004 | JP |
2004-143521 | May 2004 | JP |
2004-169169 | Jun 2004 | JP |
2004-199919 | Jul 2004 | JP |
2004-225058 | Aug 2004 | JP |
2004-342455 | Dec 2004 | JP |
2004-349101 | Dec 2004 | JP |
2004-355975 | Dec 2004 | JP |
2005-044592 | Feb 2005 | JP |
2005-101505 | Apr 2005 | JP |
2005-122980 | May 2005 | JP |
2005-163099 | Jun 2005 | JP |
2005-165015 | Jun 2005 | JP |
2005-174843 | Jun 2005 | JP |
2005-206939 | Aug 2005 | JP |
2005-213616 | Aug 2005 | JP |
2005-235568 | Sep 2005 | JP |
2005-293968 | Oct 2005 | JP |
2005-296737 | Oct 2005 | JP |
3705237 | Oct 2005 | JP |
2006-028583 | Feb 2006 | JP |
2006-172930 | Jun 2006 | JP |
2006-176809 | Jul 2006 | JP |
2006-210038 | Aug 2006 | JP |
2006-219760 | Aug 2006 | JP |
2006-275433 | Oct 2006 | JP |
2006-292955 | Oct 2006 | JP |
2006-307247 | Nov 2006 | JP |
2007-047293 | Feb 2007 | JP |
2007-66862 | Mar 2007 | JP |
2007-146219 | Jun 2007 | JP |
2007-157886 | Jun 2007 | JP |
2007-186740 | Jul 2007 | JP |
2007-242436 | Sep 2007 | JP |
2007-291506 | Nov 2007 | JP |
2008-19477 | Jan 2008 | JP |
2008-108628 | May 2008 | JP |
2008-121098 | May 2008 | JP |
2008-521165 | Jun 2008 | JP |
2008-156686 | Jul 2008 | JP |
2008-196003 | Aug 2008 | JP |
2008-248301 | Oct 2008 | JP |
2008-274373 | Nov 2008 | JP |
2008-300056 | Dec 2008 | JP |
2009-019243 | Jan 2009 | JP |
2009-024208 | Feb 2009 | JP |
2009-049223 | Mar 2009 | JP |
2009-081165 | Apr 2009 | JP |
2009-087910 | Apr 2009 | JP |
2009-117231 | May 2009 | JP |
2010-159167 | Jul 2010 | JP |
2010-261081 | Nov 2010 | JP |
2011-47035 | Mar 2011 | JP |
WO 2011034011 | Mar 2011 | JP |
2011-146377 | Jul 2011 | JP |
2012-92448 | May 2012 | JP |
2012-211352 | Nov 2012 | JP |
1997-0008709 | Feb 1997 | KR |
10-0257219 | Feb 2000 | KR |
10-2000-0019254 | Apr 2000 | KR |
10-2000-0023929 | May 2000 | KR |
10-1997005430 | May 2000 | KR |
2001-0024652 | Mar 2001 | KR |
2001-0030175 | Apr 2001 | KR |
10-2001-0039298 | May 2001 | KR |
10-2001-0059939 | Jul 2001 | KR |
10-2001-0092914 | Oct 2001 | KR |
10-2001-0093666 | Oct 2001 | KR |
20-0257218 | Dec 2001 | KR |
10-2002-0000201 | Jan 2002 | KR |
2002-0001555 | Jan 2002 | KR |
2002-0025760 | Apr 2002 | KR |
10-2002-0050922 | Jun 2002 | KR |
10-2002-0090934 | Dec 2002 | KR |
10-2002-0091457 | Dec 2002 | KR |
2003-0001745 | Jan 2003 | KR |
10-2003-0034730 | May 2003 | KR |
10-2003-0043012 | Jun 2003 | KR |
2003-0046090 | Jun 2003 | KR |
2003-0069684 | Aug 2003 | KR |
10-0405080 | Nov 2003 | KR |
10-0406059 | Nov 2003 | KR |
10-2003-0091947 | Dec 2003 | KR |
10-2003-0093959 | Dec 2003 | KR |
2003-0094033 | Dec 2003 | KR |
10-2004-0014258 | Feb 2004 | KR |
20-0342433 | Feb 2004 | KR |
10-2004-0034537 | Apr 2004 | KR |
10-2004-0039910 | May 2004 | KR |
