Claims
- 1. A liquid electrophotographic toner composition comprising:
a) a liquid carrier having a Kauri-Butanol number less than about 30 mL; and b) a plurality of toner particles dispersed in the liquid carrier, wherein the toner particles comprise polymeric binder comprising at least one amphipathic copolymer comprising one or more S material portions and one or more D material portions, wherein one or more of the S or D material portions comprises the residue of a Soluble High TgMonomer having a Tgat least about 20° C., wherein:
the absolute difference in Hildebrand solubility parameters between the Soluble High TgMonomer and the liquid carrier is less than about 3 MPa½; and the D portions of the amphipathic copolymer each have a Tgat least about 30° C.
- 2. The liquid electrophotographic toner composition according to claim 1 further comprising at least one visual enhancement additive.
- 3. The liquid electrophotographic toner composition according to claim 2 wherein the Soluble High TgMonomer has a Tgat least about 40° C.
- 4. The liquid electrophotographic toner composition according to claim 2 wherein the Soluble High TgMonomer has a Tgat least about 60° C.
- 5. The liquid electrophotographic toner composition according to claim 2 wherein the Soluble High TgMonomer has a Tgat least about 100° C.
- 6. The liquid electrophotographic toner composition according to claim 2 wherein the D portions of the amphipathic copolymer each have a Tgat least about 40° C.
- 7. The liquid electrophotographic toner composition according to claim 2 wherein the D portions of the amphipathic copolymer each have a Tgat least about 45° C.
- 8. The liquid electrophotographic toner composition according to claim 2 wherein the absolute difference in Hildebrand solubility parameters between the Soluble High TgMonomer and the liquid carrier is less than about 2.2 MPa½.
- 9. The liquid electrophotographic toner composition according to claim 2 wherein the Soluble High TgMonomer is selected from the group consisting of t-butyl methacrylate, n-butyl methacrylate, isobornyl(meth)acrylate, TCHMA, and combinations thereof.
- 10. The liquid electrophotographic toner composition according to claim 2 wherein the Soluble High TgMonomer is present at a concentration of between about 5 and 30% by weight of the amphipathic copolymer.
- 11. The liquid electrophotographic toner composition according to claim 1 wherein the S portions and the D portions of the amphipathic copolymer each have a Tggreater than about 45° C.
- 12. The liquid electrophotographic toner composition according to claim 1 wherein the Soluble High TgMonomer is in the D material portion of the amphipathic copolymer.
- 13. The liquid electrophotographic toner composition according to claim 1 wherein the Soluble High TgMonomer is in the S material portion of the amphipathic copolymer.
- 14. The liquid electrophotographic toner composition according to claim 1 wherein the Soluble High TgMonomer is TCHMA.
- 15. The liquid electrophotographic toner according to claim 1, wherein the S portion has a glass transition temperature calculated using the Fox equation (excluding grafting site components) of at least about 90° C.
- 16. The liquid electrophotographic toner according to claim 1, wherein the S portion has a glass transition temperature calculated using the Fox equation (excluding grafting site components) of from about 100° C. to about 130° C.
- 17. The liquid electrophotographic toner according to claim 1, wherein the S portion has a glass transition temperature calculated using the Fox equation (excluding grafting site components) of at least 90° C., and wherein the absolute difference in Hildebrand solubility parameter between the S portion and the liquid carrier is from about 2 MPa1/2 to about 3 MPa½.
- 18. The liquid electrophotographic toner according to claim 1, wherein the S portion (excluding grafting site components) has a calculated Hildebrand solubility parameter of from about 16 MPa1/2 to about 17.5 MPa½.
- 19. The liquid electrophotographic toner according to claim 1, wherein at least about 75% of the S portion (excluding grafting site components) is derived from ingredients selected from the group consisting of trimethyl cyclohexyl methacrylate; t-butyl methacrylate; n-butyl methacrylate; isobornyl(meth)acrylate; 1,6-Hexanediol di(meth)acrylate and combinations thereof.
- 20. The liquid electrophotographic toner according to claim 1, wherein at least about 90% of the S portion (excluding grafting site components) is derived from ingredients selected from the group consisting of trimethyl cyclohexyl methacrylate; t-butyl methacrylate; n-butyl methacrylate; isobornyl(meth)acrylate; 1,6-Hexanediol di(meth)acrylate and combinations thereof.
- 21. A method of making a liquid electrophotographic toner composition comprising steps of:
a) providing a dispersion of amphipathic copolymer in a liquid carrier having a Kauri-Butanol number less than about 30 mL, wherein said amphipathic polymeric comprises one or more S material portions and one or more D material portions, wherein one or more of the S or D material portions comprises the residue of a Soluble High TgMonomer having a Tgat least about 20° C., wherein:
the absolute difference in Hildebrand solubility parameters between the Soluble High TgMonomer and the liquid carrier is less than about 3 MPa½; and the D portions of the amphipathic copolymer each have a Tgat least about 30° C.; and b) mixing the dispersion with one or more ingredients comprising at least one visual enhancement additive under conditions effective to form a plurality of toner particles.
- 22. A method of electrophotographically forming an image on a substrate surface comprising steps of:
a) providing a liquid toner composition of claim 1;b) causing an image comprising the toner particles to be formed on the substrate surface; c) fusing said image on the substrate surface.
Parent Case Info
[0001] This application claims the benefit of U.S. Provisional Application Serial No. 60/425,467, filed Nov. 12, 2002, entitled “ORGANOSOL INCLUDING AMPHIPATHIC COPOLYMERIC BINDER MADE WITH SOLUBLE HIGH TG MONOMER AND LIQUID TONERS FOR ELECTROPHOTOGRAPHIC APPLICATIONS,” which application is incorporated herein by reference in its entirety.
Provisional Applications (1)
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Number |
Date |
Country |
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60425467 |
Nov 2002 |
US |