1. Field of the invention
The present invention relates to an organic light emitting diode, and more particularly, relates to a structure of a transparent substrate for an organic light emitting diode. In addition, the present invention relates to a light emitting element formed in combination with an organic light emitting diode.
2. Description of Related Art
When a direct-current voltage is applied between the transparent electrode layer 32 (anode) and the rear electrode layer 34 (cathode), holes injected from the transparent electrode layer 32 and electrons injected from the rear electrode layer 34 are combined in the organic light emitting layer 33 to produce luminescence. Because the rear electrode layer 34 is opaque, light 35 generated in the organic light emitting layer 33 is emitted through the transparent electrode layer 32 and the transparent substrate 31 to the outside (downward).
As another example of an organic light emitting diode, JP 2008-108731 A discloses an organic light emitting diode for displaying still signs and characters. The organic light emitting diode disclosed in JP 2008-108731 A has, not shown, a rear electrode layer formed to have two layers, one of which is intended for sign and character patterns. However, a transparent substrate thereof is not particularly different from the transparent substrate 31 of the organic light emitting diode 30 shown in
The light 35 generated in the organic light emitting layer 33 is not directional, and the light 35 passing through the transparent electrode layer 32 thus travels in various directions inside the transparent substrate 31. The critical angle of light at the boundary between the transparent substrate 31 and the outside (for example, air) is determined by the ratio between the refractive index of the transparent substrate 31 and the refractive index of the outside. Light incident from the inside of the transparent substrate 31 onto the boundary between the transparent substrate 31 and the outside at an angle larger than the critical angle is totally reflected at the boundary between the transparent substrate 31 and the outside.
The light totally reflected at the boundary between the transparent substrate 31 and the outside is then totally reflected at the boundary between the transparent substrate 31 and the transparent electrode layer 32. The light is again totally reflected at the boundary between the transparent substrate 31 and the outside. Of the light 35 generated in the organic light emitting layer 33, the light incident from the inside of the transparent substrate 31 onto the boundary between the transparent substrate 31 and the outside at an angle larger than the critical angle is repeatedly totally reflected as described above, and emitted to the outside from side surfaces 31a, 31b of the transparent substrate 31.
In the organic light emitting diode disclosed in JP 2008-108731 A, the transparent substrate also has the same structure as in the organic light emitting diode 30 shown in
In the conventional organic light emitting diode 30, a portion of the light 35 generated in the organic light emitting layer 33 is repeatedly totally reflected, and emitted to the outside from the side surfaces 31a, 31b of the transparent substrate 31. The conventional organic light emitting diode 30 has a problem of having low light extraction efficiency because it is not possible to use the light emitted to the outside from the side surfaces 31a, 31b of the transparent substrate 31.
The conventional organic light emitting diode 30 is not flexible because a glass substrate is used widely as the transparent substrate 31. Therefore, it is difficult to create a curved light emitting element or a curved display with the use of the conventional organic light emitting diode 30 which is large-sized.
Small-sized conventional organic light emitting diodes 30 can be arranged to create a curved light emitting element or a curved display. However, it is necessary to arrange the organic light emitting diodes 30 in a reticular pattern in order to create a curved light emitting element or a curved display because the conventional organic light emitting diodes 30 typically have a square or nearly square rectangular shape. For this reason, the number of the organic light emitting diodes 30 will be increased, and the wiring will be also complicated. Accordingly, it is not practical to arrange the conventional small-size organic light emitting diodes 30 for creating a curved light emitting element or a curved display.
In the conventional organic light emitting diode 30, a portion of the light 35 generated in the organic light emitting layer 33 is repeatedly totally reflected at the boundary between the transparent substrate 31 and the outside and at the boundary between the transparent substrate 31 and the transparent electrode layer 32, and emitted to the outside from the side surfaces 31a, 31b of the transparent substrate 31. The conventional organic light emitting diodes 30 have the problem of having low light extraction efficiency because it is not possible to use the light 35 emitted to the outside from the side surfaces 31a, 31b of the transparent substrate 31.
The conventional organic light emitting diode 30 generally has a square or nearly square rectangular planar shape. In addition, the conventional organic light emitting diode 30 is not flexible because the transparent substrate 31 is a glass plate. For this reason, it is difficult to create a curved light emitting element or a curved display with the use of the conventional organic light emitting diodes 30.
The summary of the present invention is described as follows:
In a first preferred aspect of the present invention, an organic light emitting diode according to the present invention comprises at least a transparent substrate, a transparent electrode layer, an organic light emitting layer, and a rear electrode layer in this order. The organic light emitting diode according to the present invention has a rectangular planar shape, and the length of a long side of the rectangular shape is 5 or more times as long as the length of a short side thereof (the length of the long side is also simply referred to as a length, whereas the length of the short side is also simply referred to as a width). The length of a side of the transparent substrate on the transparent electrode layer side is shorter than the length of a side thereof on an emission side in a cross section parallel to the short side of the transparent substrate. An end of the side of the transparent substrate on the transparent electrode layer side and an end of the side thereof on the emission side are connected by a straight line or a curved line. An angle formed by the straight line or the curved line and the side on the emission side is larger than 0° and smaller than 90°. The angle herein formed by the curved line and the side on the emission side refers to an angle formed by a tangent line on the curved line at the end of the side on the emission side with the side on the emission side.