10-0430336 | May 2004 | KR |
2004-0050045 | Jun 2004 | KR |
2004-0069281 | Aug 2004 | KR |
10-2004-0084747 | Oct 2004 | KR |
10-2004-0087142 | Oct 2004 | KR |
10-2004-0110718 | Dec 2004 | KR |
10-0463212 | Dec 2004 | KR |
10-2005-0018234 | Feb 2005 | KR |
10-2005-0024324 | Mar 2005 | KR |
10-2005-0028943 | Mar 2005 | KR |
10-2005-0039140 | Apr 2005 | KR |
10-0483487 | Apr 2005 | KR |
10-2005-0062853 | Jun 2005 | KR |
10-2005-0082644 | Aug 2005 | KR |
10-0520159 | Oct 2005 | KR |
10-0532657 | Dec 2005 | KR |
10-2006-0008602 | Jan 2006 | KR |
10-2006-0018745 | Mar 2006 | KR |
10-2006-0020050 | Mar 2006 | KR |
10-2006-0045225 | May 2006 | KR |
10-2006-0049050 | May 2006 | KR |
10-2006-0051746 | May 2006 | KR |
10-2006-0053926 | May 2006 | KR |
10-2006-0056706 | May 2006 | KR |
10-2006-0058459 | May 2006 | KR |
10-2006-0059068 | Jun 2006 | KR |
10-2006-0059323 | Jun 2006 | KR |
10-2006-0060994 | Jun 2006 | KR |
10-2006-0065978 | Jun 2006 | KR |
10-2006-0073367 | Jun 2006 | KR |
10-2006-0077887 | Jul 2006 | KR |
10-2006-0080475 | Jul 2006 | KR |
10-2006-0080481 | Jul 2006 | KR |
10-2006-0080482 | Jul 2006 | KR |
10-2006-0081943 | Jul 2006 | KR |
10-2006-0083510 | Jul 2006 | KR |
10-2006-0092387 | Aug 2006 | KR |
10-2006-0098755 | Sep 2006 | KR |
10-2006-0104288 | Oct 2006 | KR |
10-2006-0104675 | Oct 2006 | KR |
10-2006-0104677 | Oct 2006 | KR |
10-2006-0109561 | Oct 2006 | KR |
10-2006-0109627 | Oct 2006 | KR |
10-0635903 | Oct 2006 | KR |
10-2006-0114462 | Nov 2006 | KR |
10-2006-0114477 | Nov 2006 | KR |
10-2006-0114573 | Nov 2006 | KR |
10-0645719 | Nov 2006 | KR |
10-0646160 | Nov 2006 | KR |
10-2006-0123944 | Dec 2006 | KR |
10-0687007 | Feb 2007 | KR |
10-2007-0025164 | Mar 2007 | KR |
10-0696547 | Mar 2007 | KR |
10-0696550 | Mar 2007 | KR |
10-0697663 | Mar 2007 | KR |
10-0698033 | Mar 2007 | KR |
10-0700466 | Mar 2007 | KR |
10-2007-0035796 | Apr 2007 | KR |
10-2007-0037848 | Apr 2007 | KR |
10-0711885 | Apr 2007 | KR |
10-2007-0050793 | May 2007 | KR |
10-0723627 | May 2007 | KR |
10-2007-0056190 | Jun 2007 | KR |
10-0726132 | Jun 2007 | KR |
10-0736218 | Jul 2007 | KR |
10-0739309 | Jul 2007 | KR |
10-0741142 | Jul 2007 | KR |
10-2007-0078713 | Aug 2007 | KR |
10-2007-0080635 | Aug 2007 | KR |
10-2007-0091437 | Sep 2007 | KR |
10-2006-0028115 | Oct 2007 | KR |
10-2007-0097218 | Oct 2007 | KR |
10-2007-0098122 | Oct 2007 | KR |
10-2007-0101842 | Oct 2007 | KR |
10-2007-0105595 | Oct 2007 | KR |
10-0768212 | Oct 2007 | KR |
10-0770653 | Oct 2007 | KR |
10-2007-0112668 | Nov 2007 | KR |
10-2007-0114094 | Nov 2007 | KR |
10-0787457 | Dec 2007 | KR |
10-2008-0001184 | Jan 2008 | KR |
10-2008-0003720 | Jan 2008 | KR |
10-2008-0007896 | Jan 2008 | KR |
