Claims
- 1. A photographic element comprising a light sensitive silver halide emulsion layer having associated therewith an open chain .alpha.-carbonyl acetanilide yellow dye-forming coupler having the formula: ##STR14## wherein R.sub.1 is selected from the group consisting of alkyl, aryl, heterocyclic, and amino groups, provided that R.sub.1 may form a ring bonded to another carbon atom which is a member of Ring "A";
- each R.sub.2 is independently selected from the group consisting of those substituents having a Hammett's sigma value of 0 or less, and m is from 0 to 4;
- each R.sub.3 and R.sub.4 for each of the n carbon atoms is independently selected from the group consisting of hydrogen, alkoxy, aryl, heterocyclic, aryloxy, and alkyl groups, and n is 0 to 16;
- each R.sub.5 is independently selected from the group consisting of halogen, amino, alkyl groups, and groups linked to the "B" ring by oxygen or sulfur, and p is 0 to 3, provided that two R.sub.5 groups may join to form a ring;
- ring each L is independently a divalent linking group selected from the group consisting of ##STR15## wherein R is hydrogen or an alkyl group and R' is an alkylene group and q is 0 to 3;
- Ring "A" is bonded indirectly to the 3-, 4-, or 5-position of Ring "B";
- R.sub.6 is selected from the group consisting of alkyl, aryl, and amino groups; and
- Z is hydrogen, or a group capable of coupling-off when the coupler reacts with an oxidized color developing agent said coupling-off group selected from the group consisting of:
- (a) an arylthio group;
- (b) a heterocyclic group containing, in a five or six membered ring, one or two nitrogen atoms, wherein the group Z is bonded to the remainder of the coupler through a nitrogen atom in the ring; and
- (c) a benzotriazole group wherein the group Z is bonded to the remainder of the coupler through a nitrogen atom in the triazole group.
- 2. The element of claim 1 wherein m is at least 1.
- 3. The element of claim 2 wherein there is at least one R.sub.2 substituent on ring "A" ortho to the acyloxy group to which R.sub.1 is attached.
- 4. The element of claim 3 wherein said at least one R.sub.2 substituent on ring "A" ortho to the acyloxy group to which R.sub.1 is attached contains branching.
- 5. The element of claim 4 wherein said at least one R.sub.2 substituent on ring "A" ortho to the acyloxy group to which R.sub.1 is attached is a branched alkyl group.
- 6. The element of claim 5 wherein said at least one R.sub.2 substituent on ring "A" ortho to the acyloxy group to which R.sub.1 is attached contains at least 3 carbon atoms.
- 7. The element of claim 6 wherein said at least one R.sub.2 substituent on ring "A" ortho to the acyloxy group to which R.sub.1 is attached is selected from the group consisting of i-propyl, t-butyl, t-amyl, t-octyl, and adamantyl groups.
- 8. The element of claim 1 wherein R.sub.1 contains at least 4 carbon atoms.
- 9. The element of claim 1 wherein at least one R.sub.5 is bonded at the 2-,4-, or 6-position of ring "B".
- 10. A photographic element comprising a light sensitive silver halide emulsion layer having associated therewith an open chain .alpha.-carbonyl acetanilide yellow dye-forming coupler having the formula: ##STR16## wherein R.sub.1 is selected from the group consisting of alkyl, aryl, heterocyclic, and amino groups, provided that R.sub.1 may form a ring bonded to another carbon atom which is a member of Ring "A";
- each R.sub.2 is independently selected from the group consisting of those substituents having a Hammett's sigma value of 0 or less, wherein there is at least one R.sub.2 substituent on ring "A" ortho to the acyloxy group to which R.sub.1 is attached, and m is from 1 to 4;
- each R.sub.3 and R4 for each of the n carbon atoms is independently selected from the group consisting of hydrogen, alkoxy, aryl, heterocyclic, aryloxy, and alkyl groups, and n is 0 to 16;
- each R.sub.5 is independently selected from the group consisting of halogen, amino, alkyl groups, and groups linked to the "B" ring by oxygen or sulfur, and p is 0 to 3, provided that two R.sub.5 groups may join to form a ring;
- each L is independently a divalent linking group and q is 0 to 3;
- Ring "A" is bonded indirectly to the 3-, 4-, or 5-position of Ring "B";
- R.sub.6 is selected from the group consisting of alkyl, aryl, and amino groups; and
- Z is hydrogen, or a group capable of coupling-off when the coupler reacts with an oxidized color developing agent said coupling-off group selected from the group consisting of:
- (a) an arylthio group;
- (b) a heterocyclic group containing, in a five or six membered ring, one or two nitrogen atoms, wherein the group Z is bonded to the remainder of the coupler through A nitrogen atom in the ring; and
- (c) a benzotriazole group wherein the group Z is bonded to the remainder of the coupler through a nitrogen atom in the triazole group.
- 11. The element of claim 10 wherein q is at least 1 and each L comprises a member selected from the group consisting of: ##STR17## wherein R is hydrogen or an alkyl group and R' is an alkylene group.
- 12. The element of claim 10 wherein said at least one R.sub.2 substituent on ring "A" ortho to the acyloxy group to which R.sub.1 is attached contains branching.
- 13. The element of claim 12 wherein said at least one R.sub.2 substituent on ring "A" ortho to the acyloxy group to which R.sub.1 is attached is a branched alkyl group.
- 14. The element of claim 13 wherein said at least one R.sub.2 substituent on ring "A" ortho to the acyloxy group to which R.sub.1 is attached is selected from the group consisting of i-propyl, t-butyl, t-amyl, t-octyl, and adamantyl groups.
- 15. The element of claim 13 wherein R.sub.1 contains at least 4 carbon atoms.
- 16. The element of claim 10 wherein at least one R.sub.5 is bonded at the 2-,4-, or 6-position of ring "B".
- 17. A process for forming a color image comprising imagewise exposing an element as desribed in claim 1 and then contacting the element with a color developing agent.
CROSS-REFERENCE TO RELATED APPLICATIONS
This application is a continuation-in-part of U.S. Ser. No. 08/680,743, filed Jul. 15, 1996, now abandoned, which is in turn a continuation-in-part of U.S. Ser. No. 08/565,517 filed Nov. 30, 1995, now abandoned.
US Referenced Citations (1)
Number |
Name |
Date |
Kind |
5677114 |
Lussier et al. |
Oct 1997 |
|
Foreign Referenced Citations (3)
Number |
Date |
Country |
56-030126 |
Mar 1981 |
JPX |
63-85631 |
Apr 1988 |
JPX |
63-97951 |
Apr 1988 |
JPX |
Continuation in Parts (2)
|
Number |
Date |
Country |
Parent |
680743 |
Jul 1996 |
|
Parent |
565517 |
Nov 1995 |
|