Claims
- 1. In photosensitive resin composition consisting essentially of: an unsaturated polyester having an acid value of at least 20 and present in from 0.01 to 10% by weight based on the weight of the entire composition; a cross-linking agent; and a photosensitizer; the improvement comprising:
- a cross-linking agent present in from 5 to 70% by weight based on the weight of the entire composition and consisting essentially of the combination of
- (1) a polyacrylate or polymethacrylate compound,
- (2) an acrylamide or methacrylamide compound present in from 1 to 20% by weight based on the weight of the entire composition of the formula ##STR5## wherein R is hydrogen or alkyl and X.sub.1 and X.sub.2 are organic groups, and
- (3) a compound present in from 0.5 to 40% by weight based on the weight of the entire composition and not more than 80% by weight based on the total weight of the cross-linking agent of the formula ##STR6## wherein n is an integer of at least 1, p, q, and r are 0 or an integer of at least 1, with the proviso that p+q+r equals from 2 to 6, R.sup.1 is hydrogen or methyl, R.sup.2 is lower alkyl optionally substituted with a halogen, and R.sup.3 is alkyl, aryl or saturated acyl optionally substituted with a halogen.
- 2. The improved composition of claim 1 wherein the acid value of the unsaturated polyester is at least 50.
- 3. The improved composition of claim 1 wherein said compound (3) is present in from 0.5 to 30% by weight based on the weight of the entire composition and from 10 to 70% by weight based on the weight of the cross-linking agent, and wherein said compound (2) is present in from 3 to 12% by weight on the weight of the entire composition.
- 4. The improved composition of claim 1 with the addition of a heat polymerization inhibitor present in an amount of 0.0001 to 5% by weight based on the weight of the entire composition and selected from the group consisting of phenols, hydroquinones, catechols, or picric acids.
- 5. The improved composition of claim 1 wherein compound (2) is selected from the group consisting of acrylamide, diacetone acrylamide, and methacrylamide, compound (1) is selected from the group consisting of tetraethylene glycol diacrylate, polyethylene glycol diacrylate, tetraethylene glycol dimethacrylate, and and triethylene glycol dimethacrylate, and compound (3) is selected from the group consisting of butoxyethyl methacrylate, diethylene glycol monoethyl ether methacrylate, diethylene glycol monobutyl ether methacrylate, ethoxyethyl methacrylate, 2-hydroxyethyl methacrylate acetate, diethylene glycol monomethacrylate acetate, phenoxyethyl methacrylate, and 3-chloro-2-hydroxypropyl methacrylate acetate.
- 6. The composition of claim 1 wherein said acrylamide compound is selected from the group consisting of acrylamide, diacetone acrylamide, N-methylol acrylamide, N-ethylol acrylamide, N-butyrol acrylamide, N-methyl acrylamide, N-isopropyl acrylamide, and N,N-dimethyl acrylamide; said methacrylamide compound is selected from the group consisting of methacrylamide, N-methylol acrylamide, N-ethylolacrylamide, N-butyrol acrylamide, N-methyl methacrylamide and N-isopropyl methacrylamide; said polyacrylate compound is selected from the group consisting of diethylene glycol diacrylate, triethylene glycol diacrylate, tetraethylene glycol diacrylate, polyethylene glycol diacrylate, trimethylol propane triacrylate and pentaerythritol triacrylate; and said poly methacrylate compound is selected from the group consisting of diethylene glycol dimethacrylate, triethylene glycol dimethacrylate, tetraethylene glycol dimethacrylate, polyethylene glycol dimethacrylate, dipropylene glycol dimethacrylate, polypropylene glycol dimethacrylate, trimethylol propane trimethacrylate and glycerine trimethacrylate.
- 7. The composition of claim 1 wherein said compound (2) is at least one compound selected from the group consisting of acrylamide, diacetone acrylamide, and methacrylamide.
- 8. The composition of claim 1 wherein said compound (1) is at least one compound selected from the group consisting of tetraethylene glycol diacrylate, polyethylene glycol diacrylate, tetraethylene glycol dimethacrylate, and triethylene glycol dimethacrylate.
- 9. The composition of claim 1 wherein said compound (3) is selected from the group consisting of butoxyethyl methacrylate, diethylene glycol monoethyl ether methacrylate, diethylene glycol monobutyl ether methacrylate, ethoxyethyl methacrylate, 2-hydroxyethyl methacrylate acetate, diethylene glycol monomethacrylate acetate, phenoxyethyl methacrylate, and 3-chloro-2-hydroxypropyl methacrylate acetate.
- 10. The composition of claim 1 wherein R.sup.3 is an alkyl group selected from the group consisting of methyl, ethyl, propyl and butyl, said alkyl group optionally being substituted with a halogen atom.
- 11. The composition of claim 1 wherein R.sup.3 is an aryl group selected from the group consisting of phenyl and naphthyl, wherein said aryl group may be substituted with a halogen atom.
- 12. The composition of claim 1 wherein R.sup.3 is a saturated acyl group selected from the group consisting of acetyl, propionyl, butyryl and benzoyl, wherein said saturated acyl group may be substituted with a halogen atom.
- 13. The composition of claim 9 wherein said compound (1) is at least one compound selected from the group consisting of tetraethylene glycol diacrylate, polyethylene glycol diacrylate, tetraethylene glycol dimethacrylate, and triethylene glycol dimethacrylate; said compound (2) is at least one compound selected from the group consiting of acrylamide, diacetone acrylamide, and methacrylamide; and said compound (3) has as the R.sup.3 moiety in the formula a moiety selected from the group consisting of methyl, ethyl, propyl, butyl, phenyl, naphthyl, acetyl, propionyl, butyryl, benzoyl, and their halogen substitution products.
- 14. The compound of claim 13 wherein the acid value of the unsaturated polyester is at least 50, and wherein said compound (2) is present in from 3 to 12% and said compound (3) is present in from 10 to 70%, both amounts being by weight based on the weight of the entire composition.
Priority Claims (2)
Number |
Date |
Country |
Kind |
48-72214 |
Jun 1973 |
JPX |
|
48-73596 |
Jul 1973 |
JPX |
|
Parent Case Info
This is a continuation-in-part of application Ser. No. 673,809, filed Apr. 5, 1976, which is a continuation of application Ser. No. 482,552, filed June 24, 1974 both now abandoned. Priority under 35 U.S.C. 119 is claimed based upon Japanese patent application No. 72214/48, filed June 28, 1973 and Japanese patent application No. 73596/48, filed July 2, 1973.
US Referenced Citations (7)
Foreign Referenced Citations (3)
Number |
Date |
Country |
48-14173 |
May 1973 |
JPX |
51-999 |
Jan 1976 |
JPX |
1304112 |
Jan 1973 |
GBX |
Continuations (1)
|
Number |
Date |
Country |
Parent |
482552 |
Jun 1974 |
|
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
673809 |
Apr 1976 |
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