10-2008-0009285 | Jan 2008 | KR |
10-0797787 | Jan 2008 | KR |
10-0800125 | Jan 2008 | KR |
10-0815265 | Mar 2008 | KR |
10-2008-0036983 | Apr 2008 | KR |
10-0823508 | Apr 2008 | KR |
10-0823511 | Apr 2008 | KR |
10-2008-0044239 | May 2008 | KR |
10-2008-0044775 | May 2008 | KR |
10-2008-0046761 | May 2008 | KR |
10-0827760 | May 2008 | KR |
10-2008-0048653 | Jun 2008 | KR |
10-2008-0055124 | Jun 2008 | KR |
10-2008-0057159 | Jun 2008 | KR |
10-0839380 | Jun 2008 | KR |
10-2008-0060400 | Jul 2008 | KR |
10-2008-0061132 | Jul 2008 | KR |
10-2008-0061666 | Jul 2008 | KR |
10-2008-0061774 | Jul 2008 | KR |
10-2008-0062212 | Jul 2008 | KR |
10-2008-0076574 | Aug 2008 | KR |
10-2008-0088737 | Oct 2008 | KR |
10-2008-0104479 | Dec 2008 | KR |
10-2008-0104695 | Dec 2008 | KR |
10-2008-0109559 | Dec 2008 | KR |
10-2009-0017910 | Feb 2009 | KR |
10-0889872 | Mar 2009 | KR |
10-2009-0038733 | Apr 2009 | KR |
10-2009-0040618 | Apr 2009 | KR |
10-2009-0047953 | May 2009 | KR |
10-2009-0052155 | May 2009 | KR |
10-2009-0052828 | May 2009 | KR |
10-2009-0053417 | May 2009 | KR |
10-0899279 | May 2009 | KR |
10-2009-0066996 | Jun 2009 | KR |
10-2009-0075887 | Jul 2009 | KR |
10-2009-0079765 | Jul 2009 | KR |
10-2009-0081717 | Jul 2009 | KR |
10-0908232 | Jul 2009 | KR |
10-2009-0093161 | Sep 2009 | KR |
10-2009-0094911 | Sep 2009 | KR |
10-2009-0097453 | Sep 2009 | KR |
10-2009-0107702 | Oct 2009 | KR |
10-0922763 | Oct 2009 | KR |
10-2010-0000128 | Jan 2010 | KR |
10-2010-0000129 | Jan 2010 | KR |
10-2010-0002381 | Jan 2010 | KR |
10-2010-0026655 | Mar 2010 | KR |
10-2010-0038088 | Apr 2010 | KR |
10-2010-0044606 | Apr 2010 | KR |
10-2010-0047796 | May 2010 | KR |
10-0961110 | Jun 2010 | KR |
10-2010-0090070 | Aug 2010 | KR |
10-2010-0099806 | Sep 2010 | KR |
10-2010-0119368 | Nov 2010 | KR |
10-2010-0126125 | Dec 2010 | KR |
10-2010-0128589 | Dec 2010 | KR |
10-2010-0130786 | Dec 2010 | KR |
10-2010-0133678 | Dec 2010 | KR |
10-2010-0138139 | Dec 2010 | KR |
10-1017654 | Feb 2011 | KR |
10-2011-0021090 | Mar 2011 | KR |
10-2011-0022512 | Mar 2011 | KR |
10-2011-0032589 | Mar 2011 | KR |
10-2011-0082418 | Jul 2011 | KR |
10-2011-0101767 | Sep 2011 | KR |
10-2011-0110525 | Oct 2011 | KR |
10-2011-0120213 | Nov 2011 | KR |
10-2011-0138787 | Dec 2011 | KR |
10-2012-0006322 | Jan 2012 | KR |
10-2012-0006324 | Jan 2012 | KR |
10-2012-0012300 | Feb 2012 | KR |
10-2012-0042155 | May 2012 | KR |
10-2012-0065789 | Jun 2012 | KR |
10-2012-0080855 | Jul 2012 | KR |
10-2012-0081811 | Jul 2012 | KR |
10-1193186 | Oct 2012 | KR |
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Number | Date | Country | |
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20130008379 A1 | Jan 2013 | US |