In a second preferred aspect of the organic light emitting diode according to the present invention, each end of a side of the transparent substrate on the transparent electrode layer side and each end of a side thereof on the emission side are connected by a straight line in a cross section parallel to the short side of the transparent substrate. Therefore, the cross section parallel to the short side of the transparent substrate has a trapezoidal shape.
In a third preferred aspect of the organic light emitting diode according to the present invention, a cross section parallel to the short side of the transparent substrate has a trapezoidal shape, and the trapezoidal shape has a basic angle of 40° to 50° on the emission side.
In a fourth preferred aspect of the organic light emitting diode according to the present invention, the end of the side of the transparent substrate on the transparent electrode layer side and the end of the side thereof on the emission side are connected by a parabola.
In a fifth preferred aspect of the organic light emitting diode according to the present invention, the end of the side of the transparent substrate on the transparent electrode layer side and the end of the side thereof on the emission side are connected by an arc.
In a sixth preferred aspect of the organic light emitting diode according to the present invention, the transparent substrate comprises a flexible polymer film.
In a seventh preferred aspect, a light emitting element according to the present invention is formed by arranging the organic light emitting diode described above in a reed screen fashion.
The organic light emitting diode according to the present invention controls the path of light, the light being conventionally emitted from the side surfaces of the transparent substrate to the outside and being not available, thereby emitting the light from the front of the transparent substrate. The organic light emitting diodes according to the present invention has a light extraction efficiency higher than conventional efficiencies, because the light emitted from the front of the transparent substrate can be used.
The organic light emitting diode according to the present invention has an elongate rectangular shape. With the use of this shape, the organic light emitting diodes according to the present invention can be arranged parallel in a reed screen fashion to create a large-size curved light emitting element or a curved display (for example, a cylindrical display), even when the transparent substrate is not flexible.
The organic light emitting diodes according to the present invention can use a flexible polymer film for the transparent substrate to create a curved light emitting element or a curved display (for example, a spherical display) which is further free in terms of shape.
a) is a cross-sectional view of an organic light emitting diode of the present invention;
b) is a cross-sectional view of an organic light emitting diode according to the present invention;
c) is a cross-sectional view of an organic light emitting diode of the present invention;
d) is a cross-sectional view of a conventional organic light emitting diode;
The organic light emitting diode 10 of the present invention may have, not shown, other layers placed between the respective layers mentioned above. For example, a hole injection layer and a hole transport layer may be placed between the transparent electrode layer 12 and the organic light emitting layer 13. Alternatively, an electron transport layer and an electron injection layer may be placed between the organic light emitting layer 13 and the rear electrode layer 14.
As shown in
As shown in
As shown in
The material for forming the transparent substrate 11 to be used in the present invention is preferably excellent in transparency, and for example, polyester resins, polyimide resins, polycycloolefin resins, or polycarbonate resins are suitable for the material. The transparent substrate 11 to be used in the present invention preferably has a thickness of 10 μm to 500 μm.
As shown in
In the conventional organic light emitting diode 30 shown in
In an example of the transparent substrate 11 to be used in the present invention as shown in
As shown in
In another example of the transparent substrate 11 to be used in the present invention as shown in
In yet another example of the transparent substrate 11 to be used in the present invention as shown in
While the cross sections of the transparent substrates 11 as shown in
The cross-sectional shapes of the transparent substrates 11 as shown in
As shown in
Also in the transparent substrate 11 shown in
In the transparent substrate 11 used for the organic light emitting diode 10 of the present invention, the length of the side 11a (upper side) on the transparent electrode layer 12 side is shorter than the length of the side 11b (lower side) on the emission side in a cross section parallel to the short side 16. Furthermore, the ends 11c, 11d of the side 11a (upper side) on the transparent electrode layer 12 side and the ends 11e, 11f of the side 11b (lower side) on the emission side are connected by straight lines or curved lines. The straight lines or curved lines represent the side surfaces 11g, 11h of the transparent substrate 11.
The angles (α,β) formed by the straight lines or curved lines (the side surfaces 11g, 11h of the transparent substrate 11) and the side 11b (lower side) on the emission side are larger than 0° and smaller than 90°. It is to be noted that the angles formed by the curved lines (the side surfaces 11g, 11h of the transparent substrate 11) and the side 11b (lower side) on the emission side refer to angles formed by the tangent lines on the curved lines at the ends 11e, 11f of the side 11b (lower side) on the emission side with the side 11b (lower side) on the emission side.
The organic light emitting diode 10 of the present invention, which has the side surfaces 11g, 11h of the transparent substrate 11 with the shape as described above, can reflect light by the side surfaces 11g, 11h of the transparent substrate 11 toward the front (the side 11b on the emission side) of the transparent substrate 11, while the light is emitted from the side surfaces 31a, 31b of the transparent substrate 31 to the outside in the case of the conventional organic light emitting diode 30. As a result, the organic light emitting diode 10 of the present invention increases the use efficiency of the light.
The transparent electrode layer 12 to be used in the present invention is a layer which has high transparency, and a high electric conductivity (a low resistivity). The transparent electrode layer 12 is used as an anode for injecting holes into the organic light emitting layer 13. The resistivity of the transparent electrode layer 12 is preferably 1×10[−3] Ω·cm or less (10n is represented as 10 [n] in this specification).
The material for forming the transparent electrode layer 12 to be used in the present invention is not particularly limited, but is typically an indium tin oxide (ITO) or an indium zinc oxide (IZO). These layers are formed by, for example, a vacuum deposition method or a sputtering method. The transparent electrode layer 12 to be used in the present invention preferably has a thickness of 20 nm to 500 nm.
The organic light emitting layer 13 to be used in the present invention is a layer in which injected charges are recombined and thereby excited to produce luminescence.
The material for forming the organic light emitting layer 13 for use in the present invention is not particularly limited, but is, for example, a low-molecular luminescent pigment, a π-conjugated polymer, a pigment containing polymer, or a luminescent oligomer. These layers are formed by, for example, a vacuum deposition method or a solution applying method or the like. The organic light emitting layer 13 to be used in the present invention preferably has a thickness of 10 nm to 300 nm.
The rear electrode layer 14 to be used in the present invention is used as a cathode for injecting electrons into the organic light emitting layer 13. The material for forming the rear electrode layer 14 to be used in the present invention is not particularly limited, but is typically an alloy containing aluminum, magnesium, or lithium. The rear electrode layer 14 to be used in the present invention preferably has a thickness of 20 nm to 500 nm.
The transparent substrate 11 composed of polyethylene naphthalate of 10 mm in width, 100 μm in thickness, and 100 mm in length was prepared, and both side surfaces thereof on the long side 15 were processed by dicing into 45°-inclined surfaces. This processing produced an isosceles trapezoid in a cross section parallel to the short side 16 of the transparent substrate 11, with a basic angle α and a basic angle β each having 45°.
On the upper surface of the transparent substrate 11, the transparent electrode layer 12 composed of an indium tin oxide (ITO) of 85 nm in thickness, a hole transport layer composed of naphthyldiamine (α-NPD) of 50 nm in thickness, the organic light emitting layer 13 composed of an aluminum quinoline complex of 50 nm in thickness, and the rear electrode layer 14 composed of aluminum of 100 nm in thickness were formed sequentially by a vacuum deposition method.
Ten organic light emitting diodes 10 created in this way were prepared, and electrically connected by arranging the organic light emitting diodes 10 in a reed screen fashion as shown in
A transparent substrate composed of square polyethylene naphthalate of 100 mm in length and width was prepared, and the side surfaces on a pair of opposed sides were processed by dicing into 45°-inclined surfaces (a basic angle α and a basic angle β each having 45°). Apart from this processing, organic light emitting diodes were created by the same method as in Example 1, and electrically connected to create a square light emitting element of 100 mm in length and width. The light extraction efficiency of this light emitting element is shown in Table 1.
A transparent substrate composed of square polyethylene naphthalate of 100 mm in length and width was prepared. The transparent substrate was rectangular in a cross section parallel to the sides of the transparent substrate because the end surfaces of the transparent substrate were not processed by dicing. Apart from this processing, organic light emitting diodes were created by the same method as in Example 1, and electrically connected to create a square light emitting element of 100 mm in length and width. The light extraction efficiency of this light emitting element is shown in Table 1.
When Example 2 is compared with Comparative Example, the front luminance and the light extraction efficiency are slightly higher in Example 2. The reason is considered to be because light was reflected in the front direction by the two sides processed by dicing in Example 2, whereas any side was not processed by dicing in Comparative Example. Less light is leaked from the sides processed by dicing, whereas more light is leaked from the sides which are not processed by dicing.
When Example 1 is compared with Example 2, the front luminance and the light extraction efficiency are much higher in Example 1. The reason is considered to be because Example 1 has the twenty sides processed by dicing, whereas Example 2 has only the two sides processed by dicing. The larger number of sides processed by dicing increases the light toward the front, thus increasing the front luminance and the light extraction efficiency.
A direct-current voltage of 10 V was applied to the organic light emitting diode (light emitting element) to measure the luminance in a normal direction near the center of the light emitting element, with the use of “Organic EL Luminous Efficiency Measurement System EL 1003” manufactured by PRECISE GAUGES CO., LTD.
The organic light emitting diode and light emitting element according to the present invention are not particularly limited in application, and can be used for, for example, displays, electronic papers, electronic advertisements, and lighting or the like.
Number | Date | Country | Kind |
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2009-287164 | Dec 2009 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP2010/072232 | 12/10/2010 | WO | 00 | 4/30/2012 |